KR0137843B1 - Preparation method of bio-ceramics synthetic aqueous paint - Google Patents

Preparation method of bio-ceramics synthetic aqueous paint

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KR0137843B1
KR0137843B1 KR1019940010960A KR19940010960A KR0137843B1 KR 0137843 B1 KR0137843 B1 KR 0137843B1 KR 1019940010960 A KR1019940010960 A KR 1019940010960A KR 19940010960 A KR19940010960 A KR 19940010960A KR 0137843 B1 KR0137843 B1 KR 0137843B1
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water
aqueous paint
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KR950032513A (en
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곽성근
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곽성근
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/23—Magnetisable or magnetic paints or lacquers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 하기 제 1, 제2, 제3 공정을 결합함을 특징으로 하는 바이오 세라믹스 합성 수성 페인트의 제조방법에 관한 것이다:The present invention relates to a method for producing a bioceramic synthetic water paint, comprising combining the following first, second and third processes:

제 1공정;First step;

천연의 사문암에 각섬석 6∼10중량%와 지르코늄실리케이트 1∼3중량%를 섞어 1,150℃∼1,300℃에서 소성한 다음 300메쉬 이상으로 분쇄하여 원적외선 방사 자성체 분말을 얻는다.6-10% by weight of biotite and 1-3% by weight of zirconium silicate are mixed with natural serpentine and calcined at 1,150 ° C to 1,300 ° C and then pulverized to 300 mesh or more to obtain far-infrared radiation magnetic powder.

제 2공정;Second process;

산화티탄 8∼12중량부, 탈크 20∼25중량부, 유화제 2∼3중량부, 분산제 10∼20중량부, 25% 암모니아수 0.2중량부, 안정제 2∼3중량부, CaCO3분말 8∼12중량부, 방부제 0.1∼0.3중량부, EG0.8∼1.2중량부, 아크릴수지에멀죤 40∼50중량부와 용제인 물80∼150중량부를 혼합하여 수성페인트 조성물을 얻는다.8 to 12 parts by weight of titanium oxide, talc and 20 to 25 parts by weight, 2 to 3 parts by weight of an emulsifier, a dispersing agent of 10 to 20 parts by weight of 25% ammonia water 0.2 part by weight of stabilizer 2-3 parts by weight of a CaCO 3 powder, 8 to 12 wt. In addition, 0.1-0.3 weight part of preservatives, 0.8-1.2 weight part of EG, 40-50 weight part of acrylic resin emulsions, and 80-150 weight part of water which are solvents are mixed, and an aqueous paint composition is obtained.

제 3공정;Third process;

제 1공정에서 얻은 원적외선 방사 자성체 분말을 제 2공정에서 얻은 수성페인트 조성물중에 5∼20중량%가 함유되도록 혼합조성한다.The far-infrared radiation magnetic powder obtained in the first step is mixed and mixed to contain 5 to 20% by weight of the aqueous paint composition obtained in the second step.

Description

바이오(원적외선 방사) 세라믹스 합성 수성페인트 제조방법Bio (Far Infrared Radiation) Ceramics Synthetic Aqueous Paint Manufacturing Method

본 발명은 바이오 세라믹스 합성수성페인트 제조방법에 관한 것으로, 더 상세하게는 원적외선 방사기능과 자성을 띈 원적외선방사 세라믹스가 배합된 합성수성 페인트를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a bio ceramics synthetic aqueous paint, and more particularly, to a method for preparing a synthetic aqueous paint containing a far infrared radiation ceramics having a far infrared radiation function and magnetic properties.

