JPWO2014109068A1 - Unsaturated polyester resin composition for LED reflector and granule, tablet, LED reflector, surface mount LED light emitting device, LED lighting using the same - Google Patents

Abstract

Small discoloration due to heat deterioration and UV deterioration, excellent heat resistance / UV discoloration resistance, LED lamps using this have a long life, are relatively inexpensive, and have excellent material storage stability, handling properties, and processability. Provided are a general-purpose unsaturated polyester resin composition for LED reflectors and granular materials, tablets, LED reflectors, surface-mounted LED light-emitting devices, and LED lightings using the same. An unsaturated polyester resin composition for an LED reflector containing an unsaturated polyester resin, a polymerization initiator, an inorganic filler, a white pigment and a reinforcing material, wherein the unsaturated polyester resin composition comprises a (meth) acrylic group, an alkyl A (meth) acryl-modified silicone alkoxy oligomer having a group and an alkoxy group is contained in an amount of 1 to 15 parts by mass with respect to 100 parts by mass of the unsaturated polyester resin.

Description

  The present invention relates to an unsaturated polyester resin composition for LED reflectors and granular materials, tablets, LED reflectors, surface-mounted LED light-emitting devices, and LED lighting using the same.

  In recent years, it has become a problem how long the initial luminance of an LED can be maintained in an LED whose use is rapidly expanding.

  The factor of the LED brightness decrease is a decrease in reflectance due to thermal discoloration of the LED reflectors formed, and the adoption of a material with less discoloration due to heat is a factor in extending the life of the LED.

  DESCRIPTION OF RELATED ART Conventionally, the LED reflector made from ceramics with favorable heat-resistant discoloration property is known (refer patent document 1). However, ceramics have limitations in workability and are expensive, and thus are not suitable as general-purpose LED reflectors.

  Therefore, as a general-purpose reflector for an LED as a light source that replaces a fluorescent lamp or an incandescent lamp, nylon or polyamide resin that has been conventionally known for illumination is used (see Patent Documents 2 to 4). These have relatively good heat resistance and are inexpensive.

  However, LED reflectors made of heat-resistant nylon or polyamide resin have the disadvantage that the discoloration due to heat is large and the life of the LED lamp is short.

  In such a background, the present inventors have proposed an unsaturated polyester resin composition that is superior in heat discoloration than nylon and the like (see Patent Document 5).

WO2006 / 013899 JP-A-6-200153 JP 2002-374007 A JP 2010-1000068 A2 Japanese Patent No. 4844699 JP 2008-50539 A

  However, with the recent increase in power of LEDs, it is required to further improve the heat discoloration.

  Patent Document 6 describes a composition in which an unsaturated polyester resin and a reactive silicone oil in which an acrylic acid-based organic acid is introduced as a functional group are blended. However, this composition is used as a molding material for electronic parts such as terminals, coil bobbins, and the like for sealing electronic components such as capacitors, coils, resistors, etc. Not considered.

  The present invention has been made in view of the circumstances as described above, has a small discoloration due to thermal deterioration and UV deterioration, has excellent heat resistance and UV discoloration resistance, and an LED lamp using this has a long life, General-purpose unsaturated polyester resin composition for LED reflectors, which is excellent in workability such as storage stability, handling properties, burr processing and mold release properties, and granular materials and tablets using the same It is an object to provide an LED reflector, a surface-mounted LED light-emitting device, and LED lighting.

  In order to solve the above-mentioned problems, the unsaturated polyester resin composition for LED reflector of the present invention is an unsaturated polyester resin for LED reflector containing an unsaturated polyester resin, a polymerization initiator, an inorganic filler, a white pigment and a reinforcing material. It is a resin composition, Comprising: The said unsaturated polyester resin composition is a (meth) acryl group, an alkyl group, and the (meth) acryl modified silicone alkoxy oligomer which has an alkoxy group with respect to 100 mass parts of said unsaturated polyester resins. It is characterized by containing in the range of 1-15 mass parts.

  In the unsaturated polyester resin composition for LED reflector, the (meth) acryl-modified silicone alkoxy oligomer is represented by the following formula (I):

(Wherein, OR ¹ represents the alkoxy group having 1 to 3 carbon atoms, R ² represents the (meth) acryl group or the alkyl group having 1 to 3 carbon atoms, and n represents an integer). It is preferable that it is 10-100 mm < ² > / s (at 25 degreeC), the amount of alkoxy groups is 10-40 mass%, and (meth) acryl equivalent is 180-320 g / mol.

  In the unsaturated polyester resin composition for LED reflector, the unsaturated polyester resin is 10 to 50% by mass with respect to the total amount of the resin composition, and the total amount of the inorganic filler and the white pigment is The ratio of the white pigment in the total amount of the inorganic filler and the white pigment is at least 10% by mass with respect to the total amount of the resin composition. Is preferred.

  In the unsaturated polyester resin composition for an LED reflector, the unsaturated polyester resin is preferably a mixture of an unsaturated alkyd resin and a crosslinking agent.

  In this unsaturated polyester resin composition for LED reflectors, the reflectivity after 1000 hours of UV irradiation treatment in a 140 ° C. environment of the cured product obtained by curing the unsaturated polyester resin composition for LED reflectors is 80% or more. Is preferred.

  The granular material for LED reflector of the present invention is characterized in that the unsaturated alkyd resin is formed from the unsaturated polyester resin composition for LED reflector, which starts to soften at 50 ° C. or higher.

  The tablet for LED reflectors of the present invention is characterized in that the unsaturated alkyd resin is formed from the unsaturated polyester resin composition for LED reflectors that starts to soften at 50 ° C. or higher.

  The LED reflector of the present invention is formed by molding the granular material for an LED reflector or the tablet for an LED reflector.

The surface-mounted LED light-emitting device of the present invention includes the LED reflector. The LED illumination of the present invention includes the surface-mounted LED light-emitting device.

  According to the present invention, when the LED reflector is used, the color change due to heat deterioration / UV deterioration is small, the heat resistance / UV discoloration resistance is excellent, the LED light-emitting device has a long life, can be injection molded together with transfer molding, It is possible to obtain a resin composition for an LED reflector that has excellent processability such as good mold releasability from the mold and can be subjected not only to blasting but also to alkali treatment as burr treatment.

1 is a cross-sectional view schematically showing an embodiment of a surface-mounted LED light-emitting device of the present invention. It is a top view of the surface mount type LED light-emitting device of FIG. It is (a) front photograph, (b) spectral distribution, and (c) light distribution curve of transparent mercury lamp 400 type H400. It is a graph which shows the time-dependent change (wavelength: 460 nm) of the reflectance under UV irradiation of an LED reflector.

  The present invention is described in detail below.

  The unsaturated polyester resin composition for LED reflectors of the present invention uses an unsaturated alkyd resin that starts softening at 50 ° C. or higher as the unsaturated polyester resin.

  In addition, the temperature which starts softening of unsaturated alkyd resin can confirm softening when it heats gradually from about room temperature about solid unsaturated alkyd resin visually or visually.

  The unsaturated polyester resin composition for an LED reflector of the present invention is used by molding it into a granular material or tablet, but in actual implementation, it is necessary to store and transport the granular material or tablet. At the time of this storage / transportation, in a general storage / transportation mode, there is a possibility that the particulate matter and the tablet are exposed to the environment up to 50 ° C. Accordingly, when the unsaturated alkyd resin starts to soften at a temperature lower than 50 ° C., the storage stability of the granular materials and tablets deteriorates. Therefore, it is desirable that the unsaturated alkyd resin starts to soften at 50 ° C. or higher.

  The unsaturated polyester resin composition for LED reflectors of the present invention is a dry unsaturated polyester resin composition. Here, the dry type is a solid in a temperature range of 30 ° C. or lower, and is pulverized using a pulverizer and then processed into a pulverized processed product classified by a predetermined sieve or a pellet such as a pellet processed by extrusion using a pelletizer. Means you can. Here, the pulverized product is also called a granule or granule.

  In addition, although the granular material for LED reflectors processed from the unsaturated polyester resin composition for LED reflectors of the present invention into a pulverized processed product (granular product, granule) or a pellet can be most suitably used for injection molding. It can also be used for transfer molding. This point is greatly different from thermoplastic resin compositions such as nylon that can only be injection molded and thermosetting resin compositions such as epoxy resin that can only be transfer molded.

  Such a granular material for an LED reflector is excellent in processability, for example, by forming into a granular material, in addition to transfer molding, injection molding is possible. And storage stability can be improved by using the unsaturated polyester resin composition for LED reflectors in which unsaturated alkyd resin starts softening at 50 degreeC or more.

  Moreover, the unsaturated polyester resin composition for LED reflector of this invention can also be made into the form of the normal tablet used for melt-heat-molding methods, such as transfer molding.

  Such a tablet for an LED reflector of the present invention enables transfer molding in which bubbles are difficult to enter.

  The unsaturated polyester resin is obtained by mixing an unsaturated alkyd resin and a crosslinking agent such as a copolymerizable monomer. The copolymerizable monomer is mixed with the resin together with other mixtures at the time of preparing the resin composition, but may be mixed with the resin before preparing the resin composition.

  The unsaturated alkyd resin is obtained by subjecting unsaturated polybasic acids, saturated polybasic acids and glycols to a dehydration condensation reaction.

  Examples of unsaturated polybasic acids include maleic anhydride, fumaric acid, itaconic acid, citraconic acid and the like.

  Saturated polybasic acids include phthalic anhydride, isophthalic acid, terephthalic acid, adipic acid, sebacic acid, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, endomethylenetetrahydrophthalic anhydride, het acid, tetrabromophthalic anhydride, etc. Can be mentioned.

  As glycols, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, neopentyl glycol, 1,3-butanediol, 1,6-hexanediol, hydrogenated bisphenol A, bisphenol A propylene oxide compound, dibromoneopentyl A glycol etc. can be mentioned.

  In the present invention, among the unsaturated alkyd resins, an unsaturated alkyd resin having a melt viscosity of 1000 to 2500 cP can be preferably used, and in particular, an isophthalic acid-based unsaturated alkyd resin and a terephthalic acid-based unsaturated alkyd resin are preferably used. be able to.

  By using these unsaturated alkyd resins, an unsaturated polyester resin composition for LED reflectors excellent in moldability and heat discoloration can be obtained.

  As the crosslinking agent mixed with the unsaturated alkyd resin, for example, vinyl copolymerizable monomers such as styrene, vinyltoluene, divinylbenzene, α-methylstyrene, methyl methacrylate, and vinyl acetate can be used.

  Further, a copolymerizable monomer such as diallyl phthalate, triallyl cyanurate, diallyl tetrabromophthalate, phenoxyethyl acrylate, 2-hydroxyethyl acrylate, 1-6 hexanediol diacrylate can be used. Furthermore, these prepolymers can be used.

  In the present invention, diallyl phthalate prepolymer, diallyl phthalate monomer, and styrene monomer can be particularly preferably used. Moreover, these crosslinking agents may be used individually by 1 type, and may be used in combination of 2 or more types.

  The ratio of the unsaturated alkyd resin and the crosslinking agent in the unsaturated polyester resin is preferably in the range of 99/1 to 50/50 by mass ratio. In addition, when using a monomer as a crosslinking agent, since it will not become a dry-type unsaturated polyester resin composition of a normal temperature solid when the compounding quantity of a monomer increases, the compounding quantity of a monomer shall be 10 mass parts or less in 100 mass parts of unsaturated polyester resins. Is preferred.

  The blending amount of the unsaturated polyester resin is preferably in the range of 10 to 50% by mass with respect to the total amount of the unsaturated polyester resin composition.

  The unsaturated polyester resin composition for an LED reflector of the present invention is blended with a (meth) acryl-modified silicone alkoxy oligomer having a (meth) acryl group, an alkyl group, and an alkoxy group.

  By compounding this (meth) acryl-modified silicone alkoxy oligomer, a chemically stable siloxane skeleton is introduced into the network structure of the unsaturated polyester resin, and functions as a crosslinking point for crosslinking with the unsaturated polyester resin. Thus, heat discoloration resistance and UV discoloration resistance can be improved.

  This (meth) acrylic-modified silicone alkoxy oligomer has water repellency because it has an organic substituent that is not readily compatible with water. Thereby, alkaline water immersion is suppressed, and not only the blast method but also the alkali treatment can be performed as the burr treatment.

The (meth) acryl-modified silicone alkoxy oligomer is preferably represented by the formula (I). In the formula (I), OR ¹ represents an alkoxy group having 1 to 3 carbon atoms, R ² represents a (meth) acryl group or an alkyl group having 1 to 3 carbon atoms, and n represents an integer. This (meth) acryl-modified silicone alkoxy The oligomer has a viscosity of 10 to 100 mm ² / s (at 25 ° C.), an alkoxy group amount of 10 to 40% by mass, and a (meth) acryl equivalent of 180 to 320 g / mol.

  The content of the (meth) acryl-modified silicone alkoxy oligomer is preferably in the range of 1 to 15 parts by mass with respect to 100 parts by mass of the unsaturated polyester resin. When the content of the (meth) acryl-modified silicone alkoxy oligomer is 1 part by mass or more, the heat discoloration resistance and the UV discoloration resistance can be improved, and the content of the (meth) acryl-modified silicone alkoxy oligomer is 15 parts by mass or less. Then, the crosslinking density reaches the limit and does not become difficult to crosslink, and a decrease in moldability due to the remaining (meth) acryl-modified silicone alkoxy oligomer can be suppressed.

  In the unsaturated polyester resin composition for LED reflectors of the present invention, a heat-decomposable organic peroxide usually used in an unsaturated polyester resin composition can be used as a polymerization initiator.

  These include ketone peroxides, diacyl peroxides, percarbonates, and the like. These may be used alone or in combination of two or more.

  Specifically, dicumyl peroxide which is an organic peroxide having a 10-hour half-life temperature of 100 ° C. or higher can be suitably used.

  In the present invention, at least one selected from the group consisting of titanium oxide, barium titanate, strontium titanate, aluminum oxide, magnesium oxide, zinc oxide, barium sulfate, magnesium carbonate, and barium carbonate is blended as a white pigment.

  In the present invention, among these white pigments, titanium oxide, aluminum oxide, and barium titanate can be preferably used.

  Examples of the titanium oxide include anatase type titanium oxide, rutile type titanium oxide, and brucite type titanium oxide. Among these, rutile type titanium oxide excellent in thermal stability can be preferably used.

  Aluminum oxide and barium titanate can be used without particular limitation as long as they are known, for example.

  The average particle diameter of the white pigment is preferably 2.0 μm or less, more preferably 0.1 to 1.0 μm, and still more preferably 0.3 to 0.7 μm. The average particle diameter can be measured by a laser diffraction scattering method or the like.

  In this invention, the compounding quantity of a white pigment becomes like this. Preferably it is 100 mass parts or more with respect to 100 mass parts of unsaturated polyester resins, More preferably, it is the range of 100-300 mass parts.

  By making the compounding quantity of a white pigment into this range, it can be set as the LED reflector which is excellent in heat-resistant discoloration property and has a high reflectance with white.

  In the present invention, at least one selected from the group consisting of silica, aluminum hydroxide, aluminum oxide, magnesium oxide, barium sulfate, magnesium carbonate, and barium carbonate is blended as the inorganic filler.

  In the present invention, silica can be particularly preferably used among these inorganic fillers, and examples thereof include fused silica powder, spherical silica powder, crushed silica powder, and crystalline silica powder. .

  The average particle size of the inorganic filler is preferably 250 μm or less, more preferably in the range of 10 to 100 μm. By making an average particle diameter into this range, it can be set as the unsaturated polyester resin composition for LED reflectors which was excellent in favorable moldability, heat discoloration resistance, and moisture resistance. The average particle diameter can be measured by a laser diffraction scattering method or the like.

  In this invention, the compounding quantity of an inorganic filler becomes like this. Preferably it is 50 mass parts or more with respect to 100 mass parts of unsaturated polyester resins, More preferably, it is the range of 50-250 mass parts.

  By setting it as this blending range, it is possible to obtain an unsaturated polyester resin composition for LED reflectors having excellent moldability, and by molding using this, an LED having excellent heat discoloration and high reflectance. A reflector can be obtained.

  The total amount of the white pigment and the inorganic filler is preferably 40 to 90% by mass, more preferably 50 to 72% by mass, based on the total amount of the unsaturated polyester resin composition.

  The proportion of the white pigment in the total amount of the white pigment and the inorganic filler is preferably 10% by mass or more, more preferably in the range of 40 to 85% by mass.

  Furthermore, the total amount of the blending amount when the white pigment and the inorganic filler are combined is preferably 500 parts by mass or less, more preferably in the range of 100 to 400 parts by mass with respect to 100 parts by mass of the unsaturated polyester resin. By setting the total amount of the white pigment and the inorganic filler to be in this range, it is possible to obtain an appropriate resin fluidity and to obtain good moldability.

  In addition, since white pigments and inorganic fillers are more likely to be aggregated or oil-absorbed as they become finer and filling may be difficult, the surface may be surface-treated with a fatty acid or a coupling agent.

  In addition, the unsaturated polyester resin composition for LED reflectors of the present invention can be appropriately mixed with other inorganic fillers as long as the fluidity of the resin composition and the reflectance when used as an LED reflector are not impaired. it can.

  Examples of these include oxides and hydrates thereof, inorganic foam particles, and hollow particles such as silica balloons.

  As the reinforcing material used in the present invention, any reinforcing material can be used without limitation as long as it is used as a reinforcing material for unsaturated polyester resin compositions used for FRP such as BMC and SMC.

  Examples of these include glass fiber, vinylon fiber, aramid fiber, polyester fiber, wollastonite, potassium titanate whisker, etc. Among these, glass fiber can be preferably used.

  As glass fibers, silicate glass, E glass (alkali-free glass for electricity), C glass (alkali glass for chemistry), A glass (acid-resistant glass), S glass (high strength glass) Glass fibers such as these can be used, and those made of long fibers (roving) and short fibers (chopped strands) can be used.

  Furthermore, what performed surface treatment with respect to these glass fibers can also be used.

  In the present invention, in particular, E glass fibers having a fiber diameter of 10 to 15 μm are converged with a converging agent such as vinyl acetate, and after surface treatment with a silane coupling agent, chopped strands cut to 3 to 6 mm are preferably used. Can be used.

  The compounding amount of the reinforcing material is preferably 10 to 200 parts by mass, more preferably 10 to 100 parts by mass, and further preferably 20 to 80 parts by mass with respect to 100 parts by mass of the unsaturated polyester resin.

  By using the reinforcing material under these conditions, it is possible to obtain an unsaturated polyester resin composition for an LED reflector that has excellent strength characteristics, suppresses curing shrinkage, and has excellent reflectance.

  In the present invention, a release agent may be used as necessary. As the release agent, waxes such as fatty acids, fatty acid metal salts, and minerals that are generally used in thermosetting resins can be used. A thing can be used suitably.

  Specific examples of these include stearic acid, zinc stearate, aluminum stearate, calcium stearate, magnesium stearate and the like. These mold release agents may be used independently and may use 2 or more types together.

  In the present invention, in addition to these blending components, a curing catalyst and a polymerization inhibitor for adjusting the curing conditions of the unsaturated polyester resin, a colorant, a thickener, other organic additives, inorganic additives, etc. It can mix | blend suitably as needed.

  The unsaturated polyester resin composition for an LED reflector of the present invention is blended with each component and mixed sufficiently uniformly using a mixer, a blender or the like, and then kneaded with a pressure kneader, a heat roll, an extruder, or the like. Next, LED reflector pellets, pulverized products (granules, granules), tablets, and the like can be produced by pulverizing and sizing.

  The polymerization initiator is preferably used as a masterbatch with higher safety against fire and explosion.

  Since the unsaturated polyester resin composition for LED reflector of the present invention by such a blending is a dry unsaturated polyester resin composition, by using a liquid as a blending component, the dry unsaturated polyester resin composition of the present invention can be used. Unlike wet unsaturated polyester resin compositions having viscosity other than dry conditions, epoxy resin compositions, etc., they are excellent in storage stability and handling properties.

  Moreover, the LED reflector using this can be shape | molded with the shaping | molding method of various conventional thermosetting resin compositions, The discoloration by heat deterioration and UV deterioration is small, and the lifetime of LED lighting fixtures, such as an LED bulb, is long. An inexpensive LED reflector can be manufactured.

  In addition, the unsaturated polyester resin composition for LED reflectors of the present invention is dry and has good thermal stability at the time of melting, and therefore, as a molding method, a melting method such as an injection molding method, an injection compression molding method, a transfer molding method, etc. A thermoforming method can be suitably used.

  Among these, the injection molding method using an injection molding machine is particularly suitable, and the molding time can be further shortened by the injection molding method, and it becomes possible to manufacture an LED reflector having a complicated shape.

  In addition, in the case of a wet unsaturated polyester resin composition having a viscosity other than the dry conditions of the present invention, since it cannot be formed into a normal pellet form, handling properties are poor, and when molding with an injection molding machine However, it is necessary to provide a hopper with equipment such as a plunger, which is expensive to manufacture.

  On the other hand, the unsaturated polyester resin composition for LED reflectors of the present invention is excellent in storage stability because it is in the form of a dry pellet, and can be molded simply by feeding from the hopper of an injection molding machine, so that it is easy to handle. Are better. Further, the manufacturing cost can be kept low.

  Moreover, although it is a thermosetting resin, a burr | flash generate | occur | produces on the flame | frame of the shape | molded LED reflector, The burr | flash can be easily removed with the unsaturated polyester resin composition for LED reflectors of this invention.

The removal of the generated burrs can be performed by, for example, a known method, and among them, it is preferable to perform (1) blast treatment or (2) alkali treatment.
(1) Blasting treatment As the blasting treatment, a blasting method usually used for deburring can be used, and examples thereof include shot blasting, sand blasting, and glass bead blasting.
(2) Alkali treatment The alkali treatment can be performed, for example, by a method of treating the end of the molded body using a mini-velocity gun or the like. For the alkali treatment, an alkaline aqueous solution having a concentration of about 5% can be used. Usually, the resin is corroded (yellowed) by an aqueous alkaline solution and the initial luminous flux tends to decrease. However, in the present invention, since the (meth) acryl-modified silicone alkoxy oligomer is blended, the resin is given water repellency. In this way, the entry of alkali can be suppressed, and the decrease in the initial luminous flux can be suppressed.

  The LED reflector of the present invention can be suitably used for a surface-mounted LED light-emitting device. Examples of the surface-mounted LED light-emitting device include a structure exemplified in Japanese Patent No. 4893874.

  FIG. 1 is a cross-sectional view schematically showing an embodiment of a surface-mounted LED light-emitting device of the present invention, and FIG. 2 is a plan view. FIG. 1 shows an AA cross section of FIG.

  The surface-mount LED light-emitting device includes a light-emitting element 10, a first resin body 40 on which the light-emitting element 10 is placed, and a second resin body 50 that covers the light-emitting element 10.

  The 1st resin body 40 consists of an LED reflector which shape | molded the above-mentioned granular material for LED reflectors by the unsaturated polyester resin composition for LED reflectors of this invention. A first lead 20 for mounting the light emitting element 10 and a second lead 30 electrically connected to the light emitting element 10 are integrally formed.

  The light emitting element 10 has a pair of positive and negative first electrodes 11 and second electrodes 12 on the same surface side. Here, an electrode having a pair of positive and negative electrodes on the same surface will be described, but an electrode having a pair of positive and negative electrodes from the upper surface and the lower surface of the light emitting element 10 can also be used. In this case, the electrode on the lower surface of the light emitting element 10 is electrically connected to the first lead 20 using an electrically conductive die bond member without using a wire.

  The first lead 20 has a first inner lead portion 20a and a first outer lead portion 20b. The light emitting element 10 is mounted on the first inner lead portion 20a via a die bond member. The first inner lead portion 20 a is electrically connected to the first electrode 11 of the light emitting element 10 via the wire 60. The first outer lead portion 20 b is exposed from the first resin body 40. The first lead 20 has a portion exposed on the back surface side of the first resin body 40 except for the case where the first outer lead portion 20 b is provided outside the side surface of the first resin body 40. 1 may be referred to as one outer lead portion 20b. That is, the first outer lead portion 20b may be a portion that is electrically connected to the external electrode. Since the first lead 20 is connected to the external electrode, a metal member is used.

  The second lead 30 has a second inner lead portion 30a and a second outer lead portion 30b. The second inner lead portion 30 a is electrically connected to the second electrode 12 of the light emitting element 10 via the wire 60. The second outer lead portion 30 b is exposed from the first resin body 40. The second lead 30 not only has the second outer lead portion 30b on the outer side surface of the second resin body 50, but also the portion exposed on the back surface side of the second resin body 50. It may be called the 2nd outer lead part 30b. That is, the second outer lead portion 30b may be a portion that is electrically connected to the external electrode. The second lead 30 uses a metal member to connect to the external electrode. Insulating members 90 are provided in the vicinity of the first lead 20 and the second lead 30 on the back surface side so that the first lead 20 and the second lead 30 are not short-circuited.

  The first resin body 40 has a recess 40c having a bottom surface portion 40a and a side surface portion 40b. The first inner lead portion 20 a of the first lead 20 is exposed from the bottom surface portion 40 a of the concave portion 40 c of the first resin body 40. The light emitting element 10 is mounted on the exposed portion via a die bond member. The first resin body 40 can be molded by injection molding or the like. The first resin body 40 uses the aforementioned unsaturated polyester resin composition for an LED reflector, and contains a white pigment 70 such as titanium oxide. The opening of the recess 40c has a wider opening than the bottom surface 40a, and the side surface 40b is preferably provided with an inclination. A resin insulating portion 45 that insulates the first lead 20 and the second lead 30 is provided on the bottom surface portion 40a of the recess 40c.

  The 2nd resin body 50 is arrange | positioned in the recessed part 40c so that the light emitting element 10 may be coat | covered. The second resin body 50 uses a thermosetting resin. The second resin body 50 contains a fluorescent material 80. Since the fluorescent material 80 uses a material having a specific gravity greater than that of the second resin body 50, the fluorescent material 80 settles on the bottom surface portion 40a side of the recess 40c.

  In the following description, the side on which the light emitting element 10 is placed is referred to as a main surface side for convenience, and the opposite side is referred to as a back surface side.

  The size of the light emitting element 10 can be mounted in a size of □ 1 mm, and a size of □ 600 μm, □ 320 μm, etc. can be mounted.

  The 1st resin body 40 has the recessed part 40c which has the bottom face part 40a and the side part 40b. The first resin body 40 is integrally formed with the first lead 20 and the second lead 30 that extend outward from the bottom surface portion 40a of the recess 40c. The first inner lead portion 20a of the first lead 20 forms a part of the bottom surface portion 40a of the recess 40c. The second inner lead portion 30a of the second lead 30 forms a part of the bottom surface portion 40a of the recess 40c and is separated from the first inner lead portion 20a by a predetermined distance. The light emitting element 10 is mounted on the first inner lead portion 20a corresponding to the bottom surface portion 40a of the recess 40c. The first inner lead portion 20a corresponding to the bottom surface portion 40a of the recess 40c, the second inner lead portion 30a corresponding to the bottom surface portion 40a of the recess 40c, the first outer lead portion 20b, and the second outer lead portion. 30 b is exposed from the first resin body 40. The first lead 20 and the second lead 30 on the back side are exposed. Thereby, it can electrically connect from the back side.

  The recess 40c is inclined so as to have a wide opening in the opening direction. Thereby, the extraction of light in the forward direction can be improved. However, it is possible to form a cylindrical recess without providing an inclination. Moreover, although it is preferable that the inclination is smooth, unevenness can be provided. By providing the unevenness, the adhesion at the interface between the first resin body 40 and the second resin body 50 can be improved. The inclination angle of the recess 40c is preferably 95 to 150 °, more preferably 100 to 120 °, as measured from the bottom surface portion 40a.

  The shape on the main surface side of the first resin body 40 is a rectangle, but may be an ellipse, a circle, a pentagon, a hexagon, or the like. The shape of the main surface side of the recess 40c is an ellipse, but may be a substantially circular shape, a rectangular shape, a pentagonal shape, a hexagonal shape, or the like. In certain cases, a cathode mark is attached.

  The 1st resin body 40 is the hardened | cured material (dry unsaturated polyester resin molding) which shape | molded the pellet for LED reflectors formed from the unsaturated polyester resin composition for LED reflectors of this invention.

  The first lead 20 has a first inner lead portion 20a and a first outer lead portion 20b. The bottom surface portion 40a of the recess 40c of the first resin body 40 in the first inner lead portion 20a is exposed, and the light emitting element 10 is placed thereon. The exposed first inner lead portion 20a only needs to have an area on which the light emitting element 10 is placed, but a larger area is preferable from the viewpoint of thermal conductivity, electrical conductivity, reflection efficiency, and the like. . The first inner lead portion 20 a is electrically connected to the first electrode 11 of the light emitting element 10 via the wire 60. The first outer lead portion 20b is a portion exposed from the first resin body 40 excluding a portion where the light emitting element 10 is placed. The first outer lead portion 20b is electrically connected to the external electrode and has a function of transferring heat.

  The second lead 30 has a second inner lead portion 30a and a second outer lead portion 30b. The bottom surface portion 40a of the concave portion 40c of the first resin body 40 in the second inner lead portion 30a is exposed. The exposed second inner lead portion 30a only needs to have an area electrically connected to the second electrode 12 of the light emitting element 10, but a larger area is preferable from the viewpoint of reflection efficiency. The first outer lead portion 20b and the second outer lead portion 30b on the back surface side are exposed and form substantially the same plane. Thereby, the mounting stability of the surface-mounted LED light-emitting device can be improved. Moreover, in order to prevent the back surfaces of the first inner lead portion 20a and the second inner lead portion 30a from being short-circuited by solder during soldering, the electrically insulating insulating member 90 can be thinly coated. The insulating member 90 is formed of resin or the like.

  The first lead 20 and the second lead 30 can be configured using a good electrical conductor such as iron, phosphor bronze, or copper alloy. In addition, in order to improve the reflectance of light from the light emitting element 10, the surface of the first lead 20 and the second lead 30 can be subjected to metal plating such as silver, aluminum, copper or gold. Moreover, in order to improve the reflectance of the surface of the 1st lead | read | reed 20 and the 2nd lead | read | reed 30, it is preferable to make it smooth. Further, the area of the first lead 20 and the second lead 30 can be increased in order to improve heat dissipation. Thereby, the temperature rise of the light emitting element 10 can be effectively suppressed, and a relatively large amount of electricity can be passed through the light emitting element 10. Moreover, heat dissipation can be improved by making the first lead 20 and the second lead 30 thick. In this case, since the forming process such as bending the first lead 20 and the second lead 30 is difficult, it is cut into a predetermined size. Further, by making the first lead 20 and the second lead 30 thick, the deflection of the first lead 20 and the second lead 30 is reduced, and the light emitting element 10 can be easily mounted. . On the contrary, by forming the first lead 20 and the second lead 30 into a thin flat plate shape, the bending process can be easily performed, and the first lead 20 and the second lead 30 can be formed into a predetermined shape.

  The first lead 20 and the second lead 30 are a pair of positive and negative electrodes. The first lead 20 and the second lead 30 may be at least one at a time, but a plurality of them may be provided. In addition, when a plurality of light emitting elements 10 are mounted on the first lead 20, it is necessary to provide a plurality of second leads 30.

  The second resin body 50 is provided to protect the light emitting element 10 from external force, dust, moisture, and the like from the external environment. Further, the light emitted from the light emitting element 10 can be efficiently emitted to the outside. The second resin body 50 is disposed in the recess 40 c of the first resin body 40.

  The material of the second resin body 50 is a thermosetting resin. Examples of the thermosetting resin include an epoxy resin, a modified epoxy resin, a silicone resin, a modified silicone resin, an acrylate resin, and a urethane resin. These may be used alone or in combination of two or more.

  The fluorescent material 80 may be any material that absorbs light from the light emitting element 10 and converts the wavelength into light having a different wavelength. As the fluorescent material 80, those having an emission spectrum in yellow, red, green, and blue can be used by the excitation light of the light emitting element 10, and the emission material has an emission spectrum in yellow, blue-green, orange, etc. which are intermediate colors thereof. Things can also be used. By using these fluorescent materials 80 in various combinations, surface-mount type LED light-emitting devices having various emission colors can be manufactured.

  In addition, the heat radiating member can be provided in the back surface side of the surface mount type LED light-emitting device through a heat radiating adhesive.

  The surface mount type LED light emitting device having the above configuration electrically connects the first outer lead portion 20b of the first lead 20 and the second outer lead portion 30b of the second lead 30 to the external electrode. Can be implemented. For example, since the first lead 20 and the second lead 30 are thick flat plates, they can be electrically connected so as to be sandwiched between the external electrode and the heat dissipation member. Further, lead-free solder can be used for electrical connection between the first outer lead portion 20b and the second outer lead portion 30b and the external electrode. In addition, electrical connection can be made so that the first outer lead portion 20b and the like are placed on the external electrode.

  This surface-mounted LED light-emitting device can be manufactured by the following method. As a molding method of the first resin body 40, a melt heating molding method such as an injection molding method, an injection compression molding method, or a transfer molding method can be suitably used. Among these, the injection molding method using an injection molding machine is particularly suitable, and the first resin body 40 having a complicated shape can be manufactured by the injection molding method.

  First, the first inner lead portion 20a and the second inner lead portion 30a corresponding to the bottom surface portion 40a of the concave portion 40c of the first resin body 40, and the first outer lead portion 20b and the second outer lead portion 30b, Is sandwiched between the upper mold and the lower mold.

  The upper mold forms a recess corresponding to the recess 40 c of the first resin body 40. A portion of the upper mold corresponding to the bottom surface portion 40a of the recess 40c of the first resin body 40 is formed so as to be in contact with the first inner lead portion 20a and the second inner lead portion 30a.

  Then, the unsaturated polyester resin composition for an LED reflector is poured into a recessed portion sandwiched between the upper mold and the lower mold.

  The poured unsaturated polyester resin composition for an LED reflector is heated and cured to obtain a first resin body 40 of a dry unsaturated polyester resin molded body having a recess 40c having a bottom surface portion 40a and a side surface portion 40b. . A resin insulating portion 45 that insulates the first lead 20 and the second lead 30 is provided as a dry unsaturated polyester resin molded body on the bottom surface portion 40a of the recess 40c.

  Thereafter, the upper mold and the lower mold are removed. When the curing is insufficient, post-curing is performed to improve the mechanical strength of the first resin body 40 to such an extent that no problem occurs in work.

  Then, after performing deburring etc. as needed, the light emitting element 10 is mounted in the 1st inner lead part 20a. Deburring can be performed by blasting, but as described above, it can also be performed by alkali treatment.

  Next, the first electrode 11 of the light emitting element 10 and the first inner lead portion 20a are electrically connected. Further, the second electrode 12 of the light emitting element 10 and the second inner lead portion 30a are electrically connected.

  The first electrode 11 and the first inner lead portion 20a are electrically connected via a wire 60. However, when the light emitting element 10 has electrodes on the upper surface and the lower surface, electrical connection is established only by die bonding without using wires. Next, the second electrode 12 and the second inner lead portion 30 a are electrically connected via the wire 60.

  Next, thermosetting resin is arrange | positioned in the recessed part 40c in which the light emitting element 10 was mounted. As a method for arranging the thermosetting resin, dropping means, injection means, extrusion means, and the like can be used, but it is preferable to use dropping means. By using the dropping means, the air remaining in the recess 40c can be effectively expelled. The thermosetting resin is preferably mixed with a fluorescent material 80 in advance. Thereby, the color tone adjustment of the surface-mounted LED light-emitting device can be facilitated. This thermosetting resin is cured by heating, and the second resin body 50 is formed. In this way, a surface mount type LED light emitting device can be manufactured.

  The surface-mounted LED light-emitting device of the present invention can be used for LED lighting such as an LED bulb by wearing this.

EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.
<Manufacture of unsaturated polyester resin composition for LED reflector>
The unsaturated polyester resin compositions for LED reflectors of Examples and Comparative Examples shown in Table 1 and Table 2 were blended with each blending component and blending amount, and the blend was uniformly mixed with a sigma blender. Then, it knead | mixed with the biaxial kneader heated at the temperature of 70 degreeC, and produced the worm-like kneaded material, this was cooled, grind | pulverized, and sized, and the granular resin composition (pellet) was produced.

The following components were used as blending components.
(I) Unsaturated polyester resin / resin unsaturated alkyd resin: terephthalic acid-based unsaturated alkyd resin Iupika 8552 made by Nippon Yupika Co., Ltd. Crosslinking agent 2: diallyl phthalate monomer Daiso Co., Ltd. dap monomer (ii) Silicone alkoxy oligomer liquid A: (meth) acrylic modified silicone alkoxy oligomer, Shin-Etsu Chemical Co., Ltd. “KR513”
Liquid B: (meth) acryl-modified silicone alkoxy oligomer, “X-40-2655A” manufactured by Shin-Etsu Chemical Co., Ltd.
(Iii) Polymerization initiator dicumyl peroxide (40% masterbatch) Park Mill D40 manufactured by NOF Corporation
(Iv) White pigment White pigment 1: Titanium oxide (rutile-type titanium oxide, average particle size 0.4 μm) Tioxide R-TC30 manufactured by Thai Oxide Japan Co., Ltd.
White pigment 2: Aluminum oxide (average particle size 0.5 μm)
White pigment 3: barium titanate (average particle size 0.4 μm)
(V) Inorganic filler Inorganic filler 1: Silica (Fused silica, average particle size 25 μm) FB820, manufactured by Denki Kagaku Kogyo Co., Ltd.
Inorganic filler 2: Aluminum hydroxide (average particle size 29 μm)
(Vi) Release agent Release agent: Zinc stearate SZ-P manufactured by Sakai Chemical Industry Co., Ltd.
(Vii) Reinforcing material Reinforcing material: Glass fiber (3 mm length) CS03IE830A manufactured by Owens Corning Japan
<Evaluation method>
(1) Moldability Using the unsaturated polyester resin composition for LED reflectors in the blending ratios of the examples and comparative examples shown in Tables 1 and 2, the mold temperature was measured by a transfer molding machine (manufactured by Matsuda Seisakusho, 30 tons) A test piece for reflectance measurement was produced under conditions of 160 ° C. and a curing time of 60 seconds, and an actual molding evaluation was performed visually.

Excellent ones were marked with ◯, good ones with Δ, and poor ones with ×. The results are shown in Table 1.
(2) Reflectivity characteristics (2-1) Initial reflectance, heat-resistant discoloration property Transfer molding machine using unsaturated polyester resin compositions for LED reflectors in the proportions of Examples and Comparative Examples shown in Tables 1 and 2 A test piece for reflectivity measurement was produced by (Matsuda Seisakusho, 30 tons).

  The reflectance of this test piece was measured with a reflectance meter (spectral colorimeter manufactured by Nippon Denshoku Industries Co., Ltd.) (wavelength: 460 nm).

  The initial reflectance was evaluated as ◎ for 95% or more, ◯ for 90% or more and less than 95%, and x for less than 90%.

  Further, the reflectivity of the surface of the test piece after processing at 150 ° C. for 1000 hours is measured. The reflectivity is 75% or more, ○ is 70% or less and less than 75%, and 70% or less is ×. evaluated.

Tables 1 and 2 show initial reflectances and evaluations of Examples and Comparative Examples, and reflectances after 1000 hours and evaluation results.
(2-2) UV discoloration resistance Using an unsaturated polyester resin composition for LED reflectors in the blending ratios of Examples and Comparative Examples shown in Tables 1 and 2, using a transfer molding machine (manufactured by Matsuda Seisakusho, 30 tons). Then, a reflectance measurement test piece was produced.

  The reflectance of this test piece was treated at 140 ° C. under UV irradiation, and measured with a reflectance measuring device (Spectral Colorimeter manufactured by Nippon Denshoku Industries Co., Ltd.).

  UV irradiation was performed by installing a fluorescent mercury lamp (transparent mercury lamp type 400 H400, manufactured by Panasonic Corporation) in a dark room so that the distance between the LED reflector and the central part of the mercury lamp was 300 mm.

