JPWO2015174300A1 - 増粘安定剤、及びそれを用いた増粘安定化組成物 - Google Patents
増粘安定剤、及びそれを用いた増粘安定化組成物 Download PDFInfo
- Publication number
- JPWO2015174300A1 JPWO2015174300A1 JP2016519215A JP2016519215A JPWO2015174300A1 JP WO2015174300 A1 JPWO2015174300 A1 JP WO2015174300A1 JP 2016519215 A JP2016519215 A JP 2016519215A JP 2016519215 A JP2016519215 A JP 2016519215A JP WO2015174300 A1 JPWO2015174300 A1 JP WO2015174300A1
- Authority
- JP
- Japan
- Prior art keywords
- thickening
- organic substance
- stabilizer
- formula
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000008719 thickening Effects 0.000 title claims abstract description 75
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000003381 stabilizer Substances 0.000 title claims abstract description 49
- 230000000087 stabilizing effect Effects 0.000 title claims abstract description 23
- 239000000126 substance Substances 0.000 claims abstract description 58
- 150000001875 compounds Chemical class 0.000 claims abstract description 47
- 230000009969 flowable effect Effects 0.000 claims abstract description 36
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 6
- 239000012530 fluid Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 7
- 230000006641 stabilisation Effects 0.000 claims description 4
- 238000011105 stabilization Methods 0.000 claims description 4
- 239000000499 gel Substances 0.000 abstract description 7
- 150000001412 amines Chemical class 0.000 description 41
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000011368 organic material Substances 0.000 description 19
- 239000002904 solvent Substances 0.000 description 19
- -1 aromatic carboxylic acids Chemical class 0.000 description 14
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 10
- 230000032683 aging Effects 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- ZPAKUZKMGJJMAA-UHFFFAOYSA-N Cyclohexane-1,2,4,5-tetracarboxylic acid Chemical compound OC(=O)C1CC(C(O)=O)C(C(O)=O)CC1C(O)=O ZPAKUZKMGJJMAA-UHFFFAOYSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- SADAOYKNIHVPHS-UHFFFAOYSA-N cyclohexane-1,1,2,2-tetracarbonyl chloride Chemical compound ClC(=O)C1(C(Cl)=O)CCCCC1(C(Cl)=O)C(Cl)=O SADAOYKNIHVPHS-UHFFFAOYSA-N 0.000 description 8
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- RZIPTXDCNDIINL-UHFFFAOYSA-N cyclohexane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCCC1(C(O)=O)C(O)=O RZIPTXDCNDIINL-UHFFFAOYSA-N 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 5
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 5
- BDNKZNFMNDZQMI-UHFFFAOYSA-N 1,3-diisopropylcarbodiimide Chemical compound CC(C)N=C=NC(C)C BDNKZNFMNDZQMI-UHFFFAOYSA-N 0.000 description 4