우리들의 조상은 원적외선을 모르면서도 원적외선이 방사되는 온돌을 이용하였고 진흙으로 지은 한증막에서 땀을 흘리며 건강관리를 하였으며, 동의보감에서도 맥반석이 피부병, 부스럼, 여드름 등의 상처치유와 진통에 탁월한 효능이 있다고 기술되어 있는 등의 사실로 미루어 보아 원적외선 방사체를 우리 생활 주변에 놓고 원적외선을 이용하여 왔다는 사실을 알 수 있다.Our ancestors used ondol which emits far-infrared rays without knowing far-infrared rays, and took care of their health by sweating in a mud-steamed steam room. Even in Dongbogam, elvan has excellent efficacy in healing and pain relief of skin disease, swelling, acne, etc. In fact, we can see that far infrared emitters have been used around our lives and have used far infrared rays.

원적외선은 생체에 닿게 되면 빨리 따뜻하게 되고 생체의 혈액순환을 촉진시키고 식물의 동화작용에 중요한 역할을 하므로써 일명 생육광선이라고 불리어지고 있다. 원적외선에 대하여 최근 국내외에서 많은 연구결과가 발표되고 있으며, 그 중에서 배우현 교수는 원적외선이 생체에 영향을 미치는 파장대는 8∼14미크론이고 이 파장대의 원적외선이 생체내에 있는 물에 방사하게 되면 원적외선의 열에너지가 생체내에 있는 물 분자의 결합각도를 104.5°에서 104.8°로 변화시켜 준다는 사실을 관찰하고 이와 같은 각도의 변화가 생체내의 물분자를 활성화한다고 발표(1995. 6. 발행 월간 세라믹 원적외선 및 벤적외선 이용기술에 관한 자료집 제 1권)하였고, 이 준근 박사는 FT-1R분광계를 이용하여 원적외선 방사율 및 방사각도를 측정하는 방법을 발표(1995.6 발행 월간 세라믹 원적외선 및 원적외선 이용기술에 관한 자료집 제 1권)하는 등 원적외선이 물을 함유하고 있는 생체를 활성화시켜주는 원인과 원적외선의 방사율 및 방사강도까지도 측정할 수 있게 되어 원적외선 방사물질 및 원적외선 방사원리를 산업에 이용하는 연구를 활발하게 진행시킬 수 있게 되었다.Far infrared rays are called warm growth rays because they warm up quickly when they come in contact with the living body and promote vital blood circulation and play an important role in the assimilation of plants. Recently, many research results have been published in Korea and abroad. Among them, Prof. Actor Hyun says that far infrared rays affect the living body with 8 to 14 microns, and when far infrared rays are radiated to the living water, the thermal energy of far infrared rays Observing the change in the binding angle of water molecules in the body from 104.5 ° to 104.8 °, the change in angle activates water molecules in vivo. Dr. Lee has published a method for measuring far-infrared emissivity and radiation angle using the FT-1R spectrometer (Volume 1 on monthly ceramic far-infrared and far-infrared technology) published by 1986. The cause of the activation of living organisms containing water by far infrared rays, the emissivity of far infrared rays, Radiation intensity can also be measured, enabling research to use far-infrared radiation and far-infrared radiation in the industry.

한편 지구상의 모든 생물은 지자기속에서 생존하고 있으며 인체에 대한 자력의 보충은 인체건강에 유리하다는 각종 연구 결과가 발표되고 있으나, 그 메카니즘에 대하여도 아직 많은 과학자들이 연구중에 있다.On the other hand, all the living things on earth are living in the geomagnetic field, and various research results suggest that supplementing magnetic force to the human body is beneficial to human health, but many scientists are still studying the mechanism.

