JPS6349057A - Calcium replenishing solution and production thereof - Google Patents
Calcium replenishing solution and production thereofInfo
- Publication number
- JPS6349057A JPS6349057A JP61191085A JP19108586A JPS6349057A JP S6349057 A JPS6349057 A JP S6349057A JP 61191085 A JP61191085 A JP 61191085A JP 19108586 A JP19108586 A JP 19108586A JP S6349057 A JPS6349057 A JP S6349057A
- Authority
- JP
- Japan
- Prior art keywords
- calcium
- solution
- citric acid
- fish scales
- acid solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims description 63
- 229910052791 calcium Inorganic materials 0.000 title claims description 63
- 239000011575 calcium Substances 0.000 title claims description 63
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 102
- 241000251468 Actinopterygii Species 0.000 claims abstract description 38
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 235000015097 nutrients Nutrition 0.000 abstract description 5
- 239000007864 aqueous solution Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 235000019688 fish Nutrition 0.000 description 35
- 230000000052 comparative effect Effects 0.000 description 10
- 238000004090 dissolution Methods 0.000 description 9
- 210000001198 duodenum Anatomy 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000013060 biological fluid Substances 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 235000014214 soft drink Nutrition 0.000 description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 239000001630 malic acid Substances 0.000 description 3
- 235000011090 malic acid Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000009469 supplementation Effects 0.000 description 3
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229940069978 calcium supplement Drugs 0.000 description 2
- 229920001436 collagen Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 235000019512 sardine Nutrition 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 230000004102 tricarboxylic acid cycle Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000555825 Clupeidae Species 0.000 description 1
- 229920000715 Mucilage Polymers 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Meat, Egg Or Seafood Products (AREA)
Abstract
Description
【発明の詳細な説明】
［技術分野］
本発明は、魚鱗を原材料として調製したカルシウム補給
用溶液及びその製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a calcium replenishment solution prepared using fish scales as a raw material and a method for producing the same.
［背景技術］
魚鱗は２０％内外のカルシウム分を含有しており、カル
シウム補給源として注目される。特に我が国で膨大な水
揚げ量のあるマイワシは水洗いするだけでも鱗が剥がれ
易く、水揚げ址が膨大′Ｃあるために鱗も膨大な量が出
てくることになり、カルシウム補給源として再生利用す
ることが望まれるところである。[Background Art] Fish scales contain around 20% calcium and are attracting attention as a source of calcium supplementation. In particular, the scales of sardines, which are caught in a huge amount in Japan, tend to peel off even when washed with water, and since the landing site is huge, a huge amount of scales comes out, so it is important to reuse them as a source of calcium supplementation. is desired.
しかし、魚鱗は有姿状態では鱗片状をしているために喉
を通す−ことができず、また有姿状態のままでは表皮が
表面を覆っているためにカルシウム分を体内に吸収する
ことはできないものであり、カルシウム補給源として利
用することは難しいという問題があった。However, when fish scales are present, they are flaky and cannot be passed through the throat, and when they are present, calcium cannot be absorbed into the body because the surface is covered by the epidermis. Therefore, there was a problem that it was difficult to use it as a calcium supplement source.
Ｌ発明の目的］
本発明は、上記の点に鑑みて為されたものであり、魚鱗
のカルシウム分を体内に有効に吸収させることができる
カルシウム補給用溶液を提供することを第１の目的とし
、またががるカルシウム補給用溶液を容易に製造するこ
とができるカルシウム補給用溶液の製造方法を第２の目
的とするものである。LObject of the Invention The present invention has been made in view of the above points, and its first object is to provide a calcium replenishment solution that can effectively absorb the calcium content of fish scales into the body. A second object of the present invention is to provide a method for producing a calcium replenishment solution that can easily produce a calcium replenishment solution that straddles the .
［発明の開示］
しかして本発明に係るカルシウム補給用溶液は、魚鱗を
クエン酸溶液に溶解させて成ることを特徴とするもので
あり、また本発明に係るカルシウム補給用溶液の製造方
法は、魚鱗を有姿状態でクエン酸溶液に配合し、クエン
酸；８液に魚鱗を溶解させることを特徴とするものであ
り、以下本発明の詳細な説明する。[Disclosure of the Invention] The calcium replenishment solution according to the present invention is characterized by dissolving fish scales in a citric acid solution, and the method for producing the calcium replenishment solution according to the present invention includes: The present invention is characterized in that the fish scales are blended in a citric acid solution in their present state, and the fish scales are dissolved in the citric acid solution.The present invention will be described in detail below.
魚鱗は水洗して乾燥や脱水する程度で用いることができ
るが、７０〜８０゛Ｃ程度の温湯に魚鱗を浸漬すること
によって、魚臭を除去しまた魚鱗の表面に皮膜として付
着するコラーゲンなどの粘質物を除去したのちに用いる
よろにするのが望ましい。そして魚鱗とクエン酸の水溶
液とを混合して攪４↑゛動ろことによってクエン酸溶液
に魚鱗を溶解させ、この溶液を濾過して調製した濾液を
カルシウム補給用溶液として得ることができる。ここで
、魚鱗は有姿状想の鱗片状のままでクエン酸溶液と混合
することによってクエン酸溶液に溶解させることができ
るものであり、クエン酸溶改に溶解させるホｊ（こ魚鱗
を粉砕などしておく必要はな（、カルシウム補給用溶液
の製造を容易におこなうことができ乙。もちろん粉砕し
た魚鱗をクエン酸溶液に溶解してカルシウム補給用？８
液を調製することもできる。また、クエン酸溶液は濃度
が高い程魚鱗の溶解率を高めることができるが、温度は
通常１％〜１０％程度に設定するのが好ましい。濃度が
１％未満であるとクエン酸溶液への魚鱗の溶解が困難に
なる。クエン酸溶液への魚鱗の配合址は、カルシウム補
給用溶液の目的とするカルシウム含量に応じて決定され
るのはもちろんであり、またクエン酸溶液の濃度によっ
て種々異なるが、一般的にクエン酸溶液１１に対して乾
燥重量で１０ｇ〜３０ｇ程度が好ましい。Fish scales can be used by simply washing them with water and drying or dehydrating them, but by immersing them in warm water of about 70-80°C, you can remove the fish odor and remove collagen and other substances that adhere to the surface of the fish scales as a film. It is preferable to use it as a guard after removing the mucus. Then, by mixing the fish scales and an aqueous solution of citric acid and stirring 4 times, the fish scales are dissolved in the citric acid solution, and this solution is filtered to obtain a filtrate as a calcium replenishment solution. Here, fish scales can be dissolved in a citric acid solution by mixing them with a citric acid solution while remaining in the form of scales. There is no need to prepare a solution for calcium replenishment (it is possible to easily manufacture a solution for calcium replenishment. Of course, crushed fish scales can be dissolved in a citric acid solution for calcium replenishment.
Liquids can also be prepared. Further, the higher the concentration of the citric acid solution, the higher the dissolution rate of fish scales, but the temperature is usually preferably set to about 1% to 10%. When the concentration is less than 1%, it becomes difficult to dissolve fish scales in the citric acid solution. The amount of fish scales to be added to the citric acid solution is determined depending on the desired calcium content of the calcium replenishment solution, and varies depending on the concentration of the citric acid solution, but in general, the amount of fish scales added to the citric acid solution is It is preferable that the dry weight is about 10 g to 30 g for No. 11.
このようにして調製されたカルシラ１１補給用溶液は例
えば、栄養飲料剤や栄養分含有清涼飲料水にカルシウム
分を補給する目的で、これら栄養飲料剤や栄養分含有清
涼飲料水の原料の一部として用いることができる。この
ｌ１３．合、クエン酸は栄養飲料剤や清涼飲料水に酸味
を付けるために用いられており、クエン酸に魚鱗を溶解
させ−〔調製される本発明に係るカルシウム補給用溶液
は、栄養飲料剤や清涼飲料水の味を特に損なったりする
おそれなく用いることができることになる。尚、クエン
酸はトリカルボン酸サイクル（クエン酸サイクル）とし
て知られているように生体における代謝サイクルおいて
生成されるものであり、人体に対して悪影響を及ぼした
りすることが全くないのはいうまでもない。The solution for replenishing Calcilla 11 prepared in this way is used, for example, as part of the raw material for nutritional drinks and soft drinks containing nutrients, for the purpose of replenishing calcium content in these nutritional drinks and soft drinks containing nutrients. be able to. This l13. In this case, citric acid is used to add sourness to nutritional drinks and soft drinks. This means that it can be used without any particular fear of impairing the taste of drinking water. Furthermore, citric acid is produced in the metabolic cycle of living organisms, known as the tricarboxylic acid cycle (citric acid cycle), and it goes without saying that it does not have any negative effects on the human body. Nor.
また後述の実施例や比較例の記載に見られるように、魚
鱗は各種の有機酸によって溶解させることができ、特に
リンゴ酸や乳酸、酢酸においては高い溶解率で魚鱗のカ
ルシウムを溶解させることができるが、クエン酸以外の
有機酸は体内へのカルシウム分の吸収のうえで不適当で
ある。すなわち、カルシウムは体内において主として十
二指腸において吸収されるが、十二指腸における生体液
のｐＨは４．８〜８．２である。そして魚鱗をこれら有
伝酸に溶解した溶液はｐＨが３前後であるが、十二指腸
にこの溶液が至ると生体液によって中和作用を受けてｐ
ト■は高くなる。このときクエン酸以外の有機酸ではｐ
Ｈが高くなるに従ってカルシウムの溶解率が大きく低下
して沈、！ｉ９物として析出することになり、この沈澱
物として析出するカルシウムは体内に吸収されずカルシ
ウムの吸収効率が著しく低下することになる。従って本
発明では魚鱗を溶解させる有機酸としてクエン酸を選択
して用いるのである。Furthermore, as seen in the Examples and Comparative Examples below, fish scales can be dissolved with various organic acids, and especially malic acid, lactic acid, and acetic acid can dissolve calcium in fish scales at a high dissolution rate. However, organic acids other than citric acid are inappropriate for calcium absorption into the body. That is, calcium is absorbed in the body mainly in the duodenum, and the pH of the biological fluid in the duodenum is 4.8 to 8.2. A solution of fish scales dissolved in these acids has a pH of around 3, but when this solution reaches the duodenum, it is neutralized by biological fluids and the pH is around 3.
■ will be higher. At this time, with organic acids other than citric acid, p
As H increases, the dissolution rate of calcium decreases significantly and sedimentation occurs! The calcium deposited as a precipitate is not absorbed into the body, and the efficiency of calcium absorption is significantly reduced. Therefore, in the present invention, citric acid is selected and used as the organic acid for dissolving fish scales.
次ぎに本発明を実施例によって具体的に説明する。Next, the present invention will be specifically explained with reference to Examples.
マイワシの鱗を有姿のまま水洗浄したのちに、７０〜８
０゛Ｃの温湯を加尤て鱗を浸漬し、時々攪拌しながら１
０分間放置することによって鱗から魚臭と表面に付着す
る粘質物（コラーゲン）を除去した。次いでこの麟を再
び水洗浄してこれをすのこの上で圧搾したのちに遠心分
離磯で５分間脱水し、含有水分が３０．６％の試供魚鱗
を得た。この魚鱗のカルシウムを定量したところ、カル
シウム全含量は１５６．８ｍｇ／ｇであった。カルシウ
ムの定量は、魚鱗的５ｇを白金皿に正確にとって低赤熱
で炭化し、これを３００ｍｆｆ１容のトールビーカーに
水で移し込んで塩酸１０ｍ１を徐々に加え、さらに水を
加えて約１００ａ＋ｆとして約５分間煮沸し、次いで冷
却後水を加えて正確に５０Ｏｎ＋７！とじてこれを’ｌ
燥え１紙で濾過し、これについてエチレンジアミン四酢
酸塩法で定量して算出することによっておこなった。After washing the sardine scales with water,
Add warm water of 0°C and soak the scales, stirring occasionally.
By leaving the scales for 0 minutes, the fish odor and mucilage (collagen) adhering to the surface were removed from the scales. Next, the scales were washed with water again, pressed on a drainboard, and dehydrated for 5 minutes on a centrifugal rock to obtain sample fish scales with a water content of 30.6%. When the calcium in this fish scale was quantified, the total calcium content was 156.8 mg/g. To quantify calcium, accurately place 5 g of fish scales in a platinum dish, carbonize with low red heat, transfer this to a 300 mff 1 volume tall beaker with water, gradually add 10 ml of hydrochloric acid, and then add water to make about 100 a + f, about 5 Boil for a minute, then add water after cooling to make exactly 50On+7! Close this and close it.
Calculation was performed by filtering through dried paper and quantitatively determining the amount using the ethylenediaminetetraacetate method.
次ぎにこの魚鱗を２５ｇ採り、２％水溶液に調整したク
エン酸溶液（ｐＨ１，９５）を２１加えて１分間３０〜
４０回転の振り混ぜ磯で１時間振り混ぜ、さらに全体の
容量が２．５！になるように水を加えた。そしてこの溶
液を乾燥ｍ＃、で濾過することによって、！ｆ液をカル
シウム補給用溶液として得た。このようにして得たカル
シウム補給用溶液のｐＨを測定すると共にカルシウム含
量を定量したところ、第１表に示す結果が得られた。カ
ルシウムの定量はエチレンジアミン四酢酸塩法でおこな
い、またカルシウム補給用溶液におけるカルシウムの溶
解率を表に示した。溶解率はカルシウム補給用溶：Ｖ１
．のカルシウムｔｉを魚鱗のカルシツム含量で割った数
値の百分率として算出することができる。Next, take 25g of these fish scales and add 21g of citric acid solution (pH 1,95) adjusted to 2% aqueous solution for 1 minute.
After 1 hour of shaking at 40 rpm, the total volume is 2.5! I added water to make it. And by filtering this solution with dry m#,! Solution f was obtained as a solution for calcium replenishment. When the pH of the calcium replenishment solution thus obtained was measured and the calcium content was quantified, the results shown in Table 1 were obtained. Calcium was determined by the ethylenediaminetetraacetate method, and the dissolution rate of calcium in the calcium replenishment solution is shown in the table. The dissolution rate is calcium supplement solution: V1
．． It can be calculated as the percentage of calcium ti divided by the calcium content of fish scales.
Ｘ】ｊすじし
クエン酸溶液として濃度を５％の水、−８液に調整した
もの（ｐＨ１，８０）を用いるようにした池は、実施例
１と同様にしてカルシウム補給用溶液を得た。X] j Sujishi The pond used a citric acid solution with a concentration of 5% water adjusted to -8 (pH 1,80), and a calcium replenishment solution was obtained in the same manner as in Example 1. .
思上ｆｌ立工」−
魚鱗を溶解させる有機酸として、２％水溶液のリンゴ酸
溶液（比較例１）、５％水溶液のリンゴ酸溶液（比較例
２）、２％水溶液の乳酸溶液（比較例３）、５％水溶液
の乳酸溶！（比較例４）、２％水溶液の酒石酸溶液（比
較例５）、５％水溶液の酒石酸溶ａ（比較例６）、２％
水溶液の酢酸溶液（比較例７）、５％水溶液の酢酸溶液
（比較例８）を用い、他は実施例１と同様にしてカルシ
ウム？ｌｉｉ給用溶液を得た。Shijo fl Riku' - Organic acids for dissolving fish scales include 2% aqueous malic acid solution (Comparative Example 1), 5% aqueous malic acid solution (Comparative Example 2), and 2% aqueous lactic acid solution (Comparative Example 3), 5% aqueous lactic acid solution! (Comparative Example 4), 2% aqueous tartaric acid solution (Comparative Example 5), 5% aqueous tartaric acid solution a (Comparative Example 6), 2%
Calcium? lii feeding solution was obtained.
＠１表の結果、クエン酸溶液を用いた実施例１゜２のも
のでは魚鱗に含有されるカルシウムは殆どが溶解されて
おり、有姿状態でも魚Ｓをクエン酸溶液に容易に溶解で
きることがＲ１認される。As a result of Table @1, in Examples 1 and 2 using citric acid solution, most of the calcium contained in the fish scales was dissolved, indicating that fish S can be easily dissolved in the citric acid solution even when the fish S is present. R1 approved.
また上記のようにして得た実施例１，２及ゾ比較例１乃
至８のカルシウム補給用溶液について、０．１６８４Ｎ
の水酸化す） ＋７ウム水溶衣を用いてｐＨを７．０に
中和した。このときクエン酸溶液を用いた実施例１，２
以外はｐＨが５．０〜６．５になった際に沈澱が発生し
た。この、Ｈを７．０に調整した溶液を濾過し、濾液に
ついてカルシウム含量を測定した。カルシウム含量の側
室結果及びこれをもとに算出したカルシウムの溶解率を
第１表に示す。第１表の結果、クエン酸溶液を用いた実
施例１，２のものでは溶解率の低下はわずかで、沈澱は
殆ど生じていないのに対して、各比較例では溶解率が低
下して沈澱が多く生じでいることが確認される。従って
、カルシウム補給用溶液が十二指腸で生体液によって中
和される作用を受けた場合、各比較例のものではカルシ
ウムの一部が沈澱してカルシウムの体内への吸収効率が
低下するおそれがあるが、クエン酸を用いた実施例１，
２のものではカルシウムは殆ど沈５２されずカルシウム
の吸収効率が低下することを防止できることになる。Further, regarding the calcium replenishment solutions of Examples 1 and 2 and Comparative Examples 1 to 8 obtained as described above, 0.1684N
The pH was neutralized to 7.0 using +7um water solution. Examples 1 and 2 using citric acid solution at this time
In all other cases, precipitation occurred when the pH reached 5.0 to 6.5. This solution in which H was adjusted to 7.0 was filtered, and the calcium content of the filtrate was measured. Table 1 shows the results of the side chamber calcium content and the calcium dissolution rate calculated based on the results. As shown in Table 1, in Examples 1 and 2 using citric acid solutions, the dissolution rate decreased only slightly and almost no precipitation occurred, whereas in each comparative example, the dissolution rate decreased and no precipitation occurred. It is confirmed that many occur. Therefore, when the calcium replenishment solution is neutralized by biological fluids in the duodenum, some of the calcium in the comparative examples may precipitate, reducing the absorption efficiency of calcium into the body. , Example 1 using citric acid,
In the case of No. 2, almost no calcium is precipitated 52, and a decrease in calcium absorption efficiency can be prevented.
尚、実施例１，２のものについて水酸化す） ＋７ウム
水溶液でｐＨをさら；こ高めるように調整したところ、
ＤＨが７６６０の時点で白濁が発生して沈澱が生じ始め
た。また９Ｈを８．２に３！ｌ整した実施例１．２の溶
液の濾液についてカルシウム含量を測定した。このカル
シウム含量の測定結果及びこれをらとに算出したカルシ
ウムの溶解率を第１表に示す、クエン酸溶液を用いた実
施例１，２のものではｐＨを８．２にＦＡ整してもなお
高いカルシウムの溶解率を維持することが１４認される
。In addition, when the pH of Examples 1 and 2 was adjusted to further increase with a +7 um aqueous solution,
When the DH reached 7660, white turbidity occurred and precipitate began to form. Also 9H to 8.2 to 3! The calcium content was determined in the filtrate of the prepared solution of Example 1.2. Table 1 shows the measurement results of calcium content and the calcium dissolution rate calculated based on the results. Furthermore, it was confirmed that a high calcium solubility rate was maintained.
また、ドリンク剤と称して市販される各種の栄養飲料剤
や栄養分含有清涼飲料水のＤＨを測定したところ第２表
の結果が得られた。ドリンク剤のｐＨはいずれら実施例
１，２のカルシウム補給用溶液のｐＨと大きな相異がな
く、カルシウム補給用溶液をドリンク剤の原料の一部と
して用いることに問題がないことが確認される。In addition, when the DH of various nutritional drinks and nutrient-containing soft drinks marketed as drinks was measured, the results shown in Table 2 were obtained. The pH of the drinks is not significantly different from the pH of the calcium replenishment solutions of Examples 1 and 2, and it is confirmed that there is no problem in using the calcium replenishment solutions as part of the raw materials for the drinks. .
［発明の効果］
上述のように本発明に係るカルシウム補給用溶液は、魚
鱗をクエン酸溶液に溶解させたものであり、魚鱗のカル
シウム分を溶解させた溶液として飲用に適したものとす
ることができると共にカルシウムを体内に吸収し易い状
態にすることができるものであり、しかも十二指腸にお
いて生体液で中和作用を受けてもクエン酸溶液に溶解さ
れたカルシウムは沈澱されるおそれはなく、魚鱗のカル
シツム分を十二指腸において体内に有効に吸収させるこ
とができるものである。また本発明に係るカルシウム補
給用溶液の９１遣方法は、魚鱗を有姿状憇でクエン酸溶
液に配合してクエンｐＨ溶液に溶解させるようにしたも
のであり、魚鱗を粉砕などする必要なくクエン酸溶液に
良好に溶解させて容易：こカルシウム補給用溶液を：！
４製することができるものである。[Effects of the Invention] As described above, the calcium replenishment solution according to the present invention is made by dissolving fish scales in a citric acid solution, and is suitable for drinking as a solution in which the calcium content of fish scales is dissolved. In addition, calcium can be easily absorbed into the body, and even if it is neutralized by biological fluids in the duodenum, there is no risk that the calcium dissolved in the citric acid solution will precipitate. of calcium can be effectively absorbed into the body in the duodenum. In addition, the method for dispensing the calcium replenishing solution according to the present invention is to mix fish scales in the form of a citric acid solution and dissolve it in a citric acid solution. Easy to dissolve well in acid solutions: This solution for calcium supplementation:!
4 can be made.
Claims (2)
とするカルシウム補給用溶液。(1) A calcium replenishment solution characterized by dissolving fish scales in a citric acid solution.
酸溶液に魚鱗を溶解させることを特徴とするカルシウム
補給用溶液の製造方法。(2) A method for producing a calcium replenishment solution, which comprises blending fish scales in a citric acid solution in the present state and dissolving the fish scales in the citric acid solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61191085A JPS6349057A (en) | 1986-08-14 | 1986-08-14 | Calcium replenishing solution and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61191085A JPS6349057A (en) | 1986-08-14 | 1986-08-14 | Calcium replenishing solution and production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6349057A true JPS6349057A (en) | 1988-03-01 |
| JPH0231941B2 JPH0231941B2 (en) | 1990-07-17 |
Family
ID=16268607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61191085A Granted JPS6349057A (en) | 1986-08-14 | 1986-08-14 | Calcium replenishing solution and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6349057A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03213630A (en) * | 1990-01-17 | 1991-09-19 | Mitsubishi Motors Corp | Variable compression ratio device of internal combustion engine |
| WO1999040941A1 (en) * | 1998-02-17 | 1999-08-19 | Zeinoun, Robert, B. | A fish scale extract as a calcium supplement |
| JP2012000004A (en) * | 2010-06-14 | 2012-01-05 | Aishisu:Kk | Agent for treating fish and shell fish |
| JP2012170360A (en) * | 2011-02-18 | 2012-09-10 | Suminori Suga | Processed product of little fish with big catch rate and method for producing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5114586A (en) * | 1974-07-25 | 1976-02-05 | Daifuku Machinery Works | SHIIKEN SUSEIGYO SOCHI |
| JPS52110878A (en) * | 1976-03-13 | 1977-09-17 | Hisaharu Kaji | Production of calcium salt of organic acid for foodstuff from natural shell |
| JPS5798527A (en) * | 1980-07-07 | 1982-06-18 | Rgb Lab | Mineral enhanced substance and manufacture |
-
1986
- 1986-08-14 JP JP61191085A patent/JPS6349057A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5114586A (en) * | 1974-07-25 | 1976-02-05 | Daifuku Machinery Works | SHIIKEN SUSEIGYO SOCHI |
| JPS52110878A (en) * | 1976-03-13 | 1977-09-17 | Hisaharu Kaji | Production of calcium salt of organic acid for foodstuff from natural shell |
| JPS5798527A (en) * | 1980-07-07 | 1982-06-18 | Rgb Lab | Mineral enhanced substance and manufacture |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03213630A (en) * | 1990-01-17 | 1991-09-19 | Mitsubishi Motors Corp | Variable compression ratio device of internal combustion engine |
| WO1999040941A1 (en) * | 1998-02-17 | 1999-08-19 | Zeinoun, Robert, B. | A fish scale extract as a calcium supplement |
| JP2012000004A (en) * | 2010-06-14 | 2012-01-05 | Aishisu:Kk | Agent for treating fish and shell fish |
| JP2012170360A (en) * | 2011-02-18 | 2012-09-10 | Suminori Suga | Processed product of little fish with big catch rate and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0231941B2 (en) | 1990-07-17 |
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