- NWDVCUXGELFJOC-UHFFFAOYSA-N 1-n,2-n,3-n-tris(2-methylcyclohexyl)propane-1,2,3-tricarboxamide Chemical compound CC1CCCCC1NC(=O)CC(C(=O)NC1C(CCCC1)C)CC(=O)NC1C(C)CCCC1 NWDVCUXGELFJOC-UHFFFAOYSA-N 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 150000001718 carbodiimides Chemical class 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- BGRWYRAHAFMIBJ-UHFFFAOYSA-N diisopropylcarbodiimide Natural products CC(C)NC(=O)NC(C)C BGRWYRAHAFMIBJ-UHFFFAOYSA-N 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 4
- 229940113162 oleylamide Drugs 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 3
- GTVGXWMIEPEVNL-UHFFFAOYSA-N 4,5-bis(2-ethylhexylcarbamoyl)cyclohexane-1,2-dicarboxylic acid Chemical compound C(C)C(CNC(=O)C1C(CC(C(C1)C(=O)O)C(=O)O)C(=O)NCC(CCCC)CC)CCCC GTVGXWMIEPEVNL-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 2
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004440 column chromatography Methods 0.000 description 2
- 238000011437 continuous method Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- BMFVGAAISNGQNM-UHFFFAOYSA-N isopentylamine Chemical compound CC(C)CCN BMFVGAAISNGQNM-UHFFFAOYSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 2
- 239000002600 sunflower oil Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DWNAUQMXBUXKSX-UHFFFAOYSA-N 1-N,2-N-bis(2-ethylhexyl)-4-N,5-N-dioctadecylcyclohexane-1,2,4,5-tetracarboxamide Chemical compound C(CCCCCCCCCCCCCCCCC)NC(=O)C1CC(C(CC1C(=O)NCCCCCCCCCCCCCCCCCC)C(=O)NCC(CCCC)CC)C(=O)NCC(CCCC)CC DWNAUQMXBUXKSX-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide Chemical compound CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- 125000006040 2-hexenyl group Chemical group 0.000 description 1
- FEUISMYEFPANSS-UHFFFAOYSA-N 2-methylcyclohexan-1-amine Chemical compound CC1CCCCC1N FEUISMYEFPANSS-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- 125000006042 4-hexenyl group Chemical group 0.000 description 1
- 125000006043 5-hexenyl group Chemical group 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
- OSJHTLOGFHGOEK-UHFFFAOYSA-N [2,2-dimethyl-3-(6-methylheptanoyloxy)propyl] 6-methylheptanoate Chemical compound CC(C)CCCCC(=O)OCC(C)(C)COC(=O)CCCCC(C)C OSJHTLOGFHGOEK-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000000480 butynyl group Chemical group [*]C#CC([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000005070 decynyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C#C* 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- DWMMZQMXUWUJME-UHFFFAOYSA-N hexadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC DWMMZQMXUWUJME-UHFFFAOYSA-N 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- 125000005980 hexynyl group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002634 lipophilic molecules Chemical class 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- SKTCDJAMAYNROS-UHFFFAOYSA-N methoxycyclopentane Chemical compound COC1CCCC1 SKTCDJAMAYNROS-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005069 octynyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C#C* 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229940100684 pentylamine Drugs 0.000 description 1
- 125000005981 pentynyl group Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 235000014438 salad dressings Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/57—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C233/58—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/007—Preparations for dry skin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
Abstract
本発明の化合物は、下記式(1)で表される。式中、R1、R2は互いに異なって、炭素数4以上の脂肪族炭化水素基である。nは1〜3の整数を示す。本発明の増粘安定剤は前記化合物を含む。
【化1】
Description
本発明の他の目的は、前記化合物を含有する増粘安定剤、前記増粘安定剤により増粘、ゲル化、又は安定化された増粘安定化組成物、及びその製造方法を提供することにある。
[1] 式(1)で表される化合物。
[2] 式(1)で表される化合物が式(1-1)〜(1-4)で表される化合物から選択される少なくとも1種の化合物である[1]に記載の化合物。
[3] 式中のR1、R2の一方が炭素数6〜10の分岐鎖状アルキル基であり、他方が炭素数12〜18の直鎖状アルキル基又は直鎖状アルケニル基である[1]又は[2]に記載の化合物。
[4] [1]〜[3]の何れか1つに記載の化合物を含む増粘安定剤。
[5] 増粘安定剤全量(100重量%)において式(1)で表される化合物の含有量(2種以上含有する場合はその総量)が60重量%以上である[4]に記載の増粘安定剤。
[6] [4]又は[5]に記載の増粘安定剤と流動性有機物質を含む増粘安定化組成物。
[7] 流動性有機物質が、レオメーターによる粘度[25℃、せん断速度10(1/s)における粘度(η)]が0.1Pa・s未満の有機物質である[6]に記載の増粘安定化組成物。
[8] 流動性有機物質が、炭化水素油、エーテル、ハロゲン化炭化水素、石油成分、動植物油、シリコーン油、エステル、芳香族カルボン酸、及びピリジンから選択される少なくとも1種の化合物である[6]又は[7]に記載の増粘安定化組成物。
[9] [4]又は[5]に記載の増粘安定剤と流動性有機物質を相溶させる工程を経て増粘安定化組成物を得る増粘安定化組成物の製造方法。
[10] [4]又は[5]に記載の増粘安定剤と流動性有機物質を混合して加温し、相溶させた後、冷却する工程を経て増粘安定化組成物を得る増粘安定化組成物の製造方法。
1.シクロヘキサンテトラカルボン酸を塩化チオニルと反応させてシクロヘキサンテトラカルボン酸テトラクロライドを得、得られたシクロヘキサンテトラカルボン酸テトラクロライドにアミン(1)(R1−NH2)及びアミン(2)(R2−NH2)(R1、R2は前記に同じ)を反応させる方法
2.シクロヘキサンテトラカルボン酸二無水物にアミン(1)(R1−NH2)を反応させてアミック酸を得、更にアミン(2)(R2−NH2)を縮合剤を用いて縮合させる方法
R−N=C=N−R’
上記式中、R、R’としては、例えば、ヘテロ原子含有置換基を有していてもよい、炭素数3〜8の直鎖状若しくは分岐鎖状のアルキル基、又は3〜8員のシクロアルキル基を挙げることができる。R、R’は同一であってもよく、異なっていてもよい。また、RとR’は互いに結合して上記式中の(−N=C=N−)基と共に環を形成していてもよい。
本発明の増粘安定剤は、上記式(1)で表される化合物を1種単独で、又は2種以上を組み合わせて含むことを特徴とする。
本発明の増粘安定化組成物は、上記増粘安定剤と流動性有機物質を含み、前記増粘安定剤により流動性有機物質が増粘、ゲル化、又は流動性有機物質を含有する組成物が均一に安定化されてなる組成物である。
ジムロート冷却管、窒素導入口、滴下ロート、熱電対を備えた100mL4つ口セパラブルフラスコにピリジン20mL、1,2,4,5−シクロヘキサンテトラカルボン酸−1,2:4,5−二無水物4.5g(0.02mol)、オレイルアミン10.6g(0.04mol)を仕込み、系内温度を50℃に設定して、3時間熟成した。
その後、2−エチルヘキシルアミン5.2g(0.04mol)、ジイソプロピルカルボジイミド5.5g(0.044mol)を仕込み、更に8時間熟成を行った。
その後、得られた粗液の低沸分をエバポレータにて除去し、メタノールで洗浄し、淡黄色の湿粉を得た。更に得られた湿粉についてCHCl3/CH3OH(70/30(v/v))で再結晶を行い、1,2,4,5−シクロヘキサンテトラカルボン酸ジ(2−エチルヘキシルアミド)ジ(オレイルアミド)[1,2,4,5−シクロヘキサンテトラカルボン酸−1,4−ジ(2−エチルヘキシルアミド)−2,5−ジ(オレイルアミド)と1,2,4,5−シクロヘキサンテトラカルボン酸−1,5−ジ(2−エチルヘキシルアミド)−2,4−ジ(オレイルアミド)の混合物]を11.9g得た(収率:61%)。反応生成物の構造は1H−NMRにより確認した。
1H-NMR(270MHz,CDCl3): δ0.81-0.88(m,18H), 1.0-1.4(m,68H), 1.40-1.45(m,2H), 1.76-1.99(m,8H), 2.50-3.10(m,8H), 3.30-3.45(m,4H), 5.21-5.40(m,4H), 6.31(s,4H)
ジムロート冷却管、窒素導入口、滴下ロート、熱電対を備えた100mL4つ口セパラブルフラスコにピリジン20mL、1,2,4,5−シクロヘキサンテトラカルボン酸−1,2:4,5−二無水物4.5g(0.02mol)、ステアリルアミン10.7g(0.04mol)を仕込み、系内温度を50℃に設定して、3時間熟成した。
その後、2−エチルヘキシルアミン5.2g(0.04mol)、ジイソプロピルカルボジイミド5.5g(0.044mol)を仕込み、更に8時間熟成を行った。
その後、得られた粗液の低沸分をエバポレータにて除去し、メタノールで洗浄し、淡黄色の湿粉を得た。更に得られた湿粉についてCHCl3/CH3OH(70/30(v/v))で再結晶を行い、1,2,4,5−シクロヘキサンテトラカルボン酸ジ(2−エチルヘキシルアミド)ジ(ステアリルアミド)[1,2,4,5−シクロヘキサンテトラカルボン酸−1,4−ジ(2−エチルヘキシルアミド)−2,5−ジ(ステアリルアミド)と1,2,4,5−シクロヘキサンテトラカルボン酸−1,5−ジ(2−エチルヘキシルアミド)−2,4−ジ(ステアリルアミド)の混合物]を11.2g得た(収率:57%)。反応生成物の構造は1H−NMRにより確認した。
1H-NMR(270MHz,CDCl3):δ 0.81-0.88(m,18H), 1.0-1.4(m,84H), 1.40-1.45(m,2H), 2.57-2.77(m,8H), 2.85-3.12(m,4H), 6.31(s,4H)
ジムロート冷却管、窒素導入口、滴下ロート、熱電対を備えた100mL4つ口セパラブルフラスコにピリジン20mL、1,2,3−プロパントリカルボン酸2.97g(0.017mol)、ジイソプロピルカルボジイミド7.0g(0.056mol)を仕込み、系内温度を50℃に設定して、3時間熟成した。
更に2−メチルシクロヘキシルアミン5.7g(0.051mol)を仕込み8時間熟成を行った。
その後、得られた粗液の低沸分をエバポレータにて除去し、メタノールで洗浄し、淡黄色の湿粉を得た。更に得られた湿粉についてアセトンで洗浄し、1,2,3−プロパントリカルボン酸トリス(2−メチルシクロヘキシルアミド)を4.7g得た(収率:61%)。
表1に示す各種流動性有機物質(流動パラフィン、イソドデカン、オクタン酸セチル:何れも沸点は100℃以上)を試験管に1cm3ずつ秤とり、これに上記実施例1、2、及び比較例1で得られた増粘安定剤をそれぞれ10mg加えて混合し、100℃で加熱撹拌して流動性有機物質と増粘安定剤を相溶させ、25℃まで冷却して増粘安定化組成物を得た。
得られた増粘安定化組成物の粘度を測定し、各種流動性有機物質の粘度が何倍に増粘されたかを確認して下記基準に従って増粘性を評価し、これらの溶媒に対する増粘性評価結果が全て4以上の場合は増粘効果良好「○」、これらの溶媒に対する増粘性評価結果に3以下が含まれる場合は増粘効果不良「×」とした。
<評価基準>
1: 1.0倍を超え、2.0倍以下
2: 2.0倍を超え、4.8倍以下
3: 4.8倍を超え、10倍以下
4: 10倍を超え、50倍以下
5: 50倍を超え、100倍以下
6: 100倍を超え、10000倍以下
Claims (4)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014098783 | 2014-05-12 | ||
JP2014098783 | 2014-05-12 | ||
PCT/JP2015/063103 WO2015174300A1 (ja) | 2014-05-12 | 2015-05-01 | 増粘安定剤、及びそれを用いた増粘安定化組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2015174300A1 true JPWO2015174300A1 (ja) | 2017-04-20 |
JP6558705B2 JP6558705B2 (ja) | 2019-08-14 |
Family
ID=54479841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016519215A Active JP6558705B2 (ja) | 2014-05-12 | 2015-05-01 | 増粘安定剤、及びそれを用いた増粘安定化組成物 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10065923B2 (ja) |
EP (1) | EP3144294B1 (ja) |
JP (1) | JP6558705B2 (ja) |
KR (1) | KR102390771B1 (ja) |
CN (1) | CN106458858B (ja) |
WO (1) | WO2015174300A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6620349B2 (ja) * | 2014-07-07 | 2019-12-18 | 株式会社ダイセル | 増粘安定剤、及びそれを用いた増粘安定化組成物 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10273477A (ja) * | 1997-01-29 | 1998-10-13 | Kenji Hanabusa | シクロヘキサントリカルボキサミド誘導体及びそれからなる増粘・ゲル化剤 |
JP2008024614A (ja) * | 2006-07-19 | 2008-02-07 | New Japan Chem Co Ltd | ポリカルボン酸ポリ(アルキル置換シクロヘキシルアミド)の製造方法 |
JP2009155592A (ja) * | 2007-12-28 | 2009-07-16 | New Japan Chem Co Ltd | 新規な有機ゲル化剤 |
WO2013040718A1 (en) * | 2011-09-23 | 2013-03-28 | Synoil Fluids Holdings Inc. | Pyromellitamide gelling agents |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2584262B2 (ja) | 1987-12-21 | 1997-02-26 | 株式会社資生堂 | 透明性基剤及びそれを用いた化粧料 |
