JPS6354241A - Amorphous metal reinforced composite wire rod - Google Patents
Amorphous metal reinforced composite wire rodInfo
- Publication number
- JPS6354241A JPS6354241A JP61198541A JP19854186A JPS6354241A JP S6354241 A JPS6354241 A JP S6354241A JP 61198541 A JP61198541 A JP 61198541A JP 19854186 A JP19854186 A JP 19854186A JP S6354241 A JPS6354241 A JP S6354241A
- Authority
- JP
- Japan
- Prior art keywords
- amorphous metal
- reinforced composite
- composite wire
- wire
- metal reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005300 metallic glass Substances 0.000 title claims description 24
- 239000002131 composite material Substances 0.000 title claims description 17
- 239000000835 fiber Substances 0.000 claims description 21
- 239000011888 foil Substances 0.000 claims description 20
- 239000002861 polymer material Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 239000011162 core material Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- 239000000057 synthetic resin Substances 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 229920000620 organic polymer Polymers 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920005613 synthetic organic polymer Polymers 0.000 claims description 3
- 229920001875 Ebonite Polymers 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 239000004809 Teflon Substances 0.000 claims description 2
- 229920006362 Teflon® Polymers 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000012779 reinforcing material Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229920000271 Kevlar® Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000004761 kevlar Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000000386 athletic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000007578 melt-quenching technique Methods 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はアモルファス金属の箔線又は繊維を合成樹脂あ
るいは有機高分子材と複合化することにより種々の分野
において補強材として使用し得るようにしたアモルファ
ス金属強化複合線材に関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention is capable of being used as a reinforcing material in various fields by compositing amorphous metal foil wires or fibers with synthetic resins or organic polymer materials. The present invention relates to an amorphous metal reinforced composite wire rod.
アモルファス金属の箔線あるいは繊維を合成樹脂あるい
は有機高分子材と複合化することにより、引張り強度の
みならずねじりに対しても強い性質を付与することがで
きるのでこれにより強化繊物、運動用具、レジャー用具
、光通信ケーブル用テンションメンバー線、その他補強
材などに有利に用いることができる。なお、ここでいう
ｆｆ３線とは幅が比較的狭い（約５ｎ以下）が厚みに比
べて充分大きなテープ状の材料を云う。By combining amorphous metal foil wires or fibers with synthetic resins or organic polymer materials, it is possible to impart strong properties not only in tensile strength but also in torsion. It can be advantageously used for leisure equipment, tension member wires for optical communication cables, and other reinforcing materials. Note that the ff3 line here refers to a tape-shaped material that is relatively narrow in width (approximately 5 nm or less) but is sufficiently large compared to its thickness.
（従来の技術）
従来、引張り強度の大きな線材が各種補強材として使用
されてきた。金属では、ピアノ線、ステンレス線、タン
グステン線、モリブデン線など、高分子材としては、ケ
ブラー繊維や炭素繊維などが代表的である。また近年ア
モルファス金属繊維が登場し、ピアノ線を凌ぐ高抗張力
が実用的に注目されるようになった。(Prior Art) Conventionally, wire rods with high tensile strength have been used as various reinforcing materials. Typical metals include piano wire, stainless steel wire, tungsten wire, and molybdenum wire, and typical polymer materials include Kevlar fiber and carbon fiber. In recent years, amorphous metal fibers have appeared, and their high tensile strength, which exceeds that of piano wire, has attracted attention for practical purposes.
アモルファス金属のこのような性質は原子の配列に規則
性がないことに起因するものである。This property of amorphous metals is due to the lack of regularity in the arrangement of atoms.
アモルファス金属は気相、液相、固相それぞれから作製
可能であるが、液相すなわち金属・合金の溶湯から急冷
してつくる方法が生産性および経済性の面から有利であ
る。Although amorphous metals can be produced from the gas phase, liquid phase, or solid phase, a method in which they are produced from the liquid phase, that is, by rapidly cooling a molten metal or alloy, is advantageous in terms of productivity and economy.
アモルファス金属は上述したように長軸方向の張力に対
しては、従来材を超える強さを有するが、ねじり力に対
して弱い欠点がある。この欠点のためアモルファス金属
の繊維（又は箔線）を織ったり、編んだりする加工工程
で破断が起りやすく、作業性を著しく低下させるほか、
製品の機械的性質を劣化させ、用途が制限されていた。As mentioned above, amorphous metal has strength exceeding conventional materials against tension in the longitudinal direction, but has the drawback of being weak against torsional force. Due to this drawback, amorphous metal fibers (or foil wires) are easily broken during weaving or knitting processes, which significantly reduces workability.
It deteriorates the mechanical properties of the product, limiting its use.
（発明が解決しようとする問題点）
アモルファス金属は上述したように長手方向の引張りに
は強いが、ねじりに弱い欠点をもつ。本発明はこの欠点
を改善することにより、アモルファス金属本来の性質で
ある高い引張り強度をもち、加工工程における作業性、
生産性の優れた新規な材料を提供することにある。(Problems to be Solved by the Invention) As mentioned above, amorphous metals are strong against tension in the longitudinal direction, but have the disadvantage of being weak against twisting. By improving this drawback, the present invention has high tensile strength, which is an inherent property of amorphous metal, and improves workability in the processing process.
Our goal is to provide new materials with excellent productivity.
（問題点を解決するための手段）
本発明は複数のアモルファス金属箔線又は繊維を芯材と
し、合成樹脂あるいは有機高分子材で被覆してなること
を特徴とするものである。(Means for Solving the Problems) The present invention is characterized in that a plurality of amorphous metal foil wires or fibers are used as a core material and covered with a synthetic resin or an organic polymer material.
アモルファス金属の箔線又は繊維は一般に板厚が薄い（
２０〜３０μ１１）ので単独で強度部材として用いられ
ることは少ない。板厚を大きくすることはできるが、板
厚の増大とともに脆化の傾向を示すので単に板厚を大き
くすることによって強度部材どしての要求特性を改善す
ることはできない。Amorphous metal foil wires or fibers are generally thin (
20 to 30μ11), so it is rarely used alone as a strength member. Although it is possible to increase the plate thickness, the properties required for a strength member cannot be improved simply by increasing the plate thickness, as the plate tends to become brittle as the plate thickness increases.
本発明者はアモルファス金属箔線又は繊維を２本以上積
層し、それを樹脂あるいは有機高分子材で被覆すること
によって、従来の単線では得られない強い引張り強度を
もち、かつねじり力に対する耐性の大きい新規な強度部
材が得られることを見出した。The present inventor has discovered that by laminating two or more amorphous metal foil wires or fibers and coating them with resin or organic polymer material, the present inventors can obtain strong tensile strength that cannot be obtained with conventional single wires and have high resistance to torsional force. It has been found that a new high strength member can be obtained.
薄い箔線あるいは偏平な繊維状のアモルファス金属を複
数本積層するとき、ねじりに対する破断までの耐力（破
断トルク）は単に単線の耐力の積層本数倍ではないこと
を本発明者らは実験的に見い出した。The present inventors have experimentally demonstrated that when laminating multiple thin foil wires or flat fibrous amorphous metals, the torsional strength (rupture torque) until rupture is not simply the strength of a single wire multiplied by the number of laminated wires. I found it.
第１表にアモルファス金属箔線について積層枚数と破断
するトルクの大きさの実験結果を示した。Table 1 shows the experimental results regarding the number of laminated sheets and the magnitude of breaking torque for amorphous metal foil wires.
サンプルの組成はＦｅｙＪ＋ｚＣａＣｒｅ （ａｔｅ）
で幅は０．６ｍｍ、２．５ｍおよび板厚はそれぞれ１９
μｍ、２４μｍの２種類である。The composition of the sample is FeyJ+zCaCre (ate)
The width is 0.6mm, 2.5m and the plate thickness is 19.
There are two types: μm and 24 μm.
第 １ 表
なお測定のゲージ長さく１０ｃｍ）、張力は一定に保持
した。第１表の測定は被覆なしの条件で行なった。理由
は破断が生じたことを目視するためであるが、結果は被
覆材に対しても同一傾向を示した。即ち、積層枚数を増
すほど箔線−本当りの破断トルクは増大し、単線で用い
るより有利であることを示している。(Table 1) The gauge length of the measurement was 10 cm), and the tension was kept constant. The measurements in Table 1 were carried out under uncoated conditions. The reason for this was to visually confirm that a break had occurred, but the results showed the same tendency for the covering material. That is, as the number of laminated sheets increases, the breaking torque of the foil wire-to-strand increases, indicating that it is more advantageous than using a single wire.
本発明で芯材として用いられるアモルファス箔線の寸法
は厚さが１０μｍ〜７０μｍ１幅が０．１ｎ〜５龍とす
る。厚さが１０μｍより薄いとビンホールの形成やエツ
ジの一様性不良が生じ機械的に弱くなる。また７０μｌ
を越えると脆化によりねじり耐性が低下するだけでなく
折損なども生ずるので好ましくない。The dimensions of the amorphous foil wire used as the core material in the present invention are 10 μm to 70 μm in thickness and 0.1 nm to 5 μm in width. If the thickness is less than 10 μm, the formation of via holes and poor edge uniformity occur, resulting in mechanical weakness. Also 70μl
Exceeding this is not preferable because it not only reduces torsion resistance due to embrittlement but also causes breakage.
幅に対する制約は厳密なものではない。下限の０．１鶴
は融体急冷法で今日作製できる最小の幅であり、上限は
線材として用いることを念頭において５鶴とした。The width constraints are not strict. The lower limit of 0.1 Tsuru is the minimum width that can be produced today by the melt quenching method, and the upper limit was set at 5 Tsuru keeping in mind that it will be used as a wire.
本発明の複合線材の芯材として用いるアモルファス金属
箔線又は繊維の組成はＦｅをベースとしてＦｅ、Ｘ、Ｍ
。で表示される合金が適当である。Ｘは磁性や耐食性、
機械的性質、被覆材との密着性などを高めるために添加
する合金元素で、Ｃｒ、 Ｍｏ、 Ｗ、７１％ Ｎｉ５
Ｃｏから選ばれる１種又は２種以上である。The composition of the amorphous metal foil wire or fiber used as the core material of the composite wire of the present invention is based on Fe, Fe, X, M
. Alloys shown in are suitable. X is magnetism and corrosion resistance,
Alloying elements added to improve mechanical properties, adhesion with coating materials, etc. Cr, Mo, W, 71% Ni5
One or more types selected from Co.
Ｍは半金属元素でＢ、Ｃ，Ｐ、Ｓｉ、Ｇｅの１種又は２
種以上である。それぞれの含有量はａ：６０〜９０（ａ
ｔχ）、ｂ：０超１５未満、Ｃ：１０〜３５、ただしａ
＋ｂ＋ｃ＝’ｌｏｏである。M is a metalloid element and is one or two of B, C, P, Si, and Ge.
More than a species. The content of each is a: 60 to 90 (a
tχ), b: more than 0 and less than 15, C: 10 to 35, but a
+b+c='loo.
上記組成の合金は過熱溶解された後、所定のノズルを介
して移動する冷却基板あるいは互いに逆回転する一対の
ロールで少なくとも１０’ ｋ／ｓｅｃの冷却速度で急
冷することにより、アモルファス合金の箔線あるいは繊
維が形成される。After the alloy having the above composition is superheated and melted, it is rapidly cooled at a cooling rate of at least 10' k/sec using a cooling substrate moving through a predetermined nozzle or a pair of rolls rotating in opposite directions to produce an amorphous alloy foil wire. Alternatively, fibers are formed.
積層した箔線あるいは繊維を被覆するために用いられる
樹脂あるいは有機高分子材はポリ塩化ビニル、ナイロン
、ポリエチレン、ポリスチレン、テフロン、ポリウレタ
ン、硬質ゴムのいずれかである。The resin or organic polymer material used to cover the laminated foil wires or fibers is polyvinyl chloride, nylon, polyethylene, polystyrene, Teflon, polyurethane, or hard rubber.
被覆の厚さは用途に応じて１μ＋ｗ〜５鶴の範囲である
。アモルファス金属箔線又は繊維の積層体を一体化して
固定するために必要な最小の被覆厚さとして１μ腸が下
限である。被覆厚みの上限は複合体を線材として用いる
ために好ましい厚みの上限である。The thickness of the coating ranges from 1 μ+w to 5 μm depending on the application. The lower limit of the minimum coating thickness required to integrate and fix the laminate of amorphous metal foil wires or fibers is 1 micron. The upper limit of the coating thickness is the preferable upper limit for using the composite as a wire.
（実施例） 次に実施例をあげて説明する。(Example) Next, an example will be given and explained.
実施例１
原子数比でＦｅｑｂＢ＋ ｚＣ４Ｃｒｓの合金組成で幅
０．６鶴、厚さ３３μ１１長さ１０，０００ｍのアモル
ファス合金繊維１を３本重ねて連続的にノズルを通して
樹脂押し出し機に送り、直径１鶴の円形に製作した押し
出し金型のダイスからナイロン階６を吐出し、第１図に
示すような断面をもつアモルファス金属繊維を芯材とし
ナイロン樹脂２を被覆した複合線材を得た。Example 1 Three amorphous alloy fibers 1 having an alloy composition of FeqbB + zC4Crs in atomic ratio and having a width of 0.6 mm, a thickness of 33μ11, and a length of 10,000 m are stacked and continuously passed through a nozzle to a resin extruder to obtain a fiber with a diameter of 1 A nylon layer 6 was discharged from a die of an extrusion mold made in the shape of a crane to obtain a composite wire having a core material of an amorphous metal fiber having a cross section as shown in FIG. 1 and coated with a nylon resin 2.
上記工程によって得た直径１ｎの複合線材１本を直径０
．９Ｎの光フアイバー６本を円形に組んだ中心にテンシ
ョンメンバーとして用い、光通信線を製作した。同じ目
的で用いた他の補強材（ケブラー、炭素繊維、タングス
テン線、ステンレス線など）に比べて本発明の複合線材
は引張り強度、熱膨張特性が優れ、ねじり強度も単線に
比べて大幅に改善された。One composite wire with a diameter of 1n obtained by the above process is
．． An optical communication line was fabricated using six 9N optical fibers arranged in a circular shape and used as a tension member at the center. Compared to other reinforcing materials used for the same purpose (Kevlar, carbon fiber, tungsten wire, stainless steel wire, etc.), the composite wire of the present invention has superior tensile strength and thermal expansion properties, and its torsional strength is also significantly improved compared to solid wire. It was done.
実施例２
原子数比でＦｅＨ，５ｓｉａ、 ｓＢ＋ ｚｃＩの合金
組成で幅２關、厚さ２５μｍ１長さ１５，０００ｍのア
モルファス合金箔線１′を４本第２図に示すような断面
をもつ複合体に成形した。複合体成形工程において実施
例１と異なる点は押し出し金型のダイスの形状が幅２．
２龍、厚さ０．３ｍｍの角のとれた矩形状である点およ
び被覆する樹脂３がポリ塩化ビニルである点である。Example 2 Four amorphous alloy foil wires 1' with an alloy composition of FeH, 5sia, sB + zcI in atomic ratio, 2 widths, 25 μm thickness, 15,000 m length, and a cross section as shown in Fig. 2 were made. Molded into the body. The difference from Example 1 in the composite molding process is that the die shape of the extrusion mold has a width of 2.
Two points are that it has a rectangular shape with rounded corners and a thickness of 0.3 mm, and that the covering resin 3 is polyvinyl chloride.
上記工程によって得たアモルファス金属強化複合線材を
使用して強化繊物を製作した。この強化繊物は経糸とし
て本発明に係る幅２．２鶴、厚さ０．３ｆｌの複合線材
を１ｍの幅に４５０本を整径し、緯糸として５Ｏ５−３
１６、直径０．１ ｔ＊の細線を用い、１ｍの間隔←工
４００本を打ち込み、アモルファス強化ビニル線とステ
ンレス線から成る交織強化繊物を製作した。このように
構成された成品は引張り強度、熱膨張特性、ねじり強度
等、在来品より著しく優れた特性を有していた。A reinforced fiber was produced using the amorphous metal-reinforced composite wire obtained through the above steps. In this reinforced fiber, 450 composite wires according to the present invention having a width of 2.2 mm and a thickness of 0.3 fl are adjusted to a width of 1 m as warp yarns, and 5O5-3 as weft yarns.
16. Using fine wire with a diameter of 0.1 t*, 400 wires were inserted at 1 m intervals to produce a mixed-woven reinforced fiber consisting of amorphous reinforced vinyl wire and stainless steel wire. The product thus constructed had properties such as tensile strength, thermal expansion properties, and torsional strength that were significantly superior to conventional products.
（発明の効果）
本発明の複数のアモルファス金属の箔線又は繊維を芯材
とし合成樹脂あるいは有機高分子を被覆した複合線材は
本来の高抗張力を保持しながら、柔軟性をもち、ねじり
に対する耐性が強く、かつ熱膨張率も小さいため、光フ
ァイバーのテンションメンバー、強化繊物、運動用具、
スクラバーブラシなどの強化材として有利に用いること
ができる。また加工中の破断や折損が生じないため、生
産性を改善することが出来る。(Effects of the Invention) The composite wire of the present invention, which has a plurality of amorphous metal foil wires or fibers as a core material and is coated with a synthetic resin or an organic polymer, has flexibility and resistance to torsion while maintaining its original high tensile strength. is strong and has a low coefficient of thermal expansion, making it suitable for optical fiber tension members, reinforced textiles, athletic equipment,
It can be advantageously used as a reinforcing material for scrubber brushes and the like. Furthermore, since no breakage or breakage occurs during processing, productivity can be improved.
第１図は円形断面からなる本発明線材の断面図、第２図
は偏平断面からなる本発明線材の断面図である。・
１：アモルファス合金繊維、１′：アモルファス合金箔
線、２：ナイロン樹脂、３：塩化ビニール樹脂。
特許出願人 新日本製鐵株式會社他１名第１図FIG. 1 is a cross-sectional view of the wire rod of the present invention having a circular cross section, and FIG. 2 is a cross-sectional view of the wire rod of the present invention having a flat cross section. - 1: amorphous alloy fiber, 1': amorphous alloy foil wire, 2: nylon resin, 3: vinyl chloride resin. Patent applicant Nippon Steel Corporation and one other person Figure 1
Claims (4)
し、合成樹脂あるいは有機高分子材で被覆してなること
を特徴とするアモルファス金属強化複合線材。(1) An amorphous metal-reinforced composite wire material comprising a plurality of amorphous metal foil wires or fibers as a core material and coated with a synthetic resin or an organic polymer material.
ｍ〜７０μｍ、幅０．１ｍｍ〜５ｍｍであることを特徴
とする特許請求の範囲第１項記載のアモルファス金属強
化複合線材。(2) The reinforcement amorphous metal foil wire has a thickness of 10 μm.
The amorphous metal reinforced composite wire according to claim 1, wherein the amorphous metal reinforced composite wire has a width of 0.1 mm to 5 mm.
Ｘ＿ｂＭ＿ｃであることを特徴とする特許請求の範囲第
１項または第２項記載のアモルファス金属強化複合線材
。ここでＸはＣｒ、Ｍｏ、Ｗ、Ｔｉ、Ｎｉ、Ｃｏの１種
又は２種以上、ＭはＢ、Ｃ、Ｐ、Ｓｉの１種又は２種以
上で、ａ：６０〜９０（ａｔ％）、ｂ：０超１５未満、
ｃ：１０〜３５、ただしａ＋ｂ＋ｃ＝１００である。(3) The chemical composition of the amorphous metal foil wire is Fe_a
The amorphous metal reinforced composite wire according to claim 1 or 2, characterized in that it is X_bM_c. Here, X is one or more of Cr, Mo, W, Ti, Ni, and Co, M is one or more of B, C, P, and Si, and a: 60 to 90 (at%) , b: more than 0 and less than 15,
c: 10-35, but a+b+c=100.
リ塩化ビニル、ナイロン、ポリエチレン、ポリスチレン
、テフロン、ポリウレタン、硬質ゴムで被覆の厚さが１
μｍ〜５ｍｍの範囲であることを特徴とする特許請求の
範囲第１項記載のアモルファス金属強化複合線材。(4) The synthetic resin or organic polymer material used for the coating is polyvinyl chloride, nylon, polyethylene, polystyrene, Teflon, polyurethane, or hard rubber, and the coating thickness is 1.
The amorphous metal reinforced composite wire according to claim 1, wherein the amorphous metal reinforced composite wire has a diameter in the range of μm to 5 mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61198541A JPS6354241A (en) | 1986-08-25 | 1986-08-25 | Amorphous metal reinforced composite wire rod |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61198541A JPS6354241A (en) | 1986-08-25 | 1986-08-25 | Amorphous metal reinforced composite wire rod |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6354241A true JPS6354241A (en) | 1988-03-08 |
| JPH0335102B2 JPH0335102B2 (en) | 1991-05-27 |
Family
ID=16392873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61198541A Granted JPS6354241A (en) | 1986-08-25 | 1986-08-25 | Amorphous metal reinforced composite wire rod |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6354241A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7193221B2 (en) | 2002-06-13 | 2007-03-20 | Toudai Tlo, Ltd. | Electronic optical lens barrel and production method therefor |
| JP2010015818A (en) * | 2008-07-03 | 2010-01-21 | Hitachi High-Technologies Corp | Electron source device and ion system |
-
1986
- 1986-08-25 JP JP61198541A patent/JPS6354241A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7193221B2 (en) | 2002-06-13 | 2007-03-20 | Toudai Tlo, Ltd. | Electronic optical lens barrel and production method therefor |
| JP2010015818A (en) * | 2008-07-03 | 2010-01-21 | Hitachi High-Technologies Corp | Electron source device and ion system |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0335102B2 (en) | 1991-05-27 |
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