JPWO2017022522A1 - Coal-fired power generation facility - Google Patents

Coal-fired power generation facility Download PDF

Info

Publication number
JPWO2017022522A1
JPWO2017022522A1 JP2017505666A JP2017505666A JPWO2017022522A1 JP WO2017022522 A1 JPWO2017022522 A1 JP WO2017022522A1 JP 2017505666 A JP2017505666 A JP 2017505666A JP 2017505666 A JP2017505666 A JP 2017505666A JP WO2017022522 A1 JPWO2017022522 A1 JP WO2017022522A1
Authority
JP
Japan
Prior art keywords
coal
denitration
exhaust gas
discharge
pulverized coal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2017505666A
Other languages
Japanese (ja)
Other versions
JP6233545B2 (en
Inventor
敏和 吉河
敏和 吉河
健治 引野
健治 引野
啓一郎 盛田
啓一郎 盛田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chugoku Electric Power Co Inc
Original Assignee
Chugoku Electric Power Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chugoku Electric Power Co Inc filed Critical Chugoku Electric Power Co Inc
Publication of JPWO2017022522A1 publication Critical patent/JPWO2017022522A1/en
Application granted granted Critical
Publication of JP6233545B2 publication Critical patent/JP6233545B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/10Capture or disposal of greenhouse gases of nitrous oxide (N2O)

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

微小な粒径の堆積物が脱硝触媒の表面を被覆することを防ぐことで脱硝触媒の劣化を抑制できる石炭火力発電設備を提供すること。石炭火力発電設備1は、石炭を粉砕して微粉炭を製造する微粉炭機30と、微粉炭機30において製造された微粉炭を燃焼させる燃焼ボイラ40と、燃焼ボイラ40の下流側に配置され燃焼ボイラ40において微粉炭が燃焼されて発生した排ガス中に含まれる窒素酸化物を除去する脱硝装置60と、脱硝装置60の上流側に配置され排ガスに含まれる石炭灰を正極又は負極に帯電させる放電装置10と、脱硝装置60を石炭灰と同じ極性に帯電させる荷電装置15と、を備える。To provide a coal-fired power generation facility capable of suppressing deterioration of a denitration catalyst by preventing deposits having a small particle size from covering the surface of the denitration catalyst. The coal-fired power generation facility 1 is disposed on the downstream side of the combustion boiler 40, a pulverized coal machine 30 that pulverizes coal to produce pulverized coal, a combustion boiler 40 that burns the pulverized coal produced in the pulverized coal machine 30, and the combustion boiler 40. A denitration device 60 that removes nitrogen oxides contained in the exhaust gas generated by the combustion of pulverized coal in the combustion boiler 40 and a coal ash that is disposed upstream of the denitration device 60 and contained in the exhaust gas is charged to the positive electrode or the negative electrode. Discharge device 10 and charging device 15 for charging denitration device 60 to the same polarity as coal ash are provided.

Description

本発明は、石炭火力発電設備に関する。より詳しくは、脱硝装置を構成する脱硝触媒の劣化を抑制できる石炭火力発電設備に関する。   The present invention relates to a coal-fired power generation facility. More specifically, the present invention relates to a coal-fired power generation facility that can suppress deterioration of a denitration catalyst that constitutes a denitration apparatus.

石炭火力発電所では、石炭の燃焼に伴い窒素酸化物が発生するが、大気汚染防止法等により、窒素酸化物の排出は一定水準以下に抑えることが必要となっている。そこで発電所では、窒素酸化物を還元分解するために脱硝装置を設置している。この脱硝装置には、五酸化バナジウム等の活性成分を含む脱硝触媒が配置されており、ここにアンモニアを共存させることで、高温下の還元反応により脱硝を実現している。   At coal-fired power plants, nitrogen oxides are generated as coal is burned, but it is necessary to keep nitrogen oxide emissions below a certain level by the Air Pollution Control Law and other standards. Therefore, denitration equipment is installed at power plants to reduce and decompose nitrogen oxides. In this denitration apparatus, a denitration catalyst containing an active component such as vanadium pentoxide is disposed, and denitration is realized by a reduction reaction at a high temperature by coexisting ammonia therein.

この脱硝触媒は、一般に300℃〜400℃の高温雰囲気下で効率的に作動するため、ボイラにおいて石炭を燃焼させた直後の煤塵が非常に多く含まれた排ガスを脱硝させる必要がある。脱硝装置の性能を維持するために、活性が低下した触媒は、新品の触媒に取替えたり、再生したりする必要がある。   Since this denitration catalyst generally operates efficiently in a high temperature atmosphere of 300 ° C. to 400 ° C., it is necessary to denitrate exhaust gas containing a large amount of soot immediately after burning coal in a boiler. In order to maintain the performance of the denitration apparatus, it is necessary to replace or regenerate a catalyst whose activity has decreased with a new catalyst.

例えば、下記の特許文献1には、脱硝触媒が複数段充填された排煙脱硝装置の脱硝触媒の交換方法であって、最上流側に位置する第1段目の脱硝触媒を取出す触媒取出し工程と、第2段目以降の全ての脱硝触媒を順次、1段上流側に移動させる触媒移動工程と、触媒移動工程により移動して空となった最下流段に新たな脱硝触媒を補充する触媒補充工程と、を含む脱硝触媒の交換方法が開示されている。   For example, the following Patent Document 1 discloses a method for replacing a denitration catalyst of a flue gas denitration apparatus filled with a plurality of stages of denitration catalysts, and a catalyst removal step of taking out a first-stage denitration catalyst located on the most upstream side. And a catalyst moving step for sequentially moving all the denitration catalysts in the second and subsequent stages to the upstream side of the first stage, and a catalyst for replenishing a new denitration catalyst in the most downstream stage that has been emptied through the catalyst moving process And a replenishment step. A method for replacing the denitration catalyst is disclosed.

特開2013−052335号公報JP2013-052335A

しかしながら、そもそも、どのタイミングで脱硝触媒の取替えや再生を行うかについて、従来は知見がない。このため、現地での排ガス測定や実際に触媒サンプルを採取して触媒性能試験等を実施し、脱硝率の低下を測定しているのが現状である。石炭火力発電所の操業における脱硝触媒の機能の低下は長期間に亘って徐々に進行するものであるから、この劣化メカニズムを明らかにすることは、劣化予測や劣化抑制対策を講じる上で極めて重要である。   However, in the first place, there is no knowledge in the past regarding when to replace or regenerate the denitration catalyst. For this reason, the present situation is that the exhaust gas measurement at the site or the catalyst sample is actually collected and the catalyst performance test is carried out to measure the decrease in the denitration rate. Decreasing the function of denitration catalysts in the operation of coal-fired power plants gradually progresses over a long period of time, so it is extremely important to clarify this deterioration mechanism in order to predict deterioration and take measures to suppress deterioration. It is.

本発明者らは、脱硝触媒の劣化メカニズムにつき鋭意検討した結果、従来の石炭灰の粒径である数十μm以上百μm以下程度の範囲に比べて遥かに小さい粒径の堆積物が脱硝触媒の表面を被覆して被覆層を形成し、それによって、脱硝触媒と排ガスの接触が阻害され脱硝触媒の性能が低下していることを見出した。   As a result of intensive investigations on the deterioration mechanism of the denitration catalyst, the present inventors have found that a deposit having a particle size far smaller than the conventional coal ash particle size range of several tens to hundreds of μm or less is a denitration catalyst. It was found that the surface of the catalyst was coated to form a coating layer, whereby contact between the denitration catalyst and the exhaust gas was hindered and the performance of the denitration catalyst was lowered.

