JPWO2019115020A5 - - Google Patents

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JPWO2019115020A5
JPWO2019115020A5 JP2020530638A JP2020530638A JPWO2019115020A5 JP WO2019115020 A5 JPWO2019115020 A5 JP WO2019115020A5 JP 2020530638 A JP2020530638 A JP 2020530638A JP 2020530638 A JP2020530638 A JP 2020530638A JP WO2019115020 A5 JPWO2019115020 A5 JP WO2019115020A5
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JP7189215B2 (en
JP2021507002A (en
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Priority claimed from PCT/EP2018/069081 external-priority patent/WO2019115020A1/en
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Priority to JP2022127646A priority Critical patent/JP2022166148A/en
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Figure 2019115020000001
Figure 2019115020000001

Claims (16)

（Ａ）
ｉ）フッ素原子を含まず、ポリウレタン、ポリエーテル、ポリエステル、ポリカーボネートまたはこれらの２つ以上のハイブリッドから選択される主鎖を有し、次式
－（ＣｍＨ２ｍ）－Ｓｉ（Ｒ１）（３－ｎ）（ＯＲ２）ｎ （Ｉ）
（式中、
ｎ＝１、２または３、であり、
Ｒ１およびＲ２それぞれは、独立に、１～６個の炭素原子を有するアルキル基であり、
ｍは、１～２０の範囲の値の整数である）の少なくとも１つの末端またはペンダント状アルコキシシリル基を有する、硬化性ポリマー、ならびに
ｉｉ）任意選択の硬化剤および／または触媒
を含む硬化性樹脂系と、
（Ｂ）殺海洋生物剤ならびに／またはフッ素化ポリマー、ステロールおよびステロール誘導体、ならびに親水性修飾ポリシロキサン油からなる群から選択される非硬化性不揮発性化合物と
を含む、人工物体上の水生生物汚損を防除するための非水液体汚損剥離塗料組成物であって、
前記塗料組成物が、０．５重量％未満の硬化性ポリシロキサンを含み、前記塗料組成物が、非硬化性親水性修飾ポリシロキサン油以外の非硬化性ポリシロキサンを０．５重量％未満含む、非水液体汚損剥離塗料組成物。 (A)
i) It is free of fluorine atoms and has a main chain selected from polyurethane, polyether, polyester, polycarbonate or a hybrid of two or more of these, and has the following formula- (Cm H 2 m ) -Si (R 1 ) ( 3-n) (OR 2 ) n (I)
(During the ceremony,
n = 1, 2 or 3,
Each of R 1 and R 2 is an alkyl group having 1 to 6 carbon atoms independently.
m is a curable polymer having at least one terminal or pendant alkoxysilyl group (which is an integer in the range of 1-20), and ii) a curable resin containing an optional curing agent and / or catalyst. System and
(B) Aquatic biofouling on man-made objects, including marine killing agents and / or non-curable non-volatile compounds selected from the group consisting of fluorinated polymers, sterols and sterol derivatives, and hydrophilic modified polysiloxane oils. A non-aqueous liquid fouling peeling paint composition for controlling
The coating composition contains less than 0.5% by weight of curable polysiloxane , and the coating composition contains less than 0.5% by weight of non-curable polysiloxane other than non-curable hydrophilic modified polysiloxane oil. , Non-aqueous liquid stain peeling paint composition. 硬化性ポリマー（ｉ）が、式（Ｉ）の少なくとも１つのアルコキシシリル末端基を有する、請求項１に記載の汚損剥離塗料組成物。 The fouling stripping paint composition according to claim 1, wherein the curable polymer (i) has at least one alkoxysilyl end group of the formula (I). 前記少なくとも１つの末端またはペンダント状アルコキシシリル基が、ウレタンまたは尿素連結を介して前記硬化性ポリマー（ｉ）の前記主鎖に結合している、請求項１または２に記載の汚損剥離塗料組成物。 The fouling stripping paint composition according to claim 1 or 2, wherein the at least one terminal or pendant alkoxysilyl group is bonded to the main chain of the curable polymer (i) via a urethane or urea link. .. ｍが１または３である、請求項１から３のいずれか一項に記載の汚損剥離塗料組成物。 The fouling peeling paint composition according to any one of claims 1 to 3, wherein m is 1 or 3. Ｒ２が、メチル基またはエチル基である、請求項１から４のいずれか一項に記載の汚損剥離塗料組成物。 The fouling stripping paint composition according to any one of claims 1 to 4, wherein R 2 is a methyl group or an ethyl group. 前記硬化性樹脂系が、テトラ－アルコキシオルトシリケートおよびその部分的縮合体、有機官能性アルコキシシラン、ならびにこれらの組み合わせからなる群から選択される硬化剤を含む、請求項１から５のいずれか一項に記載の汚損剥離塗料組成物。 Any one of claims 1 to 5, wherein the curable resin system comprises a tetra-alkoxy orthosilicate and a partial condensate thereof, an organic functional alkoxysilane, and a curing agent selected from the group consisting of combinations thereof. The fouling peeling paint composition according to the section. 前記硬化剤が、有機官能基に対してアルファ位にアルコキシシリル官能基を有する有機官能性アルコキシシランであり、前記塗料組成物が、本質的に硬化触媒を含まない、請求項６に記載の汚損剥離塗料組成物。 The fouling according to claim 6, wherein the curing agent is an organic functional alkoxysilane having an alkoxysilyl functional group at the alpha position with respect to the organic functional group, and the coating composition essentially does not contain a curing catalyst. Peeling paint composition. 前記塗料組成物が、殺海洋生物剤を含まない、請求項１から７のいずれか一項に記載の汚損剥離塗料組成物。 The stain-removing paint composition according to any one of claims 1 to 7, wherein the paint composition does not contain a marine-killing biological agent. 前記塗料組成物が、親水性修飾ポリシロキサン油からなる群から選択される、非硬化性不揮発性化合物を含む、請求項１から８のいずれか一項に記載の汚損剥離塗料組成物。 The stain-removing coating composition according to any one of claims 1 to 8, wherein the coating composition contains a non-curable non-volatile compound selected from the group consisting of hydrophilic modified polysiloxane oil. 前記非硬化性不揮発性親水性修飾ポリシロキサン油が、ポリ（オキシアルキレン）修飾ポリシロキサンである、請求項９に記載の汚損剥離塗料組成物。 The fouling peeling paint composition according to claim 9, wherein the non-curable non-volatile hydrophilic modified polysiloxane oil is a poly (oxyalkylene) modified polysiloxane. 請求項１から１０のいずれか一項に記載の汚損剥離塗料組成物で被覆された基材。 A base material coated with the fouling release coating composition according to any one of claims 1 to 10. － 前記基材に塗布され、プライマー塗料組成物から堆積される、任意選択のプライマー層と、
－ 前記基材または前記任意選択のプライマー層に塗布され、硬化性アルコキシシリル官能基を有するバインダーポリマーを含むタイコート組成物から堆積されるタイコート層と、
－ 前記タイコート層に塗布され、請求項１から１０のいずれか一項に記載の液体汚損剥離塗料組成物から堆積される、トップコート層と
を含む多層塗料系で被覆されている、請求項１１に記載の基材。 -With an optional primer layer applied to the substrate and deposited from the primer coating composition,
-A tie coat layer applied to the substrate or the optional primer layer and deposited from a tie coat composition comprising a binder polymer having a curable alkoxysilyl functional group.
-Claim, which is coated with a multilayer paint system including a top coat layer, which is applied to the tie coat layer and deposited from the liquid stain peeling paint composition according to any one of claims 1 to 10. 11. The substrate according to 11. 前記タイコート組成物が、硬化性アルコキシシリル官能基を有するポリアクリレートを含む、請求項１１または１２に記載の基材。 The substrate according to claim 11 or 12, wherein the tie coat composition comprises a polyacrylate having a curable alkoxysilyl functional group. 人工物体の表面上の水生生物汚損を防除するための方法であって、
（ａ）請求項１から１０のいずれか一項に記載の汚損剥離塗料組成物を、前記人工物体の前記表面の少なくとも一部分に塗布するステップと、
（ｂ）前記汚損剥離塗料組成物を硬化させて、硬化汚損剥離塗料層を形成するステップと、
（ｃ）前記人工物体を少なくとも部分的に水中に浸漬するステップと
を含む、方法。 A method for controlling aquatic biofouling on the surface of artificial objects.
(A) A step of applying the stain-removing paint composition according to any one of claims 1 to 10 to at least a part of the surface of the artificial object.
(B) A step of curing the stain-removing paint composition to form a cured stain-removing paint layer.
(C) A method comprising the step of immersing the artificial object in water at least partially. 前記汚損剥離塗料組成物を塗布する前に、請求項１２または１３に規定のタイコート組成物から堆積されるタイコート層を、前記人工物体の前記表面の前記少なくとも一部分に塗布するステップをさらに含む、請求項１４に記載の方法。 Further comprising the step of applying the tie coat layer deposited from the tie coat composition according to claim 12 or 13 to the at least a part of the surface of the artificial object before applying the stain release coating composition. , The method according to claim 14. 人工物体上の水生生物汚損を防除するための、請求項１から１０のいずれか一項に記載の汚損剥離塗料組成物の使用。
Use of the stain-removing paint composition according to any one of claims 1 to 10 for controlling aquatic biofouling on an artificial object.
JP2020530638A 2017-12-14 2018-07-13 Fouling Release Coating Compositions, Substrates Coated with the Coating Compositions, and Uses of the Coating Compositions Active JP7189215B2 (en)

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JP2022127646A JP2022166148A (en) 2017-12-14 2022-08-10 Foul release coating composition, substrate coated with such coating composition, and use of such coating composition

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EP17207444 2017-12-14
EP17207444.5 2017-12-14
PCT/EP2018/069081 WO2019115020A1 (en) 2017-12-14 2018-07-13 Foul release coating composition, substrate coated with such coating composition, and use of such coating composition

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JPWO2019115020A5 true JPWO2019115020A5 (en) 2022-02-16
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JP2020530638A Active JP7189215B2 (en) 2017-12-14 2018-07-13 Fouling Release Coating Compositions, Substrates Coated with the Coating Compositions, and Uses of the Coating Compositions
JP2022127646A Pending JP2022166148A (en) 2017-12-14 2022-08-10 Foul release coating composition, substrate coated with such coating composition, and use of such coating composition

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US (2) US20210179863A1 (en)
EP (2) EP3724277B1 (en)
JP (3) JP6931131B2 (en)
KR (2) KR102230998B1 (en)
CN (2) CN111448267B (en)
AU (2) AU2018383882B2 (en)
CA (2) CA3084599C (en)
DK (1) DK3724277T3 (en)
ES (2) ES2959947T3 (en)
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