JPWO2016133096A1 - Veneer - Google Patents

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JPWO2016133096A1
JPWO2016133096A1 JP2017500695A JP2017500695A JPWO2016133096A1 JP WO2016133096 A1 JPWO2016133096 A1 JP WO2016133096A1 JP 2017500695 A JP2017500695 A JP 2017500695A JP 2017500695 A JP2017500695 A JP 2017500695A JP WO2016133096 A1 JPWO2016133096 A1 JP WO2016133096A1
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plate
glass plate
layer
glass
decorative board
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JP6614235B2 (en
Inventor
松井 徹
徹 松井
広和 小平
広和 小平
和章 白茂
和章 白茂
原田 知明
知明 原田
智道 今井
智道 今井
みどり 黒川
みどり 黒川
富永 紘正
紘正 富永
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AGC Inc
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Asahi Glass Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • B32B7/022Mechanical properties
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C21/00Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/15Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass characterised by the use of glass elements, i.e. wherein an outer layer is not of glass

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Glass (AREA)
  • Finishing Walls (AREA)

Abstract

大きな衝撃が加えられても割れ難く、割れたとしても飛散しない化粧板を提供する。意匠性を有する脆性の板状体2と、板状体2に積層された樹脂層3とを有し、樹脂層3は、厚さが1.5mm以上であり、樹脂層3のショアA硬度は、10以上60以下である。Provided is a decorative board which is difficult to break even when a large impact is applied and does not scatter even if it is cracked. The brittle plate-like body 2 having design properties and the resin layer 3 laminated on the plate-like body 2 have a thickness of 1.5 mm or more, and the Shore A hardness of the resin layer 3 Is 10 or more and 60 or less.

Description

本発明は、化粧板に関する。   The present invention relates to a decorative board.

建築物の内壁や収納家具に用いられる化粧板として、ガラス化粧板が知られている(例えば、特許文献1、2参照)。ガラス化粧板は、ガラス板の一面に顔料などを含む塗料が塗布されて形成された意匠層を有しており、ガラス板と意匠層とが密着しているため、ガラス越しに意匠層を見ることで高級感を演出することができる。例えば、ビルディングや店舗において、コンクリート等の下地材にガラス化粧板の意匠層側を貼り付けることで高級感のある内壁を実現することができる。   A glass decorative board is known as a decorative board used for an inner wall of a building or storage furniture (for example, see Patent Documents 1 and 2). The glass decorative plate has a design layer formed by applying a paint containing pigment on one side of the glass plate, and the glass plate and the design layer are in close contact, so the design layer is seen through the glass. It can produce a sense of quality. For example, in a building or a store, a high-quality inner wall can be realized by pasting the design layer side of a glass decorative board on a base material such as concrete.

特開2014−76625号公報JP 2014-76625 A 登録実用新案第2560753号公報Registered Utility Model No. 2560753

しかしながら、ガラス板のような脆性材料を使用した化粧板は、脆性材料であるため割れやすいというイメージがある。また、このような化粧板は、大きな衝撃が加わって割れた際にその破片が飛散するおそれがある。そのため、特にガラス化粧板については、ビルディングや店舗などでは採用されているが、一般住宅では採用され難いものであった。   However, there is an image that a decorative board using a brittle material such as a glass plate is easily broken because it is a brittle material. Moreover, when such a decorative board is cracked due to a large impact, there is a risk that the fragments will scatter. For this reason, glass decorative boards are used in buildings and stores, but are difficult to use in ordinary houses.

本発明は、上記課題に鑑みてなされたものであって、大きな衝撃が加えられても割れ難く、割れたとしても飛散しない化粧板を提供することを目的とする。   This invention is made | formed in view of the said subject, Comprising: It aims at providing the decorative board which is hard to break even if a big impact is added, and does not fly even if it cracks.

本発明の化粧板は、意匠性を有する脆性の板状体と、前記板状体に積層された樹脂層とを有し、前記樹脂層は、厚さが1.5mm以上であり、前記樹脂層のショアA硬度は、10以上、60以下である。   The decorative board of the present invention has a brittle plate having design properties and a resin layer laminated on the plate, and the resin layer has a thickness of 1.5 mm or more, and the resin The Shore A hardness of the layer is 10 or more and 60 or less.

本発明によれば、大きな衝撃が加えられても割れ難く、割れたとしても飛散しない化粧板を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, even if a big impact is applied, it is hard to break and even if it breaks, the decorative board which does not fly can be provided.

本発明に係る化粧板の実施形態の模式的断面図である。It is typical sectional drawing of embodiment of the decorative board which concerns on this invention. 本発明の一実施例の補強材付き化粧板の模式的断面図である。It is typical sectional drawing of the decorative board with a reinforcing material of one Example of this invention.

以下、本発明を実施するための形態について図面を参照して説明するが、本発明は、以下の実施形態に制限されることはなく、本発明の範囲を逸脱することなく、以下の実施形態に種々の変形および置換を加えることができる。   DESCRIPTION OF EMBODIMENTS Hereinafter, embodiments for carrying out the present invention will be described with reference to the drawings. However, the present invention is not limited to the following embodiments, and the following embodiments are not deviated from the scope of the present invention. Various modifications and substitutions can be made.

本発明に係る実施形態の化粧板は、意匠性を有する脆性の板状体と、板状体に積層された樹脂層とを有する。板状体の意匠性は、板状体自体が模様や色彩等を有することで意匠性を発現してもよく、意匠性が板状体と樹脂層との間に介在された意匠層によって付与されてもよい。なお、板状体と樹脂層との間に介在された意匠層とは、板状体の表面に直接形成された意匠層および樹脂層の表面に直接形成された意匠層の形態も含む。
また本実施形態の樹脂層は、板状体の表面の80%以上に積層されるのが好ましい。より好ましくは、樹脂層が板状体の表面の90%以上に積層される。板状体の大部分に樹脂層を積層させることにより、大きな衝撃が加えられても割れ難く、割れたとしても飛散しない化粧板となる。
板状体としては、脆性材料であれば、本発明の効果を享受できる。例えば、ガラス板、樹脂板やセラミック板が挙げられる。以下では、ガラス板を用いたガラス化粧板の例について説明する。
図1は、本実施形態を示す模式的断面図である。本実施形態における化粧板1は、ガラス板2と、ガラス板2に積層された樹脂層3と、ガラス板2と樹脂層3との間に介在された意匠層4とを有している。
The decorative board according to the embodiment of the present invention includes a brittle plate having design properties and a resin layer laminated on the plate. The design property of the plate-like body may be expressed by the plate-like body itself having a pattern, color, etc., and the design property is imparted by the design layer interposed between the plate-like body and the resin layer. May be. The design layer interposed between the plate-like body and the resin layer includes a design layer directly formed on the surface of the plate-like body and a design layer directly formed on the surface of the resin layer.
Moreover, it is preferable that the resin layer of this embodiment is laminated | stacked on 80% or more of the surface of a plate-shaped object. More preferably, the resin layer is laminated on 90% or more of the surface of the plate-like body. By laminating a resin layer on the majority of the plate-like body, it becomes a decorative board that is difficult to break even when a large impact is applied, and that does not scatter even if cracked.
If the plate-like body is a brittle material, the effects of the present invention can be enjoyed. For example, a glass plate, a resin plate, and a ceramic plate are mentioned. Below, the example of the glass decorative board using a glass plate is demonstrated.
FIG. 1 is a schematic cross-sectional view showing this embodiment. The decorative board 1 in the present embodiment includes a glass plate 2, a resin layer 3 laminated on the glass plate 2, and a design layer 4 interposed between the glass plate 2 and the resin layer 3.

本実施形態の化粧板1は、壁、天井等の建材や収納家具等の各種用途に適用できる。ガラス板2を樹脂層3と積層させることによってガラス板2を補強して割れ難くし、万が一割れた時にも、ガラス板2と樹脂層3とが接着されていることによりガラス片が飛散しないため、従来のガラス化粧板にない高い安全性を有する。一方、従来のガラス化粧板と同様に、ガラス板2に意匠層4が密着されるため、高級感のある美観を演出できる。   The decorative board 1 of the present embodiment can be applied to various uses such as building materials such as walls and ceilings and storage furniture. By laminating the glass plate 2 with the resin layer 3, the glass plate 2 is reinforced to make it difficult to break, and even if it breaks, the glass piece 2 does not scatter due to the glass plate 2 and the resin layer 3 being bonded. High safety not found in conventional glass decorative panels. On the other hand, since the design layer 4 is brought into close contact with the glass plate 2 in the same manner as the conventional glass decorative plate, a high-quality aesthetic appearance can be produced.

ガラス板2は、ガラスの種類は、特に限定されないが、例えばソーダライムガラス、無アルカリガラスやアルミノシリケートガラス等が挙げられる。化学強化処理を施す場合には、酸化物基準の質量%でAlを3%以上含有するアルミノシリケートガラスが好ましい。ガラス板2の板厚は、0.5mm以上であるのが好ましい。ガラス板2の板厚が0.5mm以上であると、樹脂層と積層することにより充分な強度が得られる。1.0mm以上であることがより好ましく、1.5mm以上であることがさらに好ましい。また、板厚が8.0mm以下であると、従来のガラス化粧板の板厚と同等であるため、壁面への施工も従来と同様に特別な作業を要さないため好ましい。また、6.0mm以下であることがさらに好ましい。As for the glass plate 2, although the kind of glass is not specifically limited, For example, soda-lime glass, an alkali free glass, an aluminosilicate glass, etc. are mentioned. When the chemical strengthening treatment is performed, an aluminosilicate glass containing 3% or more of Al 2 O 3 by mass% based on the oxide is preferable. The plate thickness of the glass plate 2 is preferably 0.5 mm or more. When the plate thickness of the glass plate 2 is 0.5 mm or more, sufficient strength can be obtained by laminating with the resin layer. It is more preferably 1.0 mm or more, and further preferably 1.5 mm or more. Moreover, since it is equivalent to the plate | board thickness of the conventional glass decorative board as the plate | board thickness is 8.0 mm or less, since the construction to a wall surface does not require a special operation | work similarly to the past, it is preferable. Moreover, it is more preferable that it is 6.0 mm or less.

ところで、ガラス板は、比重が大きく、壁面へ施工するガラス化粧板ではガラス板が大面積となるため、重量が非常に重くなる。そのためガラス化粧板の壁面への施工は、作業員が数名で施工する必要があるなど容易ではなかった。本実施形態では、樹脂層3と積層して強度が確保できるため、ガラス板の薄板化が可能となる。すなわち、従来のガラス化粧板よりも重量が軽くなるため、ガラス板の板厚は、4.0mm以下であることが好ましい。また、3.0mm以下であることがさらに好ましい。このようにガラス化粧板の薄板化が可能となるため、本実施形態のガラス化粧板の面積は、特に限定されないが、1m以上であるときに従来のガラス化粧板と比較して軽量化できるため効果的である。さらに2m以上のときに効果的である。また、ガラス化粧板を軽量化できることにより、従来は脱落防止のために接着材により強固に下地材に貼り付けていたが、下地材に留め具を準備して接着材を使用しない嵌め込みによる施工も可能となる。By the way, the specific gravity of a glass plate is large, and the glass plate has a large area in a glass decorative plate applied to a wall surface, so that the weight becomes very heavy. Therefore, the construction of the glass decorative panel on the wall surface has not been easy because several workers need to construct it. In this embodiment, since the strength can be ensured by being laminated with the resin layer 3, it is possible to reduce the thickness of the glass plate. That is, since the weight is lighter than the conventional glass decorative plate, the thickness of the glass plate is preferably 4.0 mm or less. Moreover, it is more preferable that it is 3.0 mm or less. Thus, since the glass decorative plate can be thinned, the area of the glass decorative plate of the present embodiment is not particularly limited, but when it is 1 m 2 or more, it can be reduced in weight as compared with the conventional glass decorative plate. Therefore, it is effective. Furthermore, it is effective when it is 2 m 2 or more. In addition, because the glass decorative panel can be reduced in weight, it has traditionally been affixed firmly to the base material with an adhesive to prevent falling off. It becomes possible.

ガラス板2は、意匠層4と密着していることが好ましい。密着することによってガラス板を通して意匠層4を見た時のガラス化粧板は、奥行き感、高級感が増し美観上優れる。また、ガラス板2の可視光透過率(JIS R3106に準拠して求められる)は、60%以上であることが美観上好ましく、より好ましくは70%以上である。   The glass plate 2 is preferably in close contact with the design layer 4. When the design layer 4 is viewed through the glass plate by adhering, the glass decorative plate has a sense of depth and luxury, and is excellent in aesthetics. Further, the visible light transmittance of the glass plate 2 (obtained in accordance with JIS R3106) is preferably 60% or more, and more preferably 70% or more.

なお、ガラス板2は、ガラス板2の表面にテクスチャーを設けるために、表面にフロスト加工等の後加工によってテクスチャー処理を施してもよい。   In addition, in order to provide a texture on the surface of the glass plate 2, the glass plate 2 may be subjected to a texture treatment by post-processing such as frost processing on the surface.

ガラス板2は、公知の方法で製造できる。すなわち、フロート法、フュージョン法、ダウンドロー法、ロールアウト法等によりリボン状に成形されたガラスを切断して製造される。   The glass plate 2 can be manufactured by a known method. That is, it is manufactured by cutting glass formed into a ribbon shape by a float method, a fusion method, a downdraw method, a roll-out method or the like.

ガラス板2は、表層に圧縮応力層を有していてもよい。ガラス板2が強化処理を施されると、ガラス板2は、強化ガラス板となる。強化処理が施された強化ガラス板は、強化処理が施されていない場合と比較して割れ難くなり好ましい。強化ガラス板は、表層に圧縮応力層、すなわち、残留圧縮応力を有する表面層及び裏面層、並びに表面層と裏面層との間に形成され、残留引張応力を有する中間層を含む。強化ガラス板の板厚方向両端から内部に向かうほど残留圧縮応力が小さくなり、強化ガラス板の内部には残留引張応力が生じている。   The glass plate 2 may have a compressive stress layer on the surface layer. When the glass plate 2 is tempered, the glass plate 2 becomes a tempered glass plate. A tempered glass sheet that has been subjected to a tempering treatment is preferred because it is less likely to break compared to a case in which no tempering treatment is performed. The tempered glass plate includes a compressive stress layer on the surface layer, that is, a front surface layer and a back surface layer having residual compressive stress, and an intermediate layer formed between the front surface layer and the back surface layer and having residual tensile stress. The residual compressive stress decreases as it goes from both ends in the thickness direction of the tempered glass plate to the inside, and a residual tensile stress is generated inside the tempered glass plate.

強化ガラス板の端面は、表面層及び裏面層に連続して残留圧縮応力で覆われていてもよい。強化ガラス板の端面が残留圧縮応力で覆われることで、衝撃に対して割れ難くなり好ましい。なお、強化ガラス板の端面は、残留圧縮応力で覆われておらず、強化ガラス板の端面に中間層の端面が露出していてもよい。その場合は、樹脂などのカバー材料で覆われていることが好ましい。   The end surface of the tempered glass plate may be continuously covered with residual compressive stress on the front surface layer and the back surface layer. It is preferable that the end face of the tempered glass plate is covered with residual compressive stress because it is difficult to break against impact. The end face of the tempered glass plate may not be covered with residual compressive stress, and the end face of the intermediate layer may be exposed on the end face of the tempered glass plate. In that case, it is preferably covered with a cover material such as resin.

強化ガラス板は、強化処理を施すことでガラス板の表面や裏面に残留圧縮応力を生じさせて、作製される。強化ガラス板は、イオン交換法等の化学強化処理によって得られる化学強化ガラス、風冷強化法等の物理強化処理によって得られる物理強化ガラスのいずれでもよい。化学強化処理であれば、より板厚の薄いガラス板であっても表面層や裏面層の残留圧縮応力の値を大きくできる。例えば、表層の残留圧縮応力の値が300MPa以上であることが好ましく、400MPa以上であることがより好ましい。化学強化ガラスの場合、圧縮応力層の厚さは、50μm以下であってよく、40μm以下であってもよい。   The tempered glass plate is produced by applying a tempering treatment to cause residual compressive stress on the front and back surfaces of the glass plate. The tempered glass plate may be either a chemically tempered glass obtained by a chemical tempering treatment such as an ion exchange method or a physical tempered glass obtained by a physical tempering treatment such as an air cooling tempering method. If it is a chemical strengthening process, even if it is a glass plate with thinner plate | board thickness, the value of the residual compressive stress of a surface layer or a back surface layer can be enlarged. For example, the residual compressive stress value of the surface layer is preferably 300 MPa or more, and more preferably 400 MPa or more. In the case of chemically strengthened glass, the thickness of the compressive stress layer may be 50 μm or less, or 40 μm or less.

イオン交換法は、ガラス板の表面や裏面をイオン交換し、ガラスに含まれる小さなイオン半径のイオン(例えば、Liイオン、Naイオン)を大きなイオン半径のイオン(例えば、Kイオン)に置換する。これにより、ガラス板の表面や裏面に残留圧縮応力を生じさせることができる。イオン交換法では、ガラス板を高温の処理液に浸漬してイオン交換を行う。   In the ion exchange method, the front and back surfaces of a glass plate are ion-exchanged, and ions having a small ion radius (for example, Li ions and Na ions) contained in the glass are replaced with ions having a large ion radius (for example, K ions). Thereby, a residual compressive stress can be produced in the surface and back surface of a glass plate. In the ion exchange method, ion exchange is performed by immersing a glass plate in a high-temperature treatment solution.

風冷強化法は、軟化点付近の温度のガラス板を両側から急冷し、ガラス板の表面や裏面と、ガラス板の内部との間に温度差をつけることで、ガラス板の表面や裏面に残留圧縮応力を生じさせることができる。風冷強化法等の物理強化法は、強化処理に要する時間が数秒から数十秒であるため、イオン交換法等による化学強化法よりも生産性が非常に優れている。   The air-cooling strengthening method rapidly cools the glass plate at the temperature near the softening point from both sides, and creates a temperature difference between the front and back surfaces of the glass plate and the inside of the glass plate. Residual compressive stress can be generated. Since the physical strengthening method such as the air cooling strengthening method takes several seconds to several tens of seconds for the strengthening process, the productivity is much superior to the chemical strengthening method such as the ion exchange method.

ガラス板2と樹脂層3との間には意匠層4が形成されている。意匠層4は、例えば着色顔料を含む塗料をガラス板2の表面に塗布して乾燥、硬化させることによって形成される。塗料は、例えば、アクリル樹脂系塗料が挙げられる。アクリル樹脂系塗料は、付着力が大きく、耐候性、耐食性にも優れている。また、仕上げが美麗である点で好ましい。なお、意匠層4は、意匠性を付与できるものであれば特に限定されず、例えば、メラミン樹脂系塗料、エポキシ樹脂系塗料であってもよく、着色顔料も様々な色であってよい。また、意匠層4は、金属を蒸着させた鏡であってもよい。   A design layer 4 is formed between the glass plate 2 and the resin layer 3. The design layer 4 is formed, for example, by applying a paint containing a color pigment to the surface of the glass plate 2 and drying and curing. Examples of the paint include acrylic resin paints. Acrylic resin-based paints have high adhesion and are excellent in weather resistance and corrosion resistance. Moreover, it is preferable at the point that a finish is beautiful. The design layer 4 is not particularly limited as long as it can provide design properties. For example, the design layer 4 may be a melamine resin-based paint or an epoxy resin-based paint, and the color pigments may have various colors. The design layer 4 may be a mirror on which a metal is deposited.

