JPWO2018193861A1 - Liquid crystal display device - Google Patents

Abstract

The problem to be solved by the present invention is to provide an n-type liquid crystal composition having improved viewing angle characteristics while satisfying various properties required for a so-called n-type liquid crystal composition having a negative dielectric anisotropy (Δε). And providing a liquid crystal display device using the same. The total content of the compound represented by General Formula (i) to the total composition is 3% or more, and the total content of the compound represented by General Formula (ii) to the total composition is 3% or more And the sum of the compound represented by general formula (i) to the total amount of the compound represented by general formula (i), the compound represented by general formula (ii) and the compound represented by general formula (L) The present invention provides a liquid crystal composition having a negative dielectric anisotropy of which amount is 20% or more, and also provides a liquid crystal display device using the same.

Description

  The present invention relates to a so-called n-type liquid crystal composition having a negative dielectric anisotropy (Δε) and a liquid crystal display device using the same.

  The liquid crystal display element using the composition which shows a negative value of (DELTA) epsilon is widely used for liquid crystal TV etc., and the extremely high characteristic is requested | required in the composition used for these uses in recent years. Specifically, high brightness, improvement of viewing angle characteristics, and high resolution are required while responding to high-speed response, low power consumption, long-term and short-term reliability, and a wide liquid crystal phase temperature range corresponding to moving image display. ing. Therefore, optimization of the liquid crystal compound contained and optimization of the content thereof are sought for the liquid crystal composition in accordance with the required characteristics of the liquid crystal composition (patent documents 1, 2, 3) conventionally used. It has come. In addition, there is a demand for stable dischargeability of the composition in the ODF process, which is less likely to cause display defects such as burn-in of display elements, less likely to cause dripping marks at the time of manufacture, and these must be addressed.

WO 2016/017569 JP, 2016-040368, A JP, 2016-033132, A

  The problem to be solved by the present invention is to provide an n-type liquid crystal composition having improved viewing angle characteristics while satisfying various properties required for a so-called n-type liquid crystal composition having a negative dielectric anisotropy (Δε). And providing a liquid crystal display device using the same.

  The present inventors have found that the above-mentioned problems can be solved by examining various liquid crystal compounds and various chemical substances, and performing selection and adjustment of their contents, and have completed the present invention. .

The present invention relates to one or more compounds selected from compounds represented by the general formula (i), one or more compounds selected from compounds represented by the general formula (ii), a general formula One or more compounds selected from the compounds represented by (N-1d), one or more compounds selected from the compounds represented by formula (N-1), a compound represented by formula (L Containing one or more compounds selected from the compounds represented by
The total content of the compound represented by General Formula (i) to the total composition is 3% or more, and the total content of the compound represented by General Formula (ii) to the total composition is 3% or more And the sum of the compound represented by general formula (i) to the total amount of the compound represented by general formula (i), the compound represented by general formula (ii) and the compound represented by general formula (L) The present invention provides a liquid crystal composition having a negative dielectric anisotropy of which amount is 20% or more, and also provides a liquid crystal display device using the same.

(Wherein, R ⁱ¹ and R ⁱⁱ¹ each independently represent an alkyl group having 1 to 5 carbon atoms, and R ⁱ² and R ⁱⁱ² each independently represent a methyl group or a methoxy group,
R ^Nd11 , R ^Nd12 , R ^N11 , R ^N12 , R ^L1 and R ^L2 each independently represent an alkyl group having 1 to 8 carbon atoms, and one or two or more non-adjacent ones in the alkyl group -CH ₂ -may be each independently substituted by -CH = CH-, -C≡C-, -O-, -CO-, -COO- or -OCO-,
n ^Nd11 represents 1, 2 or 3; n ^N11 and n ^N12 represent 0, 1, 2 or 3; n ^N11 + n ^N12 represents 1, 2 or 3; n ^L1 represents 0, 1, 2 or 3 Represents three,
A ^N11 , A ^N12 , A ^L1 , A ^L2 and A ^L3 are each independently (a) 1,4-cyclohexylene group (one -CH _2- present in this group or _two not adjacent to each other) The above -CH _2- may be replaced by -O-.) And (b) 1,4-phenylene group (one -CH = present in this group or two or more not adjacent to each other) -CH = may be replaced by -N =)
(C) Naphthalene-2,6-diyl group, 1,2,3,4-tetrahydronaphthalene-2,6-diyl group or decahydronaphthalene-2,6-diyl group (naphthalene-2,6-diyl group or One —CH = or two or more non-adjacent —CH = present in the 1,2,3,4-tetrahydronaphthalene-2,6-diyl group may be replaced by —N =. )
And the group (a), the group (b) and the group (c) may be each independently substituted with a cyano group, a fluorine atom or a chlorine atom,
^{Z N11,} Z N12, Z ^L1 and ^{Z L2} each independently represent a single _{bond, -CH 2 CH 2 -, -} (CH 2) 4 -, - OCH 2 -, - CH 2 O -, - COO -, - OCO-, -OCF _2- , -CF ₂ O-, -CH = N-N = N-CH-, -CH = CH-, -CF = CF- or -C≡C-
When there are a plurality of A ^N11 , A ^N12 , A ^L1 , A ^L2 and / or A ^L3 , they may be the same or different, and Z ^N11 , Z ^N12 , Z ^L1 and / or Z ^L2 are When two or more of them are present, they may be the same or different, but the compounds represented by the general formula (N-1) have the general formula except for the compounds represented by the general formula (N-1d) The compound represented by (L) excludes the compounds represented by general formula (i), general formula (ii), general formula (N-1d) and general formula (N-1). )

  The so-called n-type liquid crystal composition having a negative Δε of the present invention has improved viewing angle characteristics while satisfying various properties required for the n-type liquid crystal composition, and has excellent display characteristics. The liquid crystal display device of the present invention is useful for display devices such as liquid crystal TVs and monitors.

  As described above, the present invention relates to a specific n-type liquid crystal composition and a liquid crystal display device using the same. Hereinafter, first, an embodiment of the liquid crystal composition in the present invention will be described.

  The composition of the present invention comprises one or more compounds selected from the compounds represented by the general formula (i), and one or more compounds selected from the compounds represented by the general formula (ii) And one or more compounds selected from the compounds represented by the general formula (N-1d), one or more compounds selected from the compounds represented by the general formula (N-1), and the like It contains one or more compounds selected from the compounds represented by formula (L).

  The compounds represented by the general formula (i) correspond to dielectrically neutral compounds (where Δε is −2 to 2).

  Although the compound represented by General formula (i) may use only 1 type, 2 or more types may be used. It is preferable to use only one type from the viewpoint of easiness of procurement.

In the general formula (i), R ⁱ¹ is preferably an ethyl group, a propyl group or a pentyl group, preferably an ethyl group or a propyl group, and more preferably a propyl group. R ⁱ² is preferably a methoxy group.

  The lower limit of the preferable content of the compound represented by the formula (i) to the total amount of the composition of the present invention is 3%, 5%, 7%, 9%, 10 %, 12%, and 13%. The upper limit value of the preferred content is 30%, 27%, 25%, 23%, 20%, 19%, 18%, 17%.

  As a compound represented by General formula (i), the compound represented by Formula (i-1)-(i-4) is preferable, and the compound represented by Formula (i-4) is preferable.

  The lower limit of the preferable content of the compound represented by the formula (i-4) to the total amount of the composition of the present invention is 3%, 5%, 7%, 9% 10%, 12% and 13%. The upper limit value of the preferred content is 30%, 27%, 25%, 23%, 20%, 19%, 18%, 17%.

  The compounds represented by the general formula (ii) correspond to dielectrically neutral compounds (where Δε is −2 to 2).

  Although the compound represented by General formula (ii) may use only 1 type, 2 or more types may be used. It is preferable to use only one type from the viewpoint of easiness of procurement.

In the general formula (ii), R ⁱⁱ¹ is preferably an ethyl group, a propyl group or a pentyl group, preferably an ethyl group or a propyl group, and more preferably a propyl group. R ⁱⁱ² is preferably a methyl group.

  The lower limit of the preferable content of the compound represented by the formula (ii) to the total amount of the composition of the present invention is 2%, 3%, 5%, 7%, 9 %. The upper limit value of the preferable content is 25%, 23%, 20%, 18%, 16% and 14%.

  As a compound represented by General formula (ii), the compound represented by Formula (ii-1)-(ii-4) is preferable, and the compound represented by Formula (ii-3) is preferable.

  The lower limit of the preferable content of the compound represented by the formula (ii-3) to the total amount of the composition of the present invention is 3%, 5%, 7% and 9%. 10%, 12% and 13%. The upper limit value of the preferred content is 30%, 27%, 25%, 23%, 20%, 19%, 18%, 17%.

  For the compound represented by the general formula (i) and the compound represented by the general formula (ii), it is preferable to use a large number of compounds represented by the general formula (i), and represented by the general formula (i) It is preferable to increase the content of the compound as 2%.

  The preferable lower limit of the total content of the compound represented by the general formula (i) and the compound represented by the general formula (ii) based on the total amount of the composition is 15%, 18% and 20%. 22% and 24%. The upper limit value of the preferable content is 40%, 37%, 35%, 33%, 30%, 28%.

  The preferable lower limit of the total content of the compound represented by the general formula (i-4) and the compound represented by the general formula (ii-3) based on the total amount of the composition is 15%, 18%. It is 20%, 22% and 24%. The upper limit value of the preferable content is 40%, 37%, 35%, 33%, 30%, 28%.

  The compounds represented by the general formula (N-1d) correspond to dielectrically negative compounds (the sign of Δε is negative and the absolute value is larger than 2).

  Although the compound represented by general formula (N-1d) may use only 1 type, 2 or more types may be used.

In the general formula (N-1d), R ^Nd11 is an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyl having 2 to 8 carbon atoms An oxy group is preferable, and an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms or an alkenyloxy group having 2 to 5 carbon atoms is preferable. An alkyl group of 1 to 5 or an alkenyl group of 2 to 5 carbon atoms is more preferable, an alkyl group of 2 to 5 carbon atoms or an alkenyl group of 2 to 3 carbon atoms is further preferable, and an alkenyl of 3 carbon atoms Groups (propenyl groups) are particularly preferred. A linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms are preferable. In order to stabilize the nematic phase, the total of carbon atoms and oxygen atoms, if present, is preferably 5 or less, preferably linear.

  Particularly preferred are ethyl and propyl.

R ^Nd12 is preferably an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms, An alkyl group of 1 to 5, an alkoxy group of 1 to 5 carbon atoms, an alkenyl group of 2 to 5 carbon atoms or an alkenyloxy group of 2 to 5 carbon atoms is preferable, and an alkyl group of 1 to 5 carbon atoms or An alkenyl group having 2 to 5 carbon atoms is further preferable, an alkyl group having 2 to 5 carbon atoms or an alkenyl group having 2 to 3 carbon atoms is further preferable, and an alkenyl group having 3 carbon atoms (propenyl group) is particularly preferable. . A linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms are preferable. In order to stabilize the nematic phase, the total of carbon atoms and oxygen atoms, if present, is preferably 5 or less, preferably linear.

  Particularly preferred are methoxy and ethoxy.

n ^Nd11 is preferably 1 or 2, and preferably contains both a compound in which n ^Nd11 is 1 and a compound in which n ^Nd11 is 2.

One or two compounds in which n ^Nd11 is 1 can be used, but it is preferable to use two compounds from the viewpoint of improvement of the lower limit temperature of the nematic phase. When two compounds are used, R ^Nd11 is used. It is preferable to use the same substituent.

One or two compounds in which n ^{Nd 11} is 2 can be used, but it is preferable to use two compounds from the viewpoint of improvement of the lower limit temperature of the nematic phase. When two compounds are used, R ^{Nd 12} is used. It is preferable to use the same substituent.

When a compound in which n ^Nd11 is 1 and a compound in which n ^Nd11 is 2 are used together, it is preferable to use more compounds in which n ^Nd11 is 2.

  The compound represented by the general formula (N-1d) is preferably a compound represented by the compound represented by the general formula (N-1-10) and the compound represented by the general formula (N-1-11) .

  The compounds represented by General Formula (N-1-10) are the following compounds.

(Wherein, each of ^{RN 1101} and ^{RN 1102} independently represents the same meaning as ^{RN 11} and ^{RN 12} in General Formula (N)).
R N ¹¹⁰¹ is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group, a butyl group, a vinyl group or a 1-propenyl group. R N ¹¹⁰² is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although a compound denoted by a general formula (N-1-10) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher, and when importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content Setting high to be effective. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-10) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  Furthermore, the compound represented by General Formula (N-1-10) is a compound selected from the compound group represented by Formula (N-1-10.1) to Formula (N-1-1.21) Are preferably represented by formulas (N-1-10.1) to (N-1-10.5), formulas (N-1-1.20) and formulas (N-1-1.21). It is preferable that it is a compound, Formula (N-1-10.1), Formula (N-1-1.20), Formula (N-1-1.20), and Formula (N-1-1.21) And the compounds represented by the formula (N-1-10.1) and the formula (N-1-10.2) are preferable, and the compounds represented by the formula (N-1-10.1) are preferable. Compounds are preferred.

  The compounds represented by the formula (N-1-10.1), the formula (N-1-10.2), the formula (N-1-1.20) and the formula (N-1-10.21) can be used alone. The lower limit of the preferred content of these compounds alone or in the total amount of the composition of the present invention is 3%, and 5%, although it is possible to use them in combination or in combination. 8%, 10%, 13% and 15%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %.

  The compounds represented by General Formula (N-1-11) are the following compounds.

( ^Wherein , each of R N ¹¹¹¹ and R N ^{11 12} independently represents the same meaning as R ^{N 11} and R ^{N 12} in General Formula (N).)
R ^{N 1111} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group, a butyl group, a vinyl group or a 1-propenyl group. R ^{N 1112} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although a compound denoted by a general formula (N-1-11) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content lower is more effective, and when _TNI is emphasized, the content Setting high to be effective. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-11) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  Furthermore, the compound represented by General Formula (N-1-11) is a compound selected from the compound group represented by Formula (N-1-11.1) to Formula (N-1-11.15) And the compounds represented by formulas (N-1-11.1) to (N-1-11.15) are preferable. The compound represented by 1-11.4) is preferable.

  Although the compounds represented by the formula (N-1-11.2) and the formula (N-1-11.4) can be used alone or in combination, the composition of the present invention The lower limit value of the preferred content of these compounds alone or in the total amount of is 3%, 5%, 8%, 10%, 13%, 15%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  It is selected from compounds represented by formula (N-1-10.1), formula (N-1-10.2), formula (N-1-11.2) and formula (N-1-11.4). Compounds are preferably used, and compounds represented by formula (N-1-10.1), formula (N-1-11.2) and formula (N-1-11.4) It is preferable to use a combination of the formula (N-1-10.1), the formula (N-1-10.2), the formula (N-1-11.2) and the formula (N-1-11.4). It is preferred to use a combination of compounds represented by).

  Although the compound represented by General formula (N-1) may use only 1 type, 2 or more types may be used. The compounds represented by the general formula (N-1) correspond to dielectrically negative compounds (the sign of Δε is negative and the absolute value is larger than 2).

  The compound represented by General Formula (N-1) is preferably a compound in which Δε is negative and the absolute value is larger than 3.

In the general formula (N-1), ^RN11 and ^RN12 are each independently an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or An alkenyloxy group having 2 to 8 carbon atoms is preferable, and an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or 2 to 5 carbon atoms An alkenyloxy group is preferable, an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms is further preferable, and an alkyl group having 2 to 5 carbon atoms or an alkenyl group having 2 to 3 carbon atoms is further added Preferably, an alkenyl group having 3 carbon atoms (propenyl group) is particularly preferred.

  When the ring structure to which it is bonded is a phenyl group (aromatic), a linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and carbon Alkenyl group having 4 to 5 atoms is preferable, and when the ring structure to which it is bonded is a saturated ring structure such as cyclohexane, pyran and dioxane, a linear alkyl group having 1 to 5 carbon atoms, a straight chain Preferred is an alkoxy group having 1 to 4 carbon atoms and a linear alkenyl group having 2 to 5 carbon atoms. In order to stabilize the nematic phase, the total of carbon atoms and oxygen atoms, if present, is preferably 5 or less, preferably linear.

  The alkenyl group is preferably selected from the groups represented by any one of formulas (R1) to (R5). (The black dot in each formula represents a carbon atom in the ring structure.)

  Preferably, they are a C1-C5 alkyl group and a C1-C5 alkoxy group, and they are a methyl group, an ethyl group, a propyl group, a methoxy group, an ethoxy group, and a propoxy group.

It is preferable that A ^N11 and A ^N12 be each independently aromatic when it is required to increase Δn, and in order to improve the response speed, it is preferably aliphatic, and trans-1,4 -Cyclohexylene group, 1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, 3,5-difluoro-1,4-phenylene group 2, 3-difluoro-1,4-phenylene group, 1,4-cyclohexenylene group, 1,4-bicyclo [2.2.2] octylene group, piperidine-1,4-diyl group, naphthalene-2,6- It is preferable to represent a diyl group, decahydronaphthalene-2,6-diyl group or 1,2,3,4-tetrahydronaphthalene-2,6-diyl group, and more preferable to represent the following structure,

A trans-1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group is preferable, and a trans-1,4-cyclohexylene group or a 1,4-phenylene group is more preferable.

Z ^N11 and ^{Z N12} are each _{independently -CH 2 O -, - CF 2} O -, - CH 2 CH 2 -, - CF 2 CF 2 - or preferably a single bond, _-CH 2 O-, -CH ₂ CH ₂ - or a single bond is more preferable, _-CH 2 O-or a single bond is particularly preferred.

n ^N11 + ^{n N12} is preferably 1 or ^2, in combination ^{n N11} is 1 ^{n N12} is ^0, the combination ^{n N11} is 2 ^{n N12} is ^{0, n N11} is 1 in ^{n N12} is 1 It is preferable that a certain combination be a combination in which n ^N11 is 2 and n ^N12 is 1.

  However, the compound represented by general formula (N-1d) is remove | excluded.

  The lower limit of the preferable content of the compound represented by General Formula (N-1) to the total amount of the composition of the present invention is 1%, 10%, 20%, 30% Yes, 40%, 50%, 55%, 60%, 65%, 70%, 75%, 80%. The upper limit of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%, 20% It is.

  The lower limit of the preferable content of the total of the compound represented by General Formula (N-1d) and the compound represented by General Formula (N-1) relative to the total amount of the composition of the present invention is 1% Yes, 10%, 20%, 30%, 40%, 50%, 55%, 60%, 65%, 70%, 75% Yes, 80%. The upper limit of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%, 20% It is.

  When it is necessary to keep the viscosity of the composition of the present invention low and have a high response speed, it is preferable that the above lower limit is low and the upper limit is low. Furthermore, when the composition of the present invention is required to keep Tni high and a composition having good temperature stability is required, it is preferable that the above lower limit is low and the upper limit is low. When it is desired to increase the dielectric anisotropy in order to keep the driving voltage low, it is preferable that the above lower limit value be high and the upper limit value be high.

  As a compound represented by general formula (N-1), the compound group represented by the following general formula (N-1a)-(N-1g) can be mentioned.

^{(Wherein, R N11} and ^{R N12} are as defined ^{R N11} and ^{R N12} in the general formula ^{(N-1), n Na11} represents 0 or ^{1, n NB11} is 1 or ^{2, n NC11} is N ^Ne11 represents 1 or 2; n ^Nf11 represents 1 or 2; n ^Ng11 represents 1 or 2; A ^Ne11 represents a trans-1,4-cyclohexylene group or 1,4 ^-Phenylene group, A ^Ng11 represents a trans-1, 4-cyclohexylene group, 1,4-cyclohexenylene group or 1,4-phenylene group, but at least one is 1,4-cyclohexenylene group And Z ^{Ne 11} represents a single bond or ethylene, but at least one represents ethylene).
More specifically, the compound represented by General Formula (N-1) is a compound selected from the group of compounds represented by General Formulas (N-1-1) to (N-1-21) preferable.

  The compounds represented by General Formula (N-1-1) are the following compounds.

( ^Wherein , R ^N111 and R ^N112 each independently represent the same meaning as R ^N11 and R ^N12 in the general formula (N).)
R ^{N 111} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably a propyl group, a pentyl group or a vinyl group. R ^{N 112} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms, or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group or butoxy group.

    Although a compound denoted by a general formula (N-1-1) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content Setting a lower value is more effective. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-1) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17%, 20%, 23%, 25%, 27%, 30%, 33%, 35%. The upper limit of the preferred content is 50%, 40%, 38%, 35%, 33%, 30%, or 50%, based on the total weight of the composition of the present invention. %, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8%, 7%, 6 %, 5% and 3%.

  Furthermore, the compound represented by General Formula (N-1-1) is a compound selected from the group of compounds represented by Formula (N-1-1. 1) to Formula (N- 1-1.23) And the compounds represented by formulas (N-1-1. 1) to (N- 1.1.4) are preferable, and the compounds represented by formulas (N- 1.1. 1) and (N- The compound represented by 1-1.3) is preferable.

  The compounds represented by the formulas (N-1.1.) To (N-1.1.22) may be used alone or in combination, but the composition of the present invention The lower limit of the preferable content of these compounds alone or in the total amount is 5%, 10%, 13%, 15%, 17%, 20%, 23% 25%, 27%, 30%, 33% and 35%. The upper limit of the preferred content is 50%, 40%, 38%, 35%, 33%, 30%, or 50%, based on the total weight of the composition of the present invention. %, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8%, 7%, 6 %, 5% and 3%.

  The compounds represented by General Formula (N-1-2) are the following compounds.

(Wherein, R ^N121 and R ^N122 each independently represent the same meaning as R ^N11 and R ^N12 in general formula (N).)
^{RN 121} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group, a butyl group or a pentyl group. R ^{N 122} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and a methyl group, a propyl group, a methoxy group, an ethoxy group or a propoxy group is preferred preferable.

    Although a compound denoted by a general formula (N-1-2) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher, and when importance is given to solubility at low temperature, setting it smaller is more effective, and when _TNI is emphasized, the content It is effective to set a larger value. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-2) to the total amount of the composition of the present invention is 5%, 7%, 10%, 13% , 15%, 17%, 20%, 23%, 25%, 27%, 30%, 33%, 35%, 37% 40% and 42%. The upper limit of the preferred content is 50%, 48%, 45%, 43%, 40%, 38%, 35%, based on the total weight of the composition of the present invention. %, 33%, 30%, 28%, 25%, 23%, 20%, 18%, 18%, 15%, 13%, 10%. %, 8%, 7%, 6%, 5%.

Furthermore, the compound represented by General Formula (N-1-2) is a compound selected from the compound group represented by Formula (N-1-2. 1) to Formula (N- 1-2. 22) It is preferable that the formula (N-1-2.3) to the formula (N-1-2.7), the formula (N-1-2.10), the formula (N-1-2.11), the formula It is preferable that it is a compound represented by (N-1-2.13) and Formula (N-1-2.20), and when emphasizing improvement of (DELTA) (epsilon), Formula (N-1-2. 3) Or a compound represented by the formula (N-1-2.7), and when emphasis is placed on improvement of T _NI , the formula (N-1-2.10), the formula (N-1-2.11) And the compound represented by the formula (N-1-2.13), and in the case of emphasizing the improvement of the response speed, the compound represented by the formula (N-1-2.20) Is preferred.

  Although the compounds represented by Formula (N-1-2. 1) to Formula (N- 1-2. 22) can be used alone or in combination, the composition of the present invention The lower limit of the preferred content of these compounds alone or in the total amount of these is 5%, 10%, 13%, 15%, 17%, 20%, 23 %, 25%, 27%, 30%, 33%, 35%. The upper limit of the preferred content is 50%, 40%, 38%, 35%, 33%, 30%, or 50%, based on the total weight of the composition of the present invention. %, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8%, 7%, 6 %, 5% and 3%.

  The compounds represented by General Formula (N-1-3) are the following compounds.

( ^Wherein , R ^{N 131} and R ^{N 132} each independently represent the same meaning as R ^{N 11} and R ^{N 12} in general formula (N).)
R ^{N 131} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 132} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 3 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and 1-propenyl group, ethoxy group, propoxy group or butoxy group is preferable .

  Although the compound represented by general formula (N-1-3) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-3) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  Furthermore, the compound represented by the general formula (N-1-3) is a compound selected from the group of compounds represented by the formula (N-3.1. 1) to the formula (N-1 3.2. 1) And the compounds represented by formulas (N-3.1.) To (N-1-3. 7) and formula (N-1-3. 21) are preferable. -1-3.1), the formula (N-1-3.2), the formula (N-1-3.3), the formula (N-1-3.4) and the formula (N-1-3.6) The compounds represented by) are preferred.

  The compounds represented by the formulas (N-3.1.) To (N-1-3.4), (N-1-3.6) and (N-1-3.21) can be used alone. Although it is possible to use in combination or in combination, a combination of formula (N-3.1.) And formula (N-1-3.2), a formula (N-1-3. 3) Or a combination of two or three selected from formula (N-1-3.4) and formula (N-1-3.6). The lower limit of the preferred content of these compounds alone or in the total amount of the composition of the present invention is 5%, 10%, 13%, 15%, 17%, 20 %. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-4) are the following compounds.

( ^Wherein , each of R ^{N 141} and R ^{N 142} independently represents the same meaning as R ^{N 11} and R ^{N 12} in General Formula (N).)
Independently R ^N141 and ^{R N142} are each an alkyl group having 1 to 5 carbon atoms, preferably an alkenyl group or an alkoxy group having 1 to 4 carbon atoms carbon atoms 4-5, methyl group, propyl group, ethoxy Preferred is a group or butoxy group.

  Although the compound represented by general formula (N-1-4) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content Setting a lower value is more effective. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-4) to the total amount of the composition of the present invention is 3%, 5%, 7%, 10% 13%, 15%, 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15%, 13%, 11%, 10%, 8%.

  Furthermore, the compound represented by the general formula (N-1-4) is a compound selected from the group of compounds represented by formula (N-4.1. 4) to formula (N-1-4. 14) And the compounds represented by formulas (N-4.1.) To (N-1-4. 4) are preferable, and the compounds represented by formulas (N-4-1. 4) and (N The compounds represented by the formula (1--4.2) and the formula (N-1-4.4) are preferred.

  The compounds represented by the formulas (N-4.1.) To (N-1-4.14) can be used alone or in combination, but the composition of the present invention The lower limit of the preferred content of these compounds alone or in the total amount is 3%, 5%, 7%, 10%, 13%, 15%, 17% And 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15%, 13%, 11%, 10%, 8%.

  The compounds represented by General Formula (N-1-5) are the following compounds.

( ^Wherein , R ^{N 151} and R ^{N 152} each independently represent the same meaning as R ^{N 11} and R ^{N 12} in General Formula (N).)
R ^{N 151} and R ^{N 152} are each independently an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms, or an alkoxy group of 1 to 4 carbon atoms, preferably an ethyl group, a propyl group or a butyl group Is preferred.

  Although a compound denoted by a general formula (N-1-5) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher, and when importance is given to solubility at low temperature, setting it smaller is more effective, and when _TNI is emphasized, the content It is effective to set a larger value. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-5) to the total amount of the composition of the present invention is 5%, 8%, 10%, 13% 15%, 17% and 20%. The upper limit value of the preferred content is 35%, 33%, 30%, 28%, 25%, 23%, or 35%, based on the total weight of the composition of the present invention. %, 18%, 15% and 13%.

  Furthermore, the compound represented by the general formula (N-1-5) is a compound selected from the group of compounds represented by the formula (N-1-5.1) to the formula (N-1-5.6) The compounds represented by the formula (N-1-5.1), the formula (N-1-5.2) and the formula (N-1-5.4) are preferable.

  The compounds represented by the formulas (N-1-5.1), (N-1-5.2) and (N-1-5.4) may be used alone or in combination. The lower limit of the preferred content of these compounds alone or in the total amount of the composition of the present invention is 5%, 8%, 10%, 13%, although it is also possible. It is 15%, 17% and 20%. The upper limit value of the preferred content is 35%, 33%, 30%, 28%, 25%, 23%, or 35%, based on the total weight of the composition of the present invention. %, 18%, 15% and 13%.

  The compounds represented by General Formula (N-1-12) are the following compounds.

^{(Wherein, R N1121} and ^{R N1122} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
R ^{N 1121} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 1122} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms, or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although the compound represented by general formula (N-1-12) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-12) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-13) are the following compounds.

^{(Wherein, R N1131} and ^{R N1132} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
R ^{N 1131} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 1132} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although the compound represented by general formula (N-1-13) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-13) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-14) are the following compounds.

( ^Wherein , each of R N ¹¹⁴¹ and R ^{N 114 2} independently represents the same meaning as R ^{N 11} and R ^{N 12} in General Formula (N).)
R ^{N 1141} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 1142} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms, or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although a compound denoted by a general formula (N-1-14) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-14) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-15) are the following compounds.

^{(Wherein, R N1151} and ^{R N1152} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
R ^{N 1151} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 1152} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although a compound denoted by a general formula (N-1-15) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-15) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-16) are the following compounds.

^{(Wherein, R N1161} and ^{R N1162} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
R ^{N 1161} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 1162} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although the compound represented by general formula (N-1-16) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-16) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-17) are the following compounds.

^{(Wherein, R N1171} and ^{R N1172} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
R ^{N 1171} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group. R ^{N 1172} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although the compound represented by general formula (N-1-17) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-17) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-18) are the following compounds.

( ^Wherein , each of R ^N1181 and R ^N1182 independently represents the same meaning as R ^N11 and R ^N12 in General Formula (N).)
R ^{N 1181} is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably a methyl group, an ethyl group, a propyl group or a butyl group. R ^{N 1182} is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.

  Although a compound denoted by a general formula (N-1-18) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-18) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  Furthermore, the compound represented by General Formula (N-1-18) is a compound selected from the group of compounds represented by Formula (N-1-18.1) to Formula (N-1-18.5) And the compounds represented by formulas (N-1-18.1) to (N-1-11.3) are preferable. The compound represented by 1-18.3) is preferable.

  The compounds represented by General Formula (N-1-20) are the following compounds.

^{(Wherein, R N1201} and ^{R N1202} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
Each of ^{RN 1201} and ^{RN 1202} is independently preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.

  Although a compound denoted by a general formula (N-1-20) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-20) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-21) are the following compounds.

( ^Wherein , each of R N ¹²¹¹ and R N ^{12 12} independently represents the same meaning as R ^{N 11} and R ^{N 12} in general formula (N).)
^Each of R ^N1211 and R ^N1212 is independently preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.

  Although the compound represented by general formula (N-1-21) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-21) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.

  The compounds represented by General Formula (N-1-22) are the following compounds.

^{(Wherein, R N1221} and ^{R N1222} independently represents the same meaning as ^{R N11} and ^{R N12} in the general formula (N).)
^Each of R ^N1221 and R ^N1222 is independently preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.

  Although a compound denoted by a general formula (N-1-22) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

When importance is attached to improvement of Δε, it is preferable to set the content higher. When importance is given to solubility at low temperature, setting the content higher is more effective, and when _TNI is emphasized, the content It is effective to set up to Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (N-1-21) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% 15%, 17% and 20%. The upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15%, 13%, 10%, 5%.

  Furthermore, the compound represented by General Formula (N-1-22) is a compound selected from the compound group represented by Formula (N-1-22.1) to Formula (N-1-22.12) Are preferably compounds represented by formulas (N-1-22.1) to (N-1-22.5), and compounds represented by formulas (N-1-22.1) to (N- The compound represented by 1-22.4) is preferable.

  The liquid crystal composition of the present invention preferably contains one or more compounds represented by General Formula (L). The compounds represented by the general formula (L) correspond to dielectric substantially neutral compounds (the value of Δε is −2 to 2).

  However, the compound represented by general formula (i), general formula (ii), general formula (N-1d), and general formula (N-1) is remove | excluded.

  The compounds represented by formula (L) may be used alone or in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the desired performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of compound used is, for example, one type in one embodiment of the present invention. Or in another embodiment of the present invention, there are 2 types, 3 types, 4 types, 5 types, 5 types, 6 types, 7 types, 8 types, 9 types and 10 It is more than kind.

  In the composition of the present invention, the content of the compound represented by the general formula (L) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping marks, image sticking, It is necessary to appropriately adjust according to the required performance such as dielectric anisotropy.

  The compounds represented by formula (L) are so-called nonpolar compounds in which Δε is around zero. Therefore, the number of polar groups such as halogen atoms in the molecule is preferably 2 or less, preferably 1 or less, and 1 to improve the solubility with other liquid crystal compounds. It is preferable that it is not substituted, when paying attention to viscosity.

  The lower limit value of the preferable content of the compound represented by the general formula (L) to the total amount of the composition of the present invention is 1%, 10%, 20%, 30%. 40%, 50%, 55%, 60%, 65%, 70%, 75%, 80%. The upper limit value of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%.

  Compounds represented by general formula (i), general formula (ii), general formula (N-1 d), general formula (N-1) and general formula (L) with respect to the total amount of the composition of the present invention The lower limit value of the preferable content is 1%, 10%, 20%, 30%, 40%, 50%, 55%, 60%, 65% 70%, 75% and 80%. The upper limit value of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%.

  When the composition of the present invention is required to keep the viscosity low and have a high response speed, it is preferable that the above lower limit is high and the upper limit is high. Furthermore, when the composition of the present invention is required to keep Tni high and a composition having good temperature stability is required, it is preferable that the above lower limit value is high and the upper limit value is high. When it is desired to increase the dielectric anisotropy in order to keep the drive voltage low, it is preferable that the above lower limit value be low and the upper limit value be low.

When reliability is important, both R ^L1 and R ^L2 are preferably alkyl groups, and when importance is given to reducing the volatility of the compound, alkoxy groups are preferable, and viscosity reduction is important When doing, at least one is preferably an alkenyl group.

    The number of halogen atoms present in the molecule is preferably 0, 1, 2 or 3 and is preferably 0 or 1. When importance is attached to compatibility with other liquid crystal molecules, 1 is preferred.

R ^L1 and R ^L2 are, when the ring structure to which they are bonded is a phenyl group (aromatic), a linear alkyl group of 1 to 5 carbon atoms, or a linear alkyl group of 1 to 4 carbon atoms Alkoxy groups and alkenyl groups having 4 to 5 carbon atoms are preferred, and in the case where the ring structure to which they are attached is a saturated ring structure such as cyclohexane, pyran and dioxane, a straight chain having 1 to 5 carbon atoms The alkyl group, the linear alkoxy group having 1 to 4 carbon atoms, and the linear alkenyl group having 2 to 5 carbon atoms are preferable. In order to stabilize the nematic phase, the total of carbon atoms and oxygen atoms, if present, is preferably 5 or less, preferably linear.

  The alkenyl group is preferably selected from the groups represented by any one of formulas (R1) to (R5). (The black dot in each formula represents a carbon atom in the ring structure.)

n ^L1 is preferably 0 when importance is attached to the response speed, 2 or 3 is preferable to improve the upper limit temperature of the nematic phase, and 1 is preferable to balance them. Moreover, in order to satisfy the characteristics required as a composition, it is preferable to combine compounds of different values.

A ^{L 1} , A ^{L 2} and A ^{L 3} are preferably aromatic when it is required to increase Δn, and are preferably aliphatic to improve the response speed, and each of them is independently trans- 1,4-cyclohexylene group, 1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, 3,5-difluoro-1,4-phenylene group 1,4-cyclohexenylene group 1,4-bicyclo [2.2.2] octyrene group piperidine-1,4-diyl group naphthalene-2,6-diyl group decahydronaphthalene-2,6 -Preferably represents a diyl group or 1,2,3,4-tetrahydronaphthalene-2,6-diyl group, more preferably represents the following structure,

More preferably, it represents a trans-1,4-cyclohexylene group or a 1,4-phenylene group.

It is preferable that Z ^L1 and Z ^L2 be a single bond when the response speed is important.

  The compound represented by formula (L) preferably has 0 or 1 halogen atoms in the molecule.

  The compound represented by formula (L) is preferably a compound selected from the group of compounds represented by formulas (L-1) to (L-7).

  The compounds represented by General Formula (L-1) are the following compounds.

(Wherein, R ^L11 and R ^L12 each independently represent the same meaning as R ^L1 and R ^L2 in general formula (L).)
R ^L11 and R ^L12 are preferably linear alkyl groups having 1 to 5 carbon atoms, linear alkoxy groups having 1 to 4 carbon atoms, and linear alkenyl groups having 2 to 5 carbon atoms. .

  Although the compound represented by general formula (L-1) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

  The lower limit value of the preferable content is 1%, 2%, 3%, 5%, 7%, 10% with respect to the total amount of the composition of the present invention. The upper limit of the preferred content is 40%, 35%, 33%, 30%, and 25% based on the total weight of the composition of the present invention.

  When the composition of the present invention is required to keep the viscosity low and have a high response speed, it is preferable that the above lower limit is high and the upper limit is high. Furthermore, when the composition of the present invention needs to have a high Tni and a composition having good temperature stability is required, it is preferable that the above lower limit value is medium and the upper limit value is medium. When it is desired to increase the dielectric anisotropy in order to keep the drive voltage low, it is preferable that the above lower limit value is low and the upper limit value is low. In order to improve the viewing angle characteristics, it is not preferable to increase the upper limit value.

  The compound represented by Formula (L-1) is preferably a compound selected from the group of compounds represented by Formula (L-1-1).

(Wherein, R ^L12 represents the same meaning as in the general formula (L-1).)
The compound represented by General Formula (L-1-1) is a compound selected from the compound group represented by Formula (L-1-1. 1) to Formula (L- 1-1. 3) It is preferable that it is a compound represented by formula (L-1-1.2) or formula (L-1-1.3), in particular, it is represented by formula (L-1-1.3) It is preferable that it is a compound.

  The lower limit value of the preferable content of the compound represented by the formula (L-1-1.3) to the total amount of the composition of the present invention is 1%, 2%, 3%, It is 5%, 7% and 10%. The upper limit of the preferred content is 20%, 15%, 13%, 10%, 8%, 7%, based on the total weight of the composition of the present invention. %, 5% and 3%.

  The compound represented by Formula (L-1) is preferably a compound selected from the group of compounds represented by Formula (L-1-2).

(Wherein, R ^L12 represents the same meaning as in the general formula (L-1).)
The lower limit of the preferable content of the compound represented by the formula (L-1-2) to the total amount of the composition of the present invention is 1%, 5%, 10%, 15% , 17%, 20%, 23%, 25%, 27%, 30%, 35%. The upper limit of the preferred content is 60%, 55%, 50%, 45%, 42%, 40%, based on the total weight of the composition of the present invention. %, 35%, 33%, and 30%.

  Furthermore, the compound represented by General Formula (L-1-2) is a compound selected from the group of compounds represented by Formula (L-2.1) to Formula (L-1-2.4) And the compounds represented by formulas (L-1-2.2) to (L-1-2.4) are preferable. In particular, a compound represented by the formula (L-1-2.2) is preferable in order to particularly improve the response speed of the composition of the present invention. When Tni higher than the response speed is to be determined, it is preferable to use a compound represented by Formula (L-1-2.3) or Formula (L-1-2.4). It is not preferable that the content of the compounds represented by Formula (L-1-2.3) and Formula (L-1-2.4) be 30% or more in order to improve the solubility at low temperature.

  The lower limit of the preferable content of the compound represented by the formula (L-1-2.2) to the total amount of the composition of the present invention is 10%, 15% and 18%, 20%, 23%, 25%, 27%, 30%, 33%, 35%, 38%, 40%. The upper limit of the preferred content is 60%, 55%, 50%, 45%, 43%, 40%, 60%, based on the total weight of the composition of the present invention. %, 35%, 32%, 30%, 27%, 25%, 22%.

  Lower limit of preferable content of the total of the compound represented by the formula (L-1-1.3) and the compound represented by the formula (L-1-2.2) relative to the total amount of the composition of the present invention The values are 10%, 15%, 20%, 25%, 27%, 30%, 35%, 40%. The upper limit of the preferred content is 60%, 55%, 50%, 45%, 43%, 40%, 60%, based on the total weight of the composition of the present invention. %, 35%, 32%, 30%, 27%, 25%, 22%.

  The compound represented by Formula (L-1) is preferably a compound selected from the group of compounds represented by Formula (L-1-3).

(In the formula, R ^L13 and R ^L14 each independently represent an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms.)
R ^L13 and R ^L14 are preferably a linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms. .

The lower limit of the preferable content of the compound represented by the formula (L-1-3) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% , 15%, 17%, 20%, 23%, 25%, 30%. The upper limit of the preferred content is 60%, 55%, 50%, 45%, 40%, 37%, 35%, based on the total weight of the composition of the present invention. %, 33%, 30%, 27%, 25%, 23%, 20%, 17%, 15%, 13%, 10%. %.
Further, the compound represented by the general formula (L-1-3) is a compound selected from the group of compounds represented by the formula (L-3.1. 1) to the formula (L-1.3.1. 2) It is preferable that it is a compound represented by Formula (L-1-3.1), Formula (L-1-3.3), or Formula (L-1-3.4). In particular, the compound represented by the formula (L-3.1) is preferable in order to particularly improve the response speed of the composition of the present invention. In addition, when Tni higher than the response speed is to be determined, the formula (L-1-3.3), the formula (L-1-3.4), the formula (L-1-3.11) and the formula (L-) can be obtained. It is preferable to use the compound represented by 1-3.12). The total of the compounds represented by the formula (L-1-3.3), the formula (L-1-3.4), the formula (L-1.3.11) and the formula (L-1.3.12) It is not preferable to make the content of 20% or more to improve the solubility at low temperature.

  The lower limit of the preferable content of the compound represented by the formula (L-3.1) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%, 10%, 13%, 15%, 18%, 20%. The upper limit of the preferred content is 20%, 17%, 15%, 13%, 10%, 8%, or 20%, based on the total weight of the composition of the present invention. % And 6%.

  The compound represented by formula (L-1) is preferably a compound selected from the group of compounds represented by formula (L-1-4) and / or (L-1-5).

(In the formula, R ^L15 and R ^L16 each independently represent an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms.)
R ^L15 and R ^L16 are preferably a linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms. .

  The lower limit of the preferable content of the compound represented by the formula (L-1-4) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% 15%, 17% and 20%. The upper limit of the preferred content is 25%, 23%, 20%, 17%, 15%, 13%, 10%, based on the total weight of the composition of the present invention. %.

  The lower limit of the preferable content of the compound represented by the formula (L-1-5) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% 15%, 17% and 20%. The upper limit of the preferred content is 25%, 23%, 20%, 17%, 15%, 13%, 10%, based on the total weight of the composition of the present invention. %.

  Furthermore, the compounds represented by general formulas (L-1-4) and (L-1-5) are represented by formulas (L-4.1.) To (L-1-5.3) It is preferable that it is a compound selected from the compound group, and it is preferable that it is a compound represented by Formula (L-1-4.2) or Formula (L-1-5.2).

  The lower limit of the preferable content of the compound represented by the formula (L-1-4.2) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%, 10%, 13%, 15%, 18%, 20%. The upper limit of the preferred content is 20%, 17%, 15%, 13%, 10%, 8%, or 20%, based on the total weight of the composition of the present invention. % And 6%.

Formula (L-1-1.3), Formula (L-1-2.2), Formula (L-1-3.1), Formula (L-1-3.3), Formula (L-1-1.3) 3.4), It is preferable to combine 2 or more types of compounds chosen from the compound represented by Formula (L-1-3.11) and Formula (L-1-3.12), It is preferable -1.3), formula (L-1-2.2), formula (L-1-3.1), formula (L-1-3.3), formula (L-1-3.4) and It is preferable to combine two or more types of compounds selected from the compounds represented by the formula (L-1-4.2), and the lower limit of the preferable content of the total content of these compounds is the composition of the present invention 1%, 2%, 3%, 5%, 7%, 10%, 13%, 15%, 18% with respect to the total amount of 20% and 23%, 5%, 27%, 30%, 33%, 35%, and the upper limit is 80%, 70% with respect to the total amount of the composition of the present invention, 60%, 50%, 45%, 40%, 37%, 35%, 33%, 30%, 30%, 28%, 25%, It is 23% and 20%. When importance is placed on the reliability of the composition, compounds represented by Formula (L-3.1.), Formula (L-1-3.3) and Formula (L-1-3.4)) It is preferable to combine two or more compounds selected from the above, and when importance is attached to the response speed of the composition, it is represented by the formula (L-1-1.3) and the formula (L-1-2.2) It is preferable to combine two or more compounds selected from
The compound represented by Formula (L-1) is preferably a compound selected from the group of compounds represented by Formula (L-1-6).

(In the formula, R ^L17 and R ^L18 each independently represent a methyl group or a hydrogen atom.)
The lower limit of the preferable content of the compound represented by the formula (L-1-6) to the total amount of the composition of the present invention is 1%, 5%, 10%, 15% , 17%, 20%, 23%, 25%, 27%, 30%, 35%. The upper limit of the preferred content is 60%, 55%, 50%, 45%, 42%, 40%, based on the total weight of the composition of the present invention. %, 35%, 33%, and 30%.

  Furthermore, the compound represented by General Formula (L-1-6) is a compound selected from the compound group represented by Formula (L-1-6.1) to Formula (L-1-6.3) Is preferred.

  The compound represented by general formula (L-2) is the following compound.

(Wherein, R ^L21 and R ^L22 each independently represent the same meaning as R ^L1 and R ^L2 in general formula (L).)
R ^L21 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and R ^L22 is an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or a carbon atom The alkoxy group of the number 1-4 is preferable.

    Although the compound represented by general formula (L-1) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

  When importance is given to solubility at low temperature, setting the content higher is more effective, and conversely, when importance is placed on response speed, setting the content smaller is more effective. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  The lower limit of the preferable content of the compound represented by the formula (L-2) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7% and 10%. The upper limit of the preferred content is 20%, 15%, 13%, 10%, 8%, 7%, based on the total weight of the composition of the present invention. %, 5% and 3%.

  Furthermore, the compound represented by General Formula (L-2) is preferably a compound selected from the group of compounds represented by Formula (L-2.1) to Formula (L-2.6), It is preferable that it is a compound represented by (L-2.1), Formula (L-2.3), Formula (L-2.4), and Formula (L-2.6).

  The compounds represented by General Formula (L-3) are the following compounds.

(Wherein, R ^L31 and R ^L32 each independently represent the same meaning as R ^L1 and R ^L2 in general formula (L).)
Each of R ^L31 and R ^L32 is preferably independently an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 4 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms.

  Although a compound denoted by a general formula (L-3) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

  The lower limit of the preferable content of the compound represented by the formula (L-3) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7% and 10%. The upper limit of the preferred content is 20%, 15%, 13%, 10%, 8%, 7%, based on the total weight of the composition of the present invention. %, 5% and 3%.

  In the case of obtaining a high birefringence, it is effective to set the content to a large value, and conversely, in the case of placing importance on high Tni, the effect is set to a small amount. Furthermore, in the case of improving the drop marks and the sticking characteristic, it is preferable to set the range of the content in the middle.

  Furthermore, the compound represented by General Formula (L-3) is preferably a compound selected from the group of compounds represented by Formula (L-3.3) or Formula (L-3.4).

  The compounds represented by General Formula (L-4) are the following compounds.

(Wherein, R ^L41 and R ^L42 each independently represent the same meaning as R ^L1 and R ^L2 in General Formula (L).)
R ^L41 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and R ^L42 is an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or a carbon atom The alkoxy group of the number 1-4 is preferable. )
Although a compound denoted by a general formula (L-4) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

  In the composition of the present invention, the content of the compound represented by the general formula (L-4) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping mark, It is necessary to appropriately adjust according to the required performance such as burn-in and dielectric anisotropy.

  The lower limit of the preferable content of the compound represented by the formula (L-4) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16%, 20%, 23%, 26%, 30%, 35%, 40% . The upper limit of the preferable content of the compound represented by the formula (L-4) to the total amount of the composition of the present invention is 50%, 40%, 35%, and 30%. 20%, 15%, 10% and 5%.

  The compound represented by General Formula (L-4) is preferably a compound represented by Formula (L-4.1) to Formula (L-4.3), for example.

  Depending on required properties such as low temperature solubility, transition temperature, electrical reliability, birefringence, etc., the compound represented by the formula (L-4.1) may be represented by the formula (L-4.1) Even if it contains the compound represented by -4.2), it contains both the compound represented by the formula (L-4.1) and the compound represented by the formula (L-4.2) Or all of the compounds represented by Formula (L-4.1) to Formula (L-4.3) may be contained. The lower limit of the preferable content of the compound represented by the formula (L-4.1) or the formula (L-4.2) to the total amount of the composition of the present invention is 3%, 5% Yes, 7%, 9%, 11%, 12%, 13%, 18%, 21%, preferred upper limit is 45, 40% , 35%, 30%, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8% .

  When both the compound represented by the formula (L-4.1) and the compound represented by the formula (L-4.2) are contained, both compounds relative to the total amount of the composition of the present invention The lower limit of the preferable content is 15%, 19%, 24%, 30%, and the preferable upper limit is 45, 40%, 35%, 30% Yes, 25%, 23%, 20%, 18%, 15%, 13%.

  The compound represented by General Formula (L-4) is preferably a compound represented by Formula (L-4.4) to Formula (L-4.6), for example. It is preferable that it is a compound represented by these.

  Depending on the required properties such as low temperature solubility, transition temperature, electrical reliability, birefringence, etc., the compound represented by formula (L-4.4) may also contain formula (L Even if it contains the compound represented by -4.5), it contains both the compound represented by the formula (L-4.4) and the compound represented by the formula (L-4.5) May be

  The lower limit of the preferable content of the compound represented by the formula (L-4.4) or the formula (L-4.5) to the total amount of the composition of the present invention is 3%, 5% Yes, 7%, 9%, 11%, 12%, 13%, 18%, 21%. The preferred upper limit is 45, 40%, 35%, 30%, 25%, 23%, 20%, 18%, 15%, 13%. %, 10%, and 8%.

  When both the compound represented by the formula (L-4.4) and the compound represented by the formula (L-4.5) are contained, both compounds relative to the total amount of the composition of the present invention The lower limit of the preferable content is 15%, 19%, 24%, 30%, and the preferable upper limit is 45, 40%, 35%, 30% Yes, 25%, 23%, 20%, 18%, 15%, 13%.

  The compound represented by Formula (L-4) is preferably a compound represented by Formula (L-4.7) to Formula (L-4.10), and in particular, a compound represented by Formula (L-4. The compound represented by 9) is preferable.

  The compounds represented by General Formula (L-5) are the following compounds.

(Wherein, R ^L51 and R ^L52 each independently represent the same meaning as R ^L1 and R ^L2 in general formula (L).)
R ^L51 is preferably an alkenyl group having 2 to 5 alkyl groups or carbon atoms of 1 to 5 carbon ^{atoms, R L52} is an alkyl group having 1 to 5 carbon atoms, an alkenyl group or a carbon atom of the carbon atoms 4-5 The alkoxy group of the number 1-4 is preferable.

  Although the compound represented by general formula (L-5) can also be used independently, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

  In the composition of the present invention, the content of the compound represented by the general formula (L-5) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping mark, It is necessary to appropriately adjust according to the required performance such as burn-in and dielectric anisotropy.

The lower limit of the preferable content of the compound represented by the formula (L-5) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16%, 20%, 23%, 26%, 30%, 35%, 40% . The upper limit of the preferable content of the compound represented by the formula (L-5) to the total amount of the composition of the present invention is 50%, 40%, 35%, and 30%. The compound represented by the general formula (L-5), which is 20%, 15%, 10% and 5%, is a compound represented by the formula (L-5.1) or the formula (L-5.2) It is preferable that it is a compound represented by these, and it is preferable that it is a compound represented by Formula (L-5.1) especially.

  The lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%. The upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.

  The compound represented by General Formula (L-5) is preferably a compound represented by Formula (L-5.3) or Formula (L-5.4).

  The lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%. The upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.

  The compound represented by General Formula (L-5) is preferably a compound selected from the group of compounds represented by Formula (L-5.5) to Formula (L-5.7), and in particular It is preferable that it is a compound represented by L-5.7.

  The lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%. The upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.

  The compounds represented by General Formula (L-6) are the following compounds.

(Wherein, R ^L61 and R ^L62 each independently represent the same as R ^L1 and R ^L2 in General Formula (L), and X ^L61 and X ^L62 each independently represent a hydrogen atom or a fluorine atom. )
Each of R ^L61 and R ^L62 is preferably independently an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms, and one of X ^L61 and X ^L62 is a fluorine atom, and the other is a hydrogen atom Is preferred.

  Although a compound denoted by a general formula (L-6) can also be used alone, it can also be used combining two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.

  The lower limit of the preferable content of the compound represented by the formula (L-6) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16%, 20%, 23%, 26%, 30%, 35%, 40% . The upper limit of the preferable content of the compound represented by the formula (L-6) relative to the total amount of the composition of the present invention is 50%, 40%, 35%, and 30%. 20%, 15%, 10% and 5%. When emphasis is placed on increasing Δn, it is preferable to increase the content, and when emphasis is put on precipitation at low temperature, it is preferable to reduce the content.

  The compound represented by General Formula (L-6) is preferably a compound represented by Formula (L-6.1) to Formula (L-6.9).

  Although there is no restriction | limiting in particular in the kind of compound which can be combined, It is preferable to contain 1 type-3 types in these compounds, and 1 type-4 types are more preferable to contain. In addition, since a broad molecular weight distribution of the selected compound is also effective for solubility, for example, one compound represented by the formula (L-6.1) or (L-6.2), a compound of the formula (L- 6.4) or (L-6.5) from the compound represented by the formula (L-6.6) or the formula (L-6.7) It is preferable to select one type of compound from the compounds represented by -6.8) or (L-6.9) and appropriately combine these. Among them, it is represented by the formula (L-6.1), the formula (L-6.3) the formula (L-6.4), the formula (L-6.6) and the formula (L-6.9) It is preferred to include a compound.

  Furthermore, the compound represented by General Formula (L-6) is preferably a compound represented by Formula (L-6.10) to Formula (L-6.17), for example. It is preferable that it is a compound represented by L-6.

  The lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%. The upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.

  The compounds represented by General Formula (L-7) are the following compounds.

(Wherein, R ^L71 and R ^L72 each independently represent the same as R ^L1 and R ^L2 in the general formula (L), and A ^L71 and A ^L72 are each independently A ^L2 and A ^L2 in the general formula (L) A hydrogen having the same meaning as A ^L3 is represented, but each of hydrogen atoms on A ^L71 and A ^L72 may be independently substituted by a fluorine atom, and Z ^L71 has the same meaning as Z ^L2 in formula (L), X ^L71 and X ^L72 each independently represent a fluorine atom or a hydrogen atom.)
^{Wherein, R L71} and ^{R L72} are each independently an alkyl group having 1 to 5 carbon atoms, an alkenyl group or an alkoxy group having 1 to 4 carbon atoms 2 to 5 carbon atoms ^{preferably, A L71} and ^{A L72} each independently 1,4-cyclohexylene group or a 1,4-phenylene group is preferably a hydrogen atom on a ^L71 and a ^L72 may be substituted by fluorine atoms independently, Z ^L71 is a single A bond or COO- is preferable, a single bond is preferable, and X ^L71 and X ^L72 are preferably hydrogen atoms.

  There is no particular limitation on the types of compounds that can be combined, but they are combined according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like. The type of compound used is, for example, one type, two types, three types, and four types according to one embodiment of the present invention.

  In the composition of the present invention, the content of the compound represented by the general formula (L-7) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping mark, It is necessary to appropriately adjust according to the required performance such as burn-in and dielectric anisotropy.

  The lower limit of the preferable content of the compound represented by the formula (L-7) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16% and 20%. The upper limit of the preferable content of the compound represented by the formula (L-7) to the total amount of the composition of the present invention is 30%, 25%, 23%, and 20%. 18%, 15%, 10% and 5%.

  It is preferable to increase the content of the compound represented by formula (L-7) when the composition of the present invention is desired to have a high Tni embodiment, and the content is desired if a low viscosity embodiment is desired. It is preferable to reduce the

  Furthermore, the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.1) to Formula (L-7.4), and the compound represented by Formula (L-7. It is preferable that it is a compound represented by 2).

  Furthermore, the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7. 11) to Formula (L-7. 13), and the compound represented by Formula (L-7. It is preferable that it is a compound represented by 11).

  Furthermore, the compound represented by General Formula (L-7) is a compound represented by Formula (L-7.21) to Formula (L-7.23). It is preferable that it is a compound represented by Formula (L-7.21).

  Furthermore, the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7. 31) to Formula (L-7. 34), and the compound represented by Formula (L-7. 31) or / and a compound represented by the formula (L-7. 32) is preferable.

  Furthermore, the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.41) to Formula (L-7.44), and the compound represented by Formula (L-7. 41) or / and a compound represented by the formula (L-7. 42) are preferable.

  Furthermore, the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.51) to Formula (L-7.53).

Compounds represented by general formula (i), general formula (ii), general formula (N-1 d), general formula (N-1) and general formula (L) with respect to the total amount of the composition of the present invention The lower limit of the total preferable content is 80%, 85%, 88%, 90%, 92%, 93%, 94%, 95%, and It is 96%, 97%, 98%, 99% and 100%. The upper limit of the preferred content is 100%, 99%, 98% and 95%.

  The conventional composition is a combination of a compound having a bicyclohexane skeleton represented by the formula (L-3.1. 1) of the present application and a compound having a biphenyl skeleton represented by the formula (ii-3). However, the composition of the present invention uses the compounds represented by the general formulas (i) and (ii) and further displays a table of the general formula (N-1d), the general formula (N-1) and the general formula (L) So-called neutral compounds (compounds represented by general formula (i), general formula (ii)), each containing a predetermined amount of a compound represented by general formula (i) or (ii) The subject of the present application is solved by adjusting the content of the compounds represented by the general formulas (i) and (ii) in the compound represented by and the compound represented by the general formula (L) .

  General formulas (i) and (ii) in neutral compounds (compounds represented by general formula (i), compounds represented by general formula (ii) and compounds represented by general formula (L) Lower limit value of the total content of the compounds to be added is 20%, 25%, 30%, 35%, 38%, 40%, 42%, 45 %. A preferred upper limit is 70%, 65%, 63%, 60%, 58%, 56%, 55%.

  The lower limit of the preferable content of the total of the compounds represented by General Formula (i), General Formula (ii) and General Formula (L-4.4) to the total amount of the composition of the present invention is 8% 10%, 13%, 15% and 20%. The upper limit value of the preferable content is 50%, 45%, 43%, 40%, 38%, 35%. General Formula (i), General Formula (ii) in a Neutral Compound (a Compound Represented by General Formula (i), a Compound Represented by General Formula (ii), and a Compound Represented by General Formula (L) And the lower limit value of the preferable content of the total of the compounds represented by general formula (L-4.4) is 20%, 25%, 30%, 35%, 38% 40%, 42% and 45%. A preferred upper limit is 70%, 65%, 63%, 60%, 58%, 56%, 55%.

  In the present composition, as a combination of neutral compounds, it is possible to combine the compounds represented by the general formulas (i), (ii), (L-1), (L-4) and (L-5) preferable.

  General Formulas (i), (ii) and ((Compounds represented by General Formula (i), Compounds Represented by General Formula (ii) and Compounds Represented by General Formula (L)) The lower limit value of the preferable content of the total of the compounds represented by L-5) is 20%, 25%, 30%, 35%, 38%, 40%, 42% and 45%. A preferred upper limit is 70%, 65%, 63%, 60%, 58%, 56%, 55%.

  The upper limit of the preferable content of the total of the compound having an alkenyl group to the total amount of the composition of the present invention is 30%, 25%, 20%, 15%, 13% 10%, 8%, 5%, 3%, 2%, 2%, 1%, preferably not substantially containing. The inclusion of a compound having an alkenyl group is effective for improving the response speed, but from the viewpoint of reliability and wavelength dispersion of Δn, it is preferable that the content be as small as possible.

  Preferred upper limit of the total content of the compound represented by General Formula (N-1d) and the compound represented by General Formula (N-1) relative to the total amount of the composition of the present invention is the compound having an alkenyl group The values are 20%, 18%, 15%, 13%, 10%, 8%, 5%, 3%, 2%, 1% It is preferable not to contain substantially. The inclusion of a compound having an alkenyl group is effective for improving the response speed, but from the viewpoint of reliability and wavelength dispersion of Δn, it is preferable that the content be as small as possible.

  The composition of the present invention preferably does not contain a compound having a structure in which oxygen atoms such as a peracid (-CO-OO-) structure are bonded to each other in the molecule.

  When importance is placed on the reliability and long-term stability of the composition, the content of the compound having a carbonyl group is preferably 5% or less, more preferably 3% or less, based on the total mass of the composition. Preferably, it is more preferably 1% or less, and most preferably substantially free.

  When importance is placed on stability due to UV irradiation, the content of the compound substituted with chlorine atoms is preferably 15% or less, preferably 10% or less, based on the total mass of the composition. % Is preferable, 5% or less is more preferable, 3% or less is preferable, and substantially no content is further preferable.

  It is preferable to increase the content of compounds in which all ring structures in the molecule are six-membered rings, and the content of compounds in which all ring structures in the molecule are six-membered rings is 80 based on the total mass of the composition. % Or more is preferable, 90% or more is more preferable, 95% or more is more preferable, and the composition is composed only of compounds in which all ring structures in the molecule are substantially 6-membered rings. Most preferred.

  In order to improve the stability when the composition is dispersed, it is preferable to increase the content of the compound whose side chain is an alkyl group and an alkoxy group, and the content of the compound whose side chain is an alkyl group and an alkoxy group The total weight of the composition is preferably 85% or more, more preferably 87% or more, preferably 90% or more, and preferably 93% or more, preferably 95% or more. Is preferably 98% or more, and more preferably substantially 100%. By substantially 100% is meant 100%, excluding polymerizable compounds, stabilizers and additionally incorporated impurities.

  In order to suppress deterioration due to oxidation of the composition, it is preferable to reduce the content of the compound having a cyclohexenylene group as a ring structure, and the content of the compound having a cyclohexenylene group is the total mass of the composition. On the other hand, it is preferably 10% or less, preferably 8% or less, more preferably 5% or less, preferably 3% or less, and even more preferably substantially non-containing.

  In the case of focusing on the improvement of the viscosity and the improvement of Tni, the content of the compound having a 2-methylbenzene-1,4-diyl group in which the hydrogen atom may be substituted by halogen in the molecule may be reduced. Preferably, the content of the compound having the 2-methylbenzene-1,4-diyl group in the molecule is preferably 10% or less, and more preferably 8% or less, based on the total mass of the composition. And 5% or less is more preferable, 3% or less is preferable, and substantially no content is more preferable.

  In the present application, "not substantially contained" means that it is not contained except for unintentionally contained substances.

  When the compound contained in the composition of the first embodiment of the present invention has an alkenyl group as a side chain, when the alkenyl group is bonded to cyclohexane, the number of carbon atoms of the alkenyl group is 2 to 5 When the alkenyl group is bonded to benzene, the number of carbon atoms of the alkenyl group is preferably 4 to 5, and the unsaturated bond of the alkenyl group and benzene are directly bonded. Preferably not.

The average elastic constant (K _AVG ) of the liquid crystal composition used in the present invention is preferably 10 to 25, but the lower limit is preferably 10, 10.5 is preferred, 11 is preferred and 11.5 is preferred. , 12 is preferable, 12.3 is preferable, 12.5 is preferable, 12.8 is preferable, 13 is preferable, 13.3 is preferable, 13.5 is preferable, 13.8 is preferable, 14 is preferable, 14 3 is preferable, 14.5 is preferable, 14.8 is preferable, 15 is preferable, 15.3 is preferable, 15.5 is preferable, 15.8 is preferable, 16 is preferable, 16.3 is preferable, 16 5 is preferable, 16.8 is preferable, 17 is preferable, 17.3 is preferable, 17.5 is preferable, 17.8 is preferable, and 18 is preferable, and the upper limit thereof is 25 is preferable, 24.5 is preferable, 24 is preferable, 23.5 is preferable, 23 is preferable, 22.8 is preferable, 22.5 is preferable, 22.3 is preferable, 22 is preferable, 21.8 is 21.5 is preferable, 21.3 is preferable, 21 is preferable, 20.8 is preferable, 20.5 is preferable, 20.3 is preferable, 20 is preferable, 19.8 is preferable, and 19.5 is 19.3 is preferable, 19 is preferable, 18.8 is preferable, 18.5 is preferable, 18.3 is preferable, 18 is preferable, 17.8 is preferable, 17.5 is preferable, 17.3 is Preferably, 17 is preferable. When importance is given to reducing power consumption, it is effective to reduce the amount of light from the backlight, and it is preferable to improve the light transmittance of the liquid crystal display element. For that purpose, the value of K _AVG should be set lower. preferable. When emphasis is placed on improvement of response speed, it is preferable to set the value of K _AVG higher.

  The composition of the present invention may contain a polymerizable compound in order to produce a liquid crystal display device such as PS mode, in-plane type PSA mode or in-plane type PSVA mode. Examples of the polymerizable compound that can be used include photopolymerizable monomers whose polymerization proceeds by energy rays such as light, and the like, and a structure having a liquid crystal skeleton in which a plurality of six-membered rings such as biphenyl derivative and terphenyl derivative are linked. A polymerizable compound etc. are mentioned. More specifically, general formula (XX)

( ^Wherein , each of X ²⁰¹ and X ²⁰² independently represents a hydrogen atom or a methyl group,
Sp ²⁰¹ and Sp ²⁰² each independently represent a single bond, an alkylene group having 1 to 8 carbon atoms, or -O- (CH ₂ ) _s- (wherein, s represents an integer of 2 to 7, and an oxygen atom is Preferably bonded to an aromatic ring),
Z ²⁰¹ is _{-OCH 2 -, - CH 2 O} -, - COO -, - OCO -, - CF 2 O -, - OCF 2 -, - CH 2 CH 2 -, - CF 2 CF 2 -, - CH = CH-COO -, - CH = CH-OCO -, - COO-CH = CH -, - OCO-CH = CH -, - COO-CH 2 CH 2 -, - OCO-CH 2 CH 2 -, - CH 2 CH ₂ -COO-, -CH ₂ CH ₂ -OCO-, -COO-CH _2- , -OCO-CH _2- , -CH ₂ -COO-, -CH ₂ -OCO-, -CY ¹ = CY ^2- (Wherein, Y ¹ and Y ² each independently represent a fluorine atom or a hydrogen atom), -C≡C- or a single bond,
M ²⁰¹ represents a 1,4-phenylene group, a trans-1,4-cyclohexylene group or a single bond, and in all the 1,4-phenylene groups in the formula, any hydrogen atom is a fluorine atom, and the carbon number is 1 to It may be substituted by an alkyl group of 3 and / or an alkoxy group having 1 to 2 carbon atoms. The bifunctional monomer represented by is preferable.

X ²⁰¹ and X ²⁰² are all diacrylate derivatives represents a hydrogen atom, both preferably none of dimethacrylate derivatives having a methyl group, preferred compounds where one represents the other is a methyl group represents a hydrogen atom. As for the polymerization rate of these compounds, the diacrylate derivative is the fastest, the dimethacrylate derivative is the slow, and the asymmetrical compound is the middle thereof, and a more preferable embodiment can be used depending on its use. In the PSA display element, dimethacrylate derivatives are particularly preferred.

Sp ²⁰¹ and Sp ²⁰² each independently represent a single bond, an alkylene group having 1 to 8 carbon atoms, or -O- (CH ₂ ) _s- , but in a PSA display element, at least one is a single bond. And the embodiment in which one is a single bond and the other is an alkylene group having 1 to 8 carbon atoms or -O- (CH ₂ ) _s- is preferable. In this case, an alkyl group of 1 to 4 is preferable, and s is preferably 1 to 4.

Z ²⁰¹ _{is, -OCH 2 -, - CH 2} O -, - COO -, - OCO -, - CF 2 O -, - OCF 2 -, - CH 2 CH 2 -, - CF 2 CF 2 - or a single bond Is preferred, -COO-, -OCO- or a single bond is more preferred, and a single bond is particularly preferred.

M ²⁰¹ represents a 1,4-phenylene group in which any hydrogen atom may be substituted by a fluorine atom, a trans-1,4-cyclohexylene group or a single bond, but a 1,4-phenylene group or a single bond is preferable. When C represents a ring structure other than a single bond, Z ²⁰¹ is also preferably a linking group other than a single bond, and when M ²⁰¹ is a single bond, Z ²⁰¹ is preferably a single bond.

From these points, in General Formula (XX), the ring structure between Sp ²⁰¹ and Sp ²⁰² is preferably the structure specifically described below.

In the general formula (XX), in the case where M ²⁰¹ represents a single bond and the ring structure is formed by two rings, it is preferable to represent the following formula (XXa-1) to the formula (XXa-7), It is more preferable to represent Formula (XXa-1) to Formula (XXa-3) and Formula (XXa-6) to Formula (XXa-7), and Formula (XXa-1), Formula (XXa-2) or Formula (XXa) It is particularly preferred to represent -6).

(Wherein both ends are bound to Sp ²⁰¹ or Sp ²⁰² )
The polymerizable compound containing such a skeleton has the optimum alignment control power after polymerization for the PSA type liquid crystal display element, and a good alignment state is obtained, so that display unevenness is suppressed or does not occur at all.

  From the above, as the polymerizable monomer, general formulas (XX-1) to (XX-4) are particularly preferable, and among these, general formula (XX-2) is the most preferable.

(Wherein, benzene may be substituted by a fluorine atom, an alkyl group of 1 to 3 carbon atoms and / or an alkoxy group of 1 to 2 carbon atoms, and Sp ²⁰ represents an alkylene group of 2 to 5 carbon atoms .)
When a monomer is added to the composition of the present invention, although polymerization proceeds even in the absence of a polymerization initiator, a polymerization initiator may be contained to accelerate the polymerization. Examples of the polymerization initiator include benzoin ethers, benzophenones, acetophenones, benzyl ketals, and acyl phosphine oxides.

  The composition in the present invention can further contain a compound represented by General Formula (Q).

(Wherein, R ^Q represents a linear or branched alkyl group having 1 to 22 carbon atoms, and one or more CH ₂ groups in the alkyl group are not directly adjacent to an oxygen atom) a, -O -, - CH = CH -, - CO -, - OCO -, - COO -, - C≡C -, - CF 2 O -, - OCF 2 - may be substituted with, in ^{R Q} The hydrogen atom may be substituted with 4-hydroxy-3,5-di-t-butylphenyl group, and M ^Q is a trans-1,4-cyclohexylene group, a 1,4-phenylene group or a single bond However, one or two non-adjacent —CH ₂ — in the trans-1,4-cyclohexylene group may be substituted by —O—.
R ^Q represents a linear or branched alkyl group having 1 to 22 carbon atoms, and one or more CH ₂ groups in the alkyl group are not -O, so that oxygen atoms are not directly adjacent to each other. -, -CH = CH-, -CO-, -OCO-, -COO-, -C≡C-, -CF ₂ O- or -OCF _2- , which may be substituted, but having 1 to 10 carbon atoms A linear alkyl group, a linear alkoxy group, a linear alkyl group in which one CH ₂ group is substituted by -OCO- or -COO-, a branched alkyl group, a branched alkoxy group, one CH ₂ group is -OCO- Or a branched alkyl group substituted by -COO-, and is preferably a linear alkyl group having 1 to 20 carbon atoms, a linear alkyl group wherein one CH ₂ group is substituted by -OCO- or -COO-, branched Chain alkyl group, branched alkoxy group, one CH ₂ group Further preferred is a branched alkyl group substituted with -OCO- or -COO-. M ^Q represents a trans-1,4-cyclohexylene group, a 1,4-phenylene group or a single bond, preferably a trans-1,4-cyclohexylene group or a 1,4-phenylene group.

  More specifically, compounds represented by General Formula (Q-a) to General Formula (Q-d) below are preferable as the compounds represented by General Formula (Q).

In the formula, R ^Q1 is preferably a linear alkyl group having 1 to 10 carbon atoms or a branched alkyl group, R ^Q2 is preferably a linear alkyl group having 1 to 20 carbon atoms or a branched alkyl group, and R ^Q3 is A linear alkyl group having 1 to 8 carbon atoms, a branched alkyl group, a linear alkoxy group or a branched alkoxy group is preferable, and L ^Q is preferably a linear alkylene group having 1 to 8 carbon atoms or a branched alkylene group . Among the compounds represented by general formula (Q-a) to general formula (Q-d), the compounds represented by general formula (Q-c) and general formula (Q-d) are more preferable.

  In the composition of the present invention, it is preferable to contain one or two types of compounds represented by general formula (Q), more preferably to contain one to five types, and the content thereof is from 0.001 to It is preferably 1%, more preferably 0.001 to 0.1%, and particularly preferably 0.001 to 0.05%.

  More specifically, compounds represented by the following (III-1) to (III-38) are preferable as the antioxidant or the light stabilizer which can be used in the present invention.

(Wherein, n represents an integer of 0 to 20)
In the composition of the present invention, it is preferable to contain one or two or more compounds represented by general formula (Q) or compounds selected from general formulas (III-1) to (III-38), one type It is further preferable to contain five types, and the content is preferably 0.001 to 1%, more preferably 0.001 to 0.1%, and particularly preferably 0.001 to 0.05%.
Generally, various parameters calculated from physical property values of the liquid crystal composition are used as a method of expressing the characteristics of the liquid crystal display element. They include γ ₁ / K ₃₃ which controls the response speed, K ₁₁ / K ₃₃ which controls the steepness of the electro-optical effect, and | K ₃₃ / Δε | which controls the drive voltage. Etc. The liquid crystal composition of the present invention is a combination of high-speed response, low drive voltage, good low temperature storage stability, wide viewing angle and high transmittance. Therefore, the parameter γ ₁ / K ₃₃ which governs the response speed is 10. 0 mPa · s · pN ⁻¹ or less is preferable, 9.8 mPa · s · pN ⁻¹ or less is preferable, 9.5 mPa · s · pN ⁻¹ or less is preferable, and 9.2 mPa · s · pN ⁻¹ or less is preferable, 9.0 mPa · s · pN ⁻¹ or less is particularly preferable. 1.11 or less is preferable, 1.15 or less is preferable, 1.10 or less is preferable, 1.07 or less is preferable, and K ₁₁ / K _33, which is a parameter that governs the steepness of the electro-optical effect, is preferably 1.05 or less Is preferred, and 1.03 or less is particularly preferred. The parameter which governs the driving voltage, | K ₃₃ / Δε |, is preferably 6.0 pN or less, preferably 5.7 pN or less, preferably 5.5 pN or less, preferably 5.3 pN or less, particularly preferably 5.1 pN or less .

  The composition containing the polymerizable compound of the present invention is imparted with liquid crystal alignment ability by polymerizing the polymerizable compound contained therein by ultraviolet irradiation, and the transmitted light quantity of light is controlled using birefringence of the composition Used in liquid crystal display devices.

  The liquid crystal display device using the composition of the present invention is useful in achieving both high-speed response and suppression of display defects, and is particularly useful for liquid crystal display devices for driving an active matrix. VA mode, PSVA mode, PSA The present invention can be applied to liquid crystal display elements for mode, IPS mode or ECB mode.

  Moreover, in the manufacturing process of the liquid crystal display element by the ODF method, it is necessary to drop the optimal liquid crystal injection amount according to the size of the liquid crystal display element, but the liquid crystal composition of the present invention is, for example, Since the liquid crystal can be stably dropped over a long time with little influence on rapid pressure change and impact in the device, the yield of the liquid crystal display element can be kept high. In particular, small liquid crystal display devices frequently used in recent smartphones are difficult to control the deviation from the optimum value within a certain range itself because the optimum liquid crystal injection amount is small, but the liquid crystal composition of the present invention By using a material, it is possible to realize a stable liquid crystal material discharge amount even in a small liquid crystal display element.

  The present invention will be described in more detail by way of examples, but the present invention is not limited to these examples. Moreover, "%" in the composition of the following example and a comparative example means "mass%."

  The characteristics measured in the examples are as follows.

T _ni : Nematic phase-isotropic liquid phase transition temperature (° C.)
Δn: refractive index anisotropy at 293 K Δε: dielectric anisotropy at 293 K γ ₁ : rotational viscosity at 293 K (mPa · s)
Elastic constant of spread (pN) at K ₁₁ : 293 K
K ₃₃ : elastic constant of bending at 293 K (pN)
In the Examples, the following abbreviations are used for the descriptions of compounds.
<Ring structure>

<Side chain structure>

(However, n in the table is a natural number.)
<Connected structure>

(However, n in the table is a natural number.)
<Examples 1 to 6>
As an example, LC-1 (Example 1), LC-2 (Example 2), LC-3 (Example 3), LC-4 (Example 4), LC-5 (Example 5) and LC The liquid crystal composition of No.-6 (Example 6) was prepared, and its physical property value was measured. The composition of the liquid crystal composition and the results of physical properties are shown below.

LC-1 (Example 1), LC-2 (Example 2), LC-3 (Example 3), LC-4 (Example 4), LC-5 (Example 5) and LC-6 (Implementation In Example 6), the parameter γ ₁ / K ₃₃ which controls the response speed is sufficiently small, and the parameter K ₁₁ / K ₃₃ which controls the steepness of the electro-optical effect is sufficiently small, which controls the drive voltage. It turned out that it is a liquid crystal composition whose parameter | K ₃₃ / Δε | is sufficiently low. Also, it was found that the wavelength dispersion of Δn was sufficiently small.

  Next, a vertical alignment (VA) liquid crystal display device is fabricated by injecting these liquid crystal compositions into a cell with ITO coated with a polyimide alignment film inducing homeotropic alignment with a cell gap of 3.0 μm by vacuum injection method. Obtained. It was confirmed that these VA liquid crystal display devices show high-speed response, low drive voltage, good low temperature storage stability, wide viewing angle, and high transmittance.

From the above, it has been found that the liquid crystal composition of the present invention is an excellent liquid crystal composition in which high-speed response, low drive voltage, good low temperature storage stability, wide viewing angle and high transmittance can be all compatible.
<Comparative Examples 1 to 7>
As comparative examples, LC-A (comparative example 1), LC-B (comparative example 2), LC-C (comparative example 3), LC-D (comparative example 4), LC-E (comparative example 5), LC The liquid crystal composition of -F (comparative example 6) and LC-G (comparative example 7) was prepared, and the physical-property value was measured. The composition of the liquid crystal composition and the physical properties thereof are shown below.

LC-A (comparative example 1), LC-B (comparative example 2), LC-C (comparative example 3), LC-D (comparative example 4), LC-E (comparative example 5), LC-F (comparative example Example 6) and LC-G (comparative example 7) have a parameter γ ₁ / K ₃₃ which controls the response speed in comparison with the example, and a parameter K ₁₁ / K which controls the steepness of the electro-optical effect. ₃₃ , it was found that one or more of the wavelength dispersion of | K ₃₃ / Δε |, which is a parameter governing the driving voltage, or Δn were inferior.

  Next, a vertical alignment (VA) liquid crystal display device is fabricated by injecting these liquid crystal compositions into a cell with ITO coated with a polyimide alignment film inducing homeotropic alignment with a cell gap of 3.0 μm by vacuum injection method. Obtained. The result of having evaluated the electro-optical characteristic of the obtained vertical alignment (VA) liquid crystal display element is shown below. In the following table, ○ indicates that the performance is equal to or higher than the liquid crystal display device obtained in the example, and x indicates that the liquid crystal display device obtained in the example is significantly inferior to the liquid crystal display device Represents what has been confirmed.

It is confirmed that these VA liquid crystal display devices are inferior in response speed, drive voltage, low temperature storage stability, viewing angle, transmittance or one or more of them to the display devices prepared in the examples. The
Examples 7 to 24
A polymerizable compound represented by XX-2, XX-2-F and XX-2-O1 is added as a polymerizable compound to the liquid crystal composition LC-1 to LC6 prepared, and a polymerizable compound-containing liquid crystal composition Objects MLC-1 to MLC-18 (Examples 7 to 24) were prepared.

The composition of the obtained polymerizable compound-containing liquid crystal composition is shown below.

A vertical alignment (VA) liquid crystal display element is injected by vacuum injection of the polymerizable compound-containing liquid crystal composition into a cell with ITO coated with a polyimide alignment film inducing homeotropic alignment with a cell gap of 3.0 μm. I got With respect to the obtained VA liquid crystal display element, while applying a rectangular wave of 10 V and 100 Hz, 10 J exposure was performed with a high pressure mercury lamp with an intensity of 100 mW / cm ^-2 (365 nm). Furthermore, a polymer stabilized vertical alignment (PSVA) liquid crystal display device was obtained by performing 100 J exposure in a state where the voltage is cut. It was confirmed that these PSVA liquid crystal display elements exhibited the same or more characteristics as the vertical alignment (VA) liquid crystal display elements prepared in Examples 1 to 6.

  From the above, it can be seen that the liquid crystal composition of the present invention is an excellent liquid crystal composition capable of achieving both high-speed response, low driving voltage, good low temperature storage stability, wide viewing angle and high transmittance even in PSVA display elements. The

Claims (4)

One or more compounds selected from the compounds represented by the general formula (i), one or more compounds selected from the compounds represented by the general formula (ii), a compound represented by the general formula (N-1d) Or one or more compounds selected from the compounds represented by (1), one or more compounds selected from the compounds represented by formula (N-1), and the compound represented by formula (L): Containing one or more compounds selected from dielectric neutral compounds,
The total content of the compound represented by General Formula (i) to the total composition is 3% or more, and the total content of the compound represented by General Formula (ii) to the total composition is 3% or more And the sum of the compound represented by general formula (i) to the total amount of the compound represented by general formula (i), the compound represented by general formula (ii) and the compound represented by general formula (L) A liquid crystal composition having a negative dielectric anisotropy, the amount of which is 20% or more.

(Wherein, R ⁱ¹ and R ⁱⁱ¹ each independently represent an alkyl group having 1 to 5 carbon atoms, and R ⁱ² and R ⁱⁱ² each independently represent a methyl group or a methoxy group,
R ^Nd11 , R ^Nd12 , R ^N11 , R ^N12 , R ^L1 and R ^L2 each independently represent an alkyl group having 1 to 8 carbon atoms, and one or two or more non-adjacent ones in the alkyl group -CH ₂ -may be each independently substituted by -CH = CH-, -C≡C-, -O-, -CO-, -COO- or -OCO-,
n ^Nd11 represents 1, 2 or 3; n ^N11 and n ^N12 represent 0, 1, 2 or 3; n ^N11 + n ^N12 represents 1, 2 or 3; n ^L1 represents 0, 1, 2 or 3 Represents three,
A ^N11 , A ^N12 , A ^L1 , A ^L2 and A ^L3 are each independently (a) 1,4-cyclohexylene group (one -CH _2- present in this group or _two not adjacent to each other) The above -CH _2- may be replaced by -O-.) And (b) 1,4-phenylene group (one -CH = present in this group or two or more not adjacent to each other) -CH = may be replaced by -N =)
(C) Naphthalene-2,6-diyl group, 1,2,3,4-tetrahydronaphthalene-2,6-diyl group or decahydronaphthalene-2,6-diyl group (naphthalene-2,6-diyl group or One —CH = or two or more non-adjacent —CH = present in the 1,2,3,4-tetrahydronaphthalene-2,6-diyl group may be replaced by —N =. )
And the group (a), the group (b) and the group (c) may be each independently substituted with a cyano group, a fluorine atom or a chlorine atom,
^{Z N11,} Z N12, Z ^L1 and ^{Z L2} each independently represent a single _{bond, -CH 2 CH 2 -, -} (CH 2) 4 -, - OCH 2 -, - CH 2 O -, - COO -, - OCO-, -OCF _2- , -CF ₂ O-, -CH = N-N = N-CH-, -CH = CH-, -CF = CF- or -C≡C-
When there are a plurality of A ^N11 , A ^N12 , A ^L1 , A ^L2 and / or A ^L3 , they may be the same or different, and Z ^N11 , Z ^N12 , Z ^L1 and / or Z ^L2 are When two or more of them are present, they may be the same or different, but the compounds represented by the general formula (N-1) have the general formula except for the compounds represented by the general formula (N-1d) The compound represented by (L) excludes the compounds represented by general formula (i), general formula (ii), general formula (N-1d) and general formula (N-1). )   The liquid crystal composition with negative dielectric anisotropy according to claim 1, further comprising a polymerizable compound.   A liquid crystal display device using the composition according to claim 1 or 2.   A VA type liquid crystal display device using the liquid crystal composition according to claim 1 or 2.