KR0127241B1 - Method for long-term preservation of kimchi - Google Patents
Method for long-term preservation of kimchiInfo
- Publication number
- KR0127241B1 KR0127241B1 KR1019940031298A KR19940031298A KR0127241B1 KR 0127241 B1 KR0127241 B1 KR 0127241B1 KR 1019940031298 A KR1019940031298 A KR 1019940031298A KR 19940031298 A KR19940031298 A KR 19940031298A KR 0127241 B1 KR0127241 B1 KR 0127241B1
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- South Korea
- Prior art keywords
- kimchi
- mustard oil
- added
- weight
- seed extract
- Prior art date
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/10—Preserving with acids; Acid fermentation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/34—Strap connectors, e.g. copper straps for grounding power devices; Manufacturing methods related thereto
- H01L2224/36—Structure, shape, material or disposition of the strap connectors prior to the connecting process
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Storage Of Fruits Or Vegetables (AREA)
Abstract
Description
본 발명은 유산균을 포함한 세균류에 강한 항균효과를 나타내는 자몽종자 추출물과 김치발효 후기에 군등내 및 연부의 원인이 되는 효모등의 진균류에 강한 항균 활성을 나타내는 겨자유를 김치 제조시 병용 첨가하므로써, 맛, 향, 조직감 등의 품질은 손상시키지 않으면서 김치에 존재하는 미생물들에 대한 고른 저해효과에 의해 김치발효 속도를 지연시켜, 김치의 보존성을 연장시키는 방법에 관한 것이다.The present invention by adding a grapefruit seed extract showing a strong antimicrobial effect to bacteria including lactic acid bacteria and mustard oil showing a strong antimicrobial activity against fungi such as yeast, such as yeast that causes the inside of the group and soft in the late kimchi fermentation, in combination during the production of kimchi, taste, The present invention relates to a method of extending the preservation of kimchi by delaying the fermentation rate of kimchi by an even inhibitory effect on microorganisms present in kimchi without impairing the quality of fragrance and texture.
김치는 한국 고유의 발효식품으로서, 전통적으로 가정에서 담가 왔지만, 최근에 여성들의 사회 참여가 증가하는 등 사회구조와 환경이 변화함에 따라 상품 김치에 대한 요구도 증가되었다. 그러나 김치는 수많은 미생물이 관여하여 발효되어 만들어지는 식품이기 때문에, 오랫동안 보관하기 어렵다는 문제를 안고 있다. 즉, 김치를 제조한 후 그대로 방치하면 유산균이 계속적으로 산을 생성하여 산패가 일어나며, 발효 후기에는 내산, 내염성의 효모가 증식하여 군등내가 나고 김치조직의 연부 현상이 초래되어, 김치는 더 이상 먹을 수 없는 상태로 된다. 이와 같이 김치가 산패되고 연부되는 현상을 통털어 변패라 부르기도 하는데, 이러한 김치의 변패 현상은 유통경로를 거쳐 판매가 이루어지는 상품 김치에 있어서는 치명적인 약점이 되며, 김치 사업에 있어서 가장 큰 장애 요소의 하나가 되고 있음은 주지의 사실이다.Kimchi is Korea's own fermented food, traditionally soaked at home, but the demand for commodity kimchi has increased as social structure and environment have changed recently, such as increased social participation by women. However, kimchi has a problem that it is difficult to store for a long time because food is made by fermenting a large number of microorganisms. In other words, when the kimchi is left after it is left as it is, lactic acid bacteria continuously produce acid, causing rancidity.In the late fermentation, acid and salt-resistant yeasts proliferate, resulting in softening of the kimchi tissue, resulting in softening of kimchi tissue. It becomes impossible. As such, kimchi is often called rancidity and obsolescence, which is a fatal weakness in kimchi products sold through distribution channels, and one of the biggest obstacles in the kimchi business. It is well known.
현재까지 김치의 보존성을 향상시키기 위한 여러가지 방법들이 제안되었으나, 실용화되고 있는 것은 저온저장법 밖에는 없는 실정이다. 즉, 가열살균에 의한 방법(특허공고 제87-22호, 특허공고 제90-3010호)은 김치의 신선한 맛에 손상을 주며, 방사선 조사법(특허공고 제91-6614호)은 처리 기술상의 문제, 안전성의 문제 및 소비자 거부감 등의 문제가 있고, 합성보존료 이용법(특허공고 제67-305호, 특허공고 제90-3722호, 특허공고 제90-4721호) 역시 안전성의 문제 및 소비자 거부감 등으로 인하여 사용되고 있지 않다. 이와 같이 저온저장법은 현재 김치의 보존방법으로서 사용되고 있는 유일한 방법이지만, 냉장 유통 비용이 비싸고 유통 경로중에 부주의로 인해 저온 유지가 잘 안되어 상품으로서의 가치를 상실시키는 경우가 빈번하다는 것이 단점으로 지적되고 있다.Until now, various methods for improving the preservation of kimchi have been proposed, but the practical use is the only low temperature storage method. That is, the method by heat sterilization (Patent Publication No. 87-22, Patent Publication No. 90-3010) damages the fresh taste of kimchi, and the radiation irradiation method (Patent Publication No. 91-6614) is a problem in processing technology. , Safety problems and consumer rejection, and the use of synthetic preservatives (Patent Publication No. 67-305, Patent Publication No. 90-3722, Patent Publication No. 90-4721) also caused safety problems and consumer rejection. Not being used. As described above, the low temperature storage method is the only method currently used as a preservation method of kimchi, but it is pointed out that the cold storage cost is high and the loss of value as a commodity is frequently lost due to inadvertent maintenance of the distribution channel.
한편, 천연보존제를 김치에 첨가하여 보존성을 연장시켰다는 보고가 많은데(특허공고 제90-1001호, 특허공고 제90-1003호, 특허공고 제90-3008호, 특허공고 제90-3009호, 특허공고 제90-3010호, 특허공고 제91-6614호), 이들 대부분은 그 효과가 미미하거나, 또는 첨가된 천연보존제에 의해 일부 미생물만이 억제된 결과 다른 미생물이 비정상적으로 대량 증식하여 이상발효가 일어나 오히려 김치의 풍미가 나빠지는 등의 문제가 있어, 실제로 응용되고 있지는 못하다. 한가지 예로서, 김치가 시는 것을 방지하기 위하여 산을 생성하는 유산균만을 집중적으로 억제시킬 경우, 산도는 지연되겠지만 유산균 이외의 효모등이 우점적으로 증식하여 이상발효가 일어나 김치 고유의 상큼한 풍미가 없고, 이미·이취가 나고 조직감도 나빠지게 된다.On the other hand, there are many reports that natural preservatives were added to kimchi to extend the preservation (Patent Publication 90-1001, Patent Publication 90-1003, Patent Publication 90-3008, Patent Publication 90-3009, Patent 90-3010, Patent Publication No. 91-6614), most of them are not effective, or the addition of natural preservatives, only some of the microorganisms are suppressed as a result of abnormally large growth of other microorganisms abnormal fermentation There is such a problem that the taste of kimchi worsens, and it is not actually applied. As an example, if only concentrated lactic acid bacteria that produce acid to prevent kimchi from soaking, the acidity will be delayed, but yeasts other than lactic acid bacteria predominantly proliferate, resulting in abnormal fermentation, so that there is no fresh flavor of kimchi. Already, there will be a bad smell and bad organization.
따라서, 김치의 저장성을 연장시키고자 할 경우에는, 김치발효에 직·간접적으로 관여하는 모든 미생물들을 골고루 억제시키므로써, 정상적인 발효패턴은 유지하되 다만 발효속도를 늦추어 주는 것이 바람직하다고 할 수 있다.Therefore, in order to extend the shelf life of kimchi, it is desirable to maintain a normal fermentation pattern but slow down the fermentation rate by suppressing all microorganisms directly and indirectly involved in kimchi fermentation.
본 발명자들은 상기와 같은 문제점을 해결하기 위하여 예의 연구한 결과, 두가지의 서로 다른 항균스펙트럼을 갖는 자몽종차 추출물과 겨자유를 김치 제조시 적절히 배합하여 병용처리하므로써 김치의 보존성이 월등히 향상된다는 것을 발견하여 본 발명에 이르게 되었다.The present inventors have diligently studied to solve the above problems, and found that the preservation of kimchi is greatly improved by combining the grapefruit seed extract having two different antimicrobial spectra and mustard oil in a proper combination when preparing kimchi. It came to invention.
자몽종차 추출물은 감귤류 과실인 자몽종자로부터 추출한 천연물로서 독성이 없으며, 유산균을 포함한 광범위한 세균류에 대하여 억제효과가 뛰어나다고 알려져 있고, 식품에 첨가시 향미를 개선하는 효과도 갖고 있다.Grapefruit tea extract is a natural product extracted from grapefruit seeds, which are citrus fruits, is not toxic, and is known to be excellent in inhibiting effects against a wide range of bacteria including lactic acid bacteria, and has an effect of improving flavor when added to foods.
또한 겨자유의 주성분인 알릴 이소티오시아네이트(allyl isothiocyanate)는 무, 배추, 갓 등의 겨자과 식물에 존재하는 성분으로서 효모를 포함한 진균류에 강력한 항균작용을 발휘하는 것으로 알려져 있다.In addition, allyl isothiocyanate, which is a major component of mustard oil, is present in mustard plants such as radish, cabbage, and mustard and is known to exert a strong antibacterial effect on fungi including yeast.
본 발명에서는 이들 두가지의 서로 다른 항균스펙트럼을 갖는 물질을 적절히 배합하여 병용처리하였을 경우, 이들 각각의 물질을 단독으로 처리한 경우보다 보전성이 월등히 향상되었을 뿐만 아니라, 김치 맛도 우수해짐을 발견하였다. 즉, 자몽종차 추출물과 겨자유를 동시에 처리할 경우 상승효과가 일어남을 알 수 있었는데, 그 이유는 자몽종차 추출물이 유산균을 억제하므로써 유산균에 의한 산패가 지연됨과 동시에, 겨자유가 효모를 억제하여 효모에 의한 군등내 및 연부가 방지되므로써, 김치발효 속도가 전체적으로 지연되었기 때문이다.In the present invention, when the appropriate combination of the two different antimicrobial spectrum of the combination treatment, it was found that not only the integrity is significantly improved, but also the kimchi taste is superior to the case of treating each of these substances alone. That is, synergistic effect occurs when grapefruit seed extract and mustard oil are treated simultaneously. The reason is that grapefruit seed extract inhibits lactic acid bacteria, delaying rancidity by lactic acid bacteria, and mustard oil inhibits yeast. This is because the kimchi fermentation rate was delayed as a whole by preventing in-situ and softening.
이하 본 발명을 공정별로 설명하면 다음과 같다.Hereinafter, the present invention will be described by process.
1. 자몽종차 추출물의 제조1. Preparation of Grapefruit Tea Extract
자몽의 종자를 물로 잘 씻어 60℃에서 1시간 건조시킨 후 분쇄한 다음, 건조분말 종자 20%에 대하여 추출 용매인 글리세린을 80%의 중량비율로 첨가한 후 30℃의 온도조건하에서 48시간동안 층분리 연속추출법에 의해 자몽종차 추출물을 제조하였다.The grapefruit seeds were washed well with water, dried at 60 ° C. for 1 hour and then pulverized. Then, glycerin, an extraction solvent, was added to the dry powder seed at 20% in a weight ratio of 80%, and then layered for 48 hours at a temperature of 30 ° C. Grapefruit tea extract was prepared by a separate continuous extraction method.
2. 겨자유의 제조2. Manufacture of Mustard Oil
겨자 종자를 압착하여 비휘발성유(지방유)를 제거한 후 남은 찌꺼기를 마쇄한 다음, 5배 중량의 증류수를 가하여 70℃에서 2시간동안 교반하면서 효소분해를 실시하고, 수증기 증류를 실시하여 얻어진 증류액에서 물을 제거하여 겨자유를 제조하였다. 이때 만들어진 겨자유는 물에 녹지 않으므로, 겨자유 : 슈크로오스 에스테르=2 : 98의 비율로 유화시킨 겨자유 유화액을 만들어 사용하였다.After pressing mustard seeds to remove non-volatile oil (fatty oil), the remaining residues are ground, and 5 times weight of distilled water is added to carry out enzymatic digestion with stirring at 70 ° C. for 2 hours, and steam distillation is obtained. Mustard oil was prepared by removing water. At this time, since the mustard oil is insoluble in water, it was used to make a mustard oil emulsified in a ratio of mustard oil: sucrose ester = 2: 98.
3. 김치의 제조3. Manufacture of Kimchi
통상의 방법으로 김치를 제조할때 자몽종차 추출물을 0.02-0.2중량%, 겨자유 유화액을 0.05-0.5중량% 첨가하였다. 이때 자몽종차 추출물을 0.02중량% 이하로, 그리고 겨자유 유화액을 0.05중량% 이하로 첨가하면 보존효과가 약하며, 자몽종차 추출물을 0.2% 이상, 그리고 겨자유 유화액을 0.5중량% 이상 첨가하면 첨가물에 의한 맛의 변화가 느껴지게 되어 부적당하다.When preparing kimchi in a conventional manner, 0.02-0.2% by weight of grapefruit seed extract and 0.05-0.5% by weight of mustard oil emulsion were added. At this time, when the grapefruit tea extract is added at 0.02% by weight or less, and the mustard oil emulsion is added at 0.05% by weight or less, the preservation effect is weak, and when the grapefruit tea extract is added at least 0.2%, and the mustard oil emulsion is added by 0.5% by weight or more, It is inappropriate to feel the change.
4. 김치의 숙성4. Ripening of Kimchi
상기 1-3항의 방법으로 제조한 김치를 10℃, 20℃에서 숙성시키면서 산도, pH, 맛과 향에 대한 분석을 실시하였다.The kimchi prepared by the method of paragraph 1-3 was aged at 10 ° C. and 20 ° C., and analyzed for acidity, pH, taste and aroma.
이하 본 발명을 실시예로서 구체적으로 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail as examples.
실시예 1Example 1
통상의 방법으로 김치를 제조할때 자몽종차 추출물 0.05중량%, 겨자유 유화액 0.3중량%를 양념과 함께 첨가하여 잘 혼합하고 10℃에서 숙성시키면서 산도와 pH를 측정하였으며, 그 결과를 하기 표 1에 기재하였다.When preparing kimchi by the conventional method, 0.05% by weight of grapefruit seed extract and 0.3% by weight of mustard oil emulsion were added with seasoning, mixed well, and the acidity and pH were measured while ripening at 10 ° C., and the results are shown in Table 1 below. It was.
[표 1]TABLE 1
본 발명의 김치와 일반김치와의 숙성도 비교(10℃ 숙성시)(%=중량%)Comparison of ripening degree of kimchi and general kimchi of the present invention (at 10 ° C ripening) (% =% by weight)
상기 표 1로부터 알 수 있듯이 가식기간(산도 0.75에 도달하는 기간)이 일반김치에 비해 2.3배 연장되었다. 또한 자몽종자 추출물과 겨자유를 병용처리하였을 때가 이들 각자를 단독으로 처리한 경우보다 보존성이 현저하게 향상되었으며, 이 사실로부터 자몽종자 추출물과 겨자유 유화액을 병용처리할 경우 상승효과가 나타남을 알 수 있다.As can be seen from Table 1, the decorative period (period reaching 0.75 acidity) was 2.3 times longer than that of general kimchi. In addition, the combination of grapefruit seed extract and mustard oil was significantly improved in preservation compared with the treatment of each of these alone, and from this fact, the combination of grapefruit seed extract and mustard oil emulsion showed a synergistic effect.
한편 김치가 적당히 익었을때 잘 훈련된 관능검사요원 20명을 대상으로 하여 관능검사를 실시하였으며, 그 결과는 하기 표 2에서 보는 바와 같이 일반김치와 관능적인 차이가 없었다.On the other hand, when kimchi was moderately ripe, the sensory test was carried out on 20 well-trained sensory test personnel, and the results were as shown in Table 2 below.
[표 2]TABLE 2
본 발명의 김치와 일반김치와의 관능검사 비교Comparison of sensory tests between kimchi and general kimchi of the present invention
실시예 2Example 2
상기 실시예 1과 동일한 방법으로 제조한 김치를 20℃에서 숙성시키면서 숙성도를 측정하였으며 그 결과는 하기 표 3에 나타내었다.Aging was measured while ripening kimchi prepared in the same manner as in Example 1 at 20 ℃ and the results are shown in Table 3 below.
[표 3]TABLE 3
본 발명의 김치와 일반김치와의 숙성도 비교(20℃ 숙성시)(%=중량%)Comparison of Aging Degree of Kimchi and General Kimchi of the Present Invention (at 20 ° C Aging) (% = wt%)
상기 표 3으로부터 알 수 있듯이, 본 발명에 따른 김치가 일반김치에 비해 가식기간이 2.2배 연장되었다.As can be seen from Table 3, kimchi according to the present invention is extended by 2.2 times the decorative period compared to the general kimchi.
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KR1019940031298A KR0127241B1 (en) | 1994-11-25 | 1994-11-25 | Method for long-term preservation of kimchi |
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KR100375962B1 (en) * | 2000-08-16 | 2003-03-15 | 학교법인 문화교육원 | Method for preparation of kimchi which has the optimum aging period increased |
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KR100390157B1 (en) * | 2001-02-27 | 2003-07-04 | 주식회사영산포식품 | Method for the extension of ripening period and storage period of kimchi by adding a skate ray |
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KR100375962B1 (en) * | 2000-08-16 | 2003-03-15 | 학교법인 문화교육원 | Method for preparation of kimchi which has the optimum aging period increased |
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