従って、本発明は、微小な粒径の堆積物が脱硝触媒の表面を被覆することを防ぐことで脱硝触媒の劣化を抑制できる石炭火力発電設備を提供することを目的とする。   Accordingly, an object of the present invention is to provide a coal-fired power generation facility capable of suppressing deterioration of a denitration catalyst by preventing deposits having a small particle diameter from covering the surface of the denitration catalyst.

本発明は、石炭を粉砕して微粉炭を製造する微粉炭機と、前記微粉炭機において製造された微粉炭を燃焼させる燃焼ボイラと、前記燃焼ボイラの下流側に配置され該燃焼ボイラにおいて微粉炭が燃焼されて発生した排ガス中に含まれる窒素酸化物を除去する脱硝装置と、前記脱硝装置の上流側に配置され排ガスに含まれる石炭灰を正極又は負極に帯電させる放電装置と、前記脱硝装置を石炭灰と同じ極性に帯電させる荷電装置と、を備える石炭火力発電設備に関する。   The present invention includes a pulverized coal machine that pulverizes coal to produce pulverized coal, a combustion boiler that burns the pulverized coal produced in the pulverized coal machine, and a pulverized powder disposed in a downstream side of the combustion boiler. A denitration device that removes nitrogen oxides contained in the exhaust gas generated by combustion of charcoal, a discharge device that is disposed upstream of the denitration device and charges coal ash contained in the exhaust gas to a positive electrode or a negative electrode, and the denitration device The present invention relates to a coal-fired power generation facility including a charging device that charges the device with the same polarity as coal ash.

また、前記放電装置は、放電電極と、該放電電極に高電圧を印加する荷電部と、を備え、該放電電極からコロナ放電を発生させることで石炭灰を正極又は負極に帯電させることが好ましい。   The discharge device preferably includes a discharge electrode and a charging unit that applies a high voltage to the discharge electrode, and the corona discharge is generated from the discharge electrode to charge the coal ash to the positive electrode or the negative electrode. .

また、石炭火力発電設備は、前記脱硝装置の上流側に配置され該脱硝装置に導入される排ガスを整流する整流板を更に備え、前記放電装置は、前記放電電極が前記整流板により構成されることが好ましい。   The coal-fired power generation facility further includes a rectifying plate arranged on the upstream side of the denitration device and rectifying the exhaust gas introduced into the denitration device, and the discharge device includes the discharge electrode formed by the rectification plate. It is preferable.

また、前記脱硝装置は、導電性を有する筒状のケーシングと、前記ケーシングに収容される複数のハニカム触媒であって、長手方向に延びる複数の排ガス流通穴が形成された長尺状の複数のハニカム触媒と、短手方向に隣り合って配置される前記ハニカム触媒の間に配置され排ガスの流入を防ぐシール部材と、を備え、複数の前記ハニカム触媒は、導電性担体と、該導電性担体に担持される触媒物質と、を含んで構成され、前記シール部材は、導電性を有することが好ましい。   In addition, the denitration apparatus includes a cylindrical casing having conductivity, and a plurality of honeycomb catalysts accommodated in the casing, and a plurality of elongated plurality of exhaust gas circulation holes extending in a longitudinal direction. A honeycomb catalyst, and a sealing member disposed between the honeycomb catalysts disposed adjacent to each other in the lateral direction to prevent inflow of exhaust gas, wherein the plurality of honeycomb catalysts include a conductive carrier and the conductive carrier. It is preferable that the sealing member has conductivity.

本発明によれば、微小な粒径の堆積物が脱硝触媒の表面を被覆することを防ぐことで脱硝触媒の劣化を抑制できる石炭火力発電設備を提供できる。   ADVANTAGE OF THE INVENTION According to this invention, the coal thermal power generation equipment which can suppress deterioration of a denitration catalyst can be provided by preventing the deposit of a fine particle diameter from covering the surface of a denitration catalyst.

本発明の一実施形態に係る石炭火力発電設備の構成を示す図である。It is a figure which shows the structure of the coal thermal power generation equipment which concerns on one Embodiment of this invention. 図1に示す燃焼ボイラの付近を拡大して示す図である。It is a figure which expands and shows the vicinity of the combustion boiler shown in FIG. 図1に示す脱硝装置の付近を拡大して示す図である。It is a figure which expands and shows the vicinity of the denitration apparatus shown in FIG. 脱硝装置を構成する脱硝触媒層の構造を模式的に示す図である。It is a figure which shows typically the structure of the denitration catalyst layer which comprises a denitration apparatus.

以下、本発明の石炭火力発電設備の好ましい一実施形態について、図面を参照しながら説明する。
本実施形態の石炭火力発電設備1は、図1に示すように、石炭バンカ20と、給炭機25と、微粉炭機30と、燃焼ボイラ40と、燃焼ボイラ40の下流側に設けられた排気通路50と、この排気通路50に設けられた脱硝装置60、放電装置10、荷電装置15、空気予熱器70、電気集塵装置90、ガスヒータ(熱回収用)80、誘引通風機210、脱硫装置220、ガスヒータ(再加熱用)230、脱硫通風機240、及び煙突250と、を備える。
Hereinafter, a preferred embodiment of a coal-fired power generation facility of the present invention will be described with reference to the drawings.
As shown in FIG. 1, the coal-fired power generation facility 1 of the present embodiment is provided on the downstream side of the coal bunker 20, the coal feeder 25, the pulverized coal machine 30, the combustion boiler 40, and the combustion boiler 40. Exhaust passage 50, denitration device 60, discharge device 10, charging device 15, air preheater 70, electrostatic precipitator 90, gas heater (for heat recovery) 80, induction fan 210, desulfurization provided in exhaust passage 50 The apparatus 220, the gas heater (for reheating) 230, the desulfurization ventilator 240, and the chimney 250 are provided.

石炭バンカ20は、石炭サイロ(図示しない)から運炭設備によって供給された石炭を貯蔵する。給炭機25は、石炭バンカ20から供給された石炭を所定の供給スピードで微粉炭機30に供給する。
微粉炭機30は、給炭機25から供給された石炭を粉砕して微粉炭を製造する。微粉炭機30においては、石炭は、平均粒径60μm〜80μmに粉砕される。また、微粉炭の粒度分布は、150μm以上が10〜15%、75μm〜150μmが30〜40%、75μm未満が45〜60%程度となる。
微粉炭機30としては、ローラミル、チューブミル、ボールミル、ビータミル、インペラーミル等が用いられる。
The coal bunker 20 stores coal supplied from a coal silo (not shown) by a coal transportation facility. The coal feeder 25 supplies the coal supplied from the coal bunker 20 to the pulverized coal machine 30 at a predetermined supply speed.
The pulverized coal machine 30 pulverizes the coal supplied from the coal feeder 25 to produce pulverized coal. In the pulverized coal machine 30, the coal is pulverized to an average particle size of 60 μm to 80 μm. Moreover, the particle size distribution of pulverized coal is 10 to 15% for 150 μm or more, 30 to 40% for 75 μm to 150 μm, and about 45 to 60% for less than 75 μm.
As the pulverized coal machine 30, a roller mill, a tube mill, a ball mill, a beater mill, an impeller mill, or the like is used.

燃焼ボイラ40は、微粉炭機30から供給された微粉炭を、強制的に供給された空気と共に燃焼する。微粉炭を燃焼することによりクリンカアッシュ及びフライアッシュなどの石炭灰が生成されると共に、排ガスが発生する。
尚、クリンカアッシュとは、微粉炭を燃焼させた場合に発生する石炭灰のうち、燃焼ボイラ40の底部に落下した塊状の石炭灰をいう。また、フライアッシュとは、微粉炭を燃焼させた場合に発生する石炭灰のうち、燃焼ガス(排ガス)と共に吹き上げられて排気通路50側に流通する程度の粒径(粒径200μm程度以下)の球状の石炭灰をいう。
The combustion boiler 40 burns the pulverized coal supplied from the pulverized coal machine 30 together with the forcibly supplied air. By burning pulverized coal, coal ash such as clinker ash and fly ash is generated and exhaust gas is generated.
In addition, clinker ash means the massive coal ash which fell to the bottom part of the combustion boiler 40 among the coal ash generate | occur | produced when pulverized coal is burned. Fly ash has a particle size (particle size of about 200 μm or less) of coal ash generated when pulverized coal is burned and blown up with combustion gas (exhaust gas) and circulated to the exhaust passage 50 side. Spherical coal ash.

図2を参照して、燃焼ボイラ40について詳しく説明すると、図2において、燃焼ボイラ40は全体として略逆U字状をなしており、図中矢印に沿って排ガス(燃焼ガス)が逆U字状に移動した後、2次節炭器41eを通過後に、再度小さくU字状に反転する。   The combustion boiler 40 will be described in detail with reference to FIG. 2. In FIG. 2, the combustion boiler 40 has a substantially inverted U shape as a whole, and the exhaust gas (combustion gas) is inverted U-shaped along the arrow in the figure. After passing through the secondary economizer 41e, it is again reversed into a U-shape.

燃焼ボイラ40の下方には、燃焼ボイラ40の内部のバーナーゾーン41a’付近で微粉炭を燃焼するためのバーナ41aが配置されている。また、燃焼ボイラ40の内部のU字頂部付近には、第一の過熱器41bが配置されており、更にそこから第二の過熱器41cが続いて配置されている。更に、第二の過熱器41cの終端付近からは、1次節炭器41d、2次節炭器41eが2段階に設けられている。ここで、節炭器(ECOとも呼ばれる)は、排ガスの保有する熱を利用してボイラ給水を予熱するために設けられた伝熱面群である。   Below the combustion boiler 40, a burner 41 a for burning pulverized coal is disposed in the vicinity of the burner zone 41 a ′ inside the combustion boiler 40. Moreover, the 1st superheater 41b is arrange | positioned near the U-shaped top part inside the combustion boiler 40, and also the 2nd superheater 41c is arrange | positioned from there. Furthermore, from the vicinity of the terminal end of the second superheater 41c, a primary economizer 41d and a secondary economizer 41e are provided in two stages. Here, the economizer (also referred to as ECO) is a heat transfer surface group provided for preheating boiler feedwater using heat retained by exhaust gas.

以上の燃焼ボイラ40によれば、バーナーゾーン41a’において微粉炭が燃焼される。微粉炭の燃焼温度は、1300℃から1500℃に及び、燃焼によって生成される石炭灰は、矢印の方向に沿って上昇して排ガスと共に第一の過熱器41b、第二の過熱器41c、1次節炭器41d、及び2次節炭器41eを順次通過する。燃焼ガスは、ボイラ給水を予熱するために設けられた伝熱面群を通過することによって熱交換され、450℃〜500℃程度に温度が低下する。排ガスがバーナーゾーン41a’から節炭器付近まで到達するまでに要する時間は、おおむね5秒から10秒である。   According to the above combustion boiler 40, the pulverized coal is burned in the burner zone 41a '. The combustion temperature of the pulverized coal ranges from 1300 ° C. to 1500 ° C., and the coal ash generated by the combustion rises along the direction of the arrow and together with the exhaust gas, the first superheater 41b, the second superheater 41c, The next economizer 41d and the secondary economizer 41e are sequentially passed. The combustion gas is heat-exchanged by passing through a heat transfer surface group provided for preheating boiler feedwater, and the temperature is lowered to about 450 ° C to 500 ° C. The time required for the exhaust gas to reach the economizer from the burner zone 41a 'is approximately 5 to 10 seconds.

排気通路50は、燃焼ボイラ40の下流側に配置され、燃焼ボイラ40で発生した排ガス及び生成された石炭灰を流通させる。この排気通路50には、上述のように、脱硝装置60、放電装置10、荷電装置15、空気予熱器70、ガスヒータ(熱回収用)80、電気集塵装置90、誘引通風機210、脱硫装置220と、ガスヒータ(再加熱用)230、脱硫通風機240、及び煙突250が配置される。   The exhaust passage 50 is disposed on the downstream side of the combustion boiler 40 and distributes exhaust gas generated in the combustion boiler 40 and generated coal ash. In the exhaust passage 50, as described above, the denitration device 60, the discharge device 10, the charging device 15, the air preheater 70, the gas heater (for heat recovery) 80, the electric dust collector 90, the induction ventilator 210, the desulfurization device. 220, a gas heater (for reheating) 230, a desulfurization ventilator 240, and a chimney 250 are arranged.

脱硝装置60は、排ガス中の窒素酸化物を除去する。本実施形態では、脱硝装置60は、比較的高温(300℃〜400℃)の排ガス中に還元剤としてアンモニアガスを注入し、脱硝触媒との作用により排ガス中の窒素酸化物を無害な窒素と水蒸気に分解する、いわゆる乾式アンモニア接触還元法により排ガス中の窒素酸化物を除去する。   The denitration device 60 removes nitrogen oxides in the exhaust gas. In the present embodiment, the denitration device 60 injects ammonia gas as a reducing agent into the exhaust gas at a relatively high temperature (300 ° C. to 400 ° C.), and converts the nitrogen oxides in the exhaust gas into harmless nitrogen by the action of the denitration catalyst. Nitrogen oxides in the exhaust gas are removed by a so-called dry ammonia catalytic reduction method that decomposes into water vapor.

脱硝装置60は、図3に示すように、脱硝反応器61と、この脱硝反応器61の内部に配置される複数段の脱硝触媒層62,62,62と、脱硝触媒層62の上流側に配置される整流層63と、脱硝反応器61の入口付近に配置される整流板64と、脱硝反応器61の上流側に配置されるアンモニア注入部65と、を備える。   As shown in FIG. 3, the denitration apparatus 60 includes a denitration reactor 61, a plurality of stages of denitration catalyst layers 62, 62, 62 disposed inside the denitration reactor 61, and upstream of the denitration catalyst layer 62. A rectifying layer 63 to be disposed, a rectifying plate 64 disposed in the vicinity of the inlet of the denitration reactor 61, and an ammonia injection portion 65 disposed on the upstream side of the denitration reactor 61 are provided.

脱硝反応器61は、脱硝装置60における脱硝反応の場となる。
脱硝触媒層62は、脱硝反応器61の内部に、排ガスの流路に沿って所定間隔をあけて複数段(本実施形態では3段)配置される。
The denitration reactor 61 is a place for denitration reaction in the denitration apparatus 60.
The denitration catalyst layer 62 is disposed in the denitration reactor 61 in a plurality of stages (three stages in this embodiment) at predetermined intervals along the exhaust gas flow path.

