JPS63308100A - Bathtub-cleaning agent - Google Patents
Bathtub-cleaning agentInfo
- Publication number
- JPS63308100A JPS63308100A JP14365587A JP14365587A JPS63308100A JP S63308100 A JPS63308100 A JP S63308100A JP 14365587 A JP14365587 A JP 14365587A JP 14365587 A JP14365587 A JP 14365587A JP S63308100 A JPS63308100 A JP S63308100A
- Authority
- JP
- Japan
- Prior art keywords
- bathtub
- glass
- silver
- bath
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 26
- 239000004332 silver Substances 0.000 claims abstract description 26
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 20
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 10
- 238000002844 melting Methods 0.000 claims abstract description 8
- 230000008018 melting Effects 0.000 claims abstract description 8
- 238000000465 moulding Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- -1 Na2O3 Inorganic materials 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- 239000011521 glass Substances 0.000 description 31
- 238000004090 dissolution Methods 0.000 description 14
- 229910021645 metal ion Inorganic materials 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 238000010828 elution Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000005368 silicate glass Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 230000003670 easy-to-clean Effects 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000002982 water resistant material Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
「 産業上の利用分野」
本発明は、浴槽内の湯中に単に投入するだけで、長期に
亙って湯を清浄に保つことができる浴槽清浄剤に関する
ものである。[Detailed Description of the Invention] "Field of Industrial Application" The present invention relates to a bathtub cleaner that can keep hot water clean for a long period of time by simply adding it to the hot water in the bathtub. .
「 従来の技術」
従来、入浴剤や浴用芳香剤など浴槽内の湯に芳香を与え
たり、着色したりして入浴を多様に楽しむ浴用の添加剤
は多種あるが、浴場および浴槽内を長期に亙って清浄に
保ち、浴場の好適な使用期間を延長させることのできる
浴槽清浄剤は提供されていない。``Prior art'' There are many types of bath additives, such as bath additives and bath air fresheners, that add fragrance to or color the water in the bathtub to make bathing more enjoyable. There are no bathtub cleaners available that can keep the bathtub clean for longer and extend the useful life of the bathtub.
「 解決しようとする問題点」
従来、知られている入浴剤には、殺菌剤など浴場を清浄
化することのできる薬剤が添加されているものもあるが
、その効果は入浴剤を浴湯に添加してから後の短時間に
限られ、持続性はない。しかも、前記入浴剤に添加され
ている殺菌剤は、周知の有機または無機の化合物なので
、その使用目的からして高濃度にはできないため、その
殺菌効果も充分なものでない。``Problem we are trying to solve'' Some conventional bath salts have added agents such as disinfectants that can cleanse the bath, but their effectiveness is limited by adding the bath salt to the bath water. It is limited to a short period of time after being added and is not persistent. Moreover, since the sterilizing agent added to the bath salt is a well-known organic or inorganic compound, it cannot be used at a high concentration due to its intended use, and therefore its sterilizing effect is not sufficient.
したがって、現在までのところ、例えば３人家族の家庭
において、毎日入浴するとして、浴場および浴槽は、毎
日あるいは数日で交換、清掃しなければならない状態に
なる。Therefore, up to now, if a family of three people takes a bath every day, the bathtub and bathtub must be replaced and cleaned every day or every few days.
「 問題点を解決するための手段」
周知のように、銅や銀に滅菌作用かあることが古くから
知られている。例えば、病院では治療用の器具入れに銅
製容器が用いられていたことや、中段時代では食物の腐
敗を防ぐために銀製食器が使われていたことなどである
。銅や銀の滅菌作用について詳しいことは判明していな
いが、これらのイオンの活性作用によることは明らかで
ある。``Means to Solve Problems'' As is well known, copper and silver have long been known to have sterilizing properties. For example, in hospitals, copper containers were used to hold medical equipment, and in the Middle Period, silver tableware was used to prevent food from spoiling. Although the detailed sterilization effects of copper and silver are not known, it is clear that they are due to the active effects of these ions.
すなわち、銅イオンが０．１〜０．３ｐｐｍ存在するこ
とで、はとんどの藻類が発生しないことや、銀イオンが
０．０５〜Ｑ、１Ｏｐｐ−存在することで水中の大腸菌
が死滅することが知られている。In other words, the presence of 0.1 to 0.3 ppm of copper ions prevents the growth of algae, and the presence of 0.05 to 1 Opp of silver ions kills E. coli in the water. It has been known.
そこで、この銀を用いた浴槽清浄剤の提供が考えられる
が、この銀にかぎらず、通常、金属イオンは、金属の化
合物である金属塩から得られる場合が多く、金属塩の溶
出速度は、浴槽清浄剤として適当な範囲に比べて遅いか
、速いかであり、しかも、その速度の制御は行なえない
。Therefore, it is possible to provide a bathtub cleaner using silver, but metal ions are not limited to silver, and metal ions are usually obtained from metal salts, which are metal compounds, and the elution rate of metal salts is It is either slower or faster than the appropriate range for a bathtub cleaner, and the speed cannot be controlled.
この問題に対し、本発明者らは、ガラスの低速度溶解性
に注目して鋭意研究を重ねたところ、次のような知見を
得るに至った。すなわち、石英ガラスは、物理的、化学
的な安定性からは理想的なガラスであるが、１７００’
Ｃ以上の高温でなければ融解しないので、一般的な使用
には実用的でない。実用化されているガラスは、周知の
ように、網目形成酸化物である珪酸に、ソーダ（Ｎａｎ
ｏ）や石灰（ＣａＯ）などの修飾酸化物を加えて融解し
やすくしてあり、また、いろいろの形状に成形しやすい
組成、構造にもなっている。すなわち、Ｎａイオン、Ｃ
ａイオンなどによって網目形成酸化物による共有結合的
な不規則網目構造の結合が部分的に切断された構造とな
っている。この構造を持つ代表的なガラスは、ソーダ・
石灰・珪酸系ガラス、または単に珪酸塩ガラスと言われ
、一番生産量の多いガラス製品に用いられており、低コ
ストで人手できるガラスである。この珪酸塩ガラスは、
石英ガラスに比べると、わずかではあるが、水や湿気に
よって表面が犯される。つまり、水に対して低溶解性を
持つ。しかし、その溶解速度は、かなり遅く、浴槽清浄
剤の溶解制御を担うには不適である。In response to this problem, the inventors of the present invention have conducted extensive research focusing on the low-speed dissolution of glass, and have come to the following findings. In other words, quartz glass is an ideal glass in terms of physical and chemical stability, but
It is not practical for general use because it will not melt unless it is at a high temperature of C or higher. As is well known, glasses that are in practical use contain silicic acid, which is a network-forming oxide, and soda (Nan).
Modified oxides such as O) and lime (CaO) are added to make it easier to melt, and the composition and structure make it easier to mold into various shapes. That is, Na ions, C
It has a structure in which the covalent bonds of the irregular network structure formed by the network-forming oxide are partially broken by a ions and the like. Typical glasses with this structure are soda
It is called lime-silicate glass, or simply silicate glass, and is used in the most produced glass products, and is a low-cost glass that can be made by hand. This silicate glass is
Compared to quartz glass, the surface is damaged by water and moisture, albeit to a lesser extent. In other words, it has low solubility in water. However, its dissolution rate is quite slow, making it unsuitable for controlling the dissolution of bathtub cleaners.
前記珪酸塩ガラスに、さらに修飾酸化物を加えると、珪
酸による共有結合がさらに切断されて網目構造だったの
が鎖状構造になる。この構造を持つ代表的なガラスは、
ソーダ・珪酸塩ガラスと言われ、水に溶解しやすいため
、接着剤や硬化剤などに多用されている水ガラスの組成
に用いられている。このガラスにさらに修飾酸化物を加
えると、共有結合的な珪酸イオンとなり、イオン結合が
多くなった逆性ガラスの構造となる。この逆性ガラスは
、融解過程で結晶しやすく均質にガラス化することは困
難であるが、網目形成酸化物である珪酸の一部または全
部を硼酸や燐酸で置換することにより比較的容易に均質
なガラスとすることができる。When a modified oxide is further added to the silicate glass, the covalent bonds caused by the silicic acid are further broken, and the network structure becomes a chain structure. Typical glasses with this structure are
It is called soda silicate glass, and because it dissolves easily in water, it is used in the composition of water glass, which is often used in adhesives and hardening agents. When a modified oxide is further added to this glass, it becomes a covalently bonded silicate ion, resulting in an inverted glass structure with an increased number of ionic bonds. This inverted glass tends to crystallize during the melting process and is difficult to vitrify homogeneously, but by replacing part or all of the silicic acid, which is a network-forming oxide, with boric acid or phosphoric acid, it can be relatively easily vitrified homogeneously. It can be made of glass.
このように、ガラスの水への溶解速度は、その過程の物
理的および化学的な検討が必要であるが、ガラスの組成
を適当に選べば、溶解速度を制御することが可能である
。このようなガラスを前記したように単に溶解性ガラス
（Ｓｏｌｕｂｌｅ Ｇｌａｓｓ）あるいは制御溶出性ガ
ラス（Ｃｏｎｔｒｏｌｌｅｄ Ｒｅ１ｅａｓｅ Ｇｌａ
ｓＳ）と言っている。この溶解性ガラスは、構成成分の
約半分まで有効な活性イオンである銀などの金属のイオ
ンを安定な状態で含有させることが可能であり、このガ
ラスの溶解速度を調整することによって、有効な金属イ
オンの適量を１時間から数１０年に亙り一定速度で溶出
させることができる。As described above, the dissolution rate of glass in water requires physical and chemical consideration of the process, but it is possible to control the dissolution rate by appropriately selecting the composition of the glass. As mentioned above, such glass is simply called soluble glass or controlled release glass.
sS). This meltable glass can stably contain metal ions such as silver, which are effective active ions, up to about half of the constituent components, and by adjusting the dissolution rate of this glass, it is possible to Appropriate amounts of metal ions can be eluted at a constant rate over a period of one hour to several decades.
例えば、第３図（ａ） （ｂ） （ｃ）に示すように、
溶解速度を制御した活性元素（銀）含有溶解性ガラスの
拉ｌを水中に投入すると、ガラス粒ｌ中の銀はガラスの
溶解に伴って一定濃度でイオンとして溶出する。この時
のガラスの溶解速度と銀イオンの濃度をそれぞれ時間の
関数として示すと、第４図（ａ）（ｂ）のようになる。For example, as shown in Figure 3 (a), (b), and (c),
When a particle of soluble glass containing an active element (silver) whose dissolution rate is controlled is placed in water, the silver in the glass particles is eluted as ions at a constant concentration as the glass dissolves. The dissolution rate of the glass and the concentration of silver ions at this time are shown as functions of time as shown in FIGS. 4(a) and 4(b).
（ａ）図は大容量の水中への溶解性ガラスの溶解速度変
化を示すグラフであり、（ｂ）図は所定の容量の水中に
おける銀イオンの溶出濃度変化を示すグラフである。こ
れらの１図の内、特に（ｂ）図は重要な意味を示してい
る。すなわち、この図により溶解ガラスが溶解し終わる
まで銀イオンは常に一定の１度であることが判る。Figure (a) is a graph showing changes in dissolution rate of soluble glass in a large volume of water, and Figure (b) is a graph showing changes in elution concentration of silver ions in a predetermined volume of water. Among these figures, figure (b) in particular shows an important meaning. That is, it can be seen from this figure that the silver ions are always at a constant temperature of 1 degree until the molten glass is completely melted.
前記のように、溶解性ガラスの溶解速度が制御できるの
は、ガラスは非晶質で均質な素材であり、被覆材やカプ
セルのような耐水性物質で溶解速度を制御する必要がな
いからである。また、溶解性ガラスは、多量の金属イオ
ンとの結合が可能で、溶解に伴う残留分を残さないのが
普通である。さらに、最適な溶解速度を選ぶことができ
るので、余分な金属イオンの溶出を防ぎ、最も効率的に
、しかも環境の汚染を最小限に調整することができる。As mentioned above, the melting rate of meltable glass can be controlled because glass is an amorphous and homogeneous material, and there is no need to control the dissolution rate with water-resistant materials such as coatings or capsules. be. Further, meltable glass is capable of bonding with a large amount of metal ions, and typically leaves no residue when melted. Furthermore, since the optimum dissolution rate can be selected, it is possible to prevent the elution of excess metal ions and to achieve the most efficient adjustment while minimizing environmental pollution.
また、この溶解性ガラスは、使用目的に合うように、ど
のような形状、例えば、粉末状、繊維状、フレーク状、
泡ガラス状、管状、ブロック状にすることもできる。溶
解性ガラスは、従来のガラス工学の知識で充分に生産で
き、環境汚染が低く、付加価値が高いという利点を持っ
ている。In addition, this meltable glass can be formed into any shape, such as powder, fiber, flake, etc., depending on the purpose of use.
It can also be shaped into bubble glass, tubes, or blocks. Meltable glass has the advantages of being easily produced using conventional glass engineering knowledge, causing low environmental pollution, and having high added value.
前記知見に基づいて、浴槽清浄剤として最適な銀含有ガ
ラス剤の組成および粒径を追及したところ、組成は、
Ｂ、０．・・・ ４０〜７６重量％
Ｓｉｎ、・・・ ２０〜５６重量％
Ｎａ＊Ｏｓ”” ３〜２０重量％
Ａｌ２ｆＯ５・・・ １〜５重量％Ａ ｆｈＮ Ｏ
ｓ”’ ０．２〜２．０重量％が好ましく、粒体の粒径
としては、短径が０．５ｍｍ〜１０ｃｉ＋、好ましくは
Ｉ＋＋ｖ〜５ｃｍであることが判明した。Based on the above findings, we investigated the composition and particle size of a silver-containing glass agent most suitable for use as a bathtub cleaner, and found that the composition was: B, 0. ... 40-76% by weight Sin,... 20-56% by weight Na*Os"" 3-20% by weight Al2fO5... 1-5% by weight A fhN O
It has been found that s"' is preferably 0.2 to 2.0% by weight, and the particle diameter of the particles is 0.5 mm to 10 ci+, preferably I++v to 5 cm.
本発明は、係る知見に基づいてなされたものである。す
なわち、本発明の浴槽洗浄剤は、Ｂ ｔ Ｏｓ：４０〜
７６重量％、Ｓ２Ｏ！：２０〜５６重量％、Ｎ ａ２Ｏ
５： ３〜２０重量％、Ａ（！＊Ｏｓ：ｌ 〜５重量％
、Ａ ９＊Ｎ Ｏｓ：０．２〜２．０重量％を混合、融
解して得られる銀入り溶解性ガラスを、平均短径０．５
部ｍ〜１０ｃ魔の粒体に成形してなることを特徴とする
ものである。。 以下、この発明の実施例を示す。The present invention has been made based on this knowledge. That is, the bathtub cleaning agent of the present invention has B t Os: 40-
76% by weight, S2O! :20-56% by weight, Na2O
5: 3 to 20% by weight, A(!*Os: l to 5% by weight
, A9*N Os: 0.2 to 2.0% by weight is mixed and melted to obtain a silver-containing soluble glass with an average minor axis of 0.5.
It is characterized by being formed into granules with a size of 1 to 10 cm. . Examples of this invention will be shown below.
