JPS6336767A - Edible film easily dispersible in water - Google Patents

Edible film easily dispersible in water

Info

Publication number
JPS6336767A
JPS6336767A JP61180050A JP18005086A JPS6336767A JP S6336767 A JPS6336767 A JP S6336767A JP 61180050 A JP61180050 A JP 61180050A JP 18005086 A JP18005086 A JP 18005086A JP S6336767 A JPS6336767 A JP S6336767A
Authority
JP
Japan
Prior art keywords
water
edible film
food
mixture
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61180050A
Other languages
Japanese (ja)
Other versions
JPH07121200B2 (en
Inventor
Katsutada Fukui
克任 福井
Hiromi Kobayashi
宏臣 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daicel Corp
Original Assignee
Daicel Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daicel Chemical Industries Ltd filed Critical Daicel Chemical Industries Ltd
Priority to JP61180050A priority Critical patent/JPH07121200B2/en
Publication of JPS6336767A publication Critical patent/JPS6336767A/en
Publication of JPH07121200B2 publication Critical patent/JPH07121200B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Seasonings (AREA)
  • Formation And Processing Of Food Products (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Seeds, Soups, And Other Foods (AREA)
  • Jellies, Jams, And Syrups (AREA)

Abstract

PURPOSE:To obtain an edible film which can be easily disintegrated by immersing in water to release a food, by mixing a micro-fibrillated water-insoluble natural fiber with a polyhydroxy compound and using the mixture as a binder. CONSTITUTION:Microfibrillated water-insoluble natural fiber such as cellulose, chitin, chitosan, etc., and a polyhydroxy compound such as monosaccharide, oligosaccharide, polysaccharide, polyhydric alcohol, pullulan, gelatin, pectin, etc., are suspended in water. A food having the form of powder, granule, flake, etc., is mixed to the obtained suspension and the mixture is cast and dried in the mixed state.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、粉末状、粒子状、薄片状などの形状を有する
補助食品、例えば香辛料、調味料、薬味などを含有した
フィルムに関するものであシ、湯や水に接触したとき、
それらの補助食品をもとの形状に分離放出する可食性フ
ィルムに関するものであって、主な用途はインスタント
食品の補助材料である。
[Detailed Description of the Invention] <Industrial Application Field> The present invention relates to a film containing supplementary foods in the form of powders, particles, flakes, etc., such as spices, seasonings, condiments, etc. When it comes into contact with hot water or water,
The present invention relates to an edible film that separates and releases these supplementary foods into their original form, and is mainly used as an auxiliary material for instant foods.

〈従来の技術〉 熱湯をかけてすぐ食卓に供したシ、あるいはアルミ箔な
どの耐熱性容器に収められた食品セットに水を入れ、容
器ごと加熱すれば、すぐに食べられる方式など、インス
タント食品の普及はめざましいものがあり、めん類、米
飯類が主であるが、数量・品種とも拡大傾向にある。
<Conventional technology> Instant foods are prepared by pouring boiling water over them and serving them immediately, or by pouring water into a food set placed in a heat-resistant container such as aluminum foil and heating the entire container. The spread of food is remarkable, and although noodles and cooked rice are the main products, both quantity and variety are expanding.

殆んどの場合、調味料、香辛料はポリオレフィン、防湿
セロファンなどの小袋に別々に包装されておシ、消費者
は一旦これを容器から取出して小袋を破り、中味を容器
に戻す必要がある。
In most cases, seasonings and spices are packaged separately in sachets made of polyolefin, moisture-proof cellophane, etc., and the consumer must remove them from the container, tear the sachet, and return the contents to the container.

調味料、香辛料の量が消費者の好みにより調整できる便
宜はあるが、大多数の消費者には袋を破く際に手を汚し
たシ、過剰分の始末に困ったシしてわずられしいのが現
状である。
Although it is convenient for consumers to be able to adjust the amount of seasonings and spices according to their preferences, the majority of consumers are worried about getting their hands dirty when opening the bag or having trouble disposing of the excess. The current situation is difficult.

〈問題点を解決するための手段〉 セルロース、キチン、キトサンなどの職維物質は天然に
多量に存在しており、特に精製セルロースは工業的に長
い歴史があるが、キチン、キトサンも近年は精製物が工
業的に製造されている。これらの天然繊維は水不溶性で
あるが、叩解して水に懸濁させてスラリーとしたものは
抄紙法によってシートとすることができる。
<Means to solve the problem> Cellulose, chitin, chitosan, and other fiber substances exist in large quantities in nature, and purified cellulose in particular has a long history of industrial use, but chitin and chitosan have also been refined in recent years. Things are manufactured industrially. Although these natural fibers are insoluble in water, a slurry obtained by beating and suspending them in water can be made into a sheet by a papermaking method.

さらに最近セルロース繊維を特別な方法でミクロフィブ
リル化させる方法が開発された。
Furthermore, a special method of microfibrillating cellulose fibers has recently been developed.

これはセルロース繊維を水に懸濁し、少なくとも200
 kg/、4の圧力差で小径オリスイスを通過させ、高
速で器壁に衝突させて急速に減速させることによって、
剪断力を繊維に与えるもので、この操作を繰返し行うこ
とにより、セルロース繊維をミクロフィブリル単位に分
割するものである(特公昭6O−3855)。
This involves suspending cellulose fibers in water and adding at least 200
By passing through a small-diameter Oriswiss with a pressure difference of 4 kg/kg, colliding with the vessel wall at high speed and rapidly decelerating,
A shearing force is applied to the fibers, and by repeating this operation, the cellulose fibers are divided into microfibril units (Japanese Patent Publication No. 6O-3855).

Gaufin  社のホモジナイザーは、この処理を行
うのに適当な装置である。
A Gaufin homogenizer is a suitable device for carrying out this process.

このような繊維のミクロフィブリル化はキチン又はキト
サンに対しても同様に適用しうる。
Such microfibrillation of fibers can be applied to chitin or chitosan as well.

ミクロフィブリル化させたセルロース、キチン、キトサ
ンは、所謂食物繊維として食べることができ、しかも口
あたシが良好なことが見出されている。又、上記ミクロ
フィブリル化した繊維は、懸濁液から流延すると、緻密
なフィルムを生成する。
It has been found that microfibrillated cellulose, chitin, and chitosan can be eaten as so-called dietary fibers and have good mouthfeel. The microfibrillated fibers also produce a dense film when cast from a suspension.

一方我々は、このようにして得られたフィルムは耐水性
があり、容易に水によって崩壊しないが懸濁液中に糖類
やCMC,ペクチンなどの水溶性ポリヒドロキシ化合物
を共存させ流延すると、流延フィルムは水に浸漬すると
容易に崩壊し、もとの懸濁液になる性質があることを見
出した。
On the other hand, we have found that the film obtained in this way is water resistant and does not easily disintegrate with water, but when cast in the presence of water-soluble polyhydroxy compounds such as sugars, CMC, and pectin in the suspension, It has been found that the rolled film easily disintegrates when immersed in water and returns to its original state of suspension.

我々は、ミクロフィブリル化したセルロース、キチン、
キトサンなどの懸濁液にポリヒドロキシ化合物の共存下
、粉末状、粒子状、薄片状などの食品を混合し、混合状
態で流延乾燥すると、食品を含有するフィルムが得られ
、そのフィルムは水に浸漬すると容易に崩壊して食品を
再放出する性質があることをみとめた。
We use microfibrillated cellulose, chitin,
When a powdered, particulate, or flaky food is mixed with a suspension such as chitosan in the coexistence of a polyhydroxy compound, and the mixed state is cast and dried, a film containing the food is obtained, and the film is made of water. It was found that when immersed in water, it disintegrates easily and re-releases the food.

〈発明の構成〉 本発明は、ミクロフィブリル化させた水不溶性天然繊維
とポリヒドロキシ化合物な固結剤として含有することを
特徴とする、水に容易に分散する可食性フィルムに関す
るものである。
<Structure of the Invention> The present invention relates to an edible film that is easily dispersed in water and is characterized by containing microfibrillated water-insoluble natural fibers and a polyhydroxy compound as a solidifying agent.

水不溶性天然繊維は、セルロース、キチン又はキトサン
を用いることができる。ポリヒドロキシ化合物は、本発
明の目的から当然に可食性の物質の中から選ぶことがで
きる。その例をあげれば、澱粉、デキストリン、グルコ
ース、しょ糖、ペクチン、アガロース、カルボキシメチ
ルセルロース、プルランなどである。これらのうち、天
然の食品に含有されているものは必ずしも精製した形で
使用する必要はなく、それらを主成分として含有するも
のであってもよい。
Cellulose, chitin, or chitosan can be used as the water-insoluble natural fiber. For the purpose of the present invention, the polyhydroxy compound can naturally be selected from among edible substances. Examples include starch, dextrin, glucose, sucrose, pectin, agarose, carboxymethylcellulose, pullulan, etc. Among these, those contained in natural foods do not necessarily need to be used in purified form, and may contain them as main ingredients.

例えば、澱粉の代シに米粉、麦粉、豆粉なとでもよい。For example, you can use rice flour, wheat flour, or bean flour as a substitute for starch.

あるいは、それらのポリヒドロキシ化合物がアミノ酸や
蛋白質を含有し、それを脱水すれば粉末化しうるもの、
例えば醤油、ソース、味噌のような調味料などであって
もよい。
Alternatively, those polyhydroxy compounds contain amino acids and proteins, and can be turned into powder by dehydrating them.
For example, it may be a seasoning such as soy sauce, sauce, or miso.

本発明の可食性フィルムの目的は、香辛料、調味料、薬
味などを担持させたものとして提供することにある。香
辛料、薬味とは、例えば唐辛子、山積、胡麻、肉桂、に
んにく、ねぎ、月桂樹、サフラン、わさび、しょうが等
の乾燥して小粒子状で得られるものが本発明を応用する
ことができる。
The purpose of the edible film of the present invention is to provide it as a film carrying spices, seasonings, condiments, etc. The present invention can be applied to spices and condiments that can be obtained in the form of dried small particles, such as chili pepper, yam, sesame, cinnamon, garlic, green onion, bay, saffron, wasabi, and ginger.

この場合のわさび、しょうがは植物をスライスしたもの
が該当するが、本発明はこれらの植物をおろし金ですり
おろしたもめも使用す石ことができる。
In this case, wasabi and ginger are sliced plants, but the present invention can also use stones made by grating these plants with a grater.

調味料とは、前述した醤油、ソース、味噌などのほか、
調味成分を多量に含有するけずシぶし、だしじゃこ、干
しえび、こんぶなどの粉末や小片状のものを含む広義の
ものとし、これらも本発明によりフィルム状とすること
ができる。
Seasonings include the aforementioned soy sauce, sauce, miso, etc.
It is broadly defined to include powders and pieces of kezu-shibushi, dashijako, dried shrimp, konbu, etc., which contain a large amount of seasoning ingredients, and these can also be made into a film according to the present invention.

本発明の可食性フィルム中の固結剤の量は食品の種類に
よって異なるが、食品に対し】〜10%程度が適当であ
る。
The amount of the solidifying agent in the edible film of the present invention varies depending on the type of food, but is suitably about 10% to 10% of the food.

水不溶性繊維のミクロフィブリル化は、繊維の水懸濁液
を特定の方法で処理することにより、ミクロフィブリル
化繊維の懸濁液として得られるが、ミクロフィブリル化
繊維の懸濁液にポリヒドロキシ化合物及び食品を加えて
混合し、該混合液を流延乾燥すればフィルムが得られる
。又繊維の水懸濁液を処理してミクロフィブリル化させ
る際にポリヒドロキシ化合物を共存させておいてもよい
Microfibrillation of water-insoluble fibers is obtained as a suspension of microfibrillated fibers by treating an aqueous suspension of fibers in a specific manner. A film is obtained by adding and mixing the mixture and drying the mixture by casting and drying the mixture. Further, a polyhydroxy compound may be present when processing an aqueous suspension of fibers to form microfibrillation.

〈発明の効果〉 本発明の可食性フィルムは調味料、香辛料、薬味などを
別々に、あるいは組合わせて担持させ、インスタント食
品の補助食品として提供することができる。即ち、イン
スタントめん、インスタントかゆなどのほか、お茶漬な
どに用い、湯茶をかけて直ちに食用に供することができ
るので便利であり、消費者個人による量の調節もまた可
能であるなど、食品のデザインを豊富にする材料を提供
するものである。
<Effects of the Invention> The edible film of the present invention can carry seasonings, spices, condiments, etc. separately or in combination, and can be provided as a supplement to instant foods. In other words, it is convenient because it can be used for instant noodles, instant porridge, etc., as well as tea pickles, etc., and can be eaten immediately by adding hot water, and the amount can be adjusted by the individual consumer. It provides materials that enrich the

以下に実施例をあげて本発明を説明するが、本発明はこ
れによシ限定されるものではない。
The present invention will be explained below with reference to Examples, but the present invention is not limited thereto.

実施例1゜ 分子量約20万のプルラン(林原生物化学研究所製)2
0gを水1000+++/に溶解し、さらに2紙を粉砕
した粉末10Iを加えて懸濁した。
Example 1 Pullulan with a molecular weight of approximately 200,000 (manufactured by Hayashibara Biochemical Research Institute) 2
0g was dissolved in 1000+++/water, and powder 10I obtained by crushing two pieces of paper was added and suspended.

懸濁液をホモジナイザー(Qailin社製15M−8
TA)に仕込み、420kg/、iの圧力をかけて25
回通過させ、プルランを含むミクロフィブリル化セルロ
ースの懸濁液を得た。
The suspension was homogenized using a homogenizer (15M-8 manufactured by Qailin).
TA) and apply a pressure of 420 kg/i to 25
The suspension was passed through twice to obtain a suspension of microfibrillated cellulose containing pullulan.

上記ミクロフィブリル化セルロース/プルランの懸濁液
に、たら子乾燥品70g、乾海苔粉末20g、食塩5g
、グルタミン酸ソーダ3Iを水1000x/と混合した
スラリーを加えて混合し、ポリエステルフィルム基板上
に流延乾燥してフィルムを作成した。
Add 70 g of dried cod roe, 20 g of dried seaweed powder, and 5 g of salt to the above microfibrillated cellulose/pullulan suspension.
A slurry of sodium glutamate 3I mixed with 1000x of water was added and mixed, and the mixture was cast and dried on a polyester film substrate to form a film.

得られた乾燥フィルムは、水又は湯で容易に崩壊して、
たら子、乾海苔粉末を放出するのでお茶漬用に好適であ
った。
The obtained dry film disintegrates easily with water or hot water,
Since it releases cod roe and dried seaweed powder, it was suitable for ochazuke.

実施例2゜ f紙粉末20gを水1000+x/に懸濁し、ホモジナ
イザーに仕込み、300kg/cAの圧力なかけて30
回通過させ、ミクロフィブリル化セルロースの懸濁液を
得た。
Example 2 20g of paper powder was suspended in 1000+x/water, charged into a homogenizer, and heated at 300 kg/cA under pressure.
The mixture was passed through the tube twice to obtain a suspension of microfibrillated cellulose.

味噌(水分52%)400gを熱水1600肩lにとか
したものを上記ミクロフィブリル化セルロース懸濁液に
混合し、流延乾燥して味噌を含有する乾燥フィルムを得
た。得られた乾燥フィルムはインスタントみそラーメン
の味噌用として好適であった。
400 g of miso (moisture 52%) was dissolved in 1,600 liters of hot water and mixed with the above microfibrillated cellulose suspension, followed by casting and drying to obtain a dry film containing miso. The obtained dry film was suitable for use as miso for instant miso ramen.

Claims (3)

【特許請求の範囲】[Claims] (1)ミクロフィブリル化させた水不溶性天然繊維と、
ポリヒドロキシ化合物の混合物を固結剤として含有する
ことを特徴とする、水に容易に分散する可食性フィルム
(1) Microfibrillated water-insoluble natural fiber,
An edible film easily dispersible in water, characterized in that it contains a mixture of polyhydroxy compounds as a caking agent.
(2)水不溶性天然繊維がセルロース、キチン又はキト
サンを主成分とするものである特許請求範囲第1項記載
の、水に容易に分散する可食性フィルム。
(2) The edible film that is easily dispersed in water according to claim 1, wherein the water-insoluble natural fiber is mainly composed of cellulose, chitin, or chitosan.
(3)ポリヒドロキシ化合物が単糖類、オリゴ糖類、多
糖類又はそれらの誘導体、多価アルコール、プルラン、
ゼラチン又はペクチンである特許請求範囲第1項又は第
2項記載の水に容易に分散する可食性フィルム。
(3) The polyhydroxy compound is monosaccharides, oligosaccharides, polysaccharides or derivatives thereof, polyhydric alcohols, pullulan,
An edible film easily dispersible in water according to claim 1 or 2, which is gelatin or pectin.
JP61180050A 1986-08-01 1986-08-01 Edible film that disperses easily in water Expired - Lifetime JPH07121200B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61180050A JPH07121200B2 (en) 1986-08-01 1986-08-01 Edible film that disperses easily in water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61180050A JPH07121200B2 (en) 1986-08-01 1986-08-01 Edible film that disperses easily in water

Publications (2)

Publication Number Publication Date
JPS6336767A true JPS6336767A (en) 1988-02-17
JPH07121200B2 JPH07121200B2 (en) 1995-12-25

Family

ID=16076609

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61180050A Expired - Lifetime JPH07121200B2 (en) 1986-08-01 1986-08-01 Edible film that disperses easily in water

Country Status (1)

Country Link
JP (1) JPH07121200B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02227464A (en) * 1989-02-28 1990-09-10 Nitta Gelatin Inc Polymer compounding material, polymer compound therefrom and production of polymer compound
JPH05236885A (en) * 1991-07-17 1993-09-17 Tazawa Toshihiko Flavoring and refreshing food formed into film
JP2016027795A (en) * 2014-07-10 2016-02-25 国立大学法人鳥取大学 Technology for heightening grain powder dough strength by bio-nanofiber
JP2017535519A (en) * 2014-09-15 2017-11-30 プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー Consumer products comprising chitin, lignin, and polymers or copolymers
WO2018149983A1 (en) * 2017-02-17 2018-08-23 Lts Lohmann Therapie-Systeme Ag Structured orodispersible films

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109385100A (en) * 2018-11-21 2019-02-26 四川农业大学 A kind of preparation method of bean dregs dietary fiber edible packaging composite membrane

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02227464A (en) * 1989-02-28 1990-09-10 Nitta Gelatin Inc Polymer compounding material, polymer compound therefrom and production of polymer compound
JPH05236885A (en) * 1991-07-17 1993-09-17 Tazawa Toshihiko Flavoring and refreshing food formed into film
JP2016027795A (en) * 2014-07-10 2016-02-25 国立大学法人鳥取大学 Technology for heightening grain powder dough strength by bio-nanofiber
JP2017535519A (en) * 2014-09-15 2017-11-30 プロクター アンド ギャンブル インターナショナル オペレーションズ エス エー Consumer products comprising chitin, lignin, and polymers or copolymers
WO2018149983A1 (en) * 2017-02-17 2018-08-23 Lts Lohmann Therapie-Systeme Ag Structured orodispersible films
CN110300576A (en) * 2017-02-17 2019-10-01 Lts勒曼治疗系统股份公司 The orodispersible film of structuring
AU2018221785B2 (en) * 2017-02-17 2021-08-05 Lts Lohmann Therapie-Systeme Ag Structured orodispersible films

Also Published As

Publication number Publication date
JPH07121200B2 (en) 1995-12-25

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