JPWO2019189736A1 - 合わせガラス用中間膜、合わせガラス及びヘッドアップディスプレイシステムの製造方法 - Google Patents
合わせガラス用中間膜、合わせガラス及びヘッドアップディスプレイシステムの製造方法 Download PDFInfo
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- JPWO2019189736A1 JPWO2019189736A1 JP2019519019A JP2019519019A JPWO2019189736A1 JP WO2019189736 A1 JPWO2019189736 A1 JP WO2019189736A1 JP 2019519019 A JP2019519019 A JP 2019519019A JP 2019519019 A JP2019519019 A JP 2019519019A JP WO2019189736 A1 JPWO2019189736 A1 JP WO2019189736A1
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- laminated glass
- resin layer
- resin
- interlayer film
- layer
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- G02B27/01—Head-up displays
- G02B27/0101—Head-up displays characterised by optical features
- G02B2027/0118—Head-up displays characterised by optical features comprising devices for improving the contrast of the display / brillance control visibility
- G02B2027/012—Head-up displays characterised by optical features comprising devices for improving the contrast of the display / brillance control visibility comprising devices for attenuating parasitic image effects
Abstract
Description
上記赤外線反射層は赤外線を反射する。上記赤外線反射層は、赤外線を反射する性能を有していれば特に限定されない。但し、合わせガラスの入射角度60度における波長480nm〜680nmでの光の反射率が15%以下となるように、赤外線反射層を選択して用いることが好ましい。
熱可塑性樹脂:
第1の樹脂層は、熱可塑性樹脂(以下、熱可塑性樹脂(1)と記載することがある)を含む。第1の樹脂層は、熱可塑性樹脂(1)として、ポリビニルアセタール樹脂(以下、ポリビニルアセタール樹脂(1)と記載することがある)を含むことが好ましい。第2の樹脂層は、熱可塑性樹脂(以下、熱可塑性樹脂(2)と記載することがある)を含む。第2の樹脂層は、熱可塑性樹脂(2)として、ポリビニルアセタール樹脂(以下、ポリビニルアセタール樹脂(2)と記載することがある)を含むことが好ましい。
樹脂層の接着力をより一層高める観点からは、上記第1の樹脂層は、可塑剤(以下、可塑剤(1)と記載することがある)を含むことが好ましい。樹脂層の接着力をより一層高める観点からは、上記第2の樹脂層は、可塑剤(以下、可塑剤(2)と記載することがある)を含むことが好ましい。樹脂層に含まれている熱可塑性樹脂が、ポリビニルアセタール樹脂である場合に、樹脂層は、可塑剤を含むことが特に好ましい。ポリビニルアセタール樹脂を含む層は、可塑剤を含むことが好ましい。
上記第1の樹脂層は、遮熱性物質を含んでいてもよく、含んでいなくてもよい。上記第2の樹脂層は、遮熱性物質を含むことが好ましい。赤外線反射層が反射する赤外線を効率的に外部空間に放出することができ遮熱性が一層向上することから、上記第1の樹脂層における遮熱性物質の含有量は、上記第2の樹脂層における遮熱性物質の含有量よりも少ないことが好ましい。上記遮熱性物質は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の樹脂層は、アルカリ金属塩、アルカリ土類金属塩又はマグネシウム塩である金属塩(以下、金属塩Mと記載することがある)を含むことが好ましい。上記第2の樹脂層は、上記金属塩Mを含むことが好ましい。上記金属塩Mの使用により、樹脂層と赤外線反射層及び合わせガラス部材との接着性を制御することが容易になる。上記金属塩Mは、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の樹脂層は、紫外線遮蔽剤を含むことが好ましい。上記第2の樹脂層は、紫外線遮蔽剤を含むことが好ましい。紫外線遮蔽剤の使用により、合わせガラスが長期間使用されても、可視光線透過率がより一層低下し難くなる。上記紫外線遮蔽剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の樹脂層は、酸化防止剤を含むことが好ましい。上記第2の樹脂層は、酸化防止剤を含むことが好ましい。上記酸化防止剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の樹脂層及び上記第2の樹脂層はそれぞれ、必要に応じて、カップリング剤、分散剤、界面活性剤、難燃剤、帯電防止剤、顔料、染料、金属塩以外の接着力調整剤、耐湿剤、蛍光増白剤及び赤外線吸収剤等の添加剤を含んでいてもよい。これらの添加剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1,第2の合わせガラス部材としては、ガラス板及びPET(ポリエチレンテレフタレート)フィルム等が挙げられる。上記合わせガラスには、2枚のガラス板の間に中間層が挟み込まれている合わせガラスだけでなく、ガラス板とPETフィルム等との間に中間層が挟み込まれている合わせガラスも含まれる。合わせガラスは、ガラス板を備えた積層体であり、少なくとも1枚のガラス板が用いられていることが好ましい。上記第1,第2の合わせガラス部材がそれぞれガラス板又はPET(ポリエチレンテレフタレート)フィルムであり、かつ上記合わせガラスが、上記第1,第2の合わせガラス部材として、少なくとも1枚のガラス板を含むことが好ましい。上記第1,第2の合わせガラス部材の双方がガラス板であることが特に好ましい。
上記合わせガラスの使用時には、上記建築物又は上記車両において、上記第1の合わせガラス部材が、上記外部空間側に位置するように、かつ上記第2の合わせガラス部材が上記内部空間側に位置するように、上述した合わせガラスを前記開口部に取り付ける。
ポリビニルアセタール樹脂(PVB、平均重合度1700、水酸基の含有率30.5モル%、アセチル化度1モル%、アセタール化度68.5モル%)
トリエチレングリコールジ−2−エチルヘキサノエート(3GO)
Tinuvin326(2−(2’−ヒドロキシ−3’−t−ブチル−5−メチルフェニル)−5−クロロベンゾトリアゾール、BASF社製「Tinuvin326」)0.2重量部
BHT(2,6−ジ−t−ブチル−p−クレゾール)
ITO(ITO粒子、錫ドープ酸化インジウム粒子)
CWO(CWO粒子、セシウムドープ酸化タングステン(Cs0.33WO3)粒子)
NIR−43V(成分X、フタロシアニン化合物、中心金属としてバナジウムを含有する、山田化学社製「NIR−43V」)
Nano90S(3M、多層樹脂フィルム、住友スリーエム社製「マルチレイヤー Nano 90S」)
XIR−75(金属箔付き樹脂フィルム、Southwall Technologies社製「XIR−75」)
クリアガラス(厚さ2.5mm、入射角度60度における波長480nm〜680nmでの光の反射率6.6%)
グリーンガラス(熱線吸収板ガラス、厚さ2mm、入射角度60度における波長480nm〜680nmでの光の反射率6.3%)
第1の樹脂層の作製:
以下の成分を配合し、ミキシングロールで充分に混練し、第1の樹脂層を形成するための組成物を得た。
トリエチレングリコールジ−2−エチルヘキサノエート(3GO)40重量部
得られる樹脂層中で0.2重量%となる量のTinuvin326(2−(2’−ヒドロキシ−3’−t−ブチル−5−メチルフェニル)−5−クロロベンゾトリアゾール、BASF社製「Tinuvin326」)
得られる樹脂層中で0.2重量%となる量のBHT(2,6−ジ−t−ブチル−p−クレゾール)
以下の成分を配合し、ミキシングロールで充分に混練し、第2の樹脂層を形成するための組成物を得た。
トリエチレングリコールジ−2−エチルヘキサノエート(3GO)40重量部
得られる樹脂層中で0.2重量%となる量のTinuvin326(2−(2’−ヒドロキシ−3’−t−ブチル−5−メチルフェニル)−5−クロロベンゾトリアゾール、BASF社製「Tinuvin326」)
得られる樹脂層中で0.2重量%となる量のBHT(2,6−ジ−t−ブチル−p−クレゾール)
赤外線反射層として、Nano90S(3M、多層樹脂フィルム、住友スリーエム社製「マルチレイヤー Nano 90S」)を用意した。
第1の合わせガラス部材と、第1の樹脂層と、赤外線反射層と、第2の樹脂層と、第2の合わせガラス部材とをこの順で積層して、縦100cm及び横100cmの合わせガラスを得た。第1の合わせガラス部材と、第1の樹脂層との第1の積層体の楔角は、第1の樹脂層の楔角と同じであった。
合わせガラスの構成を下記の表1〜3に示すように変更したこと以外は、実施例1と同様にして、合わせガラスを得た。
(1)光の反射率の測定
得られた合わせガラス厚みの小さい側の一端から厚みの大きい他端に向かって、4cmの位置から12cmの位置までを表示領域とし、該表示領域の中心すなわち上記一端から上記他端に向かって8cmの位置を測定位置として、後述の分光光度計が使用できる大きさに合わせガラスを切り出した。切り出された合わせガラスの該測定位置において、入射角度60度における波長480nm〜680nmでの光の反射率は、分光光度計(日本分光社製「V−670」)に絶対反射率測定ユニット(日本分光社製「ARSN−733」)を取り付け、光源からの入射角が60度となるように調整して測定した。
