JPS6358804B2 - - Google Patents
Info
- Publication number
- JPS6358804B2 JPS6358804B2 JP59077123A JP7712384A JPS6358804B2 JP S6358804 B2 JPS6358804 B2 JP S6358804B2 JP 59077123 A JP59077123 A JP 59077123A JP 7712384 A JP7712384 A JP 7712384A JP S6358804 B2 JPS6358804 B2 JP S6358804B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- integer
- general formula
- ester
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000002537 cosmetic Substances 0.000 claims description 14
- 239000003093 cationic surfactant Substances 0.000 claims description 12
- 238000006386 neutralization reaction Methods 0.000 claims description 12
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 4
- -1 Phosphate ester Chemical class 0.000 description 26
- 150000001413 amino acids Chemical class 0.000 description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 125000005907 alkyl ester group Chemical group 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 150000004665 fatty acids Chemical group 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical class OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 206010044625 Trichorrhexis Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 125000000490 cinnamyl group Chemical group C(C=CC1=CC=CC=C1)* 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- BLCJBICVQSYOIF-UHFFFAOYSA-N 2,2-diaminobutanoic acid Chemical compound CCC(N)(N)C(O)=O BLCJBICVQSYOIF-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- AHLPHDHHMVZTML-BYPYZUCNSA-N L-Ornithine Chemical compound NCCC[C@H](N)C(O)=O AHLPHDHHMVZTML-BYPYZUCNSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 description 1
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 125000005526 alkyl sulfate group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229960003104 ornithine Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940071139 pyrrolidone carboxylate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 125000002072 seryl group Chemical group 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
この発明は、毛髪化粧料組成物に関する。
毛髪は、通常、ヘアークリーム及びヘアーオイ
ル等の動植物油や毛髪自身から分泌される皮脂等
により覆われているが、石ケンや合成洗剤等で洗
髪すると、それらの油脂成分は必要以上に除去さ
れてしまう。そのため、洗髪後の毛髪はなめらか
さが失われ、パサパサした硬い感触となり、櫛通
りが悪くなつて裂毛や枝毛が生じやすくなる。
このような不都合を解消するため、従来から洗
髪後の毛髪処理剤として各種の毛髪化粧料が開発
され、使用されている。これら毛髪化粧料は、ジ
アルキルジメチルアンモニウムクロライドやアル
キルトリメチルアンモニウムクロライドに代表さ
れる第4級アンモニウム塩を主要有効成分とする
ものである。このようなアンモニウム塩には水難
溶性のものと水易溶性のものとがあり、従つてそ
れに対応して、毛髪化粧料組成物には「すすぐタ
イプ」のものと「すすがないタイプ」のものとが
あつて、それぞれその使用形態を異ならしめてい
る。
洗髪後等の毛髪のキシミやもつれを防ぎ、乾い
た状態の仕上り感をよくするためには、上記アン
モニウム塩が毛髪に吸着されていなければならな
い。しかし、従来の毛髪化粧料組成物は、どの使
用形態によつても上記アンモニウム塩の離脱性や
吸着性に問題があり、十分満足すべきものではな
かつた。特に、毛髪になめらかさ、及び柔らかさ
を与える能力において未だ不十分であつた。
さらにまた、本発明者らの調査によると、最近
の消費者は、乳濁状の製品よりも透明の製品を好
む傾向にある。これは、透明の製品の方が、乳濁
状の製品に比べ、異物等の混入の有無がよくわか
るので安心して商品を購買し、使用できるからで
ある。
この発明の目的は、洗髪後の毛髪に優れた風合
いを与え、かつ液安定性の優れた毛髪化粧料組成
物を提供することである。
すなわち、この発明は、下記一般式[]で表
わされるリン酸エステルの部分中和物であつてそ
の中和率が5ないし95%のもの、及びカチオン界
面活性剤を含む毛髪化粧料組成物を提供する。
一般式[]
(ただし、R1は炭素数1〜6のアルキル基又は
グリセリル基、nは0ないし100の整数、Xは1
ないし3の整数、Yは0ないし2の整数を示し、
かつX+Y=3である)
さらにまた、この発明は、上記一般式[]で
表わされるリン酸エステルの部分中和物であつて
その中和率が5ないし95%のもの、カチオン界面
活性剤、及びHLBが10以上のノニオン界面活性
剤を含む透明な毛髪化粧料組成物を提供する。
この発明の毛髪化粧料組成物の第1の必須成分
は上記一般式[]で表わされるリン酸エステル
の有機若しくは無機塩基性物質によるその部分中
和物である。一般式[]中、R1は炭素数1〜
6のアルキル基又はグリセリル基である。nは0
ないし100、好ましくは5ないし60の整数、Xは
1、2、又は3、Yは0、1又は2を示し、かつ
X+Y=3である。また、このリン酸エステルの
部分中和に用いられる塩基性物質の好ましい例と
して、モノエタノールアミン、ジエタノールアミ
ン、トリエタノールアミン、トリイソプロパノー
ルアミン、水酸化ナトリウム、水酸化カリウム、
アンモニア、塩基性アミノ酸等の有機又は無機の
塩基を挙げることができる。
上記リン酸エステルの部分中和物の中和率は5
ないし95%であり、好ましくは20ないし80%であ
る。中和率が5%未満であるとリン酸エステルの
アニオン性が弱いため、カチオン界面活性剤との
結合が弱くなり、毛髪への吸着量が減少して本発
明の効果を得ることができない。また、中和率が
95%を超えるとカチオン界面活性剤との結合が強
くなるため、毛髪への吸着力が強くなりすぎてし
まい、毛髪がベタついて、むしろ本発明の効果を
劣化させてしまう。一方、中和率がこの発明の範
囲内にあると、リン酸エステルが油分としての性
質のものから、界面活性能をもつたアニオン界面
活性剤となり、カチオン界面活性剤と複合体を形
成し、それが毛髪に適度な強さで吸着するため、
本発明の効果を得ることができる。なお、リン酸
エステルの部分中和物の中和率は次式により容易
に求めることができる。
リン酸エステル中和率=リン酸エステル配
合組成物の酸価/リン酸エステル酸価xリン酸エステル
配合量×100
上記リン酸エステルの部分中和物の配合量は、
毛髪化粧料組成物全量に対し0.1ないし10重量%
が好ましい。0.1重量%未満であるとこの発明の
効果があまり得られず、10重量%を超えると仕上
りがべたつく傾向にある。
この発明の第2の必須成分はカチオン界面活性
剤である。好ましいカチオン界面活性剤の例とし
て下記一般式[]で表わされる第4級アンモニ
ウム塩とアミノ酸系カチオン界面活性剤を挙げる
ことができる。
一般式[]
式中、R2は炭素数10ないし24のアルキル基、
炭素数10ないし24のヒドロキシアルキル基、又は
R6(OCH2CH2)1〜10(ただし、R6は炭素数10ない
し24のアルキル基又は炭素数10ないし24のヒドロ
キシアルキル基)、R3は炭素数10ないし24のアル
キル基又は炭素数10ないし24のヒドロキシアルキ
ル基又はR6(OCH2CH2)1〜10(ただし、Rは上記の
ものと同じ)、炭素数1ないし3のアルキル基、
The present invention relates to a hair cosmetic composition. Hair is normally covered with animal and vegetable oils such as hair creams and hair oils, as well as sebum secreted from the hair itself, but when hair is washed with soap or synthetic detergents, these oils and fats are removed more than necessary. I end up. As a result, the hair after washing loses its smoothness and feels dry and hard, making it difficult to comb and causing split ends and split ends. In order to eliminate such inconveniences, various hair cosmetics have been developed and used as hair treatment agents after hair washing. These hair cosmetics contain quaternary ammonium salts such as dialkyldimethylammonium chloride and alkyltrimethylammonium chloride as the main active ingredient. There are two types of ammonium salts: those that are poorly soluble in water and those that are easily soluble in water.Therefore, correspondingly, hair cosmetic compositions include ``rinsing type'' and ``non-rinsing type''. However, each type has a different usage pattern. In order to prevent hair from squeaking and tangling after washing, etc., and to improve the finish when dry, the above ammonium salt must be adsorbed to the hair. However, conventional hair cosmetic compositions have problems in the releasability and adsorption of the ammonium salts, regardless of the form of use, and are not fully satisfactory. In particular, the ability to impart smoothness and softness to hair was still insufficient. Furthermore, according to a survey conducted by the present inventors, consumers these days tend to prefer transparent products over emulsion-like products. This is because transparent products allow you to purchase and use the product with peace of mind, as it is easier to see if there are any foreign substances mixed in, compared to emulsion-like products. An object of the present invention is to provide a hair cosmetic composition that gives an excellent texture to hair after washing and has excellent liquid stability. That is, the present invention provides a hair cosmetic composition comprising a partially neutralized product of a phosphoric acid ester represented by the following general formula [] with a neutralization rate of 5 to 95%, and a cationic surfactant. provide. General formula [] (However, R 1 is an alkyl group having 1 to 6 carbon atoms or a glyceryl group, n is an integer from 0 to 100, and X is 1
an integer from 0 to 3, Y represents an integer from 0 to 2,
and X+Y=3) Furthermore, the present invention also provides a partially neutralized product of the phosphoric acid ester represented by the above general formula [], which has a neutralization rate of 5 to 95%, a cationic surfactant, and a nonionic surfactant with an HLB of 10 or more. The first essential component of the hair cosmetic composition of the present invention is a partially neutralized product of a phosphoric acid ester represented by the above general formula [] with an organic or inorganic basic substance. In the general formula [ ], R 1 has 1 to 1 carbon atoms
6 alkyl group or glyceryl group. n is 0
an integer from 100 to 100, preferably from 5 to 60; X represents 1, 2, or 3; Y represents 0, 1, or 2; and X+Y=3. Preferred examples of basic substances used for partial neutralization of this phosphoric acid ester include monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, sodium hydroxide, potassium hydroxide,
Examples include organic or inorganic bases such as ammonia and basic amino acids. The neutralization rate of the partially neutralized product of the above phosphoric acid ester is 5
95%, preferably 20 to 80%. If the neutralization rate is less than 5%, the anionic nature of the phosphoric acid ester is weak, so the bond with the cationic surfactant becomes weak, and the amount of adsorption to hair decreases, making it impossible to obtain the effects of the present invention. In addition, the neutralization rate
If it exceeds 95%, the bond with the cationic surfactant becomes strong, and the adsorption power to the hair becomes too strong, making the hair sticky and rather deteriorating the effect of the present invention. On the other hand, when the neutralization rate is within the range of this invention, the phosphoric acid ester changes from having oily properties to an anionic surfactant with surfactant ability and forms a complex with a cationic surfactant. Because it adsorbs to the hair with moderate strength,
The effects of the present invention can be obtained. Note that the neutralization rate of the partially neutralized product of phosphoric acid ester can be easily determined using the following formula. Phosphate ester neutralization rate = acid value of phosphate ester blended composition / phosphate ester acid value x phosphate ester blend amount x 100 The blend amount of the partially neutralized phosphate ester is:
0.1 to 10% by weight based on the total amount of hair cosmetic composition
is preferred. If the amount is less than 0.1% by weight, the effect of this invention will not be obtained much, and if it exceeds 10% by weight, the finish will tend to be sticky. The second essential component of this invention is a cationic surfactant. Examples of preferred cationic surfactants include quaternary ammonium salts represented by the following general formula [] and amino acid-based cationic surfactants. General formula [] In the formula, R 2 is an alkyl group having 10 to 24 carbon atoms,
a hydroxyalkyl group having 10 to 24 carbon atoms, or
R 6 (OCH 2 CH 2 ) 1 to 10 (wherein R 6 is an alkyl group having 10 to 24 carbon atoms or a hydroxyalkyl group having 10 to 24 carbon atoms), R 3 is an alkyl group having 10 to 24 carbon atoms or carbon A hydroxyalkyl group having 10 to 24 carbon atoms or R 6 (OCH 2 CH 2 ) 1 to 10 (where R is the same as above), an alkyl group having 1 to 3 carbon atoms,
【式】
(ただしR7は水素又はメチル基)、ベンジル基、
又はシンナミル基、R4及びR5は互いに独立に炭
素数1ないし3のアルキル基、
[Formula] (where R 7 is hydrogen or methyl group), benzyl group,
or a cinnamyl group, R 4 and R 5 are each independently an alkyl group having 1 to 3 carbon atoms,
【式】
(ただしR7は上記のものと同じ)、ベンジル基、
又はシンナミル基、X1はハロゲン原子又は炭素
数1若しくは2のアルキル硫酸基を示す。一般式
[]で表わされる代表的な第4級アンモニウム
塩として、ステアリルトリメチルアンモニウムク
ロライド、ステアリルジメチルベンジルアンモニ
ウムクロライドを挙げることができる。
アミノ酸系カチオン界面活性剤の代表例とし
て、モノN−長鎖アシル塩基性アミノ酸低級アル
キルエステル塩を挙げることができる。
モノN−長鎖塩基性アミノ酸低級アルキルエス
テル塩の塩基性アミノ酸成分は、オルニチン、リ
ジン、アルギニン等の天然のものの他、α,γ−
ジアミノ酪酸のような合成アミノ酸も同様に用い
ることができ、これらは光学活性体又はラセミ体
のいずれであてもよい。
モノN−長鎖塩基性アミノ酸低級アルキルエス
テル塩のアシル基は、炭素数8ないし22の飽和又
は不飽和の天然又は合成脂肪酸残基であり、例え
ばラウロイル基、ミリストイル基、ステアロイル
基などの単一脂肪酸残基の他、ヤシ油脂肪酸残
基、牛脂脂肪酸残基などの天然系の混合脂肪酸残
基であつてもよい。
モノN−長鎖塩基性アミノ酸低級アルキルエス
テル塩の低級アルキルエステル成分としては、メ
チルエステル、エチルエステル、プロピオエステ
ル、ブチルエステル、ペンチルエステル、ヘキシ
ルエステル、ヘプチルエステル、オクチルエステ
ルが適当である。
また、モノN−長鎖アシル塩基性アミノ酸エス
テルの塩としては、例えば塩酸塩、硫酸塩のよう
な無機酸塩、又は例えば酢酸塩、酒石酸塩、クエ
ン酸塩、p−トルエンスルホン酸塩、脂肪酸塩、
酸性アミノ酸塩、ピログルタミン酸塩、ピロリド
ンカルボン酸塩のような有機酸塩が用いられ、こ
れらの中でも酸性アミノ酸塩、塩酸塩及びL又は
DL−ピロリドンカルボン酸塩が好ましい。
カチオン界面活性剤の配合量は、この発明の毛
髪化粧料組成物全量に対し、0.1ないし5重量%
であることが好ましい。0.1重量%未満では、こ
の発明の効果があまり得られず、5重量%を超え
ると、仕上りが重くなるばかりでなく、液安定性
が著しく劣化するので好ましくない。
上述したこの発明の毛髪化粧料組成物に、
HLBが10以上のノニオン界面活性剤を配合する
と組成物が透明になる。好ましいノニオン界面活
性剤は下記一般式[]で表わされるものであ
る。
一般式[]
R8O(CH2CH2O)nH
式中、R8は炭素数8ないし24の直鎖又は分岐
鎖状アルキル基又は炭素数4ないし20のアルキル
フエニル基、mはHLBが10以上となる条件を満
たし得るエチレンオキサイド付加モル数である。
一般式[]で表わされるノニオン界面活性剤の
好ましい例として、ポリオキシエチレン(10モル
以上)オレイルエーテル、ポリオキシエチレン
(10モル以上)セチルエーテル、ポリオキシエチ
レン(10モル以上)−2−ヘキシルデシルエーテ
ル、ポリオキシエチレン(15モル以上)−2−デ
シルペンタデシルエーテル、ポリオキシエチレン
(11モル以上)ノニルフエニルエーテル、ポリオ
キシエチレン(8モル以上)オクチルフエニルエ
ーテル、ポリオキシエチレン(7モル以上)ラウ
リルエーテル等が挙げられる。
ノニオン界面活性剤の配合量は、この発明の毛
髪化粧料組成物全量に対し、0.5ないし10重量%
であることが好ましい。0.5重量%未満では低温
での液安定性を満足させることが困難となり、10
重量%を超えると、仕上り性が劣化する傾向にあ
る。
この発明の毛髪化粧料組成物には、上述した必
須成分の他に下記の任意成分がこの発明の効果に
影響のない範囲で配合されていてもよい。すなわ
ち、任意成分としては流動パラフイン、ワセリ
ン、固形パラフイン、スクワラン及びオレフイン
オリゴマー等の炭化水素;イソプロピルミリステ
ート、イソプロピルパルミテート、ステアリルス
テアレート、ミリスチン酸オクチルドデシル、オ
レイン酸オクチルドデシル及び2−エチルヘキサ
ン酸トリグリセライド等のエステル;N−(2−
ヒドロキシエチル)−N−[ビス(2−カルボキシ
エチル)アミノエチル]ラウリルアマイドジナト
リウム塩、2−ココイル−N−カルボキシメチル
−N−ヒドロキシエチルイミダゾリウムベタイン
等の両性界面活性剤;高級アルコールサルフエー
ト、アルコールエーテルサルフエート、α−オレ
フインスルホネート等のアニオン界面活性剤;ラ
ウリルアルコール、セチルアルコール、ステアリ
ルアルコール、ベヘニルアルコール等の高級アル
コール;パルミチン酸、ステアリン酸、ベヘニン
酸等の高級脂肪酸;エチレングリコーール、プロ
ピレングリコール、1,3−ブチレングリコー
ル、グリセリン及びソルビトール等の保湿剤;及
びエタノール溶剤、防腐剤、PH調整剤、養毛料、
紫外線吸収剤、酸化防止剤、安定化剤、香料等の
少量成分である。
この発明の毛髪化粧料組成物は、ヘアーリンス
剤、ヘアコンデイシヨナー、ヘアローシヨン等の
各種用途に利用することができる。
次に本発明の実施例と比較例とを示し、本発明
の効果をより具体的に説明する。なお、各例の説
明に先立つて、試験法について説明する。
仕上り後の風合い(なめらかさ、柔らかさ)
シヤンプー処理された毛束(5g、20cm)に試
料0.5gを塗布し、手で均一に伸ばした後、十分
にすすぎ、25℃、65%RHの雰囲気中で乾燥させ
た。乾燥後、20名のパネラーにより官能評価し
た。評価基準は10重量%のステアリルトリメチル
アンモニウムクロライド、3重量%のセチルアル
コール、10重量%のプロピレングリコール及び水
(残部)から成る試料により得た評価を基準とし
た5段階評価である。
◎:良い
〇:やや良い
△:同等
×:やや劣る
××:劣る
液透明性(低温安定性)
試料を0℃の恒温槽に1カ月間保存した後の液
透明性を視覚により下記の基準で判定した。
◎:均一に透明
〇:微濁く
△:白濁
×:分離
第1表に示す10種のヘアーリンス組成物を調製
し、それらの性能を評価した。なお、表中、配合
量はいずれも重量%で示されている。[Formula] (R 7 is the same as above), benzyl group,
or a cinnamyl group; X 1 represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms; Typical quaternary ammonium salts represented by the general formula [] include stearyltrimethylammonium chloride and stearyldimethylbenzylammonium chloride. A typical example of an amino acid-based cationic surfactant is a mono-N-long chain acyl basic amino acid lower alkyl ester salt. The basic amino acid components of the mono N-long chain basic amino acid lower alkyl ester salt include natural amino acids such as ornithine, lysine, and arginine, as well as α, γ-
Synthetic amino acids such as diaminobutyric acid can be used as well, and these may be in either optically active or racemic form. The acyl group of the mono N-long chain basic amino acid lower alkyl ester salt is a saturated or unsaturated natural or synthetic fatty acid residue having 8 to 22 carbon atoms, such as a mono-N-long chain basic amino acid lower alkyl ester salt, such as a lauroyl group, myristoyl group, stearoyl group, etc. In addition to fatty acid residues, it may be natural mixed fatty acid residues such as coconut oil fatty acid residues and beef tallow fatty acid residues. As the lower alkyl ester component of the mono N-long chain basic amino acid lower alkyl ester salt, methyl ester, ethyl ester, propio ester, butyl ester, pentyl ester, hexyl ester, heptyl ester, and octyl ester are suitable. Salts of mono-N-long chain acyl basic amino acid esters include inorganic acid salts such as hydrochloride, sulfate, acetate, tartrate, citrate, p-toluenesulfonate, fatty acid salt, etc. salt,
Organic acid salts such as acidic amino acid salts, pyroglutamic acid salts, and pyrrolidone carboxylic acid salts are used, and among these, acidic amino acid salts, hydrochloric acid salts, and L or
DL-pyrrolidone carboxylate is preferred. The blending amount of the cationic surfactant is 0.1 to 5% by weight based on the total amount of the hair cosmetic composition of the present invention.
It is preferable that If it is less than 0.1% by weight, the effect of the present invention will not be obtained much, and if it exceeds 5% by weight, not only will the finish become heavy, but also the liquid stability will deteriorate significantly, which is not preferable. The hair cosmetic composition of this invention described above,
When a nonionic surfactant with an HLB of 10 or more is blended, the composition becomes transparent. Preferred nonionic surfactants are those represented by the following general formula []. General formula [] R 8 O(CH 2 CH 2 O) n H In the formula, R 8 is a straight or branched alkyl group having 8 to 24 carbon atoms or an alkylphenyl group having 4 to 20 carbon atoms, and m is This is the number of moles of ethylene oxide added that can satisfy the condition that HLB is 10 or more.
Preferred examples of the nonionic surfactant represented by the general formula [] include polyoxyethylene (10 moles or more) oleyl ether, polyoxyethylene (10 moles or more) cetyl ether, polyoxyethylene (10 moles or more)-2-hexyl Decyl ether, polyoxyethylene (15 moles or more) -2-decylpentadecyl ether, polyoxyethylene (11 moles or more) nonylphenyl ether, polyoxyethylene (8 moles or more) octyl phenyl ether, polyoxyethylene (7 moles or more) mole or more) lauryl ether, etc. The blending amount of the nonionic surfactant is 0.5 to 10% by weight based on the total amount of the hair cosmetic composition of the present invention.
It is preferable that If it is less than 0.5% by weight, it will be difficult to satisfy liquid stability at low temperatures, and 10
If it exceeds % by weight, the finish tends to deteriorate. In addition to the above-mentioned essential components, the hair cosmetic composition of the present invention may contain the following optional components within a range that does not affect the effects of the present invention. That is, optional components include hydrocarbons such as liquid paraffin, vaseline, solid paraffin, squalane and olefin oligomer; isopropyl myristate, isopropyl palmitate, stearyl stearate, octyldodecyl myristate, octyldodecyl oleate, and 2-ethylhexanoic acid. Ester such as triglyceride; N-(2-
Ampholytic surfactants such as (hydroxyethyl)-N-[bis(2-carboxyethyl)aminoethyl]laurylamide disodium salt, 2-cocoyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine; higher alcohol sulfates , alcohol ether sulfate, α-olefin sulfonate, etc.; higher alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol; higher fatty acids such as palmitic acid, stearic acid, behenic acid; ethylene glycol, Humectants such as propylene glycol, 1,3-butylene glycol, glycerin and sorbitol; and ethanol solvents, preservatives, PH regulators, hair nourishing agents,
These are small amounts of ingredients such as ultraviolet absorbers, antioxidants, stabilizers, and fragrances. The hair cosmetic composition of the present invention can be used in various applications such as hair rinses, hair conditioners, and hair lotions. Next, Examples and Comparative Examples of the present invention will be shown to explain the effects of the present invention more specifically. Before explaining each example, the test method will be explained. Texture after finishing (smoothness, softness) Apply 0.5 g of the sample to a shampooed hair bundle (5 g, 20 cm), spread it evenly by hand, rinse thoroughly, and store in an atmosphere of 25°C and 65% RH. dried inside. After drying, sensory evaluation was performed by 20 panelists. The evaluation criteria is a five-level evaluation based on the evaluation obtained with a sample consisting of 10% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (the balance). ◎: Good 〇: Slightly good △: Same ×: Slightly inferior XX: Inferior liquid transparency (low temperature stability) After storing the sample in a constant temperature bath at 0°C for one month, visually check the liquid transparency according to the following criteria. It was judged. ◎: Uniformly transparent 〇: Slightly cloudy △: Cloudy ×: Separated Ten types of hair rinse compositions shown in Table 1 were prepared and their performance was evaluated. In addition, in the table, all compounding amounts are shown in weight%.
【表】【table】
【表】
第1表から明らかなように比較例1及び2は本
発明の必須成分のうち1つしか含有しておらず、
また、比較例3及び4は本発明の必須成分である
リン酸エステルの中和率が本発明の範囲外であ
り、更に比較例5は本発明の必須成分であるリン
酸エステルのアルキルエーテル部分の炭素数が本
発明の範囲外であるため、本発明の目的を達成で
きない。これに対し、実施例1ないし5は優れた
性能を示し、本発明の目的を達成している。
第2表に示す10種のヘアーリンス組成物を調製
し、それらの性能を評価した。結果を同表に示
す。同表より、HLBが10以上のノニオン界面活
性剤を加えると組成物が透明になることがわか
る。[Table] As is clear from Table 1, Comparative Examples 1 and 2 contained only one of the essential components of the present invention,
In addition, in Comparative Examples 3 and 4, the neutralization rate of the phosphoric acid ester, which is an essential component of the present invention, is outside the range of the present invention, and furthermore, in Comparative Example 5, the alkyl ether moiety of the phosphoric acid ester, which is an essential component of the present invention, is outside the range of the present invention. Since the number of carbon atoms is outside the scope of the present invention, the object of the present invention cannot be achieved. On the other hand, Examples 1 to 5 exhibited excellent performance and achieved the object of the present invention. Ten types of hair rinse compositions shown in Table 2 were prepared and their performance was evaluated. The results are shown in the same table. From the same table, it can be seen that when a nonionic surfactant with an HLB of 10 or more is added, the composition becomes transparent.
【表】
実施例 7
第3表に示すヘアーブラツシング剤組成物を調
製し、その性能を評価した。[Table] Example 7 Hair brushing agent compositions shown in Table 3 were prepared and their performance was evaluated.
【表】【table】
【表】【table】
【表】
| ‖
CH3 O
セリル基、 mは60、 モノエステルとジエ
ステルの比率は40/60)
このヘアブラツシング剤組成物は優れた性能
(なめらかさ、柔らかさ)を示した。
実施例 8
第4表に示すヘアーブラツシング剤組成物を調
製し、その性能を評価した。[Table] | ‖
CH3O
Seryl group, m is 60, monoester to diester ratio is 40/60)
This hair brushing agent composition showed excellent performance (smoothness, softness). Example 8 Hair brushing agent compositions shown in Table 4 were prepared and their performance was evaluated.
【表】
このヘアブラツシング剤組成物は優れた性能
(なめらかさ、柔らかさ)を示した。
実施例 9
第5表に示す透明ヘアートリートメント組成物
を調整し、その性能を評価した。[Table] This hair brushing agent composition showed excellent performance (smoothness, softness). Example 9 Transparent hair treatment compositions shown in Table 5 were prepared and their performance evaluated.
【表】
このヘアートリートメント組成物は優れた性能
(なめらかさ、柔らかさ)及び透明安定性を示し
た。Table: This hair treatment composition showed excellent performance (smoothness, softness) and transparency stability.
Claims (1)
ルの部分中和物であつてその中和率が5ないし95
%のもの、及びカチオン界面活性剤を含む毛髪化
粧料組成物。 一般式[] (ただし、R1は炭素数1〜6のアルキル基又は
グリセリル基、nは0ないし100の整数、Xは1
ないし3の整数、Yは0ないし2の整数を示し、
かつX+Y=3である。) 2 下記一般式[]で表わされるリン酸エステ
ルの部分中和物であつてその中和率が5ないし95
%のもの、カチオン界面活性剤、及びHLBが10
以上のノニオン界面活性剤を含む毛髪化粧料組成
物。 一般式[] (ただし、R1は炭素数1〜6のアルキル基又は
グリセリル基、nは0ないし100の整数、Xは1
ないし3の整数、Yは0ないし2の整数を示し、
かつX+Y=3である。)[Scope of Claims] 1. A partially neutralized product of a phosphoric acid ester represented by the following general formula [], which has a neutralization rate of 5 to 95.
%, and a hair cosmetic composition containing a cationic surfactant. General formula [] (However, R 1 is an alkyl group having 1 to 6 carbon atoms or a glyceryl group, n is an integer from 0 to 100, and X is 1
an integer from 0 to 3, Y represents an integer from 0 to 2,
And X+Y=3. ) 2 A partially neutralized product of a phosphoric acid ester represented by the following general formula [ ], with a neutralization rate of 5 to 95
%, cationic surfactant, and HLB 10
A hair cosmetic composition containing the above nonionic surfactant. General formula [] (However, R 1 is an alkyl group having 1 to 6 carbon atoms or a glyceryl group, n is an integer from 0 to 100, and X is 1
an integer from 0 to 3, Y represents an integer from 0 to 2,
And X+Y=3. )
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7712384A JPS60222407A (en) | 1984-04-17 | 1984-04-17 | Hair cosmetic composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7712384A JPS60222407A (en) | 1984-04-17 | 1984-04-17 | Hair cosmetic composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60222407A JPS60222407A (en) | 1985-11-07 |
JPS6358804B2 true JPS6358804B2 (en) | 1988-11-17 |
Family
ID=13625014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7712384A Granted JPS60222407A (en) | 1984-04-17 | 1984-04-17 | Hair cosmetic composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60222407A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55120507A (en) * | 1979-03-12 | 1980-09-17 | Lion Corp | Hair rinse composition |
JPS56110608A (en) * | 1980-02-05 | 1981-09-01 | Kao Corp | Hair rinse agent composition |
-
1984
- 1984-04-17 JP JP7712384A patent/JPS60222407A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55120507A (en) * | 1979-03-12 | 1980-09-17 | Lion Corp | Hair rinse composition |
JPS56110608A (en) * | 1980-02-05 | 1981-09-01 | Kao Corp | Hair rinse agent composition |
Also Published As
Publication number | Publication date |
---|---|
JPS60222407A (en) | 1985-11-07 |
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