JPS6397650A - Heat-resistant resin composition - Google Patents
Heat-resistant resin compositionInfo
- Publication number
- JPS6397650A JPS6397650A JP61243169A JP24316986A JPS6397650A JP S6397650 A JPS6397650 A JP S6397650A JP 61243169 A JP61243169 A JP 61243169A JP 24316986 A JP24316986 A JP 24316986A JP S6397650 A JPS6397650 A JP S6397650A
- Authority
- JP
- Japan
- Prior art keywords
- methylstyrene
- acrylonitrile
- aromatic polyester
- alpha
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims description 7
- 229920006015 heat resistant resin Polymers 0.000 title claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229920000728 polyester Polymers 0.000 claims abstract description 29
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 26
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 229920006249 styrenic copolymer Polymers 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 18
- 239000011347 resin Substances 0.000 abstract description 18
- 230000003287 optical effect Effects 0.000 abstract description 9
- 229920001577 copolymer Polymers 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229920001897 terpolymer Polymers 0.000 abstract 1
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、特定の芳香族ポリエステルと、特定のスチレ
ン系樹脂とをブレンドして得られる耐熱性樹脂組成物に
関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a heat-resistant resin composition obtained by blending a specific aromatic polyester and a specific styrene resin.
さらに詳しくは、一般式（１）
（ただし、ｎは重合度を衣わす）
で六わす芳香族ポリエステルと、α−メチルスチレン及
びアクリロニトリルを共１合成分として會むスチレン系
共重合体をブレンドして得られる樹脂組成物に関する。More specifically, an aromatic polyester represented by the general formula (1) (where n affects the degree of polymerization) is blended with a styrenic copolymer containing α-methylstyrene and acrylonitrile as one component. The present invention relates to a resin composition obtained by
本発明の組成物は、選明でかつ高い耐熱性を有しており
、例えば光ディスク等の光学材料として有用である。The composition of the present invention is selective and has high heat resistance, and is useful, for example, as an optical material for optical discs and the like.
（従来の技術）
一般式（２）
（ただし、ｎは重合度を表わす）
（式中、Ｘは、−ＣＨ２−１−Ｃ（ＣＨ５）ｚ−１−０
−１−Ｃ−１−Ｓ−１−８０２−等の２価の基、Ｒは、
Ｈ１−ＣＨ３、−Ｃ２Ｈ５、（衿等を示す）で戎わされ
る芳香族ポリエステルは、透明性、耐熱性、機械特性等
に優れたポリマーであり、特にＸが−Ｃ（ＣＨ３）２−
１かつＲがすべて水素であるタイプは、工業的にも製造
され、広く用いられている。これらの特性を生かして他
の種々のポリマーとブレンドする研究も数多くなされて
いる。しかし通常、他のポリマーとブレンドすると、充
分な相溶性を有していないため、機械的強度は低下し、
透明な樹脂は得られない。また機械的強度の低下がない
場合でも透明な樹脂が得られるケースはまれである。(Prior art) General formula (2) (where n represents the degree of polymerization) (wherein, X is -CH2-1-C(CH5)z-1-0
A divalent group such as -1-C-1-S-1-802-, R is
Aromatic polyesters with H1-CH3, -C2H5, (representing collars, etc.) are polymers with excellent transparency, heat resistance, mechanical properties, etc. Especially when X is -C(CH3)2-
The type in which 1 and R are all hydrogen is industrially produced and widely used. Many studies have been conducted to take advantage of these properties and blend them with various other polymers. However, when blended with other polymers, the mechanical strength usually decreases due to insufficient compatibility.
Transparent resin cannot be obtained. Furthermore, even when there is no decrease in mechanical strength, it is rare that a transparent resin can be obtained.
