JPS63319284A - Smoking agent composition - Google Patents
Smoking agent compositionInfo
- Publication number
- JPS63319284A JPS63319284A JP15423187A JP15423187A JPS63319284A JP S63319284 A JPS63319284 A JP S63319284A JP 15423187 A JP15423187 A JP 15423187A JP 15423187 A JP15423187 A JP 15423187A JP S63319284 A JPS63319284 A JP S63319284A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- smoke
- smoke generating
- generating agent
- agent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 18
- 230000000391 smoking effect Effects 0.000 title 1
- 239000000779 smoke Substances 0.000 claims description 52
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 239000000654 additive Substances 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 10
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 229920002301 cellulose acetate Polymers 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 239000003380 propellant Substances 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 9
- 239000004375 Dextrin Substances 0.000 description 8
- 229920001353 Dextrin Polymers 0.000 description 8
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 8
- 235000019425 dextrin Nutrition 0.000 description 8
- 239000008101 lactose Substances 0.000 description 8
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 8
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 229940097275 indigo Drugs 0.000 description 6
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 4
- 229960000907 methylthioninium chloride Drugs 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000004323 potassium nitrate Substances 0.000 description 4
- 235000010333 potassium nitrate Nutrition 0.000 description 4
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 4
- 229940043267 rhodamine b Drugs 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 2
- JPIYZTWMUGTEHX-UHFFFAOYSA-N auramine O free base Chemical compound C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 JPIYZTWMUGTEHX-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 235000021552 granulated sugar Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 229940046063 potassium chlorate Drugs 0.000 description 2
- 239000001057 purple pigment Substances 0.000 description 2
- 239000001054 red pigment Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000004416 zinc carbonate Nutrition 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 235000015842 Hesperis Nutrition 0.000 description 1
- 235000012633 Iberis amara Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 1
- 239000000006 Nitroglycerin Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- PWGQHOJABIQOOS-UHFFFAOYSA-N copper;dioxido(dioxo)chromium Chemical compound [Cu+2].[O-][Cr]([O-])(=O)=O PWGQHOJABIQOOS-UHFFFAOYSA-N 0.000 description 1
- LYAGTVMJGHTIDH-UHFFFAOYSA-N diethylene glycol dinitrate Chemical compound [O-][N+](=O)OCCOCCO[N+]([O-])=O LYAGTVMJGHTIDH-UHFFFAOYSA-N 0.000 description 1
- SVTDYSXXLJYUTM-UHFFFAOYSA-N disperse red 9 Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC SVTDYSXXLJYUTM-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229960003711 glyceryl trinitrate Drugs 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- WOTPFVNWMLFMFW-ISLYRVAYSA-N para red Chemical compound OC1=CC=C2C=CC=CC2=C1\N=N\C1=CC=C(N(=O)=O)C=C1 WOTPFVNWMLFMFW-ISLYRVAYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007582 slurry-cast process Methods 0.000 description 1
- 239000004509 smoke generator Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- IPPYBNCEPZCLNI-UHFFFAOYSA-N trimethylolethane trinitrate Chemical compound [O-][N+](=O)OCC(C)(CO[N+]([O-])=O)CO[N+]([O-])=O IPPYBNCEPZCLNI-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
［産業上の利用分野］
この発明は発煙剤組成物に関し、さらに詳しく言うと、
たとえば発煙飛翔体に装着してその航跡を確認するのに
好適に利用することのできる発煙剤組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] This invention relates to a smoke generating composition, and more specifically,
For example, the present invention relates to a smoke generating agent composition that can be suitably used to attach to a smoke projectile and check its trajectory.
