JPWO2016136537A1 - Member, method for manufacturing the member, and electronic component including the member - Google Patents

Abstract

A member provided with a resin-based substrate obtained by injection molding using a general resin-containing material, not a resin-containing material containing a soluble filler or a substance serving as a catalyst nucleus, and a member provided with a conductive layer As obtained from a molded product of a resin-containing material, comprising a base material having a thin part having a thickness of 0.3 mm or less, and a conductive layer formed on the surface of the thin part. A member is provided. [Selection] Figure 3

Description

  The present invention relates to a member including a base material that is a molded product of a resin-containing material and a conductive layer provided on the base material, a method for manufacturing the member, and an electronic component including the member.

  A resin-containing material, which is a material containing a resin excellent in fluidity at the time of melting, such as a liquid crystal polymer and polyferrinylene sulfide, is a material suitable for manufacturing a small and complicated member by molding. In some cases, a conductive layer is provided on a base material (also referred to as a “resin base material” in this specification) made of a molded product of such a resin-containing material to impart conductivity to the member. .

  An electroless plating process is exemplified as one type of method for forming the conductive layer. In the case of forming a conductive layer by electroless plating treatment, various countermeasures have been studied in order to improve the adhesion between the electroless plating layer formed by electroless plating treatment and the resin-based substrate. .

  Most generally, as a resin-containing material that gives a resin-based substrate, a filler (also referred to as “soluble filler” in this specification) that can be dissolved by an etching solution containing chromic acid or an alkaline substance is contained in the resin. Such a resin-containing material is commercially available as a plating grade product. The plating-grade resin-containing material dissolves the filler when it comes into contact with the etching solution, resulting in irregularities on the surface. In the electroless plating process, the plating material is also formed in the recesses, so that the electroless plating is performed. An anchor effect is generated in the layer, and the adhesion to the resin-based substrate is improved.

  However, when the thickness of the portion where the conductive layer in the resin-based substrate is to be formed becomes thin, that is, becomes thin, the moldability of the resin-containing material may deteriorate due to the influence of the soluble filler. In addition, the soluble filler embedded in the thin molded product dissolves, and as a result, irregularities are formed. As a result, the mechanical strength of the thin molded product is lowered, and it may become unusable.

  As a method for improving the adhesion between an electroless plating layer and a resin-based substrate without using a soluble filler, Patent Document 1 discloses a method of forming a plating film on a polymer member, and includes a plating catalyst inside the surface. Providing a polymer member impregnated with a core metal substance, and contacting an electroless plating solution containing pressurized carbon dioxide and alcohol with the polymer member to form a plating film on the polymer member. A method for forming a plating film is described.

JP 2008-255390 A

In order to realize the method described in Patent Document 1, it is necessary to previously contain in the polymer member (resin-based substrate) a substance that becomes a catalyst core for plating deposition during the electroless plating process. Therefore, in the above method, the catalyst nuclei are dispersed in the resin base material by bringing pressurized carbon dioxide in which a substance capable of forming catalyst nuclei is dissolved into contact with the molten resin. For this reason, even if the part which wants to provide electroconductivity is a part of member, a catalyst nucleus is disperse | distributed to all the resin-type base materials.
Since the catalyst core contained in the resin-based substrate is generally a substance containing a rare element such as palladium, the above-described method of allowing such a material to exist even in a portion that is not originally required is an efficient use of resources. From the viewpoint of

  In addition, equipment for dissolving the above-mentioned substance capable of forming the catalyst nucleus in pressurized carbon dioxide, equipment for introducing pressurized carbon dioxide in which the substance capable of forming the catalyst nucleus is dissolved into the tip of the molten resin, etc. A large number of dedicated production facilities are required.

  Furthermore, in the method as disclosed in Patent Document 1, it is difficult to increase the adhesion between the electroless plating film and the molded product only by including the catalyst nucleus in the molded product of the resin-containing material, It is necessary to make the composition of the electroless plating solution different from the usual composition. Such a production method including a step that affects other steps is not preferable from the viewpoint of industrial production.

  The present invention does not require a resin-containing material containing a soluble filler or a catalyst core that may reduce the mechanical strength of a thin molded product, and a general resin-containing material can be used. It aims at providing the member provided with a conductive layer on the surface of the thin part in the base material which consists of a molding product of material.

  One aspect of the present invention provided to solve the above problems is obtained from a molded product of a resin-containing material, and includes a base material including a thin part having a thickness of 0.3 mm or less, and the thin part. And a conductive layer formed on the surface. When the thin part made of a molded product of a resin-containing material contains a soluble filler, when the soluble filler is dissolved by the etching solution, sufficient mechanical strength is maintained in the thin part having a thickness of 0.3 mm or less. It is difficult. On the other hand, the member which concerns on this invention can be equipped with a conductive layer on the surface of a thin part, without a base material (resin-type base material) containing a soluble filler and a catalyst nucleus substantially.

  In the said invention, it is preferable that at least one part of the skin layer of the said molded product located in the said thin part is removed. In this case, even when the member according to the present invention is heated to 200 ° C. or more, the problem that the surface portion on which the conductive layer is formed in the thin portion is less likely to occur.

  In the above invention, the resin-containing material may contain a liquid crystal polymer. The liquid crystal polymer is excellent in fluidity at the time of melting, is a resin suitable for molding a component having a minute and complicated shape, and can easily form a thin portion.

  The conductive layer preferably includes an electroless plating layer formed by electroless plating. In this case, if the manufacturing method described below is employed, a member having excellent adhesion between the electroless plating layer and the surface of the thin portion can be manufactured.

  Another aspect of the present invention is a method for producing a member provided with a conductive layer including an electroless plating layer formed by electroless plating on the surface of the thin portion, and the surface of the thin portion; An attaching step of attaching the compound (α) to the surface of the thin-walled portion, including contacting a liquid containing the compound (α) represented by the following general formula [I]; the compound (α) A fixing step of irradiating the surface of the thin-walled portion to which the material is adhered to fix the substance based on the compound (α) to the surface of the thin-walled portion; the surface of the thin-walled portion that has undergone the fixing step; An activation process for adhering catalyst nuclei; and a plating process for forming an electroless plating layer on the surface of the thin wall portion to which the catalyst nuclei have adhered.

Here, in the general formula [I], E is an arbitrary group. F is an OH group or an OH generating group. -Q is -N ₃ or _-NR 1 _{(R 2).} R ₁ and R ₂ of —NR ₁ (R ₂ ) are H, a hydrocarbon group having 1 to 24 carbon atoms, or —RSi (R ′) _n (OA) _{3 -n} (R is 1 carbon atom) A chain hydrocarbon group having ˜12, R ′ is a chain hydrocarbon group having 1 to 4 carbon atoms, A is H or a chain hydrocarbon group having 1 to 4 carbon atoms. N is an integer from 0 to 2). R ₁ and R ₂ may be the same or different.

  According to said manufacturing method, the substance based on a compound ((alpha)) can be fixed to the surface of a thin part. This substance becomes an acceptor of a substance capable of forming a catalyst nucleus, and can improve the adhesion between the electroless plating layer formed by the electroless plating process and the thin portion. Moreover, in said manufacturing method, it is not required to contact highly oxidized substances, such as chromic acid, to a thin part like the case where the conventional soluble filler is used. For this reason, the mechanical strength of the resin-containing material constituting the thin portion is unlikely to decrease.

  In the above invention, it is preferable that the thin-walled portion provided for the attaching step is a skin layer removing step of removing at least a part of the skin layer from the molded product located in the thin-walled portion. Since the skin layer may have a lower mechanical strength than other parts of the molded product, if the skin layer is appropriately removed, the member having the electroless plating layer formed on the thin part is about 200 ° C. Even when heated to a low temperature, defects such as plating swelling are less likely to occur in the thin wall portion.

  In the case where the resin-containing material contains a liquid crystal polymer, it is preferable that in the skin layer removing step, the surface of the molded product located in the thin portion is brought into contact with an alkaline liquid. The alkaline liquid has a function of appropriately removing the skin layer in the molded product of the resin-containing material containing the liquid crystal polymer. In addition, since the liquid crystal polymer is a hydrophobic material, the liquid containing the compound (α) may be difficult to wet with respect to the surface of the thin portion in the attaching step. Therefore, by bringing the surface of the molded product located in the thin wall portion into contact with an alkaline liquid in advance, it is possible to improve the wettability with respect to the surface of the thin wall portion of the liquid material containing the compound (α), As a result, the compound (α) tends to adhere to the surface of the thin portion.

  In the skin layer removing step, it is preferable that after the surface of the molded product located in the thin portion is brought into contact with an alkaline liquid, a surface modification treatment is performed on the surface in contact with the alkaline liquid There is also. By performing such surface modification treatment, the wettability to the surface of the thin portion of the liquid material containing the compound (α) is enhanced while suppressing the surface roughness of the surface of the thin portion from becoming excessively large. It is possible. Therefore, when the surface of the conductive layer formed on the surface of the thin portion is a sliding surface, it may be preferable to perform the surface modification treatment in the skin layer removal step. The surface modification treatment may include light irradiation with an excimer UV lamp.

  Another aspect of the present invention is an electronic component including the member according to the present invention. In such an electronic component, the surface of the conductive layer may be a sliding surface.

  According to the present invention, a member including a conductive layer having excellent adhesion on the surface of the thin portion can be obtained. Moreover, an electronic component including a member including a conductive layer on the surface of the thin portion is excellent in productivity.

It is an image which shows the result of having observed the member which plating swelling produced with the optical microscope. It is an image which shows the result of having made a cut into a part of plating swelling shown in Drawing 1, and observing the section of plating swelling with an electron microscope. It is a graph showing etching time and the surface roughness _{(Ra, Rz,} Rz _JIS) the relationship between. It is a graph showing the relationship between the etching time and the surface roughness _{(Ra, Rz JIS).} It is a graph which shows the relationship between etching thickness and peel strength.

  Hereinafter, a member, a manufacturing method thereof, and an electronic component socket including the above member according to an embodiment of the present invention will be described.

1. Member A member according to an embodiment of the present invention is obtained from a molded product of a resin-containing material, and includes a substrate (resin-based substrate) having a thin portion having a thickness of 0.3 mm or less, and a surface of the thin portion A conductive layer formed thereon.

  The thickness of the thin portion may be 0.2 mm or less, or 0.1 mm or less. As the thickness of the thin portion is reduced, it becomes difficult to perform means for improving the adhesion between the electroless plating layer and the thin portion by forming irregularities on the surface of the thin portion. If the member according to the embodiment of the present invention is manufactured by a manufacturing method as described later, it is not necessary to form irregularities on the surface of the thin portion, so that the thickness of the thin portion is reduced as described above. However, there is a low possibility that the mechanical properties of the thin-walled portion will deteriorate.

  The composition of the resin-containing material constituting the resin-based substrate is not limited as long as it is a material that can form a thin portion by molding (specific examples include injection molding). From the viewpoint of improving the moldability of the thin-walled portion, preferred specific examples of the resin material contained in the resin-containing material include liquid crystal polymer (LCP), polyferrinylene sulfide (PPS), and the like, such as polycarbonate (PC). An example of a resin-containing material may be a so-called engineering plastic containing a fluidity improver.

  The resin-containing material constituting the resin-based substrate does not substantially contain a soluble filler. Since the soluble filler is not substantially contained, unevenness due to dissolution / dropping off of the soluble filler is unlikely to occur in the thin portion of the resin-based substrate. Therefore, the mechanical strength of the thin portion is unlikely to decrease. When the member according to an embodiment of the present invention is a component of an electronic component as described later, for example, when the mechanical strength of the thin portion is reduced, the thin portion is reduced when the electronic component is manufactured or used. The possibility of deformation increases. Excessive deformation of the thin wall portion may cause malfunction or damage of the electronic component.

  The resin-containing material constituting the resin-based substrate may contain a filler (also referred to as “insoluble filler” in the present specification) that does not substantially dissolve in an etching solution containing chromic acid or an alkaline substance. Although the shape of the insoluble filler is not limited, it is preferable to have a needle-like shape or a scale-like shape in consideration of the thickness of the thin portion. In this case, the length of the short axis is larger than the thickness of the thin portion. It is preferable that it is sufficiently short. Specific examples of the length of the short axis include 30 μm or less, and preferable examples include 20 μm or less. The material of the insoluble filler is not limited. Examples of the material constituting the insoluble filler include inorganic substances such as silica, talc, kaolin, titania, alumina, and zirconia.

  As long as the conductive layer has conductivity, its composition and structure are not limited. The conductive layer may have a single layer structure or a stacked structure. When it has a laminated structure, the specific structure of the laminated structure is appropriately set according to the application. At least one layer may be conductive, and at least the surface may be required to be conductive.

  Examples of the material constituting the conductive layer include metal materials, inorganic materials, and organic materials. Specific examples of the metal material include metals and alloys containing elements such as gold, silver, copper, aluminum, nickel, and tungsten. The layer containing these materials may be manufactured by a wet process (electroplating, electroless plating, displacement plating, etc.), or may be manufactured by a dry process (evaporation, ion plating, sputtering, etc.). Specific examples of the inorganic material include graphite and indium tin oxide (ITO). Specific examples of the organic material include polypyrrole and polyacetylene.

  The conductive layer preferably includes an electroless plating layer formed by electroless plating. In electroless plating treatment, if a substance capable of forming catalyst nuclei appropriately exists on the surface of the object to be treated (thin wall portion), the conductive metal material (plating substance) can be easily treated (thin wall). Part) can be deposited in layers. The electroless plating layer thus obtained can have excellent conductivity. The material constituting the electroless plating layer is not limited. Usually, the electroless plating layer is composed of a conductive material containing one or more metal elements selected from the group consisting of nickel, cobalt, gold and copper. When the electroless plating layer is made of a material mainly composed of nickel, a substance containing palladium is usually disposed on the surface of the object to be processed as a material that serves as a catalyst core.

2. Manufacturing method of member The manufacturing method of the member which concerns on one Embodiment of said this invention is not limited. According to the manufacturing method described below, the member according to one embodiment of the present invention can be efficiently manufactured.

  The manufacturing method of the member concerning one embodiment of the present invention is provided with the adhesion process, the adhering process, the activation process, and the plating process which are explained below, and may be equipped with the skin layer removal process before the adhesion process.

(1) Skin Layer Removal Step In the skin layer removal step, at least a part of the skin layer is removed from a portion located in a thin portion in a molded product of a resin-containing material produced by a molding process such as injection molding. As described above, at least a part of the skin layer of the molded product is removed in the thin-walled portion, so that the member having a plating layer including the electroless plating layer formed on the thin-walled portion has a temperature of 200 ° C. or higher. Even if it is a case where heating is given, possibility that problems, such as plating swelling, will arise can be reduced.

  The resin-based substrate including the thin portion is a molded product manufactured by a molding process. The surface portion of the molded product may have a fragile layer that is also called a skin layer and easily peels from the inner layer. The thermal expansion coefficient of the plating layer including the electroless plating layer formed on the thin wall portion in the plating process described later is greatly different from the thermal expansion coefficient of the resin-containing material constituting the thin wall portion. For this reason, when 200 degreeC or more heating, such as solder reflow, is given with respect to the member provided with a plating layer on the thin part of the resin-type base material, the thermal expansion coefficient of the resin-type base material and the thermal expansion coefficient of the plating layer Shear force based on the difference is applied to the skin layer. If the skin layer is particularly fragile, breakage may occur in this portion based on the shearing force. This destruction of the skin layer is observed as plating swelling as shown in FIGS. 1 and 2, and causes a failure of the member.

  Therefore, by removing at least a part of the skin layer, preferably the entire part of the skin layer that is particularly easily peeled (also referred to as “surface skin layer”) from the molded product located in the thin-walled part, a resin-based substrate is obtained. Even if the above-mentioned heating at 200 ° C. or higher is applied to a member having a plating layer on the thin-walled portion, a resin-containing material and a plating layer that constitute the thin-walled portion through a substance based on the compound (α) described later Since it adheres properly, plating bulging is unlikely to occur.

  The means for removing the skin layer is not limited. The resin-containing material constituting the skin layer may be dissolved and removed using an etching solution, or the skin layer may be physically removed using sandblasting or the like, or a corrosive substance of the resin-containing material may be used. The skin layer may be etched by a dry process.

  When the resin-containing material contains a liquid crystal polymer, an alkaline liquid can be used as an etching solution for the skin layer. In addition, since the liquid crystal polymer is a hydrophobic material, the liquid containing the compound (α) may be difficult to get wet with respect to the surface of the thin portion in the adhesion step described later. Therefore, by bringing the surface of the molded product located in the thin portion in advance into contact with an alkaline liquid, the wettability with respect to the surface of the thin portion of the liquid material containing the compound (α) is increased, and the compound is formed on the surface of the thin portion. It is possible to attach (α) appropriately.

  The composition of the alkaline liquid used for this purpose is not limited. A liquid in which an alkaline substance such as sodium hydroxide, sodium carbonate, or potassium hydroxide is dissolved in a solvent such as water can be used. The concentration of the alkaline substance is not limited as long as the above purpose is achieved. As an example, when sodium hydroxide is used as the alkaline substance, it is about 50 to 300 g / L. The contact method between the alkaline liquid and the surface of the thin portion is not limited as long as the above purpose is achieved. The thin part may be immersed in the alkaline liquid, or the alkaline liquid may be sprayed onto the surface of the thin part. The contact conditions (liquid temperature, contact time, etc.) between the alkaline liquid and the surface of the thin portion are not limited as long as the above-mentioned purpose is achieved. If the specific example which is not limited is shown, when 100 g / L sodium hydroxide is used as an alkaline liquid, it should just contact for about 80 minutes-100 minutes on the conditions of the temperature of 65 degreeC.

In order to confirm the effect of etching with an alkaline liquid on the surface roughness of the thin-walled surface of a resin-based substrate obtained by molding a resin-containing material comprising a liquid crystal polymer containing an insoluble filler, Table 1 and FIGS. 3 and 4 show the results of measuring the surface roughness parameter on the surface of the thin portion after etching by changing the contact time (etching time, unit: minute) of the alkaline liquid to the surface of the portion. In Table 1 and FIGS. 3 and 4, Ra is the arithmetic average roughness (unit: μm) defined in JIS B0601: 2013 (ISO 4287: 1997, Amd. 1: 2009), and Rz is JIS B0601: 2013. (ISO 4287: 1997, Amd. 1: 2009) is a maximum height roughness (unit: μm), and Rz _JIS is a ten-point average roughness (unit: μm) defined in JIS B0601: 2013. It is.

  As shown in Table 1 and FIGS. 3 and 4, when etching using an alkaline liquid is performed to remove the skin layer, the longer the contact time (etching time) with the alkaline liquid is, There is a tendency that the surface roughness of the surface of the thin portion also increases.

  In order to confirm the influence of the skin layer on the mechanical strength of a member having a plating layer on the thin part of the resin base material, the following confirmation experiment was performed.

  About the thin part of the resin base material obtained by molding a resin-containing material comprising a liquid crystal polymer containing an insoluble filler, the degree of removing the skin layer from the thin part by changing the immersion time in an alkaline liquid Changed. A member including the thin-walled portion thus obtained and an electroless nickel plating layer formed on each of the thin-walled portions was prepared. A 180 ° peel test was performed using the thinned portion of these members as the measurement portion. FIG. 5 shows the relationship between the removal thickness of the skin layer (“etching thickness”, unit: μm) and the peel strength (unit: N / cm) estimated from the change in weight before and after immersion in an alkaline liquid. became. As shown in FIG. 5, it was confirmed that the peel strength tends to increase as the removal amount of the skin layer increases.

  As described above, wettability with respect to the surface of the thin portion of the liquid material containing the compound (α) can be improved by contacting with an alkaline liquid. However, if the contact time (etching time) is increased, the surface roughness is also increased. There is a tendency to grow. When the thickness of the thin part is particularly thin, or when the surface of the conductive layer formed on the surface of the thin part is a sliding surface, it is preferable that the surface roughness of the thin part is relatively small There is. In such a case, the conditions for contact with the alkaline liquid are relaxed (specific examples include lowering the alkali concentration in the liquid, lowering the contact temperature, and shortening the contact time). Therefore, it is possible to reduce the change in surface roughness of the surface of the thin portion due to contact (etching) with an alkaline liquid, and to perform additional processing for surface modification on the surface of the thin portion. preferable. Examples of such surface modification treatment include irradiation with light having a short wavelength such as ultraviolet light (specific examples include irradiation with an excimer UV lamp or excimer laser), electron beam irradiation, plasma ashing, corona discharge, reverse sputtering, and the like. Is exemplified. When the surface of the thin portion is not flat but has irregularities, it may be preferable to irradiate an excimer UV lamp from the viewpoint of improving the uniformity of the surface modification treatment.

(2) Adhesion step In the adhesion step, the surface of the thin wall portion is brought into contact with the liquid material containing the compound (α) represented by the following general formula [I]. a) is attached.

Here, in the general formula [I], E is an arbitrary group. F is an OH group or an OH generating group. -Q is -N ₃ or _-NR 1 _{(R 2).} R ₁ and R ₂ of —NR ₁ (R ₂ ) are H, a hydrocarbon group having 1 to 24 carbon atoms, or —RSi (R ′) _n (OA) _{3 -n} (R is 1 carbon atom) A chain hydrocarbon group having ˜12, R ′ is a chain hydrocarbon group having 1 to 4 carbon atoms, A is H or a chain hydrocarbon group having 1 to 4 carbon atoms. N is an integer from 0 to 2). R ₁ and R ₂ may be the same or different. Examples of the OH generating group include an alkoxysilyl group.

  The compound (α) may be composed of one kind of substance or may be composed of a plurality of kinds of substances. In the case where the compound (α) is composed of a plurality of types of substances, the composition of the compound (α) is not limited. The thickness is appropriately set according to the composition of the thin portion, the type of substance capable of forming the catalyst nucleus, and the like.

  The composition of the liquid containing the compound (α) is not limited as long as the compound (α) can be attached to the surface of the thin portion. In the liquid containing the compound (α), the compound (α) may be dissolved or dispersed. Therefore, the liquid medium in the liquid containing the compound (α) may be a solvent or a dispersion medium. Specific examples of the liquid medium include water, alcohol, ketone, alkane (aliphatic hydrocarbon), aromatic compound, ether, ester and the like. The content of the compound (α) in the liquid containing the compound (α) is not limited. 0.0001 mass% or more and 10 mass% or less is illustrated, and a preferable example is 0.001 mass% or more and 2 mass% or less.

  The liquid containing the compound (α) may contain a surfactant, a colorant, an antioxidant and the like. The content of these components is appropriately set according to the purpose.

  The contact method of the liquid body containing a compound ((alpha)) and the surface of a thin part is not limited. The thin portion may be immersed in the liquid body containing the compound (α), or the liquid body containing the compound (α) may be sprayed onto the surface of the thin portion. The contact conditions (temperature, contact time, etc.) between the liquid containing the compound (α) and the surface of the thin portion are not limited. After the adhering step and before starting the next fixing step, a drying operation is performed to remove the liquid medium (solvent and / or dispersion medium) containing the compound (α) remaining on the surface of the thin portion. May be.

(3) Fixing process In the fixing process, the surface of the thin part to which the compound (α) is attached is irradiated with energy rays to fix the substance based on the compound (α) to the surface of the thin part. Examples of energy rays include ionizing radiation such as X-rays and ultraviolet rays, electron beams, and ion beams. Among these, it is convenient to use ultraviolet rays. In the case of using ultraviolet light, a UV light source including a lamp or LED that can irradiate ultraviolet light may be used. As an example, when ultraviolet rays having a wavelength of 254 nm are used, variation in irradiation can be suppressed by irradiating the irradiation intensity within the range of 0.1 to 5 mW / cm ² , more preferably 0.1 to 1 mW / cm ^2. It is preferable. Moreover, as irradiation amount, about 30-90 mJ / cm < ² > is good.

  The azide group of the compound (α) is decomposed by irradiation with energy rays. Based on the nitrene generated by this decomposition, the residue of the compound (α) is chemically bonded to the resin located on the surface of the thin portion. In this way, the substance based on the compound (α) can be fixed to the surface of the thin portion.

  The irradiation amount of energy rays is not limited as long as decomposition of the azide group of the compound (α) can be caused. In the adhering step, the liquid medium containing the compound (α) remaining on the surface of the thin portion may be removed by performing a drying operation simultaneously with the irradiation of the energy rays.

(4) Activation process In an activation process, a catalyst nucleus is made to adhere to the surface of the thin part which passed through said adhering process. A substance based on the compound (α) is fixed on the surface of the thin part after the fixing process, and a group having an active hydrogen such as a hydroxyl group or an amino group is present on the surface of the thin part derived from the substance. . For this reason, even if the resin-containing material constituting the thin portion is a hydrophobic material such as a liquid crystal polymer, a substance capable of forming a catalyst nucleus and / or a catalyst nucleus can be attached to the surface of the thin portion. By reducing the substance capable of forming the attached catalyst nucleus to form the catalyst nucleus, the catalyst nucleus can be attached to the surface of the thin portion. The material capable of forming the catalyst nucleus is not limited. Usually, platinum group elements such as platinum and palladium, and metals and alloys of iron group elements such as iron and nickel are used as the metal-based material that forms the catalyst nucleus, forming a catalyst nucleus composed of complexes containing the above metal elements. Reduction of possible materials forms catalyst nuclei.

(5) Plating treatment step In the plating treatment step, an electroless plating layer is formed on the surface of the thin portion to which the catalyst core is attached. The type of plating treatment for forming the electroless plating layer is not limited. Examples include electroless nickel plating, electroless gold plating, electroless copper plating, and electroless cobalt plating. Treatment conditions are also set as appropriate according to the type of electroless plating treatment. The thickness of the electroless plating layer formed by plating is not limited. It is set appropriately according to the application. Plural kinds of plating processes may be performed in the plating process. For example, the electroplating process may be performed after the electroless plating process.

3. Electronic Component An electronic component according to an embodiment of the present invention includes the member according to the above-described embodiment of the present invention.

  In recent years, with the miniaturization of electronic components, the pitch of wiring of electronic components has been reduced. In addition, with the increase in the frequency of electrical signals flowing through electronic components, it has been required to shield the wiring electromagnetically.

  Until now, metal-based materials have been used as the material that provides the electromagnetic shield part (electromagnetic shield part). For example, a metal plate with a thickness of about 0.1 mm is subjected to secondary processing (pressing or the like). The electromagnetic shield part was formed by. However, when a metal plate is used, it is difficult to increase the degree of freedom in designing the electromagnetic shield part because there is a limit to increasing the shape workability. Further, since the electromagnetic shield part is made of a metal-based material, it is separate from other parts of the electronic component, and a process of incorporating the electromagnetic shield part into the electronic component is required.

  Therefore, the present inventors examined forming the electromagnetic shield part integrally with the other part of the electronic component by a manufacturing method including molding a material containing a resin having excellent fluidity such as a liquid crystal polymer. . Prepare a molded product having a thickness of about 0.3 mm or less, specifically, a thin part of about 0.1 mm or less as a resin base material, and provide a conductive part on the surface of the thin part. If it can be formed, an electronic component including an integrated electromagnetic shield can be formed.

  When the resin-containing material contains a soluble filler, that is, when the resin-containing material is a so-called plating grade, dissolving the soluble filler and imparting an uneven shape to the thin portion significantly reduces the mechanical strength of the thin portion. End up. For this reason, it was substantially impossible to manufacture the thin-walled portion constituting the electromagnetic shield portion with a plating grade resin-containing material. Therefore, it has been difficult to form an electroless plating layer with high adhesion on the surface of the thin portion.

  In this regard, in the electronic component according to the embodiment of the present invention, the thickness of the thin portion constituting the electromagnetic shield portion is 0.3 mm or less, and a conductive layer is provided on the surface. For this reason, the thin part of the electromagnetic shielding part corresponding to narrow pitch can be integrated. Such an electronic component can be manufactured by the above-described method for manufacturing a member according to an embodiment of the present invention. In a specific example, the surface of the conductive layer in the thin part of the electronic component may be a sliding surface.

  The embodiment described above is described for facilitating understanding of the present invention, and is not described for limiting the present invention. Therefore, each element disclosed in the above embodiment is intended to include all design changes and equivalents belonging to the technical scope of the present invention.

  As described above, the member according to the present invention can be suitably used for an electronic component having an electromagnetic shield while having a narrow pitch.

Claims (11)

A base material provided with a thin part having a thickness of 0.3 mm or less, obtained from a molded product of a resin-containing material;
A conductive layer formed on the surface of the thin portion;
A member comprising:   The member according to claim 1, wherein at least a part of the skin layer of the molded product located in the thin portion is removed.   The member according to claim 1, wherein the resin-containing material contains a liquid crystal polymer.   The member according to any one of claims 1 to 3, wherein the conductive layer includes an electroless plating layer formed by electroless plating. It is a manufacturing method of the member according to claim 4, Comprising:
Adhesion for adhering the compound (α) to the surface of the thin portion, including contacting the surface of the thin portion with a liquid containing the compound (α) represented by the following general formula [I] Process;
A fixing step of irradiating the surface of the thin part to which the compound (α) is adhered with an energy ray to fix the substance based on the compound (α) to the surface of the thin part;
An activation step of attaching catalyst nuclei to the surface of the thin-walled portion that has undergone the fixing step; and a plating treatment step of forming an electroless plating layer on the surface of the thin-walled portion to which the catalyst nuclei are attached. Manufacturing method of member.
Here, in the general formula [I], E is an arbitrary group. F is an OH group or an OH generating group. -Q is -N ₃ or _-NR 1 _{(R 2).} R ₁ and R ₂ of —NR ₁ (R ₂ ) are H, a hydrocarbon group having 1 to 24 carbon atoms, or —RSi (R ′) _n (OA) _{3 -n} (R is 1 carbon atom) A chain hydrocarbon group having ˜12, R ′ is a chain hydrocarbon group having 1 to 4 carbon atoms, A is H or a chain hydrocarbon group having 1 to 4 carbon atoms. N is an integer from 0 to 2). R ₁ and R ₂ may be the same or different.   The member according to claim 5, wherein the thin-walled portion subjected to the attaching step is subjected to a skin layer removing step of removing at least a part of the skin layer from the molded product located in the thin-walled portion. Production method.   The method for producing a member according to claim 6, wherein the resin-containing material includes a liquid crystal polymer, and in the skin layer removing step, the surface of the molded product located in the thin portion is brought into contact with an alkaline liquid.   8. In the skin layer removing step, after the surface of the molded product located in the thin portion is brought into contact with an alkaline liquid, a surface modification treatment is performed on the surface in contact with the alkaline liquid. The manufacturing method of the member as described in any one of.   The method for manufacturing a member according to claim 8, wherein the surface modification treatment includes light irradiation with an excimer UV lamp.   The electronic component provided with the member as described in any one of Claim 1 to 4. The electronic component according to claim 10, wherein a surface of the conductive layer is a sliding surface.