KR0148205B1 - Apparatus and method for manufacture of oil by combination thermal decomposition used waste ires/oils - Google Patents
Apparatus and method for manufacture of oil by combination thermal decomposition used waste ires/oilsInfo
- Publication number
- KR0148205B1 KR0148205B1 KR1019950014824A KR19950014824A KR0148205B1 KR 0148205 B1 KR0148205 B1 KR 0148205B1 KR 1019950014824 A KR1019950014824 A KR 1019950014824A KR 19950014824 A KR19950014824 A KR 19950014824A KR 0148205 B1 KR0148205 B1 KR 0148205B1
- Authority
- KR
- South Korea
- Prior art keywords
- oil
- waste
- pyrolysis
- tires
- reactor
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C2201/00—Codes relating to disintegrating devices adapted for specific materials
- B02C2201/06—Codes relating to disintegrating devices adapted for specific materials for garbage, waste or sewage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/46—Constructional details of screens in general; Cleaning or heating of screens
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B15/00—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form
- F26B15/10—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form with movement in a path composed of one or more straight lines, e.g. compound, the movement being in alternate horizontal and vertical directions
- F26B15/105—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form with movement in a path composed of one or more straight lines, e.g. compound, the movement being in alternate horizontal and vertical directions the articles, e.g. can lids, discs, being conveyed by means of rotating screw spindles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
본 발명은 가열된 폐유내에서 폐타이어를 열분해 반응시켜 오일화하기 위한 열분해 반응조건과 장치 및 그 방법에 관한 것으로 열분해 반응시 온도를 380℃로 낮추고 폐타이어와 폐유의 공급비를 2:1하여 분해시킴으로서 폐유에 대한 폐타이어의 처리량을 높이고 열효율을 증대시켰으며 반응기내 첨가제 수산화 칼슘[Ca(OH)2]을 첨가하여 열분해 생성오일중의 유황분과 염소등의 유해물질의 함유량을 최소화하였고, 열분해 장치의 기계적 결함을 해소하기 위해 폐유가열장치, 폐타이어의 연속공급장치, 열분해 반응기 및 잔유물 건조기의 장치상의 문제점을 개선한 폐타이어/폐유의 복합열분해에 의한 오일화 장치.The present invention relates to a pyrolysis reaction condition, an apparatus and a method for pyrolyzing waste tires in a heated waste oil and to oiling the waste tires. By decomposing, it increased the throughput of waste tire to waste oil and increased the thermal efficiency. The addition of additive calcium hydroxide [Ca (OH) 2 ] in the reactor minimized the content of harmful substances such as sulfur and chlorine in the pyrolysis generating oil. An oilification apparatus by waste pyrolysis of waste tires / waste oil which improves the problems of waste oil heating device, continuous supply of waste tires, pyrolysis reactor and residue dryer to solve the mechanical defect of
Description
제1도는 본 발명의 오일화공정을 나타낸 장치의 개념도1 is a conceptual diagram of an apparatus showing the oilification process of the present invention
제2도는 제1도의 열분해 반응기의 상세도2 is a detailed view of the pyrolysis reactor of FIG.
제3도는 제1도의 잔류물 건조기의 상세도3 is a detailed view of the residue dryer of FIG.
*도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1:폐타이어 파쇄기 2:저장조1: Waste tire shredder 2: Storage tank
3:2중댐퍼 4:폐유 가열로3: 2 double dampers 4: Waste oil heating furnace
5:증발탑 6:열분해 반응기5: evaporation column 6: pyrolysis reactor
7:잔류물 건조기 8:급냉조7: residue dryer 8: quench bath
9:슬럿지 분리조 10:응축기9: slot separator 10: condenser
11:가스/오일 분리기 12:유수 분리기11: Gas / Oil Separator 12: Oil Water Separator
13:열풍로 14:잔류물 배출기13: Hot stove 14: Residue ejector
15:철심 분리기 16:파쇄기15: Iron core separator 16: Crusher
17:체 분리기17: sieve separator
본 발명은 출원인의 선특허 발명인 93특허공고 11919호의 원리를 이용하고 그 세부적인 방법과 장치를 개선한 이용발명에 관한 것이다. 최근 자동차수의 증가에 따라 폐타이어의 발생량이 급증하고 있으며 이로 인한 환경문제가 크게 대두되고 있으나 아직은 재활용이나 대량을 경제성있게 처리할 수 있는 방법이 없는 실정이다.The present invention relates to a use invention which uses the principle of Applicant's prior patent invention 93 Patent Publication No. 11919 and improves its detailed method and apparatus. As the number of automobiles is increasing recently, the amount of waste tires is rapidly increasing, and environmental problems are increasing. However, there is no way to economically process recycling or mass production.
폐타이어의 재활용 방법은 가공이용, 재생이용, 에너지원으로의 이용 기술로 구분할 수 있으며 그중 에너지원으로의 이용기술은 직접소각 및 연소, 건류가스화 소각, 열분해에 의한 오일화 기술로 분류할 수 있다. 일반적으로 폐타이어는 열을 가하면 저분자 상태로 분해가 이루어지는 열분해성 성분과 분해가 되지 않는 비분해성 성분으로 구성되어 있고, 열분해성 성분은 약50%이상이 되며 철심을 제외한 비분해성 성분은 주로 타이어 원료로 사용되는 카본블랙과 각종 첨가제로 사용된 무기물로 구성되어 있다.The recycling method of waste tires can be classified into technology for processing, recycling, and energy. Among them, technology for energy source can be divided into direct incineration and combustion, dry gasification incineration and oilification by pyrolysis. . In general, waste tires are composed of thermally decomposable components that are decomposed to low molecular weight upon application of heat, and non-degradable components that do not decompose. The thermally decomposable component is about 50% or more. It is composed of carbon black and inorganic materials used as various additives.
폐타이어를 분해반응온도 이상으로 가열하면 고분자 사슬(Porymer Chain)이 절단 분해되어 가스화가 이루어지고 비분해성 물질은 고체상태의 잔류물로 남게되며 가스화 물질을 응축하여 오일을 얻고 비응축성 가스는 가스상태로 얻게 된다.When the waste tire is heated above the decomposition reaction temperature, the polymer chain is cleaved and decomposed to make gasification, and the non-degradable material remains as a solid residue, condensing the gasified material to obtain oil, and the non-condensable gas is in a gaseous state. You get
그러므로 폐타이어의 열분해에 의한 오일화 방법에서 열분해 반응조건은 기술의 핵심이라 할 수 있으며 열분해 반응조건에 따라 생성오일의 성상이나 수율 그리고 가열 에너지의 소모량에 차이가 생기고 관련공정의 구성이나 장치의 구조가 달라지게 된다.Therefore, the pyrolysis reaction condition is the core of the technology in the process of oilification by pyrolysis of waste tires, and depending on the pyrolysis reaction conditions, there are differences in the properties, yields, and consumption of heating energy. Will be different.
폐타이어는 열전도성이 비교적 낮아 전열성이 떨어지므로 가열시 전열효과를 높이기 위한 가열방법이 필요하며 열분해시에 저온에서는 분해효율이 낮으므로 대부분500℃이상의 고온에서 열분해를 한다. 그러나 고온열분해를 하는 경우 오일보다는 가스의 생성량이 증가하며 생성오일의 품질이나 잔류물의 품질이 불균일해지고 또한 열분해 반응기내의 벽면에 탄화된 물질이 부착되어 장치의 열효율을 저하시키기 쉬운 등의 문제점이 있다.Waste tires are relatively low in thermal conductivity and thus inferior in heat transfer, so a heating method is required to enhance the heat transfer effect during heating. Most of them are pyrolyzed at high temperatures of 500 ° C. or higher since they have low decomposition efficiency at low temperatures. However, the high temperature pyrolysis increases the amount of gas produced rather than oil, and the quality of the generated oil or the residue is uneven, and carbonized materials are attached to the walls of the pyrolysis reactor, thereby reducing the thermal efficiency of the device.
현재 사용되고 있는 미국 Nu-Tec, System, ATR사등은 열분해 반응기로서 로타리 킬톤형의 반응기를 사용하여 500-700℃ 범위에서 열분해 하고 있으며 이때 오일수율은 폐타이어 량의 40wt.%정도를 얻었으며, 독일 함부르크대의 유동층 반응기에서는 700-800℃로 가열하여 열분해하며 이때 오일의 생성수율은 30%내외이며 고온에서 열분해하므로 다량의 가스가 생성되는 단점이 있다.Nu-Tec, System, and ATR, which are currently in use, are pyrolyzed in the range of 500-700 ℃ using a rotary kilton type reactor as a pyrolysis reactor, and the oil yield is about 40wt.% Of the amount of waste tire. In the fluidized bed reactor of Hamburg University, pyrolysis is heated to 700-800 ° C. At this time, the yield of oil is about 30% and there is a disadvantage in that a large amount of gas is generated due to pyrolysis at high temperature.
그리고 미국특허 원유(crude oil)에 수산화 칼슘을 접촉시켜 유흥분을 제거하는 방식으로 특허청구범위1에서 9까지 모두 원유룰 대상으로 하고 있으나 본 발명은 폐타이어를 열분해하여 생성되는 일과 수산화칼슘을 접촉시켜 폐타이어중의 유황성분과 염소성분을 제거하는 것으로서 유황성분 제거 대상물질이 원유가 아니고 폐타이어이며 염소성분에 대해서는 미국 특허에 전혀 포함되지 않은 사항이다.And to claim the crude oil rules by contacting calcium hydroxide in the United States patent crude oil (crude oil) to remove the entertainment, but the present invention is to contact the work produced by thermal decomposition of the waste tire and calcium hydroxide The removal of sulfur and chlorine from waste tires is not a crude oil, but a waste tire, and chlorine is not included in the US patent.
저온 열분해 방법은 열분해 반응시 촉매를 사용하여 반응온도를 낮추는 방법과 열분해 반응기내에서 폐타이어를 가열시 공기외의 가열매체를 사용하여 전열효과를 높이는 등의 방법이 있으며 본 발명에서는 후자의 방법인 공기외의 가열매체를 사용하여 열분해하는 방식으로 자동차에서 사용하고 폐기한 폐윤활유를 활용하여 가열시킨 폐유내에서 폐타이어를 열분해하여 오일화하는 방법으로 폐타이어를 가열된 폐유내에서 열분해하면 폐유는 폐타이어에 대하여 고무를 부풀게하는 성질 즉 팽윤제(Swelling)의 역할에 의해 물질전달 및 열전달을 촉진하므로 저온에서 열분해가 가능하고 반응기내 폐타이어에 국부가열 방지와 균일한 가열이 가능케 하므로 오일회수율이 높으며 생성오일이나 잔류물의 품질이 균일하게 되는 등의 특징이 있다.The low-temperature pyrolysis method includes a method of lowering the reaction temperature by using a catalyst during the pyrolysis reaction and a method of increasing heat transfer effect by using a heating medium other than air when heating waste tires in the pyrolysis reactor. When the pyrolysis of waste tires in the heated waste oil is carried out by pyrolysing the waste tire in the waste oil heated by using waste lubricating oil which has been used in automobiles and wasted by using other heating media. It promotes mass transfer and heat transfer by the property of swelling rubber, that is, the role of swelling agent, so it can be thermally decomposed at low temperature and prevents localized heating and uniform heating to waste tires in the reactor. The oil and residues are uniform in quality.
또한 열분해 반응시 중요한 반응조건으로 폐타이어와 폐유의 공급비, 반응온도, 체류시간, 첨가제의 사용등의 주요조건이 있으며 본 발명에서는 열분해 온도를 380℃로 낮추고 폐타이어와 폐유의 공급비를 2:1하여 분해시킴으로서 폐유에 대한 폐타이어의 처리량을 높이고 열효율을 증대시켰으며 반응기내에 첨가제 수산화 칼슘을 첨가하여 열분해 생성오일중의 유황분과 염소등의 유해물질의 함유량을 최소화 하였다. 또한 폐유의 가열방법을 개선하였고 열분해 장치의 기계적 결함을 해소하기위해 폐타이어의 연속공급장치, 열분해반응기 잔류물 건조기 장치상의 문제점을 개선한 본 발명을 창출한 것이다.In addition, there are major conditions such as supply ratio of waste tire and waste oil, reaction temperature, residence time, and use of additives as important reaction conditions in the pyrolysis reaction. In the present invention, the thermal decomposition temperature is reduced to 380 ° C. and the supply ratio of waste tire and waste oil is 2 By disassembling by 1: 1, the waste tires to waste oil was increased, thermal efficiency was increased, and additive calcium hydroxide was added to the reactor to minimize the content of harmful substances such as sulfur and chlorine in the oil of pyrolysis. In addition, to improve the heating method of the waste oil and to solve the mechanical defects of the pyrolysis device, the present invention has been developed to improve the problems of the continuous supply of waste tires, pyrolysis reactor residue dryer device.
이하 발명의 요지를 첨부된 도면에 연계시켜 그 구성과 작용효과를 상세히 설명하면 다음과 같다.Hereinafter, the configuration and the effect of the present invention will be described in detail with reference to the accompanying drawings.
제1도는 본 발명의 오일화공정을 나타낸 장치의 개념도이고 제2도는 열분해 반응장치의 상세도이며 제3도는 잔류물 건조장치의 상세도이다. 폐타이어 파쇄기(1)에서 파쇄된 폐타이어는 저장조(2)에 저장되어 2중 댐퍼(3)를 거쳐 정량적으로 열분해 반응기(6)로 공급되며, 파쇄된 폐타이어를 연속공급 할 때 외부공기가 열분해 반응기(6)로 유입되거나 내부의 오일증기가 외부로 유출되는 것을 방지하기 위하여 두밸브 사이의 공간에 차있는 가스를 질소가스로 퍼지시키고 배출되는 가스는 소각시킨다. 폐유는 폐유가열로(4)에서 예열하여 증발탑(5)에서 저비점분을 제거한 후 고비점의 유분만을 열분해 반응기(6)에 공급하며, 폐타이어와 폐유의 공급비율을 2:1로 하고, 열분해 반응기(6)내의 온도는 380℃로 유지시킨다. 상기한 폐타이어가 열분해 반응기(6)로 공급되면 스크류에 의해 열분해 반응기(6)의 하부에서 상부로 이송되면서 열분해 반응이 이루어져 가스상이 되고 열분해되지 않은 슬럿지 상태의 잔류물은 스크류에 의해 계속 이송되어 배출구를 통해 건조기(7)로 배출된다.1 is a conceptual diagram of an apparatus showing the oilification process of the present invention, FIG. 2 is a detailed diagram of a pyrolysis reaction apparatus, and FIG. 3 is a detailed diagram of a residue drying apparatus. Waste tire shredded in the waste tire shredder (1) is stored in the storage tank (2) and supplied to the pyrolysis reactor (6) quantitatively through the double damper (3), when the external air is continuously supplied The gas filled in the space between the two valves is purged with nitrogen gas in order to prevent the inflow of the pyrolysis reactor 6 or the oil vapor therein to the outside, and the discharged gas is incinerated. The waste oil is preheated in the waste oil heating furnace (4) to remove the low boiling point component from the evaporation tower (5), and then only the oil having a high boiling point is supplied to the pyrolysis reactor (6), and the feed ratio of waste tire and waste oil is 2: 1, The temperature in the pyrolysis reactor 6 is maintained at 380 ° C. When the waste tire is supplied to the pyrolysis reactor 6, the pyrolysis reaction is carried out by transferring from the lower portion of the pyrolysis reactor 6 to the upper portion of the pyrolysis reactor 6 to obtain a gaseous phase, and the residue in the sludged state which is not pyrolyzed is continuously transferred by the screw. It is discharged to the dryer 7 through the discharge port.
또한 열분해 생성오일중의 유황분과 염소등의 유해물질을 제거하기 위하여 반응기(6)내에 수산화칼슘[Ca(OH)2]첨가제를 폐타이어량의 5% 이내로 첨가시킨다.In addition, calcium hydroxide [Ca (OH) 2 ] additive is added to the reactor 6 within 5% of the amount of waste tire in order to remove harmful substances such as sulfur and chlorine in the pyrolysis generating oil.
열분해 반응기(6)에서 생성된 열분해 가스는 급냉조(8)에 도입되어 급냉조(8)상부로부터 냉각오일의 분사에 의해 중질유분의 응축이 이루어지고 중질유분에 함유된 입자들과 타르성분은 슬럿지 분리조(9)로 보내 정치하여 슬럿지를 제거한다.The pyrolysis gas generated in the pyrolysis reactor 6 is introduced into the quench tank 8 to condense heavy oil by spraying cooling oil from the top of the quench tank 8, and the particles and tar components contained in the heavy oil are The sludge is sent to the sludge separation tank (9) to remove the sludge.
급냉조(8)에서 응축되지 않은 가스상은 응축기(10)를 거친후 가스-오일 분리기(11)로 보내져 경질유분과 비응축성 가스가 분리되며 경질유분은 유수 분리기(12)에 모아서 정치하여 상분리가 일어나도록 한다. 가스-오일 분리기(11)에서 분리된 비응축성 가스는 폐유가열로(4)와 열풍로(13)의 연료로 사용되며 열분해 반응기(6)에서 슬럿지 상태로 배출된 잔류물은 스크류 건조기(7)에서 열풍로(13)의 연소가스에 의해 간접가열되어 일부 열분해가 이루어지면서 건조되며 건조된 잔류물은 이중댐퍼로 구성되어 있는 잔류물 배출기(14)로 배출되고 이를 냉각시켜 철심분리기(15), 파쇄기(16) 및 체 분리기(17)의 과정을 거쳐 제품의 잔류물 상태로된다.The non-condensed gas phase in the quench tank (8) passes through the condenser (10) and is sent to the gas-oil separator (11) to separate light and non-condensable gases, and the light oil is collected in the oil / water separator (12) to allow phase separation. To do that. The non-condensable gas separated from the gas-oil separator (11) is used as fuel for the waste oil heating furnace (4) and the hot stove (13), and the residue discharged in the sludge state from the pyrolysis reactor (6) is screw dryer (7). Indirectly heated by the combustion gas of the hot stove 13 to dry some of the pyrolysis and dried residue is discharged to the residue discharger 14 consisting of a double damper and cooled to iron core separator (15), Through the process of the crusher 16 and the sieve separator 17, it is brought to the residue state of the product.
그리고 폐타이어와 폐유를 열분해시 오일생성량을 아래 표1에 대표적인 경우를 나타내었다.And the oil production amount when pyrolysis of waste tires and waste oil is shown in Table 1 below.
상기한 표1에서와 같이 폐타이어로부터 오일생성량은 50%로서 기존의 외국 타공정에 비해 수율이 높게 나타남을 알 수 있으며 잔류물의 성상도 탄화(Coking)현상없이 비교적 일정하게 나타나고 있음을 알 수 있다. 열분해 방응시 첨가제 수산화 칼슘[Ca(OH)]을 폐타이어 량의 5%를 첨가하였을 때 열분해 오일중의 유해물질의 함유량을 아래 표2에 나타내었다.As shown in Table 1, the amount of oil produced from waste tires is 50%, which indicates that the yield is higher than that of other foreign processes, and the properties of residues are relatively constant without carbonization. . Table 2 shows the contents of harmful substances in pyrolysis oil when 5% of the amount of waste tire was added to additive calcium hydroxide [Ca (OH)].
상기한 표2에서와 같이 열분해 오일중의 유황분 및 염소분의 감소효과는 유황분 함유량이 0.47%에서 0.39%로 약 17%감소되었고, 염소분은 150ppm에서 106ppm으로 약7%의 감소 효과를 볼 수 있었다. 아래 표3에서는 열분해 생성오일의 분석치를 KS공업규격과 비교분석한 것을 나타내었다.As shown in Table 2, the sulfur and chlorine content of the pyrolysis oil was reduced by about 17% from 0.47% to 0.39% of sulfur content, and the chlorine content was reduced by about 7% from 150ppm to 106ppm. . Table 3 below shows the comparative analysis of the pyrolysis generated oil with KS Industrial Standard.
상기한 표3에서와 같이 오일의 규격은 대략적으로 경유나 경질중유의 중간정도를 나타내고 있다.As shown in Table 3, the specification of the oil indicates the intermediate degree of light oil or light heavy oil.
그러므로 본 발명은 최근 자동차의 증가에 따른 폐타이어와 폐윤활유등의 다대한 증가에 대처하여 보다 진전된 열분해에 의한 오일화 기술의 적용으로 환경문제를 해결할 뿐만아니라 새로운 에너지원으로서 활용할 수 있는 매우 유용한 발명인 것이다.Therefore, the present invention is very useful to solve the environmental problems as well as to solve the environmental problems by applying the more advanced pyrolysis oilification technology to cope with the enormous increase of the waste tire and the waste lubricating oil with the recent increase of automobiles. It is an invention.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950014824A KR0148205B1 (en) | 1995-06-05 | 1995-06-05 | Apparatus and method for manufacture of oil by combination thermal decomposition used waste ires/oils |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950014824A KR0148205B1 (en) | 1995-06-05 | 1995-06-05 | Apparatus and method for manufacture of oil by combination thermal decomposition used waste ires/oils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970001511A KR970001511A (en) | 1997-01-24 |
| KR0148205B1 true KR0148205B1 (en) | 1998-08-01 |
Family
ID=19416526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950014824A KR0148205B1 (en) | 1995-06-05 | 1995-06-05 | Apparatus and method for manufacture of oil by combination thermal decomposition used waste ires/oils |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR0148205B1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100864904B1 (en) * | 2005-07-20 | 2008-10-22 | (주)기경아이이앤드씨 | Apparatus for making oil and generating electricity with used hot gas |
| WO2009018202A2 (en) * | 2007-07-30 | 2009-02-05 | Recarbon, Inc. | Process for recycling polymeric waste materials |
| US7842106B2 (en) | 2007-07-30 | 2010-11-30 | Recarbon Corp. | Process for using polymeric waste materials to produce fuel |
| US8066785B2 (en) | 2007-07-30 | 2011-11-29 | Recarbon Corp. | Process for recycling waste materials |
| KR20230053760A (en) * | 2021-10-14 | 2023-04-24 | 김남용 | Eco-friendly hybrid waste resource treatment system with Emulsification line and heat source sharing and filtration recovery circulation line |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100473763B1 (en) * | 2002-09-28 | 2005-03-10 | 천지득 | Recycling machine of waste tire for oil, carbon and wire core by auto continuous process |
| KR102676398B1 (en) * | 2021-06-03 | 2024-06-20 | 노영수 | Manufacturing process of recyled oil using continuous waste vinyl pyrolysis unit with screw pre-heating unit |
-
1995
- 1995-06-05 KR KR1019950014824A patent/KR0148205B1/en not_active IP Right Cessation
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100864904B1 (en) * | 2005-07-20 | 2008-10-22 | (주)기경아이이앤드씨 | Apparatus for making oil and generating electricity with used hot gas |
| WO2009018202A2 (en) * | 2007-07-30 | 2009-02-05 | Recarbon, Inc. | Process for recycling polymeric waste materials |
| WO2009018202A3 (en) * | 2007-07-30 | 2009-03-19 | Recarbon Inc | Process for recycling polymeric waste materials |
| US7842106B2 (en) | 2007-07-30 | 2010-11-30 | Recarbon Corp. | Process for using polymeric waste materials to produce fuel |
| US8066785B2 (en) | 2007-07-30 | 2011-11-29 | Recarbon Corp. | Process for recycling waste materials |
| KR20230053760A (en) * | 2021-10-14 | 2023-04-24 | 김남용 | Eco-friendly hybrid waste resource treatment system with Emulsification line and heat source sharing and filtration recovery circulation line |
Also Published As
| Publication number | Publication date |
|---|---|
| KR970001511A (en) | 1997-01-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110451754B (en) | Harmless treatment method for oil sludge pyrolysis | |
| CN110848697B (en) | Waste plastic cleaning treatment process based on pyrolysis and gasification mechanism and application thereof | |
| CA2899362C (en) | Thermal process to transform contaminated or uncontaminated feed materials into useful oily products | |
| CN110451753B (en) | Treatment method of dangerous solid waste oil sludge | |
| DE4446803A1 (en) | Utilising residues and e g household and industrial waste material | |
| US8696937B2 (en) | Process for obtaining petrochemical products from carbonaceous feedstock | |
| US3925190A (en) | Preheating oil shale prior to pyrolysis thereof | |
| US20210348072A1 (en) | Process of Treating Carbonaceous Material and Apparatus Therefor | |
| WO2010053555A1 (en) | Conversion of carbon based material to natural gas and activated carbon | |
| KR0148205B1 (en) | Apparatus and method for manufacture of oil by combination thermal decomposition used waste ires/oils | |
| US4246093A (en) | Handling of solids-laden hydrocarbonaceous bottoms in a retort using solid heat-carriers | |
| EP3031881A1 (en) | Method of pyrolytic processing of polymer waste from the recycling of food packaging and a system for carrying out such method | |
| CN111019711B (en) | Thermal cracking gasification process for household garbage | |
| US4175929A (en) | Process for control of pollutants generated during coal gasification | |
| CN106701247A (en) | Method for preparing tar residue solid fuel by pyrolyzing tar residue | |
| US1639417A (en) | Method of carbonizing fuel | |
| WO2010150272A1 (en) | System and method for material recycling and resource recovery | |
| KR100695457B1 (en) | Preparation for the clean reforming gas and recycling vitrification materials from the waste oil and sludge containing and equipment thereof | |
| US4203960A (en) | Coke desulphurization | |
| KR930011919B1 (en) | Thermal cracking process for production of liquid hydrocarbon mixtures from waste tires | |
| RU2780256C1 (en) | Method for obtaining liquid products during thermal decomposition of solid carbon-containing raw materials | |
| US4373995A (en) | Pyrolysis system utilizing pyrolytic oil recycle | |
| KR20010067332A (en) | Process and plant for processing liquid and/or solid organic waste substances | |
| RU2791389C1 (en) | Thermolysis method and system for obtaining reduced soot and fuel from used tires | |
| US20240051823A1 (en) | Carbonization and pyrolyzation method and system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20130522 Year of fee payment: 16 |
|
| FPAY | Annual fee payment |
Payment date: 20140522 Year of fee payment: 17 |
|
| FPAY | Annual fee payment |
Payment date: 20150520 Year of fee payment: 18 |
|
| EXPY | Expiration of term |