JPS6339686A - Method for treating seawater - Google Patents

Method for treating seawater

Info

Publication number
JPS6339686A
JPS6339686A JP61184573A JP18457386A JPS6339686A JP S6339686 A JPS6339686 A JP S6339686A JP 61184573 A JP61184573 A JP 61184573A JP 18457386 A JP18457386 A JP 18457386A JP S6339686 A JPS6339686 A JP S6339686A
Authority
JP
Japan
Prior art keywords
seawater
tank
reverse osmosis
supplied
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61184573A
Other languages
Japanese (ja)
Inventor
Yuji Yoshii
吉井 裕二
Shoichi Suda
昇一 須田
Hatsuo Uehara
上原 初男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
Original Assignee
NKK Corp
Nippon Kokan Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NKK Corp, Nippon Kokan Ltd filed Critical NKK Corp
Priority to JP61184573A priority Critical patent/JPS6339686A/en
Publication of JPS6339686A publication Critical patent/JPS6339686A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

Abstract

PURPOSE:To treat seawater at a low running cost by injecting SO2 gas or sulfurous acid respectively to a seawater tank and between a pretreatment seawater tank and a reverse osmosis device. CONSTITUTION:Seawater is introduced into a seawater tank 22 by a seawater pump 21, and is supplied to filter tanks 24a and 24b respectively to by pumps 23a and 23b. Next, after the seawater filtered by the filter tanks 24a and 24b is supplied to a pretreatment seawater tank 25, said seawater is supplied to a reverse osmosis device 29 through a cartridge filter 27 and a high pressure pump 28 by a seawater pump 26. The resulting desalted water is stored in a desalted water tank 30. After SO2 gas is generated by feeding sulfur and air into a sulfur combustion furnace 31, SO2 gas is supplied to an absorption tower 32 where th seawater from the outlet of the pretreated seawater tank 25 is supplied. Resulting sulfurous acid is stored in a tank 33. By said process, proliferation of microbes in the seawater can be controlled.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、海水の処理方法に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a seawater treatment method.

[従来の技術] 逆浸透法により海水又はかん水を淡水化する場合、従来
、第3図に示すシステムを用いて淡水化することが行わ
れている。即ち、まずポンプ1により海水を海水タンク
2に導入し、この海水を例えば2基のポンプ3a、3b
により2つの濾過槽4 a s 4 bに夫々供給する
と共に、濾過槽4as4bに供給する前の海水に凝集剤
としての例えばF e C10を添加する。この時、後
述する逆浸透装置の半透膜への微生物のスライムの付着
や膜自体への浸蝕を防止するために前記海水タンク2に
塩素(又は次亜塩素酸ソーダ)を注入して滅菌を行なっ
ている。つづいて、濾過槽4as4bで濾過された海水
にH2SO,を注入し、これを前処理海水タンク5に供
給する。ひきつづき、前処理海水タンク5の海水をポン
プ6によりカートリッジフィルタ7を通して真空ポンプ
により真空脱気された真空脱気装置8に供給する。次い
で、真空脱気後の海水を、ポンプ9及び高圧ポンプ10
(こより逆浸透装置(東し社製商品名、PEC−100
0)11に供給し、ここで逆浸透処理された脱塩水を脱
塩水・タンク12に貯蔵する。前記逆浸透装置11に使
用される半透膜としての高分子複合膜等は、供給海水中
に残留する塩素により酸化され易く、膜性能の劣化を招
くため、前記真空脱気装置8に供給される海水及び該真
空脱気装置8に還元剤としての例えば重亜硫酸ソーダ(
N a HS O3)を注入して塩素の除去を行なって
いる。
[Prior Art] When seawater or brine is desalinated by reverse osmosis, a system shown in FIG. 3 has conventionally been used. That is, first, seawater is introduced into a seawater tank 2 by a pump 1, and then this seawater is pumped into, for example, two pumps 3a and 3b.
The seawater is supplied to the two filtration tanks 4as 4b, respectively, and a coagulant such as Fe C10, for example, is added to the seawater before being supplied to the filtration tanks 4as4b. At this time, chlorine (or sodium hypochlorite) is injected into the seawater tank 2 to sterilize it in order to prevent microbial slime from adhering to the semipermeable membrane of the reverse osmosis device, which will be described later, and from corroding the membrane itself. I am doing it. Subsequently, H2SO is injected into the seawater filtered in the filter tank 4as4b, and this is supplied to the pretreatment seawater tank 5. Subsequently, the seawater in the pretreated seawater tank 5 is supplied by a pump 6 through a cartridge filter 7 to a vacuum deaerator 8 where the seawater is vacuum degassed by a vacuum pump. Next, the seawater after vacuum degassing is pumped into a pump 9 and a high pressure pump 10.
(Koyori reverse osmosis equipment (product name manufactured by Toshisha, PEC-100)
0) 11, and the desalinated water that has been subjected to reverse osmosis treatment here is stored in the desalinated water tank 12. A polymer composite membrane or the like as a semipermeable membrane used in the reverse osmosis device 11 is easily oxidized by chlorine remaining in the supplied seawater, leading to deterioration of membrane performance. To the seawater and the vacuum deaerator 8, for example, sodium bisulfite (
Chlorine is removed by injecting Na HS O3).

[発明が解決しようとする問題点] 以上、従来の海水処理方法は滅菌のために海水タンク2
に塩素(又は次亜塩素酸ソーダ)を注入し、逆浸透装置
11まで塩素を残留させ、系内での微生物の増殖を抑制
し、更に逆浸透装置11の直前において塩素を除去する
ための還元剤(通常は重亜硫酸ソーダ)を注入している
。このように、一旦注入した塩素をまた除去する必要が
あり、操作の繁雑さや2種の薬液の使用によるランニン
グコストの高騰化を招く問題があった。
[Problems to be solved by the invention] As described above, the conventional seawater treatment method uses a seawater tank 2 for sterilization.
chlorine (or sodium hypochlorite) is injected into the system, the chlorine remains up to the reverse osmosis device 11, suppresses the growth of microorganisms in the system, and further, immediately before the reverse osmosis device 11, a reduction process is performed to remove chlorine. agent (usually sodium bisulfite). In this way, it is necessary to remove the chlorine once injected, which poses a problem of complicated operations and an increase in running costs due to the use of two types of chemical solutions.

本発明は、上記従来の問題点を解決するためになされた
もので、簡単の操作でかつ低ランニングコストにて海水
を処理し得る方法を提供しようとするものである。
The present invention has been made to solve the above-mentioned conventional problems, and aims to provide a method for treating seawater with simple operation and low running cost.

[問題点を解決するための手段] 本発明は、海水タンクに一旦貯蔵した海水を濾過した後
、前処理海水タンク、フィルタ及び逆浸透装置を通して
海水を処理する方法において、前記海水タンク及び前記
前処理海水タンクと逆浸透装置の間の配管系に夫々SO
2ガス又は亜硫酸水を注入せしめることを特徴とする海
水のα理方法である。
[Means for Solving the Problems] The present invention provides a method for filtering seawater once stored in a seawater tank, and then treating the seawater through a pretreatment seawater tank, a filter, and a reverse osmosis device. SO in the piping system between the treated seawater tank and the reverse osmosis equipment.
This is a seawater treatment method characterized by injecting two gases or sulfite water.

[作用] 本発明によれば、海水タンク及び前記前処坤海水タンク
と逆浸透装置の間の配管系に夫々SO2ガス又は亜硫酸
水を注入することによって、海水のpHを6近傍まで下
げて、海水中の全類(微生物)の増殖を抑制でき、逆浸
透装置の半透膜への微生物のスライムとしての付着及び
膜自体の浸蝕を防止できる。また、S02ガス又は亜硫
酸水は還元剤として作用するため、従来のように滅菌に
使用した塩素の還元の目的で重亜硫酸ソーダを注入する
という操作を解消できる。しかも、該S02ガス又は亜
硫酸水の還元作用により海水中の溶存酸素を除去するこ
とができる。更に、S02ガス又は亜硫酸水を海水タン
ク、及び前記前処理海水タンクと逆浸透装置の間の配管
系に夫々分けて注入することによって、多口の海水が貯
蔵される海水タンクのみにS02ガス又は亜硫酸水を注
入する場合に比べて、少ないS02ガス又は亜硫酸水の
注入で滅菌及び溶存酸素の除去を効率的に行なうことが
できる。
[Function] According to the present invention, the pH of the seawater is lowered to around 6 by injecting SO2 gas or sulfite water into the seawater tank and the piping system between the pre-treated seawater tank and the reverse osmosis device, respectively. The growth of all types of microorganisms in seawater can be suppressed, and the adhesion of microorganisms as slime to the semipermeable membrane of a reverse osmosis device and the erosion of the membrane itself can be prevented. Furthermore, since S02 gas or sulfite water acts as a reducing agent, it is possible to eliminate the conventional operation of injecting sodium bisulfite for the purpose of reducing chlorine used for sterilization. Moreover, dissolved oxygen in seawater can be removed by the reducing action of the S02 gas or sulfite water. Furthermore, by separately injecting S02 gas or sulfurous acid water into the seawater tank and the piping system between the pretreated seawater tank and the reverse osmosis device, S02 gas or sulfurous acid water is injected only into the seawater tank where multiple ports of seawater are stored. Compared to the case where sulfite water is injected, sterilization and dissolved oxygen removal can be performed efficiently by injecting a smaller amount of S02 gas or sulfite water.

[発明の実施例コ 以下、本発明の実施例を第1図を参照して説明する。[Embodiments of the invention] Embodiments of the present invention will be described below with reference to FIG.

まず、ポンプ21により海水を海水タンク22に導入し
、この海水を2基のポンプ23a、23bにより2つの
濾過槽24a、24bに夫々供給すると共に、濾過槽2
4a、24bに供給する前の海水に凝集剤としての例え
ばl;’ecJ!3を注入する。つづいて、前記a過槽
24a、24bで濾過された海水を前処理海水タンク2
5に供給した後、この海水をポンプ26によりカートリ
ッジフィルタ27及び高圧ポンプ28を通して逆浸透装
置(例えば東し社製商品名、PEC−1000)29に
供給し、ここで逆浸透処理された脱塩水を脱塩水タンク
30に貯蔵する。こうした海水処理において、硫黄燃焼
炉31に硫黄及び空気を供給してS02ガスを生成した
後、このS02ガスを前処理海水タンク25出口側から
の海水が供給される吸収塔32に供給し、生成した亜硫
酸水をタンク33に溜め、ポンプ36により亜硫酸水を
海水タンク22内の海水に注入すると共に、前処理海水
タンク25の出口側の海水に注入した。
First, seawater is introduced into the seawater tank 22 by the pump 21, and this seawater is supplied to the two filter tanks 24a, 24b by the two pumps 23a, 23b, respectively.
For example, l;'ecJ! Inject 3. Subsequently, the seawater filtered by the a filter tanks 24a and 24b is transferred to the pretreatment seawater tank 2.
5, this seawater is supplied by a pump 26 through a cartridge filter 27 and a high-pressure pump 28 to a reverse osmosis device (for example, PEC-1000 manufactured by Toshi Co., Ltd.) 29, where the reverse osmosis-treated desalinated water is is stored in the desalinated water tank 30. In such seawater treatment, sulfur and air are supplied to the sulfur combustion furnace 31 to generate S02 gas, and then this S02 gas is supplied to the absorption tower 32 to which seawater from the outlet side of the pretreated seawater tank 25 is supplied, and the S02 gas is generated. The sulfurous acid water was stored in a tank 33, and the pump 36 injected the sulfurous acid water into the seawater in the seawater tank 22 and into the seawater on the outlet side of the pretreatment seawater tank 25.

上述した本実施例によれば、海水中の微生物の増殖を抑
制できると共に、海水中の溶存酸素を効果的に除去でき
、逆浸透装置29の半透膜の浸蝕、膜性能の劣化を抑制
して該逆浸透装置29の性能を長期間に亙って維持する
ことができた。なお、海水中の溶存酸素の除去及び微生
物の増殖抑制効果は以下に示す実験より確認した。
According to the present embodiment described above, it is possible to suppress the growth of microorganisms in seawater, and also to effectively remove dissolved oxygen in seawater, suppressing corrosion of the semipermeable membrane of the reverse osmosis device 29 and deterioration of membrane performance. Therefore, the performance of the reverse osmosis device 29 could be maintained for a long period of time. The effect of removing dissolved oxygen in seawater and inhibiting the growth of microorganisms was confirmed through the experiment shown below.

東京溝から採取し、水温20°Cの一定温度とした海水
に亜硫酸水をSO2に換算して40′I51/ノ注入し
てpH,溶存酸素W(Do)及び酸化還元電位(ORP
)の経時変化を調べたところ、第2図に示す結果を得た
。この第2図より明らかなように、亜硫酸水の注入後、
略同時にpHが約6.3程度に低下し、注入後約7分間
で溶存酸素を除去できた。
Sulfurous acid water, converted to SO2, was injected into seawater collected from the Tokyo ditch and kept at a constant temperature of 20°C to determine pH, dissolved oxygen W (Do), and oxidation-reduction potential (ORP).
), the results shown in Figure 2 were obtained. As is clear from this figure 2, after injection of sulfite water,
At about the same time, the pH decreased to about 6.3, and dissolved oxygen could be removed in about 7 minutes after injection.

また、バクテリアの係数を、通常海域で使用するZob
ell 2216 E培地を用いて行なった結果を下記
第1表及び第2表に示す。なお、第1表、第2表中の培
地基であるZ/10SZ/100は、夫々Zobell
 2216 E培地を10倍、100倍に希釈したもの
である。サンプル■は原潜水、サンプル■は原潜水に薬
剤(亜硫酸水)をS02に換算して40η/ノ注入した
もの、を夫々用いた。
In addition, the coefficient of bacteria is
The results obtained using the ELL 2216 E medium are shown in Tables 1 and 2 below. In addition, Z/10SZ/100, which is a medium base in Tables 1 and 2, are respectively manufactured by Zobell.
2216E medium diluted 10 times and 100 times. Sample (2) used the original submerged water, and sample (2) used the original submerged water in which a chemical (sulfite water) was injected at a rate of 40η/no in terms of S02.

薬剤の処理時間は、10分間とした。The treatment time for the drug was 10 minutes.

上記第1表及び第2表から明らかなように、サンプル■
、■ともそれ程、大きな差はないが、原海水に亜硫酸水
を注入したサンプル■はバクテリアの抑制効果を期待で
きる。
As is clear from Tables 1 and 2 above, sample ■
There is not a big difference between samples 2 and 3, but sample 2, in which sulfite water is injected into raw seawater, can be expected to have a bacteria-inhibiting effect.

[発明の効果コ 以上詳述した如く、本発明によれば簡単な操作でかつ低
ランニングコストで海水中の微生物の増殖抑制と海水中
の溶存酸素の除去を行なうことができ、ひいては逆浸透
装置の半透膜等の浸蝕、膜性能の劣化を抑制して海水を
効果的に逆浸透処理(脱塩水処理)することが可能な塩
水の処理方法を提供できる。
[Effects of the Invention] As detailed above, according to the present invention, it is possible to suppress the proliferation of microorganisms in seawater and remove dissolved oxygen in seawater with simple operation and low running cost, and as a result, reverse osmosis equipment can be used. It is possible to provide a salt water treatment method that can effectively perform reverse osmosis treatment (desalinated water treatment) of seawater while suppressing erosion of semipermeable membranes and deterioration of membrane performance.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例に用いた海水処理システムを示
す概略図、第2図は海水に亜硫酸水を注入した時のpH
1溶存酸素ff1(DO)及び酸化還元電位(ORP)
の経時変化を示す特性図、第3図は従来の海水処理シス
テムを示す概略図である。 22・・・海水タンク、24a、24b・・・濾過槽、
25・・・前処理海水タンク、27・・・カートリッジ
フィルタ、29・・・逆浸透装置、30・・・脱塩水タ
ンク、31・・・硫黄燃焼炉、32・・・吸収塔。 出願人代理人 弁理士 鈴江武彦 第1図 第2図 手続ネm正書6i、9.18 昭和   年   月   日 特許庁長官 黒 1)明 雄  殿 1、事件の表示 特願昭61−184573号 2、発明の名称 海水の処理方法 3、補正をする者 事件との関係  特許出願人 (412)  日本m管株式会社 4、代理人 東京都千代田区霞が関3丁目7番2号 USEビル〒1
00  電話03 (502)3181 (大代表)゛
、( (5847)   弁理士  鈴  江  武  彦。 5、自発補正 明細書、図面 7、補正の内容 (1)、明wI書の特許請求の範囲を別紙の如く訂正す
る。 (2)、明細書中箱2頁1行目において、「凝集剤とし
ての例えば」とあるを「凝集剤として例えば」と訂正す
る。 (3)明m書中第2頁13行目、第4頁1〜2行目、同
頁10行目、同頁19行目、第5頁16〜17行目、第
6頁10行目、同頁11行目、第9頁9行目及び第10
頁1行目において、「逆浸透装置」とあるを「逆浸透モ
ジュール」と訂正する。 (4)、明細南中第2頁13〜14行目において、「(
東し社製商品名:PEC−1000)Jとあるを「(例
えば東し社製商品名: PEC−1000)Jと訂正す
る。 (5)、明IR丙中第3頁6行目において、「逆浸透装
置11まで塩素を残留」とあるを「逆浸透モジュール1
1の前段まで塩素を残留」と訂正する。 (6)、明細自中第3頁14行目において、[l!!′
I単の操作」とあるを「簡単な操作」と訂正する。 (7)、明細書中筒4頁9行目において、「全類」とあ
るを「菌類」と訂正する。 (8)、明細書中筒6頁1行目において、「ガスを生成
した後」とあるを「ガスを生成させた後」と訂正する。 ■)0図面の第2図を別紙の如く訂正する。 2、特許請求の範囲 海水タンクに一旦貯蔵した海水を通過した後、航α理海
水タンク、フィルタ及び逆浸透モジュール−を通して海
水を処理する方法において、前記海水タンク及び前記前
処理海水タンクと逆浸透iZニールの間の配管系に夫々
802ガス又は亜硫酸水を注入せしめることを特徴とす
る海水の処理方法。
Figure 1 is a schematic diagram showing the seawater treatment system used in the example of the present invention, and Figure 2 is the pH when sulfite water is injected into seawater.
1 Dissolved oxygen ff1 (DO) and redox potential (ORP)
FIG. 3 is a schematic diagram showing a conventional seawater treatment system. 22... seawater tank, 24a, 24b... filtration tank,
25... Pretreatment seawater tank, 27... Cartridge filter, 29... Reverse osmosis device, 30... Desalination water tank, 31... Sulfur combustion furnace, 32... Absorption tower. Applicant's Representative Patent Attorney Takehiko Suzue Figure 1 Figure 2 Procedures Manual 6i, 9.18 Showa Year Month Date Commissioner of the Patent Office Kuro 1) Akio Yu 1, Case Indication Patent Application No. 184573 No. 1988 2 , Name of the invention Seawater treatment method 3, Relationship with the person making the amendment Patent applicant (412) Japan M-Kan Co., Ltd. 4 Agent USE Building 3-7-2 Kasumigaseki, Chiyoda-ku, Tokyo 1
00 Telephone: 03 (502) 3181 (Main representative)゛, ((5847) Patent attorney Takehiko Suzue. 5. Spontaneous amended specification, drawing 7, content of amendment (1), scope of patent claims of Mei w I The correction is made as shown in the attached sheet. (2) In the first line of page 2 of the box in the specification, the phrase "for example as a flocculant" is corrected to "for example as a flocculant." (3) Section 2 in the specification Page 13, page 4, lines 1-2, page 4, line 10, page 19, page 5, lines 16-17, page 6, line 10, page 6, line 11, line 9 Page line 9 and 10
In the first line of the page, the phrase "reverse osmosis device" is corrected to "reverse osmosis module." (4), on page 2 of the specification, lines 13-14, “(
Toshisha product name: PEC-1000)J should be corrected as ``(For example, Toshisha product name: PEC-1000)J. "Chlorine remains up to reverse osmosis unit 11" is replaced with "reverse osmosis module 1.
Chlorine remains until the first stage of step 1.'' (6), on page 3, line 14 of the specification, [l! ! ′
Correct the phrase "simple operation" to "simple operation." (7) On page 4, line 9 of the specification, "all classes" is corrected to "fungi." (8) In the first line of page 6 of the specification, the phrase "after gas is generated" is corrected to "after gas is generated." ■) Correct Figure 2 of Drawing 0 as shown in the attached sheet. 2. Claims: A method of treating seawater through a seawater tank, a filter, and a reverse osmosis module after the seawater is stored in a seawater tank, passes through a seawater tank, a filter, and a reverse osmosis module. A seawater treatment method characterized by injecting 802 gas or sulfite water into the piping system between iZ Neil.

Claims (1)

【特許請求の範囲】[Claims] 海水タンクに一旦貯蔵した海水を濾過した後、前処理海
水タンク、フィルタ及び逆浸透装置を通して海水を処理
する方法において、前記海水タンク及び前記前処理海水
タンクと逆浸透装置の間の配管系に夫々SO_2ガス又
は亜硫酸水を注入せしめることを特徴とする海水の処理
方法。
In a method of filtering seawater once stored in a seawater tank, and then treating the seawater through a pretreatment seawater tank, a filter, and a reverse osmosis device, each of the piping systems between the seawater tank and the pretreatment seawater tank and the reverse osmosis device includes: A seawater treatment method characterized by injecting SO_2 gas or sulfite water.
JP61184573A 1986-08-06 1986-08-06 Method for treating seawater Pending JPS6339686A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61184573A JPS6339686A (en) 1986-08-06 1986-08-06 Method for treating seawater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61184573A JPS6339686A (en) 1986-08-06 1986-08-06 Method for treating seawater

Publications (1)

Publication Number Publication Date
JPS6339686A true JPS6339686A (en) 1988-02-20

Family

ID=16155570

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61184573A Pending JPS6339686A (en) 1986-08-06 1986-08-06 Method for treating seawater

Country Status (1)

Country Link
JP (1) JPS6339686A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2075234A1 (en) * 2007-12-19 2009-07-01 Shell Internationale Researchmaatschappij B.V. A process for lowering the pH of a water stream
US20100018921A1 (en) * 2007-08-20 2010-01-28 Earth Renaissance Technologies, Llc Reverse osmosis water recover method
US20100193436A1 (en) * 2007-08-20 2010-08-05 Earth Renaissance Technologies, Llc Pre-treatment reverse osmosis water recovery method for brine retentate metals removal
KR20210123944A (en) * 2020-04-06 2021-10-14 두산중공업 주식회사 Reverse osmosis apparatus and seawater desalination system comprising the same
KR20210150120A (en) * 2020-06-03 2021-12-10 두산중공업 주식회사 Reverse osmosis apparatus and seawater desalination system comprising the same
KR20210150121A (en) * 2020-06-03 2021-12-10 두산중공업 주식회사 Reverse osmosis system and seawater desalination system comprising the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5474288A (en) * 1977-11-02 1979-06-14 Ibm Electrolyte for electric color display apparatus
JPS5621604A (en) * 1979-07-27 1981-02-28 Toray Ind Inc Separation of liquid by semipermeable composite membrane

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5474288A (en) * 1977-11-02 1979-06-14 Ibm Electrolyte for electric color display apparatus
JPS5621604A (en) * 1979-07-27 1981-02-28 Toray Ind Inc Separation of liquid by semipermeable composite membrane

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100018921A1 (en) * 2007-08-20 2010-01-28 Earth Renaissance Technologies, Llc Reverse osmosis water recover method
US20100193436A1 (en) * 2007-08-20 2010-08-05 Earth Renaissance Technologies, Llc Pre-treatment reverse osmosis water recovery method for brine retentate metals removal
US8101083B2 (en) * 2007-08-20 2012-01-24 Earth Renaissance Technologies, Llc Pre-treatment reverse osmosis water recovery method for brine retentate metals removal
US8236178B2 (en) 2007-08-20 2012-08-07 Earth Renaissance Technologies, Llc Reverse osmosis water recover method
EP2075234A1 (en) * 2007-12-19 2009-07-01 Shell Internationale Researchmaatschappij B.V. A process for lowering the pH of a water stream
KR20210123944A (en) * 2020-04-06 2021-10-14 두산중공업 주식회사 Reverse osmosis apparatus and seawater desalination system comprising the same
KR20210150120A (en) * 2020-06-03 2021-12-10 두산중공업 주식회사 Reverse osmosis apparatus and seawater desalination system comprising the same
KR20210150121A (en) * 2020-06-03 2021-12-10 두산중공업 주식회사 Reverse osmosis system and seawater desalination system comprising the same
US11498860B2 (en) 2020-06-03 2022-11-15 Doosan Enerbility Co., Ltd. Reverse osmosis apparatus and seawater desalination system having the same
US11779884B2 (en) 2020-06-03 2023-10-10 Doosan Enerbility Co., Ltd. Reverse osmosis system and seawater desalination system having the same

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