KR0156222B1 - Coning oil composite - Google Patents
Coning oil composite Download PDFInfo
- Publication number
- KR0156222B1 KR0156222B1 KR1019940001760A KR19940001760A KR0156222B1 KR 0156222 B1 KR0156222 B1 KR 0156222B1 KR 1019940001760 A KR1019940001760 A KR 1019940001760A KR 19940001760 A KR19940001760 A KR 19940001760A KR 0156222 B1 KR0156222 B1 KR 0156222B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- corning
- oil
- oil composition
- smoothness
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
- D06M11/05—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof with water, e.g. steam; with heavy water
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Lubricants (AREA)
Abstract
본 발명은 코닝오일 조성물에 관한 것으로, 좀 더 상세하게는 석유계 광물유 50 내지 85중량%, 폴리옥시에틸렌 알킬 에테르(6 내지 10몰) 5내지 10중량%, 분자량 450 내지 800의 폴리에틸렌 글리콜 모노 올레이트 0 내지 10중량%, 채종유 글리세라이드 0 내지 10중량%, 이소옥틸 스테아레이트 0 내지 35중량%, 라우릴 포스페이트 0 내지 5중량%, 라우릴 알콜 0 내지 5중량% 및 기타 첨가제로 이루어진 코닝오일 조성물에 관한 것이다.The present invention relates to a Corning oil composition, more specifically, 50 to 85% by weight of petroleum mineral oil, 5 to 10% by weight of polyoxyethylene alkyl ether (6 to 10 moles), polyethylene glycol monool having a molecular weight of 450 to 800 Corning oil, consisting of 0 to 10% by weight of rape oil glycerides, 0 to 35% by weight of isooctyl stearate, 0 to 5% by weight of lauryl phosphate, 0 to 5% by weight of lauryl alcohol and other additives It relates to a composition.
Description
본 발명은 코닝오일(Coning oil) 조성물에 관한 것으로, 좀 더 상세하게는 합성섬유 및 천연섬유 코닝작업시 섬유와 금속(F/M)간에 평활성을 높이고, 얀(Yarn)과 가이드(Guide)간의 마찰저항을 감소시켜서 제직을 용이하게 하며 세정제거성이 우수하므로 후속공정(정련, 염색, 가공등)에서의 장해가 전혀 없으며, 정전기발생을 억제하고, 비산이나 모우가 발생되지 않으며 착색 및 변색이 생기지 않도록 하는 코닝오일 조성물에 관한 것이다.The present invention relates to a Corning oil (Coning oil) composition, and more particularly, to improve the smoothness between the fiber and metal (F / M) during the synthetic and natural fiber corning operation, between the yarn (Yarn) and the guide (Guide) It is easy to weaving by reducing frictional resistance and has excellent cleaning and removal ability, so there is no obstacle in the subsequent process (refining, dyeing, processing, etc.), it prevents the generation of static electricity, does not cause scattering or shading, and does not cause coloring and discoloration. To a corning oil composition.
일반적으로 코닝오일은 윤활성, 평활성, 대전방지성, 집속성 및 세정성 등의 조건을 고루 갖추어야 하는바, 비이온이나 음이온 계면활성제들은 상기 조건을 복합적으로 갖는 경우가 많으므로 이를 적절히 혼합하여 사용하는 것이 매우 중요하다.In general, Corning oil should be equipped with conditions such as lubricity, smoothness, antistatic property, concentrating property and detergency. Since non-ionic or anionic surfactants often have the above conditions, they may be mixed and used properly. It is very important.
그러나, 종래의 코닝오일을 구성하는 여러 가지 화학성분들은 통상적으로 서로 상반되는 특성을 갖고 있는바(참조 : JAOCS, Vol 65, No. 01(October 1988), 즉, 평활성(lubricity)이 우수하면 집속성(Cohesiveness)이나 내열성(Heat resistance)이 불량하고, 집속성이 우수하면 평활성이나 사이징성(Sizing)이 불량하며, 또한 사이징성이 우수한 음이온 계면활성제를 다량으로 사용하게 되면 평활성이나 내열성이 불량하였다.(일본 공개특허 제73-22793호, 제73-64294호, 제73-82195호 및 제74-31994호).However, the various chemical constituents of the conventional corning oil generally have opposite characteristics (see JAOCS, Vol 65, No. 01 (October 1988), that is, if the lubricity is excellent, Poor cohesiveness and heat resistance, poor concentration, poor smoothness and sizing, and large amounts of anionic surfactants with excellent sizing properties resulted in poor smoothness and heat resistance. (JP-A-73-22793, 73-64294, 73-82195 and 74-31994).
이러한 문제점을 해결하기 위하여 본 발명은 합성섬유 및 천연섬유 코닝작업시 현장의 생산설비나 제조조건들에 의해서도 코닝오일에 요구되는 성능은 다양해지게 되므로 상술한 바와 같은 상반되는 요구성능을 갖는 성분들을 특정 배합기술에 의하여 배합시키므로써 화학성분들이 상승효과를 발휘할 수 있도록 하는데 기초하여 완성되었다.In order to solve this problem, the present invention may vary the performance required for Corning oil even by the production facilities or manufacturing conditions in the field during the synthetic and natural fiber corning operation, so that the components having the opposite performance requirements as described above are specified. The formulation was completed based on the compounding technique to allow the chemical components to exert a synergistic effect.
따라서, 본 발명의 목적은 가격이 저렴하고 코닝작업시 윤활성, 유화액 안정성 및 방적성이 우수한 코닝오일 조성물을 제공하는데 있다.Accordingly, it is an object of the present invention to provide a Corning oil composition which is inexpensive and has excellent lubricity, emulsion stability and spinning properties during Corning operations.
상기 목적을 달성하기 위한 본 발명의 조성물은 석유계 광물유 50 내지 85중량%, 폴리옥시에틸렌 알킬 에테르(6 내지 10몰) 5 내지 10중량%, 분자량 450 내지 800의 폴리에틸렌 글리콜 모노 올레이트 0 내지 10중량%, 채종유 글리세라이드 0 내지 10중량%, 이소옥틸 스테아레이트 0 내지 35중량%, 라우릴 포스페이트 0 내지 5중량%, 라우릴 알콜 0 내지 5중량% 및 기타 첨가제로 이루어진다.The composition of the present invention for achieving the above object is 50 to 85% by weight of petroleum mineral oil, 5 to 10% by weight of polyoxyethylene alkyl ether (6 to 10 mol), polyethylene glycol monooleate 0 to 10 of molecular weight 450 to 800 Weight percent, oilseed oil glycerides 0-10%, isooctyl stearate 0-35%, lauryl phosphate 0-5%, lauryl alcohol 0-5% and other additives.
이하 본 발명을 좀 더 구체적으로 살펴보면 다음과 같다.Looking at the present invention in more detail as follows.
전술한 바와 같이, 본 발명에서는 각종 섬유업계의 공정시 현장 생산설비나 제조 조건들에 따라 코닝오일에 대한 요구사항이 다변화되므로 여러 가지 요구성능을 갖출 수 있는 혼합기술(blending)에 의해 각 성분들을 배합시켜 각종 화학물질들이 그 특성을 최대로 발휘될 수 있도록 하였다.As described above, in the present invention, since the requirements for Corning oil are diversified according to on-site production facilities or manufacturing conditions during the processing of various textile industries, each component is mixed by blending technology that can have various requirements. It was formulated to allow various chemicals to maximize their properties.
