JPS6416786A - Thienopyrrolopyrroles and preparation thereof - Google Patents
Thienopyrrolopyrroles and preparation thereofInfo
- Publication number
- JPS6416786A JPS6416786A JP62172320A JP17232087A JPS6416786A JP S6416786 A JPS6416786 A JP S6416786A JP 62172320 A JP62172320 A JP 62172320A JP 17232087 A JP17232087 A JP 17232087A JP S6416786 A JPS6416786 A JP S6416786A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- preparation
- acrylate
- lower alkoxycarbonyl
- thienopyrrolopyrroles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
NEW MATERIAL:A compound of formula I (R1 is lower alkoxycarbonyl; R2, R3 are H, lower alkyl, aralkyl). EXAMPLE:5-Hydroxymethyl-4H-thieno[3,2-b]pyrrole. USE:Starting substance of electric or electronic materials and intermediate of medicines and agrochemicals. PREPARATION:A thienopyrrole of formula II (R4 is lower alkoxycarbonyl) is reduced to form a hydroxymethylthienopyrrole of formula III. The product is oxidized into a formylthienopyrrole of formula IV, which is subjected to condensation reaction with an azide of the formula: N3CH2R1 to give a thienopyrrolylazide acrylate of formula V. Then, the acrylate is thermally cyclized or N-alkylated or N-aralkylated after heat setting.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62172320A JPS6416786A (en) | 1987-07-09 | 1987-07-09 | Thienopyrrolopyrroles and preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62172320A JPS6416786A (en) | 1987-07-09 | 1987-07-09 | Thienopyrrolopyrroles and preparation thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6416786A true JPS6416786A (en) | 1989-01-20 |
Family
ID=15939726
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62172320A Pending JPS6416786A (en) | 1987-07-09 | 1987-07-09 | Thienopyrrolopyrroles and preparation thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6416786A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7902252B2 (en) | 2007-01-18 | 2011-03-08 | Sepracor, Inc. | Inhibitors of D-amino acid oxidase |
US8053603B2 (en) | 2006-01-06 | 2011-11-08 | Sunovion Pharmaceuticals Inc. | Tetralone-based monoamine reuptake inhibitors |
US9868718B2 (en) | 2006-01-06 | 2018-01-16 | Sunovion Pharmaceuticals Inc. | Cycloalkylamines as monoamine reuptake inhibitors |
-
1987
- 1987-07-09 JP JP62172320A patent/JPS6416786A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8053603B2 (en) | 2006-01-06 | 2011-11-08 | Sunovion Pharmaceuticals Inc. | Tetralone-based monoamine reuptake inhibitors |
US9868718B2 (en) | 2006-01-06 | 2018-01-16 | Sunovion Pharmaceuticals Inc. | Cycloalkylamines as monoamine reuptake inhibitors |
US10562878B2 (en) | 2006-01-06 | 2020-02-18 | Sunovion Pharamceuticals Inc. | Cycloalkylamines as monoamine reuptake inhibitors |
US7902252B2 (en) | 2007-01-18 | 2011-03-08 | Sepracor, Inc. | Inhibitors of D-amino acid oxidase |
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