本出願人は、先に特願昭６１−１５７９８１号において
、前記一般式（１）で異わされる芳香族ポリエステルと
ＡＳ１１脂をブレンドすることによって上記の問題を解
決し、透明で充分な機械的強度を有する組成物が得られ
ることを開示した。しかしながら、この組成物は特に芳
香族ポリエステルの組成が低い場合、充分な耐熱性を有
しているとはいえず、用途（例えば書換え形の光デイス
ク基板等）によっては使用が制限される場合があった。The present applicant previously solved the above problem in Japanese Patent Application No. 157981/1981 by blending the aromatic polyester represented by the general formula (1) with AS11 resin, and obtained a transparent and sufficient machine. It has been disclosed that a composition having a high physical strength can be obtained. However, this composition cannot be said to have sufficient heat resistance, especially when the composition of aromatic polyester is low, and its use may be limited depending on the application (for example, rewritable optical disk substrates, etc.). there were.
（発明が解決しようとする問題点）
本発明の目的は、特願昭６１−１５７９８１号における
、芳香族ポリエステルとＡＢｉｆＲ脂をブレンドした組
成物の特徴である透明性を生かし、かつ充分な耐熱性を
付与することにより、檀々の光学材料等に有用な組成物
を得ることである。(Problems to be Solved by the Invention) The object of the present invention is to take advantage of the transparency characteristic of the composition of blended aromatic polyester and ABifR resin as disclosed in Japanese Patent Application No. 157981/1981, and to have sufficient heat resistance. The purpose is to obtain a composition useful for various optical materials and the like.
（問題点を解決するための手段）
本発明者等は、上記問題点を解決すべく鋭意検討した結
果、前記一般式（りで表わされる芳香族ポリエステルは
、α−メチルスチレン及びアクリロニトリルを共重合成
分として含むスチレン系重合体と透明にブレンドするこ
とが可能であり、かつこのブレンドポリマーが優れた耐
熱性を有することを見出し本発明に至った。(Means for Solving the Problems) As a result of intensive studies to solve the above problems, the present inventors found that the aromatic polyester represented by the general formula The inventors have discovered that it is possible to transparently blend the blended polymer with the styrenic polymer contained as a component, and that this blended polymer has excellent heat resistance, leading to the present invention.
即ち、本発明は、一般式（１）
（ただし、ｎは重合度を表わす）
で巽わされる芳香族ポリエステルと、α−メチルスチレ
ン及びアクリロニトリルを共１合成分として含むスチレ
ン系重合体をブレンドして得られる耐熱性樹脂組成物で
ある。That is, the present invention blends an aromatic polyester represented by the general formula (1) (where n represents the degree of polymerization) and a styrenic polymer containing both α-methylstyrene and acrylonitrile as one component. This is a heat-resistant resin composition obtained by
本発明において、α−メチルスチレンとアクリロニトリ
ルを含むスチレン系重合体と芳香族ポリエステルを透明
にブレンドするためには、芳香族ポリエステルが一般式
（１）の構造であることが必須要件である。例えば、一
般式（１）のベンゼン核に置換したメチル基が水素とな
った場合、あるいは、−８０２−基を−ＣＨ２−基や一
〇（ＣＨ３）２−基に変えた場合には、本発明の如き、
充分な透明性を得ることはできない。In the present invention, in order to transparently blend a styrenic polymer containing α-methylstyrene and acrylonitrile with an aromatic polyester, it is essential that the aromatic polyester has the structure of general formula (1). For example, when the methyl group substituted on the benzene nucleus in general formula (1) becomes hydrogen, or when the -802- group is changed to -CH2- group or 10(CH3)2- group, the Like an invention,
It is not possible to obtain sufficient transparency.
本発明において芳香族ポリエステル含量は１〜９９ｍ１
１：％であるが、特願昭６１−１５７９８１号の組成物
に対する耐熱性の改善効果という点では、特に５０重量
％以下の場合が有利である。In the present invention, the aromatic polyester content is 1 to 99ml
1:%, but from the viewpoint of improving the heat resistance of the composition of Japanese Patent Application No. 61-157981, a content of 50% by weight or less is particularly advantageous.
一般式（１）の芳香族ポリエステルは、ビス−（３゜５
−ジメチル４−ヒドロキシフェニル）スルホンをジオー
ル成分とし、イソフタル酸、テレフタル酸及びそれらの
機能誘導体（テレフタル酸クロリド等）をジカルざン駿
成分とし、公知の重縮合法により得ることができる。ジ
カルボン酸成分としては、テレフタル酸とイソフタル酸
またはその機能誘導体を組合わせて用いることが物性上
好ましい。重合方法は、界面１縮合法、浴液重合法、治
融１合法等、通常芳香族ポリエステルｔ−Ｘ合する方法
から選ぶことができる。The aromatic polyester of general formula (1) is bis-(3゜5
-dimethyl 4-hydroxyphenyl) sulfone as the diol component, isophthalic acid, terephthalic acid, and their functional derivatives (terephthalic acid chloride, etc.) as the dicarzantine component, and can be obtained by a known polycondensation method. As the dicarboxylic acid component, it is preferable to use a combination of terephthalic acid and isophthalic acid or a functional derivative thereof in terms of physical properties. The polymerization method can be selected from methods such as an interfacial condensation method, a bath liquid polymerization method, and a melting method, which usually involve t-X polymerization of aromatic polyesters.
本発明に用いるα−メチルスチレン及びアクリロニトリ
ルを共重合成分として含むスチレン系共重合体において
、アクリロニトリル組成は、１５Ｘｔ＊以上であること
が好ましい。また、アクリロニトリルに対するα−メチ
ルスチレンの量は、重量比で１．５以上であることが好
ましく、かつスチレンに対するα−メチルスチレンの量
は重量比で１．８以上であることが好ましい。また、ス
チレン系重合体は、通常α−メチルスチレン／アクリロ
ニトリル２元共重合体、または、α−メチルスチレン／
スチレン／アクリ四ニトリル６元共重合体が用いられる
が、ポリマーの物性改善等を目的として、その他の成分
、例えばメチルメタクリレートやメタクリロニトリル等
♂少量加えることも可能である。重合は、塊状重合法、
乳化１合法、懸濁重合法等、公知の方法で行なわれる。In the styrenic copolymer containing α-methylstyrene and acrylonitrile as copolymerization components used in the present invention, the acrylonitrile composition is preferably 15Xt* or more. Further, the amount of α-methylstyrene to acrylonitrile is preferably 1.5 or more by weight, and the amount of α-methylstyrene to styrene is preferably 1.8 or more by weight. The styrenic polymer is usually α-methylstyrene/acrylonitrile binary copolymer or α-methylstyrene/acrylonitrile binary copolymer.
Although a styrene/acrytetranitrile 6-element copolymer is used, small amounts of other components such as methyl methacrylate and methacrylonitrile may also be added for the purpose of improving the physical properties of the polymer. Polymerization is carried out by bulk polymerization method,
This can be carried out by a known method such as an emulsification method or a suspension polymerization method.
この際目的に応じて適尚な分子量が選ばれる。At this time, an appropriate molecular weight is selected depending on the purpose.
芳香族ポリエステルとスチレン系１合体との混合は、両
者を共通に溶解する溶媒、例えは塩化メチレン等で浴液
ブレンドする方法を用いることができる。押出機やロー
ルなどで溶融混合する場合には、ポリマーの熱分解を抑
える条件を設定する必要がある。The aromatic polyester and the styrene-based monomer can be mixed using a bath liquid blending method using a solvent that commonly dissolves both, such as methylene chloride. When melt-mixing is performed using an extruder or roll, it is necessary to set conditions that suppress thermal decomposition of the polymer.
本発明の組成物には、酸化防止剤、耐光安定剤、難燃剤
等の添加剤を加え、更に特性を向上させることも可能で
ある。It is also possible to add additives such as antioxidants, light stabilizers, and flame retardants to the composition of the present invention to further improve its properties.
また、本発明の組成物と相浴性の高いポリマーをさらに
ブレンドして用いることも可能である。It is also possible to further blend the composition of the present invention with a polymer having high compatibility with the composition.
例えば、本発明の組成物とＡｓ樹脂の組合わせによって
透明な組成物を得ることができる。For example, a transparent composition can be obtained by combining the composition of the present invention and an As resin.
（発明の効果）
本発明により、透明なブレンドポリマーが得られること
のメリットは、例えば光学用途に用いた場合、複屈折を
低減できるという点である。芳香族ポリエステルにスチ
レン系樹脂をブレンドした場合、あるいは、スチレン系
樹脂に芳香族ポリエステルをブレンドした場合、いずれ
も単品のポリマーよりも低複屈折とすることができる。(Effects of the Invention) The advantage of obtaining a transparent blend polymer according to the present invention is that, for example, when used for optical purposes, birefringence can be reduced. When a styrene resin is blended with an aromatic polyester, or when an aromatic polyester is blended with a styrene resin, the birefringence can be lowered than that of a single polymer.
本発明の組成物と、特顔昭６１−１５７９８１号の組成
物のＴｇあるいは熱変形温度を同一芳香族ポリエステル
含量で比較すると、明らかに前者の方が高く、特に芳香
族ポリエステルの含量が５０Ｗ１ ％以下の場合、その
差は大きい。光学材料として本発明の組成物を使用する
場合、芳香族ポリエステル含量を５ＱＷｔ、％以下にす
ることはコストを下げ、また複屈折を小さくするという
点で好ましく、従ってこの範囲で特に高い耐熱性を有す
ることは本発明の大きなメリットと言える。Comparing the Tg or heat distortion temperature of the composition of the present invention and the composition of Tokugan Sho 61-157981 with the same aromatic polyester content, the former is clearly higher, especially when the aromatic polyester content is 50W1%. The difference is large in the following cases. When using the composition of the present invention as an optical material, it is preferable to reduce the aromatic polyester content to 5QWt.% or less in terms of lowering costs and reducing birefringence, and therefore particularly high heat resistance is achieved within this range. This can be said to be a great advantage of the present invention.
また、本発明の組成物は、光学用途に用いることができ
るだけでなく、その耐熱性等を生かし、光学用途以外の
分野でエンジニアリングプラスチックとして使用するこ
とも可能である。Furthermore, the composition of the present invention can not only be used for optical purposes, but also take advantage of its heat resistance and other properties to be used as an engineering plastic in fields other than optical purposes.
（実施例）
以下、実施例によりさらに詳細に説明するが、本発明の
内容は実施例のみに限定されるものではない。(Examples) Hereinafter, the present invention will be explained in more detail with reference to Examples, but the content of the present invention is not limited only to the Examples.
実施例１
芳香族ポリエステルの製造
５１の四つロフラスコ内で、Ｎ２気流下、ヒス−（４−
ヒドロ中シー３，５ゾメチルフェニル）スルホン１５５
ｇ、９５％の水酸化ナトリウム４８．３ ｇ、チオ硫酸
ソーダ６．６ｙを１６５０！Ｉｌｌの水に均一に溶解し
た後、氷冷する。一方、テレフタル酸クロリドとイソフ
タル酸りロリド各４４．７９とトリオクチルメチルアン
モニウムクロライド３．６ｇを６００１１８の塩化メチ
レンに溶解させ、上記水浴液にすみやかに添加する。水
浴中、激しく攪拌しながら２時間反応させた後、酢酸１
７６尼を添加してさらに１５分間攪拌を続ける。塩化メ
チレン層を数回水洗後、過剰のアセトン中に注ぎポリマ
ーを析出させる。得られたポリマーの１景平均分子量を
ＧＰＣで測定したところ、ポリスチレン換算でｓｉ ｏ
ｏｏであった。Example 1 Production of aromatic polyester His-(4-
3,5-zomethylphenyl) sulfone 155
g, 95% sodium hydroxide 48.3 g, sodium thiosulfate 6.6y 1650! After uniformly dissolving in 100 ml of water, cool on ice. On the other hand, 44.79 g each of terephthalic acid chloride, isophthalic acid chloride, and 3.6 g of trioctylmethylammonium chloride are dissolved in 600118 methylene chloride, and promptly added to the above water bath liquid. After reacting for 2 hours with vigorous stirring in a water bath, acetic acid 1
Add 76 ml and continue stirring for an additional 15 minutes. After washing the methylene chloride layer several times with water, it is poured into excess acetone to precipitate the polymer. When the single view average molecular weight of the obtained polymer was measured by GPC, it was found that sio
It was oo.