CA2884390A1 (en) | 2012-09-24 | 2014-03-27 | Synoil Fluids Holdings Inc. | Amide branched aromatic gelling agent enhancers and breakers |
JP6620349B2 (ja) * | 2014-07-07 | 2019-12-18 | 株式会社ダイセル | 増粘安定剤、及びそれを用いた増粘安定化組成物 |
-
2015
- 2015-05-01 CN CN201580022720.0A patent/CN106458858B/zh active Active
- 2015-05-01 WO PCT/JP2015/063103 patent/WO2015174300A1/ja active Application Filing
- 2015-05-01 EP EP15792352.5A patent/EP3144294B1/en active Active
- 2015-05-01 KR KR1020167033045A patent/KR102390771B1/ko active IP Right Grant
- 2015-05-01 JP JP2016519215A patent/JP6558705B2/ja active Active
- 2015-05-01 US US15/310,146 patent/US10065923B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10273477A (ja) * | 1997-01-29 | 1998-10-13 | Kenji Hanabusa | シクロヘキサントリカルボキサミド誘導体及びそれからなる増粘・ゲル化剤 |
JP2008024614A (ja) * | 2006-07-19 | 2008-02-07 | New Japan Chem Co Ltd | ポリカルボン酸ポリ(アルキル置換シクロヘキシルアミド)の製造方法 |
JP2009155592A (ja) * | 2007-12-28 | 2009-07-16 | New Japan Chem Co Ltd | 新規な有機ゲル化剤 |
WO2013040718A1 (en) * | 2011-09-23 | 2013-03-28 | Synoil Fluids Holdings Inc. | Pyromellitamide gelling agents |
Also Published As
Publication number | Publication date |
---|---|
CN106458858B (zh) | 2019-09-24 |
EP3144294A1 (en) | 2017-03-22 |
WO2015174300A1 (ja) | 2015-11-19 |
US20170158619A1 (en) | 2017-06-08 |
KR102390771B1 (ko) | 2022-04-25 |
KR20170009879A (ko) | 2017-01-25 |
EP3144294B1 (en) | 2019-05-01 |
CN106458858A (zh) | 2017-02-22 |
EP3144294A4 (en) | 2017-12-20 |
JP6558705B2 (ja) | 2019-08-14 |
US10065923B2 (en) | 2018-09-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6588338B2 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
JP6312669B2 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
US9464036B2 (en) | Thickening stabilizer, and thickening/stabilizing composition using the same | |
JP6620349B2 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
JP6464428B2 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
WO2018163989A1 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
JP6558705B2 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
KR102454158B1 (ko) | 증점 안정제 | |
TWI760294B (zh) | 增黏安定劑、及使用其之增黏安定化組成物 | |
JP6655025B2 (ja) | 増粘安定剤、及びそれを用いた増粘安定化組成物 | |
TWI662016B (zh) | 增黏安定劑、及使用其之增黏安定化組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20161031 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180416 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20180416 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190312 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190513 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190625 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190705 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6558705 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |