JPS63262456A - Production of metal vapor deposited film - Google Patents
Production of metal vapor deposited filmInfo
- Publication number
- JPS63262456A JPS63262456A JP9495387A JP9495387A JPS63262456A JP S63262456 A JPS63262456 A JP S63262456A JP 9495387 A JP9495387 A JP 9495387A JP 9495387 A JP9495387 A JP 9495387A JP S63262456 A JPS63262456 A JP S63262456A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- metal
- vapor deposited
- base film
- metal vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002184 metal Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000000203 mixture Substances 0.000 claims description 20
- 238000007740 vapor deposition Methods 0.000 claims description 8
- 239000002966 varnish Substances 0.000 claims description 3
- 238000000151 deposition Methods 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 48
- 239000010408 film Substances 0.000 description 20
- 239000012943 hotmelt Substances 0.000 description 11
- 239000002585 base Substances 0.000 description 7
- 239000002932 luster Substances 0.000 description 5
- 238000001883 metal evaporation Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 238000002844 melting Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000006732 Torreya nucifera Nutrition 0.000 description 1
- 244000111306 Torreya nucifera Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011104 metalized film Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、一般雑貨、広告関連分野、包装材料または転
写箔に利用する部分的に金属蒸着層を有する金属蒸着フ
ィルムの製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method for producing a metallized film having a partially metallized layer for use in general goods, advertising-related fields, packaging materials, or transfer foils.
〈従来技術〉
−aに、部分的の金属蒸着層を設ける方法としては、基
材フィルムに絵柄層を設けた後、金属蒸着層を不要とす
る部分に、水溶性樹脂層を塗布形成し、次に金属蒸着層
を全面に形成する。そして、水洗処理により、水溶性樹
脂層を溶解、除去して、部分的な金属蒸着層を有するフ
ィルムを得る方法がある。<Prior art> As a method for providing a partial metal vapor deposited layer in -a, after providing a pattern layer on the base film, a water-soluble resin layer is applied and formed on the portion where the metal vapor deposited layer is not required. Next, a metal vapor deposition layer is formed over the entire surface. Then, there is a method of dissolving and removing the water-soluble resin layer by washing with water to obtain a film having a partial metal-deposited layer.
また、予め全面に金属蒸着層を設けたフィルムの金属蒸
着層上に、金属蒸着層を必要とする部分に絵柄層や透明
ニスからなるレジスト層を形成後、酸やアルカリの処理
剤で、不要部分を除去して形成する方法があった。In addition, after forming a resist layer consisting of a pattern layer or transparent varnish on the parts that require a metal evaporation layer on the metal evaporation layer of a film that has previously been provided with a metal evaporation layer on the entire surface, an acid or alkali treatment agent is used to remove the unnecessary metal evaporation layer. There was a method of forming it by removing parts.
〈発明の目的〉
前記従来の方法によれば、水洗処理や酸、アルカリ処理
により、不要な金属蒸着層を除去する工程が不可欠であ
った。<Object of the Invention> According to the conventional method, a step of removing unnecessary metal vapor deposited layers by water washing treatment or acid or alkali treatment is essential.
このように処理工程の増加により、工程管理の確立の困
難さや、作業自体の複雑化のため、作業能率や製品収率
の低下をもたらしていた。そのうえ、工′程の増加によ
る価格の上昇をもたらしていた。This increase in the number of processing steps has led to a decline in work efficiency and product yield due to the difficulty of establishing process control and the complexity of the work itself. Moreover, the increase in the number of steps has led to an increase in price.
本発明の目的は、従来のように金属蒸着層の除去工程を
増すことなく、部分的に金属蒸着層を設けた金属蒸着フ
ィルムの製造方法を提供することにある。An object of the present invention is to provide a method for producing a metal-deposited film partially provided with a metal-deposited layer without increasing the number of steps for removing the metal-deposited layer as in the conventional method.
〈発明の概要〉
耐熱性を有する基材フィルムの表面に、熱溶融組成物層
を部分的に形成した後、熱溶融組成物を含む全面に金属
蒸着を施す金属蒸着フィルムの製造方法である。<Summary of the Invention> This is a method for producing a metal vapor deposited film, in which a heat melt composition layer is partially formed on the surface of a heat resistant base film, and then metal vapor deposition is performed on the entire surface containing the heat melt composition.
〈発明の詳述〉
第1図(a) (b)は、本発明の製造方法の工程を示
す説明図で、第1図(a)に示すように耐熱性を有する
基材フィルムlの表面に、熱溶融組成物層2を部分的に
形成する。<Detailed Description of the Invention> FIGS. 1(a) and 1(b) are explanatory views showing the steps of the manufacturing method of the present invention. As shown in FIG. 1(a), the surface of the heat-resistant base film l Then, the hot melt composition layer 2 is partially formed.
次に、同図(b)に示すように、熱溶融組成物層2を含
む全面に金属蒸着を施し、熱溶融組成物層2を除く部分
に金属蒸着層3を設け、光沢部4を部分的に形成する金
属蒸着フィルムの製造方法である。Next, as shown in FIG. 2B, metal vapor deposition is applied to the entire surface including the hot melt composition layer 2, a metal vapor deposition layer 3 is provided on the part excluding the hot melt composition layer 2, and the glossy part 4 is partially removed. This is a method for producing a metal-deposited film.
ここで、第2図(a)[有])に示すように、基材フィ
ルムlは、耐熱性を有する透明ニス、透明、或いは不透
明着色インキによる絵柄層5を設けてもよい。Here, as shown in FIG. 2(a), the base film 1 may be provided with a pattern layer 5 made of heat-resistant transparent varnish, transparent, or opaque colored ink.
ここで、基材フィルム1は、耐熱性が良好で真空蒸着中
で放出ガスが少ないポリエステルフィルムが好適である
が、その他の耐熱性を有するプラスチックフィルムの蒸
着面にアンダーコート層を設ければよい。Here, the base film 1 is preferably a polyester film that has good heat resistance and releases less gas during vacuum deposition, but an undercoat layer may be provided on the deposition surface of other heat-resistant plastic films. .
また、熱溶融組成物層2は、融点が低く、真空中で放出
ガスの多い熱溶融性組成物層で具体的にはカルナバワッ
クス、ライスワックス、モンタンワックス、キャンプリ
ワックス、パラフィンワックス等の天然、或いは合成ワ
ックス類、または熱溶融性の低分子量樹脂または、前記
ワックス類、低分子量樹脂を主成分とした組成物からな
る。The hot-melt composition layer 2 is a hot-melt composition layer that has a low melting point and releases a lot of gas in vacuum. , or synthetic waxes, heat-melting low molecular weight resins, or compositions containing the waxes and low molecular weight resins as main components.
〈作用〉
融点が低く、放出ガスが多い熱溶融組成物からなる熱溶
融組成物層を部分的に形成した面に、金属蒸着を施すの
で、熱溶融組成物層部分に蒸着はされるが、蒸着膜は、
形成せず、透明、或いは、半透明状態となり、金属光沢
は得られず、その他の部分は、金属光沢状態となる。<Function> Metal vapor deposition is performed on the surface on which a hot melt composition layer made of a hot melt composition having a low melting point and a large amount of released gas is partially formed. The vapor deposited film is
It is not formed and becomes transparent or translucent, and no metallic luster is obtained, and other parts become metallic luster.
〈実施例1〉
厚さ25ミクロンのポリエステルフィルムからなる基材
フィルムに耐熱性を有する橙色の透明インキにて所望の
絵柄及び文字からなる絵柄層を形成し、次に、以下の処
方の組成のもので
ライスワックス 10部カルナバワッ
クス 10部エチレンビニルアルコール
[u 2部橙色の透明インキ以外の部分に熱溶融
組成物層を形成する。しかる後に全面に金属蒸着を施し
たところ、橙色の透明インキからなる絵柄層部分のみ金
属光沢を有する金属蒸着層が形成され、それ以外の部分
は蒸着はされるが膜を形成せず半透明の層となった。こ
れをフィルムの裏面から見たところ、橙色の透明インキ
の部分のみ金属蒸着層の影響により全光沢の美麗な絵柄
及び文字を得た。<Example 1> A pattern layer consisting of a desired pattern and characters was formed using heat-resistant orange transparent ink on a base film made of a polyester film with a thickness of 25 microns, and then a pattern layer consisting of a desired pattern and characters was formed using the following composition. 10 parts of rice wax 10 parts of carnauba wax 2 parts of ethylene vinyl alcohol [u] Form a layer of hot melt composition on the area other than the orange transparent ink. When metal vapor deposition was then applied to the entire surface, a metal vapor deposited layer with metallic luster was formed only in the pattern layer made of orange transparent ink, and the other areas were vapor deposited but did not form a film and were semitransparent. It became a layer. When this was viewed from the back side of the film, only the orange transparent ink area was affected by the metal vapor deposited layer, resulting in beautiful patterns and letters with full gloss.
〈実施例2〉
厚さ25ミクロンのポリエステルフィルムる基材フィル
ムに先ず剥離層を設け、つぎに耐熱性を有するインキに
て絵柄及び文字からなる絵柄層を形成した後で、以下の
処方の組成のもので所望の絵柄及び文字からなる熱溶融
組成物層を形成する。<Example 2> First, a release layer was provided on a 25 micron thick polyester base film, and then a pattern layer consisting of a pattern and letters was formed using heat-resistant ink, and then a composition of the following formulation was applied. A hot-melt composition layer consisting of desired patterns and characters is formed using the following materials.
カルナバワックス 10部
ポリビニルブチラール 2部
しかる後に全面蒸着を施したところ熱溶融組成物層以外
の部分は金属光沢を有する金属蒸着層が形成され、上記
熱溶融組成物層の部分は、蒸着はされるが膜を形成せず
半透明の層となった。Carnauba wax 10 parts Polyvinyl butyral 2 parts Then, when the entire surface was vapor-deposited, a metal vapor-deposited layer with metallic luster was formed on the part other than the hot-melt composition layer, and the part of the heat-melt composition layer was not vapor-deposited. However, it did not form a film and became a translucent layer.
次に接着層を全面に塗布してホットスタンプ用転写フィ
ルムを作成した.このフィルムを用いてポリスチレン成
形品に転写を行ったところ、部分的に金属光沢を有する
転写品を得た。Next, an adhesive layer was applied to the entire surface to create a transfer film for hot stamping. When this film was used to transfer to a polystyrene molded product, a transferred product partially having metallic luster was obtained.
く効果〉
本発明は、金属蒸着時において、金属蒸着層と未蒸着層
部分が形成されるので、不要な金属蒸着層を除去する工
程が不要となった。Effects> In the present invention, since a metal vapor deposited layer and an undeposited layer portion are formed during metal vapor deposition, the step of removing unnecessary metal vapor deposited layers is no longer necessary.
また、金属蒸着層の除去工程が不要となったので、工程
の減少による価格の低減、および作業能率と製品収率の
低下が軽減された。In addition, since the step of removing the metal vapor deposited layer is no longer necessary, the cost is reduced due to the reduction in the number of steps, and the decrease in work efficiency and product yield is alleviated.
さらに、得られた金属蒸着フィルムに、他のプラスチッ
クをラミネート加工を施し包装材料として、また剥MN
、及び接着層を設ければ転写箔として用いることができ
る。Furthermore, the obtained metal-deposited film can be laminated with other plastics to be used as a packaging material or as a peelable MN.
, and an adhesive layer, it can be used as a transfer foil.
第1図(a)[有])および第2図(a) (b)は、
それぞれ本発明の製造方法の工程を示す説明図である。
1・・・・基材フィルム 2・・・・熱溶融組成物層
3・・・・金属蒸着層 4・・・・光沢部5・・・
・絵柄層
特 許 出 願 人
凸版印刷株式会社
代表者 鈴木和夫
第1記(Q)
茅20(b)Figure 1 (a) [with]) and Figure 2 (a) (b) are
FIG. 3 is an explanatory diagram showing the steps of the manufacturing method of the present invention, respectively. 1...Base film 2...Hot melt composition layer 3...Metal deposited layer 4...Glossy part 5...
・Picture layer patent application Representative: Toppan Printing Co., Ltd. Kazuo Suzuki No. 1 (Q) Kaya 20 (b)
Claims (2)
成物層を部分的に形成した後、前記熱溶融組成物層を含
む全面に、金属蒸着を施す金属蒸着フィルムの製造方法(1) A method for producing a metal vapor deposited film, in which a heat melt composition layer is partially formed on the surface of a heat resistant base film, and then metal vapor deposition is performed on the entire surface including the heat melt composition layer.
ンキにより絵柄層を有する特許請求の範囲第1項記載の
金属蒸着フィルムの製造方法。(2) The method for producing a metal-deposited film according to claim 1, wherein the base film has a pattern layer formed of heat-resistant varnish or ink.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62094953A JPH0772335B2 (en) | 1987-04-17 | 1987-04-17 | Method for manufacturing metal vapor deposition film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62094953A JPH0772335B2 (en) | 1987-04-17 | 1987-04-17 | Method for manufacturing metal vapor deposition film |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63262456A true JPS63262456A (en) | 1988-10-28 |
JPH0772335B2 JPH0772335B2 (en) | 1995-08-02 |
Family
ID=14124304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62094953A Expired - Lifetime JPH0772335B2 (en) | 1987-04-17 | 1987-04-17 | Method for manufacturing metal vapor deposition film |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0772335B2 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59210951A (en) * | 1983-05-16 | 1984-11-29 | Kakogawa Plast Kk | Method for preventing long strip film from being broken |
-
1987
- 1987-04-17 JP JP62094953A patent/JPH0772335B2/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59210951A (en) * | 1983-05-16 | 1984-11-29 | Kakogawa Plast Kk | Method for preventing long strip film from being broken |
Also Published As
Publication number | Publication date |
---|---|
JPH0772335B2 (en) | 1995-08-02 |
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