JPWO2014027463A1 - Induction hardening steel - Google Patents

Abstract

Provided is a steel for induction hardening that exhibits excellent rolling fatigue life after induction hardening. The steel for induction hardening according to the present embodiment is mass%, C: 0.4 to 0.6%, Si: 0.03 to 1.0%, Mn: 0.2 to 2.0%, P: 0. 0.05% or less, S: less than 0.010%, Cr: 0.05 to 0.50%, Al: 0.01 to 0.10%, Ca: 0.0003 to 0.0030%, O: 0.0. 0030% or less, N: 0.003 to 0.030%, Cu: 0 to 1.0%, Ni: 0 to 3.0%, Mo: 0 to 0.15%, V: 0 to 0.30% Nb: 0 to 0.10%, B: 0 to 0.0030%, and Ti: 0 to 0.10%, with the balance being Fe and impurities, the formulas (1) and (2) It has a chemical composition satisfying 0.7 ≦ Ca / O ≦ 2.0 (1) Ca / O ≧ 1250S−5.8 (2) Here, the element symbols in the formulas (1) and (2) include , The content (mass%) of the corresponding element is substituted.

Description

  The present invention relates to a steel material, and more particularly, to a steel material for induction hardening.

  Among automotive parts, high surface pressure repeatedly acts on parts such as constant velocity joints and hub units. Therefore, these parts are required to have excellent rolling fatigue characteristics. As a material for these parts, “carbon steel for mechanical structure” described in JIS G 4051 (2009) is mainly used. Of these parts, the parts requiring rolling fatigue characteristics are hardened by induction hardening.

  Induction hardening can cure only the necessary parts. Moreover, when an induction hardening apparatus is arrange | positioned on a production line, induction hardening can be implemented in what is called in-line. Therefore, when using induction hardening, the degree of freedom in the manufacturing process is higher than when using batch-type surface treatment.

  It is known that rolling fatigue characteristics are degraded by non-metallic inclusions in steel (hereinafter also simply referred to as “inclusions”), particularly oxides and sulfides. Therefore, conventionally, the content of O (oxygen) and S (sulfur) in the steel is reduced by a steelmaking process to increase the rolling fatigue life.

  In recent years, for example, due to demands for higher output of engines and weight reduction of parts, the use environment of the above parts has become higher and higher in surface pressure. Therefore, the induction hardening steel used as a component material is required to further improve the rolling fatigue life.

  However, it is difficult to obtain a good rolling fatigue life simply by reducing the contents of oxygen (O) and sulfur (S) in the steel. In view of this, a steel for induction hardening intended to improve the rolling fatigue life by reducing the size of oxides and sulfides in the steel is proposed in Japanese Patent Laid-Open No. 11-1749 (Patent Document 1). ing.

The steel for induction hardening disclosed in Patent Document 1 is a linear or rod-shaped rolled steel material. And, in a longitudinal section passing through the axis of the rolled steel material, a virtual line that is parallel to the axis and separated from the axis by (1/4) × D (“D” represents the diameter of the rolled steel material) is taken as the center line. The number of composite inclusions having an average particle diameter of 10 μm or more, which is made of an oxide and a sulfide, existing in a test area of 100 mm ² is 20 or less. The chemical composition of induction hardening steel of patent document 1 is 0.7% or less exceeding C: 0.3% in mass%, Mn: 0.3-2.5%, Si: 2% or less (0 %), P: 0.03% or less (including 0%), S: 0.1% or less (including 0%), Al: 0.015 to 0.05%, and O: 0.002% (Including 0%) below, and if necessary, (a) at least one selected from the group consisting of a specific amount of Cu, Ni, Cr and Mo, (b) a specific amount of V, Nb And at least one selected from the group consisting of Ti and (c) at least one selected from the group consisting of specific amounts of Ca, Pb, Te, Bi and Zr, and (d) specific amounts of B and N It contains an element selected from at least one element group of the four element groups, and the balance consists of Fe and inevitable impurities.

  In Patent Document 1, the following matters are described. If the oxide-based and sulfide-based coarse composite inclusions having an average particle diameter of 10 μm or more are suppressed as much as possible, bending fatigue characteristics and rolling fatigue characteristics are improved. And in order to reduce a coarse composite inclusion, content of Al, S, and O is controlled to an appropriate range, and also the cooling rate of a slab, the heating conditions at the time of rolling, and rolling conditions are controlled.

  Moreover, although it is not induction hardening steel, the electric resistance welded pipe aiming at improving a fatigue characteristic by controlling the form of Ca-type inclusion is disclosed by international publication 2010/110490 (patent document 2). ing.