「 実施例１ 」
Ａｇ Ｎｏ 、・・・・・・・・・・・ １．２部上記
組成分を混合、融解して得られる極めてゆっくり溶解す
る銀入り溶解性ガラスを、平均短径ＩＣＪＩＩの粒体に
成形した。第１図に示すように、得られた粒状銀入り溶
解性ガラス（浴槽清浄剤）ｌの１゜Ｏ９をナイロンメツ
シュの袋２の中に入れ、この袋２を一側面に管体３が固
定された網目状のプラスチックケース４の中に収納した
。このケース４を、第２図に示すように、その管体３を
浴槽５の外釜６に連通する下部の孔７に嵌入した。この
ようにして浴湯８中に浴槽清浄剤ｌを投入した風呂を毎
日１回４人で使用した。その結果、通常では浴槽壁に垢
や汚れを元とする付着物が発生する３〜４日を経過して
も、浴槽壁に付着物の発生が見られず、さらに使用が可
能な状態であった。"Example 1" Ag No. 1.2 parts A very slowly melting silver-containing soluble glass obtained by mixing and melting the above components was prepared with an average minor axis of ICJII. Formed into granules. As shown in Fig. 1, 1° O9 of the obtained granular silver-containing soluble glass (bathtub cleaner) was placed in a nylon mesh bag 2, and the bag 2 was placed with a tube 3 on one side. It was housed in a fixed mesh plastic case 4. As shown in FIG. 2, this case 4 was fitted into a hole 7 at the bottom of the bathtub 5, with its tube body 3 communicating with the outer pot 6 of the bathtub 5. The bath in which the bathtub cleaner 1 was added into the bath water 8 was used by 4 people once a day. As a result, even after 3 to 4 days, when deposits from dirt and grime would normally occur on the bathtub walls, no deposits were observed on the bathtub walls, and the bathtub was still usable. Ta.
これは、浴槽清浄剤ｌが浴槽５の浴湯８の中に徐々に溶
解し、溶解したガラス中の銀成分は、渦中において殺菌
作用を発揮し、浴槽中に発生する垢や汚れに付着する細
菌を死滅させ、その結果、垢や汚れを浴槽から剥離させ
、あるいは剥離しゃすくなるためである。This is because the bathtub cleaner l gradually dissolves into the bathwater 8 of the bathtub 5, and the silver component in the dissolved glass exerts a bactericidal effect in the whirlpool, and adheres to grime and dirt generated in the bathtub. This is because it kills bacteria and, as a result, makes it easier to remove dirt and grime from the bathtub.
また、この浴槽清浄剤ｌを使用中は、継続して人体には
入浴後の爽快感が得られた。Furthermore, while using this bathtub cleaner 1, the human body continued to feel refreshed after taking a bath.
「実施例２ 」
Ａｇ Ｎｏ 、・・・・・・・・・ １．２
部を融解して得られる銀入り溶解性ガラス（平均粒径１
．５ｃｍ） ２００９を前記実施例と同様にして外釜式
風呂５の中に投入しておき、この風呂を毎日１回４人で
使用した。その結果、通常では浴槽壁に垢や汚れを元と
する付着物が発生する３〜４日を経過しても、浴槽壁に
付着物の発生が見られず、さらに使用が可能な状態であ
った。また、この浴槽清浄剤を使用中は、継続して人体
には入浴後の爽快感が得られた。"Example 2" Ag No. 1.2
silver-containing soluble glass (average particle size 1
．． 5cm) 2009 was placed in the outer pot bath 5 in the same manner as in the above example, and this bath was used by four people once a day. As a result, even after 3 to 4 days, when deposits from dirt and grime would normally occur on the bathtub walls, no deposits were observed on the bathtub walls, and the bathtub was still usable. Ta. Furthermore, while using this bathtub cleaner, the human body continued to feel refreshed after taking a bath.
「実施例３ 」
Ａｇ Ｎｏ 、・・・・・・・・・ ２
部を融解して得られる銀入り溶解性ガラス（平均粒径１
．５ｃｍ）５００９をナイロンメツシュの袋２の中に入
れ、大型循環式風呂の中に投入しておき、この風呂をこ
の風呂の通常の使用人員および使用頻度で使用した。そ
の結果、通常では浴槽壁に垢や汚れを元とする付着物が
発生する４〜５日を経過しても、浴槽壁に付着物の発生
が見られず、さらに使用が可能な状態であった。また、
この浴槽清浄剤を使用中は、継続して人体には入浴後の
爽快感が得られた。"Example 3" Ag No. 2
silver-containing soluble glass (average particle size 1
．． 5 cm) 5009 was placed in a nylon mesh bag 2 and placed in a large circulation bath, and the bath was used by the number of people and frequency of use that are normal for this bath. As a result, even after 4 to 5 days, when deposits from dirt and grime would normally occur on the bathtub walls, no deposits were observed on the bathtub walls, and the bathtub was still usable. Ta. Also,
While using this bathtub cleaner, the human body continued to feel refreshed after taking a bath.
このように、本発明の浴槽清浄剤によれば、同浴槽清浄
剤の殺菌作用により風呂の循環装置（釜）の内部に付着
する垢や汚れや油脂分に付着する細菌を死滅さ仕、垢や
汚れを循環装置の壁面から剥離させ、清浄化すると同時
に、浴槽中に発生する垢や汚れに付着する細菌も死滅さ
せ、浴槽中の垢や汚れを浴槽から剥離させ、あるいは剥
離しやすくさせ、浴槽が清浄になり、あるいは極めて清
浄にしやすくなる。また、人体には入浴後の爽快感が得
られる。同浴槽清浄剤の投入を継続することにより、循
環装置内部および浴槽の清浄さを維持し、同時に入浴時
の爽快感をも維持できる。As described above, according to the bathtub cleaner of the present invention, the bactericidal action of the bathtub cleaner kills bacteria attached to grime, dirt, and oils and fats that adhere to the inside of the bath circulation system (pot). At the same time, it removes dirt and grime from the wall of the circulation device and cleans it, and at the same time kills the bacteria that adhere to the dirt and grime that occur in the bathtub, and makes it easier to remove dirt and grime from the bathtub. The bathtub becomes cleaner or extremely easy to clean. In addition, the human body can feel refreshed after taking a bath. By continuing to add the bathtub cleaner, it is possible to maintain the cleanliness of the inside of the circulation device and the bathtub, and at the same time maintain a refreshing feeling when taking a bath.
なお、本発明の浴槽清浄剤の収納容器をバス向きに楽し
い形に成形することにより、浴室あるいは浴槽内のイン
テリアとしての意味も加味したものにできる。In addition, by molding the storage container for the bathtub cleaner of the present invention into a fun shape suitable for use in baths, it can also be used as an interior decoration for the bathroom or bathtub.
「 発明の効果」
本発明の浴槽洗浄剤は、Ｂ、Ｏ，：４０〜７６重量％、
Ｓ ＋Ｏｔ：２０〜５６重量％、Ｎａｔ０３：３〜２０
重量％、ＡＱｔＯ３：１〜５重量％、Ａ９ｔＮＯ３：０
．２〜２．０重量％を混合、融解して得られる銀入り溶
解性ガラスを、平均短径０．５ｘｘ〜１ＯＣｊ！（７）
粒体に成形してなることを特徴とするものであり、次の
ような効果を発揮する。すなわち、
本発明の浴槽清浄剤の殺菌作用により風呂の循環装置（
釜）の内部に付着する垢や汚れや油脂分に付着する細菌
を死滅させ、垢や汚れを循環装置の壁面から剥離させ、
清浄化すると同時に、浴槽中に発生する垢や汚れに付着
する細菌も死滅させ、浴槽中の垢や汚れを浴槽から剥離
させ、あるいは剥離しやすくさせ、浴槽が清浄になり、
あるいは極めて清浄にしやすくなる。また、人体には入
浴後の爽快感が得られる。同浴槽清浄剤の投入を継続す
ることにより、循環装置内部および浴槽の清浄さを維持
し、同時に入浴時の爽快感をも維持できる。"Effects of the Invention" The bathtub cleaning agent of the present invention contains B, O,: 40 to 76% by weight,
S+Ot: 20-56% by weight, Nat03: 3-20
Weight %, AQtO3: 1-5 weight %, A9tNO3: 0
．． Silver-containing soluble glass obtained by mixing and melting 2 to 2.0% by weight has an average minor axis of 0.5xx to 1OCj! (7)
It is characterized by being formed into granules and exhibits the following effects. In other words, the sterilizing effect of the bathtub cleaner of the present invention improves the bath circulation system (
It kills dirt and grime adhering to the inside of the pot, as well as bacteria adhering to oil and fat, and removes dirt and grime from the walls of the circulation system.
At the same time as cleaning, it also kills the bacteria that adhere to the dirt and grime that occur in the bathtub, and causes the dirt and grime in the bathtub to be removed from the bathtub, or to be easily removed, making the bathtub cleaner.
Or it becomes extremely easy to clean. In addition, the human body can feel refreshed after taking a bath. By continuing to add the bathtub cleaner, it is possible to maintain the cleanliness of the inside of the circulation device and the bathtub, and at the same time maintain a refreshing feeling when taking a bath.
第１図は本発明の浴槽清浄剤を浴槽内に投入するのに用
いて好適な収納ケースの一例を示す構成図、第２図は本
発明の浴槽清浄剤を浴槽内に投入した状態図、第３図（
ａ）（ｂ）（ｃ）は本発明の浴槽清浄剤の溶解模式図、
第４図（ａ） （ｂ）は本発明の浴槽清浄剤の溶解速度
と含有銀イオンの溶出濃度をそれぞれ時間の関数として
示すもので、（ａ）図は大容量の水中への浴槽清浄剤（
溶解性ガラス）の溶解速度変化を示すグラフであり、（
ｂ）図は所定の容量の水中における含有銀イオンの溶出
濃度変化を示すグラフである。
Ｉ・・・・・・粒状銀入り溶解性ガラス（浴槽清浄剤）
、２・・・・・ナイロンメツシュの袋、
３・・・・・・管体、
４・・・・・・網目状のプラスチックケース、５・・・
・・・浴槽、
６・・・・・・外釜、
７・・・・・・孔、
８・・・・・・浴場。FIG. 1 is a configuration diagram showing an example of a storage case suitable for use in introducing the bathtub cleaner of the present invention into a bathtub, and FIG. 2 is a diagram showing a state in which the bathtub cleaner of the present invention is introduced into a bathtub. Figure 3 (
a), (b), and (c) are schematic diagrams of dissolution of the bathtub cleaner of the present invention;
Figures 4(a) and 4(b) show the dissolution rate and elution concentration of silver ions contained in the bathtub cleaner of the present invention as a function of time, respectively.Figure 4(a) shows the bathtub cleaner in a large volume of water. (
This is a graph showing the change in dissolution rate of (melting glass).
b) The figure is a graph showing changes in the elution concentration of contained silver ions in a predetermined volume of water. I...Dissolvable glass containing granular silver (bathtub cleaner)
, 2...Nylon mesh bag, 3...Tube body, 4...Mesh plastic case, 5...
... Bathtub, 6 ... Outer pot, 7 ... Hole, 8 ... Bathhouse.
Claims (1)
５６重量％、Ｎａ＿２Ｏ＿３：３〜２０重量％、Ａｌ＿
２Ｏ＿３：１〜５重量％、Ａｇ＿２ＮＯ＿３：０．２〜
２．０重量％を混合、融解して得られる銀入り溶解性ガ
ラスを、平均短径０．５ｍｍ〜１０ｃｍの粒体に成形し
てなる浴槽清浄剤。B_2O_5: 40~76% by weight, SiO_2: 20~
56% by weight, Na_2O_3: 3-20% by weight, Al_
2O_3: 1 to 5% by weight, Ag_2NO_3: 0.2 to
A bathtub cleaner made by molding silver-containing soluble glass obtained by mixing and melting 2.0% by weight into particles with an average minor axis of 0.5 mm to 10 cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62143655A JPH07103400B2 (en) | 1987-06-09 | 1987-06-09 | Bath cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62143655A JPH07103400B2 (en) | 1987-06-09 | 1987-06-09 | Bath cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63308100A true JPS63308100A (en) | 1988-12-15 |
| JPH07103400B2 JPH07103400B2 (en) | 1995-11-08 |
Family
ID=15343844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62143655A Expired - Lifetime JPH07103400B2 (en) | 1987-06-09 | 1987-06-09 | Bath cleaner |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07103400B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000039259A1 (en) * | 1998-12-29 | 2000-07-06 | Reckitt Benckiser N.V. | Water-soluble glass as corrosion protection for glassware in dishwashing machines |
-
1987
- 1987-06-09 JP JP62143655A patent/JPH07103400B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000039259A1 (en) * | 1998-12-29 | 2000-07-06 | Reckitt Benckiser N.V. | Water-soluble glass as corrosion protection for glassware in dishwashing machines |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07103400B2 (en) | 1995-11-08 |
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