본 발명자들은 바이오 세라믹의 합성과 이용에 관한 연구를 거듭하던 중 사문암, 각섬석(약 6∼10중량%)과 지르코늄실리케이트(약 1∼3중량%)를 1150℃내지 1300℃, 더 좋게는 1,250℃이상의 고온에서 소성한 다음 325메쉬정도로 분쇄하여 본 바 원적외선 방사율이 높고(93%이상)강력한 자성을 띄고 있음을 발견하게 되었고, 이를 5∼20중량%배합하여 수성페인트를 조성하여 본 바 바이오에라믹스의 효과인 방취, 가열 등의 효과이외에 자력에너지에 의하여 수성페인트의 건조가 빠르고 작업장 주변의 악취를 분해하며, 수성페인트의 응집력이 강하게 되어 내부스트레스에 의한 균열방지 및 피도장재와의 접착력이 향상되는 효과가 있다는 것을 발견하게 되었다.The inventors of the present invention have been conducting studies on the synthesis and use of bio-ceramic, in which serpentine, hornblende (approximately 6-10 wt%) and zirconium silicate (approximately 1-3 wt%) are 1150 to 1300 ° C, more preferably 1,250 ° C. After firing at the above high temperature, it was pulverized to about 325 mesh, and it was found that the far-infrared emissivity was high (over 93%) and it showed strong magnetism. It was mixed with 5 to 20% by weight to form an aqueous paint. In addition to the effects of deodorization, heating, etc., magnetic paints can dry the water paint quickly and decompose bad smells around the workplace, and the cohesive force of the water paint becomes stronger, preventing cracking due to internal stress and improving adhesion to the coating material. I found it effective.

본 발명품이 강력한 자력을 가지게 된 것은 사문암과 각섬석 그리고 지르코늄실리케이트를 1,250℃이상의 높은 온도에서 소성하는 과정에서 철성분과 바리움성분이 BaO·6Fe2O3를 형성하고 일부 철분이 Fe2O3로 잔존하게 됨에 따른 것으로 추정하고 이를 분석하여 본 결과 BaO·6Fe2O33.55%, Fe2O32.62%가 각각 함유되어 있었다.The present invention has a strong magnetic force in the process of calcining serpentine, hornblende and zirconium silicate at a temperature higher than 1,250 ° C. The iron and barium components form BaO · 6Fe 2 O 3 and some iron remains as Fe 2 O 3 . As a result of the analysis, it was found that BaO · 6Fe 2 O 3 3.55% and Fe 2 O 3 2.62%, respectively.

BaO·6Fe2O3는 값이 비싸고 손에 넣기 어려운 3CoO·Fe2O3·FeO·Fe2O3로 구성된 소위 OP자석의 자보력보다도 자보력이 약 30% 정도 큰 1,000 에르스테드에 달하는 특징을 지니고 있다.BaO · 6Fe 2 O 3 is 1,000 Ersted, which is about 30% larger than the magnetism of the so-called OP magnet, which is composed of 3CoO, Fe 2 O 3 , FeO, Fe 2 O 3 , which is expensive and difficult to obtain. It has features.

본 발명의 바이오 세라믹스 합성수성 페인트의 제조방법은 하기의 제1, 제2, 제3공정으로 이루어짐을 특징으로 한다:Method for producing a bio-ceramic synthetic water-based paint of the present invention is characterized by consisting of the following first, second, third process:

제 1공정;First step;

천연의 사문암에 각섬석 6∼10중량%와 지르코늄실리케이트 1∼3중량%를 섞어 1,150℃∼1,300℃에서 소성한 다음 300메쉬 이상으로 분쇄하여 원적외선 방사 자성체 분말을 얻는 공정,6-10% by weight of biotite and 1-3% by weight of zirconium silicate mixed with natural serpentine and calcined at 1,150 ° C to 1,300 ° C and then pulverized to 300 mesh or more to obtain far-infrared radioactive magnetic powder,

제 2 공정;Second process;

산화티탄 8∼12중량부, 탈크 20∼25중량부, 유화제 2∼3중량부, 분산제 10∼20중량부, 25% 암모니아수 0.2중량부, 안정제 2∼3중량부, CaCO3분말 8∼12중량부, 방부제 0.1∼0.3중량부, EG 0.8∼1.2중량부, 아크릴수지에멀죤 40∼50중량부와 용제인 물 80∼150중량부를 혼합하여 수성페인트 조성물을 얻는 공정,8 to 12 parts by weight of titanium oxide, talc and 20 to 25 parts by weight, 2 to 3 parts by weight of an emulsifier, a dispersing agent of 10 to 20 parts by weight of 25% ammonia water 0.2 part by weight of stabilizer 2-3 parts by weight of a CaCO 3 powder, 8 to 12 wt. To obtain the aqueous paint composition by mixing 0.1 to 0.3 parts by weight of preservative, 0.8 to 1.2 parts by weight of EG, 40 to 50 parts by weight of acrylic resin emulsion and 80 to 150 parts by weight of water as a solvent,

제 3공정;Third process;

제 1공정에서 얻은 원적외선 방사 자성체 분말을 제 2공정에서 얻은 수성페인트조성물중에 5∼20중량%가 함유되도록 혼합조성하는 공정.A process of mixing and mixing the far-infrared radiation magnetic powder obtained in the first step so that 5 to 20% by weight is contained in the aqueous paint composition obtained in the second step.

이하 본 발명을 실시예를 통하여 상세히 설명한다.Hereinafter, the present invention will be described in detail through examples.

실시예1Example 1

사문암 80중량%에 각섬석 8중량%, 지르코늄 실리케이트 2중량%를 1,150℃∼1,300℃정도의 고온에서 소성한 다음 입도가 326메쉬이상으로 분체될 정도로 분쇄하여 원적외선 방사 자성체 분말을 얻는다.80% by weight of serpentine, 8% by weight of hornblende and 2% by weight of zirconium silicate are fired at a high temperature of about 1,150 ° C to 1,300 ° C, and then pulverized to a particle size of 326 mesh or more to obtain far-infrared radiation magnetic powder.

이렇게 하여 얻은 원적외선 자성체분말이 수성페인트에 함유되도록 조성하는 방법으로는, 안료로서 TiO2R760(한국탄탄사제품)8중량부, TiO2∼KA 100(한국티탄사 제품) 2중량부, Talc 23중량부 A-Sol(알킬아닐 술포숙신에이트계 유화제, 아메리칸사이나미드사제품) 25중량부, M-Sol( PVA 중합도 1,700인 분산제, 일본 신월화학사 제품)15중량부, 25%암모니아수 0.3중량부, Zealex(안정제, 독일 HooVer사 제품) 2.44중량부, CaCO3분말 10중량부, Napcp(방부제, 소디움, 펜타클로로페놀, 미국듀폰사 제품) 0.2중량부, E.G.(에틸렌글리콜) 1중량부, STA(중합도가 약 10,000 정도의 아크릴수지에멀죤, 창성화학사제품)와 용제인 물 115중량부로 조성된 조성물에 원적외선 자성체분말이 5∼20중량%가 되도록 조성한다.As a method of formulating the far-infrared magnetic powder thus obtained to be contained in the aqueous paint, as a pigment, 8 parts by weight of TiO 2 R760 (manufactured by Tantan Co., Ltd.), 2 parts by weight of TiO 2 -KA 100 (manufactured by Titanium Company), Talc 23 Parts by weight 25 parts by weight of A-Sol (alkyl anyl sulfosuccinate-based emulsifier, manufactured by American Sinamide Co., Ltd.), 15 parts by weight of M-Sol (dispersant having a PVA degree of polymerization of 1,700, manufactured by Nippon Shinwol Chemical Co., Ltd.), 0.3 parts by weight of 25% ammonia water, Zealex (stabilizer, manufactured by HooVer, Germany) 2.44 parts by weight, CaCO 3 powder 10 parts by weight, Napcp (preservative, sodium, pentachlorophenol, US Dupont) 0.2 part by weight, EG (ethylene glycol) 1 part by weight, STA ( In a composition composed of an acrylic resin emulsion having a degree of polymerization of about 10,000 (manufactured by Changsung Chemical Co., Ltd.) and 115 parts by weight of water as a solvent, the far-infrared magnetic powder is prepared in an amount of 5 to 20% by weight.

이와 같이 조성된 자성을 띈 바이오 세라믹 합성수성페인트를 내부용도료로 사용할 때 원적외선 방사로 인한 생체에 대한 일반적인 효과 이외에도 원적외선과 자력선이 방사되므로써 시멘트 등에서 방출하는 인체에 해로운 단파를 차단하며, 수성페인트의 건조가 빠르고, 방취효과가 있어 작업성이 좋을 뿐만 아니라, 수성페인트의 응집력이 강하게 되어 수성페인트의 내부스트레스에 의한 균열이 방지되고 피도장재와의 접착력이 향상되는 효과가 있다.In addition to the general effects on living organisms caused by far-infrared radiation when the magnetic ceramic bio-contained water-based paint is used as an internal paint, far-infrared rays and magnetic force rays are radiated to block harmful shortwaves emitted by cement. Fast drying, deodorizing effect is not only good workability, but also the cohesive force of the water-based paint is strong to prevent cracking due to the internal stress of the water-based paint and improve the adhesion to the coating material.

Claims (1)

하기 제 1, 제2, 제 3공정을 결합함을 특징으로 하는 바이오 세라믹스 합성수성 페인트의 제조방법:Method for producing a bio-ceramic synthetic water-based paint, characterized in that combining the first, second, third process 제 1공정;First step; 천연의 사문암에 각섬석 6∼ 10중량%와 지르코늄실리케이트 1∼3중량%를 섞어 1,150℃∼1,300℃에서 소성한 다음 300메쉬 이상으로 분쇄하여 원적외선 방사 자성체 분말을 얻는 공정,6-10% by weight of hornblende and 1-3% by weight of zirconium silicate mixed with natural serpentine and calcined at 1,150 ° C to 1,300 ° C and then pulverized to 300 mesh or more to obtain far-infrared radiation magnetic powder, 제 2공정;Second process; 산화티탄 8∼12중량부, 탈크 20∼25중량부, 유화제 2∼3중량부, 분산제 10∼20중량부, 25% 암모니아수 0.2중량부, 안정제 2∼3중량부, CaCO3분말 8∼12중량부, 방부제 0.1∼0.3중량부, EG 0.8∼1.2중량부, 아크릴수지에멀죤 40∼50중량부와 용제인 물 80∼150중량부를 혼합하여 수성페인트 조성물을 얻는 공정,8 to 12 parts by weight of titanium oxide, talc and 20 to 25 parts by weight, 2 to 3 parts by weight of an emulsifier, a dispersing agent of 10 to 20 parts by weight of 25% ammonia water 0.2 part by weight of stabilizer 2-3 parts by weight of a CaCO 3 powder, 8 to 12 wt. To obtain the aqueous paint composition by mixing 0.1 to 0.3 parts by weight of preservative, 0.8 to 1.2 parts by weight of EG, 40 to 50 parts by weight of acrylic resin emulsion and 80 to 150 parts by weight of water as a solvent, 제 3공정;Third process; 제 1공정에서 얻은 원적외선 방사 자성체 분말을 제 2공정에서 얻은 수성페인트 조성물중에 5∼20중량%가 함유되도록 혼합조성하는 공정.A process of mixing and mixing the far-infrared radiation magnetic powder obtained in the first step so that 5 to 20% by weight is contained in the aqueous paint composition obtained in the second step.
KR1019940010960A 1994-05-20 1994-05-20 Preparation method of bio-ceramics synthetic aqueous paint KR0137843B1 (en)

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KR100467053B1 (en) * 2002-01-08 2005-01-24 (주)프리바이오 bio interior finishing mortar

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KR100476683B1 (en) * 2001-12-24 2005-03-17 주식회사 서울벽지 Anti-bacteria Wallpaper Comprising Far-Infared Light Radiation Material and Method of Making the Same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100467053B1 (en) * 2002-01-08 2005-01-24 (주)프리바이오 bio interior finishing mortar

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