JPS6386825A - Gas blow pipe - Google Patents

Gas blow pipe

Info

Publication number
JPS6386825A
JPS6386825A JP23004486A JP23004486A JPS6386825A JP S6386825 A JPS6386825 A JP S6386825A JP 23004486 A JP23004486 A JP 23004486A JP 23004486 A JP23004486 A JP 23004486A JP S6386825 A JPS6386825 A JP S6386825A
Authority
JP
Japan
Prior art keywords
weight
pipe
gas blowing
ports
sialon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23004486A
Other languages
Japanese (ja)
Other versions
JP2583492B2 (en
Inventor
Seishi Furushima
清史 古島
Toshio Okitsu
沖津 俊夫
Kazuyoshi Harafuji
原藤 和敬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Proterial Ltd
Original Assignee
Hitachi Metals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Metals Ltd filed Critical Hitachi Metals Ltd
Priority to JP61230044A priority Critical patent/JP2583492B2/en
Publication of JPS6386825A publication Critical patent/JPS6386825A/en
Application granted granted Critical
Publication of JP2583492B2 publication Critical patent/JP2583492B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Treatment Of Steel In Its Molten State (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

PURPOSE:To form fine bubbles and to improve degassing efficiency by mounting porous packing materials into the blow-off ports of a gas blow pipe and constituting respective parts of Si3N4 ceramics or sialor specified in bending strength, density and thermal impact temp. CONSTITUTION:The blow-off ports 5 are screwed to the other end of a distribution rod 4 of the gas blow pipe 1 and porous refractories as the packing materials 6 are mounted into the space parts at the ends of the ports 5. The blown gas passes the microgaps of the materials 6 in the ports 5 and disintegrates the bubbles formed in a molten metal to the finer bubbles. The degassing efficiency is thus improved. The Si3N4 ceramics or sialor is used as the material for the respective parts to constitute said pipe 1. The material the bending strength of which is >=50kg/mm<2>, the density is >=95% of theoretical density, and the thermal impact temp. by an underwater charging method is DELTAT=>=400 deg.C is used as said material. The reduction in the size and weight of the pipe 1 and the extension of the life thereof are thereby attained.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、IF ’Q ’2t 、’;4冶解炉に用い
られる脱ガスのためのガス吹込管に関づるものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a gas blowing pipe for degassing used in an IF 'Q '2t,';4 smelting furnace.

従来の技術 非鉄金属溶解炉にJ3いて、ガス吹込゛ごによりノ\r
ガスを?8(間中に吹込んでR、a a’ Iiて11
)1ガスが行なわれている。
Conventional technologyIn a non-ferrous metal melting furnace, the
Gas? 8 (Blow in the middle R, a a' Ii te 11
) 1 gas is being conducted.

このガス吹込管は鉄又(よ5J!I jJ単独、あるい
はこれらを芯金としてその外jミ面に耐火!才を;′1
.・′5したものが用いら(tでいる。そして、これら
のガス吹造管は1本のパイプででさたものやその先端部
が複数本に枝分れしたちの専がある。
This gas blowing pipe is made of iron or iron (5J!
..・'5' is used (t.

発明が解決しようとする問題点 しかしながら、上述のJ、うな3大又は鋳鉄製ガス吹込
管は、溶湯により侵蝕され、溶、ε中への鉄等の溶出が
あり、これが製品中へ不純物として氾入し、材7゛iに
悪影響を及ばづ。ガス吹込管の表面に、溶湯による侵蝕
を防ぐために、耐火材を’g:rHL’たものも用いら
れているが、使用により剥離したりするので手直しする
必要があり、メインテブンスの工数が必要である。また
、波音により容積と1呈が必要以上に大きくな−)で取
扱いに不便がある。
Problems to be Solved by the Invention However, the above-mentioned J, Eel, or cast iron gas blowing pipes are eroded by molten metal, and iron and other substances are leached into the molten metal, which floods into the product as impurities. This will have a negative impact on the material 7゛i. A refractory material 'g:rHL' is also used on the surface of the gas injection pipe to prevent corrosion by molten metal, but it peels off with use, so it needs to be reworked and maintenance work is required. be. In addition, the volume and size of the product are unnecessarily large due to the sound of the waves, which is inconvenient to handle.

本発明は上述のような実状に対応づるため検討を重ねて
創作されたもので、その目的とJるところは、吹込まれ
たArガスが吹込管の先端で微細な泡が発泡するように
しで1lt2ガスの効率を向上させ、さらに、ガス吹込
管を構成する各部品の材質を3 i 3 Nu系セラミ
ック又は1ナイアロンにすることにより、溶湯にス4す
る耐食性および強度を持たせ、高密度化により表面をな
めらかにして溶湯の付着を防止し、なj3かつ、被覆耐
火材などの手入れ工数をなくすると共に小型軽量化によ
り取扱いやすくしたガス吹込v・:を(是(共すること
である。
The present invention was created after repeated studies in order to cope with the above-mentioned actual situation, and its purpose is to make the Ar gas blown into it form fine bubbles at the tip of the blowing pipe. By improving the efficiency of 1lt2 gas, and by using 3i3Nu ceramic or 1Nylon as the material for each part that makes up the gas blowing pipe, we are able to give the molten metal superior corrosion resistance and strength, and achieve higher density. The gas injection system smoothes the surface and prevents the adhesion of molten metal, eliminates the need for maintenance of coated refractory materials, and is easier to handle due to its smaller size and lighter weight.

問題点を解決するための手段 上記問題点を解決するために本発明は、非鉄a属溶解炉
用ガス吹込含においC,先32H部にポーラスな耐火材
を装着した吹出口を有し、該吹出口tこ吹込棒を連通し
て設けたガス吹込管ぐある。
Means for Solving the Problems In order to solve the above-mentioned problems, the present invention provides a gas blowing outlet for a non-ferrous Class A melting furnace. There is a gas blowing pipe connected to the blowing outlet and the blowing rod.

さらに、ガス吹込管を(構成する各部品の材質としてS
i3N4系セラミック又はサイアロンを用い、Si3N
4系セラミック又はサイアロンは、曲げ強度が50 k
M mm2以上で、密1良が理論密[ケの90%以上で
、水中投下法による熱’1!I Z’J i易摩がΔT
=400℃以上をイコするものであるっそして、前記S
i3N4系レラミツク又【よ4jイアロンはα相を65
千昂%以上含むSi3N470重a%以上と、周期律表
ma族元素の酸化物のなかの1種以上20重量%以下と
、7へ120320弔1%以下と、AIN固溶体(Al
N−Si3N4 ・Al2O3系)もしくはへ1N15
重量%以下とからなる混合物を焼結したものである。
Furthermore, the gas blowing pipe (the material of each component is S)
Using i3N4 ceramic or sialon, Si3N
4 series ceramic or Sialon has a bending strength of 50 k
M mm2 or more, density 1 good is theoretical density [ke] 90% or more, heat '1 by underwater drop method! I Z'J i Ima ga ΔT
= 400℃ or more.And the above S
i3N4 series Relamitsumata [yo4j Iaron has α phase of 65
Si3N containing 1,000% or more, 470% by weight or more, at least 20% by weight of one or more of the oxides of group MA elements of the periodic table, 1% or less of 7 to 120320, and an AIN solid solution (Al
N-Si3N4 ・Al2O3 system) or 1N15
% by weight or less.

また、Si3N4系セラミック又はサイアロンはα損金
65・■吊%以上含むSi3N470千量c)6以上と
、周期律表ma族元素の酸化物のなかの1秤取上20重
a%以下と、A I20320fflfm%以下とから
なる混合物を焼結したものでもよい。
In addition, Si3N4 ceramics or sialon contain more than 470,000% of Si3N, including more than 65% of α loss, and less than 20% by weight of the oxides of group Ma elements of the periodic table, and A It may also be a mixture obtained by sintering a mixture consisting of I20320fflfm% or less.

作  用 吹Δ棒より索込んだArガスは、吹出口の先端部にポー
ラス耐火材が装るされているので、耐火材の微小な空隙
間を通って溶湯中に発泡し、泡をta″a化することが
できる。
Function: Since the tip of the blowing port is covered with porous refractory material, the Ar gas introduced from the blowing Δ rod passes through the minute gaps in the refractory material and foams in the molten metal, causing the bubbles to ta''. It can be made into a.

さらに、ガス吹込管を構成する各部品の材質を上述のよ
うなSi3N=$系セラミック又はサイアロンにするこ
とにより、溶:εに対する耐食性および高強度を右する
ので、非鉄金属溶湯に)C蝕されることなり、衝撃荷重
を受けても割れることがない。また、高密度化により表
面がなめらかにtZっているので、溶湯のfJ 6を防
+Hることかできる。
Furthermore, by making the material of each part constituting the gas blowing pipe Si3N = $ system ceramic or sialon as mentioned above, corrosion resistance against ε and high strength are achieved, so that non-ferrous metal molten metal is not corroded by C. This means that it will not crack even if subjected to impact loads. Furthermore, since the surface is smooth due to high density, fJ 6 of the molten metal can be prevented.

実11パ瞼(ル1 以下、本発明の実施例を図面に基づいて説明jる。Fruit 11 eyelids (le 1 Embodiments of the present invention will be described below based on the drawings.

第1図(a)は本発明の実施例に係るガス吹込管の正面
図、(b)は下面図、第2図t、L第1図の縦断面図で
ある。
FIG. 1(a) is a front view of a gas blowing pipe according to an embodiment of the present invention, FIG. 1(b) is a bottom view, and FIG. 2(t) is a vertical sectional view of FIG. 1.

第1図(a)および(b)、第2図に示すJ、うに、ガ
ス吹込・答1は吹込(全2.継手31分配捧4.吹出口
5より構成されている。継手3にはねじ孔7゜8が連通
して設けられてI3す、されぞれ分配外4と吹込捧2を
螺嵌する。
J shown in Figures 1 (a) and (b) and Figure 2. Gas blowing/response 1 is composed of 2 joints 31 distribution shafts 4 and air outlet 5. Joint 3 has Threaded holes 7.8 are provided in communication with each other to screw the distribution hole 4 and the blowing rod 2, respectively.

分配外4の他端には中空パイプ状の吹出口5を螺嵌し、
吹出口5の先ti;空間部に充1.Q +46としてポ
ーラス耐火(イを装るケる。
A hollow pipe-shaped outlet 5 is screwed into the other end of the distribution outer 4,
The tip of the air outlet 5; the space is filled with 1. Q +46 as porous fireproof (pretend to be a).

吹込棒2よりArガスを吹込むと、’n% f 3 、
分配li4を通って吹出D 5よりA、rガスは4方向
に分れて流出し、吹出口5には充填材6としてポーラス
耐火材が装着されているので、微小な空隙131を通っ
て溶湯中に発泡した泡は徽;’:l (ヒされ、脱カス
の効率が向上する。
When Ar gas is blown from the blowing rod 2, 'n% f3,
The A and R gases flow out in four directions from the outlet D5 through the distribution li4, and since the outlet 5 is equipped with a porous refractory material as the filler 6, the molten metal passes through the minute gap 131. The foam that foams inside is heated, which improves the efficiency of removing scum.

ガス吹込管1を(j4成J−る各部品のF ?3として
、Si3N4系セラミック又はサイアロンを用い、その
曲げ強度は60kg/mm2、密度は理−≧密度の96
%、水中投下法による熱衝撃湿度は八T=500℃であ
る。また、Si3N4系セラミック又はサイアロンはα
相を65重5%以上3むSi3N470重ε%以上と、
周!’IJ律表[[a族元素の酸化物のなかの1秤取上
20重昂%以下と、Al203201量%以下ト、AI
N固溶体(AlN−8i3N4 ・Al2O3系)もし
くはAI  ’N15重口%以下とからなる混合物を焼
結したものである。
The gas blowing pipe 1 is made of Si3N4 ceramic or sialon, and its bending strength is 60 kg/mm2, and the density is 96
%, and the thermal shock humidity by the underwater drop method is 8T=500°C. In addition, Si3N4 ceramic or sialon is α
The phase is 65% by weight or more and 3% or more by Si3N470% by weight or more,
Zhou! 'IJ table [[1% by weight of oxides of group A elements, not more than 20% by weight, Al203201% by weight or less, AI
It is obtained by sintering a N solid solution (AlN-8i3N4 .Al2O3 system) or a mixture consisting of 15% by weight or less of AI'N.

上記材質のガス吹込管1をアルミニウム溶解炉に用いた
結果、微細な泡が得られ、脱ガスの効率が向上し、さら
に、溶湯による侵蝕は殆んど見られず、使用中の衝撃荷
担や熱衝撃にも充分耐えた。
As a result of using the gas blowing pipe 1 made of the above material in an aluminum melting furnace, fine bubbles are obtained and degassing efficiency is improved.Furthermore, there is almost no corrosion due to molten metal, and there is no impact load during use. It also withstood thermal shock well.

また、取り扱いが容易であると共に寿命も従来の鋳鉄製
ガス吹込管に比べ大幅に延び、手入れなしで1年以上の
長寿命となり、使用中の事故がない限り、はぼ半永久的
に使用できることがわかった。
In addition, it is easy to handle and has a significantly longer lifespan than conventional cast iron gas blowing pipes, with a lifespan of more than one year without maintenance, meaning that it can be used almost permanently as long as there are no accidents during use. Understood.

ガス吹込管1を構成する各部品の材質は本実旌例のみに
限定されるものではない。他のSi3N4系セラミック
又はサイアロン、例えばα相を65重斤%以上含むSi
3N470Φ量%以上ど、周期律表1ea族元素の酸化
物のなかの1腫以上20重R%以下と、Al20320
単但%以下とからなる混合物を焼結したものでもよい。
The materials of each component constituting the gas blowing pipe 1 are not limited to those in this practical example. Other Si3N4 ceramics or sialon, such as Si containing 65% or more of α phase
3N470Φ amount% or more, 1% or more and 20% or less of oxides of group 1ea elements of the periodic table, and Al20320
It is also possible to sinter a mixture consisting of 1% or less.

発明の詳細 な説明したように、本発明によれば、吹込棒より吹込ん
だArガスは溶湯中に微細化しで発泡するので、脱ガス
の効率が向上する。さらに本発明は非鉄金属溶解炉用ガ
ス吹込管を構成り“る各部品の材質を高強度を有するS
i3N4系セラミック又はサイアロンにすることにより
、R命を大幅に向上し得るのみならず、小型軽量のため
取り扱いが容易であると共に使用中の手入れの必B1を
なくし、また、製品への不粍物の混入を避けろことによ
り悪影響を排除し、−4品を安定かつ良好に製造し得る
などの効果を右するものであって、工業的にその価値は
高い。
As described in detail, according to the present invention, the Ar gas blown into the molten metal from the blowing rod becomes fine and foams, so that the efficiency of degassing is improved. Furthermore, the present invention uses high-strength steel as the material of each part constituting the gas blowing pipe for a non-ferrous metal melting furnace.
By using i3N4 ceramic or sialon, not only can the R life be greatly improved, but it is also small and lightweight, making it easy to handle, eliminating the need for maintenance during use, and reducing the risk of impurities in the product. By avoiding the contamination of other substances, the negative effects can be eliminated and -4 products can be produced stably and in good condition.This has high industrial value.

【図面の簡単な説明】 第1図(a)は本発明の実施例に係るガス吹込むの正面
図、(b)は下面図、第2図は′fS1図の縦断面図で
ある。 1・・・ガス吹込管、2・・・吹込棒、5・・・吹出口
、6・・・充填材
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1(a) is a front view of a gas injector according to an embodiment of the present invention, FIG. 1(b) is a bottom view, and FIG. 2 is a longitudinal sectional view of FIG. 'fS1. 1...Gas blowing pipe, 2...Blowing rod, 5...Blowout port, 6...Filling material

Claims (3)

【特許請求の範囲】[Claims] (1)非鉄金属溶解用ガス吹込管において、先端部にポ
ーラスな充填材を装着した吹出口を有し、各部を構成す
る部品がSi_3N_4系セラミック又はサイアロンに
てなり、前記Si_3N_4系セラミック又はサイアロ
ンは、曲げ強度が50kg/mm^2以上で、密度が理
論密度の90%以上で、水中投下法による熱衝撃温度が
ΔT=400℃以上であることを特徴とするガス吹込管
(1) A gas blowing pipe for melting non-ferrous metals, which has a blowing outlet equipped with a porous filler at the tip, and the parts constituting each part are made of Si_3N_4 ceramic or Sialon, and the Si_3N_4 ceramic or Sialon is A gas blowing tube having a bending strength of 50 kg/mm^2 or more, a density of 90% or more of the theoretical density, and a thermal shock temperature measured by an underwater dropping method of ΔT=400° C. or more.
(2)前記Si_3N_4系セラミック又はサイアロン
はα相を65重量%以上含むSi_3N_470重量%
以上と、周期律表IIIa族元素の酸化物のなかの1種以
上20重量%以下と、 Al_2O_320重量%以下と、AlN固溶体(Al
N−Si_3N_4・Al_2O_3系)もしくはAl
N15重量%以下とからなる混合物を焼結したものであ
ることを特徴とする特許請求の範囲第1項記載のガス吹
込管。
(2) The Si_3N_4 ceramic or sialon is Si_3N_470% by weight containing 65% by weight or more of α phase.
The above, at least 20% by weight of one or more of the oxides of Group IIIa elements of the periodic table, up to 20% by weight of Al_2O_3, and an AlN solid solution (Al
N-Si_3N_4・Al_2O_3 system) or Al
2. The gas blowing tube according to claim 1, wherein the gas blowing tube is made by sintering a mixture consisting of 15% by weight or less of N.
(3)前記Si_3N_4系セラミック又はサイアロン
はα相を65重量%以上含むSi_3N_470重量%
以上と、周期律表IIIa族元素の酸化物のなかの1種以
上20重量%以下と、 Al_2O_320重量%以下とからなる混合物を焼結
したものであることを特徴とする特許請求の範囲第1項
記載のガス吹込管。
(3) The Si_3N_4 ceramic or sialon contains 65% by weight or more of α phase and 70% by weight of Si_3N_4
Claim 1, characterized in that it is a sintered mixture consisting of the above, at least 20% by weight of one or more of the oxides of group IIIa elements of the periodic table, and not more than 20% by weight of Al_2O_3. Gas blowing pipe as described in section.
JP61230044A 1986-09-30 1986-09-30 Gas injection tube for molten aluminum Expired - Lifetime JP2583492B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61230044A JP2583492B2 (en) 1986-09-30 1986-09-30 Gas injection tube for molten aluminum

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61230044A JP2583492B2 (en) 1986-09-30 1986-09-30 Gas injection tube for molten aluminum

Publications (2)

Publication Number Publication Date
JPS6386825A true JPS6386825A (en) 1988-04-18
JP2583492B2 JP2583492B2 (en) 1997-02-19

Family

ID=16901681

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61230044A Expired - Lifetime JP2583492B2 (en) 1986-09-30 1986-09-30 Gas injection tube for molten aluminum

Country Status (1)

Country Link
JP (1) JP2583492B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0549148U (en) * 1991-12-16 1993-06-29 日本重化学工業株式会社 Gas injector for molten metal degassing equipment
JP2008200739A (en) * 2007-02-22 2008-09-04 Japan Metals & Chem Co Ltd Rotary member for molten metal degassing apparatus, and molten metal degassing apparatus comprising the same
WO2010143536A1 (en) * 2009-06-08 2010-12-16 三井金属鉱業株式会社 Lance pipe
CN109182655A (en) * 2018-10-23 2019-01-11 王子晨 A kind of Air blowing stick for the low blow of liquid
CN109182654A (en) * 2018-10-22 2019-01-11 王子晨 A kind of self-action Air blowing stick for liquid bottom blow

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS581025A (en) * 1981-05-27 1983-01-06 Sumitomo Light Metal Ind Ltd Treating device of molten metal
JPS58163555U (en) * 1982-04-27 1983-10-31 住友金属鉱山株式会社 Chlorine gas blowing pipe for molten metal refining

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS581025A (en) * 1981-05-27 1983-01-06 Sumitomo Light Metal Ind Ltd Treating device of molten metal
JPS58163555U (en) * 1982-04-27 1983-10-31 住友金属鉱山株式会社 Chlorine gas blowing pipe for molten metal refining

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0549148U (en) * 1991-12-16 1993-06-29 日本重化学工業株式会社 Gas injector for molten metal degassing equipment
JP2008200739A (en) * 2007-02-22 2008-09-04 Japan Metals & Chem Co Ltd Rotary member for molten metal degassing apparatus, and molten metal degassing apparatus comprising the same
WO2010143536A1 (en) * 2009-06-08 2010-12-16 三井金属鉱業株式会社 Lance pipe
JP2010279988A (en) * 2009-06-08 2010-12-16 Mitsui Mining & Smelting Co Ltd Lance pipe
CN109182654A (en) * 2018-10-22 2019-01-11 王子晨 A kind of self-action Air blowing stick for liquid bottom blow
CN109182655A (en) * 2018-10-23 2019-01-11 王子晨 A kind of Air blowing stick for the low blow of liquid

Also Published As

Publication number Publication date
JP2583492B2 (en) 1997-02-19

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