塗料の塗布方法としては、特に限定されないが、例えばロールコート法、スプレーコート法、ディップコート法、フローコート法、スクリーン印刷法、スピンコート法等が用いられる。   The coating method of the paint is not particularly limited, and for example, a roll coating method, a spray coating method, a dip coating method, a flow coating method, a screen printing method, a spin coating method and the like are used.

また、塗料ではなく、シート状に成形された意匠層4をガラス板2に接着剤などによって貼着させてもよい。その場合、シート状に成形された意匠層4は、単色であっても複数色であってもよいし、天然石調やレンガ調等の模様が形成されていてもよい。   Moreover, you may affix the design layer 4 shape | molded on the glass plate 2 with the adhesive agent etc. instead of the coating material. In that case, the design layer 4 formed into a sheet shape may be a single color or a plurality of colors, or a pattern such as a natural stone tone or a brick tone may be formed.

樹脂層3は、厚さが1.5mm以上である。樹脂層3の厚さが1.5mm以上であると、ガラス板2と積層させた際に充分な強度が得られる。また、樹脂層3の厚さが2.0mm以上であると、剛性があるため施工時の取り扱いが容易となる。さらに好ましくは3.0mm以上である。また、樹脂層3の厚さが8mm以下であると、従来のガラス化粧板の板厚と同等であるため、壁面への施工も従来と同様に特別な作業を要さないため好ましい。また、6mm以下であることがさらに好ましい。また、樹脂層3の形状は、平面視でガラス板2と同じであることが好ましい。   The resin layer 3 has a thickness of 1.5 mm or more. When the thickness of the resin layer 3 is 1.5 mm or more, sufficient strength can be obtained when the resin layer 3 is laminated with the glass plate 2. Further, when the thickness of the resin layer 3 is 2.0 mm or more, since it is rigid, handling during construction becomes easy. More preferably, it is 3.0 mm or more. Moreover, since it is equivalent to the plate | board thickness of the conventional glass decorative board, since the thickness of the resin layer 3 is 8 mm or less, since the construction to a wall surface does not require a special operation | work like the past, it is preferable. Moreover, it is more preferable that it is 6 mm or less. The shape of the resin layer 3 is preferably the same as that of the glass plate 2 in plan view.

さらに、樹脂層3は、衝撃や火災によるガラス板2の割れを抑制し、万が一ガラス板2が破損したときにガラス破片の飛散を防止することができる。特に、樹脂層3が発泡樹脂からなることが、軽量であるため好ましい。また樹脂層3が緩衝層となって、壁面への施工時に、壁面の凹凸を吸収できるようにすることも好ましい。   Furthermore, the resin layer 3 can suppress the breakage of the glass plate 2 due to an impact or a fire, and can prevent the glass fragments from being scattered when the glass plate 2 is broken. Particularly, it is preferable that the resin layer 3 is made of a foamed resin because it is lightweight. Moreover, it is also preferable that the resin layer 3 becomes a buffer layer so that unevenness of the wall surface can be absorbed during construction on the wall surface.

樹脂層3は、板状の部材であってもよいし、ガラス板2に射出成型や押出成型で一体成形されてもよい。樹脂層3が板状の部材であった場合、ガラス板2と板状の樹脂層3とを意匠層4がガラス板2と樹脂層3の間に介在するように接着剤、粘着剤(以下、粘着剤を含め、接着剤という。)等で貼着される。接着剤は、樹脂層3の全面に塗布されてもよいし、一部でもよい。接着剤を全面に塗布する方が、ガラス板が割れ難くなるため有利である。また、ガラス板2の意匠層4に接着剤を塗布してもよい。接着剤としては、一般的な建築用シーリング材が使用でき、例えば変成シリコーン系シーリング材、アクリル系粘着剤や合成ゴム系粘着剤等が挙げられる。接着剤は、両面テープのようなシート状であってもよい。また、接着剤は、不燃性が高くなるよう材料や塗布量を選定することが建築材料として好適である。   The resin layer 3 may be a plate-like member, or may be integrally formed on the glass plate 2 by injection molding or extrusion molding. When the resin layer 3 is a plate-like member, an adhesive or a pressure-sensitive adhesive (hereinafter referred to as “glass layer 2”) and the plate-like resin layer 3 are interposed between the glass plate 2 and the resin layer 3. , Adhesive, including pressure-sensitive adhesive). The adhesive may be applied to the entire surface of the resin layer 3 or a part thereof. It is advantageous to apply the adhesive to the entire surface because the glass plate is difficult to break. Further, an adhesive may be applied to the design layer 4 of the glass plate 2. As the adhesive, a general architectural sealant can be used, and examples thereof include a modified silicone sealant, an acrylic adhesive, and a synthetic rubber adhesive. The adhesive may be in the form of a sheet such as a double-sided tape. Moreover, it is suitable as a building material that an adhesive agent selects a material and application quantity so that nonflammability may become high.

樹脂層3をガラス板2に一体成形させる場合は、意匠層4が形成されたガラス板2を成形型内に設置して意匠層4上に樹脂が射出されて一体成形される。押出成形の場合は、ガラス板2の意匠層4上に樹脂が押出型より供給され硬化することで一体成形される。なお、必要に応じて、ガラス板2側に接着剤や下塗り剤(プライマー)、例えばシランカップリング剤等を塗布した後に樹脂層3を一体成型してもよい。   When the resin layer 3 is integrally formed on the glass plate 2, the glass plate 2 on which the design layer 4 is formed is placed in a mold and the resin is injected onto the design layer 4 to be integrally formed. In the case of extrusion molding, the resin is supplied from the extrusion mold onto the design layer 4 of the glass plate 2 and is integrally molded. If necessary, the resin layer 3 may be integrally formed after applying an adhesive or an undercoat (primer) such as a silane coupling agent to the glass plate 2 side.

ガラス板2と樹脂層3とを合わせた総厚は、2.5mm以上、10mm以下であるのが好ましい。2.5mm以上であると、充分な強度が得られ、ガラス板2が割れ難い。また、ガラス化粧板は、大面積となることが多く、剛性があることで施工性が高くなる。2.5mm以上であることで充分な剛性が得られ、施工性が良い。好ましくは、3.0mm以上であり、より好ましくは4.0mm以上である。また、10mm以下であることで、従来のガラス化粧板の板厚と同等であるため、壁面への施工も従来と同様に特別な作業を要さないため好ましい。また、8.0mm以下であることがさらに好ましい。   The total thickness of the glass plate 2 and the resin layer 3 is preferably 2.5 mm or more and 10 mm or less. When it is 2.5 mm or more, sufficient strength is obtained, and the glass plate 2 is hardly broken. In addition, the glass decorative plate often has a large area, and the workability is enhanced due to the rigidity. Sufficient rigidity is obtained by being 2.5 mm or more, and workability is good. Preferably, it is 3.0 mm or more, more preferably 4.0 mm or more. Moreover, since it is equivalent to the plate | board thickness of the conventional glass decorative board because it is 10 mm or less, since construction to a wall surface does not require a special operation | work similarly to the past, it is preferable. Moreover, it is more preferable that it is 8.0 mm or less.

