JPS63262484A - Corrosion inhibitor - Google Patents
Corrosion inhibitorInfo
- Publication number
- JPS63262484A JPS63262484A JP63083211A JP8321188A JPS63262484A JP S63262484 A JPS63262484 A JP S63262484A JP 63083211 A JP63083211 A JP 63083211A JP 8321188 A JP8321188 A JP 8321188A JP S63262484 A JPS63262484 A JP S63262484A
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- composition according
- independently
- formula
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005260 corrosion Methods 0.000 title claims description 18
- 230000007797 corrosion Effects 0.000 title claims description 18
- 239000003112 inhibitor Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 55
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- -1 alkali metal salts Chemical class 0.000 claims description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical class C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 6
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical class CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 5
- 239000004611 light stabiliser Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- 239000003139 biocide Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 4
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CJYDWTHKOKCUPO-UHFFFAOYSA-N P(OCCCCCCCC)([O-])[O-].[Na+].[Na+] Chemical compound P(OCCCCCCCC)([O-])[O-].[Na+].[Na+] CJYDWTHKOKCUPO-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
- LLPLIJKNMIEBML-UHFFFAOYSA-N 1-(4-chlorophenyl)propane-1,1-diol Chemical compound CCC(O)(O)C1=CC=C(Cl)C=C1 LLPLIJKNMIEBML-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910001060 Gray iron Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- WLCFKPHMRNPAFZ-UHFFFAOYSA-M didodecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC WLCFKPHMRNPAFZ-UHFFFAOYSA-M 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/173—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/167—Phosphorus-containing compounds
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、燐酸塩と亜燐酸塩との混合物およびそのよう
な混合物の、特に金属の表面に対する、腐食抑制剤とし
ての使用に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to mixtures of phosphates and phosphites and the use of such mixtures as corrosion inhibitors, in particular for metal surfaces.
本発明によれば、
ａ）下記式！で示される化合物、およびＲ−（−０−Ｃ
，Ｈ２１１−）ｌｌ−０−１’−ＯＨ（１）ｂ）下記式
■で示される化合物
Ｒスー（ＱＣ１ｌＩＨ２，−）、−０−Ｐ−ＯＨ（ＩＩ
）＋１
〔上式中、ＲはＣ１／％Ｊ Ｊ）アルキル、ＣＢ ＡＩ
、）アルキル−Ｃ５，ｖｏアリルまたは−Ｇ Ｏ−Ｃ
Ｂ Ｎｘｚアルキルまたは−ＣＯ−Ｃ，〜、ユアルケニ
ルから選ばれ、Ｍはそれぞれ独立に水素、アルカリ金属
イオンまたはモル当量のアルカリ土類金属を表し、Ｒ１
はＭ（前記に規定したもの）または式ａ１Ｒ−（ＯＣｎ
”２ｎ−）ｘ−（Ｒ）
で示される基を表し、ｎはそれぞれ独立に２または３を
表し、Ｘはそれぞれ独立に０または１〜１５の整数を表
し、Ｒ２はＲとは独立に前記Ｒに規 ′定したも
のを表し、ｍはそれぞれ独立に２または３を表し、ｙは
０または１〜１５の整数を表す〕を含む組成物（腐食抑
制組成物）が提供される。According to the present invention, a) the following formula! A compound represented by, and R-(-0-C
, H211-)ll-0-1'-OH(1)b) Compound Rsu(QC1lIH2,-), -0-P-OH(II
)+1 [In the above formula, R is C1/%J J) alkyl, CB AI
,) alkyl-C5, vo allyl or -G O-C
B selected from Nxz alkyl or -CO-C, ~, youralkenyl, M each independently represents hydrogen, an alkali metal ion or a molar equivalent of an alkaline earth metal, R1
is M (defined above) or formula a1R-(OCn
"2n-)x-(R), where n each independently represents 2 or 3, X each independently represents 0 or an integer from 1 to 15, and R2 independently of R m each independently represents 2 or 3, and y represents 0 or an integer from 1 to 15] (corrosion inhibiting composition).
疑問を避けるために、この明細書においては、直鎖また
は分枝鎖であることのできるいかなる基も特記しない限
り直鎖または分枝鎖であるものとする。さらに、式中に
記号が１度以上現れる場合、その意味は特記しない限り
互いに他と独立であるものとする。For the avoidance of doubt, in this specification any group that can be straight or branched is intended to be straight or branched unless otherwise specified. Furthermore, when symbols appear more than once in a formula, their meanings are assumed to be independent of each other unless otherwise specified.
好ましくは、ＲはＲ’ｆちＣ６〜１ｓアルキルおよび０
８〜ＩＩアルキルフエニルから選ばれ、さらに好ましく
はＲはＲ“即ち０８〜！２アルキルフエニルから選ばれ
、最も好ましくはＲはＲ′“即ちオクチルフェニル、ノ
ニルフェニルおよびドデシルフェニルから選ばれる。Preferably, R is R'f C6-1s alkyl and 0
More preferably R is selected from 08 to !2 alkyl phenyl, most preferably R is selected from R' octylphenyl, nonylphenyl and dodecylphenyl.
好ましくはＲ２はＲ２′即ちＲ′とは独立にＲ′に規定
したものである。さらに好ましくはＲ２はＲ２″即ち０
６〜ＩＩアルキルである。最も好ましくはＲ２はＲ２″
即ち０８〜１２アルキルである。Preferably R2 is defined as R2', ie R' independently of R'. More preferably R2 is R2″ or 0
6-II alkyl. Most preferably R2 is R2''
That is, it is 08-12 alkyl.
Ｍは好ましくはＭ′即ちアルカリ全屈イオン、さらに好
ましくはナトリウムである。M is preferably M', i.e., an alkaline ion, more preferably sodium.
Ｒ１は好ましくはＲ１′即ちＭまたはｃ、゛〜８アルキ
ルから選ばれる。R1 is preferably selected from R1', ie M or c, ~8 alkyl.
ｎは好ましくは２である。n is preferably 2.
ｍは好ましくは２である。m is preferably 2.
Ｘは好ましくは０または１−１０の整数である。X is preferably 0 or an integer of 1-10.
ｙは好ましくは０または１〜１０の整数である。y is preferably 0 or an integer from 1 to 10.
好ましくは、本発明に係る腐食抑制組成物において、燐
酸塩の亜燐酸塩に対する比は１：４〜２０；１ （重量
）である。Preferably, in the corrosion inhibiting composition according to the invention, the ratio of phosphate to phosphite is between 1:4 and 20:1 (by weight).
式！および■の化合物は公知であるかまたは公知の化合
物から公知の方法によって製造することのできるもので
ある。formula! The compounds of (1) and (2) are known or can be produced from known compounds by known methods.
本発明に係る腐食抑制組成物は、好ましくは１種または
それ以上のフィルム形成剤を含む。好ましいフィルム形
成剤はポリアクリレートフィルム形成剤である。さらに
好ましくは、フィルム形成剤は水性アクリル樹脂分散液
からなるもの、特に英国特許１２６６２４６に記載され
たものである。Corrosion inhibiting compositions according to the invention preferably include one or more film formers. A preferred film forming agent is a polyacrylate film forming agent. More preferably, the film-forming agent consists of an aqueous acrylic resin dispersion, especially as described in GB 1266246.
これらの分散液は「乳化」重合により製造することがで
き、一般に３０〜６０％の活性成分を含む。These dispersions can be prepared by "emulsion" polymerization and generally contain 30-60% active ingredient.
本発明に係る、フィルム形成剤を含む組成物は、水で稀
釈することができる。好ましくは、そのような組成物は
水性分散液として添加される。さらに、本発明によれば
、アクリル樹脂と本発明に係る腐食防止組成物とを含む
ポリマー組成物が提供される。Compositions containing film-forming agents according to the invention can be diluted with water. Preferably such compositions are added as an aqueous dispersion. Furthermore, the present invention provides a polymer composition comprising an acrylic resin and a corrosion inhibiting composition according to the present invention.
好ましくは、本発明に係るポリマー組成物中に存在する
燐酸塩および亜燐酸塩の量は存在するアクリル樹脂の重
量に対して０．０４〜１６ｍｆｆ１％である。Preferably, the amount of phosphate and phosphite present in the polymer composition according to the invention is from 0.04 to 16 mff1%, based on the weight of the acrylic resin present.
好ましくは、本発明に係るポリマー組成物は存在するポ
リマー材料を可塑化するための軟化剤を含む。そのよう
な軟化剤の例は芳香族または脂肪族ジカルボン酸のジー
ＣＩ Ｎ４アルキルエステルを含む。Preferably, the polymer composition according to the invention comprises a softener to plasticize the polymeric material present. Examples of such softeners include di-CIN4 alkyl esters of aromatic or aliphatic dicarboxylic acids.
本発明に係る組成物のポリマーフィルム形成剤は１種ま
たはそれ以上のコモノマーと共重合されていてもよい。The polymeric film-forming agent of the composition according to the invention may be copolymerized with one or more comonomers.
そのようなコモノマーは、好ましくは、１種またはそれ
以上のアクリル酸、メタクリル酸、クロトン酸、アクリ
ルアミド、スヂレン、エヂＬ・ンおよびプロピレンから
選ばれる。Such comonomers are preferably selected from one or more of acrylic acid, methacrylic acid, crotonic acid, acrylamide, styrene, ethylene and propylene.
本発明に係る組成物は、好ましくは、ｐ Ｈ調整剤、殺
生物剤、界面活性剤、安息香酸のアルカリ全圧塩（例え
ば、安息香酸ナトリウム）、ベンズトリアゾール、トリ
ルトリアゾールおよび光安定剤から選ばれる１種または
それ以上の伯の添加剤を含む。The compositions according to the invention preferably contain pH regulators, biocides, surfactants, alkaline total pressure salts of benzoic acid (e.g. sodium benzoate), benztriazoles, tolyltriazoles and light stabilizers. Contains one or more additives.
好ましいｐＨ調整剤は水酸化ナトリウム、炭酸ナトリウ
、ム、重炭酸ナトリウム、酢酸ナトリウム、オルト燐酸
モノ−またはジ−ナトリウムおよびモノ−、ジーまたは
トリーエタノールアミン（好ましくはモノエタノールア
ミン）を含む。Preferred pH adjusting agents include sodium hydroxide, sodium carbonate, sodium bicarbonate, sodium acetate, mono- or di-sodium orthophosphate and mono-, di- or triethanolamine (preferably monoethanolamine).
好ましい殺生物剤はホルムアルデヒド、ｐ−クロロフェ
ニルプロパンジオールおよびジラウリルジメチルアンモ
ニウムクロロ、ドを含む。Preferred biocides include formaldehyde, p-chlorophenylpropanediol and dilauryldimethylammonium chloride.
好ましい界面活性剤はアニオン型およびノニオン型界面
活性剤を含む。Preferred surfactants include anionic and nonionic surfactants.
好ましい光安定剤はＮ−未置換、Ｎ−アルキルまたはＮ
−アシル置換２，２，６．６−チトラメチルピベリジニ
ル光安定剤および紫外線吸収剤を含む。Preferred light stabilizers are N-unsubstituted, N-alkyl or N-
-acyl-substituted 2,2,6,6-titramethylpiveridinyl light stabilizers and UV absorbers.
好ましくは、本発明に係るポリマー組成物は下記を含む
。Preferably, the polymer composition according to the invention comprises:
１００部の３０〜６０％水性アクリル樹脂分散液、
０．０１−１０２部の式１の化合物、
０．０１〜６．０部の式■の化合物、
０〜２．５部の安息香酸のアルカリ金属塩、０〜０．３
部のベンズトリアゾールおよびトリルトリアゾールの混
合物、および
０〜５部の軟化剤。100 parts of a 30-60% aqueous acrylic resin dispersion, 0.01-102 parts of a compound of formula 1, 0.01-6.0 parts of a compound of formula (■), 0-2.5 parts of alkali benzoic acid. Metal salt, 0-0.3
1 part of a mixture of benztriazole and tolyltriazole, and 0 to 5 parts of a softener.
本発明に係る組成物がフィルム形成剤を含む場合、それ
らは金泥表面の保護のための腐食抑制剤として特に適す
る。If the compositions according to the invention contain film-forming agents, they are particularly suitable as corrosion inhibitors for the protection of gold mud surfaces.
本発明に係る組成物は、特に、全屈対象物および、例え
ば、鋼、鼠鋳鉄、アルミニウム、マグネシウム、鉄、亜
鉛、銅または錫およびそれらの合金からなる表面の酸化
腐食を抑制するのに有効である。フィルム形成剤を含む
本発明に係る組成物は、フィルムにより腐食の作用に対
して保護され得る材料を保護するのに有効である。その
ような材料の例は、”Ｗｅｌｌ ｉｎｇｅｒ−Ｇｉ＋ｗ
＋ａｃｌ−Ｂｏｄｅｎｓｔｅｉｎ’。The composition according to the present invention is particularly effective in inhibiting oxidative corrosion of fully flexible objects and surfaces made of, for example, steel, gray cast iron, aluminum, magnesium, iron, zinc, copper or tin and their alloys. It is. Compositions according to the invention containing film-forming agents are effective for protecting materials that can be protected against the effects of corrosion by a film. An example of such a material is “Well inger-Gi+w
+acl-Bodenstein'.
ＷａｒｋｓＬｏｆｆ−Ｔａｂｅｌｌｅｎ ｄｃｒ
Ｍｅｔａｌｌｅ″ｌ ７ 八ｕｆｌａｇｅ。WorksLoff-Tabellen dcr
Metalle″l 7 eightuflage.
八１ｆｒｅｄ Ｋ８ｒｎｅｒ Ｖｅｒｌａｐ、ｅ 、ス
・ソツトガルト、中に見出すことができる。81 can be found in Fred K8rner Verlap, e.
本発明に係る、フィルム形成剤を含む組成物は、長期間
の屋内腐食保護および一時的な屋外腐食保護に有用であ
る。Compositions containing film-forming agents according to the present invention are useful for long-term indoor corrosion protection and temporary outdoor corrosion protection.
好ましくは、フィルム形成剤を含む本発明に係る組成物
は、５〜４０℃の最低限度のフィルム形成温度（Ｍ Ｆ
Ｔ）においてフィルムまたはコーチングを形成する。Preferably, the composition according to the invention comprising a film-forming agent has a minimum film-forming temperature (M F
Forming a film or coating at T).
これらの組成物は、公知の方法によって、例えば、浸漬
、スプレーまたはブラッシングによって、保護すべき表
面に適用することができる。コートすべき材料の使用に
よって、単一フィルムの厚さは好ましくは６０μまでで
ある。These compositions can be applied to the surface to be protected by known methods, for example by dipping, spraying or brushing. Depending on the use of the material to be coated, the thickness of the single film is preferably up to 60μ.
また、中間乾燥工程を用いて二層フィルムコーチングを
形成することもでき、そのような二層フィルムは８０μ
までの厚さを有するのが好ましい。Alternatively, an intermediate drying step can be used to form a two-layer film coating, such a two-layer film having a thickness of 80μ
Preferably, the thickness is up to .
χ■成物をコートすべき材料に通用後、本発明に係る組
成物は、好ましくは２０〜７０℃の温度において、空気
の流れの存在下または存在なしに、乾燥される。本発明
にかかる組成物は、好ましくはフィルムのセットの前に
４５℃までの温度において予備加温されてもよい。After applying the χ■ composition to the material to be coated, the composition according to the invention is dried, preferably at a temperature of 20 DEG to 70 DEG C., with or without a stream of air. The composition according to the invention may be prewarmed, preferably at a temperature of up to 45° C. before setting the film.
フィルム層の表面に対する最適な接着に対しては、本発
明に係る組成物の適用の前に表面を説脂するのが好まし
い。本発明に係る組成物は、また、すべてのルーズな錆
粒子が予め除去されている限り、錆びた表面に通用する
こともでき、それ以上の錆を防止するのを助けるであろ
う。For optimal adhesion of the film layer to the surface, it is preferred to degrease the surface before applying the composition according to the invention. The compositions according to the invention can also be applied to rusted surfaces as long as all loose rust particles have been removed beforehand and will help prevent further rusting.
本発明に係る組成物が適用された表面には、他のコーチ
ングまたはフィルムが適用されてもよい（組成物を乾燥
してフィルムまたはコーチングを形成後）。Other coatings or films may be applied to the surface to which the composition of the invention has been applied (after the composition has dried to form a film or coating).
本発明にがかるポリマー組成物は、２３０℃までの温度
で熱安定性である、無色透明のフィルムまたはコーチン
グを形成する。本発明に係る組成物の他の利点は、それ
らが水により稀釈可能であり、鉛および亜鉛イオンの存
在（生態学的に望ましくない）を必要とせず、毒性がな
く、生物学的に分解可能であるということである。The polymer compositions according to the invention form transparent, colorless films or coatings that are heat stable at temperatures up to 230°C. Other advantages of the compositions according to the invention are that they are dilutable with water, do not require the presence of lead and zinc ions (ecologically undesirable), are non-toxic and biologically degradable. That is to say.
明確にするために述べるならば、下記の例を除いて、式
■の化合物という場合には式■の化合物の混合物をも含
み、式Ｕの化合物という場合には式■の化合物の混合物
を含むものとする。For clarity, except in the following examples, references to compounds of formula (1) also include mixtures of compounds of formula (2), and references to compounds of formula U include mixtures of compounds of formula (2). shall be held.
下記の例は本発明をさらに説明するためのものである。The following examples serve to further illustrate the invention.
特記しない限り部および％は重量で示し、温度は℃であ
る。 ・
例１
室温（２０〜２５℃）においていっしょに十分に混合し
て、下記の組成物を調製した。Unless otherwise specified, parts and percentages are by weight and temperatures are in °C. - Example 1 The following compositions were prepared by mixing together thoroughly at room temperature (20-25°C).
８５０部の、メタクリル酸のメチルエステルとアクリル
酸のブチルエステルに基づくアクリル樹脂の、市販の（
Ｄｅｇｕｓｓａから）、水性分散液（５０％活性成分を
含む）、
１０３４部の、Ｎ−ブチルアルコールと式１ａｓＣ６１
１１７−Ｃ６１１〜−０−（ＣＩ＋２−ＣＩ！２−０−
）＠ −Ｈ（ｌａ）の化合物との混合物（２８１の比）
と五酸化燐とのｐ Ｈ８における反応により得られる、
燐酸塩混合物、
４．００部のオクチル亜燐酸ナトリウム、４．３０部の
安息香酸ナトリウム、
０．１２部のベンズトリアゾール、
０．０３部のトリルトリアゾール、
０．０５部のキシレンスルホン酸のナトリウム塩、１０
部のセバシン酸のジブチルエステル、および
１３０．１６部の水。850 parts of a commercially available (
from Degussa), aqueous dispersion (containing 50% active ingredient), 1034 parts of N-butyl alcohol and formula 1asC61
117-C611~-0-(CI+2-CI!2-0-
) @ -H(la) mixture with compound (ratio of 281)
and phosphorus pentoxide at pH 8.
Phosphate mixture, 4.00 parts sodium octyl phosphite, 4.30 parts sodium benzoate, 0.12 parts benztriazole, 0.03 parts tolyltriazole, 0.05 parts sodium salt of xylene sulfonic acid. , 10
parts of dibutyl ester of sebacic acid, and 130.16 parts of water.
得られた組成物の粘度は５０ｒｐｍおよびｐ Ｈ７゜７
において、ブルックフィールド粘度形により測定して、
２２０ｃｐであった。The resulting composition had a viscosity of 50 rpm and a pH of 7°7.
, measured by Brookfield viscosity type,
It was 220 cp.
例２
室温において、十分に攪拌して、下記の組成物を言回製
した。Example 2 The following composition was prepared at room temperature with thorough stirring.
８２部の例１の燐酸塩の混合物の５７％水溶液（４７％
活性成分を含む）、
５部のオクチル亜燐酸ナトリウム、
６．５部のベンズトリアゾール、
１、９部のトリルトリアゾール、および４．６部の水。82 parts of a 57% aqueous solution of the phosphate mixture of Example 1 (47%
5 parts sodium octyl phosphite, 6.5 parts benztriazole, 1, 9 parts tolyltriazole, and 4.6 parts water.
例３
未合金スチール３７の８０ｍｍＸ １５０ｍｍのシート
をペーパー仕上げおよび脱脂をし、次いで例１の組成物
を含む浴中に室温で浸漬した。１０秒後、シートを取り
出し、空気乾燥した０次に、処理したシートをドイツ工
業規格（Ｄ Ｉ Ｎ）試験方法５００１７に従う汗試験
およびＤＩＮ ５Ｓ５００２１に従う塩噴霧滴試験に
付した。Example 3 An 80 mm x 150 mm sheet of unalloyed Steel 37 was papered and degreased and then immersed in a bath containing the composition of Example 1 at room temperature. After 10 seconds, the sheets were removed and air dried.Then the treated sheets were subjected to the sweat test according to German Industrial Standard (DIN) test method 50017 and the salt spray drop test according to DIN 5S50021.
未処理スチールシートに比較して、例３に従って処理さ
れたシートは優れた腐食防止性を示した。Compared to the untreated steel sheet, the sheet treated according to Example 3 showed superior corrosion protection.
風雨に６力月間曝した後においても、例３に従って処理
されたシートは腐食を示さなかった。Even after six months of exposure to the elements, the sheet treated according to Example 3 showed no corrosion.
例４
例３におけると同じ未合金スチール３７のシートをペー
パー仕上げおよび脱脂し、次いで室温において例２に従
う組成物の浴中に浸漬した。また、例２の組成物をスチ
ールシート上にスプレーすることもできた。３０分間乾
燥後、同じ処理を繰り返した。工業的な環境で、４部５
ケ月問屋外暴露した後においても、これらのシートはま
ったく腐食を示さなかった。Example 4 A sheet of the same unalloyed steel 37 as in Example 3 was papered and degreased and then immersed in a bath of the composition according to Example 2 at room temperature. It was also possible to spray the composition of Example 2 onto a steel sheet. After drying for 30 minutes, the same process was repeated. In an industrial environment, part 4 5
Even after months of outdoor exposure, these sheets showed no corrosion.
シートをペーパー仕上げのみ行って、脱脂を行わず、ま
た例２に従う組成物を１回だけ通用した場合、６ケ月の
屋外暴露後、腐食に対する保護は、チューブの保存のた
めにはまだ十分であった。If the sheets were only paper-finished, without degreasing, and with only one pass of the composition according to Example 2, the protection against corrosion after 6 months of outdoor exposure was still sufficient for the preservation of the tubes. Ta.
Claims (1)
化学式、表等があります▼（ I ）ｂ）下記式IIで示さ
れる化合物 ▲数式、化学式、表等があります▼（II） 〔上式中、ＲはＣ＿１＿〜＿２＿２アルキル、Ｃ＿８＿
〜＿２＿２アルキル−Ｃ＿５＿〜＿６アリルまたは−Ｃ
Ｏ−Ｃ＿８＿〜＿２＿２アルキルまたは−ＣＯ−Ｃ＿８
＿〜＿２＿２アルケニルから選ばれ、Ｍはそれぞれ独立
に水素、アルカリ金属イオンまたはモル当量のアルカリ
土類金属を有し、Ｒ＿１はＭ（前記に規定したもの）ま
たは式ａ、Ｒ−（ＯＣ＿ｎＨ＿２＿ｎ−）＿ｘ−（ａ）
で示される基を表し、ｎはそれぞれ独立に２または３を
表し、ｘはそれぞれ独立に０または１〜１５の整数を表
し、Ｒ＿２はＲとは独立に前記Ｒに規定したものを表し
、ｍはそれぞれ独立に２または３を表し、ｙは０または
１〜１５の整数を表す〕を含む組成物（腐食抑制組成物
）。 ２、フィルム形成剤を含む、請求項１記載の組成物。 ３、ｐＨ調整剤、殺生物剤、界面活性剤、安息香酸のア
ルカリ金属塩、ベンズトリアゾール、トリルトリアゾー
ルおよび光安定剤から選ばれる１種またはそれ以上の他
の添加剤を含む、請求項１または２記載の組成物。 ４、ＲがＲ′即ちＣ＿６＿〜＿１＿０アルキルおよびＣ
＿８＿〜＿１＿０アルキルフェニルから選ばれる、請求
項１〜３のいずれかに記載の組成物。 ５、Ｒ＿２がＲ＿２′即ちＣ＿６＿〜＿１＿８アルキル
およびＣ＿８＿〜＿１＿０アルキルフェニルから選ばれ
る、請求項１〜４のいずれかに記載の組成物。 ６、Ｒ＿１がＲ＿１′即ち請求項１に規定したＭまたは
Ｃ＿１＿〜＿８アルキルである、請求項１〜５のいずれ
かに記載の組成物。 ７、アクリル樹脂と、 ａ）下記式 I で示される化合物、および ▲数式、化学式、表等があります▼（ I ） ｂ）下記式IIで示される化合物 ▲数式、化学式、表等があります▼（II） 〔上式中、ＲはＣ＿１＿〜＿２＿２アルキル、Ｃ＿８＿
〜＿２＿２アルキル−Ｃ＿５＿〜＿６アリルまたは−Ｃ
Ｏ−Ｃ＿８＿〜＿２＿２アルキルまたは−ＣＯ−Ｃ＿８
＿〜＿２＿２アルケニルから選ばれ、Ｍはそれぞれ独立
に水素、アルカリ金属イオンまたはモル当量のアルカリ
土類金属を表し、Ｒ＿１はＭ（前記に規定したもの）ま
たは式ａ、Ｒ−（ＯＣ＿ｎＨ＿２＿ｎ−）＿ｘ−（ａ）
で示される基を表し、ｎはそれぞれ独立に２または３を
表し、ｘはそれぞれ独立に０または１〜１５の整数を表
し、Ｒ＿２はＲとは独立に前記Ｒに規定したものを表し
、ｍはそれぞれ独立に２または３を表し、ｙは０または
１〜１５の整数を表す〕を含む腐食抑制組成物を含むポ
リマー組成物。 ８、ｐＨ調整剤、殺生物剤、界面活性剤、安息香酸のア
ルカリ金属塩、ベンズトリアゾール、トリルトリアゾー
ルおよび光安定剤から選ばれる１種またはそれ以上の他
の添加剤を含む、請求項７記載のポリマー組成物。 ９、ＲがＲ′即ちＣ＿６＿〜＿１＿８アルキルおよびＣ
＿８＿〜＿１＿８アルキルフェニルから選ばれる、請求
項７または８記載の組成物。 １０、Ｒ＿２がＲ＿２′即ちＣ＿６＿〜＿１＿８アルキ
ルおよびＣ＿８＿〜＿１＿８アルキルフェニルから選ば
れる、請求項７〜９のいずれかに記載の組成物。 １１、Ｒ＿１がＲ＿１′即ち請求項１に規定したＭまた
はＣ＿１＿〜＿８アルキルである、請求項７〜１０のい
ずれかに記載の組成物。 １２、材料に請求項１記載の組成物を通用することを含
む、腐食に対して材料を処理する方法。 １３、材料に請求項７記載の組成物を適用することを含
む、腐食に対して材料を処理する方法。[Scope of Claims] 1. a) A compound represented by the following formula I, and ▲Numerical formula,
There are chemical formulas, tables, etc. ▼ (I) b) Compounds represented by the following formula II ▲ There are numerical formulas, chemical formulas, tables, etc. ▼ (II) [In the above formula, R is C_1_ to_2_2 alkyl, C_8_
~_2_2 alkyl-C_5_-_6 allyl or -C
O-C_8_~_2_2 alkyl or -CO-C_8
selected from _~_2_2 alkenyl, each M independently having hydrogen, an alkali metal ion or a molar equivalent of an alkaline earth metal, and R_1 is M (as defined above) or formula a, R-(OC_nH_2_n-) ＿x-(a)
represents a group represented by, n each independently represents 2 or 3, x each independently represents 0 or an integer of 1 to 15, R_2 represents what is defined in the above R independently of R, m each independently represents 2 or 3, and y represents 0 or an integer from 1 to 15] (corrosion inhibiting composition). 2. The composition according to claim 1, comprising a film forming agent. 3. Containing one or more other additives selected from pH adjusters, biocides, surfactants, alkali metal salts of benzoic acid, benztriazole, tolyltriazole and light stabilizers, or 2. Composition according to item 2. 4, R is R', that is, C_6_-_1_0 alkyl and C
The composition according to any one of claims 1 to 3, selected from _8_ to _1_0 alkylphenyl. 5. A composition according to any of claims 1 to 4, wherein R_2 is selected from R_2', i.e. C_6_-_1_8 alkyl and C_8_-_1_0 alkylphenyl. 6. The composition according to any one of claims 1 to 5, wherein R_1 is R_1', ie M or C_1_-_8 alkyl as defined in claim 1. 7. Acrylic resin, a) A compound represented by the following formula I, and ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ ( I ) b) A compound represented by the following formula II ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ ( II) [In the above formula, R is C_1_ to_2_2 alkyl, C_8_
~_2_2 alkyl-C_5_-_6 allyl or -C
O-C_8_~_2_2 alkyl or -CO-C_8
selected from _~_2_2 alkenyl, each M independently representing hydrogen, an alkali metal ion or a molar equivalent of an alkaline earth metal, and R_1 is M (as defined above) or the formula a, R-(OC_nH_2_n-)_x -(a)
represents a group represented by, n each independently represents 2 or 3, x each independently represents 0 or an integer of 1 to 15, R_2 represents what is defined in the above R independently of R, m each independently represents 2 or 3, and y represents 0 or an integer from 1 to 15. 8. The composition further comprises one or more other additives selected from pH adjusters, biocides, surfactants, alkali metal salts of benzoic acid, benztriazole, tolyltriazole, and light stabilizers. polymer composition. 9, R is R', that is, C_6_-_1_8 alkyl and C
The composition according to claim 7 or 8, selected from _8_ to_1_8 alkylphenyl. 10. A composition according to any of claims 7 to 9, wherein R_2 is selected from R_2', i.e. C_6_-_1_8 alkyl and C_8_-_1_8 alkylphenyl. 11. The composition according to any of claims 7 to 10, wherein R_1 is R_1', ie M or C_1_-_8 alkyl as defined in claim 1. 12. A method of treating a material against corrosion, comprising applying the composition of claim 1 to the material. 13. A method of treating a material against corrosion, comprising applying the composition of claim 7 to the material.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3711805.6 | 1987-04-08 | ||
| DE3711805 | 1987-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63262484A true JPS63262484A (en) | 1988-10-28 |
Family
ID=6325110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63083211A Pending JPS63262484A (en) | 1987-04-08 | 1988-04-06 | Corrosion inhibitor |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS63262484A (en) |
| KR (1) | KR880012796A (en) |
| FR (1) | FR2614631A1 (en) |
| GB (1) | GB2203156A (en) |
| IT (1) | IT1219522B (en) |
| SE (1) | SE8801264L (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019085585A (en) * | 2013-03-16 | 2019-06-06 | ピーアールシー−デソト インターナショナル インコーポレーテッド | Azole compounds as corrosion inhibitors |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69936172T2 (en) | 1998-09-11 | 2008-01-31 | Rohm And Haas Co. | A process for corrosion inhibition in an aqueous aerosol or foam hair styling composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE631015A (en) * | 1962-01-28 | 1900-01-01 | ||
| US3133787A (en) * | 1962-09-04 | 1964-05-19 | Socony Mobil Oil Co Inc | Corrosion inhibition |
| GB1225011A (en) * | 1967-03-17 | 1971-03-17 | Ici Ltd | Phosphorus acid esters and their use in the stabilisation of polymers |
| EP0027699B1 (en) * | 1979-10-19 | 1984-03-21 | Imperial Chemical Industries Plc | Process for the production of anti-static thermoplastics films and the films thereby produced |
-
1988
- 1988-03-30 FR FR8804357A patent/FR2614631A1/en not_active Withdrawn
- 1988-04-05 IT IT47815/88A patent/IT1219522B/en active
- 1988-04-06 JP JP63083211A patent/JPS63262484A/en active Pending
- 1988-04-06 SE SE8801264A patent/SE8801264L/en not_active Application Discontinuation
- 1988-04-06 KR KR1019880003802A patent/KR880012796A/en not_active Application Discontinuation
- 1988-04-07 GB GB08808124A patent/GB2203156A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019085585A (en) * | 2013-03-16 | 2019-06-06 | ピーアールシー−デソト インターナショナル インコーポレーテッド | Azole compounds as corrosion inhibitors |
Also Published As
| Publication number | Publication date |
|---|---|
| SE8801264D0 (en) | 1988-04-06 |
| FR2614631A1 (en) | 1988-11-04 |
| SE8801264L (en) | 1988-10-09 |
| IT8847815A0 (en) | 1988-04-05 |
| KR880012796A (en) | 1988-11-29 |
| IT1219522B (en) | 1990-05-18 |
| GB8808124D0 (en) | 1988-05-11 |
| GB2203156A (en) | 1988-10-12 |
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