JPS63295435A - Compound shown by ybfezn4o7 and having hexagonal lamellar structure and its production - Google Patents
Compound shown by ybfezn4o7 and having hexagonal lamellar structure and its productionInfo
- Publication number
- JPS63295435A JPS63295435A JP12905587A JP12905587A JPS63295435A JP S63295435 A JPS63295435 A JP S63295435A JP 12905587 A JP12905587 A JP 12905587A JP 12905587 A JP12905587 A JP 12905587A JP S63295435 A JPS63295435 A JP S63295435A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- compd
- layer
- heated
- ybfezn4o7
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 150000002500 ions Chemical group 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 19
- 239000011701 zinc Substances 0.000 claims description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 claims description 5
- 229910003454 ytterbium oxide Inorganic materials 0.000 claims description 5
- 229940075624 ytterbium oxide Drugs 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 3
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 9
- 239000000696 magnetic material Substances 0.000 abstract description 6
- 239000004065 semiconductor Substances 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 4
- 239000013078 crystal Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 238000003475 lamination Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/76—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by a space-group or by other symmetry indications
Abstract
Description
【発明の詳細な説明】
産業上の利用分計
本発明は磁性材料、半導体材料及び触媒材料等として有
用な新規化合物であるマｂＦｅＺｎ４０ｔで示される六
方晶系の層状構造を有する化合物およびその製造法に関
する。Detailed Description of the Invention Industrial Application The present invention relates to a compound having a hexagonal layered structure represented by FeZn40t, which is a new compound useful as a magnetic material, a semiconductor material, a catalyst material, etc., and a method for producing the same. Regarding.
従来技術
従来、（Ｗｂ”Ｆｅ”６ｇ）１１Ｆｅ”１５（ｎは整数
を示す）で示される六方晶系の層状構造を有する化合物
は本出願人によって合成され知られている。Prior Art Conventionally, a compound having a hexagonal layered structure represented by (Wb"Fe"6g)11Fe"15 (n is an integer) was synthesized by the present applicant and is known.
マｂＦｅ１６４． Ｙｂ２Ｆａ１０７． Ｙｂ３Ｆｅ４
６１６及びＹｂａＦｅ５Ｑ、１の六方晶系としての格子
定数、マｂ６１ａ５層ｅ Ｆ ｅ ＯＨ＊ ５層ｐ Ｆ
ｅ２６＠ａ’ｓ層の単位格子内における層数を示すと表
−１の通りである。MabFe164. Yb2Fa107. Yb3Fe4
616 and YbaFe5Q, 1 lattice constant as a hexagonal system, Ma b61a 5 layers e F e OH* 5 layers p F
Table 1 shows the number of layers in the unit cell of the e26@a's layer.
これらの化合物は酸化鉄１モル（Ｆｅ（５）に対して、
ＹｂＦｅ０．がｎ モル（ｎ ＝ １ 、２ 、３−）
の割合で化合していると考えられる層状構造を持つ化合
物である。These compounds are based on 1 mole of iron oxide (Fe(5))
YbFe0. is n moles (n = 1, 2, 3-)
It is a compound with a layered structure that is thought to be combined at a ratio of .
発明の目的
本発明は（Ｙ ｂ Ｆ ｅ ６ ｓ ） ｎ Ｆ ｅ
６の化学式において、ｎ＝＝１７４に相当しＦｅ”の代
わりにＺｎ”を置きかえて得られる新規な化合物を提供
するにある。Object of the invention The present invention is based on (Y b Fe 6 s ) n Fe
The object of the present invention is to provide a novel compound obtained by replacing Fe'' with Zn'', which corresponds to n==174 in the chemical formula No. 6.