組成物の製造及び試験
前記で得られた芳香族ポリエステル肌８ｆＩと一般に知
られた乳化１合法で得られたスチレン系樹脂（ＡＮ／α
−メチルスチレン／スチレン＝２０／６５／１５；ｉ量
比） ０．２ ｇとを１Ｑｍｌの塩化メチレンに均一に
俗解させた後、内径９０間の平底シャーレ上に流延し自
然乾燥させて厚さ１２０μｍの透明なフィルムを得た。Manufacture and testing of composition The aromatic polyester skin 8fI obtained above and the styrene resin (AN/α
- Methylstyrene/styrene = 20/65/15; i amount ratio) 0.2 g was uniformly dissolved in 1Qml of methylene chloride, and then cast onto a flat-bottomed petri dish with an inner diameter of 90 mm and air-dried to give a thick A transparent film with a diameter of 120 μm was obtained.
このフィルムの熱変形温度を、ＲＨＥＯＶＩＢＲＯＮ
−ＤＤＶ −ＩＩ −Ｅ Ａ （東洋ボールドウィン製
）を用い、動的粘弾性が急激に低下し始める温度として
測定した。結果を第１衣に示す。The heat distortion temperature of this film is RHEOVIBRON
-DDV-II-E A (manufactured by Toyo Baldwin), and was measured as the temperature at which the dynamic viscoelasticity began to decrease rapidly. The results are shown in Figure 1.
実施例２〜５
芳香族ポリエステルとスチレン系樹脂の配合割合（重量
比）を６０／４０（実施例２）、４０／６０（実施例３
）、２０／８０ （実施例４）、５／９５（実施例５）
に変化させる以外はすべて実施例１と同様にしてフィル
ムを製造した。得られたフィルムはいずれも透明であっ
た。これらのフィルムの熱変形温度を実施例１と同様の
方法で測定した結果を第１我に示す。Examples 2 to 5 The blending ratio (weight ratio) of aromatic polyester and styrene resin was 60/40 (Example 2) and 40/60 (Example 3).
), 20/80 (Example 4), 5/95 (Example 5)
A film was produced in the same manner as in Example 1 except that the film was changed to . All of the obtained films were transparent. The heat distortion temperatures of these films were measured in the same manner as in Example 1, and the results are shown in Part 1.
比較例１〜４
実施例１で用いたスチレン系樹脂のかわりにＡ８樹脂（
ポリマー中のアクリロニトリル組成が２９Ｗｚ％）を用
いる以外は、実施例１と同様の方法でフィルムを作製し
た。同様に芳香族ポリエステルとＡＳ樹脂の配合割合を
重量比で６０／４０（比較例２）、４０／６Ｇ（比較例
３）、２０７８０（比較例４）と変化させてフィルムを
作製した。Comparative Examples 1 to 4 A8 resin (
A film was produced in the same manner as in Example 1, except that the acrylonitrile composition in the polymer was 29 Wz%. Similarly, films were produced by changing the weight ratio of aromatic polyester and AS resin to 60/40 (Comparative Example 2), 40/6G (Comparative Example 3), and 20780 (Comparative Example 4).
得られたフィルムの熱変形温度を実施例１と同様の方法
で測定した結果を第１表に示す。The heat distortion temperature of the obtained film was measured in the same manner as in Example 1, and the results are shown in Table 1.