樹脂層3のショアA硬度は、10以上、60以下である。なお、本願でいうショアA硬度は、デュロメータ(アスカー製アスカーゴム硬度計A型)の測定値による。被測定物の表面に圧子(押針)を押し込み変形させ、その変形量(押込み深さ)を測定し、少なくとも4か所の平均値とする。樹脂層3が薄く軟い場合には、厚さが6〜12mmになるように樹脂層を重ね合わせて計測する。ショアA硬度が10以上であれば、充分な剛性を有するため施工性が良い。好ましくは20以上であり、より好ましくは30以上である。また、ショアA硬度が60以下であれば充分な衝撃吸収性を有するため、ガラス板2が強い衝撃を受けたとしても割れ難い。好ましくは50以下である。   The Shore A hardness of the resin layer 3 is 10 or more and 60 or less. In addition, the Shore A hardness said by this application is based on the measured value of a durometer (Asker rubber hardness meter A type made from Asker). An indenter (pushing needle) is pushed into the surface of the object to be measured and deformed, and the amount of deformation (pushing depth) is measured to obtain an average value of at least four locations. When the resin layer 3 is thin and soft, measurement is performed with the resin layers superimposed so that the thickness is 6 to 12 mm. If the Shore A hardness is 10 or more, workability is good because of sufficient rigidity. Preferably it is 20 or more, More preferably, it is 30 or more. Further, if the Shore A hardness is 60 or less, it has sufficient shock absorption, so that even if the glass plate 2 receives a strong impact, it is difficult to break. Preferably it is 50 or less.

本実施形態の樹脂層3は、例えば、ガラス板2に物体が衝突した場合に衝撃を吸収するために所定の弾性を有する弾性体である必要がある。しかしながら、弾性が大き過ぎるとガラス板2が強い衝撃を受けた時に局所的に曲がって破損することがある。すなわち、樹脂層3は、充分な衝撃吸収ができ、かつガラス板2の変形量が大きくならない程度のショアA硬度が必要である。   The resin layer 3 of the present embodiment needs to be an elastic body having a predetermined elasticity in order to absorb an impact when an object collides with the glass plate 2, for example. However, if the elasticity is too great, the glass plate 2 may be locally bent and damaged when subjected to a strong impact. That is, the resin layer 3 needs to have a Shore A hardness that allows sufficient shock absorption and does not increase the amount of deformation of the glass plate 2.

そのため、樹脂層3は、発泡樹脂であってもよい。発泡樹脂であることで、樹脂層3を上記のショアA硬度にすることが容易に制御できるので製造上好ましい。すなわち、発泡倍率を変化させることによって、ショアA硬度の制御が容易となり、本実施形態の化粧板1を適用する場所に合わせて、樹脂層3を必要とされるショアA硬度にすることが容易に可能となる。   Therefore, the resin layer 3 may be a foamed resin. Since it is a foamed resin, the resin layer 3 can be easily controlled to have the Shore A hardness described above, which is preferable in production. That is, by changing the expansion ratio, the Shore A hardness can be easily controlled, and the resin layer 3 can be easily set to the required Shore A hardness according to the place where the decorative board 1 of the present embodiment is applied. It becomes possible.

樹脂層3は、発泡ポリエチレン樹脂、発泡ウレタン樹脂または発泡ゴムであってもよい。これらの樹脂であれば燃えにくいため、建築材料として不燃材の認定が得られやすくなるため好ましい。また発泡させることができるため、上記したようなショアA硬度にすることが容易に制御できるので製造上好ましい。
ガラス板2は、樹脂層3とは反対側の表面に、化粧板に特別な機能を付加する機能層を有してもよい。機能層の一例としては、防汚膜、抗菌膜または防曇膜が挙げられる。
防汚膜は、指紋の付着を低減させたり、汚れを付き難くしたりする効果を有する。特に、化粧板1を手で直接触れると、ガラス板2に指紋が付着し意匠性を損なうため、指紋の付着を低減させるAFP(Anti−Finger Print)機能を有することが好ましい。AFP機能は、AFP剤をガラス板2に付着させて、AFP膜をガラス板に形成する。AFP剤としては、フッ素含有有機ケイ素化合物が挙げられる。フッ素含有有機ケイ素化合物としては、防汚性、撥水性および撥油性を付与するものであれば特に限定されず使用できる。AFP剤の分子量は、3,000〜10,000であることが好ましく、3,000〜8,000であることがより好ましく、3,000〜6,000であることがさらに好ましい。AFP剤の分子量が3,000以上であることにより、分子構造に柔軟性が付与され、耐スクラッチ性、表面滑り性を得ることができる。また、10,000以下であることにより、AFP剤1分子あたりの反応基を十分確保でき、ガラス板の表面との密着性を確保できる。
抗菌膜は、抗菌性を発現させる抗菌剤をガラス板2に付着させて形成させる。抗菌剤としては、わさびをはじめとする天然抗菌剤、銅や銀をはじめとする金属系抗菌剤、および酸化チタンをはじめとする酸化物系抗菌剤が挙げられる。特に、銀を含有する溶液をガラス板に塗布し銀膜を形成させ、銀膜が形成されたガラス板を加熱処理することにより、ガラス板の表面から内部に銀イオンを拡散させることが効果の持続性の点で好ましい。
防曇膜は、ガラス板2の表面に吸水性樹脂層を設け、ガラス板表面に形成された微小水滴を吸水して除去することで、ガラス板2の表面が曇ることを防止し、意匠性を維持する効果を有する。防曇膜は、例えば、下地層と吸水層とを含む。下地層は、ガラス板から吸水層を剥がれ難くするための層であり、例えば、シラン系カップリング剤を含む組成物をガラス板に塗布して反応させることで得られる。吸水層は、硬化エポキシ樹脂、ウレタン樹脂および架橋アクリル樹脂から選ばれる硬化樹脂の原料成分を含有する組成物を下地層上に塗布して反応させることで得られる。
The resin layer 3 may be a foamed polyethylene resin, a foamed urethane resin, or a foamed rubber. Since these resins are difficult to burn, it is preferable because it is easy to obtain a non-combustible material as a building material. Moreover, since it can be made to foam, since it can control easily as above-mentioned Shore A hardness, it is preferable on manufacture.
The glass plate 2 may have a functional layer that adds a special function to the decorative plate on the surface opposite to the resin layer 3. Examples of the functional layer include an antifouling film, an antibacterial film, and an antifogging film.
The antifouling film has an effect of reducing the adhesion of fingerprints or making it difficult to get dirt. In particular, when the decorative plate 1 is directly touched by a hand, a fingerprint is attached to the glass plate 2 to impair the design, and therefore it is preferable to have an AFP (Anti-Finger Print) function for reducing the adhesion of the fingerprint. In the AFP function, an AFP agent is attached to the glass plate 2 to form an AFP film on the glass plate. Examples of the AFP agent include fluorine-containing organosilicon compounds. Any fluorine-containing organosilicon compound can be used without particular limitation as long as it imparts antifouling properties, water repellency and oil repellency. The molecular weight of the AFP agent is preferably 3,000 to 10,000, more preferably 3,000 to 8,000, and still more preferably 3,000 to 6,000. When the molecular weight of the AFP agent is 3,000 or more, flexibility is imparted to the molecular structure, and scratch resistance and surface slip properties can be obtained. Moreover, when it is 10,000 or less, sufficient reactive groups per molecule of the AFP agent can be secured, and adhesion with the surface of the glass plate can be secured.
The antibacterial film is formed by attaching an antibacterial agent that exhibits antibacterial properties to the glass plate 2. Antibacterial agents include natural antibacterial agents such as wasabi, metal antibacterial agents such as copper and silver, and oxide antibacterial agents such as titanium oxide. In particular, a solution containing silver is applied to a glass plate to form a silver film, and heat treatment is performed on the glass plate on which the silver film is formed, thereby diffusing silver ions from the surface of the glass plate to the inside. It is preferable in terms of sustainability.
The anti-fogging film is provided with a water-absorbing resin layer on the surface of the glass plate 2 and absorbs and removes fine water droplets formed on the surface of the glass plate, thereby preventing the surface of the glass plate 2 from being fogged and having a design property. Has the effect of maintaining The antifogging film includes, for example, a base layer and a water absorption layer. An underlayer is a layer for making it difficult to peel a water absorption layer from a glass plate, for example, is obtained by apply | coating the composition containing a silane coupling agent to a glass plate, and making it react. The water-absorbing layer is obtained by applying a composition containing a raw material component of a cured resin selected from a cured epoxy resin, a urethane resin, and a crosslinked acrylic resin on the base layer and reacting.