発明の構成
本発明のＹｂＦｅＺｎ４Ｑ７で示される化合物は、イオ
ン結晶モテルテハ、Ｙｂ” （Ｆｅ”°Ｚｎ’°１Ｚｎ
３”ｅ１７”−として記載され、その構造はＹｂＱ、
、５層、 （Ｆｅ、Ｚｎ）０３．５層およびＺｎＯ層
の積層によって形成されており著しい構造異方性を持っ
ていることがその特徴の一つである。Ｚｎ”イオンの’
／ａはＦｅ”と共に（Ｆｅ”。Structure of the Invention The compound represented by YbFeZn4Q7 of the present invention is an ionic crystal motelteha, Yb"(Fe"°Zn'°1Zn
3"e17"-, its structure is YbQ,
, 5 layers, (Fe, Zn)03.5 layers, and a ZnO layer, and one of its characteristics is that it has remarkable structural anisotropy. Zn"ion's"
/a is (Fe”) with “Fe”.
Ｚｎ”）６２．５層を作り、残り（７） ’／ ４１！
ＺｎＯ１層を作ッテいろ。六万品系としての格子定数
は次の通りである。Zn'') 62.5 layers are made, remaining (7)' / 41!
Make one layer of ZnO. The lattice constants for the 60,000-product system are as follows.
ａ＝３．３４７±０．００１（入）
ｃ＝３２．４５±０．０１（入）
この化合物の面指数（ｈ ｋ ｔ ）、面間隔（ｄ（Ｘ
））（ｄＯは実測値ｙ ｄＣは計算値を示す）およびｘ
Ｒに対する相対反射強度（１（％））を示すと表−２の
通りである。a=3.347±0.001 (in) c=32.45±0.01 (in) Planar index (h k t ), plane spacing (d(X
)) (dO is the measured value y dC is the calculated value) and x
Table 2 shows the relative reflection intensity (1 (%)) with respect to R.
この化合物は磁性材料、半導体材料および触媒材料とし
て有用なものである。例えば、異方性の強い２次元的性
質を持つ磁性体・半導体および触媒物質としての利用の
可能性が考えられろ。This compound is useful as a magnetic material, a semiconductor material, and a catalytic material. For example, consider the possibility of using them as magnetic materials, semiconductors, and catalyst materials that have two-dimensional properties with strong anisotropy.
表 −２ 乙の化合物は次の方法によって製造し得られる。Table-2 Compound B can be produced by the following method.
金属イッテルビウムあるいは酸化イッテルビウムもしく
は加熱により酸化イッテルビウムに分解される化合物と
、金属鉄あるいは酸化鉄もしくは加熱により酸化鉄に分
解される化合物と、金属亜鈴あるいは酸化亜鉛もしくは
加熱により酸化亜鉛に分解される化合物と、Ｙｂ、 Ｆ
ｅおよびＺｎの割合が原子比で１対１対２の割合で混合
し、該混合物を６００℃以上の温度で、大気中、酸化性
雰囲気中あるいはｖｂおよびＦｅが各々３価イオン状態
、Ｚｎが２価イオン状態より還元されない還元雰囲気中
で加熱することによって製造し得られる。Metallic ytterbium or ytterbium oxide or a compound that decomposes into ytterbium oxide when heated; Metallic iron or iron oxide or a compound that decomposes into iron oxide when heated; Metallic tin or zinc oxide or a compound that decomposes into zinc oxide when heated. , Yb, F
e and Zn are mixed in an atomic ratio of 1:1:2, and the mixture is heated at a temperature of 600°C or higher in the air, in an oxidizing atmosphere, or in a state where Vb and Fe are each in a trivalent ion state and Zn is in a trivalent ion state. It can be produced by heating in a reducing atmosphere that does not reduce the divalent ion state.
本発明に用いる出発物質は市販のものをそのまま使用し
てもよいが、化学反応を速やかに進行させるためには粒
径が小さい方がよく、特に１０μｍ以下であることが好
ましい。Commercially available starting materials for use in the present invention may be used as they are, but in order to allow the chemical reaction to proceed rapidly, it is better to have a smaller particle size, particularly preferably 10 μm or less.