脱硝触媒層62は、図4に示すように、脱硝触媒としての複数のハニカム触媒622を含んで構成される。より詳細には、脱硝触媒層62は、複数のケーシング621と、これら複数のケーシング621に収容される複数のハニカム触媒622と、シール部材623と、を備える。   As shown in FIG. 4, the denitration catalyst layer 62 includes a plurality of honeycomb catalysts 622 as denitration catalysts. More specifically, the denitration catalyst layer 62 includes a plurality of casings 621, a plurality of honeycomb catalysts 622 accommodated in the plurality of casings 621, and a seal member 623.

ケーシング621は、一端及び他端が開放された角筒状の金属部材により構成される。ケーシング621は、開放された一端及び他端が脱硝反応器61における排ガスの流路に向かい合うように、つまり、ケーシング621の内部を排ガスが流通するように配置される。また、複数のケーシング621は、脱硝反応器61における排ガスの流路を塞ぐように当接した状態で連結されて配置される。   The casing 621 is configured by a rectangular tube-shaped metal member having one end and the other end opened. The casing 621 is arranged so that one end and the other end opened face the exhaust gas flow path in the denitration reactor 61, that is, the exhaust gas flows through the inside of the casing 621. The plurality of casings 621 are connected and arranged so as to be in contact with each other so as to block the exhaust gas flow path in the denitration reactor 61.

ハニカム触媒622は、長手方向に延びる複数の排ガス流通穴624が形成された長尺状(直方体状)に形成される。複数のハニカム触媒622は、排ガス流通穴624の延びる方向が排ガスの流路に沿うように配置される。本実施形態では、複数のハニカム触媒622は、ケーシング621に収容された状態で脱硝反応器61の内部に配置される。
本実施形態では、ハニカム触媒622は、バナジウムやタングステン等の触媒物質を導電性担体に担持させた後、押出成形することで形成される。導電性担体は、酸化チタンや酸化ジルコニウム等のセラミック材料に金属繊維等の導電性繊維やカーボンブラック又は金属からなる導電性フィラーを混合することで構成できる。
The honeycomb catalyst 622 is formed in a long shape (a rectangular parallelepiped shape) in which a plurality of exhaust gas circulation holes 624 extending in the longitudinal direction are formed. The plurality of honeycomb catalysts 622 are arranged so that the direction in which the exhaust gas circulation holes 624 extend is along the flow path of the exhaust gas. In the present embodiment, the plurality of honeycomb catalysts 622 are disposed inside the denitration reactor 61 while being accommodated in the casing 621.
In the present embodiment, the honeycomb catalyst 622 is formed by extruding after supporting a catalytic material such as vanadium or tungsten on a conductive carrier. The conductive carrier can be constituted by mixing a conductive material such as a metal fiber, carbon black, or a metal with a ceramic material such as titanium oxide or zirconium oxide.

シール部材623は、短手方向に隣り合って配置されるハニカム触媒622の間に配置され、隣り合って配置されるハニカム触媒622の間の隙間に排ガスが流入することを防ぐ。本実施形態では、シール部材623は、導電性を有するシート状部材により構成され、ハニカム触媒622の長手方向の一端側及び他端側の所定の長さの部分(例えば、端部から150mm)に巻きつけられている。   The seal member 623 is disposed between the honeycomb catalysts 622 arranged adjacent to each other in the lateral direction, and prevents exhaust gas from flowing into the gap between the honeycomb catalysts 622 arranged adjacent to each other. In the present embodiment, the sealing member 623 is configured by a sheet-like member having conductivity, and is formed in a portion of a predetermined length (for example, 150 mm from the end portion) on one end side and the other end side in the longitudinal direction of the honeycomb catalyst 622. It is wrapped around.

シール部材623としては、アルミナやシリカを主成分とした無機繊維及びバインダに導電性繊維や導電性を有するフィラーを混合して構成したセラミックペーパを用いることができる。   As the seal member 623, ceramic paper configured by mixing inorganic fibers mainly composed of alumina or silica and a binder with conductive fibers or conductive fillers can be used.

以上の脱硝触媒層62において、ハニカム触媒622としては、例えば、150mm×150mm×860mmの直方体形状で目開き6mm×6mmの排ガス流通穴が400個(20×20)形成されたものが用いられる。また、ケーシング621としては、このハニカム触媒622を72本(縦6本×横12本)収容可能なものが用いられる。そして、一層の脱硝触媒層62には、このケーシング621が120〜150個用いられる。即ち、一層の脱硝触媒層62には、9000本から10000本のハニカム触媒622が設置される。   In the above-described denitration catalyst layer 62, for example, a honeycomb catalyst 622 having a rectangular parallelepiped shape of 150 mm × 150 mm × 860 mm and 400 exhaust gas circulation holes (20 × 20) having openings of 6 mm × 6 mm is used. Further, as the casing 621, a casing that can accommodate 72 honeycomb catalysts 622 (length 6 × width 12) is used. In addition, 120 to 150 casings 621 are used for one denitration catalyst layer 62. In other words, 9000 to 10,000 honeycomb catalysts 622 are installed in one denitration catalyst layer 62.

整流層63は、脱硝触媒層62の上流側に配置される。整流層63は、格子状に形成された複数の開口を有する金属部材等により構成され、脱硝反応器61における排ガスの流路を区画する。整流層63は、排気通路50を流通し脱硝反応器61に導入される排ガスを整流して脱硝触媒層62に均等に導く。   The rectifying layer 63 is disposed on the upstream side of the denitration catalyst layer 62. The rectifying layer 63 is composed of a metal member or the like having a plurality of openings formed in a lattice shape, and partitions the exhaust gas flow path in the denitration reactor 61. The rectifying layer 63 rectifies the exhaust gas introduced through the exhaust passage 50 and introduced into the denitration reactor 61, and uniformly guides it to the denitration catalyst layer 62.

整流板64は、脱硝反応器61の入口の近傍における整流層63よりも上流側に配置される。より具体的には、整流板64は、脱硝反応器61又は排気通路50の内壁における屈曲部分に配置され、内壁から内面側に突出する。整流板64は、排気通路50又は脱硝反応器61における屈曲部分における排ガスの流れを整える。   The rectifying plate 64 is disposed on the upstream side of the rectifying layer 63 in the vicinity of the inlet of the denitration reactor 61. More specifically, the rectifying plate 64 is disposed at a bent portion of the inner wall of the denitration reactor 61 or the exhaust passage 50 and protrudes from the inner wall to the inner surface side. The rectifying plate 64 adjusts the flow of exhaust gas at the bent portion of the exhaust passage 50 or the denitration reactor 61.

アンモニア注入部65は、脱硝反応器61の上流側に配置され、排気通路50にアンモニアを注入する。   The ammonia injection part 65 is arranged upstream of the denitration reactor 61 and injects ammonia into the exhaust passage 50.

放電装置10は、脱硝装置60の上流側に配置され、排ガス中に含まれる石炭灰を正極又は負極に帯電させる。具体的には、放電装置10は、排ガス中に含まれる石炭灰を、脱硝装置60(ハニカム触媒622)と同じ極性に帯電させる。この放電装置10は、放電電極12と、荷電部11と、を備える。放電電極12は、正極電極及び負極電極を備え、排気通路50又は脱硝反応器61の内面に配置される。本実施形態では、放電電極12は、整流板64により構成される。
荷電部11は、放電電極12(整流板64)に高電圧を印加する。
The discharge device 10 is disposed on the upstream side of the denitration device 60, and charges the coal ash contained in the exhaust gas to the positive electrode or the negative electrode. Specifically, the discharge device 10 charges the coal ash contained in the exhaust gas to the same polarity as the denitration device 60 (honeycomb catalyst 622). The discharge device 10 includes a discharge electrode 12 and a charging unit 11. The discharge electrode 12 includes a positive electrode and a negative electrode, and is disposed on the inner surface of the exhaust passage 50 or the denitration reactor 61. In the present embodiment, the discharge electrode 12 is constituted by a rectifying plate 64.
The charging unit 11 applies a high voltage to the discharge electrode 12 (rectifying plate 64).

以上の放電装置10によれば、荷電部11により放電電極12(整流板64)に高電圧を印加することで、放電電極12(整流板64)の正極電極又は負極電極からコロナ放電が発生する。放電電極12の正極電極からコロナ放電が発生する場合には、正極イオンが発生する。一方で、放電電極12の負極電極からコロナ放電が発生する場合には、負極イオンが発生する。
放電電極12(整流板64)の正極電極からコロナ放電が発生する場合には、脱硝装置60に導入される石炭灰は、正極に帯電される。一方で、放電電極12(整流板64)の負極電極からコロナ放電が発生する場合には、脱硝装置60に導入される石炭灰は、負極に帯電される。これにより、放電電極12(整流板64)を通過する石炭灰は、正極又は負極に帯電されて脱硝装置60(脱硝触媒層62)に導入される。
According to the above discharge device 10, corona discharge is generated from the positive electrode or the negative electrode of the discharge electrode 12 (rectifier plate 64) by applying a high voltage to the discharge electrode 12 (rectifier plate 64) by the charging unit 11. . When corona discharge is generated from the positive electrode of the discharge electrode 12, positive ions are generated. On the other hand, when corona discharge is generated from the negative electrode of the discharge electrode 12, negative ions are generated.
When corona discharge occurs from the positive electrode of the discharge electrode 12 (rectifying plate 64), the coal ash introduced into the denitration device 60 is charged to the positive electrode. On the other hand, when corona discharge is generated from the negative electrode of the discharge electrode 12 (rectifying plate 64), the coal ash introduced into the denitration device 60 is charged to the negative electrode. Thus, the coal ash passing through the discharge electrode 12 (rectifying plate 64) is charged to the positive electrode or the negative electrode and introduced into the denitration device 60 (denitration catalyst layer 62).

荷電装置15は、脱硝装置60に接続され、脱硝装置60を石炭灰と同じ極性に帯電させる。本実施形態では、荷電装置15は、脱硝触媒層62,62,62にそれぞれ接続され、脱硝触媒層62を石炭灰と同じ極性(正極又は負極)に帯電させる。ここで、本実施形態では、脱硝触媒層62を構成するケーシング621、ハニカム触媒622及びシール部材623は、いずれも導電性を有するように構成されている。これにより、脱硝触媒層62は、石炭灰と同じ極性(正極又は負極)に帯電される。   The charging device 15 is connected to the denitration device 60 and charges the denitration device 60 to the same polarity as the coal ash. In the present embodiment, the charging device 15 is connected to the denitration catalyst layers 62, 62, 62, respectively, and charges the denitration catalyst layer 62 to the same polarity (positive electrode or negative electrode) as the coal ash. Here, in the present embodiment, the casing 621, the honeycomb catalyst 622, and the seal member 623 constituting the denitration catalyst layer 62 are all configured to have conductivity. Thereby, the denitration catalyst layer 62 is charged to the same polarity (positive electrode or negative electrode) as the coal ash.

排ガス中に含まれる石炭灰は、負極に帯電しやすい(正極に帯電しにくい)。このような観点から、放電装置10は石炭灰を、荷電装置15は脱硝触媒層62を、それぞれ負極に帯電させることが好ましい。これにより、効率よく脱硝装置60(脱硝触媒層62)を石炭灰と同じ極性に帯電させることができる。
一方で、脱硝装置60(脱硝反応器61)の内部で脱硝触媒層62は、正極に帯電しやすい(負極に帯電しにくい)。このような観点から、放電装置10は石炭灰を、荷電装置15は脱硝触媒層62を、それぞれ正極に帯電させることが好ましい。これにより、効率よく脱硝装置60(脱硝触媒層62)を石炭灰と同じ極性に帯電させることができる。
Coal ash contained in the exhaust gas is easily charged on the negative electrode (not easily charged on the positive electrode). From such a viewpoint, it is preferable that the discharge device 10 charges the coal ash, and the charging device 15 charges the denitration catalyst layer 62 to the negative electrode. Thereby, the denitration apparatus 60 (denitration catalyst layer 62) can be efficiently charged to the same polarity as coal ash.
On the other hand, the denitration catalyst layer 62 in the denitration apparatus 60 (denitration reactor 61) is easily charged to the positive electrode (not easily charged to the negative electrode). From such a viewpoint, it is preferable that the discharge device 10 charges the coal ash, and the charging device 15 charges the denitration catalyst layer 62 to the positive electrode. Thereby, the denitration apparatus 60 (denitration catalyst layer 62) can be efficiently charged to the same polarity as coal ash.

以上の脱硝装置60、放電装置10及び荷電装置15によれば、まず、アンモニア注入部65において、排気通路50を流通する高温の排ガス(300℃〜400℃)にアンモニアが注入される。アンモニアが注入された排ガスは、整流板64及び整流層63により整流される。
ここで、整流板64を通過する石炭灰は、この整流板64から発生するコロナ放電により、正極又は負極に帯電される。そして、この正極又は負極に帯電された石炭灰が脱硝装置60(脱硝触媒層62)に導入される。
According to the above denitration device 60, discharge device 10, and charging device 15, first, ammonia is injected into the high-temperature exhaust gas (300 ° C. to 400 ° C.) flowing through the exhaust passage 50 in the ammonia injection unit 65. The exhaust gas into which ammonia has been injected is rectified by the rectifying plate 64 and the rectifying layer 63.
Here, the coal ash passing through the rectifying plate 64 is charged to the positive electrode or the negative electrode by corona discharge generated from the rectifying plate 64. Then, the coal ash charged on the positive electrode or the negative electrode is introduced into the denitration device 60 (denitration catalyst layer 62).