본 발명에 사용된 석유계 광물유는 코닝공정시에 제품에 윤활성 및 평활성을 향상시킬 목적으로 사용되며, 동점도가 40℃에서 8cSt 내지 96cSt를 갖는 광물유를 50 내지 85중량%로 사용하는 것이 바람직한데, 동점도가 8cSt 미만인 경우에는 윤활성 및 평활성이 다소 불충분하고 96cSt를 초과하는 고점도를 갖는 경우에는 점도과다로 인한 오염의 위험과 평활성이 불량해질 소지가 있다. 또한, 광물유는 각각의 점도를 갖는 성분을 혼합하여 사용할 수 있으며, 50중량%이하로 사용할 경우에는 윤활성이 떨어져 섬유절단이 생길수가 있고, 85중량%이상으로 사용할 경우에는 유화성 및 세정제거성이 저하되어 무라 및 오염이 생겨 양질의 섬유생산에 문제가 발생될 수 있다.Petroleum-based mineral oil used in the present invention is used for the purpose of improving lubricity and smoothness to the product during the Corning process, it is preferable to use a mineral oil having a kinematic viscosity of 8cSt to 96cSt at 40 ℃ to 50 to 85% by weight, If the kinematic viscosity is less than 8 cSt, the lubricity and smoothness is somewhat insufficient, and if the kinematic viscosity is higher than 96 cSt, the risk of contamination and smoothness may be poor due to excessive viscosity. In addition, mineral oil can be used by mixing the components having each viscosity, and when used at 50% by weight or less, the lubricity is poor, fiber cutting may occur, and when used at 85% by weight or more, the emulsification and detergency are deteriorated Mura and contamination can cause problems in the production of high quality fibers.
상기 폴리옥시에틸렌 알킬에테르는 코닝공정시에 제품에 유화성, 습윤성, 세정성 및 침투성을 향상시킬 목적으로 사용되며, 그 사용랑은 5 내지 10중량%가 바람직하다. 이때 폴리옥시에틸렌 알킬에테르가 5중량%이하일 경우에는 세정제거성이 떨어져 염색공정 등에서 문제가 발생될 위험이 있고 10중량%이상 사용의 경우에는 윤활성 및 평활성, 집속성이 저하되어서 섬유절단이 생기므로 주의해야 한다. 또한, 폴리옥시에틸렌은 6내지 10몰의 몰수를 갖는 것이 바람직하다.The polyoxyethylene alkyl ether is used for the purpose of improving emulsification, wettability, detergency, and permeability to the product during the corning process, the use of which is preferably 5 to 10% by weight. At this time, if the polyoxyethylene alkyl ether is less than 5% by weight, there is a risk that problems occur in the dyeing process, etc., and in the case of using more than 10% by weight, the lubricity, smoothness, and concentration may decrease, resulting in fiber cutting. Should be. In addition, the polyoxyethylene preferably has a molar number of 6 to 10 moles.
본 발명에 있어서, 0 내지 10중량%로 사용되는 분자량 450 내지 800의 폴리에틸렌 글리콜 모노 올레이트는 제품에 평활성, 윤활성 및 유화성을, 0내지 10중량%로 사용되는 채종유 글리세라이드, 0 내지 35중량%로 사용되는 이소옥틸 스테아레이트는 제품에 평활성 및 윤활성을 향상시킬 목적으로 사용되며, 0 내지 5중량%로 사용되는 라우릴 포스페이트 및 라우릴 알콜은 대전방지성에 탁월한 효과를 가진 음이온 계면활성제로서 제품에 대전방지성 및 윤활성을 향상시킬 목적으로 사용되나, 5중량%이상 사용할 때에는 점도를 필요이상으로 상승시키고 유화성을 불량하게 하고 섬유에 오염을 가중시켜 오히려 역효과를 낼수 있기 때문에 적당량 사용해야 한다. 하지만 평활성, 윤활성, 집속성, 대전방지성 등과 같은 어느 특수한 성질이 많이 요구될 때에는 성질에 맞는 첨가제를 많이 투입하는 경우도 있다. 상기 성분들은 코닝공정시 현장 생산설비나 제조 조건들에 따라 선택적으로 첨가되어 코닝오일을 구성 하는바, 이러한 코닝오일은 유화액이 아닌 원액을 그대로 섬유에 묻혀서 사용하며, 그 구체적인 예는 실시예에 기재하였다.In the present invention, polyethylene glycol monooleate having a molecular weight of 450 to 800, which is used at 0 to 10% by weight, is a rapeseed oil glyceride which is used at 0 to 10% by weight for smoothness, lubricity and emulsification in a product. Isooctyl stearate, used in%, is used for the purpose of improving smoothness and lubricity in products. Lauryl phosphate and lauryl alcohol, used in 0 to 5% by weight, are anionic surfactants with excellent antistatic properties. It is used for the purpose of improving the antistatic property and lubricity. However, when it is used more than 5% by weight, an appropriate amount should be used because the viscosity may be increased more than necessary, the emulsification property may be poor, and the fiber may be adversely affected. However, when certain special properties such as smoothness, lubricity, focusing property, antistatic property, and the like are required, a lot of additives suitable for the properties may be added. The components are selectively added according to the on-site production equipment or manufacturing conditions during the Corning process to form Corning oil, such Corning oil is used by embedding the raw liquid in the fiber as it is not an emulsion, specific examples thereof are described in the Examples It was.
본 발명에 사용된 기타첨가제는 비이온성으로 유화성을 갖는 소프타놀(50) 0 내지 7중량%, 원액의 pH가 6이하가 되면 액의 부패와 변색이 촉진될 우려가 있으므로 3중량%이하의 수산화칼륨(48.5% KOH), 원액의 점도를 향상시킬 수 있는 이온교환수 0 내지 5중량%, 윤활성 및 금속 마모 방지성을 갖는 인산에스테르 0 내지 5중량%, 글리세린 지방산 에스테르 0 내지 10중량%, 코코낫 디에타놀아마이드 0 내지 5중량% 및 솔비톨지방산 에스테르 0 내지 10중량%로 이루어진다.Other additives used in the present invention 0 to 7% by weight of non-ionic emulsifying sorbtanol (50), when the pH of the stock solution is 6 or less, there is a risk of promoting the decay and discoloration of the solution of less than 3% by weight Potassium hydroxide (48.5% KOH), 0 to 5% by weight of ion-exchanged water which can improve the viscosity of the stock solution, 0 to 5% by weight of phosphate ester having lubricity and metal abrasion resistance, 0 to 10% by weight of glycerin fatty acid ester, It consists of 0 to 5% by weight of coconat diethanolamide and 0 to 10% by weight of sorbitol fatty acid ester.
전술한 바와 같이, 일반적인 코닝오일은 유화액이 아닌 원액을 그대로 섬유장에 묻혀서 사용하게 되므로 점도와 윤활성관계는 밀접하다. 따라서, 본 발명의 코닝오일 원액 동점도는 40℃에서 10cSt 내지 50cSt까지 다양하게 선택하여 각종기계으 요구성능과 다양한 제품의 요구를 모두 수용하였다.As described above, in general, Corning oil is used as the original liquid rather than the emulsion is buried in the fiber length as it is closely related to the viscosity and lubricity. Therefore, the Corning oil stock solution kinematic viscosity of the present invention was variously selected from 10 cSt to 50 cSt at 40 ° C. to accommodate both the performance and various product requirements.
이하 실시예 및 비교예를 통하여 본 발명의 구성 및 효과를 좀 더 구체적으로 살펴보지만, 하기 예에 본 발명의 범주가 한정되는 것은 아니다.Although the configuration and effects of the present invention will be described in more detail with reference to the following Examples and Comparative Examples, the scope of the present invention is not limited to the following Examples.
[실시예 1]Example 1
하기 표1에 기재된 성분과 함량으로 제조된 코닝오일 원액을 나일론에 O.P.U(Oil pick up) 상태로 2%를 부착시켜 그 성능 및 효과를 시험하였다.본 실시예에 의한 조성물은 평활성, 내열성, 제전성, 균일 부착성이 뛰어나 후속공정에서의 트러블(trouble)을 극소화시킬수 있다.The Corning oil stock solution prepared with the ingredients and contents shown in Table 1 was attached to nylon in an OPU (Oil pick up) state to test 2% of its performance and effect. Excellent malleability and uniform adhesion can minimize troubles in subsequent processes.
[실시예 2]Example 2
실시예1에서 하기 표2에 기재된 성분과 함량으로 변경시킨 것을 제외하고는 실시예1과 동일하게 실시하였다. 본 실시예에 의한 조성물은 천연섬유 및 합성섬유의 코닝공정에 적용하는 것이 바람직하다.Example 1 was the same as in Example 1 except for changing to the components and contents shown in Table 2. The composition according to the present embodiment is preferably applied to the corning process of natural fibers and synthetic fibers.
[실시예 3]Example 3
실시예1에서 하기 표3에 기재된 성분과 함량으로 변경시킨 것을 제외하고는 실시예1과 동일하게 실시하였다. 본 실시예에 의한 조성물은 합성 필라멘트 NSY용으로 평활성, 접속성 및 내금속마모성이 우수하여 소량의 무착량으로도 우수한 효과를 얻을 수 있다.Example 1 was the same as in Example 1 except for changing to the components and contents shown in Table 3. The composition according to the present embodiment is excellent in smoothness, connectivity and wear resistance of metal for synthetic filament NSY, so that an excellent effect can be obtained even with a small amount of unbonded.
[실시예 4]Example 4
실시예1에서 하기 표4에 기재된 성분과 함량으로 변경시킨 것을 제외하고는 실시예1과 동일하게 실시하였다.Example 1 was the same as in Example 1 except for changing to the components and contents shown in Table 4.
[실시예 5]Example 5
실시예1에서 하기 표5에 기재된 성분과 함랴으로 변경시킨 것을 제외하고는 실시예1과 동일하게 실시하였다.Example 1 was carried out in the same manner as in Example 1 except for changing to the components shown in Table 5.
[실시예6]Example 6
실시예 1에서 하기 표6에 기재된 성분과 함량으로 변경시킨 것을 제외하고는 실시예1과 동일하게 실시하였다.Example 1 was the same as in Example 1 except for changing to the components and contents shown in Table 6.
[비교예1 내지 2][Comparative Examples 1 and 2]
실시예1에서 하기 표7 및 8에 기재된 성분과 함량으로 변경시킨 것을 제외하고는 실시예1과 동일하게 실시하였다. 본 실시예에 사용된 성분들은 상기 실시예1 내지 6에 사용된 것과 동일한 성분들이다.Example 1 was the same as in Example 1 except for changing to the components and contents shown in Tables 7 and 8. The components used in this example are the same components as those used in Examples 1 to 6 above.
상기 실시예1 내지 6 및 비교예 1 내지 2에 따른 유제에 대해 평활성, 집속성, 대전방지성, 내금속마찰성, 내타르성, 내열성시험 및 세정제거성시험을하여 하기 표9에 나타내었고 그 측정방법은 다음과 같다.The emulsions according to Examples 1 to 6 and Comparative Examples 1 to 2 were shown in Table 9 below by performing smoothness, focusing, antistatic property, metal friction resistance, tar resistance, heat resistance test and cleaning removal test. The method is as follows.
1) 평활성 시험1) smoothness test
시편을 벤젠-에탄올 혼합용액으로 세척시킨 후 급유기를 이용하여 O.P.U가 3내지 4중량%가 되도록 각 처리용 유제를 균일하게 부착시킨 다음, 24시간동안 콘디쇼닝한 시료사를 μ-Meter(일본, Elko Co, 모델 TWD-4)마찰계수 측정기를 이용하여 섬유/금속(F/M)간의 마찰계수를 아래와 같은 측정조건으로 평활성능을 측정하였다.The specimens were washed with a benzene-ethanol mixture solution, and then each oil was uniformly attached so that the OPU was 3 to 4% by weight using an oil feeder, and then the sample yarn was conditioned for 24 hours. The friction coefficient between fiber / metal (F / M) was measured by Elko Co, Model TWD-4) Friction Coefficient Measuring Machine.
마찰계 : 표면크롬 이지처리된 직경 16mm의 철계 환통Friction gauge: 16 mm diameter steel cylinder with surface chrome
접촉각 : 90˚ 초기장력 : 20gContact Angle: 90˚ Initial Tension: 20g
주행속도 : 300m/분 분위기 : 25℃, RH 65%Travel Speed: 300m / min Atmosphere: 25 ℃, RH 65%
2) 집속성 시험2) focusing test
평활성 시험에서와 동일한 시료사로서 10개의 필라멘트의 100g의 하중을 달아놓고, 마찰을 300회 반복 실시한 후 필라멘트를 무게중심으로 되돌려 놓은 다음에 필라멘트의 손상이나 루프발생 여부를 관찰하였다.The same sample yarn as in the smoothness test was loaded with 100g of 10 filaments, and after repeated friction 300 times, the filament was returned to the center of gravity, and then the filament was damaged or looped.
3) 대전방지성 시험3) Antistatic test
평활성 시험에서와 동일한 시료사에 대하여 μ-Meter에서 시료사가 마찰제를 지난 직후, 집전식 전위 측정기를 주행사로 향하게하여 주행 사의 발생대전압을 측정하였다.Immediately after the sample yarn passed the friction agent at μ-Meter for the same yarn as in the smoothness test, the generated potential voltage of the traveling yarn was measured with the current collector potential meter facing the traveling yarn.
4) 금속마찰시험4) Metal Friction Test
직경 800mm인 유압실린더에 쇠구슬(Ball) 3개를 넣고 시료 30중량% 유화액 70cc를 넣은 후 내하중 시험기에 넣고 1500rpm의 속도로 회전시켜 쇠구슬이 마모될 때 압력을 측정한다.Three ball balls (Ball) are put in a hydraulic cylinder having a diameter of 800 mm, and 70 cc of a 30 wt% emulsion is put into a load tester. The pressure is measured when the ball is worn by rotating at a speed of 1500 rpm.
5) 타르화 시험5) Tarization Test
직경 3.5cm의 원형도가니에 방모방적용 유제 원시료를 약 2g을 정확히 측량하고 전기로(HY-MFI)에 넣고 700 내지 800℃에서 30분간 가열하였다가 최종적으로 타르화 물질을 아세톤으로 세척한 다음 접시에 남아있는 타트량을 계산한다.After measuring exactly 2 g of raw materials for spinning spinning emulsion in a round crucible having a diameter of 3.5 cm, it was placed in an electric furnace (HY-MFI), heated at 700 to 800 ° C. for 30 minutes, and finally the tar material was washed with acetone. Calculate the amount of tart remaining on the plate.
6) 내열성 시험6) heat resistance test
직경 1cm, 높이 10cm의 시험관에 유제원액을 넣고 가드너 칼라(Gardner Color)를 측정하고, 다른 시험관에 유제를 넣고 200℃에서 2시간동안 방치하였다가 가드너 칼라를 측정하여 비교한다.Emulsion stock is added to a test tube having a diameter of 1 cm and a height of 10 cm, and the Gardner Color is measured. The oil is placed in another test tube and allowed to stand at 200 ° C. for 2 hours, and the Gardner color is measured and compared.
평가기준(최초 유제의 가드너 칼라와 열을 가한 유제의 가드너 칼라의 차이)Evaluation standard (difference between gardner color of the first emulsion and gardner color of the heated emulsion)
7) 변색시험7) Discoloration test
유제를 30중량% 유화시켜 가로 5cm, 세로 7cm의 시편을 3분간 담근 다음 상온에서 24시간 건조시킨후, 자외선 램프속에서 24시간동안 노출시켜 백도율(%)를 측정한다.The emulsion was emulsified in 30 wt%, soaked 5 cm long and 7 cm long specimens for 3 minutes, dried at room temperature for 24 hours, and then exposed for 24 hours in an ultraviolet lamp to measure whiteness (%).
8) 세정제거성 시험8) Detergency test
물 400g에 유제 0.8g을 혼합한 시료액을 45 내지 50℃로 가열하여 시편 20g을 넣고 20분간 교반한 다음 물에 3번 씻어내어 105℃인 열풍 건조기에 1시간동안 건조시킨 후 무게를 달아 아래의 식에 의하여 소숫점이하 2자리까지 계산한다.Heat the sample liquid mixed with 0.8 g of oil and 400 g of water to 45 to 50 ° C., add 20 g of the specimen, stir for 20 minutes, rinse three times in water, dry for 1 hour in a hot air dryer at 105 ° C., weigh down Calculate up to two decimal places using the equation
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940001760A KR0156222B1 (en) | 1994-01-31 | 1994-01-31 | Coning oil composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940001760A KR0156222B1 (en) | 1994-01-31 | 1994-01-31 | Coning oil composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR950023695A KR950023695A (en) | 1995-08-18 |
| KR0156222B1 true KR0156222B1 (en) | 1998-12-01 |
Family
ID=19376547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019940001760A KR0156222B1 (en) | 1994-01-31 | 1994-01-31 | Coning oil composite |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR0156222B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101010291B1 (en) * | 2010-09-17 | 2011-01-25 | 김정수 | Ecological self-cleaning knitting/coning oil compsition and method therefor |
| CN104389164A (en) * | 2014-11-28 | 2015-03-04 | 何庆堃 | Printing and dyeing pretreatment aid for silk fabric finishing |
-
1994
- 1994-01-31 KR KR1019940001760A patent/KR0156222B1/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101010291B1 (en) * | 2010-09-17 | 2011-01-25 | 김정수 | Ecological self-cleaning knitting/coning oil compsition and method therefor |
| CN104389164A (en) * | 2014-11-28 | 2015-03-04 | 何庆堃 | Printing and dyeing pretreatment aid for silk fabric finishing |
Also Published As
| Publication number | Publication date |
|---|---|
| KR950023695A (en) | 1995-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4995884A (en) | Polyalphaolefin emulsions for fiber and textile applications | |
| US3664855A (en) | Size for fibers and glass fibers coated therewith | |
| AU765393B2 (en) | Spin finish | |
| US4552671A (en) | Spin finish compositions for polyester and polyamide yarns | |
| JP2008063713A (en) | Fiber treating agent and method for producing synthetic fiber using the same | |
| US4561987A (en) | Lubricating agents for processing synthetic yarns and method of processing synthetic yarns therewith | |
| CN114687212A (en) | High-temperature-resistant wear-resistant spinning oil and preparation method thereof | |
| US4066558A (en) | Low viscosity spin finish systems for neat finish application | |
| EP0077406B1 (en) | Lubricant for treating synthetic fibers | |
| US3687721A (en) | Polyester multifilament yarns | |
| KR0156222B1 (en) | Coning oil composite | |
| EP0778822A1 (en) | Novel polyol esters of ether carboxylic acids and fiber finishing methods | |
| US5648010A (en) | Lubricant for air entanglement replacement | |
| KR0156234B1 (en) | Slip composite for wool spinning | |
| US4900455A (en) | Finishes for stable fibers of synthetic polymers | |
| US4725371A (en) | Partially oriented polyester yarn emulsion finish with elevated pH | |
| US2956949A (en) | Fiber treating compositions | |
| US2622045A (en) | Process of conditioning cellulose acetate yarn and product resulting therefrom | |
| KR100873552B1 (en) | polypropylene spinning oil composition | |
| KR930005935B1 (en) | Spinning oil composition for polyester fiber | |
| KR100402175B1 (en) | Lubricant products for spining in textile industry | |
| Bajaj | Spin finishes for manufactured fibres | |
| KR900008701B1 (en) | Spin finish for polyester fialment | |
| CA1219252A (en) | Fatty acid esters of phenol derivative alkoxylates and their use as fiber finish components | |
| KR920006474B1 (en) | A composition of fiber lubricant for un-drawn of polyester filament |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E701 | Decision to grant or registration of patent right | ||
| N231 | Notification of change of applicant | ||
| GRNT | Written decision to grant | ||
| LAPS | Lapse due to unpaid annual fee |