また、磁性材料、半導体材料として用いる場合には不純
物の混入をきらうので、純度の高いことが好ましい。出
発物質が加熱により金属酸化物を得る化合物としては、
それぞれの金属の水酸化物、炭酸塩、硝酸塩等が挙げら
れる。Further, when used as a magnetic material or a semiconductor material, it is preferable to have high purity since contamination with impurities is avoided. Compounds whose starting materials yield metal oxides by heating include:
Examples include hydroxides, carbonates, and nitrates of each metal.
原料はそのまま、あるいはアルコール類、アセトン等と
共に充分に混合する。The raw materials are thoroughly mixed as they are or together with alcohols, acetone, etc.
原料の混合割合は、Ｙｂ、 Ｆｅ、およびＺｎの割合が
原子比で１対１対２の割合であることが必要である。こ
れをはずすと目的とする化合物の単−相を得ることがで
きない。The mixing ratio of the raw materials must be such that the atomic ratio of Yb, Fe, and Zn is 1:1:2. If this is removed, a single phase of the target compound cannot be obtained.
この混合物を大気中、酸化性雰囲気中あるいはＹｂおよ
びＦｅが各々３１ａ＆イオン状態、 Ｚｎが各々２価イ
オン状態から還元されない還元雰囲気中で６００℃以上
で加熱する。加熱時間は数時間もしくはそれ以上である
。加熱の際の昇温速度には制約はない。加熱終了後急冷
するか、あるいは大気中に急激に引き出せばよい。This mixture is heated at 600° C. or higher in the air, in an oxidizing atmosphere, or in a reducing atmosphere in which Yb and Fe are not reduced from their 31a & ion states, and Zn is not reduced from its divalent ion state. Heating time is several hours or more. There are no restrictions on the rate of temperature increase during heating. After heating, it can be rapidly cooled, or it can be rapidly drawn out into the atmosphere.
得られたＹｂＦｅＺｎ４ｅ１７化合物の粉末は福色であ
り、粉末Ｘ線回折法によって結晶構造を有することが分
かった。その結晶構造は層状構造であり、ＹｂＹｂ０１
−５Ｊ、 （Ｆｅ、 Ｚｎ）Ｑｌ、５層、およびＺｎ６
層の積重ねによって形成されていることが分かった。The obtained powder of the YbFeZn4e17 compound was bright yellow in color and was found to have a crystalline structure by powder X-ray diffraction. Its crystal structure is a layered structure, and YbYb01
-5J, (Fe, Zn)Ql, 5 layers, and Zn6
It turns out that it is formed by stacking layers.
実施例 純度９９．９９％以上の酸化イッテルビウム（Ｙｂ。Example Ytterbium oxide (Yb) with a purity of 99.99% or more.
ＯＳ）粉末、純度９９．９％以上の酸化鉄（Ｆｅｌｅｌ
、 ）粉末、試薬特級の酸化亜＃ａ（Ｚｎ６）粉末をモ
ル比で１対１対８の割合に秤量し、めのう乳鉢内でエタ
ノールを加えて、約３０分間部合し、平均粒径数μｍの
微粉末混合物を得た。該混合物を白金管内に封入し、１
４５０℃に設定された管状シリコニット炉内に入れ、４
日間加熱し、その後、試料を炉外にとりだし室温まで急
速に冷却した。OS) powder, iron oxide (Felel) with a purity of 99.9% or more
) Powder, reagent grade suboxide #a (Zn6) powder was weighed at a molar ratio of 1:1:8, ethanol was added in an agate mortar, and the mixture was mixed for about 30 minutes to determine the average particle size. A fine powder mixture of μm was obtained. The mixture was sealed in a platinum tube, and 1
Placed in a tubular siliconite furnace set at 450°C,
After heating for one day, the sample was taken out of the furnace and rapidly cooled to room temperature.
得られた試料（よ、ＹｂＦｅＺｎ４Ｏ７単−相であり、
粉末Ｘ線回折法によって、各面指数（ｈｋｔｌ。The obtained sample (YbFeZn4O7 single-phase,
Each surface index (hktl.
面間隔（ｄｏ）および相対反射強度を測定した結果は表
−２の通りであった。The results of measuring the interplanar spacing (do) and relative reflection intensity are shown in Table 2.
六方晶系としての格子定数は ａ＝３，３４７±０．００１（λ） ｃ＝３２．４５±０．０１ （人）であった。The lattice constant as a hexagonal system is a=3,347±0.001(λ) c=32.45±0.01 (person).
上記の格子定数および表−２の面指数（ｂｋｌ）より算
出した面間隔（ｄ、（Ａ ））は、実測の面間隔（ｄｏ
（入））と極めてよく一致している。The interplanar spacing (d, (A)) calculated from the above lattice constant and the planar index (bkl) in Table 2 is the actually measured interplanar spacing (do
(in)) agrees extremely well.
発明の効果
本発明は磁性材ｖ４．半導体材料および触媒として有用
な新規化合物を提供する。Effects of the Invention The present invention uses magnetic material v4. Novel compounds useful as semiconductor materials and catalysts are provided.
Claims (2)
状構造を有する化合物(1) Compound with hexagonal layered structure represented by YbFeZn_4O_7
もしくは加熱により酸化イッテルビウムに分解される化
合物と、金属鉄あるいは酸化鉄もしくは加熱により酸化
鉄に分解される化合物と、金属亜鉛あるいは酸化亜鉛も
しくは加熱により酸化亜鉛に分解される化合物と、Ｙｂ
、ＦｅおよびＺｎの割合が原子比で１対１対４の割合で
混合し、該混合物を６００℃以上の温度で大気中、酸化
性雰囲気中あるいはＹｂおよびＦｅが各々３価イオン状
態、Ｚｎが２価イオン状態より還元されない還元雰囲気
中で加熱することを特徴とするＹｂＦｅＺｎ＿４Ｏ＿７
で示される六方晶系の層状構造を有する化合物の製造法
。(2) Metallic ytterbium or ytterbium oxide or a compound that decomposes into ytterbium oxide when heated; Metallic iron or iron oxide or a compound that decomposes into iron oxide when heated; Metallic zinc or zinc oxide or a compound that decomposes into zinc oxide when heated. and Yb
, Fe and Zn are mixed in an atomic ratio of 1:1:4, and the mixture is heated at a temperature of 600°C or higher in the air, in an oxidizing atmosphere, or in a state where Yb and Fe are each in a trivalent ion state and Zn is in a trivalent ion state. YbFeZn_4O_7 characterized by being heated in a reducing atmosphere where it is not reduced beyond the divalent ion state
A method for producing a compound having a hexagonal layered structure represented by
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12905587A JPS63295435A (en) | 1987-05-26 | 1987-05-26 | Compound shown by ybfezn4o7 and having hexagonal lamellar structure and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12905587A JPS63295435A (en) | 1987-05-26 | 1987-05-26 | Compound shown by ybfezn4o7 and having hexagonal lamellar structure and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63295435A true JPS63295435A (en) | 1988-12-01 |
| JPH0367972B2 JPH0367972B2 (en) | 1991-10-24 |
Family
ID=14999972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12905587A Granted JPS63295435A (en) | 1987-05-26 | 1987-05-26 | Compound shown by ybfezn4o7 and having hexagonal lamellar structure and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63295435A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5943416A (en) * | 1982-09-01 | 1984-03-10 | Matsushita Electric Ind Co Ltd | Temperature controller |
-
1987
- 1987-05-26 JP JP12905587A patent/JPS63295435A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5943416A (en) * | 1982-09-01 | 1984-03-10 | Matsushita Electric Ind Co Ltd | Temperature controller |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0367972B2 (en) | 1991-10-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |