JPS6363566B2 - - Google Patents
Info
- Publication number
- JPS6363566B2 JPS6363566B2 JP22018583A JP22018583A JPS6363566B2 JP S6363566 B2 JPS6363566 B2 JP S6363566B2 JP 22018583 A JP22018583 A JP 22018583A JP 22018583 A JP22018583 A JP 22018583A JP S6363566 B2 JPS6363566 B2 JP S6363566B2
- Authority
- JP
- Japan
- Prior art keywords
- polyether
- caprolactam
- polyether prepolymer
- lactam
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 31
- 229920000570 polyether Polymers 0.000 claims description 31
- 229920006147 copolyamide elastomer Polymers 0.000 claims description 10
- 150000003951 lactams Chemical class 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 238000010539 anionic addition polymerization reaction Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002685 polymerization catalyst Substances 0.000 claims description 3
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 20
- 239000000203 mixture Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000007711 solidification Methods 0.000 description 7
- 230000008023 solidification Effects 0.000 description 7
- LBXFCUWIEJKZFT-UHFFFAOYSA-N 2-oxoazepane-1-carbonyl chloride Chemical compound ClC(=O)N1CCCCCC1=O LBXFCUWIEJKZFT-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229920001451 polypropylene glycol Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000011259 mixed solution Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- YIFCDKDXYUCWAZ-UHFFFAOYSA-L magnesium;azepan-2-one;dibromide Chemical compound [Mg+2].[Br-].[Br-].O=C1CCCCCN1 YIFCDKDXYUCWAZ-UHFFFAOYSA-L 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000012661 block copolymerization Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 description 3
- -1 polyol compound Chemical class 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- PWXIKGAMKWRXHD-UHFFFAOYSA-N 3-butylaziridin-2-one Chemical compound CCCCC1NC1=O PWXIKGAMKWRXHD-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001623 magnesium bromide Inorganic materials 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- UMLPONXXJIKBMA-UHFFFAOYSA-N 2-oxopyrrolidine-1-carbonyl chloride Chemical compound ClC(=O)N1CCCC1=O UMLPONXXJIKBMA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000011952 anionic catalyst Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- YDVNLQGCLLPHAH-UHFFFAOYSA-N dichloromethane;hydrate Chemical compound O.ClCCl YDVNLQGCLLPHAH-UHFFFAOYSA-N 0.000 description 1
- WOAZEKPXTXCPFZ-UHFFFAOYSA-N dimethyl(phenyl)azanium;chloride Chemical compound Cl.CN(C)C1=CC=CC=C1 WOAZEKPXTXCPFZ-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-IGMARMGPSA-N magnesium-24 Chemical compound [24Mg] FYYHWMGAXLPEAU-IGMARMGPSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Polyamides (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22018583A JPS60112825A (ja) | 1983-11-22 | 1983-11-22 | ポリエ−テルポリアミドブロック共重合体の製造方法 |
| CA000467817A CA1257028A (fr) | 1983-11-22 | 1984-11-14 | Methode de preparation d'un copolymere a sequence de polyether-polyamide |
| EP84308009A EP0147051B1 (fr) | 1983-11-22 | 1984-11-19 | Préparation de copolymères polyether-polyamides et de leur prépolymères |
| DE8484308009T DE3485458D1 (de) | 1983-11-22 | 1984-11-19 | Herstellung von polyaether-polyamid-blockcopolymeren und prepolymeren. |
| US06/914,515 US4792603A (en) | 1983-11-22 | 1986-10-02 | Method of producing a polyether prepolymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22018583A JPS60112825A (ja) | 1983-11-22 | 1983-11-22 | ポリエ−テルポリアミドブロック共重合体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60112825A JPS60112825A (ja) | 1985-06-19 |
| JPS6363566B2 true JPS6363566B2 (fr) | 1988-12-07 |
Family
ID=16747209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22018583A Granted JPS60112825A (ja) | 1983-11-22 | 1983-11-22 | ポリエ−テルポリアミドブロック共重合体の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60112825A (fr) |
-
1983
- 1983-11-22 JP JP22018583A patent/JPS60112825A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60112825A (ja) | 1985-06-19 |
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