中間膜の一端が下となるように、得られた合わせガラスをフロントガラスの位置に設置した。合わせガラスの下方に設置した表示ユニットから表示情報を合わせガラスに反射させ、所定の位置で多重像の有無を目視で確認した。なお、表示情報には、多重像の抑制効果を評価するために、太い線部分と細い線部分とが含まれるようにした。多重像を下記の基準で判定した。
〇〇〇:多重像が完全に確認されず、かつ太い線部分の像及び細い線部分の像の双方が鮮明に表示される
〇〇:多重像が確認されず、かつ太い線部分の像は鮮明に表示されるが、細い線の像の鮮明性がわずかに劣る(実使用可能)
〇:多重像が確認されず、かつ太い線部分の像及び細い線部分の像の双方の鮮明性がわずかに劣る(実使用可能)
×:多重像が確認される
得られた合わせガラスの面内で可視光線透過率並びに色差をそれぞれ、JIS R 3211 2015及びJIS Z 8730に準拠して、分光光度計(日立ハイテク社製「U−4100」)を用いて算出し、面内の色差の最大値を面内色差として算出した。
2,2A…第1の樹脂層
3,3A…赤外線反射層
4,4A…第2の樹脂層
5,5A…第2の合わせガラス部材
10,10A…中間膜
10a…一端
10b…他端
11,11A…合わせガラス
11a…一端
11b…他端
R1…表示領域
R2…周囲領域
R3…シェード領域
Claims (12)
- 赤外線反射層と、熱可塑性樹脂を含む第1の樹脂層と、熱可塑性樹脂を含む第2の樹脂層とを有し、
前記赤外線反射層の第1の表面側に前記第1の樹脂層が配置されており、前記赤外線反射層の前記第1の表面とは反対の第2の表面側に前記第2の樹脂層が配置されており、
前記第1の樹脂層が0.1mrad以上の楔角を有し、
中間膜の前記第1の樹脂層の外側に厚さ2.5mmのクリアガラスを配置し、中間膜の前記第2の樹脂層の外側に厚さ2mmのグリーンガラスを配置して合わせガラスを得て、合わせガラスの前記第2の樹脂層の外側に位置するグリーンガラスの外側から光を照射したときに、入射角度60度における波長480nm〜680nmでの光の反射率が15%以下である、合わせガラス用中間膜。 - 前記第2の樹脂層が、遮熱性物質を含む、請求項1に記載の合わせガラス用中間膜。
- 前記第1の樹脂層中の前記熱可塑性樹脂が、ポリビニルアセタール樹脂であり、
前記第2の樹脂層中の前記熱可塑性樹脂が、ポリビニルアセタール樹脂である、請求項1又は2に記載の合わせガラス用中間膜。 - 前記第1の樹脂層が可塑剤を含み、
前記第2の樹脂層が可塑剤を含む、請求項1〜3のいずれか1項に記載の合わせガラス用中間膜。 - ヘッドアップディスプレイである合わせガラスに用いられる、請求項1〜4のいずれか1項に記載の合わせガラス用中間膜。
- 第1の合わせガラス部材と、第2の合わせガラス部材と、中間膜とを備え、
前記中間膜は、赤外線反射層と、熱可塑性樹脂を含む第1の樹脂層と、熱可塑性樹脂を含む第2の樹脂層とを有し、
前記赤外線反射層の第1の表面側に前記第1の樹脂層が配置されており、前記赤外線反射層の前記第1の表面とは反対の第2の表面側に前記第2の樹脂層が配置されており、
前記第1の樹脂層の外側に前記第1の合わせガラス部材が配置されており、前記第2の樹脂層の外側に前記第2の合わせガラス部材が配置されており、
前記第1の合わせガラス部材と前記第1の樹脂層との積層体が、0.1mrad以上の楔角を有し、
合わせガラスの前記第2の合わせガラス部材の外側から光を照射したときに、入射角度60度における波長480nm〜680nmでの光の反射率が15%以下である、合わせガラス。 - 前記第1の樹脂層が、0.1mrad以上の楔角を有する、請求項6に記載の合わせガラス。
- 前記第2の樹脂層が、遮熱性物質を含む、請求項6又は7に記載の合わせガラス。
- 前記第1の樹脂層中の前記熱可塑性樹脂が、ポリビニルアセタール樹脂であり、
前記第2の樹脂層中の前記熱可塑性樹脂が、ポリビニルアセタール樹脂である、請求項6〜8のいずれか1項に記載の合わせガラス。 - 前記第1の樹脂層が可塑剤を含み、
前記第2の樹脂層が可塑剤を含む、請求項6〜9のいずれか1項に記載の合わせガラス。 - ヘッドアップディスプレイである、請求項6〜10のいずれか1項に記載の合わせガラス。
- 外部空間と前記外部空間から熱線が入射される内部空間との間の開口部と、画像表示用の光を前記合わせガラスに照射するための光源装置とを有する建築物又は車両にて、
前記第1の合わせガラス部材が、前記外部空間側に位置するように、かつ前記第2の合わせガラス部材が前記内部空間側に位置するように、請求項6〜11のいずれか1項に記載の合わせガラスを前記開口部に取り付ける工程を備える、ヘッドアップディスプレイシステムの製造方法。
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CN111918853B (zh) | 2023-04-18 |
EP3778516A1 (en) | 2021-02-17 |
US20200406587A1 (en) | 2020-12-31 |
KR20200138721A (ko) | 2020-12-10 |
MX2020010145A (es) | 2020-10-20 |
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