JPWO2007142232A1 - Swimsuit and manufacturing method thereof - Google Patents

Swimsuit and manufacturing method thereof Download PDF

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JPWO2007142232A1
JPWO2007142232A1 JP2008520587A JP2008520587A JPWO2007142232A1 JP WO2007142232 A1 JPWO2007142232 A1 JP WO2007142232A1 JP 2008520587 A JP2008520587 A JP 2008520587A JP 2008520587 A JP2008520587 A JP 2008520587A JP WO2007142232 A1 JPWO2007142232 A1 JP WO2007142232A1
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water
swimsuit
absorbing gel
repellent
particles
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JP4839372B2 (en
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松崎 健
健 松崎
尚和 弓削
尚和 弓削
敏昭 清水
敏昭 清水
星人 久保田
星人 久保田
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Mizuno Corp
Toray Industries Inc
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Mizuno Corp
Toray Industries Inc
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D7/00Bathing gowns; Swim-suits, drawers, or trunks; Beach suits
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2400/00Functions or special features of garments
    • A41D2400/24Reducing drag or turbulence in air or water

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

本発明の水着は、伸縮性生地からなり、多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子が、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に固定されている。これにより、伸縮性生地の繊維表面に親水性を付与した水着を提供する。吸水ゲル樹脂は多孔質無機粒子に吸着していることにより、水に濡れても吸水ゲル樹脂は見掛け上の膨潤は起こさず、寸法変化も起こらず、親水性が付与される。吸水ゲル吸着粒子が固定された部分(1)は親水性となり、水との親和性が高まり、水抜け性も向上して、全体として水との摩擦抵抗が低下する。The swimsuit of the present invention is made of a stretchable fabric, and water-absorbing gel adsorbing particles in which a water-absorbing gel resin is adsorbed to porous inorganic particles are fixed to at least a part of the surface of the stretchable fabric together with a binder resin. Thereby, the swimsuit which provided hydrophilicity to the fiber surface of elastic cloth is provided. Since the water-absorbing gel resin is adsorbed on the porous inorganic particles, the water-absorbing gel resin does not swell apparently and does not change in size even when it gets wet, and is imparted with hydrophilicity. The part (1) to which the water-absorbing gel adsorbent particles are fixed becomes hydrophilic, increases the affinity with water, improves the drainage property, and reduces the frictional resistance with water as a whole.

Description

本発明は、繊維表面に親水性を付与した水着及びその製造方法に関する。   The present invention relates to a swimsuit in which hydrophilicity is imparted to the fiber surface and a method for producing the same.

水着に求められる一つの機能は、競泳時に生ずる水着の水中での表面摩擦抵抗をいかに削減するかにあり、従来から、水着の表面摩擦抵抗を削減する技術が種々提案されている。例えば、特許文献1には分子量4,000,000〜5,000,000のポリエチレンモノオキサイドを水溶液にして水着の表面に付着させている。しかし、この技術は付着ポリマーが水中で溶け出しプールの水を汚すという問題があった。また、水着の全面に撥水加工をし、さらに任意の位置にバインダ樹脂を使用して親水性加工をすることが特許文献2で提案されている。しかし、バインダ樹脂のみでは、親水性が不十分であり、表面の摩擦抵抗を低減することができないという問題があった。さらに別の提案として、生地表面の摩擦抵抗を削減し、水抜け性も確保する目的で、生地表面に撥水部分と非撥水部分を設ける技術が特許文献3〜4に開示されている。   One function required for a swimsuit is to reduce the surface frictional resistance of the swimsuit that occurs during swimming, and various techniques for reducing the surface frictional resistance of the swimsuit have been proposed. For example, in Patent Document 1, polyethylene monooxide having a molecular weight of 4,000,000 to 5,000,000 is made into an aqueous solution and attached to the surface of a swimsuit. However, this technique has a problem that the adhered polymer dissolves in the water and pollutes the water in the pool. Further, Patent Document 2 proposes that a water repellent process is performed on the entire surface of the swimsuit and a hydrophilic process is performed using a binder resin at an arbitrary position. However, the binder resin alone has a problem that the hydrophilicity is insufficient and the frictional resistance of the surface cannot be reduced. As another proposal, Patent Documents 3 to 4 disclose techniques for providing a water-repellent portion and a non-water-repellent portion on the fabric surface for the purpose of reducing the frictional resistance on the fabric surface and ensuring water drainage.

従来技術において、生地表面に撥水部と非撥水部を設けることで抵抗減少効果は発現する。また、撥水面積を多くすることで摩擦抵抗減少の効果は増大するが、逆に水着内に浸入した水の水抜け性が低下し、着用抵抗が増大する傾向にあった。そのため、ストライプ状の撥水部の幅を広くし、非撥水部分の占める面積比を小さくすると、摩擦抵抗減少の効果が水抜け性の低下による着用抵抗の増加によって相殺され、相対的に抵抗が増大してしまうという問題があった。   In the prior art, the resistance reduction effect is exhibited by providing a water-repellent part and a non-water-repellent part on the fabric surface. Further, increasing the water repellent area increases the effect of reducing the frictional resistance, but conversely, the water drainage property of the water that has entered the bathing suit is lowered and the wearing resistance tends to increase. Therefore, if the width of the striped water-repellent part is widened and the area ratio occupied by the non-water-repellent part is reduced, the effect of reducing the frictional resistance is offset by the increase in wearing resistance due to the decrease in water drainage, and the relative resistance There has been a problem that increases.

また、撥水面積を増やす為に、ストライプ状の非撥水部にストライプ方向に断続的に撥水部を設け、所謂、梯子状に撥水部を形成した場合、撥水面積の増加による抵抗減少効果はあるものの、梯子状撥水部の横木に相当する部分が水泳時に水の流れに直交する為、摩擦抵抗減少効果が小さいといった問題があった。これを改良するため、水着表面の少なくとも一部分に、連続的に撥水加工を施した連続撥水部分と、撥水加工を施した撥水部と撥水加工を施していない非撥水部とを断続的に形成した断続撥水部とを体長方向に平行なストライプ状に形成することが提案されている(特許文献5)。
特許第2715088号公報 特開2004−292962号公報 特開平8−311751号公報 特開平9−49107号公報 特開2000−226709号公報
In addition, in order to increase the water-repellent area, when the water-repellent part is intermittently provided in the stripe direction in the stripe-shaped non-water-repellent part and the water-repellent part is formed in a so-called ladder shape, the resistance due to the increase in the water-repellent area Although there is a reduction effect, there is a problem that the frictional resistance reduction effect is small because the portion corresponding to the rung of the ladder-like water repellent portion is orthogonal to the water flow during swimming. In order to improve this, at least a part of the swimsuit surface has a continuous water-repellent part that has been subjected to continuous water-repellent treatment, a water-repellent part that has been subjected to water-repellent process, and a non-water-repellent part that has not been subjected to water-repellent process. It has been proposed to form intermittent water-repellent portions formed intermittently in stripes parallel to the body length direction (Patent Document 5).
Japanese Patent No. 2715088 Japanese Patent Application Laid-Open No. 2004-292962 JP-A-8-311751 JP-A-9-49107 JP 2000-226709 A

前記のように従来から水着は様々に改良されてきたが、水中における摩擦抵抗をさらに改良することが求められている。   As described above, swimwear has been variously improved, but there is a demand for further improving the frictional resistance in water.

本発明者らは、水中に生息する魚類や鯨などの哺乳類の皮膚や鱗が本質的に親水性であることを注目した。本発明は、基本的な考え方を見直し、伸縮性生地の繊維表面に親水性を付与した水着及びその製造方法を提供する。   The inventors have noted that the skin and scales of mammals such as fish and whales that live in water are essentially hydrophilic. The present invention reviews the basic idea and provides a swimsuit in which hydrophilicity is imparted to the fiber surface of a stretchable fabric and a method for producing the same.

本発明の水着は、伸縮性生地からなる水着であって、多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子が、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に固定されていることを特徴とする。   The swimsuit of the present invention is a swimsuit made of stretchable fabric, wherein water-absorbing gel adsorbent particles in which a water-absorbing gel resin is adsorbed on porous inorganic particles are fixed to at least a part of the surface of the stretchable fabric together with a binder resin. It is characterized by being.

本発明の水着の製造方法は、伸縮性生地からなる水着の製造方法であって、多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子を、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に付与することを特徴とする。   The method for producing a swimsuit according to the present invention is a method for producing a swimsuit comprising a stretchable fabric, wherein the water-absorbing gel adsorbent particles in which the water-absorbent gel resin is adsorbed on the porous inorganic particles are combined with at least the surface of the stretchable fabric together with the binder resin It is given to a part.

図1Aは本発明の一実施例の女性用水着の正面図、図1Bは同背面図である。FIG. 1A is a front view of a female swimsuit according to an embodiment of the present invention, and FIG. 1B is a rear view thereof. 図2は図1の拡大図であり、親水性生地の部分とその表面の断続的形状の撥水性部分を配置した状態を示す。FIG. 2 is an enlarged view of FIG. 1, showing a state in which a hydrophilic fabric portion and an intermittently formed water-repellent portion on the surface thereof are arranged. 図3は本発明実施例で使用した水中における表面摩擦抵抗試験装置の概略説明図である。FIG. 3 is a schematic explanatory view of a surface friction resistance test apparatus in water used in the embodiment of the present invention. 図4Aは本発明の別の実施例における男性用水着の正面図、図4Bは同側面図、図4Cは同背面図である。4A is a front view of a men's swimsuit according to another embodiment of the present invention, FIG. 4B is a side view thereof, and FIG. 4C is a rear view thereof. 図5は本発明の一実施例における多孔質無機粒子(凝集粒子)の模式的概念図である。FIG. 5 is a schematic conceptual view of porous inorganic particles (aggregated particles) in one embodiment of the present invention. 図6は本発明の別の実施例における水着生地の模様を示す。FIG. 6 shows a pattern of a swimsuit fabric according to another embodiment of the present invention. 図7は本発明の別の実施例における水着生地の模様を示す。FIG. 7 shows a pattern of a swimsuit fabric according to another embodiment of the present invention. 図8は本発明の別の実施例における水着生地の模様を示す。FIG. 8 shows a pattern of a swimsuit fabric according to another embodiment of the present invention.

本発明の水着は、多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子が、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に固定されている。吸水ゲル樹脂は多孔質無機粒子に吸着していることにより、水に濡れても吸水ゲル樹脂は見掛け上の膨潤は起こさず、寸法変化も起こらないため、抵抗を生じず、単に親水性が付与されるだけである。この結果、吸水ゲル吸着粒子が固定された部分は親水性となる。以下、かかる粒子が固定された部分を「親水性部分」という。これにより水との親和性が高まり、水抜け性も向上して、全体として水との摩擦抵抗が低下する。また、吸水ゲル樹脂だけでは例えバインダ樹脂と併用しても生地に耐久性高く固定することは困難であるが、多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子がバインダ樹脂とともに伸縮性生地に固定されていることにより、生地に耐久性高く固定できる。この結果、耐久性の高い親水性表面が得られる。   In the swimsuit of the present invention, the water-absorbing gel adsorbing particles in which the water-absorbing gel resin is adsorbed on the porous inorganic particles are fixed to at least a part of the surface of the stretchable fabric together with the binder resin. Since the water-absorbing gel resin is adsorbed on the porous inorganic particles, the water-absorbing gel resin does not swell apparently and does not change in size even when it gets wet. It is only done. As a result, the portion where the water-absorbing gel adsorbing particles are fixed becomes hydrophilic. Hereinafter, the part to which such particles are fixed is referred to as “hydrophilic part”. Thereby, the affinity with water is increased, the water drainage is improved, and the frictional resistance with water is lowered as a whole. In addition, it is difficult to fix to the fabric with high durability even if it is used in combination with the binder resin alone, but the water-absorbing gel adsorbent particles in which the water-absorbing gel resin is adsorbed on the porous inorganic particles are expanded and contracted together with the binder resin. By being fixed to the sex cloth, it can be fixed to the cloth with high durability. As a result, a highly durable hydrophilic surface is obtained.

本発明の水着は、多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子が、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に固定されている。吸水ゲル樹脂は、通常おむつなどの内部に使用されており、自重の数倍〜数百倍の水を吸収し、吸収した分膨潤する性質を有する。しかし、吸水ゲル樹脂を単独で使用すると、水を吸収して膨潤し、水との摩擦抵抗が上がると考えられる。このため本発明においては、吸水ゲル樹脂を多孔質無機粒子に吸着させて使用する。   In the swimsuit of the present invention, the water-absorbing gel adsorbing particles in which the water-absorbing gel resin is adsorbed on the porous inorganic particles are fixed to at least a part of the surface of the stretchable fabric together with the binder resin. The water-absorbing gel resin is usually used in a diaper or the like, and has a property of absorbing water several times to several hundred times as much as its own weight and swelling due to absorption. However, it is considered that when the water-absorbing gel resin is used alone, it absorbs water and swells to increase the frictional resistance with water. Therefore, in the present invention, the water-absorbing gel resin is used by being adsorbed on the porous inorganic particles.

吸水ゲル樹脂を多孔質無機粒子に吸着させるには、例えばシリカ(SiO2)、ゼオライト、アルミナ(Al23)粒子、炭酸カルシウム、窒化ホウ素、雲母、チタニア(TiO2)、ジルコニア、活性炭等の多孔質無機粒子粉体に、飽和吸水させたゲル樹脂を混合し、乾燥することにより得られる。前記多孔質無機粒子粉体は、一次粒子をそのまま使用しても良いし(例えば活性炭)、一次粒子を凝集させた凝集粒子(例えばシリカ)でも良い。凝集粒子を使用する場合は、一次粒子に吸水させたゲル樹脂を混合し、乾燥時に一次粒子を凝集させて凝集粒子を形成することにより得られる。前記において、一次粒子は必ずしも多孔質である必要はなく、凝集粒子にしたときに吸水ゲル樹脂を内部に含む程度の多孔質で良い。In order to adsorb the water-absorbing gel resin to the porous inorganic particles, for example, silica (SiO 2 ), zeolite, alumina (Al 2 O 3 ) particles, calcium carbonate, boron nitride, mica, titania (TiO 2 ), zirconia, activated carbon, etc. The porous inorganic particle powder is mixed with a saturated water-absorbing gel resin and dried. As the porous inorganic particle powder, primary particles may be used as they are (for example, activated carbon) or aggregated particles (for example, silica) obtained by aggregating the primary particles. In the case of using aggregated particles, the primary particles are mixed with water-absorbed gel resin, and the primary particles are aggregated during drying to form aggregated particles. In the above, the primary particles do not necessarily need to be porous, and may be porous to the extent that the water-absorbing gel resin is contained inside when the aggregated particles are formed.

