JPS63292963A - Deodorizing material - Google Patents
Deodorizing materialInfo
- Publication number
- JPS63292963A JPS63292963A JP62127229A JP12722987A JPS63292963A JP S63292963 A JPS63292963 A JP S63292963A JP 62127229 A JP62127229 A JP 62127229A JP 12722987 A JP12722987 A JP 12722987A JP S63292963 A JPS63292963 A JP S63292963A
- Authority
- JP
- Japan
- Prior art keywords
- cellulose acetate
- deodorizing
- deodorant
- granular
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 36
- 239000000463 material Substances 0.000 title claims abstract description 27
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 22
- 239000002781 deodorant agent Substances 0.000 claims abstract description 17
- 239000003086 colorant Substances 0.000 claims abstract description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000008187 granular material Substances 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 5
- 239000000049 pigment Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 6
- -1 ester derivatives of acrylic acid Chemical class 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000021736 acetylation Effects 0.000 description 4
- 238000006640 acetylation reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- WQRWNOKNRHCLHV-TWGQIWQCSA-N (z)-2-bromo-3-phenylprop-2-enal Chemical compound O=CC(/Br)=C/C1=CC=CC=C1 WQRWNOKNRHCLHV-TWGQIWQCSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- 241000209507 Camellia Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920001747 Cellulose diacetate Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- RSAZYXZUJROYKR-UHFFFAOYSA-N indophenol Chemical compound C1=CC(O)=CC=C1N=C1C=CC(=O)C=C1 RSAZYXZUJROYKR-UHFFFAOYSA-N 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は人の目に付きやすい場所でも用いることのでき
る美麗な消臭材に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a beautiful deodorizing material that can be used even in places where people can easily see it.
〈従来技術〉
熱可塑性重合体に消臭剤を付与してなる消臭材は公知で
ある。たとえば「有機高分子重合体と粒径２５０ミクロ
ン以下の活性炭とから構成される微細複合体からなる吸
着・脱臭剤」 （特開昭５３−９６９８３号公報）が知
られている。ここに有機高分子重合体としてはスチレン
誘導体、アクリル酸またはメタクリル酸のエステル誘導
体、エチレン系不飽和単量体又はジエン系中吊体からな
る単独重合体または共重合体、ポリウレタン系、ポリ味
素。<Prior Art> Deodorizing materials made by adding a deodorant to a thermoplastic polymer are known. For example, ``an adsorption/deodorizing agent consisting of a fine composite composed of an organic polymer and activated carbon having a particle size of 250 microns or less'' (Japanese Patent Application Laid-Open No. 53-96983) is known. Examples of organic polymers include styrene derivatives, ester derivatives of acrylic acid or methacrylic acid, homopolymers or copolymers consisting of ethylenically unsaturated monomers or diene-based hollow bodies, polyurethanes, and polyphenols. .
ポリエステル、芳香族ポリアミド、ポリスルフォン、ポ
リエーテルスルフォン、ポリフェニレンオキサイド、ポ
リカーボネート等が挙げられている。Examples include polyester, aromatic polyamide, polysulfone, polyethersulfone, polyphenylene oxide, polycarbonate, and the like.
また［少なくとも表面が高吸水性機能を有する樹脂であ
る基材に植物より抽出された水溶性の消臭成分が吸収さ
れていることを特徴とする消臭材］（特開昭６０−２５
９２６７号公報）が開示されている。[Deodorizing material characterized in that a water-soluble deodorizing component extracted from plants is absorbed into a base material whose surface is made of a resin having a highly water-absorbing function] (Japanese Patent Laid-Open No. 60-25
No. 9267) is disclosed.
ここに高吸水性機能を有する樹脂とはイオン性基を有す
る電解質ポリマーを架橋した樹脂（粉状物または粒状物
）であり、たとえばアクリレートポリマーのケン化物、
ポリアクリル酸ナトリウムなどアニオン性基を有する水
溶性ポリマーの架橋物。Here, the resin having a super-absorbent function is a resin (powdered or granular) obtained by crosslinking an electrolyte polymer having an ionic group, such as a saponified acrylate polymer,
A crosslinked product of water-soluble polymers with anionic groups such as sodium polyacrylate.
でんぷん、アミロース、ポリビニルアルコールなどにア
クリレートモノマーをグラフト重合しケン化した物など
である。These include starch, amylose, polyvinyl alcohol, etc., which are graft-polymerized with acrylate monomers and then saponified.
樹脂被覆される基材としてはアクリル系樹脂のほかポリ
エチレン、ポリプロピレン、ポリエステル、ナイロン、
ビニロン等の合成繊維、麻、綿。Base materials coated with resin include acrylic resin, polyethylene, polypropylene, polyester, nylon,
Synthetic fibers such as vinylon, linen, and cotton.
羊毛等の天然繊維、ガラスファイバー、炭素Ｉｌｉ維・
金属繊維などが挙げられている。また粒状消臭材につい
ては［０，２〜Ｏ０’ｌｃｃ／ ｇｒの細孔容積及び２
〜１０ｍｍの粒径を有する粒状固体吸着材に該吸着剤当
り０．３〜１０重間％のα−ブロモシンナミックアルデ
ヒド及び２〜３０重量％の香料を担持させたことを特徴
とする粒状消臭材」 （特開昭５７−１４８９５０号公
報）が開示されている。ここに粒状固体吸着剤とはたと
えばシリカ、アルミナ、シリカアルミ、す、ぜオライド
等である。Natural fibers such as wool, glass fibers, carbon fibers, etc.
Examples include metal fibers. In addition, for granular deodorizing materials, the pore volume of [0.2~O0'lcc/gr] and 2
A granular extinguisher characterized in that a granular solid adsorbent having a particle size of ~10 mm carries 0.3 to 10% by weight of α-bromocinnamic aldehyde and 2 to 30% by weight of fragrance per adsorbent. "Odor material" (Japanese Unexamined Patent Publication No. 148950/1983) is disclosed. The particulate solid adsorbent herein includes, for example, silica, alumina, silica aluminum, sulphate, and zeolide.
しかしながら従来の消臭材は悪臭発生源に直接役人され
たり散布されたりあるいは冷蔵庫内の隅に置かれたりい
わば人の目にふれにくい場所で使われることが多く、ま
た人の目につきやすい場所で使用できるだけの美観を有
しないものであった。However, conventional deodorizing materials are often applied or sprayed directly to the source of the odor, or placed in a corner of the refrigerator, or in places that are hard to see, or in places that are easily seen by people. It did not have a good enough appearance to be usable.
すなわち従来の消臭材は悪臭除去機能と共に美観を要求
する最近の感性の時代にマツチしないものである。In other words, conventional deodorizing materials do not suit the modern era of sensibilities, which require aesthetic appearance as well as odor removal functions.
本発明者はかかる観点から新しい時代にマツチする消臭
材を開発するべく種々の素材について検討した結果、消
臭性、美観、安価、成型性を兼備した消臭材として本発
明に至ったものである。From this point of view, the inventor studied various materials in order to develop a deodorant material suitable for the new era, and as a result, the present inventor arrived at the present invention as a deodorizing material that combines deodorizing properties, aesthetics, low cost, and moldability. It is.
〈発明の構成〉
ザなわら本発明は「熱可塑性重合体に消臭剤を付与して
なる消臭材において、粒状酢酸セルロースに透明性消臭
剤と着色剤とを付与したことを特徴とする消臭材」であ
る。<Structure of the Invention> The present invention is a deodorizing material made by adding a deodorizing agent to a thermoplastic polymer, characterized in that a transparent deodorizing agent and a coloring agent are added to granular cellulose acetate. It is a deodorizing material that
本発明の酢酸セルロースはその酢化度が約５４％のセル
ロースジアセテート、その酢化度が約６２％のセルロー
ストリアセテートのいずれのものも適する。しかし本発
明の消臭材では、酢化度は特に必要的条件とはならない
。Suitable cellulose acetates of the present invention include cellulose diacetate with a degree of acetylation of about 54% and cellulose triacetate with a degree of acetylation of about 62%. However, in the deodorizing material of the present invention, the degree of acetylation is not a particularly necessary condition.
本発明でいう粒状体とは、単に粒状の形状物に限らず、
フレークのような板状のもの、或いはタブレット状のも
の、球状乃至楕円状のもののいずれでもよい。そして表
面は平滑でも凹凸を呈するものであってもよい。酢酸セ
ルロースのテトラヒドロフラン、酢酸等の溶液から非溶
媒中に凝固させる工程で、濃度、温度、撹拌条件等を適
宜調整することによって、種々な粒状体としての形状。The granular material in the present invention is not limited to simply a granular shape,
It may be plate-shaped like flakes, tablet-shaped, or spherical or elliptical. The surface may be smooth or uneven. This is a process of coagulating cellulose acetate from a solution of tetrahydrofuran, acetic acid, etc. in a non-solvent, and by appropriately adjusting the concentration, temperature, stirring conditions, etc., various granular shapes can be obtained.
粒径のものを得ることができる。また、一旦粒状体とし
た後でも、溶媒によって膨潤乃至部分溶解させた粒状体
を非溶媒に浸漬してその表面の状態を種々変えることも
可能である。粒状体は０．５〜５ ｍｍ程度の平均粒径
（粒径は最大径をいう。１００ケの平均粒径）の範囲と
なるように制御すればよい。１〜３ ｍｍ程度のものが
、取扱いの点で容易である。粒径が０．５ｓ未満では粉
末状となり取扱い性が極度に低下する。粒径が５ ｍｍ
を越えると単位重量当りの表面積が小さくなり消臭効率
が低下する。Particle size can be obtained. Furthermore, even after the granules have been formed into granules, it is possible to variously change the surface condition of the granules that have been swollen or partially dissolved in a solvent by immersing them in a non-solvent. The granules may be controlled to have an average particle size of approximately 0.5 to 5 mm (particle size refers to the maximum diameter; average particle size of 100 particles). A diameter of about 1 to 3 mm is easy to handle. If the particle size is less than 0.5 s, it becomes powdery and the handling properties are extremely reduced. Particle size is 5 mm
If it exceeds 100%, the surface area per unit weight becomes small and the deodorizing efficiency decreases.
本発明の粒状消臭材を集合体として用いる場合は見掛は
比重を１００ ｃｔ／Ｉ当り１０〜７０ｇｒ（０，１〜
０．７ｇ／ ｃｒｄ ）程度とするのが好ましい。ここ
に見掛は比重は内径５ｏｍｍ、高さ５１ｍＭの円筒（頁
論などがよい）からなる １００ ｃｄの容器に酢酸セ
ルロース粒状体を入れ、机上で落下させながら充填させ
、しかる後その重量を計測するものである。落下による
酢酸セルロース粒状体の充填は５〜６回程程度飽和充填
状態に達するので、重■の測定に際しては１０回程度の
落下充填回数でよい。When the granular deodorizing material of the present invention is used as an aggregate, the apparent specific gravity is 10 to 70 gr (0.1 to 70 gr per 100 ct/I).
The amount is preferably about 0.7 g/crd). Here, cellulose acetate granules are placed in a 100 cd container (apparently a cylinder with an inner diameter of 5 omm and a height of 51 mm) and the specific gravity is dropped on a desk, and the weight is then measured. It is something to do. Since the filling of cellulose acetate granules by dropping reaches a saturated filling state about 5 to 6 times, the number of times of dropping and filling may be about 10 times when measuring the weight.
着色剤は顔料でも染料でもよい。公知の着色剤を用いて
よい。着色は染料や顔料を酢酸セルロース溶液中に分散
させて行う。ついで着色酢酸セルロース溶液を粒状化す
る。The coloring agent may be a pigment or a dye. Known colorants may be used. Coloring is performed by dispersing dyes or pigments in a cellulose acetate solution. The colored cellulose acetate solution is then granulated.
透明性消臭剤は着色酢酸セルロース粒状体の色調をそこ
なわない程度の透明性を有するものである。無色透明で
も着色透明でもよい。たとえばツバキ科植物の葉から抽
出された消臭剤（特開昭５６−１０００６０号公報）な
どを用いることができる。The transparent deodorant has transparency to the extent that it does not impair the color tone of the colored cellulose acetate particles. It may be colorless and transparent or colored and transparent. For example, a deodorizing agent extracted from leaves of plants of the Camellia family (Japanese Unexamined Patent Publication No. 100060/1983) can be used.
酢酸セルロースに消臭剤を付与するには酢酸セルロース
溶液に消臭剤を付与することもできるが若色酢１ｌｌｔ
？ルロース粒状体に消臭剤溶液をスプレーするか消臭剤
溶液に着色酢酸セルロース粒状体を浸漬したのち乾燥す
る。To add a deodorant to cellulose acetate, you can also add a deodorizer to the cellulose acetate solution, but 1 liter of young white vinegar
? A deodorant solution is sprayed onto the ululose granules, or the colored cellulose acetate granules are dipped in the deodorant solution and then dried.
〈発明の効果〉 本発明の消臭性粒状体は、以下のごとき効果を有する。<Effect of the invention> The deodorizing granules of the present invention have the following effects.
（１） 消臭性能が高い（消臭性〉。(1) High deodorizing performance (deodorizing property).
（２）悪臭の再放出性が低い（消臭性）。(2) Low re-release of bad odors (deodorizing properties).
（３）つぶれにくく、摩滅しにくい（形態寸法安定性、
耐久性）。(3) Resistant to crushing and abrasion (morphological stability,
durability).
（４）自由に着色することができる。美しい色に着色す
ることができるので美観を生かして商品化することかで
きる。(4) Can be colored freely. Since it can be colored in beautiful colors, it can be commercialized to take advantage of its aesthetic appearance.
また着色した消臭材を混合して異色効果を出すことがで
さる（着色性、美観）。It is also possible to create a unique effect by mixing colored deodorizing materials (colorability, aesthetics).
（５）つぶれにくく摩滅にしくい粒状体をなしているの
で取扱いがきわめて容易である（取扱性）。(5) It is extremely easy to handle because it is in the form of granules that are difficult to crush and wear out (handlability).
（６） 製造が容易でありかつ安圃に製造することが
できる（生産性）。(6) It is easy to manufacture and can be manufactured in a safe field (productivity).
（７）粒状集合体として成形することができる（成形性
）。(7) Can be molded as a granular aggregate (moldability).
〈実施例〉 以下本発明の消臭材の製造方法を実施例で示ず。<Example> The method for producing the deodorizing material of the present invention will not be shown in Examples below.
なお実施例における性能評価は下記の方法に従って行っ
た。Note that performance evaluation in Examples was performed according to the following method.
消臭性評価
２０リツトルの密閉容器に消臭材２０ｇ「を入れ、さら
に２．８％のアンモニア水溶液５ｄを加えて密閉した。Evaluation of deodorizing properties: 20 g of deodorizing material was placed in a 20 liter airtight container, and 5 d of a 2.8% aqueous ammonia solution was added and the container was sealed.
常温で一定時間装置したのち残留するアンモニアガスを
インドフェノール法（吸光度法）により測定した。同様
にブランクテス１へを行い除去率を求めた。また試験後
、試供消臭材を３５０ｃｄの密閉容器に入れ再放出の有
無を検知管により測定した。After the device was left at room temperature for a certain period of time, residual ammonia gas was measured by the indophenol method (absorbance method). Blank test 1 was similarly performed to determine the removal rate. After the test, the sample deodorizing material was placed in a 350 cd airtight container and the presence or absence of re-release was measured using a detection tube.
実施例２
酢化度５５％の酢酸セルロースフレークス（平均粒径１
．ａｍｒｒ＋見掛は比重０．４２ ）を分散染料Ｏｒａ
ｎｇｅ ＧＦ２Ｒ（ＢＡＳＦ社製）浴比１：３０゜昇温
時間３０分間、染色温度９８℃、染色時間４５分間で染
色したのち水洗、脱液、乾燥（１１５℃で２０分間）し
たく染着量は酢酸セルロースフレークス重ωに対し０．
５重量％）。Example 2 Cellulose acetate flakes with a degree of acetylation of 55% (average particle size 1
．． amrr + apparent specific gravity 0.42) as disperse dye Ora
nge GF2R (manufactured by BASF) Bath ratio: 1:30°, heating time: 30 minutes, dyeing temperature: 98°C, dyeing time: 45 minutes, then washing with water, deliquing, and drying (20 minutes at 115°C). is 0 for cellulose acetate flakes weight ω.
5% by weight).
ついで消臭剤水溶液（消臭剤［フレッシュシライマツ■
ＦＳ−５００Ｊにノニオン系界面活性剤１ｇ／磨を添加
）に染色フレークスを６０分間浸漬し、ついで１分間遠
心脱液したのち風乾した。消臭剤付着量は酢酸セルロー
スフレークス重量に対し１．４倍であった。得られた消
臭材の消臭性は第１表のとおりであった。Next, deodorant aqueous solution (deodorant [Fresh Shiraimatsu ■
The dyed flakes were immersed in FS-500J (adding 1 g of nonionic surfactant/polish) for 60 minutes, centrifuged for 1 minute to remove liquid, and then air-dried. The amount of deodorant attached was 1.4 times the weight of cellulose acetate flakes. The deodorizing properties of the obtained deodorant material were as shown in Table 1.
得られた消臭材の消臭性は高く再放出性は低かった（第
１表）。消臭材は美しい色に着色されつぶれにくく摩滅
しにくい粒状体であり形態寸法安定性、耐久性の優れた
ものであった。The obtained deodorizing material had high deodorizing properties and low re-release properties (Table 1). The deodorizing material was a beautifully colored granular material that was resistant to crushing and abrasion, and had excellent dimensional stability and durability.
Claims (1)
、粒状酢酸セルロースに透明性消臭剤と着色剤とを付与
したことを特徴とする消臭材。A deodorizing material made by adding a deodorant to a thermoplastic polymer, characterized in that a transparent deodorant and a coloring agent are added to granular cellulose acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62127229A JPS63292963A (en) | 1987-05-26 | 1987-05-26 | Deodorizing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62127229A JPS63292963A (en) | 1987-05-26 | 1987-05-26 | Deodorizing material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63292963A true JPS63292963A (en) | 1988-11-30 |
Family
ID=14954924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62127229A Pending JPS63292963A (en) | 1987-05-26 | 1987-05-26 | Deodorizing material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63292963A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5588766A (en) * | 1978-12-27 | 1980-07-04 | Katsuraya Fine Goods | Deodorizing cleaning agent of toilet |
| JPS60122566A (en) * | 1983-12-06 | 1985-07-01 | 日進香料株式会社 | Deodorant |
| JPS61265145A (en) * | 1985-05-18 | 1986-11-22 | 工業技術院長 | Solid deodorant |
-
1987
- 1987-05-26 JP JP62127229A patent/JPS63292963A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5588766A (en) * | 1978-12-27 | 1980-07-04 | Katsuraya Fine Goods | Deodorizing cleaning agent of toilet |
| JPS60122566A (en) * | 1983-12-06 | 1985-07-01 | 日進香料株式会社 | Deodorant |
| JPS61265145A (en) * | 1985-05-18 | 1986-11-22 | 工業技術院長 | Solid deodorant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4638057A (en) | Cellulose acetate molding containing odoriferous substance | |
| US3963442A (en) | Colorimetric indicator compositions and method of manufacture | |
| TW519493B (en) | Fragranced hydrogel air freshener kits | |
| US4735626A (en) | Air freshener unit | |
| GB2066839A (en) | A Method of Manufacture of Perfumed Detergents | |
| JPS60197746A (en) | Porous spherical particles and preparation thereof | |
| TW200909484A (en) | Granular composites of inorganic particulates and redispersible latex powders and methods | |
| CN109322155A (en) | A kind of preparation method of triple responsive nano fiber hydrogels | |
| JPH02255704A (en) | Fine hollow polymer particle, production and use thereof | |
| CN107974831A (en) | Polypropylene non-woven fabric that a kind of calcium alginate is modified and preparation method thereof | |
| JPS63292963A (en) | Deodorizing material | |
| JPH01256965A (en) | Deodorizer and deodorant molding therefrom | |
| CN108504167A (en) | A kind of discoloration of chance water and indiffusible ink and its preparation method and application | |
| US3336156A (en) | Copolymer vinylpyrrolidone vinylacetate film former for coating or printing on water soluble films | |
| JPS59106501A (en) | Diaper type wear article | |
| CN108097034B (en) | It can quick, high-efficient cleaning removal organic polluter environmentally protective nanometer sustained-release gel | |
| JPH01201364A (en) | Moisture-detective water-absorptive composition and water-absorptive molding | |
| CN112358701A (en) | Reflective film component and preparation method thereof | |
| JPH0699022A (en) | Deodorant sheet | |
| CN107699399A (en) | A kind of anti-colour contamination block of long-acting washing machine and preparation method thereof | |
| KR0162879B1 (en) | Air fresh aromatic substances and method for producing thereof | |
| CN109060789A (en) | A kind of visualization oxygen indicator and preparation method thereof | |
| JPH0280313A (en) | Colored active carbon | |
| JP4255316B2 (en) | Functional carrier and functional material using the same | |
| JP4384135B2 (en) | Method for producing transparent bead-like superabsorbent resin colored without color transfer and sustained-release preparation containing the same |