JPS6362843A - Electrogalvanized baling hoop having high strength - Google Patents

Electrogalvanized baling hoop having high strength

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Publication number
JPS6362843A
JPS6362843A JP20875286A JP20875286A JPS6362843A JP S6362843 A JPS6362843 A JP S6362843A JP 20875286 A JP20875286 A JP 20875286A JP 20875286 A JP20875286 A JP 20875286A JP S6362843 A JPS6362843 A JP S6362843A
Authority
JP
Japan
Prior art keywords
hoop
electrogalvanized
baling
strength
steel sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20875286A
Other languages
Japanese (ja)
Inventor
Ichiro Kokubo
小久保 一郎
Kazuhiko Gunda
郡田 和彦
Hidenori Shirasawa
白沢 秀則
Fukuteru Tanaka
田中 福輝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP20875286A priority Critical patent/JPS6362843A/en
Publication of JPS6362843A publication Critical patent/JPS6362843A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To prevent deterioration in elongation percentage and bendability due to electrogalvanizing, by properly controlling the chemical composition and structure of a steel sheet as a stock for electrogalvanized baling hoop. CONSTITUTION:As baling hoop used for packaging raw cotton, wool, steel products, etc., an electrogalvanized hoop excellent in rust resistance, value of goods, etc., is used. In this hoop, elongation and bending moment are deteriorated pursuant to application of electrogalvanizing. In order to prevent the above deterioration, a low-carbon steel sheet which contains, by weight, 0.10-0.25% C, 1.0-2.3% Si, and 1.0-3.0% Mn and in which value of Si/Mn by weight is regulated to >=0.5 or the one further containing one kind among <0.10% P, <=0.50% each of Cu, Cr, Ni, and Mo, <=0.10% each of Ti, Nb, and V, and 0.006% B is used as a cold-rolled steel sheet as a stock for electrogalvanized hoop. In this way, the electrogalvanized baling hoop in which martensitic structure comprises >=80% by area ratio and which has >0.8 notch strength ratio and >130kgf/mm<2> tensile strength can be obtained.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、原綿、羊毛、鋼材等の梱包に用いられる電気
亜鉛めっきしたベーリングフープに関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an electrogalvanized baling hoop used for packaging raw cotton, wool, steel, etc.

(従来の技術) 従来、ブルーイング処理して、その表裏面に美麗な酸化
スケールを生成させたベーリングフープ(以下、単にフ
ープという。)が広く梱包資材として用いられているが
、最近、ブルーイングに代わって、塗装やめつき処理、
特に、電気亜鉛めっきしたフープが使用時の耐誘性や商
品価値等にすぐれるために用いられるに至っている。
(Prior art) Baling hoops (hereinafter simply referred to as hoops), which have been subjected to bluing treatment to produce beautiful oxide scales on their front and back surfaces, have been widely used as packaging materials. Instead of painting and glazing treatment,
In particular, electrogalvanized hoops have come to be used because of their excellent resistance to induction during use and their commercial value.

引張強さ130 kgf/+nm”以上の高強度フープ
に要求される主な特性は、長標点間距離の引張試験にお
けるすぐれた伸びと曲げ加工性である。しかし、素材冷
延鋼板がこれらの性質にすぐれている場合でも、電気亜
鉛めっきしたフープは、これらの特性に劣ることが知ら
れている。例えば、製品仕様として、曲げ半径31mで
の90°繰り返し曲げが4回以上要求される場合、繰り
返し曲げを6回以上行ない得る1 40kgf/mm”
級無処理フープに目付量表裏回答10 g/mとした電
気亜鉛めっきを施したとき、繰り返し曲げ回数が2回に
も激減し、製品仕様を満たさないことがある。この原因
は明らかではないが、亜鉛等を含むめっき層は、水素の
拡散を著しく抑制するといわれているので、電気亜鉛め
っきを施すことによって、鋼中の水素の散逸が妨げられ
る結果、銅が劣化する所謂水素脆化が関係しているとみ
られる。
The main properties required for a high-strength hoop with a tensile strength of 130 kgf/+nm or more are excellent elongation and bending workability in long gauge length tensile tests. Electrogalvanized hoops are known to be inferior in these properties even when they have excellent properties. For example, when product specifications require 90° repeated bending at a bending radius of 31 m four or more times. , 140kgf/mm” that can be repeatedly bent 6 times or more
When an untreated hoop is subjected to electrogalvanizing with a basis weight of 10 g/m, the number of repeated bends is drastically reduced to 2, and the product specifications may not be met. The cause of this is not clear, but it is said that a plating layer containing zinc etc. significantly suppresses the diffusion of hydrogen, so electrogalvanizing prevents the dissipation of hydrogen in the steel, causing the copper to deteriorate. This appears to be related to so-called hydrogen embrittlement.

更に、フープは、よく知られているように、その先端部
において、剪断切抜きによる裏面側に隆起する切目が長
手方向に沿って所定の間隔をおいて多数形成され、後端
部においては、反対に表面側に隆起する切目が長手方向
に沿って所定の間隔をおいて多数形成されて、かかる切
欠付き継手によって結束されることが多い。従って、フ
ープには、この切欠付き継手の重ね合わせによる接合部
の引張強さの高いことも必要であり、一般に、フープの
引張強さに対するこの継手の引張強さの比(以下、切欠
強度比という。)が0.75以上であることが必要とさ
れている。
Furthermore, as is well known, the hoop has a large number of protruding cuts on the back side by shear cutouts at the tip thereof at predetermined intervals along the longitudinal direction, and at the rear end, there are A large number of notched notches are formed along the longitudinal direction at predetermined intervals, and the joints are often bound by such a notched joint. Therefore, the hoop must also have a high tensile strength at the joint formed by overlapping the notched joints, and in general, the ratio of the tensile strength of this joint to the hoop's tensile strength (hereinafter referred to as notch strength ratio) is required. ) is required to be 0.75 or more.

以上のように、フープには、伸び及び曲げ加工性にすぐ
れるほか、大きい切欠強度比等が要求されるが、従来、
これらの特性を考慮したフープ用鋼板の冶金学的見地か
らの研究は殆どなされていない。
As mentioned above, hoops are required to have excellent elongation and bending workability as well as a large notch strength ratio.
There has been almost no research conducted on steel plates for hoops from a metallurgical standpoint, taking these characteristics into consideration.

(発明の目的) 本発明者らは、電気亜鉛めっきしたフープにおける上記
した問題を解決するために鋭意研究した結果、鋼の化学
成分及び組織を適正に規制することによって、複合組織
冷延鋼板の電気亜鉛めっきに伴う伸び及び曲げ加工性の
低下を著しく抑制し得ることを見出して、本発明に至っ
たものである。
(Objective of the Invention) As a result of intensive research to solve the above-mentioned problems in electrogalvanized hoops, the present inventors have discovered that by appropriately regulating the chemical composition and structure of steel, a cold-rolled steel sheet with a composite structure can be produced. The present invention was achieved by discovering that the reduction in elongation and bending workability caused by electrogalvanizing can be significantly suppressed.

従って、本発明は、曲げ加工性にすぐれる電気亜鉛めっ
きした高強度フープを提供することを目的とする。
Accordingly, it is an object of the present invention to provide a high-strength electrogalvanized hoop with excellent bendability.

(発明の構成) 本発明による電気亜鉛めっきしたベーリングフープは、
重量%で C0.10〜0.25%、 Si1.0〜2.3%、及び Mn  1.0〜3.0%を含有し、且つ、S i /
 M n重量比≧0.5を満たし、残部鉄及び不可避的
不純物よりなり、面積率にて80%以上のマルテンサイ
トを含有することを特徴とし、かかる鋼板は、切欠強度
比が0.8以上、引張強さが130kgf/mm”以上
である。
(Structure of the Invention) The electrogalvanized baling hoop according to the present invention comprises:
Contains 0.10 to 0.25% of C, 1.0 to 2.3% of Si, and 1.0 to 3.0% of Mn in weight%, and S i /
The steel plate is characterized by satisfying Mn weight ratio ≧0.5, the balance being iron and unavoidable impurities, and containing martensite in an area ratio of 80% or more, and such a steel plate has a notch strength ratio of 0.8 or more. , the tensile strength is 130 kgf/mm” or more.

先ず、化学成分量の種々異なる0、 7 **厚140
kgf/mm”級複合組織冷延鋼板を水焼入れ型連続焼
鈍をシミュレートしたソルトバス熱処理によって製造し
た後、表裏面の各目付量10 g/ry?として、電気
亜鉛めっきを行なって、これに伴う伸び及び曲げ加工性
の変化を調べた。結果を第1表に示す。
First of all, 0, 7 ** Thickness 140 with different amounts of chemical components.
kgf/mm" grade composite structure cold-rolled steel sheet was manufactured by salt bath heat treatment simulating water quenching type continuous annealing, and then electrogalvanized with a basis weight of 10 g/ry? on the front and back surfaces. The accompanying changes in elongation and bending workability were investigated.The results are shown in Table 1.

いずれの鋼板も、電気亜鉛めっき処理によって、伸び及
び曲げ加工性が劣化する。高C量低Si量鋼板Aは、め
っき前に既に伸び及び曲げ加工性が悪い、これに対して
、C量を低減した鋼板Cは延性が改善され、めっき後の
特性も若干改善されるが、尚、曲げ加工性は十分ではな
い。高C高Si鋼板Bは、めっき前に比較的すぐれた伸
びを有するが、めっき後の曲げ加工性の劣化が著しい。
The elongation and bending workability of any steel sheet deteriorates due to the electrogalvanizing treatment. Steel plate A with high C content and low Si content already has poor elongation and bending properties before plating, whereas steel plate C with reduced C content has improved ductility and properties after plating, but However, the bending workability is not sufficient. The high C high Si steel plate B has relatively good elongation before plating, but the bending workability after plating deteriorates significantly.

しかし、鋼板Bに対して、clを低減し、Mn量を若干
増加した鋼板りはすぐれた延性を有し、めっき後にもこ
れを保持して、伸び及び曲げ加工性にもすぐれる。
However, compared to steel plate B, a steel plate with reduced Cl and slightly increased Mn content has excellent ductility, retains this even after plating, and has excellent elongation and bending workability.

従って、伸び及び曲げ加工性にすぐれる電気亜鉛めっき
したフープを得るには、素材冷延鋼板にすぐれた延性を
付与すると共に、鋼の化学成分としては、C及びMn量
を比較的少なくし、Si量を比較的多くすることが望ま
しいことが示される。
Therefore, in order to obtain an electrogalvanized hoop with excellent elongation and bending workability, the cold-rolled steel sheet material should have excellent ductility, and the chemical components of the steel should include relatively low amounts of C and Mn. It is shown that it is desirable to increase the amount of Si relatively.

本発明者らは、複合組織冷延鋼板に電気亜鉛めっきした
1 30kgf/1111”級フープについて、添加合
金元素量の影響を詳細に研究すると共に、組織の影響に
ついても鋭意研究した結果、元素量及び組織を適正に規
制することによって、すぐれた曲げ加工性を有する電気
亜鉛めっきフープを得ることができることを見出して、
本発明を完成したものである。
The present inventors conducted a detailed study on the influence of the amount of added alloying elements on a 130 kgf/1111'' class hoop made of electrogalvanized cold-rolled steel sheet with a composite structure, and as a result of intensive research on the influence of the structure, the amount of elements and found that by properly controlling the structure, it is possible to obtain an electrogalvanized hoop with excellent bending workability,
This completes the present invention.

次に、本発明による高強度フープにおける化学成分の限
定理由について説明する。
Next, the reason for limiting the chemical components in the high-strength hoop according to the present invention will be explained.

Cは、鋼板の強度を確保するために必要な元素であって
、0.10%よりも少ないときは、引張強さ130kg
f/mmz以上を得ることが困難である。
C is an element necessary to ensure the strength of the steel plate, and when it is less than 0.10%, the tensile strength is 130 kg.
It is difficult to obtain f/mmz or higher.

しかし、0.25%を越えるときは、高強度化は達成し
得ても、伸びや曲げ加工性が著しく劣化する。
However, when it exceeds 0.25%, although high strength can be achieved, elongation and bending workability deteriorate significantly.

従って、本発明においては、Cの添加量は0.10〜0
.25%の範囲とする。
Therefore, in the present invention, the amount of C added is 0.10 to 0.
.. The range is 25%.

Siは、1.0%よりも少ないときは、電気亜鉛めっき
後に鋼板の延性が著しく低下し、他方、2゜3%を越え
て過多に添加するときは、製造費用の上昇が大きいほか
、スラブの割れ感光性が高まる。
When Si is less than 1.0%, the ductility of the steel sheet decreases significantly after electrogalvanizing.On the other hand, when Si is added in excess of 2.3%, manufacturing costs increase significantly and the slab Increases cracking photosensitivity.

更に、本発明においては、Si/Mn重量比が0゜5以
上であることを必要とする。S i / M n重量比
が0.5よりも小さいときも、電気亜鉛めっき後に鋼板
の延性が著しく低下するからである。
Furthermore, the present invention requires that the Si/Mn weight ratio be 0.5 or more. This is because when the S i /M n weight ratio is smaller than 0.5, the ductility of the steel sheet decreases significantly after electrogalvanizing.

Mnは、鋼板の強度を確保するために必要な元素である
。添加量が1.0%よりも少ないときは、引張強さ13
0kgf/ma+”以上を得るためには、その他の合金
元素の添加を必要として、製造費用を上昇させる。しか
し、3.0%よりも多いときは、鋼のバンド組織が強く
なり、伸び及び曲げ加工性が低下する。
Mn is an element necessary to ensure the strength of the steel plate. When the amount added is less than 1.0%, the tensile strength is 13
In order to obtain 0 kgf/ma+" or more, it is necessary to add other alloying elements, which increases manufacturing costs. However, when the amount is more than 3.0%, the band structure of the steel becomes strong, making it difficult to stretch and bend. Processability decreases.

本発明においては、鋼には上記した元素に加えて、必要
に応じて、P、Cu、Cr、Ni5Mo。
In the present invention, in addition to the above-mentioned elements, the steel contains P, Cu, Cr, and Ni5Mo as necessary.

Tis Nb、V及びBよりなる群から選ばれる少なく
とも1種の元素を添加することができる。
At least one element selected from the group consisting of TisNb, V, and B can be added.

Pは、鋼の強化及び耐食性の向上のために添加されるが
、0.1%を越えて過多に添加するときは、鋼の脆化が
著しくなるので、添加量は001%以下の範囲とする。
P is added to strengthen steel and improve corrosion resistance, but if added in excess of 0.1%, the steel will become significantly brittle, so the amount added should be within 0.01%. do.

Crs Ni、Cu及びMoも、いずれも鋼の強化及び
耐食性の向上環のために添加される。しかし、これらの
元素は、CJpPに比べて高価であり、多量の添加は好
ましくないので、添加量は0.50%を上限とする。
Crs Ni, Cu and Mo are also added to strengthen the steel and improve corrosion resistance. However, these elements are more expensive than CJpP, and it is not preferable to add them in large amounts, so the upper limit of the amount added is 0.50%.

Ti、Nb及び■は、少量にて鋼の強化に効果を有する
が、0.10%を越える過多量を添加しても、上記効果
が飽和し、経済性の点からも好ましくないので、添加量
の上限を0.10%とする。
Ti, Nb, and ■ have the effect of strengthening steel in small amounts, but if they are added in an excessive amount exceeding 0.10%, the above effects will be saturated, and this is not preferable from an economic point of view, so they should not be added. The upper limit of the amount is 0.10%.

Bは、微量の添加にて鋼の焼入れ性を高める効果を有し
、鋼の強度上昇に有利であるが、添加量が0.006%
を越えるときは、鋼の曲げ加工性を劣化させるので、添
加量は0.006%を上限とする。
B has the effect of increasing the hardenability of steel when added in a small amount, and is advantageous in increasing the strength of steel, but when added in an amount of 0.006%
If it exceeds the above, the bending workability of the steel will deteriorate, so the upper limit of the amount added is 0.006%.

更に、本発明においては、鋼の局部変形能を高めるため
に、鋼にZr、Ca、REM等を必要に応じて添加して
もよい。
Furthermore, in the present invention, Zr, Ca, REM, etc. may be added to the steel as necessary in order to enhance the local deformability of the steel.

本発明によるフープは、上記した化学成分を有すると共
に、電気亜鉛めっきを施しても、所要の曲げ加工性を確
保するために、面積率にて80%以上のマルテンサイト
を含有することが必要である。
The hoop according to the present invention has the chemical components described above, and must also contain martensite in an area ratio of 80% or more in order to ensure the required bending workability even after electrogalvanizing. be.

前述したように、フープには、切欠強度比が0゜75以
上であることが必要とされるが、本発明の電気亜鉛めっ
きフープによれば、切欠強度比0.8以上を得ることが
できると共に、前記曲げ回数4回以上及び伸び5.0%
以上を達成することができる。
As mentioned above, the hoop is required to have a notch strength ratio of 0°75 or more, but according to the electrogalvanized hoop of the present invention, a notch strength ratio of 0.8 or more can be obtained. In addition, the number of bending times is 4 or more and the elongation is 5.0%.
The above can be achieved.

(発明の効果) 以上のように、本発明によれば、複合組織冷延鋼板にお
ける化学成分及び組織を適正に規制することによって、
伸び及び曲げ加工性にすぐれる引張強度130kgf/
w+n+”以上の電気亜鉛めっき高強度フープを得るこ
とができる。
(Effects of the Invention) As described above, according to the present invention, by appropriately regulating the chemical components and structure of a cold-rolled steel sheet with a composite structure,
Tensile strength 130kgf/ with excellent elongation and bending workability
An electrogalvanized high-strength hoop with a strength of w+n+'' or more can be obtained.

(実施例) 以下に実施例を挙げて本発明を説明するが、本発明はこ
れら実施例により何ら限定されるものではない。
(Examples) The present invention will be described below with reference to Examples, but the present invention is not limited to these Examples in any way.

第2表に示す化学成分を有する10に「真空溶解鋼を用
いて、常法に従って、分塊、熱間圧延及び冷間圧延を行
なって、0.7 +n厚冷延鋼板を製造した。これに水
焼入れ型連続焼鈍をシミュレートしたソルトバス熱処理
を施した0次いで、脱脂及び洗浄した後、表裏面に目付
量10 g/rrrにて電気亜鉛めっきを施した。これ
をJIS 5号引張試験片及び1911幅のシャーまま
引張試験片(標点間距離100m)に加工し、機械的性
質を評価した。
Using vacuum melted steel No. 10 having the chemical composition shown in Table 2, blooming, hot rolling and cold rolling were performed according to conventional methods to produce a 0.7 +n thick cold rolled steel plate. The was subjected to salt bath heat treatment simulating water quenching type continuous annealing.Then, after degreasing and washing, electrogalvanization was applied to the front and back surfaces at a basis weight of 10 g/rrr.This was subjected to a JIS No. 5 tensile test. The specimens were processed into tensile test specimens with a width of 1911 (gage distance 100 m) and their mechanical properties were evaluated.

結果を第2表に示す。The results are shown in Table 2.

比較@2は、マルテンサイト量が過少であるので、伸び
は高いが、切欠強度比に劣る。比較f43は、Si量が
過少であるので、マルテンサイト面積率は80%を越え
るが、延性が乏しく、切欠強度比に劣る。比較鋼4も、
Si量が過少であるので、切欠強度比に劣る。また、比
較allは、化単成分は、本発明で規定する範囲内にあ
るが、マルテンサイト量が過少であるので、切欠強度比
に劣る。
In Comparison @2, since the amount of martensite is too small, the elongation is high, but the notch strength ratio is inferior. Comparative f43 has too little Si content, so the martensite area ratio exceeds 80%, but it has poor ductility and poor notch strength ratio. Comparative steel 4 also
Since the amount of Si is too small, the notch strength ratio is poor. In addition, in comparison all, although the chemical component is within the range specified by the present invention, the amount of martensite is too small, so the notch strength ratio is inferior.

これらに対して、本発明によるフープは、切欠強度比0
.8以上、曲げ半径3Nでの繰り返し90゜曲げにおけ
る破断までの曲げ回数4回以上の満足すべき性質を有す
る。
In contrast, the hoop according to the present invention has a notch strength ratio of 0
.. 8 or more, and has satisfactory properties such that the number of bends before breakage in repeated 90° bending with a bending radius of 3N is 4 or more times.

Claims (2)

【特許請求の範囲】[Claims] (1)重量%で C 0.10〜0.25%、 Si 1.0〜2.3%、及び Mn 1.0〜3.0%を含有し、且つ、 Si/Mn重量比≧0.5を満たし、 残部鉄及び不可避的不純物よりなり、面積率にて80%
以上のマルテンサイトを含有することを特徴とする切欠
強度比が0.8以上、引張強さが130kgf/mm^
2以上である電気亜鉛めつきした高強度ベーリングフー
プ。
(1) Contains 0.10 to 0.25% of C, 1.0 to 2.3% of Si, and 1.0 to 3.0% of Mn in weight%, and has a Si/Mn weight ratio ≧0. 5, the balance consists of iron and unavoidable impurities, and the area ratio is 80%.
The notch strength ratio is 0.8 or more, and the tensile strength is 130 kgf/mm^.
High-strength baling hoop with electrogalvanized coating of 2 or more.
(2)重量%で (a)C 0.10〜0.25%、 Si 1.0〜2.3%、及び Mn 1.0〜3.0%を含有し、且つ、 Si/Mn重量比≧0.5を満たし、 (b)P 0.10%以下、 Cu 0.50%以下、 Cr 0.50%以下、 Ni 0.50%以下、 Mo 0.50%以下、 Ti 0.10%以下、 Nb 0.10%以下、 V 0.10%以下、及び B 0.006%以下 よりなる群から選ばれる少なくとも1種の元素を含有し
、 残部鉄及び不可避的不純物よりなり、面積率にて80%
以上のマルテンサイトを含有することを特徴とする切欠
強度比が0.8以上、引張強さが130kgf/mm^
2以上であることを特徴とする電気亜鉛めつきした高強
度ベーリングフープ。
(2) Contains (a) C 0.10 to 0.25%, Si 1.0 to 2.3%, and Mn 1.0 to 3.0% in weight%, and Si/Mn weight ratio ≧0.5, (b) P 0.10% or less, Cu 0.50% or less, Cr 0.50% or less, Ni 0.50% or less, Mo 0.50% or less, Ti 0.10% Contains at least one element selected from the group consisting of Nb 0.10% or less, V 0.10% or less, and B 0.006% or less, with the balance consisting of iron and unavoidable impurities, and has an area ratio of 80%
The notch strength ratio is 0.8 or more, and the tensile strength is 130 kgf/mm^.
A high-strength baling hoop electrogalvanized, characterized by a strength of 2 or more.
JP20875286A 1986-09-03 1986-09-03 Electrogalvanized baling hoop having high strength Pending JPS6362843A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20875286A JPS6362843A (en) 1986-09-03 1986-09-03 Electrogalvanized baling hoop having high strength

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20875286A JPS6362843A (en) 1986-09-03 1986-09-03 Electrogalvanized baling hoop having high strength

Publications (1)

Publication Number Publication Date
JPS6362843A true JPS6362843A (en) 1988-03-19

Family

ID=16561493

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20875286A Pending JPS6362843A (en) 1986-09-03 1986-09-03 Electrogalvanized baling hoop having high strength

Country Status (1)

Country Link
JP (1) JPS6362843A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999032670A1 (en) * 1997-12-19 1999-07-01 Exxonmobil Upstream Research Company Ultra-high strength ausaged steels with excellent cryogenic temperature toughness
US6254698B1 (en) 1997-12-19 2001-07-03 Exxonmobile Upstream Research Company Ultra-high strength ausaged steels with excellent cryogenic temperature toughness and method of making thereof
KR20200124289A (en) * 2018-03-30 2020-11-02 제이에프이 스틸 가부시키가이샤 High strength galvanized steel sheet, high strength member and their manufacturing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999032670A1 (en) * 1997-12-19 1999-07-01 Exxonmobil Upstream Research Company Ultra-high strength ausaged steels with excellent cryogenic temperature toughness
US6251198B1 (en) 1997-12-19 2001-06-26 Exxonmobil Upstream Research Company Ultra-high strength ausaged steels with excellent cryogenic temperature toughness
US6254698B1 (en) 1997-12-19 2001-07-03 Exxonmobile Upstream Research Company Ultra-high strength ausaged steels with excellent cryogenic temperature toughness and method of making thereof
ES2181566A1 (en) * 1997-12-19 2003-02-16 Exxon Production Research Co Ultra-high strength ausaged steels with excellent cryogenic temperature toughness
KR20200124289A (en) * 2018-03-30 2020-11-02 제이에프이 스틸 가부시키가이샤 High strength galvanized steel sheet, high strength member and their manufacturing method
US11530463B2 (en) 2018-03-30 2022-12-20 Jfe Steel Corporation High-strength galvanized steel sheet, high strength member, and method for manufacturing the same

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