JPS63288915A - 欠陥ＬａＯＦ構造型ビスマス・ストロンチウム・テルル複酸化物固溶体、その製造法及び該固溶体からなる酸素の超イオン伝導材料 - Google Patents
欠陥ＬａＯＦ構造型ビスマス・ストロンチウム・テルル複酸化物固溶体、その製造法及び該固溶体からなる酸素の超イオン伝導材料Info
- Publication number
- JPS63288915A JPS63288915A JP12482687A JP12482687A JPS63288915A JP S63288915 A JPS63288915 A JP S63288915A JP 12482687 A JP12482687 A JP 12482687A JP 12482687 A JP12482687 A JP 12482687A JP S63288915 A JPS63288915 A JP S63288915A
- Authority
- JP
- Japan
- Prior art keywords
- solid solution
- double oxide
- laof
- bismuth
- tellurium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006104 solid solution Substances 0.000 title claims description 32
- 229910052760 oxygen Inorganic materials 0.000 title claims description 17
- 239000001301 oxygen Substances 0.000 title claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 15
- 229910052714 tellurium Inorganic materials 0.000 title claims description 12
- 239000004020 conductor Substances 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 230000002950 deficient Effects 0.000 title description 6
- 239000000203 mixture Substances 0.000 claims description 35
- 239000000126 substance Substances 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 9
- 238000010304 firing Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 230000007547 defect Effects 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000523 sample Substances 0.000 description 5
- 229910000018 strontium carbonate Inorganic materials 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002226 superionic conductor Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical group [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004455 differential thermal analysis Methods 0.000 description 2
- 239000010436 fluorite Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 2
- -1 oxygen ion Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 229910000953 kanthal Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000001144 powder X-ray diffraction data Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Oxygen, Ozone, And Oxides In General (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Conductive Materials (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12482687A JPS63288915A (ja) | 1987-05-21 | 1987-05-21 | 欠陥ＬａＯＦ構造型ビスマス・ストロンチウム・テルル複酸化物固溶体、その製造法及び該固溶体からなる酸素の超イオン伝導材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12482687A JPS63288915A (ja) | 1987-05-21 | 1987-05-21 | 欠陥ＬａＯＦ構造型ビスマス・ストロンチウム・テルル複酸化物固溶体、その製造法及び該固溶体からなる酸素の超イオン伝導材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63288915A true JPS63288915A (ja) | 1988-11-25 |
| JPH0250053B2 JPH0250053B2 (enrdf_load_stackoverflow) | 1990-11-01 |
Family
ID=14895060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12482687A Granted JPS63288915A (ja) | 1987-05-21 | 1987-05-21 | 欠陥ＬａＯＦ構造型ビスマス・ストロンチウム・テルル複酸化物固溶体、その製造法及び該固溶体からなる酸素の超イオン伝導材料 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63288915A (enrdf_load_stackoverflow) |
-
1987
- 1987-05-21 JP JP12482687A patent/JPS63288915A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0250053B2 (enrdf_load_stackoverflow) | 1990-11-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |