KR0162879B1 - Air fresh aromatic substances and method for producing thereof - Google Patents

Air fresh aromatic substances and method for producing thereof Download PDF

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Publication number
KR0162879B1
KR0162879B1 KR1019950036848A KR19950036848A KR0162879B1 KR 0162879 B1 KR0162879 B1 KR 0162879B1 KR 1019950036848 A KR1019950036848 A KR 1019950036848A KR 19950036848 A KR19950036848 A KR 19950036848A KR 0162879 B1 KR0162879 B1 KR 0162879B1
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weight
parts
air freshener
producing
solvent
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KR1019950036848A
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KR970020123A (en
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강한철
오수일
민현진
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신현우
주식회사옥시
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/21—Use of chemical compounds for treating air or the like

Abstract

본 발명은 나쁜 냄새를 제거하고 상쾌하고 은은한 방향을 내게하고 소취역할을 하는 공기청향제 및 그의 제조방법에 관한 것이다.The present invention relates to an air freshener which removes bad odors, gives off a fresh and gentle fragrance, and acts as a deodorant, and a manufacturing method thereof.

종래의 공기청향제는 압축가스와 방향성 물질의 혼합물을 압축용기에 넣어 분사 살포하여 사용하였으나 시각적인 효과를 전혀 고려하지 않은 것이다.Conventional air fresheners are used by spraying and spraying a mixture of compressed gas and aromatic material into a compression vessel, but does not consider any visual effects.

본 발명의 공기청향제는 모양이 좋고 고급스런 외관을 나타내면서 그 효능을 장시간 유지시킬 수 있다.The air freshener of the present invention can maintain its efficacy for a long time while having a good appearance and high-quality appearance.

Description

공기청향제 및 그의 제조방법Air freshener and preparation method thereof

본 발명은 실리카겔 입자에 염료, 소취제, 향료 및 펄제(Pearl Luster)를 함침시켜서 된 공기청향제와 그의 제조방법에 관한 것이다.The present invention relates to an air freshener obtained by impregnating silica gel particles with dyes, deodorants, perfumes and pearl luster, and a method for producing the same.

구체적으로는 실내에서 사용되는 담배 재떨이에 소량 넣어 주거나 냉장고 등에 넣어 실내의 담배 냄새를 제거하고 상쾌하고 은은한 방향(芳香)을 내게하거나 냉장고 내의 소취 역할을 하는 공기청향제(Air freshening preparation)와 그의 제조방법에 관한 것이다.Specifically, an air freshening preparation and a method of manufacturing the same which are put in a small amount in a cigarette ashtray used indoors or put in a refrigerator to remove the smell of cigarettes indoors, give a fresh and gentle aroma, or act as a deodorant in the refrigerator. It is about.

종래에 시판되고 있는 공기청향제는 압축가스와 방향성 물질의 혼합물을 압축 용기내에 넣은 것을 거실, 욕실 또는 주방 등에 분산(spray) 살포하여 거실, 욕실 또는 주방의 나쁜 냄새를 제거하는데 사용하는 것이 있으나 이러한 공기청향제는 실내의 시각적인 효과는 전혀 고려하고 있지 않으며 냉장고 등에 넣어주는 소취제도 역시 시각적인 효과는 전혀 고려하지 않고 있다.Conventional air fresheners are sprayed with a mixture of compressed gas and aromatic material in a compression container to spray a living room, bathroom or kitchen to remove bad odors in the living room, bathroom or kitchen. Fresheners do not consider the visual effects of the room at all, and the deodorant that is put in the refrigerator does not consider the visual effects at all.

본 발명은 실내의 시각적인 효과를 나타내면서도 공기청향제의 역할을 하는 공기청향제와 그의 제조방법에 관한 것이다.The present invention relates to an air freshener which acts as an air freshener while exhibiting visual effects in a room and a method of manufacturing the same.

본 발명에서 사용하는 실리카겔(Silica gel)은 다공성 무수규산(SiO2)의 입자를 사용하며 이 무수규산은 다공성 구조를 갖으며 화학적으로 안정하고 광대한 표면적에 따른 물리화학적 흡착력이 탁월하며, 무색 투명하고 무취하여 방향제와 소취제를 흡착시키기에 용이할 뿐 아니라 그 효능을 장시간 유지시킬 수 있는 특성이 있다.The silica gel used in the present invention uses porous silicate (SiO 2 ) particles, which have a porous structure, are chemically stable, have excellent physicochemical adsorption capacity according to a large surface area, and are colorless and transparent. As it is odorless and easy to adsorb the fragrance and deodorant, it has the property of maintaining its efficacy for a long time.

실리카겔은 화학적 흡착에 의하여 수분이 실리카겔의 다공 및 표면에서 수소결합을 형성하는데, 이것을 미리 용제로써 불활성 처리를 하여 실리카겔 표면을 친유기 쪽으로 성질을 강하게 만들면, 수분의 흡수를 막아주며 향이 함침되기 쉬워진다. 그 위에 모양이 좋고 고급스러운 외관을 나타내주기 위해 펄제(pearl 劑)를 코팅하려면 펄제에는 친수성이 강한 산화티탄(TiO2)이 존재하므로 접착제를 사용하여야 한다. 이에 따라 친유기와 친수기를 동시에 갖는 용제가 필요하다. 이에 적합한 용제로는 에틸렐글리콜(ethylene glycol), 프로필렌글리콜(propylene glycol), 폴리프로필렌글리콜(polypropylene glycol)등이 있다.Silica gel has a hydrogen bond in the pores and the surface of the silica gel by chemical adsorption, which is inertly treated with a solvent in advance to make the silica gel surface strong toward the lipophilic, preventing the absorption of moisture and fragrance is easily impregnated. In order to coat a pearl on the surface of the pearl to provide a good appearance and a high-quality appearance, since the hydrophilic titanium oxide (TiO 2 ) is present on the pearl, an adhesive should be used. Accordingly, a solvent having both a lipophilic group and a hydrophilic group is required. Suitable solvents include ethylene glycol, propylene glycol, polypropylene glycol, and the like.

펄제는 투명한 운모(mica)를 산화티탄으로 코팅한 것으로서 산화티탄피막의 큰 굴절율에 의한 빛의 반사에 의해 진주 광택의 효과를 낸다.Pearls are coated with transparent mica (titanium oxide), which gives pearl luster by the reflection of light due to the large refractive index of the titanium oxide film.

진주 광택의 색상은 코팅된 산화티탄의 두께에 따라 달라지며 층이 두꺼워 짐에 따라 은색(silver), 금색(gold), 적색(red), 청색(blue), 초록(green)등으로 나타나게 된다.The color of the pearl luster depends on the thickness of the coated titanium oxide, and as the layer thickens, it appears in silver, gold, red, blue, green and so on.

펄제는 가소제와 반죽한 페이스트(paste) 상태의 것과 이를 용제에 희석한 액상의 것과 분체상의 것이 있는데 본 발명에서는 분체상의 것을 사용하였다. 펄제의 입자가 너무 작으면 표면은 아주부드러우나, 광택이 죽고 본래의 색을 잃게 한다. 반면 입자가 너무 크면 광택은 좋으나 표면이 거칠어진다. 본 발명에서 가장 적합한 입자 크기는 5∼50㎛정도이다.The pulsing agent is a pasty state kneaded with a plasticizer, a liquid form diluted with a solvent, and a powdery one. In the present invention, a powdery one is used. If the particles of pearl are too small, the surface will be very smooth, but the luster will die off and lose its original color. On the other hand, if the particles are too large, the gloss is good but the surface is rough. The most suitable particle size in this invention is about 5-50 micrometers.

고체입자인 펄제를 코팅하기 위해서는 접착제가 필요하며, 실리카겔 기공속에 함침된 향이 밖으로 휘산되려면 향투과성이 좋은 접착제가 필요하다. 이러한 요구를 충족시키는 접착제로는 폴리비닐아세트산(PVAC), 메틸셀룰로오스(methyl cellulose), 폴리비닐알콜(PVA), 폴리비닐피롤리돈(PVP), 아크릴수지(acryl resin)등이 있다. 펄제 입자에는 친수성이 강한 산화티탄이 코팅되어 있고, 표면에는 친유성의 향이 함침되어 있으므로 접착제는 용제와 마찬가지로 친수성과 친유성을 동시에 갖는 물질이어야 한다.An adhesive is required to coat the pearl particles, which are solid particles, and an adhesive having a good permeability is required for the fragrance impregnated in the pores of silica gel to be volatilized out. Adhesives that meet these demands include polyvinyl acetic acid (PVAC), methyl cellulose, polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), and acrylic resins. Since the pearlescent particles are coated with a strong hydrophilic titanium oxide, and the surface is impregnated with a lipophilic fragrance, the adhesive should be a material having both hydrophilicity and lipophilic properties as well as solvents.

염료를 실리카겔에 처리할 때 유성염료는 광택과 일광에 대한 안전성면에서 수성염료 보다 성능이 떨어진다. 따라서 염료는 수성염료가 적당하다.When dyes are treated with silica gel, oil dyes are less performant than aqueous dyes in terms of gloss and safety against sunlight. Therefore, the dye is suitably an aqueous dye.

본 발명의 공기청향제의 제조방법과 같다.It is the same as the manufacturing method of the air freshener of this invention.

용제에 염료와 향료 또는 소취제를 넣은 A용액을 먼저 준비한다. 이 용액의 조성을 용제 5∼20중량부, 염료 0.001∼0.2중량부, 향료 또는 소취제 0.1∼10중량부로 한다. 소취제(deodorant)로서는 산화아연(ZnO) 또는 과산화아연 등이 사용된다.Prepare solution A with dye, fragrance or deodorant in the solvent. The composition of this solution is 5 to 20 parts by weight of solvent, 0.001 to 0.2 part by weight of dye, and 0.1 to 10 parts by weight of perfume or deodorant. As the deodorant, zinc oxide (ZnO), zinc peroxide or the like is used.

용제와 접착제와 펄제를 넣은 B용액은 용제 5∼20중량부, 접착제 0.1∼10중량부, 펄제 0.1∼1중량부의 조성을 가진다. 0.1∼10중량부의 접착제를 찬물에 혼합후 온도를 90℃까지 가열한다. 투명한 용액이 되면 상온으로 냉각시킨다. 이 접착제액에 용제를 소량씩 투입하면서 균일해지도록 교반한다. 그 후 펄제를 투입하면서 혼합한다.The solution B containing the solvent, the adhesive and the pearl agent has a composition of 5 to 20 parts by weight of the solvent, 0.1 to 10 parts by weight of the adhesive and 0.1 to 1 part by weight of the pearl agent. 0.1-10 parts by weight of the adhesive is mixed with cold water and the temperature is heated to 90 ° C. Cool to room temperature when a clear solution is obtained. It stirs so that it may become uniform, putting a small amount of solvent into this adhesive liquid. Thereafter, while mixing with a pearl agent.

무수규산 50∼80중량부에 A용액을 서서히 첨가하면서 혼합한다. A용액 분사단계가 마무리된 뒤 B용액을 서서히 첨가하면서 다시 혼합한다. 이를 건조하여 용제를 휘발시키면 외관이 투명하며 원하는 색상을 나타내는 공기청향제가 된다.50-80 weight part of silicic anhydrides are mixed, gradually adding A solution. After the solution A spraying step is completed, mix again while slowly adding solution B. When it is dried and volatilized, it becomes an air freshener which is transparent in appearance and has a desired color.

필요에 따라 소취제와 염료만을 함침시킨 실리카겔과 향료와 염료를 함침시킨 실리카겔, 그리고 외관을 좋게 하기 위해 염료만을 함침시킨 실리카겔 세가지를 동일 부피로 섞어 사용할 수도 있고 각기 색상이 다른 염료를 사용한 것을 혼합하여 사용할 수도 있다.If necessary, silica gel impregnated with deodorant and dye only, silica gel impregnated with perfume and dye, and silica gel impregnated with dye only for better appearance may be mixed in the same volume or mixed with dyes of different colors. It may be.

이하 본 발명을 실시예를 들어 구체적으로 설명한다.Hereinafter, the present invention will be described in detail with reference to Examples.

[실시예 1]Example 1

[실시예 2]Example 2

[실시예 3]Example 3

[실시예 4]Example 4

이상 실시예에서 실리카겔은 입자성의 것을 사용하였으나 본 발명을 실시하는데는 구상(球狀)의 실리카겔도 사용할 수도 있다.Silica gel in the above embodiment was used in the form of particulates, but spherical silica gel may also be used in the present invention.

상기 실시예에 있어서, 염료 및 향료는 시판되고 있는 것 중에서 필요에 따라 선택하여 사용할 수 있으며 소취제는 산화아연 또는 과산화아연중에서 선택된 것이며 펄제는 시판되고 있는 분체상의 것을 사용하였다.In the above examples, dyes and fragrances can be selected and used according to need from commercially available deodorant and zinc oxide or zinc peroxide.

Claims (5)

공기청향제에 있어서, 염료 0.001∼0.2중량부와 향료 또는 소취제 0.1∼10중량부를 용제 5∼20중량부에 용해시켜서 된 용액과 펄제 0.1∼1.0중량부와 접착제 0.1∼10중량부를 용제 5∼20중량부에 용해시켜서 된 용액을 실리카겔 50∼80중량부에 함침시킨 후 건조시킨 공기청향제.In the air freshener, 0.001 to 0.2 parts by weight of the dye and 0.1 to 10 parts by weight of the perfume or deodorant are dissolved in 5 to 20 parts by weight of the solvent, 0.1 to 1.0 parts by weight of the pearl agent and 0.1 to 10 parts by weight of the adhesive 5 to 20 parts by weight of the solvent. An air freshener dried by impregnating 50 to 80 parts by weight of a solution obtained by dissolving in a silica gel. 공기청향제의 제조방법에 있어서, 염료 0.001∼0.2중량부와 향료 또는 소취제 0.1∼10중량부를 용제 5∼20중량부에 용해시켜서 된 용액과 펄제 0.1∼1.0중량부와 접착제 0.1∼10중량부를 용제 5∼20중량부에 용해시켜서 된 용액을 실리카겔 50∼80중량부에 함침시킨 후 건조시키는 공정을 포함하는 것을 특징으로 하는 공기청향제의 제조방법.In the method for producing an air freshener, a solution obtained by dissolving 0.001 to 0.2 parts by weight of dye and 0.1 to 10 parts by weight of fragrance or deodorant in 5 to 20 parts by weight of solvent, 0.1 to 1.0 part by weight of pearl agent and 0.1 to 10 parts by weight of adhesive 5 A method for producing an air freshener comprising the step of impregnating 50 to 80 parts by weight of a silica gel solution dissolved in -20 parts by weight and then drying. 제2항에 있어서, 용제가 에틸렌글리콜, 프로필렌글리콜, 폴리프로필렌글리콜 중에서 선택된 공기청향제의 제조방법.The method for producing an air freshener according to claim 2, wherein the solvent is selected from ethylene glycol, propylene glycol, and polypropylene glycol. 제2항에 있어서, 접착제가 폴리비닐아세트산, 폴리비닐알콜, 메틸셀룰로오스, 아크릴수지, 폴리비닐필로리돈 중에서 선택된 공기청향제의 제조방법.The method of producing an air freshener according to claim 2, wherein the adhesive is selected from polyvinyl acetic acid, polyvinyl alcohol, methyl cellulose, acrylic resin, and polyvinylpyrrolidone. 제2항에 있어서, 펄제의 입자 크기가 5∼50㎛인 공기청향제의 제조방법.The method for producing an air freshener according to claim 2, wherein the particle size of the pearl agent is 5 to 50 µm.
KR1019950036848A 1995-10-24 1995-10-24 Air fresh aromatic substances and method for producing thereof KR0162879B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100375552B1 (en) * 2000-06-28 2003-03-10 이재덕 Aromatic for Air Conditioner
KR200452131Y1 (en) * 2008-11-13 2011-02-08 주식회사 대륙 Magnetic Contactor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100375552B1 (en) * 2000-06-28 2003-03-10 이재덕 Aromatic for Air Conditioner
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