ガラス板2と樹脂層3の周囲が補強材で覆われていてもよい。図2は、化粧板1の端面に補強材5を装着させた模式的断面図である。補強材5は、化粧板1の周囲に額縁状に形成されている。補強材6は、額縁状にシームレスに形成されている必要はなく、各辺毎に分離されていてよい。補強材6は、化粧板1のすべての辺を覆う必要はなく、少なくとも1辺を覆うことでよい。補強材6は、例えば塩化ビニル樹脂で形成されている。化粧板1が補強材6で覆われることにより、施工時にガラス化粧板の端面を保護するため、割れ難くなり、施工性の点で好ましい。   The periphery of the glass plate 2 and the resin layer 3 may be covered with a reinforcing material. FIG. 2 is a schematic cross-sectional view in which the reinforcing material 5 is attached to the end face of the decorative board 1. The reinforcing material 5 is formed in a frame shape around the decorative board 1. The reinforcing material 6 does not need to be seamlessly formed in a frame shape, and may be separated for each side. The reinforcing material 6 does not need to cover all the sides of the decorative board 1, and may cover at least one side. The reinforcing material 6 is made of, for example, a vinyl chloride resin. Since the decorative board 1 is covered with the reinforcing material 6 to protect the end face of the glass decorative board during construction, it is difficult to break, which is preferable in terms of workability.

補強材5は、アンカー6を有しており、アンカー6が樹脂層3に差し込まれることにより補強材5が化粧板1に固定されていてもよい。化粧板1が矩形である場合、各辺に1か所以上、好ましくは複数個所にアンカー6が設けられる。アンカー6は、例えば図2に示すように化粧板1の樹脂層3に貫入されて係合される。アンカー6が樹脂層3と係合されることにより補強材6が化粧板1に固定される。なお、接着剤によって補強材5を化粧板1の端面に固定させてもよい。アンカー6によって補強材5を化粧板1に固定する方が、接着剤を硬化させる時間を不要とすることができるため、好ましい。また、アンカー6と接着剤とを併用することでもよい。その場合、アンカー6が仮止めとして機能し、接着剤の硬化前の補強材5の位置ずれを防止できる。
以上は、板状体としてガラス板を用いた例について説明したが、ガラス板の代わりに脆性を有する樹脂板やセラミック板であってもよい。脆性を有する樹脂板としては、例えば、メラミン系樹脂板、アクリル系樹脂板、ポリカーボネート系樹脂板や塩ビ板等が挙げられる。セラミック板としては、タイルなどの陶製の部材が挙げられる。板状体は石材で構成されていてもよい。これらの脆性の板状体も同様に本発明の化粧板に好適に用いることができる。
また、意匠層は、板状体の表面に凹凸などで型模様を設けた、例えば型板ガラスによって意匠性を付与されていてもよい。
The reinforcing material 5 has an anchor 6, and the reinforcing material 5 may be fixed to the decorative board 1 by inserting the anchor 6 into the resin layer 3. When the decorative board 1 is rectangular, the anchor 6 is provided in one or more places on each side, preferably in a plurality of places. For example, as shown in FIG. 2, the anchor 6 is inserted into and engaged with the resin layer 3 of the decorative board 1. The reinforcing material 6 is fixed to the decorative board 1 by the anchor 6 being engaged with the resin layer 3. The reinforcing material 5 may be fixed to the end face of the decorative board 1 with an adhesive. Fixing the reinforcing material 5 to the decorative board 1 with the anchor 6 is preferable because it can eliminate the time for curing the adhesive. Moreover, you may use together the anchor 6 and an adhesive agent. In that case, the anchor 6 functions as a temporary fixing, and the displacement of the reinforcing material 5 before the adhesive is cured can be prevented.
Although the example which used the glass plate as a plate-shaped body was demonstrated above, the resin board and ceramic board which have brittleness instead of a glass plate may be sufficient. Examples of the brittle resin plate include a melamine resin plate, an acrylic resin plate, a polycarbonate resin plate, and a vinyl chloride plate. Examples of the ceramic plate include a ceramic member such as a tile. The plate-like body may be made of stone. These brittle plate-like bodies can also be suitably used for the decorative board of the present invention.
In addition, the design layer may be provided with designability by, for example, template glass in which a pattern is provided on the surface of the plate-like body by unevenness or the like.

(衝撃試験)
本発明の一実施形態のガラス化粧板について実施した衝撃試験について以下に説明する。以下の表1に示す実施例、比較例では、ガラス板として縦300mm、横300mmのソーダライムガラス(旭硝子社製AS)を使用した。また、樹脂層として化学架橋ポリエチレン発泡樹脂(三和化工社製SUNPELICA(登録商標))の発泡倍率を変えて所望のショアA硬度に調整した発泡ポリエチレン樹脂板を使用した。ガラス板に接着剤(セメダイン社製POSシールマルチ(登録商標))を全面に塗布して樹脂層を貼り合わせた。ガラス板の板厚と樹脂層の厚さおよびショアA剛度を表1に記載のとおり変化させて各種ガラス化粧板を作製した。ショアA硬度が65〜70の樹脂層には汎用シリコーンゴム板(ミスミ社製シリコンゴムシート)、ショアA硬度が80〜85の樹脂層には汎用アクリル樹脂板(三菱レイヨン社製アクリライトE(登録商標))を用いた。また別の比較例として、樹脂層のないガラス板を評価した。なお、衝撃試験のため意匠層は、省略してガラス化粧板を作製した。
(Impact test)
The impact test performed on the glass decorative plate of one embodiment of the present invention will be described below. In Examples and Comparative Examples shown in Table 1 below, soda lime glass (ASA manufactured by Asahi Glass Co., Ltd.) having a length of 300 mm and a width of 300 mm was used as a glass plate. Moreover, the foaming polyethylene resin board which changed the foaming magnification of the chemically crosslinked polyethylene foaming resin (SUNPELICA (trademark) by Sanwa Kako Co., Ltd.) as the resin layer and adjusted to desired Shore A hardness was used. An adhesive (POS Seal Multi (registered trademark) manufactured by Cemedine Co., Ltd.) was applied to the entire surface of the glass plate, and the resin layer was bonded. Various glass decorative plates were prepared by changing the thickness of the glass plate, the thickness of the resin layer, and the Shore A stiffness as shown in Table 1. General-purpose silicone rubber plate (Misumi silicon rubber sheet) for resin layer with Shore A hardness 65-70, and general-purpose acrylic resin plate (Acrylite E (Mitsubishi Rayon Co., Ltd.) for resin layer with Shore A hardness 80-85 Registered trademark)). Moreover, the glass plate without a resin layer was evaluated as another comparative example. In addition, the design layer was abbreviate | omitted for the impact test and the glass decorative board was produced.

衝撃試験は、建築用ボード類の曲げ及び衝撃試験方法(JIS A1408)において、砂上に石膏ボードを設置し、石膏ボード上に載置したガラス化粧板に対して、重量が225gの鋼球を、75cmおよび100cmの高さから落下させることで実施した。その結果を表1に示す。表1では、75cmの高さから鋼球を落下させたときにガラス化粧板が破損しなかった確率が50%以上の場合を「△」とし、50%未満の場合を「×」とした。また、100cmの高さから鋼球を落下させたときにガラス化粧板が破損しなかった確率が80%以上の場合を「○」とした。各例の確率は、2〜5のサンプル数で試験した結果から算出し、「○」、「△」または「×」の評価を実施した。なお、表1において空欄の部分は、該当する作製サンプル無しを示す。   In the impact test, in the bending and impact test method for building boards (JIS A1408), a gypsum board is set on sand, and a steel ball having a weight of 225 g is placed on a glass decorative plate placed on the gypsum board. It was carried out by dropping from a height of 75 cm and 100 cm. The results are shown in Table 1. In Table 1, the case where the probability that the glass decorative plate was not broken when the steel ball was dropped from a height of 75 cm was 50% or more was designated as “Δ”, and the case where it was less than 50% was designated as “X”. Moreover, the case where the probability that the glass decorative plate was not damaged when the steel ball was dropped from a height of 100 cm was 80% or more was evaluated as “◯”. The probability of each example was calculated from the results of testing with 2 to 5 samples, and an evaluation of “◯”, “Δ”, or “×” was performed. In Table 1, a blank part indicates no corresponding sample.

Figure 2016133096
Figure 2016133096

以上の結果から、樹脂層の厚さが1.5mm以上であり、樹脂層のショアA硬度が、10以上、60以下である化粧板は、耐衝撃性に優れており、割れにくく、特にガラス板の板厚が0.5mm以上であり、樹脂層の厚さが1.5mm以上であり、樹脂層のショアA硬度が10以上、60以下である場合に、板厚が4.0mmのガラス板のみのガラス化粧板と同等以上の強度を有することがわかった。
(発熱性試験)
本発明の一実施形態のガラス化粧板について実施した発熱性試験について以下に説明する。ガラス板としてソーダライムガラス(旭硝子社製AS、縦300mm、横300mm、板厚は1.1mmのものと2.0mmのもの2種類)に、接着剤(セメダイン社製POSシールマルチ(登録商標))を全面に塗布して、樹脂層として化学架橋ポリエチレン発泡樹脂(三和化工社製SUNPELICA(登録商標)、厚さは3mm、ショアA硬度は30〜32のものと25〜27のもの2種類。)を貼り合わせて、ガラス板の板厚と樹脂層のショアA硬度それぞれの条件を変更して4種類のガラス化粧板を5枚ずつ作製した。
From the above results, the decorative board in which the resin layer thickness is 1.5 mm or more and the Shore A hardness of the resin layer is 10 or more and 60 or less is excellent in impact resistance, is hard to break, especially glass Glass having a plate thickness of 4.0 mm when the plate thickness is 0.5 mm or more, the resin layer thickness is 1.5 mm or more, and the Shore A hardness of the resin layer is 10 or more and 60 or less. It has been found that it has a strength equal to or higher than that of a glass decorative plate made of only a plate.
(Exothermic test)
An exothermic test performed on the glass decorative plate of one embodiment of the present invention will be described below. Soda lime glass (ASA manufactured by Asahi Glass Co., Ltd., 300 mm long, 300 mm wide, two types of plate thickness 1.1 mm and 2.0 mm) as a glass plate, and adhesive (POS Seal Multi (registered trademark) manufactured by Cemedine) ) Is applied to the entire surface, and a chemically cross-linked polyethylene foamed resin (SUNPELICA (registered trademark) manufactured by Sanwa Kako Co., Ltd., having a thickness of 3 mm, a Shore A hardness of 30 to 32 and 25 to 27, is available in two types. .) Were bonded together to change the conditions of the thickness of the glass plate and the Shore A hardness of the resin layer, and five types of four decorative glass sheets were produced.

作製したガラス化粧板の表面に対向して電気ヒーターを設置し、電気ヒーターから50kW/mの輻射熱をガラス化粧板に照射し、ガラス化粧板の近くに点火プラグをスパークさせたまま設置してガラス化粧板の発熱量を測定する、発熱性試験を行なった。An electric heater is installed facing the surface of the produced glass decorative board, radiant heat of 50 kW / m 2 is applied to the glass decorative board from the electric heater, and the spark plug is installed in the vicinity of the glass decorative board. An exothermic test was conducted to measure the calorific value of the glass decorative board.

発熱性試験においては、加熱開始後20分間において、(1)総発熱量が8MJ/m以下であること、(2)最大発熱速度が10秒以上継続して200kW/mを超えないこと、および(3)防火上有害な裏面まで貫通する亀裂及び穴がないこと、の3つの評価を実施した。上記した実施形態の一例のすべてのガラス化粧板は、以上の3つの評価項目をクリアした。この結果、本実施例のガラス化粧板は、不燃性の高い建築材料であることがわかった。In the exothermic test, 20 minutes after the start of heating, (1) the total calorific value is 8 MJ / m 2 or less, and (2) the maximum heat generation rate does not exceed 200 kW / m 2 continuously for 10 seconds or more. And (3) three evaluations were made: no cracks and holes penetrating to the back side, which is harmful to fire prevention. All the glass decorative boards in the example of the embodiment described above cleared the above three evaluation items. As a result, it was found that the glass decorative board of this example is a highly incombustible building material.

本発明によれば、大きな衝撃が加えられても割れ難く、割れたとしても飛散しない化粧板を提供することができ、一般住宅用も含め、ビルディングや店舗等の各種用途の化粧版として幅広く使用でき、有用である。
なお、2015年2月18日に出願された日本特許出願2015−030004号の明細書、特許請求の範囲、図面および要約書の全内容をここに引用し、本発明の開示として取り入れるものである。
According to the present invention, it is possible to provide a decorative plate that is difficult to break even when a large impact is applied, and that does not scatter even if it is cracked, and is widely used as a decorative plate for various uses such as buildings and stores, including for general housing. Can and is useful.
The entire contents of the specification, claims, drawings and abstract of Japanese Patent Application No. 2015-030004 filed on February 18, 2015 are incorporated herein by reference. .

1 化粧板
2 ガラス板
3 樹脂層
4 意匠層
5 補強材
6 アンカー
DESCRIPTION OF SYMBOLS 1 Decorative plate 2 Glass plate 3 Resin layer 4 Design layer 5 Reinforcement material 6 Anchor

Claims (16)

意匠性を有する脆性の板状体と、前記板状体に積層された樹脂層とを有し、
前記樹脂層は、厚さが1.5mm以上であり、
前記樹脂層のショアA硬度は、10以上、60以下である、化粧板。
It has a brittle plate having design properties, and a resin layer laminated on the plate,
The resin layer has a thickness of 1.5 mm or more,
A decorative board having a Shore A hardness of 10 or more and 60 or less.
前記樹脂層は、発泡樹脂である、請求項1に記載の化粧板。   The decorative sheet according to claim 1, wherein the resin layer is a foamed resin. 前記樹脂層は、発泡ポリエチレン樹脂、発泡ウレタン樹脂または発泡ゴムである、請求項1に記載の化粧板。   The said resin layer is a decorative board of Claim 1 which is a foaming polyethylene resin, a foaming urethane resin, or foaming rubber. 前記樹脂層は、前記板状体の表面の80%以上に積層される、請求項1〜3のいずれか1項に記載の化粧板。   The said resin layer is a decorative board of any one of Claims 1-3 laminated | stacked on 80% or more of the surface of the said plate-shaped object. 前記板状体は、ガラス板である、請求項1〜4のいずれか1項に記載の化粧板。   The decorative plate according to any one of claims 1 to 4, wherein the plate-like body is a glass plate. 前記ガラス板は、板厚が0.5mm以上であり、
前記ガラス板と前記樹脂層とを合わせた総厚は、2.5mm以上、10mm以下である、請求項5に記載の化粧板。
The glass plate has a thickness of 0.5 mm or more,
The decorative board according to claim 5, wherein a total thickness of the glass plate and the resin layer is 2.5 mm or more and 10 mm or less.
前記ガラス板は、板厚が4mm以下である、請求項6に記載の化粧板。   The decorative sheet according to claim 6, wherein the glass plate has a thickness of 4 mm or less. 前記総厚は、8.0mm以下である、請求項6または7に記載の化粧板。   The decorative board according to claim 6 or 7, wherein the total thickness is 8.0 mm or less. 前記ガラス板は、前記意匠性が前記樹脂層との間に介在された意匠層によって付与される、請求項5〜8のいずれか1項に記載の化粧板。   The said glass plate is a decorative board of any one of Claims 5-8 with which the said design property is provided by the design layer interposed between the said resin layers. 前記ガラス板は、表層に圧縮応力層を有する強化ガラスである、請求項5〜9のいずれか1項に記載の化粧板。   The said glass plate is a decorative board of any one of Claims 5-9 which is tempered glass which has a compressive-stress layer in a surface layer. 前記ガラス板は、化学強化ガラスである、請求項5〜10のいずれか1項に記載の化粧板。   The said glass plate is a decorative board of any one of Claims 5-10 which is chemically strengthened glass. 前記板状体は、前記樹脂層とは反対側の表面に機能層を有する、請求項1〜11のいずれか1項に記載の化粧板。   The said plate-shaped body is a decorative board of any one of Claims 1-11 which has a functional layer in the surface on the opposite side to the said resin layer. 前記機能層は、防汚膜である、請求項12に記載の化粧板。   The decorative board according to claim 12, wherein the functional layer is an antifouling film. 前記機能層は、抗菌膜である、請求項12に記載の化粧板。   The decorative layer according to claim 12, wherein the functional layer is an antibacterial film. 前記板状体と前記樹脂層の周囲が補強材で覆われている、請求項1〜14のいずれか1項に記載の化粧板。   The decorative board according to any one of claims 1 to 14, wherein a periphery of the plate-like body and the resin layer is covered with a reinforcing material. 前記補強材は、アンカーを有しており、前記アンカーが前記樹脂層に差し込まれることにより前記補強材が固定されている、請求項15に記載の化粧板。   The decorative board according to claim 15, wherein the reinforcing material has an anchor, and the reinforcing material is fixed by inserting the anchor into the resin layer.
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