The electric resistance welded steel pipe disclosed in Patent Document 2 is in mass%, C: 0.15 to 0.55%, Si: 0.01 to 0.30%, M n: 0.5 to 1.5%, Ca: 0.0010 to 0.0030%, S: 0.0005 to 0.0050%, O: 0.0005 to 0.0050%. Furthermore, content of Ca, O, and S in steel satisfies 0.10 ≦ [Ca] (1-124 [O]) / 1.25 [S] ≦ 2.50. Furthermore, the average particle diameter of the Ca-based inclusions present in the base material and the ERW weld is 1.0 to 10 μm, and the density of the Ca-based inclusions is 3 to 300 / mm ² . Furthermore, the difference ΔHv between the maximum hardness of the ERW weld and the average hardness of the base material is 100 to 500.

  Patent Document 2 describes that by satisfying the above formula, the average particle diameter and distribution density of calcium-based oxides (CaO) and sulfides (CaS) are in an appropriate range, and fatigue characteristics are enhanced. Yes.

Japanese Patent Laid-Open No. 11-1749 International Publication No. 2010/110490

  However, in Patent Document 1, no consideration is given to the composition control of oxides and sulfides. Therefore, even when the content of Al or O is small, coarse oxides may appear and an excellent rolling fatigue life may not be obtained.

  Patent Document 2 relates to an electric resistance welded pipe in the first place, and does not consider rolling fatigue life. Moreover, the ERW steel pipe is not premised on performing hot forging and induction hardening. Furthermore, Patent Document 2 does not consider the composition control of oxides and sulfides.

  An object of the present invention is to provide a steel for induction hardening that exhibits excellent rolling fatigue life after induction hardening.

The steel for induction hardening according to the present embodiment is in mass%, C: 0.4 to 0.6%, Si: 0.03 to 1.0%, Mn: 0.2 to 2.0%, P: 0.05% or less, S: less than 0.010%, Cr: 0.05 to 0.50%, Al: 0.01 to 0.10%, Ca: 0.0003 to 0.0030%, O: 0 .0030% or less, N: 0.003 to 0.030%, Cu: 0 to 1.0%, Ni: 0 to 3.0%, Mo: 0 to 0.15%, V: 0 to 0.30 %, Nb: 0 to 0.10%, B: 0 to 0.0030%, and Ti: 0 to 0.10%, with the balance being Fe and impurities, and the formulas (1) and (2) ).
0.7 ≦ Ca / O ≦ 2.0 (1)
Ca / O ≧ 1250S−5.8 (2)
Here, the content (mass%) of the corresponding element is substituted for the element symbols in the formulas (1) and (2).

  The steel for induction hardening according to the present embodiment has an excellent rolling fatigue life.

FIG. 1 is a diagram for explaining the influence of the amount of Ca / O and S in steel on the formation of coarse oxides and dot-like oxides. FIG. 2A is a plan view of a thrust type rolling fatigue test piece used in Examples. FIG. 2B is a schematic diagram for explaining the induction hardening process for the test piece shown in FIG. 2A.

  In general, the mechanism of rolling fatigue is understood as follows. Repeated loads are applied to the inclusions present in the steel material, and the steel material cracks due to stress concentration. Thereafter, the crack gradually develops due to repeated loading, and finally a part of the steel material is peeled off.

  The inventors of the present invention have studied by focusing on the composition and form of inclusions in steel. As a result, the present inventors obtained knowledge (A) to (D).

  (A) The composition of the sulfide can be controlled. Specifically, for example, Ca is added to molten steel to generate (Mn, Ca) S and CaS. Due to the formation of (Mn, Ca) S and CaS, the diameter of the sulfide is reduced and dispersed. Therefore, coarse sulfides that become a stress concentration source of rolling fatigue are reduced.

(B) even if with reduced content of oxygen (O) in the steel, if the oxide is a chemical composition mainly composed of _{Al 2 O 3, Al 2 O} 3 principal oxides are aggregated and coalesced May exist as coarse inclusions. If a coarse Al ₂ O ₃ main oxide is formed, a good rolling fatigue life may not be obtained.

(C) When Ca is added to molten steel of aluminum killed steel (hereinafter referred to as “Al killed steel”), Al ₂ O ₃ which is a deoxidation product reacts with Ca to form (Al , Ca) changes to O. Due to this change, the oxide in the molten steel is spheroidized. Therefore, aggregation and coarsening of the oxide are suppressed.

(D) Ca in the molten steel of the above item (C) reacts with S in the molten steel and Al ₂ O ₃ which is a deoxidation product of Al killed steel. The two reactions are competing. Therefore, the amount of Ca that can react with Al ₂ O ₃ varies depending on the S content in the molten steel. Therefore, in order to appropriately change the oxide composition in the molten steel and suppress the coarsening of the oxide, it is necessary to control the Ca, O, and S contents in the steel to an appropriate relationship.

  The inventors investigated the effect of Ca content on the composition and morphology of oxides and sulfides in steel. As a result, the present inventor further obtained knowledge (E) and (F).

(E) The composition of oxides in steel (types of oxides produced in steel) depends on the ratio of Ca content to Ca content (Ca / O) in steel. When Ca / O satisfies the formula (1), many (Al, Ca) O are generated in the steel, and the formation of coarse oxides (oxides mainly composed of Al ₂ O ₃ and / or CaO) is suppressed. Is done.
0.7 ≦ Ca / O ≦ 2.0 (1)

(F) If S content in steel is too high, Ca will react not only with O but with S. For this reason, if S content in steel is high, even if Ca content and O content in steel satisfy | fill Formula (1), a coarse oxide may arise. If the Ca content, O content, and S content in the steel satisfy the formula (1) and the following formula (2), generation of coarse oxides and / or point-like oxides is suppressed. .
Ca / O ≧ 1250S−5.8 (2)

  The steel material for induction hardening according to the present embodiment completed based on the above knowledge is as follows.

The steel for induction hardening according to the present embodiment is in mass%, C: 0.4 to 0.6%, Si: 0.03 to 1.0%, Mn: 0.2 to 2.0%, P: 0 0.05% or less, S: less than 0.010%, Cr: 0.05 to 0.50%, Al: 0.01 to 0.10%, Ca: 0.0003 to 0.0030%, O: 0.0. 0030% or less, N: 0.003 to 0.030%, Cu: 0 to 1.0%, Ni: 0 to 3.0%, Mo: 0 to 0.15%, V: 0 to 0.30% Nb: 0 to 0.10%, B: 0 to 0.0030%, and Ti: 0 to 0.10%, with the balance being Fe and impurities, the formulas (1) and (2) It has a chemical composition satisfying
0.7 ≦ Ca / O ≦ 2.0 (1)
Ca / O ≧ 1250S−5.8 (2)
Here, the content (mass%) of the corresponding element is substituted for the element symbols in the formulas (1) and (2).

  The chemical composition of the steel for induction hardening may include C: 0.48 to 0.6%. The chemical composition of the steel for induction hardening may include C: 0.50 to 0.6%.

  The chemical composition of the steel for induction hardening may include N: more than 0.0050% to 0.030%.

  The chemical composition of the steel for induction hardening is selected from the group consisting of Cu: 0.05 to 1.0%, Ni: 0.05 to 3.0%, and Mo: 0.02 to 0.15%. 1 type (s) or 2 or more types may be contained.

  The chemical composition of the steel for induction hardening includes one or two selected from the group consisting of V: 0.01 to 0.30% and Nb: 0.01 to 0.10%. Good.

  The chemical composition of the steel for induction hardening may include B: 0.0005 to 0.0030% and Ti: 0.01 to 0.10%.

  The steel material for induction hardening according to the present embodiment has good durability against damage due to rolling fatigue even under severe use environments of rolling members in recent years. Therefore, the rolling fatigue life after induction hardening is excellent. The steel material for induction hardening according to the present embodiment can be suitably used as a material for parts subjected to induction hardening such as “constant velocity joints” and “hub units” used as automobile parts.

  Hereinafter, the above-described steel for induction hardening will be described in detail. “%” Of the content of each element means “mass%”.

  The chemical composition of the steel for induction hardening according to the present embodiment contains the following elements.

C: 0.4 to 0.6%
Carbon (C) increases the hardness of the rolling part of the component after induction hardening. If the C content is too low, the above effect cannot be obtained. On the other hand, if the C content is too high, the hardness of the steel material becomes too high, and the forgeability of the steel material decreases. Furthermore, the tool life for cutting the steel material is reduced. If the C content is too high, the toughness of the induction-quenched portion may further decrease and the rolling fatigue life may decrease. Therefore, the C content is 0.4 to 0.6%. The minimum with preferable C content is 0.42%, More preferably, it is 0.48%, More preferably, it is 0.50%. The upper limit with preferable C content is 0.58%.

Si: 0.03-1.0%
Silicon (Si) enhances the hardenability of the steel material and forms a hardened layer in the rolling part after induction hardening. If the Si content is too low, a cured layer having a sufficient depth cannot be formed. On the other hand, if the Si content is too high, the hardness of the steel material becomes too high and the forgeability of the steel material decreases. Furthermore, the tool life for cutting the steel material is reduced. Therefore, the Si content is 0.03 to 1.0%. The minimum with preferable Si content is 0.1%, More preferably, it is 0.12%. The upper limit with preferable Si content is 0.8%.

Mn: 0.2 to 2.0%
Manganese (Mn) increases the hardenability of the steel material and increases the hardness of the rolling part after induction hardening. If the Mn content is too low, the above effect cannot be obtained. On the other hand, if the Mn content is too high, the hardness of the steel material becomes too high and the forgeability of the steel material decreases. Furthermore, the tool life for cutting the steel material is reduced. Therefore, the Mn content is 0.2 to 2.0%. The minimum with preferable Mn content is 0.3%, More preferably, it is 0.5%. The upper limit with preferable Mn content is 1.5%, More preferably, it is 1.0%.