［従来の技術およびその問題点］
従来、発煙剤組成物としては、たとえばヘキサクロロエ
タン、亜鉛粉末および炭酸亜鉛からなる塩化亜鉛煙；硝
酸カリウム、硫黄および鶏冠面からなる硫黄煙；硝酸カ
リウム、硫黄および鶏冠面からなる鶏冠石焼：過塩素酸
カリウム、硫黄およびアントラセンからなる炭素煙；塩
素酸カリウム、ローダミンＢコンク、ｌ−メチルアミノ
アンソラキノン、バラレッドおよびデキストリン（また
は乳糖、グラニユー糖）からなる赤色色素塩；塩素酸カ
リウム、メチレンブルー、インジゴピュア、オーラミン
およびデキストリン（または乳糖）からなる緑色色素煙
；塩素酸カリウム、メチレンブルー、インジゴピュア、
デキストリン（または乳糖）からなる青色色素煙；塩素
酸カリウム、ローダミンＢコンク、１−メチルアミノア
ンソラキノン、バラレッド、インジゴピュアおよびデキ
ストリン（または乳糖）からなる紫色色素煙などが代表
的なものとして知られている。[Prior art and its problems] Conventionally, smoke generating compositions include, for example, zinc chloride smoke made of hexachloroethane, zinc powder, and zinc carbonate; sulfur smoke made of potassium nitrate, sulfur, and comb; potassium nitrate, sulfur, and comb. Carbon smoke consisting of potassium perchlorate, sulfur and anthracene; red pigment consisting of potassium chlorate, rhodamine B conc., l-methylamino anthoraquinone, rose red and dextrin (or lactose, granulated sugar) Salt; potassium chlorate, methylene blue, indigo pure, green pigment smoke consisting of auramine and dextrin (or lactose); potassium chlorate, methylene blue, indigo pure,
Typical examples include blue pigment smoke made of dextrin (or lactose); potassium chlorate, rhodamine B conc., 1-methylaminoanthoraquinone, rose red, indigo pure, and purple pigment smoke made of dextrin (or lactose). Are known.
しかしながら、これらの発煙剤組成物は、φ５５以下の
小型の発煙筒に適するが、φ５５以上の大型の発煙筒に
使用する場合、特に内面燃焼型にした場合の問題点とし
て、ロケットに使用するダブルベース系、コンポジット
系推進剤とは異なり、燃焼抜の残渣が圧填した時点での
形状そのままに残り、特に内圧が１０気圧以上に上昇し
たとき、その残液がノズル方向に集中するため、Ｋｎ比
の増加をまねき、そのため内圧が上昇し、爆発の危険を
起すことがしばしばあった。However, these smoke generating compositions are suitable for small smoke tubes with a diameter of 55 mm or less, but when used in large smoke tubes with a diameter of 55 mm or more, there is a problem with the internal combustion type, especially when using double smoke generators used in rockets. Unlike base and composite propellants, the residue from combustion remains in the same shape as when it was pressurized, and especially when the internal pressure rises to 10 atmospheres or more, the residual liquid concentrates in the nozzle direction. This often resulted in an increase in the internal pressure and an explosion hazard.
［発明の目的］
この発明の目的は、前記問題を解消し、内圧が１０ｋｇ
／ｃ腸２以下の場合は勿論、内圧が１０ｋｇ／ｃ層２以
上となる大型の発煙筒においても線燃焼速度を均一にし
、より安定した発煙状態を実現することのできる発煙剤
組成物を提供することである。[Object of the invention] The object of the invention is to solve the above problem and reduce the internal pressure to 10 kg.
To provide a smoke generating agent composition that can make the linear combustion rate uniform and realize a more stable smoke generation state not only when the internal pressure is 10 kg/c layer 2 or less, but also in large smoke cylinders where the internal pressure is 10 kg/c layer 2 or more. It is to be.
［前記目的を達成するための手段］
前記目的を達成するために、この発明者が鋭意検討を重
ねた結果、特定の添加剤を特定の割合で配合した場合に
は、内圧が上昇しても燃焼残渣成分が堅牢強固でくずれ
にくく、そのため内圧が上昇しても、ノズル側に燃焼残
渣成分が崩壊移動することがなく、しかも、発煙量の低
下及び発煙色の劣化がない発煙剤組成物が得られること
を見い出してこの発明に到達した。[Means for achieving the above object] In order to achieve the above object, the present inventor has made extensive studies and found that when a specific additive is blended in a specific ratio, even if the internal pressure increases, A smoke generating agent composition in which the combustion residue component is strong and hard to crumble, so even if the internal pressure increases, the combustion residue component does not disintegrate and move to the nozzle side, and also does not reduce the amount of smoke generated or deteriorate the smoke color. This invention was achieved by discovering what could be obtained.
すなわち、この発明の概要は、発煙剤と添加剤とからな
る発煙剤組成物において、発煙剤１００重量％に対し、
ポリ塩化ビニル、ポリビニルアルコール、酢酸セルロー
スおよびアクリル樹脂からなる群より選ばれる少なくと
も一種からなる添加剤０．８〜３重量％を配合してなる
ことを特徴とする発煙剤組成物である。That is, the outline of the present invention is that in a smoke generating composition comprising a smoke generating agent and an additive, based on 100% by weight of the smoke generating agent,
This is a smoke generating composition characterized in that it contains 0.8 to 3% by weight of an additive consisting of at least one selected from the group consisting of polyvinyl chloride, polyvinyl alcohol, cellulose acetate, and acrylic resin.
前記発煙剤としては、従来より公知のものを用いること
ができる。具体例としては、ヘキサクロロエタン５０重
量％、亜鉛粉末２５重量％、炭酸亜鉛２５重量％からな
る塩化亜鉛煙；硝酸カリウム４８．５重量％、硫黄４８
．５重量％、鶏冠石３．０重量％からなる硫黄煙；硝酸
カリウム２５重量％、硫黄１６重量％、鶏冠石５８重量
％からなる鶏冠石煙：過塩素酸カリウム５８重量％、硫
黄１１重量％、アントラセン３３重量％からなる炭素煙
；塩素酸カリウム２５重量％、ローダミンＢコンク（又
はメチルアミノアンソラキノン）２４重量％、パラレッ
ド３Ｂ重量％、デキストリン（または乳糖）１５重量％
からなる赤色色素１！Ｉ：塩素酸カリウム２８重量％、
メチレンブルー１７重量％、インジゴピュア３０重量％
、オーラミン１０重量％、デキストリン（または乳糖）
１５重量％からなる綴色色素煙：塩素酸カリウム２８
重量％、メチレンブルー１７重量％、インジゴピュア４
０重量％、デキストリン（または乳糖）１５重量％から
なる青色色素煙；塩素酸カリウム２６重量％、ローダミ
ンＢコンク１６重量％、バラレッド２１重量％、インジ
ゴピュア２２重量％、デキストリン（または乳糖）１５
重量％からなる紫色色素煙などが挙げられる。As the smoke generating agent, conventionally known ones can be used. Specific examples include zinc chloride smoke consisting of 50% by weight of hexachloroethane, 25% by weight of zinc powder, and 25% by weight of zinc carbonate; 48.5% by weight of potassium nitrate, and 48% by weight of sulfur.
．． Sulfur smoke consisting of 5% by weight, 3.0% by weight of sulfur; 25% by weight of potassium nitrate, 16% by weight of sulfur, 58% by weight of sulfur: 58% by weight of potassium perchlorate, 11% by weight of sulfur; Carbon smoke consisting of 33% by weight of anthracene; 25% by weight of potassium chlorate, 24% by weight of Rhodamine B conc (or methylamino anthoraquinone), 24% by weight of Parared 3B, 15% by weight of dextrin (or lactose)
A red pigment consisting of 1! I: potassium chlorate 28% by weight,
Methylene blue 17% by weight, Indigo Pure 30% by weight
, auramine 10% by weight, dextrin (or lactose)
Color pigment smoke consisting of 15% by weight: Potassium chlorate 28
Weight%, methylene blue 17% by weight, Indigo Pure 4
0% by weight, 15% by weight of dextrin (or lactose); 26% by weight of potassium chlorate, 16% by weight of Rhodamine B Conc, 21% by weight of Rose Red, 22% by weight of Indigo Pure, 15% by weight of dextrin (or lactose)
Examples include purple pigment smoke consisting of % by weight.
前記添加剤には、ポリ塩化ビニル、ポリビニルアルコー
ル、酢酸セルロースおよびアクリル樹脂よりなる群から
選ばれる少なくとも一種を使用する。The additive used is at least one selected from the group consisting of polyvinyl chloride, polyvinyl alcohol, cellulose acetate, and acrylic resin.
前記ポリ塩化ビニルおよびポリビニルアルコールは、ペ
ーストグレードのものを使用するのが好ましく、このよ
うなポリ塩化ビニルおよびポリビニルアルコールは、た
とえばポバール［商品名：クラレ縛製］などとして商業
的に入手可能である。It is preferable to use paste-grade polyvinyl chloride and polyvinyl alcohol, and such polyvinyl chloride and polyvinyl alcohol are commercially available, for example, as Poval [trade name: Kurarayibaku Co., Ltd.]. .
前記酢酸セルは−スは、その酢化度が、通常、５〜２０
％、好ましくは８〜１２％のものを用いることができ、
その溶液粘度は、通常、低いものである。前記アクリル
樹脂としては、ポリアクリレートおよびポリメタクリレ
ートのいずれをも用いることができるが、好ましいのは
ポリメタクリレートであり、特にポリメチルアクリレー
トが好ましい。The degree of acetylation of the acetic acid cell is usually 5 to 20.
%, preferably 8 to 12%,
Its solution viscosity is usually low. As the acrylic resin, both polyacrylate and polymethacrylate can be used, but polymethacrylate is preferred, and polymethyl acrylate is particularly preferred.
前記ポリ塩化ビニル、ポリビニルアルコール、酢酸セル
ロースおよびアクリル樹脂は１種単独で使用してもよい
し、２種以上を組合わせて使用してもよい。The polyvinyl chloride, polyvinyl alcohol, cellulose acetate, and acrylic resin may be used alone or in combination of two or more.
前記添加剤として、好ましい組成の具体例を示せばポリ
塩化ビニルおよび／またはポリビニルアルコ−Ｊｌｌｏ
、５〜３．５ｆｉＪ１％、酢酸セルロース０．８〜４．
０重量％、アクリル樹脂０．４〜２．５重量％である。Examples of preferable compositions of the additive include polyvinyl chloride and/or polyvinyl alcohol.
, 5-3.5fiJ1%, cellulose acetate 0.8-4.
0% by weight, and 0.4 to 2.5% by weight of acrylic resin.
この発明において、前記発煙剤に対する前記添加剤の配
合割合は、発煙剤１００重量％に対して添加剤０．８〜
３重量％、好ましくは１．０〜２．５重量％である。添
加剤の配合割合が０．８重量％未渦の場合には、この発
明の発煙剤組成物の強度が低下する。一方、３重量％を
超えると、発煙量が減少し、場合によっては火炎のみが
発生して煙を生じないことがある。In this invention, the blending ratio of the additive to the smoke generating agent is 0.8 to 100% by weight of the smoke generating agent.
3% by weight, preferably 1.0-2.5% by weight. When the blending ratio of additives is 0.8% by weight, the strength of the smoke generating composition of the present invention decreases. On the other hand, if it exceeds 3% by weight, the amount of smoke generated decreases, and in some cases, only flames may be generated and no smoke may be generated.
前記発煙剤と添加剤との混和はたとえばウニルナ−型混
和機を使用して行なうことができる。また、混和に際し
て、たとえばシクロヘキサノン、シクロペンタノン、ア
セトフェノン、アセトン等のケトン；テトラヒドロフラ
ン、テトラヒドロピラン、ジオキサン等のエーテル；ニ
トロベンゼン、アセトニトリル、プロピオニトリル等の
窒素化合物：ベンゼン、トルエン、キシレン等の芳香族
炭化水素などの溶剤を使用することができる。The smoke generating agent and the additives can be mixed using, for example, a UNILNA type mixer. In addition, upon mixing, for example, ketones such as cyclohexanone, cyclopentanone, acetophenone, and acetone; ethers such as tetrahydrofuran, tetrahydropyran, and dioxane; nitrogen compounds such as nitrobenzene, acetonitrile, and propionitrile; and aromatic compounds such as benzene, toluene, and xylene. Solvents such as hydrocarbons can be used.
前記発煙剤と添加剤とは、たとえば造粒成形法を用いて
円筒状、円柱状などの所定の形状の成形体として使用す
る。この成形体の密度は、１．０〜１．３ｇ ／ ｃ
ｍ３ である。この密度が１．０ｇ／Ｃｍ３未満の場合
には成形体の強度が低下して燃焼中に崩壊することがあ
る。一方、 １．３ｇ／Ｃｍ３を超える場合には燃焼し
ないことがある。The smoke generating agent and the additive are used in the form of a molded body having a predetermined shape such as a cylinder or column by using, for example, a granulation molding method. The density of this molded body is 1.0 to 1.3 g/c
m3. If this density is less than 1.0 g/Cm3, the strength of the compact may decrease and it may collapse during combustion. On the other hand, if it exceeds 1.3g/Cm3, it may not burn.
この発明の発煙剤組成物に用いる点火手段としては、た
とえば導火線、点火剤が挙げられるが、高速で飛翔する
発煙飛翔体に装着して使用する場合のように空気等の支
燃剤が乏しい状況下での点火性の観点からは、それ自体
に酸化成分を含有する点火剤を使用するのが好ましい０
点火剤としては、従来より公知のダブルベース推進薬お
よびコンポジット推進薬のいずれかの固体推進薬を用い
ることができる。Ignition means used in the smoke generating agent composition of the present invention include, for example, a fuse and an igniter, but in situations where combustion supporting agents such as air are scarce, such as when used attached to a smoke generating projectile flying at high speed. From the viewpoint of ignitability, it is preferable to use an ignition agent that itself contains an oxidizing component.
As the igniter, any of the conventionally known solid propellants, such as double base propellants and composite propellants, can be used.
ダブルベース推進薬は、ニトロセルロースおよびニトロ
グリセリンの二成分からなる主剤とジフェニルアミン、
エチルセントラリッドなどの安定剤とフタル酸ジエチル
、エチルセントラリッド、二硝酸ジエチレングリコール
、三硝酸トリメチロールエタンなどの可塑剤とを水を用
いて混和した後、たとえば圧伸法、モールディング法、
キャスティング法、スラリーキャスティング法などの方
法により成形したものであり、その他の成分として、た
とえば酸化鉛、ステアリン酸塩などの燃焼調節剤、カー
ボンブラック、黒鉛などの黒化剤：キャンデリラワック
スなどの添加物：およびアルコール、エーテル、アセト
ン、酢酸エチルなどの溶剤を配合することもできる。Double-base propellants consist of two main components: nitrocellulose and nitroglycerin, diphenylamine,
After mixing a stabilizer such as ethyl centralide with a plasticizer such as diethyl phthalate, ethyl centralide, diethylene glycol dinitrate, or trimethylolethane trinitrate using water, for example, drawing method, molding method, etc.
It is molded by a method such as a casting method or a slurry casting method, and other ingredients include combustion modifiers such as lead oxide and stearate, blackening agents such as carbon black and graphite, and additions such as candelilla wax. and solvents such as alcohol, ether, acetone, and ethyl acetate.
前記ダブルベース推進薬における各成分の配合割合は、
通常、主剤５０〜８９重量％、安定剤１〜５重量％、可
塑剤（非爆発性物質）０〜３０重量％、可塑剤（爆発性
物質）０〜５０重量％、燃焼調節剤０〜１０重量％、黒
化剤０〜０．３重量％、他の添加物０〜２重量％、溶剤
０〜４０重量％である。The blending ratio of each component in the double base propellant is:
Usually, 50-89% by weight of main agent, 1-5% by weight of stabilizer, 0-30% by weight of plasticizer (non-explosive substance), 0-50% by weight of plasticizer (explosive substance), 0-10% by weight of combustion modifier. % by weight, blackening agent 0-0.3% by weight, other additives 0-2% by weight, and solvent 0-40% by weight.
コンポジット推進薬は、少なくとも、たとえば過塩素酸
リチウム、過塩素酸アンモニウム、過塩素酸カリウム、
硝酸リチウム、硝酸アンモニウムなどの酸化剤；ポリ塩
化ビニル、ポリサルフィド、ポリエチレンテレフタレー
ト、ポリウレタン、ポリブタジェンなどの各種プラスチ
ック、ゴム弾性体からなる燃料兼固体成分結合剤ニアル
ミニウム、マグネシウム、ベリリウム、ホウ素などの粒
状金属燃料の三成分からなり、そのほか少量成分として
、たとえば酸化銅、クロム酸銅、酸化バナジウム、酸化
第二鉄などの燃焼触媒、さらに硬化剤、硬化触媒、可塑
剤、安定剤などを含有していてもよい。Composite propellants include at least, for example, lithium perchlorate, ammonium perchlorate, potassium perchlorate,
Oxidizing agents such as lithium nitrate and ammonium nitrate; Various plastics such as polyvinyl chloride, polysulfide, polyethylene terephthalate, polyurethane, and polybutadiene; fuel and solid component binders made of rubber elastic bodies; granular metal fuels such as aluminum, magnesium, beryllium, and boron. It consists of three components, and may also contain small amounts of combustion catalysts such as copper oxide, copper chromate, vanadium oxide, and ferric oxide, as well as curing agents, curing catalysts, plasticizers, and stabilizers. good.
前記コンポジット推進薬における各成分の配合割合は、
通常、酸化剤６０〜８０重量％、燃料兼固体成分結合剤
１５〜２５重量％、粒状金属燃料１〜５重量％、その他
の添加剤０．５〜３重量％である。前記ダブルベース推
進薬およびコンポジット推進薬のうち、好ましいのはコ
ンポジット推進薬である。The blending ratio of each component in the composite propellant is:
Usually, the content is 60 to 80% by weight of oxidizing agent, 15 to 25% by weight of fuel/solid component binder, 1 to 5% by weight of granular metal fuel, and 0.5 to 3% by weight of other additives. Among the double base propellants and composite propellants, preferred is the composite propellant.
この発明の発煙剤組成物は、たとえば発煙飛翔体に装着
して、その航跡を確認するのに好適に利用することがで
きる。The smoke generating agent composition of the present invention can be suitably used, for example, when attached to a smoke-generating flying object to check its trajectory.
［発明の効果］
この発明によると、線燃焼速度が均一であり、発煙状態
の良好な大型の内面燃焼型発煙筒の製造に有用な、工業
的に有利な発煙剤組成物を提供することができる。[Effects of the Invention] According to the present invention, it is possible to provide an industrially advantageous smoke generating composition that is useful for manufacturing a large internal combustion type smoke cylinder that has a uniform linear burning rate and produces good smoke. can.
［実施例］ 次に、この発明の実施例および比較例を示し。[Example] Next, examples and comparative examples of the present invention will be shown.
この発明についてさらに具体的に説明する。This invention will be explained in more detail.
（実施例１）
塩素酸カリウム２５重量％、１−メチルアミノアンソラ
キノン４５重量％、グラニユー糖１７重量％、重炭酸水
素ナトリウム５重量％およびケイソウ土８重量％からな
る発煙剤（赤色色素煙） １００ ｇとポリ塩化ビニル
２０重量％、酢酸セルロース２０重量％およびアクリル
樹脂６０重量％からなる添加剤２ｇ（上記発煙剤１００
重量％に対して２．０重量％）とを、アセトン１４０ｍ
ＪＬを用いて混和した。(Example 1) A fuming agent (red dye smoke) consisting of 25% by weight of potassium chlorate, 45% by weight of 1-methylaminoanthraquinone, 17% by weight of granulated sugar, 5% by weight of sodium bicarbonate, and 8% by weight of diatomaceous earth. ) and 2 g of an additive consisting of 20% by weight of polyvinyl chloride, 20% by weight of cellulose acetate and 60% by weight of acrylic resin (100% by weight of the above smoke generator)
2.0% by weight) and 140m of acetone.
Mixed using JL.
次いで、造粒成形を行なって平均粒度１６メツシユ、平
均密度１．２３ｇ ／ ｃ ｍ３の発煙剤組成物９８．
５ｇを得た。Then, granulation molding was carried out to obtain a smoke generating composition 98.0 mm with an average particle size of 16 mesh and an average density of 1.23 g/cm3.
5g was obtained.
得られた発煙剤組成物について、テストチャンバーで線
燃焼速度を測定したところ、１０ａｔ層で０．０５ｃｍ
／ｓｅｅを要した。発煙状況は良好で安定した燃焼が得
られた。The linear burning rate of the obtained smoke generating agent composition was measured in a test chamber, and it was found to be 0.05 cm in a 10at layer.
/see was required. Smoke generation was good and stable combustion was obtained.
（比較例１〜２．実施例２〜５）
第１表に示す成分を所定の配合量で配合したはかは、前
記実例１と同様に実施した。(Comparative Examples 1 to 2. Examples 2 to 5) The same method as in Example 1 was carried out in which the components shown in Table 1 were blended in predetermined amounts.
実施例１と同様にして発煙状況を観察した。The smoke generation situation was observed in the same manner as in Example 1.
結果を第１表に示す。The results are shown in Table 1.
（以下、余白）(Hereafter, margin)
Claims (1)
、発煙剤１００重量％に対し、ポリ塩化ビニル、ポリビ
ニルアルコール、酢酸セルロースおよびアクリル樹脂か
らなる群より選ばれる少なくとも一種からなる添加剤０
．８〜３重量％を配合してなることを特徴とする発煙剤
組成物。(1) In a smoke generating agent composition consisting of a smoke generating agent and an additive, 0% of the additive consisting of at least one selected from the group consisting of polyvinyl chloride, polyvinyl alcohol, cellulose acetate, and acrylic resin is added to 100% by weight of the smoke generating agent.
．． A smoke generating composition characterized in that it contains 8 to 3% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15423187A JPS63319284A (en) | 1987-06-20 | 1987-06-20 | Smoking agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15423187A JPS63319284A (en) | 1987-06-20 | 1987-06-20 | Smoking agent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63319284A true JPS63319284A (en) | 1988-12-27 |
Family
ID=15579713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15423187A Pending JPS63319284A (en) | 1987-06-20 | 1987-06-20 | Smoking agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63319284A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007161500A (en) * | 2005-12-09 | 2007-06-28 | Nippon Koki Co Ltd | Red phosphorus based smoke composition and method of manufacturing the same |
| CN102180764A (en) * | 2011-03-30 | 2011-09-14 | 中国人民解放军63976部队 | Solid-liquid treatment method of waste smoke agent containing hexachloroethane |
-
1987
- 1987-06-20 JP JP15423187A patent/JPS63319284A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007161500A (en) * | 2005-12-09 | 2007-06-28 | Nippon Koki Co Ltd | Red phosphorus based smoke composition and method of manufacturing the same |
| CN102180764A (en) * | 2011-03-30 | 2011-09-14 | 中国人民解放军63976部队 | Solid-liquid treatment method of waste smoke agent containing hexachloroethane |
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