ｔｌＸｘ表
実施例６
スチレン系樹脂として、ムＮ／α−メチルスチレン＝２
５／７Ｂ（重量比）を用い、芳香族ポリエステルとスチ
レン系樹脂の配合割合を重量比で２０／８０とする他は
、実施例１と同様な方法でフィルムを作製した。得られ
たフィルムは透明であった。tlXx Table Example 6 As styrene resin, MuN/α-methylstyrene = 2
A film was produced in the same manner as in Example 1, except that 5/7B (weight ratio) was used and the blending ratio of aromatic polyester and styrene resin was 20/80 in weight ratio. The resulting film was transparent.
このフィルムの熱変形温度を実施例１と同様に測定した
結果、１３１℃であった。The heat distortion temperature of this film was measured in the same manner as in Example 1 and was found to be 131°C.
実施例７
スチレン系樹脂として、ＡＮ／α−メチルスチレン／ス
チレン＝３５／２０／４５重量比）１−用い、芳香族ポ
リエステルとスチレン系樹脂の配合割合ｆ、ｉ量比で４
０７６０とする以外は、実施例１と同様な方法でフィル
ムを作製した。Example 7 As the styrene resin, AN/α-methylstyrene/styrene = 35/20/45 weight ratio) was used, and the blending ratio of aromatic polyester and styrene resin was f and the amount ratio of i was 4.
A film was produced in the same manner as in Example 1 except that 0760 was used.
得られたフィルムの熱変形温度を実施例１と同様に測定
した結果、１２９°Ｃであった。The heat distortion temperature of the obtained film was measured in the same manner as in Example 1 and was found to be 129°C.
Claims (3)
ン及びアクリロニトリルを共重合成分として含むスチレ
ン系重合体をブレンドして得られる耐熱性樹脂組成物(1) General formula (1) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (where n represents the degree of polymerization) A styrenic system containing an aromatic polyester represented by, α-methylstyrene and acrylonitrile as copolymerization components Heat-resistant resin composition obtained by blending polymers
１５重量％以上であり、かつアクリロニトリルに対する
α−メチルスチレンの量が重量比で１．５以上であり、
かつスチレンに対するα−メチルスチレンの量が重量比
で１．８以上であるスチレン系共重合体を用いることを
特徴とする特許請求の範囲第１項記載の耐熱性樹脂組成
物(2) the acrylonitrile composition in the styrenic copolymer is 15% by weight or more, and the weight ratio of α-methylstyrene to acrylonitrile is 1.5 or more;
The heat-resistant resin composition according to claim 1, characterized in that a styrenic copolymer is used in which the weight ratio of α-methylstyrene to styrene is 1.8 or more.
以下である特許請求の範囲第１項記載の耐熱性樹脂組成
物(3) 50% by weight of aromatic polyester of general formula (1)
The heat-resistant resin composition according to claim 1, which is the following:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61243169A JPH0739521B2 (en) | 1986-10-15 | 1986-10-15 | Heat resistant resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61243169A JPH0739521B2 (en) | 1986-10-15 | 1986-10-15 | Heat resistant resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6397650A true JPS6397650A (en) | 1988-04-28 |
| JPH0739521B2 JPH0739521B2 (en) | 1995-05-01 |
Family
ID=17099838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61243169A Expired - Fee Related JPH0739521B2 (en) | 1986-10-15 | 1986-10-15 | Heat resistant resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0739521B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5677718A (en) * | 1992-06-04 | 1997-10-14 | Tektronix, Inc. | Drop-on-demand ink jet print head having improved purging performance |
-
1986
- 1986-10-15 JP JP61243169A patent/JPH0739521B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5677718A (en) * | 1992-06-04 | 1997-10-14 | Tektronix, Inc. | Drop-on-demand ink jet print head having improved purging performance |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0739521B2 (en) | 1995-05-01 |
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