P: 0.05% or less Phosphorus (P) is an impurity. P segregates at the grain boundaries and reduces the rolling fatigue life of the steel material. Therefore, the P content is preferably as low as possible. Therefore, the P content is 0.05% or less. P content is preferably 0.03% or less, more preferably 0.02% or less.

S: Less than 0.010% Sulfur (S) is an impurity. S forms coarse sulfides and reduces the rolling fatigue life of the steel material. Accordingly, the S content is preferably as low as possible. Therefore, the S content is less than 0.010%. The preferable S content is 0.006% or less, and more preferably 0.002% or less. The S content further satisfies the formula (2).

Cr: 0.05 to 0.50%
Chromium (Cr) enhances the hardenability of the steel material and forms a hardened layer in the rolling part after induction hardening. If the Cr content is too low, a cured layer having a sufficient depth cannot be formed. On the other hand, if the Cr content is too high, the hardenability of the steel material is lowered in the case of induction heat treatment. Furthermore, the life of the tool for cutting the steel material is also reduced. Therefore, the Cr content is 0.05 to 0.50%. The minimum with preferable Cr content is 0.10%. The upper limit with preferable Cr content is 0.40%, More preferably, it is 0.30%.

Al: 0.01-0.10%
Aluminum (Al) deoxidizes steel. Further, Al combines with N to form AlN, and suppresses the coarsening of crystal grains in the quenched portion of the steel material. If the Al content is too low, this effect cannot be obtained. On the other hand, if the Al content is too high, the induction hardenability of the steel material decreases. Therefore, the Al content is 0.01 to 0.10%. A preferred lower limit of the Al content is 0.015%. The upper limit with preferable Al content is 0.08%, More preferably, it is 0.050%.

  In the present embodiment, the Al content means the total Al content.

Ca: 0.0003 to 0.0030%
Calcium (Ca) forms an appropriate amount of (Al, Ca) O as an oxide. If (Al, Ca) O is formed, the interfacial energy between the matrix and the inclusions is reduced, and the cohesive strength of the oxide is reduced. Therefore, the coarsening of the oxide in steel is suppressed and the rolling fatigue life is increased. Ca further dissolves in the sulfide to form (Mn, Ca) S and CaS. (Mn, Ca) S and CaS are not easily stretched and are not easily coarsened. Since (Mn, Ca) S and CaS are further crystallized from MnS, these sulfide inclusions are more uniformly dispersed in the steel than MnS. Therefore, the rolling fatigue life is increased. If the Ca content is too low, the above effect cannot be obtained. On the other hand, if the Ca content is too high, the oxide becomes coarse and the rolling fatigue life decreases. Therefore, the Ca content is 0.0003 to 0.0030%. A preferable lower limit of the Ca content is 0.0005%. The upper limit with preferable Ca content is 0.0025%. The Ca content further satisfies the expressions (1) and (2).

O: 0.0030% or less Oxygen (O) is an impurity. O forms a coarse oxide in the steel and reduces the rolling fatigue life of the steel material. Therefore, it is preferable that the O content is as low as possible. The O content is 0.0030% or less. A preferable O content is 0.0025% or less, and more preferably 0.0020% or less. The O content further satisfies formulas (1) and (2).

N: 0.003-0.030%
Nitrogen (N) combines with Al in the steel to form AlN and suppresses the coarsening of crystal grains in the quenched portion of the steel material. If the N content is too low, the above effect cannot be obtained. On the other hand, if the N content is too high, coarse nitrides are generated, and the rolling fatigue life of the steel material is reduced. Therefore, the N content is 0.003 to 0.030%. The minimum with preferable N content is 0.0040%, More preferably, it exceeds 0.0050%.

  In order to further suppress the coarsening of crystal grains in the quenched portion, when containing optional elements V and / or Nb, the preferred lower limit of the N content is 0.005%.

  In order to further improve the hardenability at the time of induction hardening, when B and Ti are contained, it is preferable that B can be suppressed from binding to N. Therefore, when it contains B and Ti, the upper limit with preferable N content is less than 0.030%, More preferably, it is less than 0.010%, More preferably, it is 0.008%.

[Regarding Formula (1)]
In the chemical composition of the steel for induction hardening according to the present embodiment, the ratio of Ca content to O content (Ca / O) satisfies the formula (1).
0.7 ≦ Ca / O ≦ 2.0 (1)
Here, the content (mass%) of the corresponding element is substituted for the element symbol in the formula (1).

Ca / O is an index of the oxide composition in the steel after adding Ca. When Ca / O is less than 0.7, Al ₂ O ₃ does not completely change to (Al, Ca) O, and the specific Al oxide (coarse spinel mainly composed of Al ₂ O ₃ and / or dots Column-shaped Al ₂ O ₃ oxide group). The specific Al oxide decreases the rolling fatigue life.

  On the other hand, when Ca / O exceeds 2.0, specific Ca oxide (a high-melting-point coarse oxide and / or point-sequence CaO oxide mainly composed of CaO) is formed. The specific Ca oxide decreases the rolling fatigue life.

  When Ca / O satisfies the formula (1) and the formula (2), an appropriate amount of (Al, Ca) O is generated in the steel, and the generation of the specific Al oxide and the specific Ca oxide is reduced. The

[Regarding Formula (2)]
As for the chemical composition of the steel for induction hardening of this embodiment, Ca / O further satisfies the formula (2).
Ca / O ≧ 1250S−5.8 (2)
Here, the content (mass%) of the corresponding element is substituted for the element symbol in the formula (2).

  Ca reacts not only with O in steel but also with S in steel. Therefore, even if Ca / O satisfies the formula (1), the generation of the specific Al oxide may not be suppressed.

  More specifically, when Ca / O is smaller than 1250S-5.8, the amount of Ca combined with S increases, and the amount of Ca used for (Al, Ca) O is insufficient. Therefore, a specific Al oxide is generated and the rolling fatigue life is reduced.

  If Ca / O satisfies the formula (1) and is 1250S-5.8 or more, the amount of Ca combined with S can be suppressed, and an appropriate amount of Ca can be used for the production of (Al, Ca) O. . Therefore, the production | generation of a specific Al oxide and a specific Ca oxide is suppressed, and a rolling fatigue life increases.

  FIG. 1 is a diagram schematically showing the relationship between the above-mentioned Ca / O and S content and the range satisfying the expressions (1) and (2). The vertical axis in the figure is the ratio of Ca content to O content (Ca / O). A horizontal axis is S content (mass%) in steel materials. The straight line L100 shows Ca / O = 2.0. The straight line L200 indicates Ca / O = 0.7. L300 indicates the linear function Ca / O = 1250S−5.8.

  A hatched area A1 in FIG. 1 is surrounded by straight lines L100, L200, and L300. When the Ca / O and S contents are in the region A1, (Al, Ca) O is generated, and the generation of characteristic Al oxide and specific Ca oxide is suppressed. Therefore, the rolling fatigue life of the steel material is increased.

  The balance of the steel for induction hardening according to this embodiment is made of Fe and impurities. Here, the impurities are mixed from ore as a raw material, scrap, or a manufacturing environment when the steel material is industrially manufactured, and have an adverse effect on the induction hardening steel material of the present embodiment. It means what is allowed in the range.

[Arbitrary elements]
The steel for induction hardening according to this embodiment may contain one or more selected from the group consisting of Cu, Ni, and Mo. All of Cu, Ni and Mo further increase the hardness of the rolling part of the component after induction hardening.

Cu: 0 to 1.0%
Copper (Cu) is an optional element and may not be contained. When contained, Cu, like C and Mn, increases the hardness of the rolling part of the component after induction hardening. However, if the Cu content is too high, the fatigue strength of the steel material decreases and the hot workability also decreases. Therefore, the Cu content is 0 to 1.0%. The minimum with preferable Cu content for acquiring the said effect more stably is 0.05%, More preferably, it is 0.07%. The upper limit with preferable Cu content is 0.5%.

Ni: 0 to 3.0%
Nickel (Ni) is an optional element and may not be contained. When contained, Ni increases the hardness of the rolling part of the component after induction hardening, like C and Mn. However, if Ni content is too high, the fall of the fatigue strength of steel materials will fall. Therefore, the Ni content is 0 to 3.0%. The preferable lower limit of the Ni content for obtaining the above effect more stably is 0.05%, and more preferably 0.07%. The upper limit with preferable Ni content is 2.0%.

Mo: 0 to 0.15%
Molybdenum (Mo) is an optional element and may not be contained. When contained, Mo increases the hardness of the rolling part of the component after induction hardening, like C and Mn. However, if the Mo content is too high, this effect is saturated and the manufacturing cost increases. Therefore, the Mo content is 0 to 0.15%. The minimum with preferable Mo content for acquiring the said effect more stably is 0.02%, More preferably, it is 0.03%. The upper limit with preferable Mo content is 0.12%.

  As above-mentioned, the steel materials for induction hardening of this embodiment can contain the 1 type (s) or 2 or more types selected from the group which consists of Cu, Ni, and Mo. When these elements are contained in combination, the upper limit of the total amount is 4.15%.

  The steel for induction hardening of this embodiment may further contain one or two selected from the group consisting of V and Nb. V and Nb are optional elements. In the high-frequency heat treatment, the steel material is heated to a high temperature even for a short time. V and Nb both suppress the coarsening of crystal grains in the quenched portion of the steel material.

V: 0 to 0.30%
Vanadium (V) is an optional element and may not be contained. When contained, V combines with N to form a nitride. The formed nitride suppresses the coarsening of crystal grains in the quenched portion of the steel material. V further combines with C to increase the strength of the steel material. However, if the V content is too high, the effect of suppressing the coarsening of the crystal grains in the quenched portion is saturated. Furthermore, the strength of the steel material becomes too high, and the machinability decreases. Therefore, the V content is 0 to 0.30%. The minimum with preferable V content for acquiring the said effect more stably is 0.01%, More preferably, it is 0.015%. The upper limit with preferable V content is 0.20%.

Nb: 0 to 0.10%
Niobium (Nb) is an optional element and may not be contained. When contained, Nb combines with N to form a nitride. The formed nitride suppresses the coarsening of crystal grains in the quenched portion of the steel material. Nb further combines with C to increase the strength of the steel material. However, if the Nb content is too high, the effect of suppressing the coarsening of crystal grains in the quenched portion is saturated. Furthermore, the strength of the steel material becomes too high, and the machinability decreases. Therefore, the Nb content is 0 to 0.10%. The minimum with preferable Nb content for acquiring the said effect more stably is 0.01%, More preferably, it is 0.012%. The upper limit with preferable Nb content is 0.08%.

  As above-mentioned, the steel materials for induction hardening of this embodiment can contain 1 type or 2 types selected from the group which consists of V and Nb. The upper limit of the total amount when these elements are contained in combination is 0.40%.

  The steel for induction hardening according to this embodiment may further contain B and Ti. B and Ti are optional elements.

B: 0 to 0.0030%
Boron (B) is an optional element and may not be contained. When contained, B enhances the hardenability of the steel. Therefore, the depth of the hardened layer of the rolling part of the component after induction hardening can be further increased. However, if the B content is too high, the effect is saturated. Therefore, the B content is 0 to 0.0030%. The minimum with preferable B content for obtaining the said effect more stably is 0.0005%, More preferably, it is 0.0007%. The upper limit with preferable B content is 0.0020%.

Ti: 0 to 0.10%
Titanium (Ti) is an optional element and may not be contained. The solid solution B improves the hardenability of the steel material. However, BN in which B is combined with N does not increase the hardenability of the steel material. Therefore, when B is contained, Ti also has a higher affinity with N than B and easily forms nitrides. However, if the Ti content is too high, a large amount of coarse TiN is generated, and the rolling fatigue life of the steel material is reduced. Therefore, the Ti content is 0 to 0.10%. The minimum with preferable Ti content for acquiring the said effect more stably is 0.01%, More preferably, it is 0.015%. The upper limit with preferable Ti content is 0.05%.

[Production method]
A method for producing the above-described steel for induction hardening will be described. In the present embodiment, as an example, a method for manufacturing a steel bar that is a steel material for induction hardening and a process for manufacturing a hot forged product using a steel material for induction hardening (a steel bar) will be described. The hot forged product is, for example, a part used in automobiles, industrial machines, and the like, and more specifically, is a part such as a constant velocity joint or a hub unit.

  A molten steel satisfying the above-described chemical composition and the formulas (1) and (2) is manufactured. When manufacturing molten steel, a deoxidation process is implemented with Al with respect to molten steel. Thereafter, the Ca—Si alloy is contained in the molten steel to adjust the Ca content of the steel material.

  The produced molten steel is used to make a slab by a casting method. You may make molten steel into an ingot (steel ingot) by the ingot-making method. A billet (steel piece) is manufactured by hot working a slab or an ingot. A billet is hot-worked to produce a steel bar. The hot working may be hot rolling or hot forging. The steel material for induction hardening is manufactured by the above manufacturing process.

  The manufactured steel for induction hardening is hot forged. A normalizing treatment is performed on the hot-forged steel for induction hardening as necessary. Further, if necessary, the steel material for induction hardening that has been hot forged is machined into a predetermined shape. A tempering treatment may be performed on the machined steel for induction hardening.

  Induction hardening is performed with respect to the steel materials for induction hardening which passed through the above process. The steel for induction hardening according to the present embodiment has an excellent rolling fatigue life after induction hardening is performed.

  Using a vacuum melting furnace, steels 1 to 30 having the chemical composition shown in Table 1 were produced. When manufacturing molten steel, the deoxidation process was implemented with Al with respect to molten steel. Then, Ca-Si alloy was contained in molten steel, and Ca content of steel materials was adjusted. A 150 kg steel ingot was produced using the produced molten steel.

In the “Ca / O” column in Table 1, the ratio of the Ca content of each steel 1 to 30 to the O content is described. In the “1250S-5.8” column, the right side of Expression (2) is disclosed.
The chemical composition of steels 1 to 18 in Table 1 was within the range of the chemical composition of the steel for induction hardening according to this embodiment. The chemical compositions of Steel 19 to Steel 30 were out of the range of the chemical composition of the steel for induction hardening according to this embodiment.

  After each steel ingot was once cooled to room temperature, each steel ingot was heated to a temperature in the temperature range of 1200 to 1300 ° C. according to the chemical composition. And the hot forging was implemented with respect to the heated steel ingot, and the round bar of diameter 80mm was manufactured. The finishing temperature during hot forging was 1000 ° C. or higher. The round bar after hot forging was allowed to cool to room temperature in the atmosphere.

  The normalizing process was implemented with respect to each manufactured round bar. Specifically, each round bar was heated at 850 ° C. for 30 minutes and then allowed to cool to room temperature in the atmosphere.

[Rolling fatigue test]
Using the round bars of steels 1 to 30 obtained in the above steps, the following rolling fatigue test was performed.

  FIG. 2A is a plan view of a test piece material (test material) 1 used in a rolling fatigue test. As shown in FIG. 2A, a disk-shaped test material 1 having a diameter D1 of 60 mm and a thickness of 10 mm was produced from the center of each round bar. The central axis of the test material 1 coincided with the central axis of the round bar. Of the surface of the test material 1, the inner diameter D2 of the annular region 10 was 35 mm, and the outer diameter D3 was 45 mm.

  Induction hardening was performed on the annular region 10 having a radius from the center of the surface of the test material 1 of 17.5 to 22.5 mm. As shown in FIG. 2B, the annular coil 2 formed in accordance with the shape of the annular region 10 was disposed immediately above the annular region 10. High frequency heating was performed while rotating the test material 1 in the direction of the arrow in FIG. 2B. The frequency during high-frequency heating was 30 kHz, the output was 100 kW, and the heating time was 1.7 seconds. The test material 1 after heating was water quenched. Tempering was performed on the test material 1 after quenching. Specifically, the test material 1 was heated at 150 ° C. for 1 hour and then allowed to cool in the air.

  Furthermore, in the test material 1 after tempering, the surface opposite to the surface on which induction hardening was performed was ground. Furthermore, the surface subjected to induction hardening was mirror-finished to produce a rolling fatigue test piece having a thickness of 5.0 mm.

  A rolling fatigue test was carried out with the mirror-finished surface of the surface of the rolling fatigue test piece being the test surface.

  For the rolling fatigue test, a Mori-type thrust type rolling fatigue tester was used. The test was carried out under conditions of a maximum contact surface pressure of 5230 MPa and a repetition rate of 1800 cpm (cycle per minute). The test part was an annular region having a radius of 19.25 mm from the center of the test surface. A SUJ2 tempered material defined in JIS G 4805 (2008) was used as a steel ball (counterball). In the rolling fatigue test, the number of stress repetitions until peeling was measured. Table 2 shows the detailed conditions of the rolling fatigue test.

Plot the rolling fatigue test results on paper Weibull distribution probability, it was to evaluate the L ₁₀ life that shows a 10 percent probability of failure as a "rolling contact fatigue life". When the L ₁₀ life satisfied 5.0 × 10 ⁶ or more, it was evaluated that the rolling fatigue life was excellent.

[Test results]
Table 3 shows the resulting L ₁₀ life in the above test.

In Table 3, the numerical value in the “L ₁₀ life” column describes the L ₁₀ life (× 10 ⁶ ) of each test number. With reference to Table 1 and Table 3, the chemical composition of the steels 1-18 of the test numbers 1-18 was appropriate, and Ca / O satisfy | filled Formula (1) and Formula (2). Therefore, the L ₁₀ life was 5.34 × 10 ⁶ or more, and an excellent rolling fatigue life was obtained.

On the other hand, in test number 19, Ca / O of steel 19 was as high as 2.25, exceeding the upper limit of formula (1). Therefore, likely to be formed is coarse oxides or point rows _{oxide, L 10} life was 5.0 × 10 than ⁶ (2.93 × 10 ^6).

In test number 20, Ca / O of steel 20 was as low as 0.52, which was less than the lower limit of formula (1). Therefore, it becomes easy to generate the specific Al _{oxide, L 10} life was 5.0 × 10 than ⁶ (1.20 × 10 ^6).

In test number 21, since Ca / O of steel 21 is 0.73 and 1250S-5.8 is 0.83, Ca / O is smaller than 1250S-5.8. Did not meet. Therefore, oxides in the steel tends to become _{coarse, L 10} life was less than ^{5.0 × 10 6 (3.36 × 10} 6).

In test number 22, the Ca content of steel 22 was too high at 0.0038%. Therefore, likely to be formed is coarse oxides and / or point rows _{oxide, L 10} life was less than ^{5.0 × 10 6 (1.46 × 10} 6).

In test number 23, the Ca content of steel 23 was too low at 0.0001%. Therefore, the oxide becomes that easy aggregation of the refractory, so that _{coarse, L 10} life was less than ^{5.0 × 10 6 (1.31 × 10} 6).

In test number 24, the O content of steel 24 was too high at 0.0041%. For this reason, a large amount of coarse oxide was easily generated, and the L ₁₀ life was less than 5.0 × 10 ⁶ (0.920 × 10 ⁶ ).

In test number 25, the S content of steel 25 was too high at 0.0220%. Therefore, a large amount of coarse sulfide is easily generated, and a large amount of Ca and S easily forms CaS, so that the amount of Ca that reacts with Al ₂ O ₃ tends to be small. Therefore, the L ₁₀ life was less than 5.0 × 10 ⁶ (0.765 × 10 ⁶ ).

In test number 26, the Cr content of steel 26 was too high at 1.03%. Therefore, without high frequency quenched portion is uniformly _{cured, L 10} life was less than ^{5.0 × 10 6 (3.25 × 10} 6).

In test number 27, the C content of steel 27 was too high at 0.71%. Therefore, the toughness of the induction-hardened part was lowered, and the L ₁₀ life was less than 5.0 × 10 ⁶ (2.02 × 10 ⁶ ).

In test number 28, the C content of steel 28 was too low at 0.27%. Therefore, sufficient hardness was obtained at a high frequency quenched _{portion, L 10} life was less than ^{5.0 × 10 6 (1.14 × 10} 6).

In test number 29, although steel 29 contained Cu and Ni in order to increase the hardness of the rolling part after induction hardening, Ca / O was as high as 2.71 and exceeded the upper limit of formula (1). Therefore, likely to be formed is coarse oxides or point rows _{oxide, L 10} life was less than ^{5.0 × 10 6 (2.21 × 10} 6).

In test number 30, although steel 30 contained Nb for the purpose of suppressing coarsening of crystal grains in the quenched portion, Ca / O was as low as 0.46, which was less than the lower limit of formula (1). Therefore, oxides are easily _{coarsened, L 10} life was less than ^{5.0 × 10 6 (1.36 × 10} 6).

  The embodiment of the present invention has been described above. The above-described embodiments are merely examples for carrying out the present invention. Therefore, the present invention is not limited to the above-described embodiment, and can be implemented by appropriately modifying the above-described embodiment without departing from the spirit thereof.

  The steel material for induction hardening according to this embodiment has good durability against breakage due to rolling fatigue and has an excellent rolling fatigue life even under severe use environments of rolling members in recent years. For this reason, the steel for induction hardening according to the present embodiment is widely applicable to applications requiring excellent rolling fatigue life, and particularly induction hardening such as “constant velocity joints” and “hub units” used as automobile parts. Can be suitably used as a material of a rolling member on which the above is implemented.

Claims (7)

% By mass
C: 0.4 to 0.6%
Si: 0.03-1.0%,
Mn: 0.2 to 2.0%,
P: 0.05% or less,
S: less than 0.010%,
Cr: 0.05 to 0.50%,
Al: 0.01 to 0.10%,
Ca: 0.0003 to 0.0030%,
O: 0.0030% or less,
N: 0.003-0.030%,
Cu: 0 to 1.0%
Ni: 0 to 3.0%,
Mo: 0 to 0.15%,
V: 0 to 0.30%,
Nb: 0 to 0.10%,
B: 0 to 0.0030% and
Ti: 0 to 0.10% contained,
The balance consists of Fe and impurities,
A steel material for induction hardening having a chemical composition satisfying the formulas (1) and (2).
0.7 ≦ Ca / O ≦ 2.0 (1)
Ca / O ≧ 1250S−5.8 (2)
Here, the content (mass%) of the corresponding element is substituted for the element symbols in the formulas (1) and (2). The steel for induction hardening according to claim 1,
The chemical composition is
C: Steel for induction hardening containing 0.48 to 0.6%. The steel for induction hardening according to claim 2,
The chemical composition is
C: Steel for induction hardening containing 0.50 to 0.6%. The steel material for induction hardening according to any one of claims 1 to 3,
The chemical composition is
N: Steel material for induction hardening containing more than 0.0050% to 0.030%. The steel material for induction hardening according to any one of claims 1 to 4,
The chemical composition is
Cu: 0.05 to 1.0%,
Ni: 0.05-3.0% and
Mo: Steel material for induction hardening, containing one or more selected from the group consisting of 0.02 to 0.15%. The steel material for induction hardening according to any one of claims 1 to 5,
The chemical composition is
V: 0.01-0.30% and
Nb: A steel material for induction hardening containing one or two selected from the group consisting of 0.01 to 0.10%. The steel material for induction hardening according to any one of claims 1 to 6,
The chemical composition is
B: 0.0005 to 0.0030% and
Ti: Steel material for induction hardening containing 0.01 to 0.10%.

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