本発明の吸水ゲル樹脂は、高吸水性樹脂ともいい、親水性の直鎖状あるいは分岐状高分子の架橋体であり、オングストローム単位の三次元網目構造を持ち、水と接触すると水に溶けようとする力で吸水するが、分子間に架橋構造があるため抑制され、そのバランスにより、一定量給水した膨潤状態のヒドロゲルとなる。このように吸水した水は、スポンジや綿状パルプのように多孔質の穴や毛細管現象により取り込まれた水と違い、圧力をかけても離水しにくい。その吸水量が樹脂1gあたり10g以上のものを一般に高吸水性樹脂という。   The water-absorbing gel resin of the present invention is also referred to as a highly water-absorbing resin, and is a crosslinked body of a hydrophilic linear or branched polymer, has a three-dimensional network structure in angstrom units, and dissolves in water when contacted with water. However, it is suppressed because of the cross-linked structure between the molecules, and due to the balance, a hydrogel in a swollen state in which a certain amount of water is supplied is obtained. The water absorbed in this way is unlikely to separate even when pressure is applied, unlike water taken in by porous holes or capillarity such as sponge or cotton-like pulp. Those having a water absorption of 10 g or more per 1 g of resin are generally called highly water-absorbing resins.

吸水ゲル樹脂と多孔質無機粒子粉体との配合割合は、後に水着が濡れたときに粉体粒子から吸水ゲル樹脂が膨潤して外に出ない程度に両者の体積割合を調整する。例えば、吸水により35倍に膨潤する吸水ゲル樹脂の場合は、粉体粒子の空隙(ポアー)100体積%あたり乾燥体積換算で約2〜6体積%吸着させる。あるいは、粉体粒子の空隙(ポアー)体積100体積%あたり、飽和吸水させた吸水ゲル樹脂の体積を50〜250体積%の範囲とする。吸水ゲル樹脂を少し多く配合しても良い理由は、多孔質無機粒子の空隙(ポアー)内では、完全な吸水ができないこともあるからである。吸水ゲル樹脂を多孔質無機粒子に吸着させるときにはバインダ樹脂を混合しても良い。バインダ樹脂としては、N−メチロール(尿素)系、スルホン系、エポキシ系、グリオキザール系、ポリカルボン酸系、アクリル系、アクリルシリコン系、及びウレタン系等の樹脂が使用できる。   The mixing ratio of the water-absorbing gel resin and the porous inorganic particle powder is adjusted so that the water-absorbing gel resin swells from the powder particles and does not come out when the swimsuit is later wetted. For example, in the case of a water-absorbing gel resin that swells 35 times by water absorption, about 2 to 6% by volume in terms of dry volume is adsorbed per 100% by volume of pores of the powder particles. Alternatively, the volume of the water-absorbing gel resin with saturated water absorption is set in the range of 50 to 250% by volume per 100% by volume of the pores of the powder particles. The reason why a little more water-absorbing gel resin may be blended is that complete water absorption may not be possible in the pores of the porous inorganic particles. When adsorbing the water-absorbing gel resin to the porous inorganic particles, a binder resin may be mixed. As the binder resin, resins such as N-methylol (urea), sulfone, epoxy, glyoxal, polycarboxylic acid, acrylic, acrylic silicon, and urethane can be used.

多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子は、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に固定される。バインダ樹脂としては、N−メチロール(尿素)系、スルホン系、エポキシ系、グリオキザール系、ポリカルボン酸系、アクリル系、アクリルシリコン系、及びウレタン系等の樹脂が使用できる。これらの樹脂は風合いを損なわないように選択する。   The water-absorbing gel adsorption particles in which the water-absorbing gel resin is adsorbed on the porous inorganic particles are fixed to at least a part of the surface of the stretchable fabric together with the binder resin. As the binder resin, resins such as N-methylol (urea), sulfone, epoxy, glyoxal, polycarboxylic acid, acrylic, acrylic silicon, and urethane can be used. These resins are selected so as not to impair the texture.

本発明において、吸水ゲル吸着粒子は伸縮性生地の表面の少なくとも一部に固定されていればよい。好ましくは、水着の表面に対して吸水ゲル吸着粒子は10%以上の面積に固定する。さらに好ましくは50%以上の面積であり、とくに好ましくは、70%以上の面積である。   In the present invention, the water-absorbing gel adsorbing particles may be fixed to at least a part of the surface of the stretchable fabric. Preferably, the water-absorbing gel adsorbing particles are fixed to an area of 10% or more with respect to the surface of the swimsuit. The area is more preferably 50% or more, and particularly preferably 70% or more.

吸水ゲル吸着粒子はバインダ樹脂とともに分散液とし、浸漬により伸縮性生地に付与することができる。この場合は伸縮性生地の全面に吸着ゲル粒子は固定される。また、吸水ゲル吸着粒子はバインダ樹脂とともに分散液とし、プリントにより伸縮性生地に付与することもできる。この場合は、伸縮性生地の表面の一部に固定できる。   The water-absorbing gel adsorbing particles can be made into a dispersion together with the binder resin and applied to the stretchable fabric by dipping. In this case, the adsorption gel particles are fixed on the entire surface of the stretchable fabric. Further, the water-absorbing gel adsorbing particles can be made into a dispersion together with the binder resin and applied to the stretchable fabric by printing. In this case, it can be fixed to a part of the surface of the stretchable fabric.

多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子の伸縮性生地への付着量は、生地の種類にもよるが、5〜20g/m2が好ましい。バインダ樹脂の伸縮性生地への付着量は、0.5〜20g/m2が好ましい。The amount of the water-absorbing gel adsorbent particles in which the water-absorbing gel resin is adsorbed on the porous inorganic particles is preferably 5 to 20 g / m 2 although it depends on the kind of the fabric. Adhesion amount of the binder resin of the stretch fabric, 0.5 to 20 g / m 2 is preferred.

吸水ゲル樹脂は、おむつの材料として使用できるものであればどのようなものでも良く、例えばアクリル酸と、ポリエチレングリコールジアクリレートと、ジエチレントリアミン5酢酸・5ナトリウム水溶液を混合した溶液と、水酸化ナトリウム水溶液と、過硫酸ナトリウム水溶液を混合して重合させ、架橋構造を有する吸水ゲル樹脂がある。   The water-absorbing gel resin may be any material as long as it can be used as a material for diapers. For example, a solution obtained by mixing acrylic acid, polyethylene glycol diacrylate, diethylenetriaminepentaacetic acid / 5 sodium solution, and sodium hydroxide solution And a water-absorbing gel resin having a crosslinked structure by mixing and polymerizing an aqueous sodium persulfate solution.

本発明の水着表面の少なくとも一部には、さらに撥水性部分を含んでいても良い。撥水剤としては、シリコーン系撥水剤、フッ素系撥水剤等を使用できる。また、撥水部分に用いられる処理剤は、プリント剤、シーリング剤といった名称のものでもよい。   At least a part of the swimsuit surface of the present invention may further contain a water-repellent part. As the water repellent, silicone water repellent, fluorine water repellent and the like can be used. The treatment agent used for the water repellent portion may have a name such as a printing agent or a sealing agent.

撥水性部分と親水性部分とは、水着の体長方向に沿って連続状に形成されていても良いし、断続状に形成されていても良い。さらに連続状と断続状を混在させても良い。親水性部分を存在させると、水抜け性に優れる。   The water-repellent part and the hydrophilic part may be formed continuously along the body length direction of the swimsuit or may be formed intermittently. Further, a continuous state and an intermittent state may be mixed. When a hydrophilic portion is present, water drainage is excellent.

生地表面に前記撥水性部分を形成するには、一般的に工業化されているプリント処方が好適であり、用いられる装置としては、ローラー捺染機、オートスクリーン捺染機、ハンドスクリーン捺染機等から適宜選択される。   In order to form the water-repellent part on the surface of the fabric, a generally industrialized print formulation is suitable, and the apparatus used is appropriately selected from a roller printing machine, an auto screen printing machine, a hand screen printing machine, etc. Is done.

生地への撥水剤の塗布量は、基布の目付、厚さ、撥水加工面積、及び撥水剤の種類などにより異なるが、5〜20g/m2が好ましい。The amount of the water repellent applied to the fabric varies depending on the basis weight of the base fabric, the thickness, the water repellent processed area, the type of the water repellent and the like, but is preferably 5 to 20 g / m 2 .

撥水性部分と親水性部分の面積比は、親水性部分:撥水性部分=10〜90:90〜10、より好ましくは50〜80:50〜20、さらに好ましくは60〜80:40〜20、とくに好ましくは70〜80:30〜20の範囲である。親水性部分の面積が広いほうが好ましく、親水性部分を浸漬法で全面に形成し、その上に撥水性部分をプリントにより形成するのが好ましい。   The area ratio between the water-repellent part and the hydrophilic part is as follows: hydrophilic part: water-repellent part = 10 to 90:90 to 10, more preferably 50 to 80:50 to 20, further preferably 60 to 80:40 to 20, Especially preferably, it is the range of 70-80: 30-20. It is preferable that the hydrophilic portion has a large area. It is preferable that the hydrophilic portion is formed on the entire surface by a dipping method, and the water-repellent portion is formed thereon by printing.

本発明においては、さらに水着の裏面に撥水性部分を形成しても良い。裏面に撥水性部分を形成する場合は、裏面における撥水性部分の面積割合が10〜90%の範囲であるのが好ましい。このようにすると、水着の生地自体の保水率が低下し、水の抵抗をさらに下げることができる。裏面に撥水性部分を形成する場合は、表面と同様に連続状又は断続状のパターンが採用でき、例えば縦ストライプ状、横ストライプ状(ボーダー柄)、斜めストライプ状、水玉模様、格子柄、又はこれらを任意に組み合わせたデザインなどが適用できる。   In the present invention, a water repellent portion may be further formed on the back surface of the swimsuit. When forming the water-repellent part on the back surface, the area ratio of the water-repellent part on the back surface is preferably in the range of 10 to 90%. In this way, the water retention rate of the fabric of the swimsuit itself can be reduced, and the water resistance can be further reduced. When forming a water-repellent part on the back surface, a continuous or intermittent pattern can be adopted like the front surface, for example, a vertical stripe shape, a horizontal stripe shape (border pattern), an oblique stripe shape, a polka dot pattern, a lattice pattern, or A design combining these arbitrarily can be applied.

本発明の水着に用いられる生地は、ポリアミド系、ポリエステル系、ポリプロピレン系などの合成繊維マルチフィラメント糸条、または、これらの合成繊維マルチフィラメント糸条とポリウレタン弾性糸条の交編、あるいは交織よりなる編物、織物を用いることが出来る。特に競泳用水着は動きやすさが重要視される場合も多く、素材形態としては合成繊維マルチフィラメント糸条とポリウレタン弾性糸条の交編による編物がより好ましい。また、この編物形態としては、丸編地であるシングル丸編地、ダブル丸編地、経編地であるトリコット地、ラッセル地のいずれも用いることができるが、動きやすさに影響するストレッチ性、生地薄さ等の観点からトリコット地がより好ましい。これを通常の染色加工法により、染色仕上げして、伸縮性生地とする。   The fabric used for the swimsuit of the present invention is made of synthetic fiber multifilament yarns such as polyamide, polyester and polypropylene, or knitting or weaving of these synthetic fiber multifilament yarns and polyurethane elastic yarns. Knitted fabrics and woven fabrics can be used. In particular, swimsuits for swimming often place importance on easiness of movement, and as a material form, a knitted fabric obtained by knitting synthetic fiber multifilament yarn and polyurethane elastic yarn is more preferable. In addition, as the knitted fabric form, a single circular knitted fabric that is a circular knitted fabric, a double circular knitted fabric, a tricot fabric that is a warp knitted fabric, or a russell fabric can be used, but stretch properties that affect the ease of movement. Tricot fabric is more preferable from the viewpoint of fabric thinness. This is dyed and finished by an ordinary dyeing method to obtain a stretchable fabric.

本発明の水着は競泳用に好適である。   The swimsuit of the present invention is suitable for swimming.

次に本発明の水着を構成する伸縮性生地とその物性について説明する。   Next, the stretchable fabric constituting the swimsuit of the present invention and its physical properties will be described.

(1)伸縮性
JIS1096で測定した4.9N(500gf)荷重時の伸長率は、経方向及び緯方向から選ばれる少なくとも一方が5〜150%の範囲の編み物が好ましい。この範囲であれば身体の動きに追従し着用性が高い。
(1) Stretchability As for the elongation at the time of 4.9N (500 gf) load measured according to JIS1096, a knitted fabric in which at least one selected from the warp direction and the weft direction is in the range of 5 to 150% is preferable. If it is in this range, it follows the movement of the body and is highly wearable.

(2)目付け
伸縮性生地の目付けは100〜400g/m2の範囲が好ましい。この範囲であれば透けなどの問題を起こさず、審美性に適しており、また重量感もなく着用性が高い。
(2) weight of the basis weight stretchable fabric is preferably in the range of 100 to 400 g / m 2. Within this range, problems such as sheer do not occur, it is suitable for aesthetics, and there is no feeling of weight and wearability is high.

以下図面を用いて説明する。図1Aは本発明の一実施例における女性用水着の正面図、図1Bは同背面図である。この水着は、親水性生地の部分1とその表面の断続状の撥水性部分2からなる。親水性生地の部分1は浸漬法により吸水ゲル吸着粒子をバインダ樹脂とともに生地に付着させ、固定することにより得られる。撥水性部分2は、撥水性樹脂をプリントして形成できる。   This will be described below with reference to the drawings. FIG. 1A is a front view of a women's swimsuit according to one embodiment of the present invention, and FIG. 1B is a rear view thereof. This swimsuit is composed of a hydrophilic fabric portion 1 and an intermittent water-repellent portion 2 on the surface thereof. The hydrophilic fabric portion 1 is obtained by adhering water-absorbing gel adsorbent particles together with a binder resin to the fabric by an immersion method and fixing the particles. The water repellent portion 2 can be formed by printing a water repellent resin.

図2は図1A−Bの拡大図であり、親水性生地の部分1とその表面の断続状の撥水性部分2の配置と形状を示す。図2において、撥水性部分2の幅L2は一例として12mm、撥水性部分2,2の間隔L1は10mmである。また、親水性部分1と撥水性部分2の面積割合は、親水性部分1:撥水性部分2=75:25である。   FIG. 2 is an enlarged view of FIGS. 1A-B and shows the arrangement and shape of the hydrophilic fabric portion 1 and the intermittent water-repellent portion 2 on the surface thereof. In FIG. 2, the width L2 of the water repellent portion 2 is 12 mm as an example, and the interval L1 between the water repellent portions 2 and 2 is 10 mm. The area ratio of the hydrophilic portion 1 and the water repellent portion 2 is hydrophilic portion 1: water repellent portion 2 = 75: 25.

図3は本発明の実施例で使用した水中における表面摩擦抵抗試験装置の概略説明図である。   FIG. 3 is a schematic explanatory view of a surface frictional resistance test apparatus in water used in the examples of the present invention.

図4Aは本発明の別の実施例における男性用水着の正面図、図4Bは同側面図、図4Cは同背面図である。この水着の模様と親水性生地の部分とその表面の断続状の撥水性部分は図1−2と同様である。   4A is a front view of a men's swimsuit according to another embodiment of the present invention, FIG. 4B is a side view thereof, and FIG. 4C is a rear view thereof. The swimsuit pattern, the hydrophilic fabric portion, and the intermittent water-repellent portion of the surface are the same as in FIG.

図5は本発明の一実施例における多孔質無機粒子(凝集粒子)の模式的概念図である。この多孔質無機粒子(凝集粒子)5は、無機一次粒子4の間に吸水ゲル樹脂3が存在しており、水と接触すると吸水ゲル樹脂3は所定量の水を吸収し、多孔質無機粒子(凝集粒子)5全体が親水性となる。ただし、吸水ゲル樹脂3は多孔質無機粒子(凝集粒子)5内に存在するので、多孔質無機粒子(凝集粒子)5自体は、水の吸収にともなう見かけ上の膨潤は起こらない。   FIG. 5 is a schematic conceptual view of porous inorganic particles (aggregated particles) in one embodiment of the present invention. The porous inorganic particles (aggregated particles) 5 include the water-absorbing gel resin 3 between the inorganic primary particles 4. When the water-absorbing gel resin 3 contacts with water, the water-absorbing gel resin 3 absorbs a predetermined amount of water. The (aggregated particles) 5 as a whole becomes hydrophilic. However, since the water-absorbing gel resin 3 is present in the porous inorganic particles (aggregated particles) 5, the porous inorganic particles (aggregated particles) 5 themselves do not swell apparently due to the absorption of water.

図6〜8は本発明の別の実施例における水着生地の模様を示す。この水着生地は、体長方向に断続状模様の親水性生地の部分1とその表面の連続的なストライプ状の撥水性部分2を設けた。この生地から縫製される水着も図1、図2、図4と同様に撥水性と水抜け性がバランスし、好適な水着が得られる。   6-8 shows the pattern of the swimsuit cloth in another example of the present invention. This swimsuit fabric is provided with a hydrophilic fabric portion 1 having an intermittent pattern in the body length direction and a continuous striped water-repellent portion 2 on the surface thereof. Similar to FIGS. 1, 2 and 4, the swimsuit sewn from this fabric balances water repellency and water drainage, and a suitable swimsuit can be obtained.

以下、本発明の実施例について述べるが、本発明はこれらに限定されるものではない。   Examples of the present invention will be described below, but the present invention is not limited thereto.

下記の実施例及び比較例における親水性、疎水性、撥水性は、水滴下吸収時間により測定した。温度25℃、相対湿度65%RHの条件下で、伸縮性生地を自然状態で水平に置き、上方30cmの高さからスポイトで0.05mlの蒸留水を滴下し、生地上の水滴が水による光反射をしなくなった時までの時間(吸水時間)により、10点測定した平均時間で判断した。親水性は3分未満、好ましくは2分未満、さらに好ましくは1分未満である。疎水性は3分以上15分未満、撥水性は15分以上経過しても生地の中に水を吸収しない状態(以下「無限大」という。)である。   The hydrophilicity, hydrophobicity, and water repellency in the following Examples and Comparative Examples were measured by the water dropping absorption time. Under the conditions of a temperature of 25 ° C. and a relative humidity of 65% RH, the stretchable fabric is placed horizontally in a natural state, 0.05 ml of distilled water is dropped with a dropper from a height of 30 cm above, and water droplets on the fabric are caused by water. Judgment was made based on the average time measured at 10 points according to the time until the light was no longer reflected (water absorption time). The hydrophilicity is less than 3 minutes, preferably less than 2 minutes, more preferably less than 1 minute. Hydrophobicity is 3 minutes or more and less than 15 minutes, and water repellency is a state where water is not absorbed into the fabric even after 15 minutes or more (hereinafter referred to as “infinite”).

(実施例1)
(1)水着の生地
女性水着用の伸縮性生地として、ポリエステル繊維80重量%、ポリウレタン繊維20重量%のツーウエイ編み物(美津濃社製JASPO製品に使用されている編み物と同様な編み物で、生地厚み平均0.54mm、目付け245g/cm2、JIS1096で測定した4.9N荷重時の伸長率が経方向50%、緯方向20%、17.6N荷重時の伸長率が経方向110%、緯方向90%)を使用した。
(Example 1)
(1) Swimwear fabric Two-way knitted fabric with 80% by weight polyester fiber and 20% by weight polyurethane fiber as a stretchable fabric for women's swimwear (similar to the knitting used in JASPO products by Mitsunosha) 0.54 mm, weight per unit area 245 g / cm 2 , measured by JIS 1096, the elongation at 4.9N load was 50% in the warp direction, 20% in the weft direction, the elongation at 17.6N load was 110% in the warp direction, 90% in the weft direction %)It was used.

(2)親水性処理
吸水ゲル吸着粒子として、凝集粒子の平均粒子径3〜5μmのSiO2に吸水ゲル樹脂を吸着させたエネックス社製商品名“GP−K−1”を10重量%と、バインダ樹脂としてウレタン系樹脂:日華化学株式会社製“エバファノールAP12”を1重量%採取し、水10リットルに分散し、親水性処理液とした。この親水性処理液に伸縮性生地を浸漬し、ピックアップ率16重量%となるように絞り、乾燥した。これにより、吸水ゲル吸着粒子は伸縮性生地に1.6重量%付着した。なお前記平均粒子径は市販の粒度分布計で測定できる。例えば、堀場製作所レーザ回折粒度測定器(LA920)、島津製作所レーザ回折粒度測定器(SALD2100)などを用いて測定することができる。
(2) Hydrophilic treatment As the water-absorbing gel adsorbing particles, 10 wt% of the product name “GP-K-1” manufactured by Enex Co., Ltd., in which the water-absorbing gel resin is adsorbed on SiO 2 having an average particle diameter of 3 to 5 μm of aggregated particles, 1% by weight of urethane resin: “Evaphanol AP12” manufactured by Nikka Chemical Co., Ltd. was collected as a binder resin and dispersed in 10 liters of water to obtain a hydrophilic treatment liquid. The stretchable fabric was dipped in this hydrophilic treatment solution, drawn to a pickup rate of 16% by weight, and dried. Thereby, 1.6 weight% of water-absorbing gel adsorption | suction particles adhered to the elastic cloth. The average particle diameter can be measured with a commercially available particle size distribution meter. For example, it can be measured using a Horiba laser diffraction particle size measuring device (LA920), a Shimadzu laser diffraction particle size measuring device (SALD2100), or the like.

(3)撥水性処理
次に撥水性処理液として、フッ素樹脂系撥水剤(七福化学社製の商品名”DP−10”)を4重量%と、増粘剤として七福化学社製の商品名”セブテックスM−20”を3重量%、架橋剤として七福化学社製商品名”ブロックイソシアネートZR,ZN”を3重量%水10Lに分散し、撥水性処理液とした。この撥水性処理液をプリント捺染により図1〜2に示すような模様でウェットアップ率21重量%となるように伸縮性生地にプリントし、乾燥後、170℃のピンテンターでセットし、伸縮性生地を仕上げ、水着に縫製した。
(3) Water repellent treatment Next, as a water repellent treatment liquid, 4% by weight of a fluororesin water repellent (trade name “DP-10” manufactured by Shichifuku Chemical Co., Ltd.) and a thickener made by Shichifuku Chemical Co., Ltd. The product name “Cebtex M-20” of 3% by weight and the product name “Block isocyanate ZR, ZN” manufactured by Shichifuku Chemical Co., Ltd. as a cross-linking agent were dispersed in 10 L of water 3% to obtain a water-repellent treatment solution. This water-repellent treatment liquid is printed on a stretchable fabric with a pattern as shown in FIGS. 1 and 2 by a print printing so that the wet-up rate is 21% by weight, and after drying, set with a pin tenter at 170 ° C. Finished and sewn into a swimsuit.

図1〜2において、撥水性部分2の幅L2は一例として12mm、撥水性部分2,2の間隔L1は10mmとした。また、親水性部分1と撥水性部分2の面積割合は、親水性部分1:撥水性部分2=75:25であった。   1-2, the width L2 of the water repellent portion 2 is 12 mm as an example, and the interval L1 between the water repellent portions 2 and 2 is 10 mm. Moreover, the area ratio of the hydrophilic part 1 and the water-repellent part 2 was hydrophilic part 1: water-repellent part 2 = 75: 25.

(4)水着の水滴下吸収試験
得られた水着の親水性部分の10点平均水滴下吸収時間は1.6秒であり、撥水性部分の同時間は無限大であった。
(4) Water drop absorption test of swimsuit The 10-point average water drop absorption time of the hydrophilic part of the obtained swimsuit was 1.6 seconds, and the same time of the water repellent part was infinite.

(5)水着の着用試験
得られた水着を1月間毎日1時間水泳選手に着用試験してもらい、毎日家庭洗濯を繰り返したが、親水性に変化は認められなかった。このことから、耐久性の高い親水性であることが確認できた。
(5) Swimwear wear test The swimsuit obtained was tested by a swimmer for 1 hour every day for 1 month, and home washing was repeated every day, but no change in hydrophilicity was observed. From this, it has confirmed that it was highly durable hydrophilic property.

水中における表面摩擦抵抗は後に比較例とともに表2で説明する。   The surface friction resistance in water will be described later in Table 2 together with a comparative example.

(比較例1)
比較例として、実施例1の親水性処理を行わない以外は実施例1と同様に撥水性部分を形成し、水着に縫製した。親水性処理を行わないベース生地部分(以下「非撥水部」という)は、ポリエステル繊維とポリウレタン繊維で構成され、後処理されていない。
(Comparative Example 1)
As a comparative example, a water-repellent part was formed in the same manner as in Example 1 except that the hydrophilic treatment in Example 1 was not performed, and was sewn in a swimsuit. The base fabric portion not subjected to hydrophilic treatment (hereinafter referred to as “non-water-repellent portion”) is composed of polyester fiber and polyurethane fiber, and is not post-treated.

実施例1と比較例1で得られた伸縮性生地の撥水部と親水部と非撥水部の各々の10点平均水滴下吸収時間は、次の表1に示すとおりであった。   The 10-point average water drop absorption time for each of the water-repellent part, hydrophilic part and non-water-repellent part of the stretchable fabric obtained in Example 1 and Comparative Example 1 was as shown in Table 1 below.

Figure 2007142232
Figure 2007142232

実施例1と比較例1の水着に使用した伸縮性生地の水中における表面摩擦抵抗は、図3に示す表面摩擦抵抗試験装置を用いて測定した。それぞれの上端11a,11bが水平方向(矢印B)に自由に移動できる支柱12a,12bによって支えられたガラス板13(長さ3000mm、幅600mm)の両面に試験用生地14を貼り付け、回流水路15中に所定の深度まで沈降させる。金属製支柱16の下端は前記ガラス板13に固定され、支柱16の上端は天井に固定されている。支柱16の上方部分に歪みゲージ17が設置されている。ガラス板13に貼りつけた生地14の表面が矢印Aの方向で流れる水流から受ける抵抗の大きさは、前記歪みゲージ17からの電気信号として動歪み計18により測定され、A/Dコンバーター19を介してコンピューター20に表示記録される。   The surface friction resistance in water of the stretch fabric used in the swimsuits of Example 1 and Comparative Example 1 was measured using a surface friction resistance test apparatus shown in FIG. The test cloth 14 is pasted on both sides of the glass plate 13 (length 3000 mm, width 600 mm) supported by the support columns 12a and 12b whose upper ends 11a and 11b can move freely in the horizontal direction (arrow B). Settling to a predetermined depth in 15. The lower end of the metal column 16 is fixed to the glass plate 13, and the upper end of the column 16 is fixed to the ceiling. A strain gauge 17 is installed in the upper part of the column 16. The magnitude of the resistance that the surface of the fabric 14 affixed to the glass plate 13 receives from the water flow flowing in the direction of arrow A is measured by a dynamic strain meter 18 as an electrical signal from the strain gauge 17, and the A / D converter 19 is And recorded on the computer 20.

水中における表面摩擦抵抗は後に表2で説明する。   The surface friction resistance in water will be described later in Table 2.

(実施例2)
実施例1において、撥水性処理液をプリント捺染する際の模様を図6のストライプ模様に代えた以外は実施例1と同様に水着を作製した。親水性部分1と撥水性部分2の面積割合は、親水性部分1:撥水性部分2=25:75であった。得られた水着の親水性部分の10点平均水滴下吸収時間は1分44秒であり、撥水性部分の同時間は無限大であった。また、得られた水着を1月間毎日1時間水泳選手に着用試験してもらい、毎日家庭洗濯を繰り返したが、親水性に変化は認められなかった。このことから、耐久性の高い親水性であることが確認できた。
(Example 2)
In Example 1, a swimsuit was produced in the same manner as in Example 1 except that the pattern when printing the water-repellent treatment liquid was changed to the stripe pattern of FIG. The area ratio of the hydrophilic portion 1 and the water repellent portion 2 was hydrophilic portion 1: water repellent portion 2 = 25: 75. The 10-point average water drop absorption time of the hydrophilic part of the obtained swimsuit was 1 minute 44 seconds, and the same time of the water repellent part was infinite. The obtained swimsuit was tested by a swimmer for 1 hour every day for one month, and home washing was repeated every day, but no change in hydrophilicity was observed. From this, it has confirmed that it was highly durable hydrophilic property.

実施例1〜2と比較例1の水着に使用した伸縮性生地の流水中の表面摩擦抵抗値を表2に示す。測定した流速は、いずれも競泳の選手の泳ぐ速度に近い範囲を選んだ。   Table 2 shows the surface friction resistance values of the stretch fabrics used in the swimsuits of Examples 1 and 2 and Comparative Example 1 in running water. The measured flow velocities were all selected to be close to the swimming speed of competitive athletes.

Figure 2007142232
Figure 2007142232

表2の結果から明らかなとおり、流速が速くなるにしたがい本発明の実施例1〜2における水着の表面摩擦抵抗は低下していることが確認できた。   As is clear from the results in Table 2, it was confirmed that the surface frictional resistance of the swimsuits in Examples 1 and 2 of the present invention decreased as the flow rate increased.

(実施例3)
実施例1において、生地の裏面に、表面側と同じ撥水性処理液をストライプ模様にプリント捺染した以外は実施例1と同様に水着を作製した。裏面の撥水性部分のストライプの幅は7mmとし、撥水性ストライプ間(処理なし部分)の幅は7mmとした。また、処理なし部分と撥水性部分の面積割合は、処理なし部分:撥水性部分=50:50であった。得られた水着表面の親水性部分の10点平均水滴下吸収時間は1分44秒であり、撥水性部分の同時間は無限大であった。また、得られた水着を1月間毎日1時間水泳選手に着用試験してもらい、毎日家庭洗濯を繰り返したが、親水性に変化は認められなかった。このことから、耐久性の高い親水性であることが確認できた。さらにモニター数10名の水泳選手に着用試験してもらったところ、水泳時の水切り性、及びプールから上がったときの軽量感はいずれも優れており、競泳用水着として好適であることが確認できた。
(Example 3)
In Example 1, a swimsuit was produced in the same manner as in Example 1 except that the same water-repellent treatment liquid as that on the front side was printed and printed in a stripe pattern on the back side of the fabric. The width of the stripe of the water-repellent portion on the back surface was 7 mm, and the width between the water-repellent stripes (the untreated portion) was 7 mm. The area ratio of the untreated portion and the water-repellent portion was untreated portion: water-repellent portion = 50: 50. The 10-point average water dripping absorption time of the hydrophilic part of the obtained swimsuit surface was 1 minute 44 seconds, and the same time of the water repellent part was infinite. The obtained swimsuit was tested by a swimmer for 1 hour every day for one month, and home washing was repeated every day, but no change in hydrophilicity was observed. From this, it has confirmed that it was highly durable hydrophilic property. Furthermore, when a swimmer with 10 monitors performed a wear test, it was confirmed that both the draining ability when swimming and the lightness when rising from the pool are excellent, and it is suitable as a swimsuit for swimming. It was.

(実施例4)
実施例2において、バインダ樹脂としてアクリルシリコン系樹脂:大和化学社製“フクゾールA−30S”を用い、生地の裏面に、表面側と同じ撥水性処理液を縦ストライプ模様にプリント捺染した以外は実施例2と同様に水着を作製した。裏面の撥水性部分の縦ストライプの幅は7mmとし、撥水性ストライプ間(処理なし部分)の幅は7mmとした。また、処理なし部分と撥水性部分の面積割合は、処理なし部分:撥水性部分=50:50であった。得られた水着表面の親水性部分の10点平均水滴下吸収時間は1分44秒であり、撥水性部分の同時間は無限大であった。また、得られた水着を1月間毎日1時間水泳選手に着用試験してもらい、毎日家庭洗濯を繰り返したが、親水性に変化は認められなかった。このことから、耐久性の高い親水性であることが確認できた。さらにモニター数10名の水泳選手に着用試験してもらったところ、水泳時の水切り性、及びプールから上がったときの軽量感はいずれも優れており、競泳用水着として好適であることが確認できた。
(Example 4)
In Example 2, an acrylic silicon resin: “Fukusol A-30S” manufactured by Daiwa Chemical Co., Ltd. was used as the binder resin, and the same water-repellent treatment liquid as that on the front side was printed and printed in a vertical stripe pattern on the back side of the fabric. A swimsuit was prepared as in Example 2. The width of the vertical stripe of the water-repellent portion on the back surface was 7 mm, and the width between the water-repellent stripes (the untreated portion) was 7 mm. The area ratio of the untreated portion and the water-repellent portion was untreated portion: water-repellent portion = 50: 50. The 10-point average water dripping absorption time of the hydrophilic part of the obtained swimsuit surface was 1 minute 44 seconds, and the same time of the water repellent part was infinite. The obtained swimsuit was tested by a swimmer for 1 hour every day for one month, and home washing was repeated every day, but no change in hydrophilicity was observed. From this, it has confirmed that it was highly durable hydrophilic property. Furthermore, when a swimmer with 10 monitors performed a wear test, it was confirmed that both the draining ability when swimming and the lightness when rising from the pool are excellent, and it is suitable as a swimsuit for swimming. It was.

Claims (16)