脱硝触媒層62においては、アンモニアを含む排ガスがハニカム触媒622の排ガス流通穴624を通過するときに、以下の化学反応式に従って、窒素酸化物とアンモニアとが反応し、無害な窒素と水蒸気に分解される。
4NO+4NH+O→4N+6H
NO+NO+2NH→2N+3H
In the denitration catalyst layer 62, when the exhaust gas containing ammonia passes through the exhaust gas circulation hole 624 of the honeycomb catalyst 622, nitrogen oxide and ammonia react according to the following chemical reaction formula, and decompose into harmless nitrogen and water vapor. Is done.
4NO + 4NH 3 + O 2 → 4N 2 + 6H 2 O
NO + NO 2 + 2NH 3 → 2N 2 + 3H 2 O

ところで、脱硝触媒は、使用により劣化し脱硝率が低下する。脱硝触媒の劣化の原因としては、シンタリング等の熱的劣化、触媒成分の被毒による化学的劣化、及び石炭灰が触媒表面を被覆することによる物理的劣化等が挙げられる。本発明者らは、今般、石炭灰の平均的な粒径である数十μm以上百μm以下程度の範囲に比べて遥かに小さい粒径(1μm以下、より詳細には数十nm程度)の石炭灰に起因する堆積物が脱硝触媒の表面を被覆して被覆層を形成し、それによって、脱硝触媒と排ガスの接触が阻害され脱硝触媒の性能が低下していることを見出した。このような微小な粒径の石炭灰は含有量が少ないため、これまで脱硝触媒の劣化の原因とは考えられていなかった。   By the way, a denitration catalyst deteriorates by use, and a denitration rate falls. Causes of deterioration of the denitration catalyst include thermal deterioration such as sintering, chemical deterioration due to poisoning of catalyst components, and physical deterioration due to the coal ash covering the catalyst surface. The present inventors now have a much smaller particle size (1 μm or less, more specifically about several tens of nm) compared to the average particle size of coal ash, which is about several tens μm to one hundred μm. It has been found that deposits resulting from coal ash cover the surface of the denitration catalyst to form a coating layer, thereby inhibiting the contact between the denitration catalyst and the exhaust gas and reducing the performance of the denitration catalyst. Since the coal ash having such a small particle size has a small content, it has not been considered as a cause of deterioration of the denitration catalyst.

ここで、本実施形態では、脱硝触媒層62を、荷電装置15によって正極又は負極に帯電させている。これにより、放電装置10により正極又は負極に帯電した石炭灰とハニカム触媒622とを同じ極性に帯電させられるため、石炭灰を含む排ガスがハニカム触媒622の排ガス流通穴624を通過するときに、石炭灰(特に、電気的な力が作用しやすい微小な石炭灰)がハニカム触媒622の表面に電気的に付着することを防げる。よって、ハニカム触媒622(脱硝触媒)の表面に、微小な石炭灰に起因する被覆層が形成されることを防げるので、ハニカム触媒の劣化を抑制できる。   Here, in this embodiment, the denitration catalyst layer 62 is charged to the positive electrode or the negative electrode by the charging device 15. Thereby, since the coal ash charged to the positive electrode or the negative electrode and the honeycomb catalyst 622 are charged to the same polarity by the discharge device 10, when the exhaust gas containing coal ash passes through the exhaust gas circulation hole 624 of the honeycomb catalyst 622, It is possible to prevent ash (particularly, fine coal ash on which electric force easily acts) from being electrically attached to the surface of the honeycomb catalyst 622. Therefore, since it is possible to prevent the coating layer due to the fine coal ash from being formed on the surface of the honeycomb catalyst 622 (denitration catalyst), deterioration of the honeycomb catalyst can be suppressed.

空気予熱器70は、排気通路50における脱硝装置60の下流側に配置される。空気予熱器70は、脱硝装置60を通過した排ガスと押込式通風機75から送り込まれる燃焼用空気とを熱交換させ、排ガスを冷却すると共に、燃焼用空気を加熱する。   The air preheater 70 is disposed downstream of the denitration device 60 in the exhaust passage 50. The air preheater 70 exchanges heat between the exhaust gas that has passed through the denitration device 60 and the combustion air sent from the push-in type ventilator 75 to cool the exhaust gas and heat the combustion air.

ガスヒータ80は、排気通路50における空気予熱器70の下流側に配置される。ガスヒータ80には、空気予熱器70において熱回収された排ガスが供給される。ガスヒータ80は、排ガスから更に熱回収する。   The gas heater 80 is disposed downstream of the air preheater 70 in the exhaust passage 50. The exhaust gas recovered by the air preheater 70 is supplied to the gas heater 80. The gas heater 80 further recovers heat from the exhaust gas.

電気集塵装置90は、排気通路50におけるガスヒータ80の下流側に配置される。電気集塵装置90には、ガスヒータ80において熱回収された排ガスが供給される。電気集塵装置90は、電極に電圧を印加することによって排ガス中の石炭灰(フライアッシュ)を収集する装置である。電気集塵装置90において捕集されるフライアッシュは、フライアッシュ回収装置120に回収される。   The electric dust collector 90 is disposed on the downstream side of the gas heater 80 in the exhaust passage 50. The exhaust gas recovered in the gas heater 80 is supplied to the electric dust collector 90. The electric dust collector 90 is a device that collects coal ash (fly ash) in exhaust gas by applying a voltage to electrodes. The fly ash collected by the electric dust collector 90 is collected by the fly ash collection device 120.

誘引通風機210は、排気通路50における電気集塵装置90の下流側に配置される。誘引通風機210は、電気集塵装置90においてフライアッシュが除去された排ガスを、一次側から取り込んで二次側に送り出す。   The induction ventilator 210 is disposed on the downstream side of the electric dust collector 90 in the exhaust passage 50. The induction ventilator 210 takes in the exhaust gas from which fly ash has been removed in the electrostatic precipitator 90 from the primary side and sends it to the secondary side.

脱硫装置220は、排気通路50における誘引通風機210の下流側に配置される。脱硫装置220には、誘引通風機210から送り出された排ガスが供給される。脱硫装置220は、排ガスに石灰石と水との混合液を吹き付けることにより、排ガスに含有されている硫黄酸化物を混合液に吸収させて脱硫石膏スラリーを生成させ、この脱硫石膏スラリーを脱水処理することで脱硫石膏を生成する。脱硫装置220において生成された脱硫石膏は、この装置に接続された脱硫石膏回収装置222に回収される。   The desulfurization device 220 is arranged on the downstream side of the induction fan 210 in the exhaust passage 50. The desulfurization apparatus 220 is supplied with exhaust gas sent from the induction fan 210. The desulfurization apparatus 220 sprays a mixed liquid of limestone and water on the exhaust gas, thereby absorbing the sulfur oxide contained in the exhaust gas into the mixed liquid to generate a desulfurized gypsum slurry, and dehydrating the desulfurized gypsum slurry. This produces desulfurized gypsum. The desulfurized gypsum generated in the desulfurization apparatus 220 is recovered by a desulfurization gypsum recovery apparatus 222 connected to this apparatus.

ガスヒータ230は、排気通路50における脱硫装置220の下流側に配置される。ガスヒータ230には、脱硫装置220において硫黄酸化物が除去された排ガスが供給される。ガスヒータ230は、排ガスを加熱する。ガスヒータ80及びガスヒータ230は、排気通路50における、空気予熱器70と電気集塵装置90との間を流通する排ガスと、脱硫装置220と脱硫通風機240との間を流通する排ガスと、の間で熱交換を行うガスヒータとして構成してもよい。   The gas heater 230 is arranged on the downstream side of the desulfurization device 220 in the exhaust passage 50. The gas heater 230 is supplied with exhaust gas from which sulfur oxides have been removed in the desulfurization apparatus 220. The gas heater 230 heats the exhaust gas. The gas heater 80 and the gas heater 230 are disposed between the exhaust gas flowing between the air preheater 70 and the electric dust collector 90 and the exhaust gas flowing between the desulfurization device 220 and the desulfurization ventilator 240 in the exhaust passage 50. It may be configured as a gas heater that performs heat exchange.

脱硫通風機240は、排気通路50におけるガスヒータ230の下流側に配置される。脱硫通風機240は、ガスヒータ230において加熱された排ガスを一次側から取り込んで二次側に送り出す。
煙突250は、排気通路50における脱硫通風機240の下流側に配置される。煙突250には、ガスヒータ230で加熱された排ガスが導入される。煙突250は、排ガスを排出する。
The desulfurization ventilator 240 is disposed downstream of the gas heater 230 in the exhaust passage 50. The desulfurization ventilator 240 takes in the exhaust gas heated in the gas heater 230 from the primary side and sends it to the secondary side.
The chimney 250 is arranged on the downstream side of the desulfurization ventilator 240 in the exhaust passage 50. Exhaust gas heated by the gas heater 230 is introduced into the chimney 250. The chimney 250 discharges exhaust gas.

以上説明した本実施形態の石炭火力発電設備1によれば、以下のような効果を奏する。   According to the coal-fired power generation facility 1 of the present embodiment described above, the following effects can be obtained.

(1)石炭火力発電設備1を、脱硝装置60の上流側に配置され排ガスに含まれる石炭灰を正極又は負極に帯電させる放電装置10と、脱硝装置60を石炭灰と同じ極性に帯電させる荷電装置と、を含んで構成した。これにより、脱硝装置60に導入される石炭灰と、脱硝装置60(ハニカム触媒622)と、を同じ極性に帯電させられるため、石炭灰を含む排ガスがハニカム触媒622の排ガス流通穴624を通過するときに、石炭灰(特に、電気的な力が作用しやすい微小な石炭灰)がハニカム触媒622の表面に電気的に付着することを防げる。よって、ハニカム触媒622の表面に、微小な石炭灰に起因する被覆層が形成されることを防げるので、ハニカム触媒622の劣化を抑制できる。   (1) Discharge device 10 for charging coal-fired power generation facility 1 upstream of denitration device 60 and charging coal ash contained in exhaust gas to the positive electrode or the negative electrode, and charging for charging denitration device 60 to the same polarity as coal ash And a device. Thereby, since the coal ash introduced into the denitration device 60 and the denitration device 60 (honeycomb catalyst 622) are charged with the same polarity, the exhaust gas containing coal ash passes through the exhaust gas circulation hole 624 of the honeycomb catalyst 622. Occasionally, coal ash (particularly, fine coal ash on which electric force is easily applied) can be prevented from being electrically attached to the surface of the honeycomb catalyst 622. Therefore, it is possible to prevent the coating layer due to the fine coal ash from being formed on the surface of the honeycomb catalyst 622, so that deterioration of the honeycomb catalyst 622 can be suppressed.

(2)放電装置10を、放電電極12と、この放電電極12に高電圧を印加する荷電部11と、を含んで構成し、放電電極12からコロナ放電を発生させることで石炭灰を正極又は負極に帯電させた。これにより、電気集塵装置90において用いられている技術を用いて容易に石炭灰を帯電させられる。   (2) The discharge device 10 includes the discharge electrode 12 and the charging unit 11 that applies a high voltage to the discharge electrode 12, and generates corona discharge from the discharge electrode 12 to generate coal ash as a positive electrode or The negative electrode was charged. Thereby, coal ash can be easily charged using the technique used in the electrostatic precipitator 90.

(3)放電装置10の放電電極12を整流板64により構成した。これにより、脱硝触媒層62に導入される排ガスの流れを整える部材を利用して排ガス中に含まれる石炭灰を帯電させられるので、排ガス中に含まれる石炭灰を効果的に帯電させられる。   (3) The discharge electrode 12 of the discharge device 10 is constituted by a rectifying plate 64. As a result, the coal ash contained in the exhaust gas can be charged using the member that adjusts the flow of the exhaust gas introduced into the denitration catalyst layer 62, so that the coal ash contained in the exhaust gas can be effectively charged.

(4)脱硝装置60を、ケーシング621と、ハニカム触媒622と、シール部材623と、を含んで構成し、これらケーシング621、ハニカム触媒622、及びシール部材623をいずれも導電性を有するように構成した。これにより、ハニカム触媒622を好適に帯電させられる。よって、ハニカム触媒622の表面に、微小な石炭灰に起因する被覆層が形成されることをより効果的に防げるので、ハニカム触媒622の劣化をより抑制できる。   (4) The denitration device 60 includes a casing 621, a honeycomb catalyst 622, and a seal member 623, and the casing 621, the honeycomb catalyst 622, and the seal member 623 are all configured to have conductivity. did. Thereby, the honeycomb catalyst 622 can be charged appropriately. Therefore, since it can prevent more effectively that the coating layer resulting from a fine coal ash is formed in the surface of the honeycomb catalyst 622, deterioration of the honeycomb catalyst 622 can be suppressed more.

以上、本発明の石炭火力発電設備1の好ましい一実施形態につき説明したが、本発明は、上述の実施形態に制限されるものではなく、適宜変更が可能である。
例えば、本実施形態では、脱硝触媒としてハニカム触媒を用いたが、これに限らない。即ち、脱硝触媒として、網状の基材の表面に触媒物質を塗布して構成した板状触媒を用いてもよい。
The preferred embodiment of the coal-fired power generation facility 1 of the present invention has been described above. However, the present invention is not limited to the above-described embodiment, and can be appropriately changed.
For example, in this embodiment, a honeycomb catalyst is used as the denitration catalyst, but the present invention is not limited to this. That is, as the denitration catalyst, a plate catalyst configured by applying a catalyst substance on the surface of a net-like substrate may be used.

また、本実施形態では、放電装置10の放電電極12を整流板64により構成したが、これに限らない。即ち、放電電極を、整流層により構成してもよい。また、放電電極を、整流板とは別に配置してもよい。   Moreover, in this embodiment, although the discharge electrode 12 of the discharge device 10 was comprised by the rectifying plate 64, it is not restricted to this. That is, the discharge electrode may be constituted by a rectifying layer. Moreover, you may arrange | position a discharge electrode separately from a baffle plate.

1 石炭火力発電設備
10 放電装置
11 荷電部
12 放電電極
15 荷電装置
30 微粉炭機
40 燃焼ボイラ
60 脱硝装置
64 整流板(放電電極)
621 ケーシング
622 ハニカム触媒
623 シール部材
DESCRIPTION OF SYMBOLS 1 Coal thermal power generation equipment 10 Discharge device 11 Charging part 12 Discharge electrode 15 Charging device 30 Pulverized coal machine 40 Combustion boiler 60 Denitration device 64 Rectification plate (discharge electrode)
621 Casing 622 Honeycomb catalyst 623 Seal member

Claims (4)

石炭を粉砕して微粉炭を製造する微粉炭機と、
前記微粉炭機において製造された微粉炭を燃焼させる燃焼ボイラと、
前記燃焼ボイラの下流側に配置され該燃焼ボイラにおいて微粉炭が燃焼されて発生した排ガス中に含まれる窒素酸化物を除去する脱硝装置と、
前記脱硝装置の上流側に配置され排ガスに含まれる石炭灰を正極又は負極に帯電させる放電装置と、
前記脱硝装置を石炭灰と同じ極性に帯電させる荷電装置と、を備える石炭火力発電設備。
A pulverized coal machine that pulverizes coal to produce pulverized coal;
A combustion boiler for burning the pulverized coal produced in the pulverized coal machine;
A denitration device that is disposed downstream of the combustion boiler and removes nitrogen oxides contained in the exhaust gas generated by burning pulverized coal in the combustion boiler;
A discharging device arranged on the upstream side of the denitration device and charging coal ash contained in the exhaust gas to the positive electrode or the negative electrode;
A coal-fired power generation facility comprising: a charging device that charges the denitration device to the same polarity as coal ash.
前記放電装置は、放電電極と、該放電電極に高電圧を印加する荷電部と、を備え、該放電電極からコロナ放電を発生させることで石炭灰を正極又は負極に帯電させる請求項1に記載の石炭火力発電設備。   The said discharge apparatus is provided with the discharge electrode and the charge part which applies a high voltage to this discharge electrode, The coal ash is charged to a positive electrode or a negative electrode by generating a corona discharge from this discharge electrode. Coal-fired power plant. 前記脱硝装置の上流側に配置され該脱硝装置に導入される排ガスを整流する整流板を更に備え、
前記放電装置は、前記放電電極が前記整流板により構成される請求項2に記載の石炭火力発電設備。
A rectifying plate arranged on the upstream side of the denitration device and rectifying the exhaust gas introduced into the denitration device;
The coal discharge power generation facility according to claim 2, wherein the discharge device is configured such that the discharge electrode is constituted by the rectifying plate.
前記脱硝装置は、
導電性を有する筒状のケーシングと、
前記ケーシングに収容される複数のハニカム触媒であって、長手方向に延びる複数の排ガス流通穴が形成された長尺状の複数のハニカム触媒と、
短手方向に隣り合って配置される前記ハニカム触媒の間に配置され排ガスの流入を防ぐシール部材と、を備え、
複数の前記ハニカム触媒は、導電性担体と、該導電性担体に担持される触媒物質と、を含んで構成され、
前記シール部材は、導電性を有する請求項1〜3のいずれかに記載の石炭火力発電設備。
The denitration device is
A cylindrical casing having conductivity;
A plurality of honeycomb catalysts accommodated in the casing, a plurality of elongated honeycomb catalysts in which a plurality of exhaust gas circulation holes extending in the longitudinal direction are formed;
A seal member disposed between the honeycomb catalysts disposed adjacent to each other in a short direction to prevent inflow of exhaust gas, and
The plurality of honeycomb catalysts are configured to include a conductive carrier and a catalyst substance supported on the conductive carrier,
The coal-fired power generation facility according to claim 1, wherein the seal member has conductivity.
JP2017505666A 2015-07-31 2016-07-22 Coal-fired power generation facility Expired - Fee Related JP6233545B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2015152882 2015-07-31
JP2015152882 2015-07-31
PCT/JP2016/071553 WO2017022522A1 (en) 2015-07-31 2016-07-22 Coal-fired power generation equipment

Publications (2)

Publication Number Publication Date
JPWO2017022522A1 true JPWO2017022522A1 (en) 2017-08-03
JP6233545B2 JP6233545B2 (en) 2017-11-22

Family

ID=57942885

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2017505666A Expired - Fee Related JP6233545B2 (en) 2015-07-31 2016-07-22 Coal-fired power generation facility

Country Status (2)

Country Link
JP (1) JP6233545B2 (en)
WO (1) WO2017022522A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7053393B2 (en) * 2018-07-13 2022-04-12 一般財団法人電力中央研究所 Denitration device and denitration method, exhaust gas treatment equipment and exhaust gas treatment method
JP7085431B2 (en) 2018-07-13 2022-06-16 三菱重工エンジニアリング株式会社 Catalytic reactor
KR102166597B1 (en) * 2018-11-26 2020-10-16 현대제철 주식회사 Apparatus for cleaning outgas of sintering process in the dry

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51109279A (en) * 1975-03-24 1976-09-28 Hitachi Ltd
JPH0450121U (en) * 1990-08-27 1992-04-28
JP2001153309A (en) * 1999-11-26 2001-06-08 Hitachi Ltd Pulverized coal boiler, its operating method, and method for remodeling pulverized coal boiler
JP2006257948A (en) * 2005-03-16 2006-09-28 Toyota Motor Corp Gas purifier
JP2006320818A (en) * 2005-05-18 2006-11-30 Toyota Motor Corp Pm purifying device and pm purifying method
JP2007107450A (en) * 2005-10-13 2007-04-26 Hino Motors Ltd Exhaust emission control device
JP2012067610A (en) * 2010-09-21 2012-04-05 Ngk Insulators Ltd Exhaust emission control device
JP2013504412A (en) * 2009-09-14 2013-02-07 エミテック ゲゼルシヤフト フユア エミツシオンス テクノロギー ミツト ベシユレンクテル ハフツング Exhaust gas treatment device having two honeycomb bodies for generating electric potential

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51109279A (en) * 1975-03-24 1976-09-28 Hitachi Ltd
JPH0450121U (en) * 1990-08-27 1992-04-28
JP2001153309A (en) * 1999-11-26 2001-06-08 Hitachi Ltd Pulverized coal boiler, its operating method, and method for remodeling pulverized coal boiler
JP2006257948A (en) * 2005-03-16 2006-09-28 Toyota Motor Corp Gas purifier
JP2006320818A (en) * 2005-05-18 2006-11-30 Toyota Motor Corp Pm purifying device and pm purifying method
JP2007107450A (en) * 2005-10-13 2007-04-26 Hino Motors Ltd Exhaust emission control device
JP2013504412A (en) * 2009-09-14 2013-02-07 エミテック ゲゼルシヤフト フユア エミツシオンス テクノロギー ミツト ベシユレンクテル ハフツング Exhaust gas treatment device having two honeycomb bodies for generating electric potential
JP2012067610A (en) * 2010-09-21 2012-04-05 Ngk Insulators Ltd Exhaust emission control device

Also Published As

Publication number Publication date
JP6233545B2 (en) 2017-11-22
WO2017022522A1 (en) 2017-02-09

Similar Documents

Publication Publication Date Title
WO2017022521A1 (en) Coal-fired power generation equipment
TWI449569B (en) Enhancement of conventional scr and sncr processes with ammonia destruction catalyst
KR20190024970A (en) Method and system for improving boiler efficiency
Zhou et al. Research progress on ammonium bisulfate formation and control in the process of selective catalytic reduction
JP6233545B2 (en) Coal-fired power generation facility
TW201231147A (en) Exhaust gas treatment method and apparatus
TW201118316A (en) System and method for protection of SCR catalyst
JP6586812B2 (en) Coal-fired power generation facility
WO2017022519A1 (en) Coal-fired power generation equipment
JP6848598B2 (en) How to reuse denitration catalyst
WO2017022520A1 (en) Method for inhibiting degradation of denitration device
JP6245405B2 (en) Denitration catalyst degradation evaluation method
JP6428964B1 (en) Denitration catalyst degradation evaluation method
JP2011125766A (en) Exhaust gas treatment apparatus
JP6504314B1 (en) NOx removal equipment
JP6206618B1 (en) Coal-fired power generation facility
JP2011112243A (en) Method of suppressing differential pressure for air preheater
JP6668819B2 (en) Coal-fired power plant
WO2020161874A1 (en) Combustion system
CN109331652A (en) One kind being based on ammonia process-SCR combined desulfurization and denitration system and method
WO2020161875A1 (en) Combustion system
JP2019013893A (en) Exhaust gas treatment method and exhaust gas treatment system
JP5063761B2 (en) Thermal power generation system
JP2002263440A (en) Flue gas treatment equipment for boiler using oil containing much sulfur-component as fuel
JP2015155078A (en) Mercury removal apparatus

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170308

A975 Report on accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A971005

Effective date: 20170407

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170530

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170721

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170801

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170913

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20170926

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20171009

R150 Certificate of patent or registration of utility model

Ref document number: 6233545

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees