JPH058112B2 - - Google Patents
Info
- Publication number
- JPH058112B2 JPH058112B2 JP60192714A JP19271485A JPH058112B2 JP H058112 B2 JPH058112 B2 JP H058112B2 JP 60192714 A JP60192714 A JP 60192714A JP 19271485 A JP19271485 A JP 19271485A JP H058112 B2 JPH058112 B2 JP H058112B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- colored
- metal vapor
- colored ink
- transfer material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010410 layer Substances 0.000 claims description 104
- 239000000463 material Substances 0.000 claims description 40
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 29
- 238000007650 screen-printing Methods 0.000 claims description 19
- 230000000694 effects Effects 0.000 claims description 17
- 238000005530 etching Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 239000012790 adhesive layer Substances 0.000 claims description 9
- 238000007740 vapor deposition Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000007639 printing Methods 0.000 claims description 6
- 239000011347 resin Substances 0.000 description 13
- 229920005989 resin Polymers 0.000 description 13
- 239000002585 base Substances 0.000 description 10
- 229920000178 Acrylic resin Polymers 0.000 description 8
- 239000004925 Acrylic resin Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000005406 washing Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 238000007603 infrared drying Methods 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 229920006284 nylon film Polymers 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/12—Transfer pictures or the like, e.g. decalcomanias
Landscapes
- Printing Methods (AREA)
- Duplication Or Marking (AREA)
- Decoration By Transfer Pictures (AREA)
Description
【発明の詳細な説明】
＜産業上の利用分野＞
本発明は、立体感を有し任意の色に着色された
部分メタリツク転写材及びその製造方法に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a partial metallic transfer material that has a three-dimensional effect and is colored in an arbitrary color, and a method for producing the same.
本発明に係る立体感を有し任意の色に着色され
た部分メタリツク転写材は、特に化粧品容器、家
電製品、自動用品等におけるプラスチツク素材、
金属素材、ガラス素材等に関して転写絵付するの
に好適なものである。 The partial metallic transfer material according to the present invention, which has a three-dimensional effect and is colored in any color, can be used particularly for plastic materials used in cosmetic containers, home appliances, automatic products, etc.
It is suitable for applying transfer pictures to metal materials, glass materials, etc.
＜従来の技術＞
従来、着色部分メタリツク転写材としては、金
属蒸着層の不要な部分を水洗除去して得た転写材
がある。これを詳述すれば、フイルム基材の片面
に該フイルム基材より剥離容易な透明剥離層を設
けた上へ任意の図柄に着色インキ層および水溶性
塗膜層を部分的に設け、次に全面に金属蒸着層を
施した後、水洗により水溶性塗膜を溶解除去して
該水溶性塗膜層上の金属蒸着層をも除去し、次に
全面に感熱接着剤層を設けてなる任意の図柄に金
属蒸着膜を設けた転写材（実公昭53−211124号公
報参照）である。<Prior Art> Conventionally, as a colored portion metallic transfer material, there is a transfer material obtained by removing unnecessary portions of a metal vapor deposited layer by washing with water. To explain this in detail, a transparent peeling layer that is easier to peel than the film base material is provided on one side of the film base material, a colored ink layer and a water-soluble coating layer are partially provided on the desired pattern, and then After applying a metal vapor deposited layer to the entire surface, the water-soluble coating film is dissolved and removed by washing with water to remove the metal vapor deposited layer on the water-soluble coating layer, and then a heat-sensitive adhesive layer is provided to the entire surface. This is a transfer material (see Utility Model Publication No. 53-211124) in which a metal vapor-deposited film is provided on the pattern.
この転写材は一回の加熱転写によつて、着色部
分、金属蒸着部分、金属蒸着層によつて裏打ちさ
れた着色部分および透明部分が適宜組み合わされ
た図柄を被転写物上へ現出することができるもの
であり、極めて優れたものである。 With this transfer material, a pattern in which a colored part, a metal-deposited part, a colored part backed by a metal-deposited layer, and a transparent part are appropriately combined appears on the transferred object by one heat transfer. It is extremely excellent.
＜発明が解決しようとする問題点＞
しかし、前記従来の転写材には、次のような問
題点があつた。<Problems to be Solved by the Invention> However, the conventional transfer material has the following problems.
すなわち
(1) 前記各部分は同一面上に現出されるので、金
属蒸着部分のみに立体感を求めることはできな
い。 That is, (1) since each of the above parts appears on the same surface, it is not possible to obtain a three-dimensional effect only in the metal-deposited part.
(2) 金属蒸着後の水洗工程が必須であり、残存さ
せる金属蒸着層が腐食する恐れがある。(2) A washing process with water after metal vapor deposition is essential, and there is a risk that the remaining metal vapor deposited layer will corrode.
(3) 非蒸着部分において、水溶性インキの洗い落
ち不良が発生しやすく、それに伴い転写後の耐
水性・耐アルカリ性等の諸物性において不安定
であるという問題があつた。(3) In the non-evaporated areas, the water-soluble ink tends to wash off poorly, and as a result, various physical properties such as water resistance and alkali resistance after transfer are unstable.
＜問題点を解決するための手段＞
本発明は、上記問題点を解消した立体感を有す
る着色部分メタリツク転写材及びその製造方法を
提供することにある。<Means for Solving the Problems> The object of the present invention is to provide a colored partial metallic transfer material having a three-dimensional effect that solves the above-mentioned problems, and a method for manufacturing the same.
すなわち本発明に係る立体感を有する着色部分
メタリツク転写材は、剥離性を有するフイルム基
材１上に着色インキ層１５が部分的に形成され、
その上に透明な前アンカー層２が形成され、その
上にエツチングレジスト性を有するインキを用い
てパターン状に形成されたスクリーン印刷層４で
上面が覆われた金属蒸着層３が少なくとも前記着
色インキ層１５を下方に有する位置に部分的に形
成され、その上に着色インキ層５および接着剤層
６が順次形成されたことを特徴とするものであ
る。 That is, in the colored partial metallic transfer material having a three-dimensional effect according to the present invention, a colored ink layer 15 is partially formed on a film base material 1 having releasability,
A transparent front anchor layer 2 is formed thereon, and a metal vapor deposited layer 3 whose upper surface is covered with a screen printing layer 4 formed in a pattern using an ink having etching resist properties is coated with at least the colored ink. It is characterized in that it is partially formed at a position with layer 15 below, and colored ink layer 5 and adhesive layer 6 are sequentially formed thereon.
また本発明にかかる立体感を有する部分メタリ
ツク転写材の製造方法は、剥離性を有するフイル
ム基材１上に部分的な着色インキ層１５、透明な
前アンカー層２、金属蒸着層３を順次形成し、エ
ツチングレジスト性を有するインキを用いて前記
金属蒸着層３上にパターン状のスクリーン印刷層
４を少なくとも前記着色インキ層１５を下方に有
する位置に形成し、次いでエツチングによつて前
記印刷層４で覆われていない部分の金属蒸着層３
を除去し、しかるのち着色インキ層５、接着剤層
６を順次形成することを特徴とするものである。 Further, the method for manufacturing a partial metallic transfer material having a three-dimensional effect according to the present invention includes sequentially forming a partial colored ink layer 15, a transparent front anchor layer 2, and a metal vapor deposition layer 3 on a film base material 1 having peelability. Then, a patterned screen printing layer 4 is formed on the metal vapor deposited layer 3 at least at a position below the colored ink layer 15 using an ink having etching resist properties, and then the printed layer 4 is formed by etching. Metal vapor deposited layer 3 on the part not covered with
is removed, and then a colored ink layer 5 and an adhesive layer 6 are sequentially formed.
次に、本発明にかかる立体感を有する着色部分
メタリツク転写材及びその製造方法の詳細を説明
する。 Next, details of the colored partial metallic transfer material having a three-dimensional effect and the manufacturing method thereof according to the present invention will be explained.
本発明において使用するフイルム基材１として
は、ポリエステルフイルム・ポリエチレンフイル
ム・ポリプロピレンフイルム・ナイロンフイル
ム・アセテートフイルム・アクリルフイルム等の
単体フイルム又は複合フイルムを挙げることがで
きる。本発明においては後述するようにエツチン
グ処理を施すので、このフイルム基材１を始め後
述する透明剥離層７、前アンカー層２、着色イン
キ層１５を構成する樹脂は、耐エツチング性のあ
るものを選択使用しなければならならない。 Examples of the film base material 1 used in the present invention include single films or composite films such as polyester film, polyethylene film, polypropylene film, nylon film, acetate film, and acrylic film. In the present invention, an etching process is performed as described later, so the resins constituting the film base material 1, the transparent release layer 7, the front anchor layer 2, and the colored ink layer 15, which will be described later, should have etching resistance. Must be used selectively.
前記フイルム基材１の剥離性が乏しいときに
は、その上面に透明剥離層７を形成すればよい。
この透明剥離層７は、転写材を転写した後は保護
層として機能するものであり、故に耐熱性・硬
度・透明性等が要求される。透明剥離層７を構成
する樹脂としては、アクリル樹脂・ビニル系樹
脂・メラミン系樹脂等を挙げることができる。さ
らに必要に応じてワツクス等の被膜強化剤を配合
してもよい。この透明剥離層７は、通常、印刷法
あるいはコーテイング法により膜厚0.5〜3μｍに
形成する。 When the film base material 1 has poor peelability, a transparent peeling layer 7 may be formed on its upper surface.
This transparent peeling layer 7 functions as a protective layer after the transfer material is transferred, and is therefore required to have heat resistance, hardness, transparency, etc. Examples of the resin constituting the transparent peeling layer 7 include acrylic resin, vinyl resin, and melamine resin. Furthermore, a film strengthening agent such as wax may be added if necessary. This transparent peeling layer 7 is usually formed to a thickness of 0.5 to 3 μm by a printing method or a coating method.
前記フイルム基材上に着色インキ層１５を部分
的に形成する。着色インキ層１５は、オフセツ
ト・グラビア・スクリーン印刷等の通常の印刷手
段を用いて部分的に形成する。バインダーとして
は特に限定されることはないが、被転写物が金属
素材・ガラス素材の場合には熱硬化性樹脂を用い
るのが好ましい。なぜなら、転写後に焼付処理を
行なうことにより強度強化を図ることができるか
らである。 A colored ink layer 15 is partially formed on the film base material. The colored ink layer 15 is partially formed using ordinary printing means such as offset, gravure, and screen printing. Although the binder is not particularly limited, it is preferable to use a thermosetting resin when the object to be transferred is a metal or glass material. This is because the strength can be strengthened by performing a baking process after transfer.
前アンカー層２は、後述する金属蒸着層３を形
成するに先立ち、前記フイルム基材１または透明
剥離層７および着色インキ層１５の上面に形成す
る。この前アンカー層２は、金属蒸着性を向上さ
せ、蒸着の曇りや転写時発生する蒸着ヤケを防止
するために設けるものである。この前アンカー層
２を構成する樹脂としては、ウレタン系樹脂・ア
クリル系樹脂・ビニル系樹脂・繊維系樹脂等を挙
げることができる。この前アンカー層２は、通
常、印刷法あるいはコーテイング法により膜厚
0.5〜3μｍに形成する。なお前記透明剥離層７を
設けない場合は、この前アンカー層２が転写後に
は保護層として機能することになる。 The front anchor layer 2 is formed on the upper surface of the film base material 1 or the transparent peeling layer 7 and the colored ink layer 15 before forming the metal vapor deposited layer 3 described later. The pre-anchor layer 2 is provided to improve metal deposition properties and to prevent clouding of deposition and deposition fading that occurs during transfer. Examples of the resin constituting the front anchor layer 2 include urethane resin, acrylic resin, vinyl resin, fiber resin, and the like. This pre-anchor layer 2 is usually formed by a printing method or a coating method.
Form to a thickness of 0.5 to 3 μm. Note that if the transparent peeling layer 7 is not provided, the pre-anchor layer 2 will function as a protective layer after transfer.
次いで、前記前アンカー層２の上面に金属蒸着
層３を形成する。この金属蒸着層３の形成方法は
常法に従つて行えばよい。即ち、銅・アルミニウ
ム・真鍮等の金属を真空蒸着法によつて設けると
よい。なお前記真空蒸着法の代わりにイオンプレ
ーテイング法・スパツタリング法等も適用するこ
とができることは当然である。 Next, a metal deposition layer 3 is formed on the top surface of the front anchor layer 2. This metal vapor deposition layer 3 may be formed according to a conventional method. That is, it is preferable to provide metal such as copper, aluminum, brass, etc. by vacuum evaporation. Incidentally, it is a matter of course that an ion plating method, a sputtering method, etc. can be applied instead of the vacuum evaporation method.
前記金属蒸着層３の上面に、エツチングレジス
ト性を有するインキを用いてパターン状のスクリ
ーン印刷層４を形成する。この際、スクリーン印
刷層４は、前記着色インキ層１５を下方に有する
位置に形成する。これは任意の色に着色された部
分メタリツク感を現出するためである。スクリー
ン印刷層４と着色インキ層１５との位置関係は、
要求される意匠に応じて適宜設計するとよいが、
例えばスクリーン印刷層４と着色インキ層１５と
を完全に位置を一致させて形成した場合は着色金
属蒸着層が得られ、一部一致させて形成した場合
は金属蒸着層と着色金属蒸着層とが得られる。こ
のスクリーン印刷層４は、エツチング処理後に残
存する金属蒸着層３をいわゆる底上げする作用を
する。従つて、スクリーン印刷層４の膜厚が厚い
程、立体感も大きくなる。このスクリーン層４を
構成するエツチングレジスト性を有するインキと
しては、アクリル系樹脂・ビニル系樹脂・ウレタ
ン系樹脂等を上げることができる。この場合、金
属蒸着層３との密着性のよいものを選択する必要
がある。前記スクリーン印刷層４の乾燥方法は、
熱風乾燥方式でも遠赤外線乾燥方式でも紫外線乾
燥方式でもよいが、紫外線乾燥方式による場合の
方が製品の立体効果があがるので好ましい。 A patterned screen printing layer 4 is formed on the upper surface of the metal vapor deposited layer 3 using an ink having etching resist properties. At this time, the screen printing layer 4 is formed at a position below which the colored ink layer 15 is located. This is to create a partially metallic feel colored in an arbitrary color. The positional relationship between the screen printing layer 4 and the colored ink layer 15 is as follows:
It is advisable to design as appropriate according to the required design.
For example, if the screen printing layer 4 and the colored ink layer 15 are formed in completely aligned positions, a colored metal vapor deposited layer will be obtained, and if they are formed in partially aligned positions, the metal vapor deposited layer and the colored metal vapor deposited layer will be obtained. can get. This screen printing layer 4 functions to raise the level of the metal vapor deposited layer 3 remaining after the etching process. Therefore, the thicker the screen printing layer 4, the greater the three-dimensional effect. As the ink having etching resist properties constituting the screen layer 4, acrylic resin, vinyl resin, urethane resin, etc. can be used. In this case, it is necessary to select a material that has good adhesion to the metal vapor deposition layer 3. The drying method of the screen printing layer 4 is as follows:
Although a hot air drying method, a far infrared drying method, or an ultraviolet drying method may be used, it is preferable to use an ultraviolet drying method because it improves the three-dimensional effect of the product.
つぎはエツチング工程である。エツチングは常
法に従つて行えばよい。例えば、金属蒸着層３が
アルミニウム層であれば、５％水酸化ナトリウム
溶液等のアルカリ溶液を用いて、前記の工程まで
経たシート（第２図参照）をエツチング処理す
る。このようにすることにより、前記スクリーン
印刷層４がエツチングレジスト層として作用し、
スクリーン印刷層４で覆われていない部分はエツ
チングされ、スクリーン印刷層４で覆われた部分
はそのまま残存することになる（第３図参照）。
金属蒸着層３が銅層や真鍮層の場合は、酸系のエ
ツチング液を用いればよい。 Next is the etching process. Etching may be performed according to a conventional method. For example, if the metal vapor deposited layer 3 is an aluminum layer, the sheet (see FIG. 2) that has gone through the above steps is etched using an alkaline solution such as a 5% sodium hydroxide solution. By doing so, the screen printing layer 4 acts as an etching resist layer,
The portions not covered by the screen printing layer 4 will be etched, and the portions covered by the screen printing layer 4 will remain as they are (see FIG. 3).
If the metal vapor deposition layer 3 is a copper layer or a brass layer, an acid-based etching solution may be used.
着色インキ層５は、前記着色インキ層１５と同
様な方法で全面または部分的に形成する。使用す
るバインダーは前記着色インキ層１５と同じもの
を用いるとよい。 The colored ink layer 5 is formed entirely or partially in the same manner as the colored ink layer 15. The binder used is preferably the same as that used for the colored ink layer 15.
接着剤層６を構成する樹脂としては、被転写物
がプラスチツク素材の場合、スチロール樹脂・ア
クリル樹脂・ABS樹脂・AS樹脂等が望ましい。
また転写素材が金属素材の場合、物性強度を考慮
してアクリル系樹脂・メラミン系樹脂・エポキシ
系樹脂等の熱硬化型樹脂を使用するのが望まし
い。この接着剤層６は、通常、印刷法あるいはコ
ーテイング法により膜厚0.5〜3μｍの範囲で全面
に形成する。 As the resin constituting the adhesive layer 6, when the object to be transferred is a plastic material, styrene resin, acrylic resin, ABS resin, AS resin, etc. are preferable.
Further, when the transfer material is a metal material, it is desirable to use a thermosetting resin such as acrylic resin, melamine resin, or epoxy resin in consideration of physical strength. This adhesive layer 6 is usually formed over the entire surface by a printing method or a coating method to have a thickness in the range of 0.5 to 3 μm.
上記構成をとることによつて、本発明に係る立
体感を有する着色部分メタリツク転写材（第１図
参照）を得ることができる。この転写材を被転写
物上に転写すると、第４図に示すように金属蒸着
層の存在する部分のみが突出した状態となる。 By adopting the above configuration, it is possible to obtain a colored partial metallic transfer material (see FIG. 1) having a three-dimensional effect according to the present invention. When this transfer material is transferred onto an object to be transferred, only the portion where the metal vapor deposited layer is present will be in a protruding state as shown in FIG.
＜実施例＞
ポリエステルフイルム上に熱可塑性アクリル樹
脂からなる膜厚2μｍの剥離層を印刷法により形
成し、その上に任意の着色インキにて「日写」の
パターンからなる着色インキ層を形成し、その上
にウレタン樹脂からなる膜厚2μｍの前アンカー
層を形成し、次いでこれを熱処理してアルミニウ
ムの真空蒸着を行つた。次に、スクリーン印刷機
を用いて、アクリル樹脂からなるエツチングレジ
スト性を有するインキで前記着色インキ層のパタ
ーンと一致させて「日写」のパターンからなるス
クリーン印刷層を形成し、その後60℃５％
NaOH水溶液により、アルミニウムの露出した
部分をエツチングした。次に、任意の着色インキ
を刷り重ね、最後にアクリル樹脂からなる接着剤
層を印刷した。これを乾燥することにより立体感
を有する着色部分メタリツク転写材を得た。<Example> A release layer with a thickness of 2 μm made of thermoplastic acrylic resin was formed on a polyester film by a printing method, and a colored ink layer consisting of a "Nippon" pattern was formed on top of it using any colored ink. A pre-anchor layer made of urethane resin with a thickness of 2 μm was formed thereon, and then this was heat-treated and aluminum was vacuum-deposited. Next, using a screen printing machine, a screen printing layer consisting of a "Nichisha" pattern was formed using an ink made of acrylic resin having etching resist properties to match the pattern of the colored ink layer, and then 60°C. %
The exposed portions of aluminum were etched using a NaOH aqueous solution. Next, optionally colored ink was overprinted, and finally an adhesive layer made of acrylic resin was printed. By drying this, a colored partial metallic transfer material having a three-dimensional effect was obtained.
これをスチロール樹脂に熱ロールにて転写した
ところ、任意の色に着色されたメタリツク感を呈
する部分のみが盛り上がつていた。この盛り上が
り部分を段差計で調べたところ9μｍであつた。 When this was transferred to styrene resin using a heated roll, only the parts colored in an arbitrary color and exhibiting a metallic appearance were raised. When this raised part was examined with a step meter, it was found to be 9 μm.
＜発明の効果＞
本発明は、以上の構成よりなるから次の効果を
得ることができる。<Effects of the Invention> Since the present invention has the above configuration, the following effects can be obtained.
即ち、
(1) 転写後の状態でみた場合、残存した金属蒸着
層はスクリーン印刷層によつていわゆる底上げ
された状態となるので、立体感のある着色部分
メタリツクを現出することができる。 That is, (1) When viewed in the state after transfer, the remaining metal vapor deposited layer is raised by the screen printing layer, so that a colored metallic part with a three-dimensional effect can be produced.
(2) 水洗工程を経ないので、前記従来法における
水洗に伴う諸問題も生じない。(2) Since there is no water washing step, there are no problems associated with water washing in the conventional method.
第１図は本発明に係る立体感を有する着色部分
メタリツク転写材の層構成の模式断面図、第２図
および第３図は第１図の転写材の製造過程におけ
る層構成の模式断面図、第４図は第１図の転写材
を被転写物に転写した後の状態の模式断面図を示
す。なお着色インキ層５，１５および非転写物８
以外のハツチングは省略した。
図中、１……フイルム基材、２……前アンカー
層、３……金属蒸着層、４……スクリーン印刷
層、５，１５……着色インキ層、６……接着剤
層、７……透明剥離層、８……非転写物。
FIG. 1 is a schematic sectional view of the layer structure of a colored partial metallic transfer material having a three-dimensional effect according to the present invention, FIGS. 2 and 3 are schematic sectional views of the layer structure in the manufacturing process of the transfer material of FIG. 1, FIG. 4 shows a schematic cross-sectional view of the state after the transfer material shown in FIG. 1 has been transferred to an object to be transferred. Note that the colored ink layers 5 and 15 and the non-transfer material 8
Other hatchings have been omitted. In the figure, 1... Film base material, 2... Front anchor layer, 3... Metal vapor deposition layer, 4... Screen printing layer, 5, 15... Colored ink layer, 6... Adhesive layer, 7... Transparent release layer, 8...non-transfer material.
Claims (1)
キ層１５が部分的に形成され、その上に透明な前
アンカー層２が形成され、その上にエツチングレ
ジスト性を有するインキを用いてパターン状に形
成されたスクリーン印刷層４で上面が覆われた金
属蒸着層３が少なくとも前記着色インキ層１５を
下方に有する位置に部分的に形成され、その上に
着色インキ層５および接着剤層６が順次形成され
たことを特徴とする立体感を有する着色部分メタ
リツク転写材。 ２ 剥離性を有するフイルム基材１上に部分的な
着色インキ層１５、透明な前アンカー層２、金属
蒸着層３を順次形成し、エツチングレジスト性を
有するインキを用いて前記金属蒸着層３上にパタ
ーン状のスクリーン印刷層４を少なくとも前記着
色インキ層１５を下方に有する位置に形成し、次
いでエツチングによつて前記印刷層４で覆われて
いない部分の金属蒸着層３を除去し、しかるのち
着色インキ層５、接着剤層６を順次形成すること
を特徴とする立体感を有する着色部分メタリツク
転写材の製造方法。[Claims] 1. A colored ink layer 15 is partially formed on a film base material 1 having peelability, a transparent front anchor layer 2 is formed thereon, and an ink layer having etching resist properties is formed on top of the colored ink layer 15. A metal vapor deposited layer 3 whose upper surface is covered with a screen printing layer 4 formed in a pattern using A colored partial metallic transfer material having a three-dimensional effect, characterized in that adhesive layers 6 are sequentially formed. 2. A partial colored ink layer 15, a transparent front anchor layer 2, and a metal vapor deposition layer 3 are sequentially formed on a film base material 1 having removability, and an ink having etching resist properties is used to form a layer on the metal vapor deposition layer 3. A patterned screen printing layer 4 is formed at least in a position having the colored ink layer 15 below, and then the portions of the metal vapor deposited layer 3 that are not covered with the printing layer 4 are removed by etching. A method for manufacturing a colored partial metallic transfer material having a three-dimensional effect, which comprises sequentially forming a colored ink layer 5 and an adhesive layer 6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60192714A JPS6251476A (en) | 1985-08-31 | 1985-08-31 | Colored partial metallic transfer material having three-dimensional feeling and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60192714A JPS6251476A (en) | 1985-08-31 | 1985-08-31 | Colored partial metallic transfer material having three-dimensional feeling and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6251476A JPS6251476A (en) | 1987-03-06 |
| JPH058112B2 true JPH058112B2 (en) | 1993-02-01 |
Family
ID=16295835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60192714A Granted JPS6251476A (en) | 1985-08-31 | 1985-08-31 | Colored partial metallic transfer material having three-dimensional feeling and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6251476A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63260484A (en) * | 1987-04-17 | 1988-10-27 | Nissha Printing Co Ltd | Partial dull-finished transfer material |
| JP2586205B2 (en) * | 1990-11-07 | 1997-02-26 | 三菱電機株式会社 | Failure diagnosis device for exhaust gas recirculation control device |
| KR101448231B1 (en) * | 2014-03-14 | 2014-10-10 | (주)에스아이티 | High brightness logo of cellular phone case using vacuum evaporation and manufacturing method therof |
-
1985
- 1985-08-31 JP JP60192714A patent/JPS6251476A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6251476A (en) | 1987-03-06 |
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| LAPS | Cancellation because of no payment of annual fees |