JPS6360783A - Ink jet recording method - Google Patents
Ink jet recording methodInfo
- Publication number
- JPS6360783A JPS6360783A JP61206289A JP20628986A JPS6360783A JP S6360783 A JPS6360783 A JP S6360783A JP 61206289 A JP61206289 A JP 61206289A JP 20628986 A JP20628986 A JP 20628986A JP S6360783 A JPS6360783 A JP S6360783A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- tables
- formulas
- group
- chemical formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000012736 aqueous medium Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 6
- 229920000642 polymer Polymers 0.000 claims abstract description 6
- 125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- 125000005843 halogen group Chemical group 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 13
- 150000001875 compounds Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 24
- 230000002349 favourable effect Effects 0.000 abstract 2
- 238000004040 coloring Methods 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000000975 dye Substances 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 150000007514 bases Chemical class 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- QNVQPXNRAJFKQV-UHFFFAOYSA-N 1-fluoroethane-1,2-diol Chemical compound OCC(O)F QNVQPXNRAJFKQV-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 241000238413 Octopus Species 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 229920005565 cyclic polymer Polymers 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- -1 fluoropylene gelicol Chemical compound 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
- B41M5/0017—Application of ink-fixing material, e.g. mordant, precipitating agent, on the substrate prior to printing, e.g. by ink-jet printing, coating or spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0018—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using ink-fixing material, e.g. mordant, precipitating agent, after printing, e.g. by ink-jet printing, coating or spraying
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分針〕 本発明はインクジェット記録方法に関するものである。[Detailed description of the invention] [Industrial use minute hand] The present invention relates to an inkjet recording method.
詳しくは、本発明は諸堅牢性に優れた印字物を与えるイ
ンクジェット記録方法に関するものである。Specifically, the present invention relates to an inkjet recording method that provides printed matter with excellent fastness.
インクジェット記録方法において印字物の堅牢性は！要
であるが、とりわけ耐水性は、オフィスにおける書類、
ポスター等の分野では強く求められている。What is the robustness of printed matter in inkjet recording method? Water resistance is especially important for office documents,
It is highly sought after in fields such as posters.
この耐水性を改良する手段として、例えば下記のような
方法が提案されている。As a means to improve this water resistance, the following methods have been proposed, for example.
■ 新規色素を開発して紙との直接性（親和性）を向上
させる。■ Develop new pigments to improve directness (affinity) with paper.
■ 被記録材の表面あるいはその中に色素の耐水化剤を
含有せしめる。(2) Adding a dye waterproofing agent to the surface or inside of the recording material.
■ インク中に色素の耐水化剤を含有せしめる。■ Contain a pigment waterproofing agent in the ink.
■の方法に関しては、特開昭！ターＪ／ｊ７７Ｊ特開昭
！ターコ／ｊ３ｔｒ％特開昭６０−タ弘弘７７等多数の
特許公開公報に記載されており、又■に関しても特開昭
ｔ＋−ｒ≠？タコ、特開昭ｊ６−タタ６り３特開昭！７
−６弘！り１等多数の特許に示されている。■に関して
も特開昭！６−／３３３７６、特開昭ｊｒ−／２！７６
７ 等やはり多くの特許が出題されている。■For method, see Tokukaisho! Tar J/j77J Tokukai Sho! Turco/j3tr% is described in many patent publications such as JP-A-60-TA-Hirohiro-77, and regarding ■, JP-A-A t+-r≠? Octopus, Tokukai Showa J6-Tata 6ri 3 Tokukai Showa! 7
-6 Hiromu! This is shown in numerous patents, including first class patents. ■As for Tokukai Akira! 6-/33376, Tokukai Sho Jr-/2!76
7, etc., many patents are on the list.
又、上記■、■、■以外にも、特開昭ｔ。Moreover, in addition to the above ■, ■, ■, there is also JP-A-Sho t.
−／ ？！１３の様に反応性染料を含有するインクの吐
出と同時又は前後してアルカリ性水溶液を付着させると
いった工夫がなされている。-/? ! As shown in No. 13, an attempt has been made to deposit an alkaline aqueous solution at the same time or before or after the ejection of ink containing a reactive dye.
しかしながら、この様な種々の方法によっても■の場合
には、十分な効果が得られなかったり、あるいは効果が
得られても他の堅牢性（耐光性、保存安定性等）が劣っ
たり溶解性が低下し九すするといった欠陥があり、これ
らの要件を全て涜足するには致っていない。However, even with these various methods, in the case of (2), sufficient effects may not be obtained, or even if effects are obtained, other fastness properties (light resistance, storage stability, etc.) are poor or solubility is poor. There are defects such as a decrease in the amount of water, and it is not possible to meet all of these requirements.
又■に関しては、記録紙として特定の紙を用いることに
なり電子写真用紙、ボンド紙、ストツク７オーム紙等の
安価な汎用紙に比べて記録コスト高となり、経済性に問
題がある。Regarding (2), since a specific paper is used as the recording paper, the recording cost is higher than that of inexpensive general-purpose paper such as electrophotographic paper, bond paper, stock 7 ohm paper, etc., and there is a problem in economic efficiency.
又■に関しては色素と耐水化剤の相互作用によりインク
としての保存安定性等に欠陥が生じたり、更に、特開昭
ぶ０−／りｊｔ３の場合には、色素が特殊な構造に限定
される他、本質的に反応染料の色素（反応活性基）が不
安定でありインクとしての長期保存安定性に欠陥が生じ
る等の問題がある。Regarding (2), the interaction between the dye and the water-fastening agent may cause defects in the storage stability of the ink, and furthermore, in the case of JP-A-Shobu 0-/RIJT3, the dye is limited to a special structure. In addition, there are other problems, such as the fact that the pigment (reactive group) of the reactive dye is inherently unstable, resulting in defects in long-term storage stability as an ink.
本発明は、普通紙に記録を行うことが出来、且つインク
に利用できる色素の範囲が広く、シかも印字物は諸堅牢
性に優れ、とりわけ、その耐水性に優れているインクジ
ェット記録方法の提供を目的とするものである。The present invention provides an inkjet recording method that can perform recording on plain paper, has a wide range of pigments that can be used in the ink, and provides printed matter with excellent fastness, especially its water resistance. The purpose is to
本発明は、水性媒体及び着色剤としてスルホン酸基を有
する水溶性染料を含有する記録液を、吐出オリフィスか
ら吐出させて記録するインクジェット記録方法において
、該記録液の吐出と同時又は前後して塩基性ポリマーを
含有した水性媒体液を被記録材に付着させることを特許
とするインクジェット記録方法をその要旨とするもので
ある。The present invention relates to an inkjet recording method in which recording is performed by discharging a recording liquid containing an aqueous medium and a water-soluble dye having a sulfonic acid group as a coloring agent from a discharge orifice. The gist of this patent is an inkjet recording method in which an aqueous medium containing a polymer is applied to a recording material.
本発明の記録液の着色剤として使用される水溶性染料と
しては、アゾ系、アントラキノン系、キノフタロン系、
インジゴ系及びフタロシアニン系のスルホン酸基を含有
する直接染料及び酸性染料が挙げられ、例えばＯ，１，
Ｄｉｒｅｃｔ Ｂｌａｃｋ−／７、−／り、−２２，−
３２，−ｊｔ’ｌ。Water-soluble dyes used as colorants in the recording liquid of the present invention include azo dyes, anthraquinone dyes, quinophthalone dyes,
Examples include direct dyes and acid dyes containing indigo and phthalocyanine sulfonic acid groups, such as O, 1,
Direct Black-/7,-/ri,-22,-
32,-jt'l.
−１０，−９７、−／！／及び−１ｊ４Ｌ。-10, -97, -/! / and -1j4L.
Ｃ６工、Ｄｉｒｅｃｔ Ｂｌｕｅ −ｒ ６及び−ｌタ
タ、 Ｃｊ、Ｉ。C6 Engineering, Direct Blue -r 6 and -l Tata, Cj, I.
Ｄｉｒｅｃｔ Ｒｅｄ −１ｒ Ｏ、（！ｊ、Ｄｉｒ
ｅｃｔ Ｙｅｌｏｗ−Ｉ Ａ及び−ｌｌココａ、１．
Ａｃ１ｄ Ｂｌａｃｋ−２、−２ｔＡ。Direct Red -1r O, (!j, Dir
ect Yellow-I A and -ll here a, 1.
Acld Black-2, -2tA.
−，２４，−ｕｒｌ −ｊＪ、−ＡＪ、−／ ７２、
−／Ｐ弘及び−２０１ｒ 、 Ｃ１１，Ａｏｉｄ ｆｌ
ｕｅ−２゜−１ｔｓ及び−コｊ ４！ 、 Ｃｊｊ、Ａ
ｃ１ｄ Ｒｅｄ −ｒ 、 −Ｊｊ、−７７及び−コ！
７、Ｃｊ、Ａｃ１ｄ Ｙｅｌｌｏｗ−コ３及び−≠２及
びＣｊ、１．Ｆｏｏｄ Ｂｌａｃｋ −２が挙げられる
。-,24,-url -jJ, -AJ,-/72,
-/P Hiro and -201r, C11, Aoid fl
ue-2゜-1ts and -koj 4! , Cjj, A
c1d Red -r, -Jj, -77 and -ko!
7, Cj, Ac1d Yellow-ko3 and -≠2 and Cj, 1. Food Black-2 is mentioned.
上記水溶性染料の含有量としては記録液全重量に対して
０．ｊｔ、１２％の範囲、好ましくはコ〜ｒ％の範囲が
挙げられる。The content of the above-mentioned water-soluble dye is 0.0% based on the total weight of the recording liquid. jt, in the range of 12%, preferably in the range of co-r%.
本発明の水性媒体としては、水或は水の他に例エバエチ
レングリコール、フロピレンゲリコール、フチレンゲリ
コール、ジエチレングリコール、トリエチレングリコー
ル、ポリエチレングリコール（＃２００）、ポリエチレ
ングリコール（＃グ００）、グリセリン、Ｎ−メチル−
ピロリドン、Ｎ−エチル−ピロリドン、エチレングリコ
ールモノアリルエーテル、エチレングリコールモノメチ
ルエーテル、ジエチレンクリコールモノメチルエーテル
等を含有しているのが好ましく水性媒体の含有量として
は、記録液全重量に対し、２０．ＩＰ、１重量−の範囲
が挙げられる。Examples of the aqueous medium of the present invention include water or, in addition to water, evaporated ethylene glycol, fluoropylene gelicol, fluoroethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol (#200), polyethylene glycol (#g00), glycerin, N-methyl-
It is preferable that the aqueous medium contains pyrrolidone, N-ethyl-pyrrolidone, ethylene glycol monoallyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, etc. The content of the aqueous medium is 20% based on the total weight of the recording liquid. IP, a range of 1 wt.
本発明に使用する環基性ポリマーは下記一般式〔Ｉ〕〜
（：ＸＩＶ）で表わされる化合物から選ばれる。The cyclic polymer used in the present invention has the following general formula [I] ~
(:XIV).
ＮＨ。N.H.
（式中、１は１００〜１０００００の数を示す。）ＣＨ
！
ＮＨ。(In the formula, 1 represents a number from 100 to 100,000.) CH
! N.H.
（式中、ｍは、ｔｏｏ、１ｏｏｏｏＯ数をホす。）（式
中、ｎは／ ００〜１０００００の数を示し、Ｒ１、Ｒ
２、Ｈａは水酸基で置換されていてもよいアルキル基を
示し、Ｘはハロゲン原子又は水酸基を示す。）
→ＯＨ鵞−ＯＨ，−ＮＨ力 ・・・・・・・・・
（１’Ｖ）（式中、ｐは７００〜１０００００の数を示
す−（式中Ｉは水素原子又はメチル基を示し、ｑは１ｏ
Ｓ−ｔｏｏｏの数を示す。）
（式中 Ｒ４は水素原子又はメチル基を示し、ｒは１０
〜／ ０００の数を示し、Ｘはハロゲン原子又は水酸基
を示し Ｒ５はアルキル基を示す。）
（式中 Ｈ６，Ｒ７は水素原子又はメチル基を示し、ａ
％ ｂはｔｏ〜ｔｏｏｏの数を示す。）（式中、Ｒ′は
水素原子又はメチル基を示し、ｄはｔｏ−ｉｏｏｏＯ数
を示し、Ｙは一〇−又は−ＯＨ宜−を示す。）
（式中、ｅは！θ〜１ｏｏｏの数を示す。）（式中 Ｒ
１１はアルキル基を示し、Ｘは・・ロゲン原子又は水酸
基を示し、ｆは １０〜１０００の数を示す。）
ＲＩＯ
■
夏
（式中 ＲＩＯは水素原子又はメチル基を表わし、Ｒ１
１は低級アルキレン基を示し、Ｒ１２、１！１ 、 Ｒ
１４は水酸基で置換されていても良いアルキ−基を示し
、ｇは１０〜１０００の数を示し、Ｘはハロゲン原子又
は水酸基を示す。）
（式中、Ｒｌｇは水素原子又はメチル基を示し、Ｈｌｌ
は低級アルキレン基を示し Ｒ１７、Ｂｉｇ は水酸
基で置換されていても良いアルキル基を示し。(In the formula, m represents the number too, 1ooooO.) (In the formula, n represents a number from / 00 to 100000, R1, R
2. Ha represents an alkyl group which may be substituted with a hydroxyl group, and X represents a halogen atom or a hydroxyl group. ) →OH-OH,-NH force ・・・・・・・・・
(1'V) (in the formula, p represents a number from 700 to 100,000 - (in the formula, I represents a hydrogen atom or a methyl group, and q represents 1o
Indicates the number of S-too. ) (In the formula, R4 represents a hydrogen atom or a methyl group, and r is 10
~/000, X represents a halogen atom or a hydroxyl group, and R5 represents an alkyl group. ) (In the formula, H6 and R7 represent a hydrogen atom or a methyl group, and a
%b indicates the number of too to tooo. ) (In the formula, R' represents a hydrogen atom or a methyl group, d represents the number to-ioooO, and Y represents 10- or -OH-.) (In the formula, e represents !θ~1ooo ) (in the formula R
11 represents an alkyl group, X represents a...rogen atom or a hydroxyl group, and f represents a number from 10 to 1000. ) RIO ■ Summer (In the formula, RIO represents a hydrogen atom or a methyl group, and R1
1 represents a lower alkylene group, R12, 1!1, R
14 represents an alkyl group which may be substituted with a hydroxyl group, g represents a number from 10 to 1000, and X represents a halogen atom or a hydroxyl group. ) (In the formula, Rlg represents a hydrogen atom or a methyl group, Hll
represents a lower alkylene group, and R17 and Big represent an alkyl group which may be substituted with a hydroxyl group.
ｈは１ｏ−ｉｏｏｏＯ数を示す。）
（式中 Ｒ２９、Ｒ２０は水酸基で置換されていてもよ
いアルキル基を示し ＨＨは水素原子又はメチル基を示
し、１は１０〜ｔｏｏｏの数を示す−（式中 Ｒ２！
、 Ｒ１３は アルキル基を示し、Ｘは〕・ロゲン原子
又は水酸基を示し％ ｊｄ１０００〜１０００００の数
を示す。）
上記一般式〔Ｉ〕〜（Ｘｆｆ ］で示される塩基性化合
物の具体例としては例えば次のようなものが挙げられる
。h indicates 1o-ioooO number. ) (In the formula, R29 and R20 represent an alkyl group that may be substituted with a hydroxyl group, HH represents a hydrogen atom or a methyl group, and 1 represents a number from 10 to tooo - (In the formula, R2!
, R13 represents an alkyl group; ) Specific examples of the basic compounds represented by the above general formulas [I] to (Xff) include the following.
ＮＨ。N.H.
（Ｈ雪 ＮＨ。(H snow N.H.
一＋当−Ｃ！Ｈ，−ＨＨキ ｐ：１０００〜１０００
０ｒ：コＯ〜１００
ａ、ｂ：ＺＯ〜ＳＯ
ＣＨ。One + To – C! H, -HHki p: 1000-1000
0r: KO~100 a, b: ZO~SO CH.
Ｃ！３Ｈ，Ｎ （Ｃ！２Ｈ４０Ｈ）２
これら塩基性化合物を含有させる水性媒体としては紀碌
液を調製するのに使用される前記水性媒体と同じものが
使用され、これらの水性媒体の中から使用する塩基性化
合物の種類に応じて適宜選ばれる。C! 3H,N (C!2H40H)2 As the aqueous medium containing these basic compounds, the same aqueous medium as the above-mentioned aqueous medium used to prepare the Kisoku liquid is used, and the aqueous medium used is selected from among these aqueous media. It is appropriately selected depending on the type of basic compound.
又、これら塩基性化合物の使用量としては水性媒体液全
重量に対しｏ、ｉ〜１０重量％好１しくは００１〜５重
量％の範囲が挙げられる。The amount of these basic compounds to be used is in the range of o, i to 10% by weight, preferably 1 to 001 to 5% by weight, based on the total weight of the aqueous medium.
父上記塩基性化合物は単独で使用される他混合して用い
る事もできる。The above basic compounds can be used alone or in combination.
本発明の記録方法によれば、普通紙に記録した場合でも
耐水性の良好な印字物を得ることができる。According to the recording method of the present invention, printed matter with good water resistance can be obtained even when recorded on plain paper.
又、着色剤として使用する色素は色調、耐光性、溶解性
等耐水性以外の諸性質が良好であれば色素そのものの性
質として耐水性が劣っていても本発明方法では十分利用
することが可能となるので極めて有用な方法である。Furthermore, if the pigment used as a coloring agent has good properties other than water resistance, such as color tone, light resistance, solubility, etc., it can be fully used in the method of the present invention even if the pigment itself has poor water resistance. This is an extremely useful method.
実施例
本発明を以下の実施例で更に詳細に説明するが、本発明
はこれらの実施例により限定されるものではない。EXAMPLES The present invention will be explained in more detail with the following Examples, but the present invention is not limited to these Examples.
実施例／
Ｃ０Ｉ、Ｆｏｏｄ Ｂｌａｃｋ−２５部エチレングリコ
ール ２０部水
７Ｉ部上記成分も混合溶解し、Ｃ０
弘よμのメンブランフィルタ−で加圧濾過し、超音波で
脱気処理を行ってインキを調整し念。（Ａインクとする
一エチレングリコール ２部部水
７′ｓ上記成分を、
混合溶解しｌμのメンブランフィルタ−で加圧濾過し超
音波で脱気処理を行ってインクを調整した。（Ｂ−イン
クとする。）得られ九人−インク、Ｂインクを用いてイ
ンクジェットプリンター（ｒｐ−’７コ０： シャープ
株式会社製造）で電子写真用紙に印字した。Example/C0I, Food Black-25 parts ethylene glycol 20 parts water
7I part The above components are also mixed and dissolved, and C0
The ink was carefully adjusted by pressure filtration using Hiroyo μ's membrane filter and degassing using ultrasonic waves. (A ink is one part ethylene glycol, two parts water.
7's the above ingredients,
The ink was prepared by mixing and dissolving, filtering under pressure using a 1μ membrane filter, and degassing with ultrasonic waves. (This is referred to as B-ink.) Using the obtained Kunin ink and B ink, printing was performed on electrophotographic paper using an inkjet printer (RP-'7co0: manufactured by Sharp Corporation).
該プリンターは、／４ノズルを有しており。The printer has a /4 nozzle.
このうち１２ノズルからＡインクを吐出し、その吐出部
分に重なる様にμノズルからＢインクを吐出して印字を
行った。Printing was performed by ejecting A ink from 12 of these nozzles and ejecting B ink from the μ nozzle so as to overlap the ejected portion.
得られた印字物は良好な耐水性を示した。これに対して
Ｂインクを使用しない場合は耐水性が著しく不良であっ
た。The obtained printed matter showed good water resistance. On the other hand, when B ink was not used, the water resistance was extremely poor.
実施例コ
Ａインク Ｃ０１，Ａｃ１ｄ Ｒｅｄ−Ｊｊ ３
部ジエチレングリコール ｌθ部
ｔ１−メチルピロリドン １０部
水 ７７部ＮＨ２７部
エチレングリコール ２０部
水 ７５部実施例１と
同様にしてＡインク、Ｂイ／りを調整し、印字を行った
結果その印字物の耐水性は、良好な結果を得た。Example Co A ink C01, Ac1d Red-Jj 3
Part diethylene glycol lθ part t1-Methylpyrrolidone 10 parts Water 77 parts NH27 parts Ethylene glycol 20 parts Water 75 parts A ink and B ink were adjusted in the same manner as in Example 1, and printing was performed.As a result, the printed matter was water resistant. Good results were obtained.
実施例３〜ｌ≠
実施例１と同様にして、第１表に示す人インク及びＢイ
ンクを夫々調製して印字を行なった。Examples 3 to 1≠ Printing was carried out in the same manner as in Example 1 by preparing human ink and B ink shown in Table 1, respectively.
得られた印字物の耐水性試験を行った結果何れも耐水性
は良好であった。A water resistance test was conducted on the obtained printed matter, and the results showed that all of the printed matter had good water resistance.
なお本実施例における耐水性の評価は、印字直後の印字
物を水中に２部時間浸漬し印字物のにじみ兵舎を目視に
より判断した。The water resistance in this example was evaluated by immersing the printed matter in water for two hours immediately after printing, and visually observing whether the printed matter was smeared.
第１表Table 1
Claims (3)
水溶性染料を含有する記録液を、吐出オリフィスから吐
出させて記録するインクジェット記録方法において、該
記録液の吐出と同時又は前後して塩基性ポリマーを含有
した水性媒体液を被記録材に付着させることを特徴とす
るインクジェット記録方法。(1) In an inkjet recording method in which recording is performed by discharging a recording liquid containing an aqueous medium and a water-soluble dye having a sulfonic acid group as a coloring agent from a discharge orifice, a basic An inkjet recording method characterized by attaching an aqueous medium liquid containing a polymer to a recording material.
体液を各々別個の吐出オリフィスから被記録材上のほぼ
同一部分にほぼ同一の画像を形成するように吐出するこ
とを特徴とする特許請求の範囲第１項記載のインクジェ
ット記録方法。(2) A patent claim characterized in that the recording liquid and the aqueous medium containing a basic polymer are ejected from separate ejection orifices so as to form substantially the same image on substantially the same portion of the recording material. The inkjet recording method according to item 1.
ＸIV〕で表わされる化合物から選ばれることを特徴とす
る特許請求の範囲第１項記載の記録方法。 ▲数式、化学式、表等があります▼…………〔 I 〕 （式中、ｌは１００〜１０００００の数を示す。） ▲数式、化学式、表等があります▼…………〔II〕 （式中、ｍは、１００〜１００００の数を示す。） ▲数式、化学式、表等があります▼…………〔III〕 （式中、ｎは、１００〜１０００００の数を示し、Ｒ＾
１、Ｒ＾２、Ｒ＾３は水酸基で置換されていてもよいア
ルキル基を示し、Ｘはハロゲン原子又は水酸基を示す。 ） −（ＣＨ＿２−ＣＨ＿２−ＮＨ）−＿ｐ………〔IV〕 （式中、ｐは１００〜１０００００の数を示す。） ▲数式、化学式、表等があります▼………〔Ｖ〕 （式中Ｒは水素原子又はメチル基を示し、ｑは１０〜１
０００の数を示す。） ▲数式、化学式、表等があります▼………〔VI〕 （式中、Ｒ＾４は水素原子又はメチル基を示し、ｒは１
０〜１０００の数を示し、Ｘはハロゲン原子又は水酸基
を示し、Ｒ＾５はアルキル基を示す。） ▲数式、化学式、表等があります▼…〔VII〕 （式中、Ｒ＾６、Ｒ＾７は水素原子又はメチル基を示し
、ａ、ｂは１０〜１０００の数を示す。） ▲数式、化学式、表等があります▼………〔VIII〕 （式中Ｒ＾８は水素原子又はメチル基を示し、ｄは１０
〜１００００数を示し、Ｙは−Ｏ−又は−ＣＨ＿２−を
示す。） ▲数式、化学式、表等があります▼………〔IX〕 （式中、ｅは１０〜１０００の数を示す。） ▲数式、化学式、表等があります▼………〔Ｘ〕 （式中、Ｒ＾９はアルキル基を示し、Ｘはハロゲン原子
又は水酸基を示し、ｆは１０〜１０００の数を示す。） ▲数式、化学式、表等があります▼……〔Ｘ I 〕 （式中、Ｒ＾１＾０は水素原子又はメチル基を表わし、
Ｒ＾１＾１は低級アルキレン基を示し、Ｒ＾１＾２、Ｒ
＾１＾３、Ｒ＾１＾４は水酸基で置換されていても良い
アルキル基を示し、ｇは１０〜１０００の数を示し、Ｘ
はハロゲン原子又は水酸基を示す。） ▲数式、化学式、表等があります▼………〔ＸII〕 （式中、Ｒ＾１＾５は水素原子又はメチル基を示し、Ｒ
＾１＾６は低級アルキレン基を示し、Ｒ＾１＾７、Ｒ＾
１＾８は水酸基を置換されていても良いアルキル基を示
し、ｈは１０〜１０００の数を示す。） ▲数式、化学式、表等があります▼………〔ＸIII〕 （式中、Ｒ＾１＾９、Ｒ＾２＾０は水酸基で置換されて
いてもよいアルキル基を示し、Ｒ＾２＾１は水素原子又
はメチル基を示し、ｉは１０〜１０００の数を示す。） ▲数式、化学式、表等があります▼………〔ＸIV〕 （式中、Ｒ＾２＾２、Ｒ＾２＾３はアルキル基を示し、
Ｘはハロゲン原子又は水酸基を示し、ｊは１０００〜１
０００００の数を示す。）(3) The basic polymer has the following general formula [I] to [
The recording method according to claim 1, characterized in that the recording method is selected from compounds represented by [XIV]. ▲There are mathematical formulas, chemical formulas, tables, etc.▼…………[I] (In the formula, l indicates a number from 100 to 100,000.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼…………[II] ( In the formula, m represents a number from 100 to 10,000.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼…………[III] (In the formula, n represents a number from 100 to 100,000, and R^
1, R^2, and R^3 represent an alkyl group which may be substituted with a hydroxyl group, and X represents a halogen atom or a hydroxyl group. ) -(CH_2-CH_2-NH)-_p......[IV] (In the formula, p represents a number from 100 to 100,000.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼......[V] (Formula In the middle, R represents a hydrogen atom or a methyl group, and q is 10 to 1.
Shows the number 000. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼……[VI] (In the formula, R^4 represents a hydrogen atom or a methyl group, and r is 1
It represents a number from 0 to 1000, X represents a halogen atom or a hydroxyl group, and R^5 represents an alkyl group. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼...[VII] (In the formula, R^6 and R^7 represent a hydrogen atom or a methyl group, and a and b represent a number from 10 to 1000.) ▲Mathematical formula , chemical formulas, tables, etc.▼......[VIII] (In the formula, R^8 represents a hydrogen atom or a methyl group, and d is 10
~10000 number is shown, and Y shows -O- or -CH_2-. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼......[IX] (In the formula, e indicates a number from 10 to 1000.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼......[X] (Formula (In the formula, R^9 represents an alkyl group, X represents a halogen atom or a hydroxyl group, and f represents a number from 10 to 1000.) ▲There are numerical formulas, chemical formulas, tables, etc.▼...[X I] (In the formula , R^1^0 represents a hydrogen atom or a methyl group,
R^1^1 represents a lower alkylene group, R^1^2, R
^1^3, R^1^4 represent an alkyl group which may be substituted with a hydroxyl group, g represents a number from 10 to 1000, and X
represents a halogen atom or a hydroxyl group. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼……[XII] (In the formula, R^1^5 represents a hydrogen atom or a methyl group, and R
^1^6 represents a lower alkylene group, R^1^7, R^
1^8 represents an alkyl group which may be substituted with a hydroxyl group, and h represents a number from 10 to 1000. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼......[XIII] (In the formula, R^1^9 and R^2^0 represent an alkyl group that may be substituted with a hydroxyl group, and R^2^ 1 indicates a hydrogen atom or a methyl group, and i indicates a number from 10 to 1000.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼……[XIV] (In the formula, R^2^2, R^2 ^3 represents an alkyl group,
X represents a halogen atom or a hydroxyl group, and j is 1000 to 1
Shows the number 00000. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61206289A JPS6360783A (en) | 1986-09-02 | 1986-09-02 | Ink jet recording method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61206289A JPS6360783A (en) | 1986-09-02 | 1986-09-02 | Ink jet recording method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6360783A true JPS6360783A (en) | 1988-03-16 |
Family
ID=16520840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61206289A Pending JPS6360783A (en) | 1986-09-02 | 1986-09-02 | Ink jet recording method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6360783A (en) |
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| US5792249A (en) * | 1995-01-25 | 1998-08-11 | Canon Kabushiki Kaisha | Liquid composition, ink set, image-forming method and apparatus using the same |
| US5985975A (en) * | 1995-01-31 | 1999-11-16 | Canon Kabushiki Kaisha | Liquid composition, ink set and method and apparatus for image by using the composition and ink set |
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| US6158856A (en) * | 1995-02-13 | 2000-12-12 | Canon Kabushiki Kaisha | Ink-jet recording process, ink-jet recording apparatus and image formed article |
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