JPS6411251B2 - - Google Patents
Info
- Publication number
- JPS6411251B2 JPS6411251B2 JP54143807A JP14380779A JPS6411251B2 JP S6411251 B2 JPS6411251 B2 JP S6411251B2 JP 54143807 A JP54143807 A JP 54143807A JP 14380779 A JP14380779 A JP 14380779A JP S6411251 B2 JPS6411251 B2 JP S6411251B2
- Authority
- JP
- Japan
- Prior art keywords
- light
- hydroxy
- wavelength
- film
- blue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
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- 238000002834 transmittance Methods 0.000 claims description 29
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- 235000012055 fruits and vegetables Nutrition 0.000 claims description 12
- 230000000903 blocking effect Effects 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 description 26
- 230000000694 effects Effects 0.000 description 11
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- 235000013399 edible fruits Nutrition 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000003086 colorant Substances 0.000 description 9
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- 206010016256 fatigue Diseases 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 6
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 5
- 244000013123 dwarf bean Species 0.000 description 5
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- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 5
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- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 4
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- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 4
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- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
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- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 2
- LOPXIGZYSAOSOK-UHFFFAOYSA-N 2-(5,6-dichlorobenzotriazol-2-yl)-4-methylphenol Chemical compound CC1=CC=C(O)C(N2N=C3C=C(Cl)C(Cl)=CC3=N2)=C1 LOPXIGZYSAOSOK-UHFFFAOYSA-N 0.000 description 2
- LMFQVOYNAXDCQT-UHFFFAOYSA-N 2-(5-chlorobenzotriazol-2-yl)-4-phenylphenol Chemical compound C1=C(N2N=C3C=C(Cl)C=CC3=N2)C(O)=CC=C1C1=CC=CC=C1 LMFQVOYNAXDCQT-UHFFFAOYSA-N 0.000 description 2
- NLWDAUDWBLSJGK-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butyl-6-methylphenol Chemical compound CC1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O NLWDAUDWBLSJGK-UHFFFAOYSA-N 0.000 description 2
- WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
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- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
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- 238000002360 preparation method Methods 0.000 description 2
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- 239000011347 resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- CNAILFQALPMJFF-UHFFFAOYSA-N (4-benzoyl-3-hydroxyphenyl) benzoate Chemical compound C=1C=C(C(=O)C=2C=CC=CC=2)C(O)=CC=1OC(=O)C1=CC=CC=C1 CNAILFQALPMJFF-UHFFFAOYSA-N 0.000 description 1
- ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- JHDNFMVFXUETMC-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)-4-methylphenol Chemical compound CC1=CC=C(O)C(C=2C=3N=NNC=3C=CC=2)=C1 JHDNFMVFXUETMC-UHFFFAOYSA-N 0.000 description 1
- DHMNTHVOLJVHPF-UHFFFAOYSA-N 2-(3,5-dimethyl-2-octadecoxyphenyl)-5-methylbenzotriazole Chemical compound CCCCCCCCCCCCCCCCCCOC1=C(C)C=C(C)C=C1N1N=C2C=C(C)C=CC2=N1 DHMNTHVOLJVHPF-UHFFFAOYSA-N 0.000 description 1
- LGTOWDJWJQJQAO-UHFFFAOYSA-N 2-(5-methoxybenzotriazol-2-yl)-4,6-dimethylphenol Chemical compound N1=C2C=C(OC)C=CC2=NN1C1=CC(C)=CC(C)=C1O LGTOWDJWJQJQAO-UHFFFAOYSA-N 0.000 description 1
- ODVBRJXPJKVLCZ-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-dichlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1N1N=C2C=CC=CC2=N1 ODVBRJXPJKVLCZ-UHFFFAOYSA-N 0.000 description 1
- MJFOVRMNLQNDDS-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-dimethylphenol Chemical compound CC1=CC(C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MJFOVRMNLQNDDS-UHFFFAOYSA-N 0.000 description 1
- CFZGXWYAUQYJEC-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-cyclohexylphenol Chemical compound C1=C(N2N=C3C=CC=CC3=N2)C(O)=CC=C1C1CCCCC1 CFZGXWYAUQYJEC-UHFFFAOYSA-N 0.000 description 1
- PITPRNOGWXAZAW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-methoxyphenol Chemical compound COC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 PITPRNOGWXAZAW-UHFFFAOYSA-N 0.000 description 1
- VGJKSKBMKUFKRQ-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-octoxyphenol Chemical compound CCCCCCCCOC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 VGJKSKBMKUFKRQ-UHFFFAOYSA-N 0.000 description 1
- KGVHAZMHOQLBEQ-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-phenylphenol Chemical compound C1=C(N2N=C3C=CC=CC3=N2)C(O)=CC=C1C1=CC=CC=C1 KGVHAZMHOQLBEQ-UHFFFAOYSA-N 0.000 description 1
- ITLDHFORLZTRJI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-5-octoxyphenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1N1N=C2C=CC=CC2=N1 ITLDHFORLZTRJI-UHFFFAOYSA-N 0.000 description 1
- DXPQDAHFCMBFMM-UHFFFAOYSA-N 2-benzoylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 DXPQDAHFCMBFMM-UHFFFAOYSA-N 0.000 description 1
- OUWPEHOSUWXUFV-UHFFFAOYSA-N 4-(benzotriazol-2-yl)-3-methylphenol Chemical compound CC1=CC(O)=CC=C1N1N=C2C=CC=CC2=N1 OUWPEHOSUWXUFV-UHFFFAOYSA-N 0.000 description 1
- XQRZNFAYYOJJSG-UHFFFAOYSA-N 4-amino-2-(benzotriazol-2-yl)phenol Chemical compound NC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 XQRZNFAYYOJJSG-UHFFFAOYSA-N 0.000 description 1
- RZZQDQUZAANRKE-UHFFFAOYSA-N 4-methoxy-2-(5-methylbenzotriazol-2-yl)phenol Chemical compound COC1=CC=C(O)C(N2N=C3C=C(C)C=CC3=N2)=C1 RZZQDQUZAANRKE-UHFFFAOYSA-N 0.000 description 1
- IEMHIOUNBGZEAG-UHFFFAOYSA-N 4-tert-butyl-2-(5-chlorobenzotriazol-2-yl)phenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=C(Cl)C=CC3=N2)=C1 IEMHIOUNBGZEAG-UHFFFAOYSA-N 0.000 description 1
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- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N salicylic acid phenyl ester Natural products OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 208000016255 tiredness Diseases 0.000 description 1
- 230000003867 tiredness Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Description
本発明は新規な農業用被覆材に関し、さらに詳
しくは、特定の光透過特性を有する青色系に着色
された紫外線遮蔽性の合成樹脂材料より成る、殊
に果菜類植物の施設栽培に適した農業用被覆材に
関する。
従来より紫外線遮蔽性の農業用被覆材はいくつ
か提案されている。例えば、特公昭48−37459号
公報、特公昭49−16301号公報、特公昭53−47383
号公報、特開昭51−100445号公報等参照。他方、
可視光領域の光と植物の生育との関係についても
古くからいろいろと研究されている。例えば、特
公昭27−2911号公報、特公昭47−24376号公報、
特公昭49−17093号公報、特公昭49−43778号公
報、施設農業における光質利用の技術化に関する
総合研究:農林水産技術会議事務局発行(昭和51
年2月29日発行)88〜89頁等参照。さらに、紫外
線を遮蔽すると同時にある特定の色に着色した農
業用フイルムもいくつか提案されている。例え
ば、特公昭54−15818号公報、特開昭52−43637号
公報、電力中央研究所農電研究所報告:研究報
告:71003(1972年10月)18頁参照。
しかしながら、従来提案されたこれら色つきの
紫外線遮蔽性の農業用フイルムは、栽培植物の生
育促進、増収等に対しある程度の改善効果を期待
することができるが、未だ充分とはいえない。
本発明者らもまた、従来から紫外線遮蔽性の農
業用被覆材に着目し、紫外線遮蔽性の農業用被覆
材が、植物の病害菌の繁殖阻止、トマトの裂果防
止、果実の糖度増加、葉茎菜類植物の腐敗症の防
止、ピーマンの老化防止、キユウリの老化防止等
において優れた効果があることを見い出し、先に
提案した。例えば特公昭53−47383号公報、特開
昭52−98125号公報、特開昭53−2238号公報、特
開昭53−27539号公報、特開昭53−75039号公報、
特開昭53−117546号公報、特開昭53−127126号公
報、特開昭53−127129号公報等参照。さらに、着
色した紫外線遮蔽性の農業用被覆材についても、
本発明者らは、特開昭52−117738号公報におい
て、波長400〜700nmの領域の可視光線に対する
平均透過率が少なくとも40%以上であり、400〜
500nmの波長の青色系光線に対する平均透過率
対600〜700nmの波長の赤色系光線に対する平均
透過率の比が1.2:1乃至2.5:1の範囲にあり、
且つ少なくとも370nm及びそれ以下の波長の光
線を実質的に遮蔽する性質を有する農業用合成樹
脂フイルム乃至板よりなる青色系の紫外線遮蔽性
農業用被覆材を提案した。しかしながら、この紫
外線遮蔽性農業用被覆材は特に水稲の育苗用とし
て開発したもので、赤色系領域の波長の光の透過
率がかなり低く、果菜類や葉菜類植物の施設栽培
に用いた場合には、充分な生育促進、増収効果が
期待できないという欠点がある。
そこで本発明者らは、果菜類や葉菜類植物、殊
に果粒類植物の栽培に適した着色された紫外線遮
蔽性農業用被覆材につき鋭意研究をなつた結果、
下記の光透過特性を有する農業用被覆材、すなわ
ち、
(a) 少なくとも370nm以下の波長の光の透過を
実質的に遮蔽し、
(b) 440nmから700nmまでの波長領域内におけ
る吸収極大が590〜625nm間にあり且つ該吸収
極大おける光の透過率が70〜88%の範囲内にあ
り、
(c) 440〜590nm間の波長の光の平均透過率が少
なくとも85%以上であり、
(d) 600〜700nm間の波長の光の平均透過率が少
なくとも75%以上であり、そして
(e) 400〜500nm間の波長の光の平均透過率対
600〜700nm間の波長の光の平均透過率の比率
が1.2未満である
青色系に着色された透明の合成樹脂製のフイル
ム又は板から成る農業用被覆材が、果菜類植物の
栽培に極めて適していることを見い出し、本発明
を完成するに至つた。
しかして、本発明によれば、上記(a)、(b)、(c)、
(d)及び(e)の5つの光透過特性を満足する青色系に
着色された透明の合成樹脂製のフイルム又は板か
ら成ることを特徴とする果菜類植物の栽培に適し
た農業用被覆材が提供される。
本発明により提供される農業用被覆材は、果菜
類植物の施設栽倍においてハウスやトンネルの被
覆材として使用した場合、
(イ) 果菜類植物の収穫において、成疲れ(なりづ
かれ)現象を効果的に防止することができ、特
にキユウリ、トマト、インゲン、ピーマン等に
おいてその効果が大きい(成疲れ防止効果)。
(ロ) 果菜類植物の収穫量を著るしく高めることが
できる(増収効果)。
(ハ) 果菜類植物の収穫物の品質の向上を図ること
ができる。例えば、トマトの場合裂果の発生率
を低下させることができ、また、キユウリの果
色を向上させることができる(品質向上効果)。
(ニ) 果菜類植物の草丈の生育が適度に抑制され、
節間長が短かく、がん丈な充実感があふれる株
に育てることができる(充実栽培効果)。
等の栽培効果が得られ、果菜類植物の栽培上貢献
するところ極めて大である。
本明細書において、「成疲れ」現象とは、例え
ば、「野菜生産の問題と解決」(下)一種類別技術
編−〔(株)誠文堂新光社、昭和52年8月25日第1版
発行〕の第12頁第10〜20行に記載されている如
く、果菜類植物の栽培において、果実の収穫の盛
期を越えた頃、養分の蓄積不足、葉の老化による
同化能力の低下などに起因して、一時的に果実の
収量を低下し、品質にも不良果が多発する等の現
象をいう。
本明細書において用いる「xnm以下の波長の
光の透過を実質的に遮蔽する」なる語は、xnm
以下の波長の光の透過を100%完全に遮蔽する場
合のみならず、xnm及びそれ以下の波長の光の
透過を少なくとも80%、好ましくは90%以上、さ
らに好ましくは95%以上遮蔽する場合をも包含す
る意味で用いるものである。
また、「吸収極大」とは、吸光スペクトルの吸
収曲線におけるある定められた波長領域内での最
大の吸光度又は吸光係数を示す部分をいう。な
お、吸収極大を示すピークの頂部がほぼ平坦な場
合には該平坦部の中心点を以つて吸収極大と呼ぶ
ことにする。さらに「平均透過率」とは、光線波
長(横軸:x軸とする)対光線透過率(縦軸)の
曲線〔f(x)〕における、ある定められた波長領
域内(a〜b)nmにおいて、
∫b/af(x)dx(%)/(b−a)
で示される値をいう。
しかして、本発明において好適に使用し得る農
業用被覆材は、前述の(a)、(b)、(c)、(d)及び(e)に示
す光透過特性を満足し、さらに下記(a′)、(b′)、
(c′)及び(d′)から選ばれる要件のいずれか1
つ以上をも同時に満足するものである。
(a′) 少なくとも380nm以下の波長の光の透過を
実質的に遮蔽すること。
(b′) 440nmから700nmまでの波長領域内におけ
る吸収極大が590〜625nm、一層好ましくは
595〜620nm間にあり且つ該吸収極大における
光の透過率が70〜88%、一層好適には75〜85%
の範囲内にあること。
(c′) 440〜590nm間の波長の光の平均透過率が少
なくとも85%以上、一層有利には87%以上であ
ること。及び
(d′) 600〜700nm間の波長の光の平均透過率が
少なくとも75%以上、さらに好ましくは77〜88
%の範囲内にあること。
また、本発明の農業用被覆材は、光線波長(横
軸)対光線透過率(縦軸)曲線を描いた場合に、
その曲線が光線波長380nm〜420nmの波長領域
内でできるだけ垂直に立ち上るような光線透過率
特性を示すようなものが好ましく、特に、400n
mの波長の光は15〜80%程度透過し、且つ400〜
440nm間の平均透過率が一般に65〜90%、好ま
しくは70〜85%の範囲内にあるものが望ましい。
さらに、本発明の農業用被覆材は440nmから
590nmまでの波長領域内には吸収ピークをもた
ず、殊に、440nmから525nmまでの波長領域の
透過率は85%以上であることができる。しかし、
他方、600nmから700nmまでの波長領域内には、
吸収極大を与える吸収ピークに加えて、それより
弱い吸収ピークが存在していてもよく、そのよう
な弱い吸収ピークは660〜700nm間に存在するこ
とができ、従つて、625〜700nm間の平均透過率
は一般に75〜90%、好ましくは78〜87%の範囲内
にあることができる。
また、本発明の農業用被覆材としては、500〜
600nm間の波長の光の平均透過率が600nm以上
の波長の可視光部の平均透過率の0.8〜1.1倍の範
囲内にあるものが望ましい。
なお、700nm以上の波長領域については特に
制限がないが、一般に700nm以上の波長領域、
特に赤外領域の平均透過率が95%以下で且つ60%
以上となるようにすることが望ましい。
以上に述べた光透過特性を有する農業用被覆材
は、例えば、通常のフイルム形成性合成樹脂に後
述する染料又は顔料及び紫外線吸収剤を配合しフ
イルム又は板に成形するか、通常の透明な合成樹
脂フイルム又は板の少なくとも一面に、後述する
染料又は顔料及び紫外線吸収剤と合成樹脂ベヒク
ルとを含む塗布組成物をコーテイングするか、或
いは該染料又は顔料及び紫外線吸収剤のいずれか
一方を本発明のフイルム又板中に配合し且つ他方
を上記の如き塗布組成物の形で該フイルム又は板
の少なくとも一面にコーテイングする、等の方法
により製造することができる。
使用し得るフイルム形成性熱可塑性合成樹脂と
しては、例えばポリ塩化ビニル、ポリ塩化ビニリ
デン、ポリエチレン、ポリプロピレン、ポリスチ
レン、ポリエステル、ポリアミド、ポリカーボネ
ート、ポリメチルメタクリレート、ポリアクリレ
ート、ポリ酢酸ビニル、又はこれら重合体を主体
とする共重合体もしくはブレンド物等が含まれ、
特に耐光性、光線透過性、強度等の理由から、ポ
リ塩化ビニル、ポリメチルメタクリレート、ポリ
エチレン、及びエチレン−酢酸ビニル共重合体が
好適であり、就中、ポリ塩化ビニルが好適であ
る。
これら合成樹脂に配合し得る紫外線吸収剤とし
ては、該紫外線吸収剤の紫外線吸収能や使用する
合成樹脂との相溶性等を考慮して広範囲の種類の
中から適宜選択使用することができる。使用可能
な紫外線吸収剤としては例えば下記の如きものが
挙げられる。
ハイドロキノン系−ハイドロキノン、ハイドロキ
ノンジサリチレート
サリチル酸系−フエニルサリチレート、パラオク
チルフエニルサリチレート
ベンゾフエノン系−2−ヒドロキシ−4−メトキ
シベンゾフエノン、2−ヒドロキシ−4−n−
オクトキシベンゾフエノン、2−ヒドロキシ−
4−メトキシ−2′−カルボキシベンゾフエノ
ン、2,4−ジヒドロキシベンゾフエノン、
2,2′−ジヒドロキシ−4,4′−ジメトキシベ
ンゾフエノン、2−ヒドロキシ−4−ベンゾイ
ルオキシベンゾフエノン、2,2′−ヒドロキシ
−4−メトキシベンゾフエノン、2−ヒドロキ
シ−4−メトキシ−5−スルホンベンゾフエノ
ン、2,2′,4,4′−テトラヒドロキシベンゾ
フエノン、2,2′−ヒドロキシ−4,4′−ジメ
トキシ−5−ナトリウムスルホベンゾフエノ
ン、4−ドデシルオキシ−2−ヒドロキシベン
ゾフエノン、2−ハイドロキシ−5−クロルベ
ンゾフエノン
ベンゾトリアゾール系−2−(2′−ヒドロキシ−
5′−メチルフエニル)ベンゾトリアゾール、2
−(2′−ヒドロキシ−5′−メチルフエニル)−5
−カルボン酸ブチルエステルベンゾトリアゾー
ル、2−(2′−ヒドロキシ−5′−メチルフエニ
ル)−5,6−ジクロルベンゾトリアゾール、
2−ヒドロキシ−5′−メチルフエニル)−5−
エチルスルホンベンゾトリアゾール、2−
(2′−ヒドロキシ−5′−第3ブチルフエニル)−
5−クロルベンゾトリアゾール、2−(2′−ヒ
ドロキシ−5′−第3ブチルフエニル)ベンゾト
リアゾール、2−(2′−ヒドロキシ−5′−アミ
ノフエニル)ベンゾトリアゾール、2−(2′−
ヒドロキシ−3′,5′−ジメチルフエニル)ベン
ゾトリアゾール、2−(2′−ヒドロキシ−3′,
5′−ジメチルフエニル)−5−メトキシベンゾ
トリアゾール、2−(2′−メチル−4′−ヒドロ
キシフエニル)ベンゾトリアゾール、2−
(2′−ステアリルオキシ−3′,5′−ジメチルフエ
ニル)−5−メチルベンゾトリアゾール、2−
(2′−ヒドロキシ−5′−カルボキシフエニル)
ベンゾトリアゾールエチルエステル、2−
(2′−ヒドロキシ−3′−メチル−5′−第3ブチル
フエニル)ベンゾトリアゾール、2−(2′−ヒ
ドロキシ−3′,5′−ジ−第3ブチルフエニル)
−5−クロル−ベンゾトリアゾール、2−
(2′−ヒドロキシ−5′−メトキシフエニル)ベ
ンゾトリアゾール、2−(2′−ヒドロキシ−
5′−フエニルフエニル)−5−クロルベンゾト
リアゾール、2−(2′−ヒドロキシ−5′−シク
ロヘキシルフエニル)ベンゾトリアゾール、2
−(2′−ヒドロキシ−4′,5′−ジメチルフエニ
ル)−5−フエノキシカルボニルベンゾトリア
ゾール、2−(2′−ヒドロキシ−3′,5′−ジクロ
ルフエニル)ベンゾトリアゾール、2−(2′−
ヒドロキシ−4′,5′−ジクロル)ベンゾトリア
ゾール、2−(2′−ヒドロキシ−3′,5′−ジメチ
ルフエニル)−5−エチルスルホンベンゾトリ
アゾール、2−(2′−ヒドロキシ−5′−フエニ
ルフエニル)ベンゾトリアゾール、2−(2′−
ヒドロキシ−4′−オクトキシフエニル)ベンゾ
トリアゾール、2−(2′−ヒドロキシ−5′−メ
トキシフエニル)−5−メチルベンゾトリアゾ
ール、2−(2′−ヒドロキシ−5′−メチルフエ
ニル)−5−エトキシカルボニルベンゾトリア
ゾール、2−(2′−アセトキシ−5′−メチルフ
エニル)ベンゾトリアゾール、2−(2′−ヒド
ロキシ−3′,5′−ジ−第3ブチルフエニル)−
5−クロロベンゾトリアゾール。
これらの紫外線吸収剤のうち、ベンゾフエノン
系及びベンゾトリアゾール系のものが好適であ
り、就中、ベンゾフエノン系では、2,3−ジヒ
ドロキシ−4,4−ジメトキシベンゾフエノン、
2,2′−ジヒドロキシ−4−メトキシベンゾフエ
ノン及び2,2′,4′,4′−テトラヒドロキシベン
ゾフエノン;ベンゾトリアゾール系では2−
(2′−ハイドロキシ−5′−メチルフエニル)ベン
ゾトリアゾール、2−(2′−ヒドロキシ−5′−メ
チルフエニル)−5,6−ジクロルベンゾトリア
ゾール、2−(2′−ヒドロキシ−5′−第3ブチル
フエニル)ベンゾトリアゾール、2−(2′−ヒド
ロキシ−3′−メチル−5′−第3ブチルフエニル)
ベンゾトリアゾール、2−(2′−ヒドロキシ−3′,
5′−ジ−第3ブチルフエニル)−5−クロル−ベ
ンゾトリアゾール及び2−(2′−ヒドロキシ−
5′−フエニルフエニル)−5−クロルベンゾトリ
アゾール、2−(2′−ヒドロキシ−3′,5′−ジ−第
3ブチルフエニル)−5−クロロベンゾトリアゾ
ール、2−(2′−ヒドロキシ−5′−オクトキシフ
エニル)ベンゾトリアゾール等が有効である。
特に好適な紫外線吸収剤は、式
The present invention relates to a novel agricultural covering material, and more particularly, it is made of a blue-colored UV-shielding synthetic resin material having specific light transmission properties, and is particularly suitable for agricultural cultivation of fruit and vegetable plants. Relating to coating materials. Several agricultural covering materials with UV-shielding properties have been proposed. For example, JP 48-37459, JP 49-16301, JP 53-47383.
See Japanese Patent Application Laid-open No. 100445/1983, etc. On the other hand,
For a long time, various studies have been conducted on the relationship between light in the visible light range and plant growth. For example, Japanese Patent Publication No. 27-2911, Japanese Patent Publication No. 47-24376,
Special Publication No. 49-17093, Publication No. 49-43778, Comprehensive research on technologicalization of light quality utilization in facility agriculture: Published by the Agriculture, Forestry and Fisheries Technology Council Secretariat (1972)
(Published on February 29, 2016) See pages 88-89, etc. Furthermore, some agricultural films have been proposed that block ultraviolet rays and are also colored in a specific color. For example, see Japanese Patent Publication No. 54-15818, Japanese Unexamined Patent Publication No. 52-43637, Report of the Agricultural and Electrical Research Institute of the Central Research Institute of Electric Power Industry: Research Report: 71003 (October 1972), p. 18. However, although these conventionally proposed colored ultraviolet-shielding agricultural films can be expected to have a certain degree of improvement in promoting the growth of cultivated plants and increasing yield, they are still not sufficient. The present inventors have also focused on UV-shielding agricultural covering materials, and found that UV-shielding agricultural covering materials can inhibit the propagation of pathogenic bacteria on plants, prevent tearing of tomato fruits, increase the sugar content of fruits, and increase the sugar content of leaves. We have previously proposed this method after discovering that it has excellent effects on preventing rot in stem vegetables, preventing aging in green peppers, and preventing aging in cucumbers. For example, JP-A-53-47383, JP-A-52-98125, JP-A-53-2238, JP-A-53-27539, JP-A-53-75039,
See JP-A-53-117546, JP-A-53-127126, JP-A-53-127129, etc. Furthermore, regarding colored UV-blocking agricultural covering materials,
The present inventors disclosed in Japanese Patent Application Laid-Open No. 117738/1983 that the average transmittance for visible light in the wavelength range of 400 to 700 nm is at least 40%, and that
The ratio of the average transmittance to blue light with a wavelength of 500 nm to the average transmittance to red light with a wavelength of 600 to 700 nm is in the range of 1.2:1 to 2.5:1,
In addition, we have proposed a blue-colored ultraviolet-shielding agricultural covering material made of an agricultural synthetic resin film or plate that has the property of substantially blocking light rays with wavelengths of at least 370 nm and below. However, this UV-shielding agricultural covering material was developed specifically for raising rice seedlings, and has a fairly low transmittance for light in the red wavelength region, making it difficult to use when used in the facility cultivation of fruit and leafy vegetables. However, the disadvantage is that sufficient growth promotion and yield increase effects cannot be expected. Therefore, the present inventors conducted extensive research on colored ultraviolet-shielding agricultural covering materials suitable for growing fruit vegetables and leafy vegetables, especially fruit plants.
Agricultural coverings having the following light transmission properties: (a) substantially blocking the transmission of light with a wavelength of at least 370 nm or less, and (b) having an absorption maximum in the wavelength range of 440 nm to 700 nm between 590 and (c) the average transmittance of light with a wavelength between 440 and 590 nm is at least 85%; (d) (e) the average transmittance of light of wavelengths between 600 and 700 nm is at least 75%; and (e) the average transmittance of light of wavelengths between 400 and 500 nm is
Agricultural covering materials consisting of transparent synthetic resin films or plates colored in a blue color, with an average transmittance ratio of light with wavelengths between 600 and 700 nm of less than 1.2, are extremely suitable for growing fruit and vegetable plants. The present invention was completed based on this discovery. According to the present invention, the above (a), (b), (c),
Agricultural covering material suitable for cultivating fruit and vegetable plants, characterized by being made of a blue-colored transparent synthetic resin film or board that satisfies the five light transmission characteristics of (d) and (e). is provided. When the agricultural covering material provided by the present invention is used as a covering material for greenhouses and tunnels in the facility cultivation of fruit and vegetable plants, (a) it prevents the fatigue phenomenon during harvesting of fruit and vegetable plants; It can be effectively prevented, and the effect is particularly great in cucumbers, tomatoes, green beans, green peppers, etc. (effect of preventing fatigue). (b) The yield of fruit and vegetable plants can be significantly increased (yield increase effect). (c) It is possible to improve the quality of fruits and vegetable crops. For example, in the case of tomatoes, the incidence of fruit splitting can be reduced, and in cucumbers, the fruit color can be improved (quality improvement effect). (d) The growth of the plant height of fruit and vegetable plants is moderately suppressed,
The internodes are short, allowing you to grow tall, full-bodied plants (fulfilling cultivation effect). These cultivation effects can be obtained, and the contribution to the cultivation of fruit and vegetable plants is extremely large. In this specification, the "fatigue" phenomenon refers to, for example, "Vegetable Production Problems and Solutions" (Part 2) One Type of Technology Edition - [Seibundo Shinkosha Co., Ltd., August 25, 1978, Vol. As described in lines 10 to 20 on page 12 of [edition], in the cultivation of fruit and vegetable plants, when the fruit harvest period is over, the assimilation ability decreases due to insufficient accumulation of nutrients and aging of leaves. This refers to a phenomenon in which the yield of fruit is temporarily reduced and the quality of the fruit is often poor due to such factors. As used herein, the term "substantially blocking the transmission of light having a wavelength of xnm or less" means xnm
Not only does it completely block 100% of the transmission of light with the following wavelengths, but it also covers at least 80%, preferably 90% or more, and more preferably 95% or more of the transmission of xnm or shorter wavelengths. It is also used in the sense that it also includes. Moreover, "absorption maximum" refers to a portion of an absorption curve of an absorption spectrum that exhibits the maximum absorbance or extinction coefficient within a certain wavelength range. Note that when the top of the peak indicating the absorption maximum is substantially flat, the center point of the flat portion is referred to as the absorption maximum. Furthermore, "average transmittance" refers to the wavelength range (a to b) in a curve [f(x)] of light wavelength (horizontal axis: x axis) versus light transmittance (vertical axis). In nm, it refers to the value expressed as ∫ b / a f (x) dx (%) / (ba). Therefore, the agricultural covering material that can be preferably used in the present invention satisfies the light transmission properties shown in (a), (b), (c), (d), and (e) above, and furthermore, the following ( a′), (b′),
Any one of the requirements selected from (c') and (d')
It satisfies more than one requirement at the same time. (a') Substantially blocking the transmission of light having a wavelength of at least 380 nm or less; (b') The absorption maximum in the wavelength range from 440 nm to 700 nm is 590 to 625 nm, more preferably
Between 595 and 620 nm, and the light transmittance at the absorption maximum is 70 to 88%, more preferably 75 to 85%.
be within the range of (c') The average transmittance of light with wavelengths between 440 and 590 nm is at least 85%, more advantageously 87%. and (d') the average transmittance of light with a wavelength between 600 and 700 nm is at least 75% or more, more preferably 77 to 88
Must be within the range of %. In addition, the agricultural covering material of the present invention has the following characteristics when a light wavelength (horizontal axis) versus light transmittance (vertical axis) curve is drawn.
It is preferable to have a light transmittance characteristic in which the curve rises as vertically as possible within the light wavelength range of 380nm to 420nm, especially 400nm.
About 15~80% of light with a wavelength of m is transmitted, and 400~
It is desirable that the average transmittance at 440 nm is generally in the range of 65 to 90%, preferably 70 to 85%. Furthermore, the agricultural coating material of the present invention has a wavelength from 440 nm to
There is no absorption peak in the wavelength range up to 590 nm, and in particular, the transmittance in the wavelength range from 440 nm to 525 nm can be 85% or more. but,
On the other hand, within the wavelength range from 600nm to 700nm,
In addition to the absorption peak giving the absorption maximum, weaker absorption peaks may be present, such weaker absorption peaks can exist between 660 and 700 nm, and therefore the average between 625 and 700 nm Transmission can generally be in the range 75-90%, preferably 78-87%. In addition, as the agricultural covering material of the present invention, 500~
It is desirable that the average transmittance of light with wavelengths between 600 nm and 600 nm is within the range of 0.8 to 1.1 times the average transmittance of visible light with wavelengths of 600 nm or more. There is no particular restriction on the wavelength region of 700 nm or more, but in general, the wavelength region of 700 nm or more,
In particular, the average transmittance in the infrared region is 95% or less and 60%
It is desirable that the above is achieved. Agricultural covering materials having the above-mentioned light transmitting properties can be produced, for example, by blending dyes or pigments and ultraviolet absorbers described below with ordinary film-forming synthetic resins and forming them into films or plates, or by forming ordinary transparent synthetic resins into films or plates. At least one surface of the resin film or plate is coated with a coating composition containing a dye or pigment, an ultraviolet absorber, and a synthetic resin vehicle as described below, or one of the dye or pigment and the ultraviolet absorber of the present invention is coated. It can be produced by a method such as blending it into a film or board and coating at least one surface of the film or board with the other in the form of a coating composition as described above. Film-forming thermoplastic synthetic resins that can be used include, for example, polyvinyl chloride, polyvinylidene chloride, polyethylene, polypropylene, polystyrene, polyester, polyamide, polycarbonate, polymethyl methacrylate, polyacrylate, polyvinyl acetate, or polymers thereof. Contains mainly copolymers or blends, etc.
In particular, polyvinyl chloride, polymethyl methacrylate, polyethylene, and ethylene-vinyl acetate copolymer are suitable for reasons such as light resistance, light transmittance, and strength, and polyvinyl chloride is especially suitable. The ultraviolet absorber that can be incorporated into these synthetic resins can be appropriately selected from a wide range of types, taking into consideration the ultraviolet absorbing ability of the ultraviolet absorber and its compatibility with the synthetic resin used. Examples of usable ultraviolet absorbers include the following. Hydroquinone series - hydroquinone, hydroquinone disalicylate salicylic acid series - phenyl salicylate, paraoctylphenyl salicylate benzophenone series - 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-n-
Octoxybenzophenone, 2-hydroxy-
4-methoxy-2'-carboxybenzophenone, 2,4-dihydroxybenzophenone,
2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-hydroxy-4-benzoyloxybenzophenone, 2,2'-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy -5-sulfonebenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2,2'-hydroxy-4,4'-dimethoxy-5-sodium sulfobenzophenone, 4-dodecyloxy -2-hydroxybenzophenone, 2-hydroxy-5-chlorobenzophenone benzotriazole-based -2-(2'-hydroxy-
5′-methylphenyl)benzotriazole, 2
-(2'-hydroxy-5'-methylphenyl)-5
-carboxylic acid butyl ester benzotriazole, 2-(2'-hydroxy-5'-methylphenyl)-5,6-dichlorobenzotriazole,
2-Hydroxy-5'-methylphenyl)-5-
Ethylsulfonebenzotriazole, 2-
(2'-hydroxy-5'-tert-butylphenyl)-
5-chlorobenzotriazole, 2-(2'-hydroxy-5'-tert-butylphenyl)benzotriazole, 2-(2'-hydroxy-5'-aminophenyl)benzotriazole, 2-(2'-
Hydroxy-3',5'-dimethylphenyl)benzotriazole, 2-(2'-hydroxy-3',
5'-dimethylphenyl)-5-methoxybenzotriazole, 2-(2'-methyl-4'-hydroxyphenyl)benzotriazole, 2-
(2'-stearyloxy-3',5'-dimethylphenyl)-5-methylbenzotriazole, 2-
(2'-hydroxy-5'-carboxyphenyl)
Benzotriazole ethyl ester, 2-
(2'-hydroxy-3'-methyl-5'-tert-butylphenyl)benzotriazole, 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)
-5-chlorobenzotriazole, 2-
(2'-hydroxy-5'-methoxyphenyl)benzotriazole, 2-(2'-hydroxy-
5'-Phenylphenyl)-5-chlorobenzotriazole, 2-(2'-Hydroxy-5'-cyclohexylphenyl)benzotriazole, 2
-(2'-hydroxy-4',5'-dimethylphenyl)-5-phenoxycarbonylbenzotriazole, 2-(2'-hydroxy-3',5'-dichlorophenyl)benzotriazole, 2-(2 ′−
Hydroxy-4',5'-dichloro)benzotriazole, 2-(2'-hydroxy-3',5'-dimethylphenyl)-5-ethylsulfonebenzotriazole, 2-(2'-hydroxy-5'- Phenylphenyl)benzotriazole, 2-(2'-
Hydroxy-4'-octoxyphenyl)benzotriazole, 2-(2'-hydroxy-5'-methoxyphenyl)-5-methylbenzotriazole, 2-(2'-hydroxy-5'-methylphenyl)-5 -Ethoxycarbonylbenzotriazole, 2-(2'-acetoxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)-
5-chlorobenzotriazole. Among these ultraviolet absorbers, benzophenone-based and benzotriazole-based ones are preferred, and among the benzophenone-based ones, 2,3-dihydroxy-4,4-dimethoxybenzophenone,
2,2'-dihydroxy-4-methoxybenzophenone and 2,2',4',4'-tetrahydroxybenzophenone;
(2'-hydroxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-5'-methylphenyl)-5,6-dichlorobenzotriazole, 2-(2'-hydroxy-5'-tertiary butylphenyl)benzotriazole, 2-(2'-hydroxy-3'-methyl-5'-tert-butylphenyl)
Benzotriazole, 2-(2'-hydroxy-3',
5'-di-tert-butylphenyl)-5-chloro-benzotriazole and 2-(2'-hydroxy-
5'-Phenylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-5'- Octoxyphenyl)benzotriazole and the like are effective. Particularly suitable UV absorbers have the formula
【式】又は[Formula] or
【式】
式中、R1及びR2は同一もしくは相異なり、そ
れぞれ低級アルキル基、又はアリール基特にフエ
ニル基を表わし、殊にR1は好ましくはC3以下の
分岐鎖状の低級アルキル基又はフエニル基であ
り、R3はC6以上、特にC8〜C10のアルキル基を表
わし、Xは水素原子又はハロゲン原子、特に塩素
原子である、
で表わされるベンゾトリアゾール誘導体である。
上記の如き紫外線吸収剤の配合量は、紫外線吸
収剤の種類、使用する合成樹脂の種類、フイルム
又は板の厚さ等に依存して広範に変えることがで
きるが、本発明が目的としている370nm以下、
特に380nm以下の紫外線の透過を実質的に完全
に阻止するためには、紫外線吸収剤の配合量と得
られるフイルム又は板の厚さとの間に下記式
15≦AB≦600
好適には
20≦AB≦400
式中、Aは紫外線吸収剤の配合量(PHR)を
表わし、Bはフイルム又は板の厚さ(μ)であ
る、
で示される関係が満たされていることが特に好ま
しい。ここにPHRとは合成樹脂100重量部当りの
重量部数を意味する。
また紫外線吸収剤の配合量(A)は、合成樹脂及び
紫外線吸収剤の種類により異なるが、一般に
0.003〜5PHR、特にフイルムの場合0.1〜5.0PHR
の範囲内が好適である。
他方、前記フイルム形成性合成樹脂に配合しう
る染料又は顔料としては、最大吸収波長
(λmax)が590〜625nm、好ましくは590〜620n
mの範囲内にあり且つ前記合成樹脂と相溶性の良
好な青色系の染料又は顔料を使用することができ
る。一般に染料よりも顔料の方が耐候性に優れて
おり、顔料の方が適している。
使用し得る顔料としては、例えば、下記のもの
が挙げられる。無金属フタロシアニンブルー(C.
I.Pigment Blue16;C.I.74100)、フタロシアニン
ブルー(C.I.Pigment Blue15;C.I.74160)、フタ
ロシアニングリーン(C.I.Pigment Green7;C.
I.74260)、群青(C.I.77007)、紺青(C.I.77510及
び77520)、コバルトブルー(C.I.77346)、セルリ
アンブルー(C.I.77368)、アルカリブルーレーキ
(C.I.42750A及び42770A)、ピーコツクブルーレ
ーキ(C.I.42090及び42025)、ビクトリアブルー
レーキ(C.I.44045)、フアストスカイブルー(C.
I.74180)、インダンスレンブルーRS(C.I.69800)、
インダスレンブルーBC(C.I.69825)、インジゴ
(C.I.73000)、など。
また、使用し得る染料としては、例えば、C.I.
Solvent Blue33、35、65、79、90、95、及び122
等を挙げることができる。
これら顔料又は染料はそれぞれ単独で使用する
ことができ、或いは2種又はそれ以上組合わせて
用いてもよい。
これら着色剤のうち特に好適なものはフタロシ
アニン系顔料であり、就中、無金属フタロシアニ
ンブルー、フタロシアニンブルー、フタロシアニ
ングリーン、が好ましい。また染料の中では、C.
I.Solvent Blue33、90、及び95が好ましい。
上記の如き着色剤の配合量は、使用する着色剤
の種類や合成樹脂の種類、フイルム又は板の厚さ
等に応じて広範に変えることができ、個々の場合
に必要とされる着色剤の配合量は当業者であれば
Lambert−Beerの法則に準じて簡単な小期模実
験を行なうことにより容易に決定することができ
る。しかし、前記(b)、(c)、(d)及び(e)に示す光透過
特性を有する青色系に着色された合成樹脂製のフ
イルム又は板を得るためには、一般に、着色剤の
配合量と得られるフイルム又は板の厚さとの間に
下記式
0.01≦PB≦20
好適には
0.1≦PB≦10
式中、Pは着色剤の配合量(PHR)を表わし、
Bはフイルム又は板の厚さ(μ)である、
で示される関係が成立する場合が多い。
着色剤の配合量(P)は、合成樹脂及び着色剤
の種類により異なるが、一般に0.0001〜0.4PHR、
好ましくは0.001〜0.1PHRの範囲内とすることが
できる。
また着色剤として特に好適に使用されるフタロ
シアニン系顔料の場合、配合量(P)は非常に少
なくてよく、一般に0.001〜0.06PHR、好ましく
は0.005〜0.04PHR、更に好ましくは0.01〜
0.03PHRの範囲とすることができる。
本発明に使用する合成樹脂フイルム又は板に
は、紫外線吸収剤に加えて、必要に応じて他の通
常の樹脂添加物、例えば可塑剤、滑剤、酸化防止
剤、光安定剤、帯電防止剤、防潤剤、熱安定剤、
染料、顔料等を少量含ませることもできる。
上記のフイルム又は板はそれ自体公知の種々の
方法、例えばカレンダー法、T−ダイ法、インフ
レーシヨン法等の溶融押出法、プレス法、溶液流
延法等を用いて製造することができる。
かくの如くして形成されたフイルム又は板は、
その用途等に応じて、その厚さを広い範囲に亘つ
て変えることができるが、一般に本発明の目的に
対しては、15〜5000μ、特に20〜500μの範囲が好
適である。該フイルム又は板は、必要に応じて、
補強等の目的で、他の合成樹脂のフイルムやシー
ト、ガラス等に積層して使用することもできる。
また本発明のフイルム又は板からなる被覆材の
片面または両面上には、メタクリル酸メチル、メ
タクリル酸エチル等のメタクリル酸エステル及
び/又はアクリル酸メチル、アクリル酸エチル、
アクリル酸ブチル等のアクリル酸エステル及び/
又はメタアクリル酸等のα,β−不飽和カルボン
酸よりなる重合体もしくは共重合体よりなる表面
処理剤を塗布することもできる。
本発明により提供される農業用被覆材は、農作
物、殊に果菜類植物、例えば、キユウリ、スイ
カ、メロン、ハウスメロン、露地メロン、シロウ
リ、トマト、ナス、ピーマン、イチゴ、オクラ、
インゲン、ソラマメ、エダマメ、スイートコーン
等〔「野菜生産の問題と解決」(下)−種類別技術
編−〔(株)誠文堂新光社昭和52年8月25日第1版発
行〕参照〕の作物の施設栽培において、温室、パ
イプハウス、トンネル等の被覆材として有利に使
用することができ、これにより前述した如き種々
の優れた栽培効果(成疲れ防止効果、増収効果、
品質向上効果、充実栽培効果等)を達成すること
ができる。
本発明の被覆材を用いて農作物を栽培する場
合、従来の被覆材に代えて本発明の被覆材を用い
ること以外はそれ自体通常の施設栽培方法と全く
同様にして実施することができ、何ら特別の考慮
を払う必要はない。すなわち、本発明の被覆材を
被覆した植物栽培用施設、例えば温室、パイプハ
ウス、トンネル内において、通常の農作業手順に
従つて農作物を温室栽培、ハウス栽培、トンネル
栽培することができる。この場合、従来から温室
内、ハウス内又はトンネル内の温湿度の調整のた
めに、天窓を開けたり、肩換気を行なつたり、或
いは裾上げ換気を行なうことが普通行われている
が、本発明の被覆材を用いた場合も全く同様に行
なうことができる。
以下、本発明の被覆材の製造及びそれを用いた
栽培の効果について、実施例を挙げてさらに説明
する。
実施例 A
(フイルムの調製)
ポリ塩化ビニル100重量部、ジオクチルフタレ
ート(可塑剤)47重量部、ジブチル錫マレート
(熱安定剤)1.5重量部、ステアリン酸亜鉛(熱安
定剤)0.5重量部、ステアリン酸カルシウム(熱
安定剤)1.0重量部、ステアリン酸(滑剤)0.1重
量部、ソルビタンモノラウレート(防曇剤)1.0
重量部、並びに下記表−1に示す所定量の顔料及
び紫外線吸収剤を混合し、その混合物をエクスト
ルーダーにより200℃で溶融押出し、厚さ0.1m/
mのフイルムNo.1〜10を得た。各々のフイルム
の光線透過率曲線を添付の第1図に示す。また下
記表−2に光線透過曲線の解析結果を示す。
比較例 A
(フイルムの調製)
ポリ塩化ビニル100重量部、ジオクチルフタレ
ート(可塑剤)45重量部、ジブチル錫マレート
(熱安定剤)1.5重量部、ステアリン酸亜鉛(熱安
定剤)1.0重量部、ステアリン酸(滑剤)0.1重量
部、ソルビタンモノラウレート(無滴剤)1.0重
量部、2−(2′−ヒドロキシ−3′,5′−ジ−第3級
ブチルフエニル)−5−クロルベンゾトリアゾー
ル(紫外線吸収剤)1.5重量部及び青色顔料、P.
V.First Blue A−2R0.08重量部を混合し、その
混合物をエクストールーダーにより200℃で溶融
押出し、厚さ0.1m/mのフイルムNo.11を得た。
このフイルムの光線透過率曲線を第1図に示
す。また下記表−2に光線透過曲線の解析結果を
示す。[Formula] In the formula, R 1 and R 2 are the same or different and each represents a lower alkyl group or an aryl group, particularly a phenyl group, and in particular R 1 is preferably a branched lower alkyl group having C 3 or less or It is a benzotriazole derivative represented by: a phenyl group, R 3 represents a C 6 or higher alkyl group, especially a C 8 to C 10 alkyl group, and X is a hydrogen atom or a halogen atom, especially a chlorine atom. The amount of the ultraviolet absorber as described above can be varied widely depending on the type of ultraviolet absorber, the type of synthetic resin used, the thickness of the film or plate, etc. below,
In particular, in order to substantially completely block the transmission of ultraviolet rays of 380 nm or less, the following formula should be established between the amount of ultraviolet absorber and the thickness of the resulting film or plate: 15≦AB≦600, preferably 20≦AB ≦400 In the formula, A represents the blending amount (PHR) of the ultraviolet absorber, and B represents the thickness (μ) of the film or plate. It is particularly preferable that the following relationship is satisfied. Here, PHR means parts by weight per 100 parts by weight of synthetic resin. In addition, the amount (A) of the UV absorber varies depending on the type of synthetic resin and UV absorber, but in general
0.003~5PHR, especially for film 0.1~5.0PHR
It is preferable to fall within the range of . On the other hand, the dye or pigment that can be incorporated into the film-forming synthetic resin has a maximum absorption wavelength (λmax) of 590 to 625 nm, preferably 590 to 620 nm.
A blue dye or pigment that is within the range of m and has good compatibility with the synthetic resin can be used. Generally, pigments have better weather resistance than dyes and are therefore more suitable. Examples of pigments that can be used include the following. Metal-free phthalocyanine blue (C.
I.Pigment Blue16; CI74100), Phthalocyanine Blue (CIPigment Blue15; CI74160), Phthalocyanine Green (CIPigment Green7; C.
I.74260), Ultramarine Blue (CI77007), Deep Blue (CI77510 and 77520), Cobalt Blue (CI77346), Cerulean Blue (CI77368), Alkaline Blue Lake (CI42750A and 42770A), Peacock Blue Lake (CI42090 and 42025), Victoria Blue Rake (CI44045), Fast Sky Blue (C.
I.74180), Indanthrene Blue RS (CI69800),
Industhrene Blue BC (CI69825), Indigo (CI73000), etc. In addition, dyes that can be used include, for example, CI
Solvent Blue33, 35, 65, 79, 90, 95, and 122
etc. can be mentioned. These pigments or dyes can be used alone, or in combination of two or more. Particularly preferred among these colorants are phthalocyanine pigments, with metal-free phthalocyanine blue, phthalocyanine blue, and phthalocyanine green being particularly preferred. Among dyes, C.
I.Solvent Blue 33, 90, and 95 are preferred. The amount of the colorant mentioned above can be varied widely depending on the type of colorant used, the type of synthetic resin, the thickness of the film or board, etc., and the amount of colorant required in each case can be varied widely. A person skilled in the art can determine the blending amount.
It can be easily determined by conducting a simple short-term simulation experiment according to the Lambert-Beer law. However, in order to obtain a blue-colored synthetic resin film or plate having the light transmission properties shown in (b), (c), (d), and (e) above, it is generally necessary to mix a coloring agent. The relationship between the amount and the thickness of the film or board obtained is expressed by the following formula: 0.01≦PB≦20, preferably 0.1≦PB≦10 In the formula, P represents the blending amount (PHR) of the colorant, and B represents the thickness of the film or board. In many cases, the relationship shown by the thickness (μ) holds true. The amount (P) of the colorant varies depending on the type of synthetic resin and colorant, but is generally 0.0001 to 0.4PHR,
Preferably, it can be within the range of 0.001 to 0.1 PHR. In addition, in the case of phthalocyanine pigments that are particularly suitably used as colorants, the blending amount (P) may be very small, generally 0.001 to 0.06 PHR, preferably 0.005 to 0.04 PHR, and more preferably 0.01 to 0.06 PHR.
It can be in the range of 0.03PHR. In addition to the ultraviolet absorber, the synthetic resin film or plate used in the present invention may contain other conventional resin additives, such as plasticizers, lubricants, antioxidants, light stabilizers, antistatic agents, Moisturizer, heat stabilizer,
A small amount of dye, pigment, etc. can also be included. The above-mentioned film or plate can be manufactured using various methods known per se, such as a calender method, a T-die method, a melt extrusion method such as an inflation method, a press method, a solution casting method, and the like. The film or plate thus formed is
The thickness can vary over a wide range depending on the application, but generally a range of 15 to 5000 microns, particularly 20 to 500 microns, is suitable for the purposes of the present invention. The film or plate may include, if necessary,
It can also be used by laminating it on other synthetic resin films, sheets, glass, etc. for reinforcement purposes. Furthermore, on one or both sides of the coating material made of the film or plate of the present invention, methacrylic acid esters such as methyl methacrylate and ethyl methacrylate and/or methyl acrylate, ethyl acrylate,
Acrylic esters such as butyl acrylate and/or
Alternatively, a surface treatment agent made of a polymer or copolymer of α,β-unsaturated carboxylic acid such as methacrylic acid can also be applied. The agricultural covering material provided by the present invention is suitable for agricultural crops, especially fruit and vegetable plants, such as cucumber, watermelon, melon, house melon, open field melon, white melon, tomato, eggplant, green pepper, strawberry, okra,
Green beans, fava beans, edamame, sweet corn, etc. [Refer to “Vegetable Production Problems and Solutions” (Part 2) – Technology by Type – [Seibundo Shinkosha Co., Ltd., 1st edition published on August 25, 1970]] It can be advantageously used as a covering material for greenhouses, pipe houses, tunnels, etc. in the facility cultivation of crops.
(quality improvement effect, enriched cultivation effect, etc.) can be achieved. When cultivating agricultural products using the covering material of the present invention, it can be carried out in exactly the same manner as a normal facility cultivation method, except that the covering material of the present invention is used in place of the conventional covering material. No special consideration is required. That is, in a plant cultivation facility coated with the coating material of the present invention, such as a greenhouse, a pipe house, or a tunnel, crops can be cultivated in a greenhouse, in a greenhouse, or in a tunnel according to normal agricultural procedures. In this case, in order to adjust the temperature and humidity inside the greenhouse, greenhouse, or tunnel, it has been common practice to open skylights, perform shoulder ventilation, or perform hem ventilation. Exactly the same procedure can be carried out when using the coating material of the invention. Hereinafter, the production of the coating material of the present invention and the effects of cultivation using the same will be further explained with reference to Examples. Example A (Preparation of film) 100 parts by weight of polyvinyl chloride, 47 parts by weight of dioctyl phthalate (plasticizer), 1.5 parts by weight of dibutyltin maleate (thermal stabilizer), 0.5 parts by weight of zinc stearate (thermal stabilizer), Stear Calcium phosphate (heat stabilizer) 1.0 parts by weight, stearic acid (lubricant) 0.1 parts by weight, sorbitan monolaurate (antifogging agent) 1.0 parts by weight
Parts by weight and predetermined amounts of pigments and ultraviolet absorbers shown in Table 1 below were mixed, and the mixture was melt-extruded at 200°C with an extruder to a thickness of 0.1 m/cm.
Films Nos. 1 to 10 of m were obtained. The light transmittance curves of each film are shown in the attached FIG. 1. Further, Table 2 below shows the analysis results of the light transmission curve. Comparative Example A (Preparation of film) 100 parts by weight of polyvinyl chloride, 45 parts by weight of dioctyl phthalate (plasticizer), 1.5 parts by weight of dibutyltin maleate (thermal stabilizer), 1.0 parts by weight of zinc stearate (thermal stabilizer), stearin 0.1 part by weight of acid (lubricant), 1.0 part by weight of sorbitan monolaurate (non-drop agent), 2-(2'-hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole (ultraviolet light) Absorbent) 1.5 parts by weight and blue pigment, P.
0.08 parts by weight of V.First Blue A-2R was mixed and the mixture was melt-extruded at 200°C using an extruder to obtain film No. 11 with a thickness of 0.1 m/m. The light transmittance curve of this film is shown in FIG. Further, Table 2 below shows the analysis results of the light transmission curve.
【表】【table】
【表】【table】
【表】
実施例1〜2及び比較例1〜7
6月16日にインゲン(品種:新江戸川)を播種
し、6月24日に条間60cm、株間30cmになるように
苗を定植し、表−1に示した各々のフイルムによ
る被覆下にトンネル栽培を行つた。収穫は7月27
日から8月30日まで行い、その結果を表−3及び
4に示す。上記インゲンの栽培、すなわち、施
肥、潅水、温度管理は、全栽培期間を通して、慣
行法に準じて行なつた。[Table] Examples 1 to 2 and Comparative Examples 1 to 7 Green beans (variety: Shin-Edogawa) were sown on June 16th, and seedlings were planted on June 24th with a row spacing of 60 cm and a plant spacing of 30 cm. Tunnel cultivation was carried out while covered with each film shown in Table 1. Harvest is July 27th
The results are shown in Tables 3 and 4. Cultivation of the green beans, that is, fertilization, watering, and temperature control, were carried out according to conventional methods throughout the entire cultivation period.
【表】【table】
【表】【table】
【表】【table】
【表】
表−3の結果より、フイルムNo.1及びNo.2被
覆区では、他のフイルム被覆区に比べて、草丈の
伸長量が少ないにもかかわらず、節数及び側枝数
が驚く程多いことがわかる。この結果はフイルム
No.1及びNo.2の被覆区ではインゲンの草丈が適
切に抑制され、節間長が短かく、がん丈な充実感
にあふれる株に生育したことを示している。
また、表−4から明らかなとおり、フイルム
No.1及びNo.2被覆区では、他のフイルム被覆区
に比べて、時期別収量差が、極めて少く、株の
「成疲れ」現象が、ほとんど見られず、総収量も
圧到的に多く、かつ、莢平均重量も大きく、品質
的にも優れている。
実施例3〜4及び比較例8〜16
表−1に示した各種フイルムを10棟のパイプハ
ウス(開口4.5m、奥行15m)に各々展張した。
11月20日に播種したキユウリ(品種:ときわ光
3号P型)を12月27日に各々のパイプハウス内に
4.5株/坪になるように定植し、2月6日から収
穫を始め、5月初旬まで栽培を続けた。上記キユ
ウリの栽培、すなわち、施肥、潅水、温度管理
は、全期間を通して慣行方法に準じて行つた。そ
の結果を表−5に示す。[Table] From the results in Table 3, in the film No. 1 and No. 2 covered plots, the number of nodes and lateral branches was surprisingly large despite the fact that the amount of plant height elongation was smaller than in the other film covered plots. It turns out that there are many things. This result is a film
In covered plots No. 1 and No. 2, the plant height of green beans was appropriately suppressed, and the internode length was short, indicating that the plants grew into tall, full-bodied plants. In addition, as is clear from Table 4, film
In No. 1 and No. 2 covered plots, compared to other film-covered plots, the difference in yield by season is extremely small, the phenomenon of "tiredness" of plants is hardly observed, and the total yield is also overwhelming. There are many, the average weight of the pods is large, and the quality is also excellent. Examples 3 to 4 and Comparative Examples 8 to 16 Various films shown in Table 1 were spread in 10 pipe houses (opening 4.5 m, depth 15 m). The cucumbers (variety: Tokiwa Hikari No. 3 P type) sown on November 20th were planted in each pipe house on December 27th.
They were planted at a rate of 4.5 plants per tsubo, and harvesting began on February 6th and cultivation continued until early May. Cultivation of the cucumber, that is, fertilization, watering, and temperature control, was carried out according to conventional methods throughout the entire period. The results are shown in Table-5.
【表】
表−5の結果から、フイルムNo.1及びNo.2の
被覆区では、草丈の伸長が適度に抑制され、時期
別収量差が明らかに少く成疲れ現象がなく、全栽
培期を通して、多収穫で且つ、安定した収穫をす
ることができることがわかる。
実施例5及び比較例17〜23
実施例3で使用したパイプハウス及び被覆材を
そのまま使用してトマトの栽培実験を行つた。8
月15日にトマト(品種:大型瑞光)を播種し、10
月4日にパイプハウス内に9株/坪になるように
定植し、1月3日より、収穫を開始した。上記ト
マトの栽培、すなわち、施肥、潅水、温度管理
は、慣行法に準じて行つた。[Table] From the results in Table 5, in the plots covered with Film No. 1 and No. 2, the elongation of plant height was moderately suppressed, the difference in yield between seasons was clearly small, there was no fatigue phenomenon, and there was no fatigue phenomenon throughout the entire cultivation period. It can be seen that high yields and stable harvests can be achieved. Example 5 and Comparative Examples 17 to 23 A tomato cultivation experiment was conducted using the pipe house and covering material used in Example 3 as they were. 8
Sow tomatoes (variety: large size Zuikou) on the 15th of the month,
On January 4th, we planted 9 plants per tsubo in a pipe house, and harvesting began on January 3rd. Cultivation of the tomatoes, ie, fertilization, watering, and temperature control, were carried out in accordance with conventional methods.
【表】
表−6の結果から明らかなとおり、フイルム
No.1被覆区では、他の被覆区に比べて、草丈は
適切に抑制され、時期別収量が常に高く安定収量
が達成されしかも収穫したトマトの同心円状及び
放射状の裂果の発生率も極めて低いことがわか
る。
実施例6及び比較例24
8月10日ピーマン(品種:新さきかけ)を播種
し、10月7日に表−1に示したフイルムNo.−1
(実施例6)とフイルムNo.−3(比較例22)によ
る被覆下にハウス栽培を行つた。ピーマンの栽培
は、施肥、潅水、温度管理を全期間を通して慣行
方法に準じて行なつた。
収穫は10月20日から5月末日まで行つたが、フ
イルムNo.1被覆区ではフイルムNo.3被覆区に比
べて成疲れ現象が見られず、時期別収量差が極め
て少く、総収量も増加し、品質の向上効果が見ら
れ、高収益を上げることができた。[Table] As is clear from the results in Table 6, the film
In No. 1 cover plot, compared to other cover plots, the plant height is properly controlled, the seasonal yield is always high and stable yields are achieved, and the incidence of concentric and radial fissures in the harvested tomatoes is extremely low. I understand that. Example 6 and Comparative Example 24 Green peppers (variety: Shinsakikake) were sown on August 10th, and film No.-1 shown in Table-1 was sown on October 7th.
(Example 6) and film No. 3 (Comparative Example 22) were used for greenhouse cultivation. Cultivation of peppers was carried out according to conventional methods throughout the period, including fertilization, watering, and temperature control. Harvesting was carried out from October 20th to the end of May, and the fatigue phenomenon was not observed in the plots covered with film No. 1 compared to the plots covered with film No. 3, and the difference in yield between seasons was extremely small, and the total yield was also low. We were able to see an increase in quality, and we were able to generate high profits.
第1図は実施例及び比較例で用いたフイルム
No.1〜フイルムNo.11の波長別光線透過曲線の図
である。
Figure 1 shows the films used in Examples and Comparative Examples.
FIG. 2 is a diagram of wavelength-specific light transmission curves for films No. 1 to No. 11.
Claims (1)
質的に遮蔽し、 (b) 440nmから700nmまでの波長領域内におけ
る吸収極大が595〜620nm間にあり且つ該吸収
極大における光の透過率が75〜85%の範囲内に
あり、 (c) 440〜590nm間の波長の光の平均透過率が少
くとも85%以上であり、 (d) 600〜700nm間の波長の光の平均透過率が77
〜88%であり、そして (e) 400〜500nm間の波長の光の平均透過率対
600〜700nm間の波長の光の平均透過率の比率
が1.2未満である (f) 400nmの波長の光を15%以上透過し且つ400
〜440nm間の波長の光の平均透過率が65〜90
%である 青色系に着色された透明の合成樹脂製のフイル
ム又は板から成ることを特徴とする果菜類植物の
栽培に適した農業用被覆材。[Scope of Claims] 1. Having the following light transmission properties, namely (a) substantially blocking the transmission of light having a wavelength of at least 370 nm or less, and (b) having an absorption maximum in the wavelength range from 440 nm to 700 nm. is between 595 and 620 nm, and the light transmittance at the absorption maximum is within the range of 75 to 85%, and (c) the average transmittance of light with a wavelength between 440 and 590 nm is at least 85% or more. , (d) The average transmittance of light with a wavelength between 600 and 700 nm is 77
~88%, and (e) the average transmittance of light for wavelengths between 400 and 500 nm vs.
The average transmittance ratio of light with a wavelength between 600 and 700 nm is less than 1.2 (f) Transmits 15% or more of light with a wavelength of 400 nm, and
The average transmittance of light with wavelengths between ~440nm is 65~90
% An agricultural covering material suitable for cultivating fruit and vegetable plants characterized by being made of a blue-colored transparent synthetic resin film or board.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14380779A JPS5668327A (en) | 1979-11-08 | 1979-11-08 | Agricultural cover material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14380779A JPS5668327A (en) | 1979-11-08 | 1979-11-08 | Agricultural cover material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5668327A JPS5668327A (en) | 1981-06-09 |
JPS6411251B2 true JPS6411251B2 (en) | 1989-02-23 |
Family
ID=15347423
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14380779A Granted JPS5668327A (en) | 1979-11-08 | 1979-11-08 | Agricultural cover material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5668327A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0746973B1 (en) * | 1994-02-21 | 2000-08-02 | Asahi Glass Green-Tech Company, Limited | Agricultural covering material |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58146216A (en) * | 1982-02-23 | 1983-08-31 | 三井東圧化学株式会社 | Agricultural covering material |
JPS5941346A (en) * | 1982-08-31 | 1984-03-07 | Nippon Carbide Ind Co Ltd | Ultraviolet screening agricultural vinyl film |
-
1979
- 1979-11-08 JP JP14380779A patent/JPS5668327A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0746973B1 (en) * | 1994-02-21 | 2000-08-02 | Asahi Glass Green-Tech Company, Limited | Agricultural covering material |
Also Published As
Publication number | Publication date |
---|---|
JPS5668327A (en) | 1981-06-09 |
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