The specifications of the fluorescent mercury lamp are as follows. FIG. 3 shows (a) a front photograph, (b) a spectral distribution, and (c) a light distribution curve of a transparent mercury lamp 400 type H400.
Outer tube diameter (mm): 120
Full length (mm): 285
Rated lamp power (W): 400
Lamp voltage (V): 130
Lamp current (A): 3.3
Total luminous flux (lm): 20500
Rated life (h): 12000
Color temperature: 4700K
FIG. 4 shows a graph of the reflectance change over time of the LED reflectors of Example 2 and Comparative Example 1.

  Further, the reflectivity of the surface of the test piece after 1000 hours treatment at 140 ° C. under UV irradiation is measured. The reflectivity is 90% or more, ○ is 80% or more and less than 90%, and is less than 80%. Were evaluated as x.

Tables 1 and 2 show initial reflectances and evaluations of Examples and Comparative Examples, and reflectances after 1000 hours and evaluation results.
(3) Burr processability (3-1) Blasting treatment Using the unsaturated polyester resin composition for LED reflectors in the blending ratios of the examples and comparative examples shown in Tables 1 and 2, a transfer molding machine (manufactured by Matsuda Seisakusho, 30 tons), a test piece for reflectance measurement was produced.

Each test piece was subjected to blast treatment (drive last method, bead type: nylon, condition: 1 m ³ / min with an air volume of 0.1 to 0.2 MPa), and evaluation of blast burr treatment was performed. The initial reflectance deterioration rate was less than 0.5%, 、, 0.5 to less than 1%, ○, 1% to less than 3%, and 、 ３, 3% or more.
The results are shown in Tables 1 and 2.
(3-2) Alkali treatment Reflected by a transfer molding machine (manufactured by Matsuda Seisakusho, 30 tons) using unsaturated polyester resin compositions for LED reflectors in the blending ratios of the examples and comparative examples shown in Tables 1 and 2. A test piece for rate measurement was prepared.

  Each test piece was immersed in a 10% aqueous sodium hydroxide solution for 15 minutes, subjected to alkali treatment, and evaluated for alkali treatment. The initial reflectance deterioration rate was less than 0.5%, 、, 0.5 to less than 1%, ○, 1% to less than 3%, and 、 ３, 3% or more.

The results are shown in Tables 1 and 2.
(4) Releasability Using the unsaturated polyester resin composition for LED reflectors in the blending ratios of the examples and comparative examples shown in Tables 1 and 2, an injection molding machine (manufactured by Nissei Resin Co., Ltd., 50 tons thermosetting) A reflector molded product was molded by an injection molding machine, and the degree of burr adhesion at that time was visually confirmed.

  The case where there was no burrs attached to the mold was marked with ◎, the case where it was adhered but difficult to adhere was marked with ○, the case where adhesion was noticeable was marked with △, and the case where marked adhesion was marked with ×. The results are shown in Tables 1 and 2.

<Evaluation results>
From Tables 1 and 2, all the examples in which the (meth) acryl-modified silicone alkoxy oligomer was blended showed good results in moldability, reflectance characteristics, burr processing properties, and releasability. On the other hand, in the comparative example in which the (meth) acryl-modified silicone alkoxy oligomer was not blended or was outside the range of the appropriate blending amount, these characteristics were lowered, particularly from the burr treatment property by the alkali treatment and the mold. There was a decrease in the release properties of

DESCRIPTION OF SYMBOLS 10 Light emitting element 20 1st lead 30 2nd lead 40 1st resin body 40a Bottom face part 40c Recess 45 Resin insulation part 50 2nd resin body

Claims (10)

An unsaturated polyester resin composition for an LED reflector containing an unsaturated polyester resin, a polymerization initiator, an inorganic filler, a white pigment and a reinforcing material,
The unsaturated polyester resin composition comprises (meth) acryl-modified silicone alkoxy oligomer having a (meth) acryl group, an alkyl group, and an alkoxy group in an amount of 1 to 15 parts by mass with respect to 100 parts by mass of the unsaturated polyester resin. An unsaturated polyester resin composition for LED reflectors, which is contained in a range. The (meth) acryl-modified silicone alkoxy oligomer has the following formula (I):
(Wherein, OR ¹ represents the alkoxy group having 1 to 3 carbon atoms, R ² represents the (meth) acryl group or the alkyl group having 1 to 3 carbon atoms, and n represents an integer). It is 10-100 mm < ² > / s (at 25 degreeC), 10-40 mass% of alkoxy groups, (meth) acryl equivalent 180-320 g / mol, The unsaturated polyester for LED reflectors of Claim 1 characterized by the above-mentioned. Resin composition.   The unsaturated polyester resin is 10 to 50% by mass with respect to the total amount of the resin composition, and the total amount of the inorganic filler and the white pigment is 40 to the total amount of the resin composition. The ratio of the white pigment in the total amount of the inorganic filler and the white pigment in the range of 90% by mass is at least 10% by mass or more. Unsaturated polyester resin composition for LED reflector.   The unsaturated polyester resin composition for an LED reflector according to any one of claims 1 to 3, wherein the unsaturated polyester resin is a mixture of an unsaturated alkyd resin and a crosslinking agent.   5. The reflectivity after 1000 hours of UV irradiation treatment in a 140 ° C. environment of a cured product obtained by curing the unsaturated polyester resin composition for LED reflector is 80% or more. The unsaturated polyester resin composition for LED reflectors described in 1.   The LED reflector formed of the unsaturated polyester resin composition for an LED reflector according to any one of claims 1 to 5, wherein the unsaturated alkyd resin starts to soften at 50 ° C or higher. Granules for use.   The LED reflector formed of the unsaturated polyester resin composition for an LED reflector according to any one of claims 1 to 5, wherein the unsaturated alkyd resin starts to soften at 50 ° C or higher. Tablet.   The LED reflector granule according to claim 6 or the LED reflector tablet according to claim 7 is formed, and the LED reflector is formed.   A surface-mounted LED light-emitting device comprising the LED reflector according to claim 8.   An LED illumination comprising the surface-mounted LED light-emitting device according to claim 9.