JPS633573B2 - - Google Patents
Info
- Publication number
- JPS633573B2 JPS633573B2 JP56073108A JP7310881A JPS633573B2 JP S633573 B2 JPS633573 B2 JP S633573B2 JP 56073108 A JP56073108 A JP 56073108A JP 7310881 A JP7310881 A JP 7310881A JP S633573 B2 JPS633573 B2 JP S633573B2
- Authority
- JP
- Japan
- Prior art keywords
- salt
- amount
- sodium
- potassium chloride
- stevioside
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 62
- 239000001103 potassium chloride Substances 0.000 claims description 31
- 235000011164 potassium chloride Nutrition 0.000 claims description 31
- 150000003839 salts Chemical class 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 17
- UEDUENGHJMELGK-HYDKPPNVSA-N Stevioside Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O UEDUENGHJMELGK-HYDKPPNVSA-N 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- 229940013618 stevioside Drugs 0.000 claims description 16
- OHHNJQXIOPOJSC-UHFFFAOYSA-N stevioside Natural products CC1(CCCC2(C)C3(C)CCC4(CC3(CCC12C)CC4=C)OC5OC(CO)C(O)C(O)C5OC6OC(CO)C(O)C(O)C6O)C(=O)OC7OC(CO)C(O)C(O)C7O OHHNJQXIOPOJSC-UHFFFAOYSA-N 0.000 claims description 16
- 235000019202 steviosides Nutrition 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- 229940069445 licorice extract Drugs 0.000 claims description 12
- 239000004378 Glycyrrhizin Substances 0.000 claims description 10
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 claims description 10
- 229960004949 glycyrrhizic acid Drugs 0.000 claims description 10
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 claims description 10
- 235000019410 glycyrrhizin Nutrition 0.000 claims description 10
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 claims description 10
- 244000228451 Stevia rebaudiana Species 0.000 claims description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000009938 salting Methods 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 5
- 235000011194 food seasoning agent Nutrition 0.000 claims description 5
- 239000001630 malic acid Substances 0.000 claims description 5
- 235000011090 malic acid Nutrition 0.000 claims description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 241000202807 Glycyrrhiza Species 0.000 claims description 2
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 claims description 2
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 2
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 claims description 2
- 229940010454 licorice Drugs 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 235000013599 spices Nutrition 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 39
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 21
- 239000011780 sodium chloride Substances 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 235000019643 salty taste Nutrition 0.000 description 8
- 235000019658 bitter taste Nutrition 0.000 description 7
- 235000013305 food Nutrition 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 7
- 235000013923 monosodium glutamate Nutrition 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 235000015598 salt intake Nutrition 0.000 description 6
- 229940073490 sodium glutamate Drugs 0.000 description 6
- AANLCWYVVNBGEE-IDIVVRGQSA-L Disodium inosinate Chemical compound [Na+].[Na+].O[C@@H]1[C@H](O)[C@@H](COP([O-])([O-])=O)O[C@H]1N1C(NC=NC2=O)=C2N=C1 AANLCWYVVNBGEE-IDIVVRGQSA-L 0.000 description 5
- 206010013911 Dysgeusia Diseases 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
- 235000013890 disodium inosinate Nutrition 0.000 description 5
- 235000019640 taste Nutrition 0.000 description 5
- 230000002354 daily effect Effects 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 235000021096 natural sweeteners Nutrition 0.000 description 3
- 230000035764 nutrition Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- 229940078499 tricalcium phosphate Drugs 0.000 description 3
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 3
- 235000019731 tricalcium phosphate Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000234282 Allium Species 0.000 description 2
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- 244000000231 Sesamum indicum Species 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 235000005911 diet Nutrition 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 229960002989 glutamic acid Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- -1 licorice extract Chemical compound 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229940086065 potassium hydrogentartrate Drugs 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001384 succinic acid Substances 0.000 description 2
- 229960001367 tartaric acid Drugs 0.000 description 2
- 240000002234 Allium sativum Species 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 206010024264 Lethargy Diseases 0.000 description 1
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 1
- 241000269851 Sarda sarda Species 0.000 description 1
- KPQJOKRSYYJJEL-VLQRKCJKSA-K [Na+].[Na+].CC1(C)[C@H](CC[C@@]2(C)[C@H]1CC[C@]1(C)[C@@H]2C(=O)C=C2[C@@H]3C[C@](C)(CC[C@]3(C)CC[C@@]12C)C([O-])=O)O[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)C([O-])=O)C([O-])=O Chemical compound [Na+].[Na+].CC1(C)[C@H](CC[C@@]2(C)[C@H]1CC[C@]1(C)[C@@H]2C(=O)C=C2[C@@H]3C[C@](C)(CC[C@]3(C)CC[C@@]12C)C([O-])=O)O[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)C([O-])=O)C([O-])=O KPQJOKRSYYJJEL-VLQRKCJKSA-K 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 206010061428 decreased appetite Diseases 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- FRRMMWJCHSFNSG-UHFFFAOYSA-N diazanium;propanedioate Chemical compound [NH4+].[NH4+].[O-]C(=O)CC([O-])=O FRRMMWJCHSFNSG-UHFFFAOYSA-N 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940048879 dl tartaric acid Drugs 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 229940029982 garlic powder Drugs 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 230000036449 good health Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 208000019622 heart disease Diseases 0.000 description 1
- 235000006486 human diet Nutrition 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 208000017169 kidney disease Diseases 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 235000016337 monopotassium tartrate Nutrition 0.000 description 1
- 239000004223 monosodium glutamate Substances 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 230000001575 pathological effect Effects 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- KYKNRZGSIGMXFH-ZVGUSBNCSA-M potassium bitartrate Chemical compound [K+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O KYKNRZGSIGMXFH-ZVGUSBNCSA-M 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 235000019583 umami taste Nutrition 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Landscapes
- Seasonings (AREA)
Description
〔発明の利用分野〕
本発明は、低ナトリウム散布鹹味料、即ち、低
ナトリウム振り掛け食品に関する。
〔発明の背景〕
食塩は調味料として最も基本的なものである。
殆ど全ての食品は食塩又は食塩を含有する調味料
により味付けされている。また食塩は、血液中の
最も含量の多い無機塩であると同時に、植物性食
品から体内に取りこまれたカリウム塩と複分解し
てこれを体外に排出する生理作用を有するから、
日々汗や尿で失われる量の補給は栄養上欠かせな
いものである。しかし近年に至り、食温の摂り過
ぎが高血圧、心臓疾患及び腎疾患と密接な関連の
あることが明瞭となり、特に日本人の場合、欧米
各国の人々と比べて食塩の摂取量が著しく高いこ
とが問題視されるようになつて来た。因に、厚生
省の行つた昭和54年の国民栄養調査によると、本
邦人の1日当たり食塩摂取量は13.1gで、栄養所
要量の10.0gを3.1gも上回つているとされてい
る。また世帯業態別の統計では、農家の平均15.2
gであるのに対し、非農家のそれは12.6gであ
り、特に専業農家では16.5gと高い水準にある。
さらに、青森、秋田両県を対象とする弘前大学の
調査によると、青森県では中学生でもその平均血
圧が全国平均より高かつたが、減塩指導の結果、
全国平均レベルまで低下したといわれる。なお、
栄養専門家の意見によると、中年以後は、日々の
食塩摂取量を5g以下に減じるのが健康と長生き
のコツであるとのことである。
このように、過度の食塩摂取が有害であること
は周知であるが、反面、食塩は生理物質であるか
ら、長期に亘る食塩の摂取不足は消化液の分泌減
退、胃液減少、食欲減退、全身の脱力、懈怠、疲
労、精神不安などの病的状態を惹き起こす。さら
にヒトの食生活において、鹹味が味の基本として
重要な働きをしていることは周知であるから、如
何に減塩が望ましいといつても、現実に疾患に罹
つていない限り、日量10g以下に減らすのは容易
ではない。尤も過度の摂取が健康に悪影響を与え
るのは食塩、即ちNaClそのものではなくて、食
塩中のNa+である。そこで従来から、調味料とし
て常用する程度では全く副作用がない鹹味料とし
て、塩化カリウムが食塩代用品として用いられて
来た。ところが、塩化カリウムは特有の苦味を有
するため、食塩代用品として満足すべきものでは
ない。そこで、より良質の食塩代用品の研究が試
みられ、例えば特開昭49−126854号公報による
と、焼塩末とd―酒石酸水素カリウムとクエン
酸、コハク酸、dl−リンゴ酸、dl―酒石酸等の有
機酸又はその非ナトリウム塩とL−グルタミン酸
又はその非ナトリウム塩と乳糖又はデキストリン
との混合物から成る代用粉末食塩につき記載され
ているが、これは実質的に食塩と有機酸とグルタ
ミン酸との混合物であつて、発明者等の追試の結
果、酒石酸水素カリウムを添加しても特に鹹味が
増加するとは認められなかつた。また特公昭47−
13698号公報には、塩化カリウムに食塩を添加す
ることにより鹹味が増強されると同時に苦味の減
少することが示されているが、この場合も、実用
的な配合で10〜20%のヒトが苦味を感じている。
さらに特公昭44−6235号公報によると、塩基性ア
ミノ酸のコハク酸塩及びマロン酸アンモニウム又
はイノシン酸ソーダを食塩代替鹹味料として用い
ることが提案されているが、これらはいずれも高
価なものであるから、日常の食塩代用品としては
現実性がない。かつ、本発明者が追試して得た評
価は「食塩に近い鹹味」という点で不満足なもの
であつた。
凡そ、実用的な日常の食生活における食塩代用
品となりうるためには、先づ第一に価格が安く、
第二に味が佳良で、第三に食品衛生法上、食品又
は通常の食品添加物の範畴に属するものであるこ
とが必須の要件である。仮にある鹹味物質の鹹味
が如何に良好であつても、そのものが高価であつ
たり又は医薬品としての承認を受ける必要があれ
ば、到底実用的な食塩代替品として役立たない。
〔発明の目的〕
本発明は、上記3要件をほぼ満足しうる食塩代
替組成物、より詳細には低ナトリウム散布鹹味料
を提供することを目的とする。
〔目的達成のための手段〕
本発明に係る低ナトリウム散布甘味料は、上記
の目的を達成するため、必須成分として、塩化カ
リウムAと、該A成分の粒子又は結晶の周囲を被
覆して存在し、かつA成分に対して0.04〜0.25重
量%の、グリチルリチンもしくはそれに対応する
量の甘草甘味成分濃縮物(甘草エキス)及びステ
ビオサイド、モノグルコシルステビオサイドもし
くはそれらに対応する量のステビア甘味成分濃縮
物(ステビアエキス)からなる群から選ばれた天
然甘味成分Bと、A,B両成分の合計量に対して
0.5〜3重量%の可食性多価有機酸Cと、任意量
の食塩Dとを含む乾燥混合物であることを特徴と
する。
本発明者等は前述の3要件を満たしうるような
非ナトリウム鹹味料について広汎かつ組織的な研
究を行つた結果、基本鹹味料として塩化カリウム
が最も適当であるとの結論に達し、そこで塩化カ
リウムの苦味除去手段につき探索を進めたとこ
ろ、グリチルリチンもしくは甘草エキス又はステ
ビオサイド、モノグリコシルステビオサイドもし
くはステビア抽出エキスが塩化カリウムの苦味を
消去できることを見出した。即ち、塩化カリウム
にグリチルリチンもしくは甘草エキス又はステビ
オサイドもしくはステビアエキスを0.04〜0.25%
の範囲で添加すると、恐らくこれら遅効性天然甘
味料の呈味作用に因り、塩化カリウムの苦味が著
しく軽減されるとの知見を得た。下表(第1表及
び第2表)は、種々の割合で精製甘草エキス又は
ステビオサイドを含む塩化カリウムを25名のパネ
ラーが二重盲検法により評価した結果である。な
お本実験において、試料は、表示の甘草エキス又
はステビオサイドに夫々5重量%溶液になるよう
に水を加えて溶解後、この溶液を空炒りした塩化
カリウム100gに撹拌しながら添加し、60℃で乾
燥したものである。また、パネラーの評価は無添
加の塩化カリウムを対照として以下の基準に基い
て行われた。
対照に比べ非常に良好 優
〃 良好 良
〃 やゝ良好 可
〃 同等又は不良 不可
[Field of Application of the Invention] The present invention relates to a low-sodium sprinkling flavoring agent, that is, a low-sodium sprinkling food. [Background of the Invention] Salt is the most basic seasoning.
Almost all foods are flavored with salt or seasonings containing salt. In addition, salt is the most abundant inorganic salt in the blood, and at the same time has the physiological effect of decomposing potassium salts taken into the body from plant foods and excreting them from the body.
Replenishing the amount lost daily through sweat and urine is essential for nutrition. However, in recent years, it has become clear that eating too much food is closely related to high blood pressure, heart disease, and kidney disease, and Japanese people in particular have significantly higher salt intake than people from Western countries. has come to be seen as a problem. Incidentally, according to the 1978 National Nutrition Survey conducted by the Ministry of Health and Welfare, the daily salt intake of Japanese people is 13.1g, which is 3.1g more than the nutritional requirement of 10.0g. In addition, statistics by household business type show that the average for farmers is 15.2%.
g, while that for non-farmers is 12.6g, and the level is particularly high for full-time farmers at 16.5g.
Furthermore, according to a Hirosaki University survey covering both Aomori and Akita prefectures, the average blood pressure of junior high school students in Aomori prefecture was higher than the national average, but as a result of salt reduction instruction,
It is said that this has fallen to the national average level. In addition,
According to the opinion of nutrition experts, the key to good health and longevity is to reduce daily salt intake to 5g or less after middle age. It is well known that excessive salt intake is harmful, but on the other hand, salt is a physiological substance, so long-term lack of salt intake can lead to decreased secretion of digestive juices, decreased gastric fluid, decreased appetite, and systemic health problems. It causes pathological conditions such as weakness, lethargy, fatigue, and mental anxiety. Furthermore, it is well known that salty taste plays an important role in the human diet as the basis of taste, so no matter how desirable it is to reduce salt intake, unless you are actually suffering from a disease, It is not easy to reduce the amount to less than 10g. Of course, it is not the salt itself, that is, NaCl, but the Na + in the salt that has an adverse effect on health if consumed in excess. Therefore, potassium chloride has traditionally been used as a salt substitute as a salting agent that has no side effects when used regularly as a seasoning. However, since potassium chloride has a unique bitter taste, it is not satisfactory as a salt substitute. Therefore, attempts were made to research better quality salt substitutes, and for example, according to JP-A-49-126854, baked salt powder, d-potassium hydrogen tartrate, citric acid, succinic acid, dl-malic acid, dl-tartaric acid, etc. A salt substitute powder consisting of a mixture of an organic acid or a non-sodium salt thereof, L-glutamic acid or a non-sodium salt thereof, and lactose or dextrin is described, which is essentially a mixture of salt, an organic acid, and glutamic acid. However, as a result of additional tests by the inventors, it was not found that the addition of potassium hydrogen tartrate did not particularly increase the salty taste. Also, special public service in 1977-
Publication No. 13698 shows that adding salt to potassium chloride enhances the salty taste and at the same time reduces the bitter taste. I feel bitterness.
Furthermore, according to Japanese Patent Publication No. 44-6235, it has been proposed to use succinates of basic amino acids, ammonium malonate, or sodium inosinate as a salt substitute, but these are all expensive. Therefore, it is not practical as an everyday salt substitute. In addition, the evaluation obtained by the present inventor in a follow-up test was unsatisfactory in that it had a "salty taste similar to common salt." In order for it to be a practical salt substitute in daily diet, it must first of all be cheap.
Second, it must have a good taste, and third, under the Food Sanitation Act, it must belong to the category of food or normal food additives. No matter how good the saltiness of a salty substance is, if it is expensive or requires approval as a pharmaceutical, it will never be useful as a practical salt substitute. [Object of the Invention] An object of the present invention is to provide a salt substitute composition, more specifically, a low-sodium sprinkled salting agent, which can substantially satisfy the above three requirements. [Means for achieving the object] In order to achieve the above-mentioned object, the low-sodium sprinkled sweetener according to the present invention contains potassium chloride A as an essential component, and the particles or crystals of the component A are coated around the particles or crystals. and 0.04 to 0.25% by weight based on component A, glycyrrhizin or a corresponding amount of licorice sweet component concentrate (licorice extract), and stevioside, monoglucosyl stevioside or a corresponding amount of stevia sweet component concentrate ( Natural sweetening ingredient B selected from the group consisting of stevia extract) and the total amount of both ingredients A and B.
It is characterized by being a dry mixture containing 0.5 to 3% by weight of an edible polyvalent organic acid C and an arbitrary amount of salt D. As a result of extensive and systematic research into non-sodium salting agents that can satisfy the three requirements mentioned above, the present inventors came to the conclusion that potassium chloride is the most suitable basic salting agent. As a result of our search for means for removing the bitterness of potassium chloride, we discovered that glycyrrhizin, licorice extract, stevioside, monoglycosylstevioside, or stevia extract can eliminate the bitterness of potassium chloride. That is, 0.04 to 0.25% glycyrrhizin or licorice extract or stevioside or stevia extract to potassium chloride.
It has been found that the bitterness of potassium chloride is significantly reduced when potassium chloride is added in a range of . The tables below (Tables 1 and 2) are the results of a double-blind evaluation by 25 panelists of potassium chloride containing purified licorice extract or stevioside in various proportions. In this experiment, the sample was prepared by adding water to the indicated licorice extract or stevioside to make a 5% solution by weight, then adding this solution to 100 g of air-roasted potassium chloride with stirring, and heating at 60°C. It is dry. In addition, evaluation by panelists was conducted based on the following criteria using additive-free potassium chloride as a control. Very good compared to control Excellent 〃 Good Good 〃 Fairly good Fair 〃 Same or poor Not good
【表】【table】
【表】
上記両表から明らかなように、甘草エキス及び
ステビオサイドは共に同様の傾向を示し、塩化カ
リウムに対し0.02%の添加では「良」及び「可」
と評価した者も多少あるが、「不可」の評価が圧
倒的に多い。0.04%になると「不可」が無くな
り、全員が「可」以上の評価をしている。0.1%
及び0.15%では大多数のパネラーが「優」の評価
を与えている。0.35%になると旨味、後味共に
「不可」と評価したものがかなり現れて来るが、
これは天然甘味料独特の甘味が強く現れるからで
ある。なお、当然予想されることであるが、ステ
ビオサイドに比べ後味の甘味が強い甘草エキスで
は、これを「不可」とする者がやゝ多くなつてい
る。適当と考えられる甘草エキス及びステビオサ
イドの添加量は、共に塩化カリウムに対し0.04〜
0.25%、好ましくは0.08〜0.2%の範囲内である。
以上の実験事実から、塩化カリウムに対するグ
リチルリチンもしくは甘草エキス又はステビオサ
イドもしくはステビアエキスの添加が前者の苦味
を打ち消すことは明らかであるが、反面天然甘味
料のもつ後味に対する対策が残されている。そこ
で、発明者等は天然甘味料の後味を除去する手段
につき研究した結果、リンゴ酸、クエン酸、酒石
酸又はコハク酸のような多価有機酸の添加が好ま
しい後味改善効果を齎すことを見出した。
下表(第3表)は、0.1重量%の割で精製甘草
エキスを含む空炒り塩化カリウム各100gに対し、
種々の割合で上記有機酸を添加したサンプルにつ
き、25名のパネラーが無添加(甘草エキスのみ添
加)の空炒り塩化カリウムを対照として評価した
結果を示す。[Table] As is clear from both tables above, both licorice extract and stevioside showed similar trends, and when added at 0.02% to potassium chloride, they were evaluated as "good" and "fair".
Although there are some people who rated it as ``unacceptable,'' the overwhelming majority were rated as ``unacceptable.'' When it reaches 0.04%, there are no "unsatisfactory" ratings, and everyone is rated "acceptable" or higher. 0.1%
and 0.15%, the majority of panelists gave an "excellent" rating. At 0.35%, there are quite a few items that are rated as "unacceptable" for both umami and aftertaste.
This is because the sweetness unique to natural sweeteners appears strongly. As expected, an increasing number of people say that licorice extract has a sweeter aftertaste than stevioside. The amount of licorice extract and stevioside added is considered to be 0.04 to 0.04 to potassium chloride.
0.25%, preferably within the range of 0.08-0.2%. From the above experimental facts, it is clear that the addition of glycyrrhizin, licorice extract, stevioside or stevia extract to potassium chloride cancels out the bitterness of the former, but on the other hand, countermeasures remain to be taken against the aftertaste of natural sweeteners. Therefore, the inventors researched ways to remove the aftertaste of natural sweeteners and found that the addition of polyhydric organic acids such as malic acid, citric acid, tartaric acid, or succinic acid brings about a favorable aftertaste improving effect. . The table below (Table 3) shows that for each 100g of air-roasted potassium chloride containing purified licorice extract at a rate of 0.1% by weight,
The results are shown below, in which 25 panelists evaluated samples to which the above-mentioned organic acids were added in various proportions, using air-roasted potassium chloride without additives (only licorice extract was added) as a control.
以下、実施例により発明実施の諸態様を説明す
るが、これは単なる例示であつて、発明精神の限
定を意味しないものである。
実施例 1
(食塩味を有する低ナトリウム鹹味組成物)
〔処 方〕
(1) 塩化カリウム 55.0
(2) 塩化ナトリウム 41.85
(3) リンゴ酸三カルシウム 1.0
(4) リンゴ酸 1.0
(5) グルタミン酸ナトリウム 0.8
(6) イノシン酸ナトリウム 0.1
(7) クアニル酸ナトリウム 0.1
(8) クリチルリチンナトリウム 0.15
〔製 法〕
塩化カリウムを約500℃に加熱後、撹拌放冷し
ながらクリチルリチンナトリウム0.15gを水5ml
中に溶かした溶液を噴霧して塩化カリウム粒子の
表面に付着させる。混合物が冷却すれば成分(2)〜
(7)を加え、均一になるまで撹き混ぜ、均質の組成
物とする。
〔評 価〕
以上の組成物Aを対照焼塩Bと25名のパネラー
に二重盲検法により比較させたところ、下記の結
果を得た。
AがBより良いとした者 7
BがAより良いとした者 8
AとBとの間に差が無いとした者 5
以上の結果が示す如く、本発明組成物は食塩と
殆ど変わらず、しかもナトリウム量を1/2以下に
減じることができる。
実施例2 (同上)
〔処 方〕
(1) 塩化カリウム 70.0
(2) 塩化ナトリウム 24.3
(3) リン酸三カルシウム 1.0
(4) クエン酸 1.5
(5) グルタミン酸ナトリウム 3.0
(6) ステビオサイド 0.2
〔製 法〕
実施例1と同様にして塩化カリウムにステビオ
サイドをコーテイングし、以下成分(2)〜(5)を混和
する。
〔評 価〕
本組成物の味も焼塩と殆ど同様で、何等異保を
感じさせなかつた。
実施例3 (同上)
〔処 方〕
(1) 塩化カリウム 66.2
(2) 塩化ナトリウム 30.0
(3) リン酸三カルシウム 1.0
(4) コハク酸 0.5
(5) グルタミン酸ナトリウム 2.0
(6) グリチルリチン二ナトリウム 0.3
〔製 法〕
実施例1と同様にして塩化カリウムにグリチル
リチン二ナトリウムをコーテイングし、以下成分
(2)〜(5)を混和する。
〔評 価〕
食塩と殆ど同様の鹹味を有し、異味を感じさせ
ない。
実施例4 (低ナトリウム振り掛け)
〔処 方〕
(1) 塩化カリウム 31.5
(2) 塩化ナトリウム 58.5
(3) 炒りゴマ 30.0
(4) リン酸三カルシウム 1.0
(5) グルタミン酸ナトリウム 1.0
(6) リンゴ酸 1.0
(7) グリチルリチン 0.1
〔製 法〕
グリチルリチンに水12gを加えて溶解し、これ
を空炒りした塩化カリウムに加え60℃で通風、乾
燥後、成分(2)〜(6)を加え均質に混和する。
実施例5 (同上)
〔処 方〕
(1) 塩化カリウム 65.0
(2) 塩化ナトリウム 35.0
(3) グルタミン酸ナトリウム 10.0
(4) イノシン酸ナトリウム 1.0
(5) リンゴ酸 1.0
(6) ステビオサイド 0.2
(7) かつおぶし粉末 500.0
(8) 切りノリ 50.0
(9) 炒りゴマ 50.0
〔製 法〕
実施例4に準じる。
実施例6 (低ナトリウムオニオンソルト)
〔処 方〕
(1) 塩化カリウム 65.0
(2) 塩化ナトリウム 35.0
(3) グルタミン酸ナトリウム 10.0
(4) イノシン酸ナトリウム 1.0
(5) クエン酸 1.0
(6) グリチルリチン 0.15
(7) 乾燥タマネギ末 100.0
〔製 法〕
実施例4に準じる。
実施例7 (低ナトリウムガーリツクソルト)
〔処 方〕
(1) 塩化カリウム 65.0
(2) 塩化ナトリウム 35.0
(3) グルタミン酸ナトリウム 10.0
(4) イノシン酸ナトリウム 1.0
(5) 酒石酸 1.0
(6) ステビオサイド 0.2
(7) 乾燥ニンニク末100.0
〔製 法〕
実施例4に準じる。
〔発明の効果〕
以上詳述したように、本発明は食塩に極めて近
い鹹味を有する安価な低ナトリウム散布(振り掛
け)鹹味料の提供を可能とすることにより、保健
及び食餌療法上重要な低ナトリウム食に食塩味と
変りのない美味な鹹味付けをすることができるの
で、国民健康の維持、向上及び食餌療法を必要と
する患者の療養に多大の意義を有する。
Hereinafter, various aspects of carrying out the invention will be explained with reference to Examples, but these are merely illustrative and do not mean a limitation on the spirit of the invention. Example 1 (Low sodium salty taste composition with salty taste) [Formulation] (1) Potassium chloride 55.0 (2) Sodium chloride 41.85 (3) Tricalcium malate 1.0 (4) Malic acid 1.0 (5) Monosodium glutamate 0.8 (6) Sodium inosinate 0.1 (7) Sodium quanylate 0.1 (8) Clityrrhizin sodium 0.15 [Production method] After heating potassium chloride to approximately 500°C, add 0.15 g of clityrrhizin sodium to 5 ml of water while stirring and cooling.
The solution dissolved in the solution is sprayed onto the surface of the potassium chloride particles. When the mixture cools, component (2) ~
Add (7) and stir until uniform to form a homogeneous composition. [Evaluation] When the above composition A was compared with the control grilled salt B by 25 panelists in a double-blind test, the following results were obtained. Those who thought that A was better than B 7 Those who thought that B was better than A 8 Those who said that there was no difference between A and B 5 As shown by the above results, the composition of the present invention is almost the same as common salt, Moreover, the amount of sodium can be reduced to less than half. Example 2 (same as above) [Prescription] (1) Potassium chloride 70.0 (2) Sodium chloride 24.3 (3) Tricalcium phosphate 1.0 (4) Citric acid 1.5 (5) Sodium glutamate 3.0 (6) Stevioside 0.2 [Production method] ] Potassium chloride is coated with stevioside in the same manner as in Example 1, and the following components (2) to (5) are mixed. [Evaluation] The taste of the present composition was almost the same as that of grilled salt, and did not give any unpleasant taste. Example 3 (same as above) [Prescription] (1) Potassium chloride 66.2 (2) Sodium chloride 30.0 (3) Tricalcium phosphate 1.0 (4) Succinic acid 0.5 (5) Sodium glutamate 2.0 (6) Disodium glycyrrhizin 0.3 [ Manufacturing method] Potassium chloride was coated with glycyrrhizin disodium in the same manner as in Example 1, and the following ingredients were prepared.
Mix (2) to (5). [Evaluation] It has a salty taste almost similar to table salt, and does not give off any unpleasant taste. Example 4 (Low sodium sprinkle) [Prescription] (1) Potassium chloride 31.5 (2) Sodium chloride 58.5 (3) Roasted sesame seeds 30.0 (4) Tricalcium phosphate 1.0 (5) Sodium glutamate 1.0 (6) Malic acid 1.0 (7) Glycyrrhizin 0.1 [Production method] Add 12 g of water to glycyrrhizin and dissolve it, add this to air-roasted potassium chloride, ventilate at 60℃, dry, then add ingredients (2) to (6) and mix homogeneously. . Example 5 (same as above) [Prescription] (1) Potassium chloride 65.0 (2) Sodium chloride 35.0 (3) Sodium glutamate 10.0 (4) Sodium inosinate 1.0 (5) Malic acid 1.0 (6) Stevioside 0.2 (7) Bonito flakes Powder 500.0 (8) Sliced seaweed 50.0 (9) Roasted sesame seeds 50.0 [Manufacturing method] According to Example 4. Example 6 (Low sodium onion salt) [Formulation] (1) Potassium chloride 65.0 (2) Sodium chloride 35.0 (3) Sodium glutamate 10.0 (4) Sodium inosinate 1.0 (5) Citric acid 1.0 (6) Glycyrrhizin 0.15 ( 7) Dried onion powder 100.0 [Production method] According to Example 4. Example 7 (Low sodium garlic salt) [Formulation] (1) Potassium chloride 65.0 (2) Sodium chloride 35.0 (3) Sodium glutamate 10.0 (4) Sodium inosinate 1.0 (5) Tartaric acid 1.0 (6) Stevioside 0.2 ( 7) Dried garlic powder 100.0 [Production method] According to Example 4. [Effects of the Invention] As described in detail above, the present invention makes it possible to provide an inexpensive low-sodium sprinkled (furikake) salt seasoning that has a salty taste that is extremely similar to that of table salt. Since it is possible to give food a delicious salty flavor similar to that of table salt, it has great significance in maintaining and improving national health and treating patients who require dietary therapy.
Claims (1)
分の粒子又は結晶の周囲を被覆して存在し、かつ
該A成分に対して0.04〜0.25重量%の、グリチル
リチン若しくはそれに対応する量の甘草甘味成分
濃縮物(甘草エキス)及びステビオサイド、モノ
グルコシルステビオサイド若しくはそれらに対応
する量のステビア甘味成分濃縮物(ステビアエキ
ス)からなる群から選ばれた天然甘味成分Bと、
A,B両成分の合計量に対して0.5〜3重量%の
可食性多価有機酸Cと、任意量の食塩Dとを含む
乾燥混合物であることを特徴とする低ナトリウム
散布鹹味料。 2 可食性多価有機酸が、リンゴ酸、クエン酸及
び/又は酒石酸である特許請求の範囲第1項記載
の散布鹹味料。 3 乾燥混合物が、香辛料を含む特許請求の範囲
第1項記載の散布鹹味料。[Scope of Claims] 1. Potassium chloride A as an essential component, and glycyrrhizin or a corresponding glycyrrhizin present in a coating around particles or crystals of component A, and in an amount of 0.04 to 0.25% by weight based on component A. a natural sweetening ingredient B selected from the group consisting of an amount of licorice sweetening ingredient concentrate (licorice extract) and stevioside, monoglucosyl stevioside, or a corresponding amount of stevia sweetening ingredient concentrate (stevia extract);
A low-sodium sprinkled salt seasoning agent characterized in that it is a dry mixture containing an edible polyvalent organic acid C in an amount of 0.5 to 3% by weight based on the total amount of both components A and B, and an arbitrary amount of salt D. 2. The sprayed salting agent according to claim 1, wherein the edible polyvalent organic acid is malic acid, citric acid and/or tartaric acid. 3. The sprinkled salting agent according to claim 1, wherein the dry mixture contains a spice.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56073108A JPS57186460A (en) | 1981-05-14 | 1981-05-14 | Low sodium salt substitute and food containing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56073108A JPS57186460A (en) | 1981-05-14 | 1981-05-14 | Low sodium salt substitute and food containing the same |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56175996A Division JPS57189663A (en) | 1981-10-31 | 1981-10-31 | Sodium-free salting agent and salted food |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57186460A JPS57186460A (en) | 1982-11-16 |
JPS633573B2 true JPS633573B2 (en) | 1988-01-25 |
Family
ID=13508758
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56073108A Granted JPS57186460A (en) | 1981-05-14 | 1981-05-14 | Low sodium salt substitute and food containing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57186460A (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59135856A (en) * | 1983-01-24 | 1984-08-04 | Ajinomoto Co Inc | Preparation of food or seasoning |
CN1044080C (en) * | 1992-10-06 | 1999-07-14 | 河嶋善一 | Functional salty composition |
CN1044081C (en) * | 1993-09-29 | 1999-07-14 | 河嶋善一 | Functional table salt composition |
US20070059428A1 (en) | 2005-09-14 | 2007-03-15 | Chigurupati Sambasiva R | Low-sodium salt composition |
US9629384B2 (en) | 2005-09-14 | 2017-04-25 | S & P Ingredient Development, Llc | Low sodium salt composition |
US8802181B2 (en) | 2006-10-05 | 2014-08-12 | S & P Ingredient Development, Llc | Low sodium salt composition |
JP4762196B2 (en) * | 2007-05-23 | 2011-08-31 | 焼津水産化学工業株式会社 | Granular salt flavor |
JP2011036269A (en) * | 2010-11-25 | 2011-02-24 | Kao Corp | Powder seasoning |
US9247762B1 (en) | 2014-09-09 | 2016-02-02 | S & P Ingredient Development, Llc | Salt substitute with plant tissue carrier |
CN111093391A (en) | 2017-09-18 | 2020-05-01 | S&P 配料研发有限公司 | Low sodium salt substitute containing potassium chloride |
CN114680321B (en) * | 2020-12-30 | 2024-05-28 | 广东海天创新技术有限公司 | Composite seasoning salt and preparation method thereof |
-
1981
- 1981-05-14 JP JP56073108A patent/JPS57186460A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS57186460A (en) | 1982-11-16 |
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