KR0127865B1 - Powder detervgent composition for washing a car - Google Patents
Powder detervgent composition for washing a carInfo
- Publication number
- KR0127865B1 KR0127865B1 KR1019950008374A KR19950008374A KR0127865B1 KR 0127865 B1 KR0127865 B1 KR 0127865B1 KR 1019950008374 A KR1019950008374 A KR 1019950008374A KR 19950008374 A KR19950008374 A KR 19950008374A KR 0127865 B1 KR0127865 B1 KR 0127865B1
- Authority
- KR
- South Korea
- Prior art keywords
- powder
- give
- colloid solution
- washing
- zeolite
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 8
- 239000000843 powder Substances 0.000 title abstract description 7
- 238000005406 washing Methods 0.000 title description 6
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010457 zeolite Substances 0.000 claims abstract description 9
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 6
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims abstract description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 5
- 229920002545 silicone oil Polymers 0.000 claims abstract description 4
- CMYCPTASPDMVFC-UHFFFAOYSA-N n,n,n',n'-tetraaminoethane-1,2-diamine Chemical compound NN(N)CCN(N)N CMYCPTASPDMVFC-UHFFFAOYSA-N 0.000 claims abstract description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract description 7
- 239000000376 reactant Substances 0.000 abstract description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000084 colloidal system Substances 0.000 abstract description 5
- 239000003599 detergent Substances 0.000 abstract description 4
- 230000009931 harmful effect Effects 0.000 abstract description 4
- 235000011187 glycerol Nutrition 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- 235000006408 oxalic acid Nutrition 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000012459 cleaning agent Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000003863 physical function Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 에치렌디아민테트라아세트암모늄과 선상알킬벤젠슬폰산을 반응시킨 반응물에 지오라이트(Na2O : Al2O3: SiO2)에서 선상알칼벤젠슬폰산을 반응시킨 반응물 첨가한 혼합물에 구연산암모늄, 충진제, 침윤제 등을 첨가하여서 된 분말상 차량세척제에 관한 것이다.In the present invention, citric acid is added to a mixture of reactants reacted with ethylenediaminetetraacetammonium and linear alkylbenzenesulfonic acid in the reaction of linear alkali benzenesulfonic acid in zeolite (Na 2 O: Al 2 O 3 : SiO 2 ). The present invention relates to a powdered vehicle cleaner obtained by adding ammonium, a filler, a wetting agent and the like.
현재 차량 외부세척제로 사용되는 세척제는 주로 차량의 녹과 부착된 오염물질을 제거 또는 세척을 목적으로 하는 세척제로서 주성분이 65-75%를 차지하는 수산과 음이온 계면활성제, 비이온계면활성제, 무기질세정배합제, 금속부식방지제, 소포제 등의 성분으로 구성되는 바, 이는 수산이 주성분을 구성하므로서, 인체에 크게 유해하다는 것이 이 세척제를 장시간 처리 또는 사용한 철도 차량 세척종사원의 피해 사실로 판명되었다. 본래 수산(oxalic Acid)은 흡입 또는 섭취시 인체에 유독하고 공기중 허용한도가 1㎎/㎥으로 그 이상일때는 극히 인체에 유해하다는 것으로 알려져 있다.The cleaning agent currently used as an external vehicle cleaner is mainly intended to remove or clean the vehicle's rust and attached contaminants. It is composed of 65-75% of the active ingredient, anionic surfactants, nonionic surfactants, and inorganic cleaning compound. It is composed of components such as anti-corrosion, anti-foaming agent, which is a major component of the fish, which is very harmful to the human body has been proved to damage the railway car wash employees who have used this cleaner for a long time. Originally, it is known that oxalic acid is toxic to the human body when inhaled or ingested and extremely harmful to humans when the allowable limit in the air is 1 mg / m 3 or more.
본 발명은 수산을 주성분으로 하는 기존 세정제의 인체유해성으로 발생하는 문제점을 해소하기 위하여 시도된 것으로, 이를 구체적으로 설명하던 중량비로 에치렌디아밑테트라암모늄 30%와 선상알킬벤젠슬폰산 15%을 첨가하여 얻어진 반응생성물에 지오라이트(Na2O : Al2O3: SiO2) 10%와 선상알킬벤젠슬폰산 5%를 반응시킨 반응물을 첨가한 혼합물에 구연산암모늄 20%, 황산나트륨 10%, 아크릴아마이드 5%, 실리콘오일 2%, n-옥칠알콜 2%, 그리세린 1%을 첨가하여 충분히 교반한 다음 압축건조하여 분쇄하므로서 분말상의 연성차량세척제를 얻게 된다.The present invention has been attempted to solve the problems caused by the harmful effects of the existing detergents based on aquatic acid, 30% of ethylene di-tetraammonium and 15% linear alkylbenzenesulfonic acid in the weight ratio described in detail 20% ammonium citrate, 10% sodium sulfate and acrylamide were added to the reaction product obtained by adding a reactant obtained by reacting 10% zeolite (Na 2 O: Al 2 O 3 : SiO 2 ) with 5% linear alkylbenzenesulfonic acid. 5%, 2% silicon oil, 2% n-oxyl alcohol, 1% gryserine is sufficiently stirred and then compressed and dried to obtain a soft car washing powder.
위의 방법에서 세척제의 주성분을 구성하는 에치렌디아닌테트라아세트암모늄은 에치렌디아민테트라아세트산 1몰과 암노니아수 4몰을 첨가하여 반응시키면 발열반응이 일어나고, 상온에서 약 1시간 교반하면 반응이 완료된다.In the above method, the ethylene dianthane acetammonium, which constitutes the main component of the detergent, reacts by adding 1 mole of ethylene diamine tetraacetic acid and 4 moles of ammonia water to generate an exothermic reaction, and when the mixture is stirred at room temperature for about 1 hour, the reaction is completed. do.
이것을 24시간 방치하면 투명성의 결정생성물을 얻는데 본 방법에서는 여기에서 얻어진 반응물을 사용한다. 또 선상알킬벤젠슬폰산과 에치렌디아민테트라아세트암모늄 반응으로 얻어진 반응물 및 선상알킬벤젠슬폰산과 지오라이트의 반응에 의한 반응물들은 선상알킬벤젠슬폰산, 에치렌디아민테트라암모늄, 지오라이트를 함께 반응시킨 반응물과 다르고 함께 반응시키는 경우는 암노니아가스가 발생하므로 선상알킬벤젠슬폰산과 EDTA-암모늄의 반응이 완전히 종료된 반응물에 선상알킬벤젠슬폰산과 지오라이트 반응생성물을 첨가해야 한다.It is left to stand for 24 hours to obtain a transparent crystal product. In this method, the reaction product obtained here is used. In addition, reactants obtained by the reaction of linear alkylbenzenesulfonic acid and ethylenediaminetetraacetammonium and reactants of the reaction of linear alkylbenzenesulfonic acid and zeolite are reacted with reactants of linear alkylbenzenesulfonic acid, ethylenediaminetetraammonium and zeolite together. In the case of different reactions, ammonia gas is generated. Therefore, the reaction product of linear alkylbenzenesulfonic acid and zeolite should be added to the reaction product in which the reaction of linear alkylbenzenesulfonic acid and EDTA-ammonium is completed.
그리고 본 세척을 구성하는 구성성분의 기능과 작용을 살펴보면 주성분으로 사용되는 에치렌디아민테트라아세트암모늄은 인체에 대해 유독성이 없고, 그 자체가 강력한 세척능을 가지고 있으며, 직쇄상 알킬벤젠슬폰산은 합성세제에 널리 사용하고 있는 연성형의 음이온 계면활성제로 쉽게 분해할 수 있어 공해요인이 적다.In addition, when looking at the function and action of the components constituting the washing, ethylene diaminetetraacet ammonium, which is used as a main component, is not toxic to the human body, and itself has strong washing ability, and linear alkylbenzenesulfonic acid is a synthetic detergent. It is easy to decompose with soft anionic surfactants widely used in the process, so there is little pollution.
또 암모늄사이트레이트는 물에 잘 녹아 본세척제 사용할 때 물에 녹여 사용할 수 있고 방청성을 지니고 있으며, 지오라이트 첨가로 약 알카리성을 유지 금속의 산화방지와 환경보존법의 PH수질기준에 적합하고 흡착성이 우수하여 오염물질을 쉽게 흡착하게 된다.In addition, ammonium citrate dissolves well in water, so it can be dissolved in water when used as a main cleaner and has anti-rusting properties. It maintains weak alkalinity by adding zeolite. It meets PH water quality standard of metal oxidation prevention and environmental preservation method. It will easily adsorb contaminants.
또 구연산암모늄은 방청기능을 갖고 있으며, 물에 쉽게 용해하고 인체에 해가 없으며 실리콘 오일이나 n-옥칠알콜은 소포제로서 제품에서 발생하는 기포를 억제한다. 그리고 황산나트리움은 합성청정제의 충진제로 사용되고, 이 역시 물 또는 그리세롤에 잘 녹으며, 아크릴 아마이드는 오물찌꺼기의 처리능이 있고 세척제 사용할 때 물에 연성을 부여하며 그리세린은 제품에 향기를 부여하고 침투성이 있어 세척효과에 있어 상승작용을 하게 된다.In addition, ammonium citrate has anti-corrosive function, is easily soluble in water, harmless to human body, and silicone oil or n-oxyl alcohol is an antifoaming agent that suppresses bubbles generated in products. Natrium sulfate is used as a filler for synthetic cleansers, and it is also well soluble in water or glycerol, acrylamide has the ability to treat sewage, ductility in water when used as a cleaning agent, and glycerine gives the product a fragrance. Permeability is synergistic in the cleaning effect.
그 밖에 본 발명에 의한 세척제의 조성비는 수많은 실험을 통하여 세척능, 분해능, 물에 대한 용해성, 요염제거성을 고려한 효과적인 조성비라 할 수 있다.In addition, the composition ratio of the cleaning agent according to the present invention can be said to be an effective composition ratio considering washing ability, resolution, solubility in water, and decontamination property through numerous experiments.
이상의 성분으로 반응 또는 혼합에 의하여 얻어진 본 세척제는 첨탄성의 교질 물질로서 이를 건조하면 괴상 또는 분말상으로 되고 사용할 때는 물 20-50배에 용해해서 사용하게 되며 적어도 포화용해되고, 안정성이 커 공기중에서 변질이 거의 일어나지 않고 세척능 또한 수산을 주성분으로 한 종래 세척제에 비하여 월등히 우수하다 하고 인체에 대한 해가 적다.The cleaning agent obtained by the reaction or mixing with the above components is a high-strength colloid material, and when it is dried, it is in the form of mass or powder, and when used, it is dissolved in 20-50 times of water and used at least saturate, and stability is altered in air. This hardly occurs, and the washing performance is also much better than that of the conventional cleaning agent, which is mainly composed of aquatic acid, and there is little harm to the human body.
실험예 1Experimental Example 1
에치렌디아민테트라암모늄 300g에 선상알킬벤젠슬폰산 150g을 첨가하여 반응시켜 점성액의 반용생성물을 얻은 다음 여기에 지오라이트 100g과 선상알킬벤젠슬폰산 50g을 반응시켜 얻어진 겔화된 교질액을 혼합하여 충분히 교반한 다음 구연산암모늄 200g, 황산나트륨 100g, 아크릴아마이드 50g, 실리콘오일 20g, n-옥칠알콜 20g, 그리세린 10g을 첨가하여 약 1시간 교반하여 10시간 방치한 결과 점성이 큰 탄점성교질액을 얻었다. 이를 건조하면 백색 또는 연담황색의 괴상을 얻고, 이를 분쇄하여 650g의 분말세척제를 얻었다. 이분말세척제를 물에 용해시켜 물성과 기능을 측정한 결과 아래 표 1과 같은 결과를 얻었다.After adding 150 g of linear alkylbenzenesulfonic acid to 300 g of ethrendiamine tetraammonium, the mixture was reacted to obtain a viscous solution of viscous liquid, and then the gelled colloid obtained by reacting 100 g of zeolite with 50 g of linear alkylbenzenesulfonic acid was mixed. After stirring, 200 g of ammonium citrate, 100 g of sodium sulfate, 50 g of acrylamide, 20 g of silicon oil, 20 g of n-oxyl alcohol, and 10 g of greserine were added, and the mixture was stirred for about 1 hour and left for 10 hours to obtain a highly viscous colloidal gel solution. When dried, a mass of white or light yellow was obtained, and it was ground to obtain 650 g of a powder cleaner. As a result of dissolving the powder cleaning agent in water and measuring the physical properties and functions, the results shown in Table 1 below were obtained.
[표 1] 본 발명에 의한 세척제의 물성 및 기능 [Table 1] Physical properties and functions of the cleaning agent according to the present invention
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950008374A KR0127865B1 (en) | 1995-04-11 | 1995-04-11 | Powder detervgent composition for washing a car |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950008374A KR0127865B1 (en) | 1995-04-11 | 1995-04-11 | Powder detervgent composition for washing a car |
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| Publication Number | Publication Date |
|---|---|
| KR960037816A KR960037816A (en) | 1996-11-19 |
| KR0127865B1 true KR0127865B1 (en) | 1998-04-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1019950008374A KR0127865B1 (en) | 1995-04-11 | 1995-04-11 | Powder detervgent composition for washing a car |
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| Country | Link |
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| KR (1) | KR0127865B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024182019A1 (en) * | 2023-02-28 | 2024-09-06 | Energizer Auto, Inc. | Vehicle cleaning compositions |
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1995
- 1995-04-11 KR KR1019950008374A patent/KR0127865B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024182019A1 (en) * | 2023-02-28 | 2024-09-06 | Energizer Auto, Inc. | Vehicle cleaning compositions |
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| Publication number | Publication date |
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| KR960037816A (en) | 1996-11-19 |
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