伸縮性生地からなる水着であって、
多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子が、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に固定されていることを特徴とする水着。
A swimsuit made of stretch fabric,
A swimsuit, wherein water-absorbing gel adsorbent particles in which water-absorbing gel resin is adsorbed on porous inorganic particles are fixed to at least a part of the surface of the stretchable fabric together with a binder resin.
前記吸水ゲル吸着粒子はバインダ樹脂とともに分散液とされ、浸漬により前記伸縮性生地に付与されている請求項1に記載の水着。   The swimsuit according to claim 1, wherein the water-absorbing gel adsorbent particles are made into a dispersion together with a binder resin, and are applied to the stretchable fabric by dipping. 前記吸水ゲル吸着粒子はバインダ樹脂とともに分散液とされ、プリントにより前記伸縮性生地に付与されている請求項1に記載の水着。   The swimsuit according to claim 1, wherein the water-absorbing gel adsorbing particles are made into a dispersion together with a binder resin and applied to the stretchable fabric by printing. 前記水着表面の少なくとも一部に、さらに撥水性部分を含む請求項1〜3のいずれかに記載の水着。   The swimsuit according to any one of claims 1 to 3, further comprising a water-repellent portion on at least a part of the swimsuit surface. 前記撥水性部分は水着の体長方向に沿って連続状及び断続状から選ばれる少なくとも1つのパターンに形成されている請求項4に記載の水着。   The swimsuit according to claim 4, wherein the water repellent part is formed in at least one pattern selected from a continuous form and an intermittent form along the body length direction of the swimsuit. 前記吸水ゲル吸着粒子が固定された部分を浸漬法で伸縮性生地の全面に形成し、その上に撥水性部分をプリントにより所定の形状に形成する請求項1〜5のいずれかに記載の水着。   The swimsuit according to any one of claims 1 to 5, wherein a portion where the water-absorbing gel adsorbent particles are fixed is formed on the entire surface of the stretchable fabric by a dipping method, and a water-repellent portion is formed in a predetermined shape thereon by printing. . 前記水着の裏面には撥水性部分が形成されている請求項1〜5のいずれかに記載の水着。   The swimsuit according to any one of claims 1 to 5, wherein a water-repellent portion is formed on the back surface of the swimsuit. 前記撥水性部分の面積割合が10〜90%の範囲である請求項7に記載の水着。   The swimsuit according to claim 7, wherein an area ratio of the water repellent portion is in a range of 10 to 90%. 前記水着は競泳用水着である請求項1〜8のいずれかに記載の水着。   The swimsuit according to claim 1, wherein the swimsuit is a swimsuit for swimming. 伸縮性生地からなる水着の製造方法であって、
多孔質無機粒子に吸水ゲル樹脂が吸着された吸水ゲル吸着粒子を、バインダ樹脂とともに伸縮性生地の表面の少なくとも一部に付与することを特徴とする水着の製造方法。
A method for producing a swimsuit made of stretch fabric,
A method for producing a swimsuit, comprising applying water-absorbing gel adsorption particles in which a water-absorbing gel resin is adsorbed to porous inorganic particles to at least a part of the surface of a stretchable fabric together with a binder resin.
前記吸水ゲル吸着粒子はバインダ樹脂とともに分散液とされ、浸漬により前記伸縮性生地に付与する請求項10に記載の水着の製造方法。   The method for producing a swimsuit according to claim 10, wherein the water-absorbing gel adsorbing particles are made into a dispersion together with a binder resin and applied to the stretchable fabric by dipping. 前記吸水ゲル吸着粒子はバインダ樹脂とともに分散液とされ、プリントにより前記伸縮性生地に付与する請求項10に記載の水着の製造方法。   The method for producing a swimsuit according to claim 10, wherein the water-absorbing gel adsorbing particles are made into a dispersion together with a binder resin and applied to the stretchable fabric by printing. 前記水着表面の少なくとも一部に、さらに撥水処理を施す請求項10〜12のいずれかに記載の水着の製造方法。   The method for producing a swimsuit according to any one of claims 10 to 12, wherein a water repellent treatment is further applied to at least a part of the swimsuit surface. 前記撥水処理により、撥水性部分を水着の体長方向に沿って連続状及び断続状から選ばれる少なくとも1つのパターンに形成する請求項13に記載の水着の製造方法。   The method for producing a swimsuit according to claim 13, wherein the water-repellent treatment forms the water-repellent portion in at least one pattern selected from a continuous form and an intermittent form along the body length direction of the swimsuit. 吸水ゲル吸着粒子と、バインダ樹脂ともに分散液とされ、浸漬法により伸縮性生地の全面に付与した後、撥水性部分をプリントにより所定の形状に形成する請求項10〜14のいずれかに記載の水着の製造方法。   The water-absorbing gel adsorbing particles and the binder resin are both made into a dispersion, and after being applied to the entire surface of the stretchable fabric by an immersion method, the water-repellent portion is formed into a predetermined shape by printing. Swimwear manufacturing method. 前記水着は競泳用水着である請求項10〜15のいずれかに記載の水着の製造方法。   The said swimsuit is a swimsuit for swimming races, The manufacturing method of the swimsuit in any one of Claims 10-15.
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Families Citing this family (17)

* Cited by examiner, † Cited by third party
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KR20110036070A (en) 2008-07-18 2011-04-06 미즈노 가부시키가이샤 Sportswear
JP4578559B1 (en) * 2009-06-04 2010-11-10 株式会社ゴールドウイン Swimsuit with water ingress suppression part
CN106133223B (en) * 2014-03-31 2018-11-02 美津浓株式会社 Flexible fabric and the movement clothing containing the fabric that stretches and swimming suit
US10064447B2 (en) 2014-08-27 2018-09-04 Nike, Inc. Article of footwear with soil-shedding performance
TWI706737B (en) 2014-08-27 2020-10-11 荷蘭商耐基創新公司 Article of footwear with soil-shedding performance
US10076159B2 (en) 2014-08-27 2018-09-18 Nike, Inc. Soil-shedding article of footwear, and method of using the same
US10314364B2 (en) 2014-08-27 2019-06-11 Nike, Inc. Soil-shedding article of footwear, and method of using the same
EP3169175B1 (en) * 2014-08-27 2020-06-17 NIKE Innovate C.V. Articles of footwear, apparel, and sports equipment with water absorbtion properties
JP6012817B1 (en) * 2015-06-05 2016-10-25 美津濃株式会社 Swimsuit
US10675609B2 (en) 2016-03-02 2020-06-09 Nike, Inc. Articles with soil-shedding performance
US10531705B2 (en) 2016-03-02 2020-01-14 Nike, Inc. Hydrogel tie layer
US10455893B2 (en) 2016-03-02 2019-10-29 Nike, Inc. Hydrogel with mesh for soil deflection
US10362834B2 (en) 2016-03-02 2019-07-30 Nike, Inc. Hydrogel connection
TWI700175B (en) 2017-08-01 2020-08-01 荷蘭商耐基創新公司 Method of manufacturing a component of an outsole for use in an article of footwear
US20190116927A1 (en) 2017-10-19 2019-04-25 Nike, Inc. Materials, methods of making, methods of use, and articles incorporating the materials
CN107536122A (en) * 2017-10-27 2018-01-05 上海海螺服饰有限公司 A kind of shirt
CN113226102B (en) * 2019-03-05 2022-04-26 株式会社爱世克私 Anti-slip member for equipment or sporting goods, equipment, and sporting goods

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2715088B2 (en) * 1988-02-18 1998-02-16 株式会社デサント Swimsuit with reduced fluid resistance
JPH0457970A (en) * 1990-06-26 1992-02-25 Kanebo Ltd Moisture-permeable waterproofing of textile goods
JPH091997A (en) 1995-06-21 1997-01-07 Toru Hachisu Three-dimensional frame for paper for folding
JP3283404B2 (en) 1995-07-06 2002-05-20 美津濃株式会社 Swimsuit
CN1134282C (en) * 1998-11-17 2004-01-14 三洋化成工业株式会社 Water absorbing agent and preparing method thereof
JP4214246B2 (en) * 1998-12-16 2009-01-28 東洋紡績株式会社 Woven knitted fabric with good drainage
JP3462108B2 (en) 1999-02-05 2003-11-05 美津濃株式会社 Swimsuit
JP2004292962A (en) 2003-03-26 2004-10-21 Descente Ltd Fluid resistance-reducing swimming suit
JP4017554B2 (en) * 2003-05-01 2007-12-05 株式会社デサント Fluid resistance reduced swimsuit
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