JPS63238004A - Termite-controlling material - Google Patents
Termite-controlling materialInfo
- Publication number
- JPS63238004A JPS63238004A JP62071092A JP7109287A JPS63238004A JP S63238004 A JPS63238004 A JP S63238004A JP 62071092 A JP62071092 A JP 62071092A JP 7109287 A JP7109287 A JP 7109287A JP S63238004 A JPS63238004 A JP S63238004A
- Authority
- JP
- Japan
- Prior art keywords
- termite
- hydroxyquinoline
- average particle
- polyolefin
- metal complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims abstract description 10
- -1 8-hydroxyquinoline metal complex Chemical class 0.000 claims abstract description 10
- 229960003540 oxyquinoline Drugs 0.000 claims abstract description 10
- 229920000098 polyolefin Polymers 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 3
- 239000004698 Polyethylene Substances 0.000 claims abstract description 3
- 239000004743 Polypropylene Substances 0.000 claims abstract description 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 3
- 229920001748 polybutylene Polymers 0.000 claims abstract description 3
- 229920000573 polyethylene Polymers 0.000 claims abstract description 3
- 229920001155 polypropylene Polymers 0.000 claims abstract description 3
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 3
- 229910052718 tin Inorganic materials 0.000 claims abstract description 3
- 239000004711 α-olefin Substances 0.000 claims abstract description 3
- 229910052788 barium Inorganic materials 0.000 claims abstract 2
- 229910052749 magnesium Inorganic materials 0.000 claims abstract 2
- 239000002424 termiticide Substances 0.000 claims description 15
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 10
- 150000004696 coordination complex Chemical class 0.000 claims description 6
- 241000256602 Isoptera Species 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 230000002940 repellent Effects 0.000 claims 1
- 239000005871 repellent Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 11
- 230000008018 melting Effects 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract description 3
- 238000001125 extrusion Methods 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000001276 controlling effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 1
- 229950006824 dieldrin Drugs 0.000 description 1
- NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
［発明の技術分野］
本発明は８−ヒドロキシキノリンの金属錯体を有効成分
とする防蟻剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a termiticide containing a metal complex of 8-hydroxyquinoline as an active ingredient.
［発明の技術的背娯およびその問題点］本邦の風土は気
象条件が白蟻の成育に適する為、特に気候温和な地方に
於ては木材のみならず鉄、コンクリートを用いた構造物
すら白蟻類に食い荒され、又はそれらの分泌物によって
腐食１＠潰せられ、その被害１よ甚大なものがある。白
蟻類による被害の多くは戸外に於て発生する為、これら
の駆除に用いる薬剤は気象条件、例えば風雨、日光直射
および寒暑などに影響を受けないものが望ましい。[Technical background of the invention and its problems] Japan's climate is suitable for the growth of termites, so especially in regions with a mild climate, termites are attracted to structures made not only of wood but also of iron and concrete. There are things that are more serious than the damage caused by being eaten away by these creatures or crushed by their secretions. Since most of the damage caused by termites occurs outdoors, it is desirable that the chemicals used to exterminate them be unaffected by weather conditions, such as wind and rain, direct sunlight, and cold and heat.
従来この対策としてクロルデン、アルドリン、ディルド
リン等の有Ｒ塩素系薬剤が使用されてきたが、クロルデ
ンは蒸気圧が高い為、高温雰囲気中では揮散し長期的な
効果の持続性に劣っていた。Conventionally, R-chlorinated chemicals such as chlordane, aldrin, and dieldrin have been used as a countermeasure against this problem, but because chlordane has a high vapor pressure, it volatilizes in high-temperature atmospheres and has poor long-term sustainability.
一方、アルドリン等は生物分解性が小さく、公害問題か
らその使用が制限されてきている。On the other hand, aldrin and the like have low biodegradability, and their use has been restricted due to pollution problems.
そこで本願出願人らは、従来使用されていた防蟻剤の欠
点を改良した新規防蟻剤として、８−ヒドロキシキノリ
ン又はその誘導体を有効成分として含有する防蟻剤を先
に出願した（特公昭６〇−２３０８２号公報参照）。Therefore, the applicants of the present application previously filed an application for a termiticide containing 8-hydroxyquinoline or its derivatives as an active ingredient as a new termiticide that improves the drawbacks of conventionally used termiticides (Japanese Patent Publication No. (See Publication No. 60-23082).
しかしながら、このような防蟻剤を、例えばケーブルシ
ース材料のプラスチック等のポリマーに練り込んだ場合
には、相溶性が悪く、長期間にわたって少しずつ防蟻剤
が流出（ブリードアウト）して環境汚染の問題を引き起
こしたり、防蟻効果が低下する等のおそれがあった。However, when such termiticides are mixed into polymers such as plastic for cable sheath materials, they are not compatible and the termiticides gradually bleed out over a long period of time, causing environmental pollution. There was a risk that this would cause problems and that the anti-termite effect would be reduced.
また、防蟻剤とポリマーとの組合せによっては、ポリマ
ーの熱安定性が低下し、加工性が損われるという問題点
があった。Furthermore, depending on the combination of the termiticide and the polymer, there is a problem in that the thermal stability of the polymer decreases and processability is impaired.
［発明の目的］
本発明は以上の点に看目してなされたもので、各種ポリ
マーに防蟻剤を練り込む場合に、均一にポリマー中に分
散させることができ、かつ長期間にわたってもポリマー
からの流出を防止することができる防蟻剤を提供するこ
とを目的とする。[Objective of the Invention] The present invention has been made in view of the above points, and when kneading termiticides into various polymers, it can be uniformly dispersed in the polymer and can remain in the polymer for a long period of time. The purpose of the present invention is to provide a termiticide that can prevent the leakage of termiticides.
［発明の概要］
本発明は即ち、融点が１００℃以上のポリオレフィン中
に、８−ヒドロキシキノリンの金属錯体の少くとも１種
を０．０５重量％〜９０重量％含有してなり、かつ平均
粒径が５０μｍ以下であることを特徴とする防蟻剤であ
る。[Summary of the invention] That is, the present invention comprises a polyolefin having a melting point of 100° C. or higher, containing 0.05% to 90% by weight of at least one metal complex of 8-hydroxyquinoline, and having an average particle size of 0.05% to 90% by weight. This is a termiticide characterized by having a diameter of 50 μm or less.
本発明の８−ヒドロキシキノリンの金Ｒ６Ｍ体としては
、８−ヒドロキシキノリンとＳｎ、Ｓｒ。The gold R6M form of 8-hydroxyquinoline of the present invention includes 8-hydroxyquinoline, Sn, and Sr.
Ｃａ、Ｃｕ、ｌ”ｅ、ＭＯ，Ｂａ５Ｎａ、に、Ｍｎ。Ca, Cu, l"e, MO, Ba5Na, Mn.
Ｃ０１Ｎ ｉ、ｐｂ、Ｇａ等の金属との錯体が挙げられ
るが、この中でもＳｒ１、Ｂａ、５ｒＳＣａ。Examples include complexes with metals such as C01N i, pb, and Ga, among which Sr1, Ba, and 5rSCa.
Ｍｑ、Ｆｅとの金属錯体が防蟻効果が大きく好ましい。A metal complex with Mq and Fe is preferable because it has a great anti-termite effect.
本発明のポリオレフィンは、防蟻剤をポリマーに混合す
る場合にポリオレフィンが溶融して有効成分である８−
ヒドロキシキノリンの金属錆体のバインダーとしての役
割が損われるのを防ぐために、ポリエチレン、ポリプロ
ピレン、エチレン−α−オレフィン共重合体、ポリブテ
ン−１、ポリメチルペンテン−１等のように融点が１０
０℃以上のポリオレフィンが好ましい。In the polyolefin of the present invention, when the termiticide is mixed with the polymer, the polyolefin melts and the active ingredient 8-
In order to prevent the role of hydroxyquinoline as a binder for metal rust bodies to be impaired, it is necessary to use polyethylene, polypropylene, ethylene-α-olefin copolymers, polybutene-1, polymethylpentene-1, etc. with a melting point of 10.
Polyolefins having a temperature of 0° C. or higher are preferred.
８−ヒドロキシキノリンの金属錯体の配合量は、ポリオ
レフィン中に０．０５重ｆｆｉ％〜９０重壷％が好まし
く、０．０５重量％未満であると防蟻効果が不充分とな
り、９０重量％を越えると加工性が低下して、ポリマー
への練り込みが困難となる。The amount of the metal complex of 8-hydroxyquinoline in the polyolefin is preferably 0.05% by weight to 90% by weight, and if it is less than 0.05% by weight, the anti-termite effect will be insufficient, so 90% by weight is less than 0.05% by weight. If it exceeds this, the processability will decrease and it will be difficult to incorporate it into the polymer.
また、平均粒径が５０μｍを越えると、ポリマーに練り
込んだ場合に特性劣化を引き起こす場合があるので、平
均粒径が５０μｍ以下が好ましい。Furthermore, if the average particle size exceeds 50 μm, properties may deteriorate when kneaded into a polymer, so the average particle size is preferably 50 μm or less.
本発明の防蟻剤の使用法としては、プラスチック、ゴム
等への練り込みの他に、適当な分散剤とともに乳剤とし
て土壌処理に使用しても有効である。In addition to kneading into plastics, rubber, etc., the termiticide of the present invention can also be effectively used in soil treatment as an emulsion with a suitable dispersant.
［発明の実施例］ 本発明の実施例について詳細に説明する。[Embodiments of the invention] Examples of the present invention will be described in detail.
第１表に示す通り、８−ヒドロキシキノリンの各種金属
塩をポリオレフィンに混練した後、−１９０℃の低温で
微粉砕し平均粒径２０ｕｍの防蟻パウダーを作成した。As shown in Table 1, various metal salts of 8-hydroxyquinoline were kneaded with polyolefin, and then finely pulverized at a low temperature of -190°C to prepare an anti-termite powder with an average particle size of 20 um.
これを可塑剤、安定剤等とともにプラスチックまたはゴ
ムに混練しベレット化した。このペレットを押出機によ
りシートに成型して各種特性を測定した。また、作成し
た１重厚、１０ｃＪｌ角のシートを白蟻とともに３０日
間、３０℃ ９０％ＲＨの容器中に入れ、シートの食害
状況を観察して防蟻特性を測定した。This was kneaded into plastic or rubber together with a plasticizer, stabilizer, etc. to form a pellet. The pellets were molded into a sheet using an extruder and various properties were measured. In addition, the prepared 1-thick, 10 cJl square sheet was placed in a container at 30° C. and 90% RH for 30 days with termites, and the damage to the sheet was observed to measure termite-proofing properties.
以下余白
［発明の効果］
以上説明した本発明の防蟻剤は、良好な防蟻特性を有す
るとともに、押出加工性が良好であり、かつポリマーと
の相溶性が良く、ブリードアウトがほとんどない等の利
点を有する。Margin below [Effects of the Invention] The termiticide of the present invention described above has good termitproof properties, good extrusion processability, good compatibility with polymers, almost no bleed-out, etc. It has the following advantages.
Claims (3)
ヒドロキシキノリンの金属錯体の少くとも１種を０．０
５重量％〜９０重量％含有してなり、かつ平均粒径が５
０μｍ以下であることを特徴とする防蟻剤。(1) 8-
0.0 of at least one metal complex of hydroxyquinoline
5% to 90% by weight, and has an average particle size of 5% by weight.
An anticide characterized by having a particle size of 0 μm or less.
ロキシキノリンと、Ｓｎ、Ｂａ、Ｓｒ、Ｃａ、Ｍｇ、Ｆ
ｅから選ばれた何れか１種の金属との錯体である特許請
求の範囲第１項記載の防蟻剤。(2) A metal complex of 8-hydroxyquinoline and Sn, Ba, Sr, Ca, Mg, F
The termiticide according to claim 1, which is a complex with any one metal selected from e.
ン、エチレン−α−オレフィン共重合体、ポリブテン−
１、ポリメチルペンテン−１である特許請求の範囲第１
項記載の防蟻剤。(3) The polyolefin is polyethylene, polypropylene, ethylene-α-olefin copolymer, polybutene-
1. Claim 1 which is polymethylpentene-1
Termite repellent as described in section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62071092A JPS63238004A (en) | 1987-03-25 | 1987-03-25 | Termite-controlling material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62071092A JPS63238004A (en) | 1987-03-25 | 1987-03-25 | Termite-controlling material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63238004A true JPS63238004A (en) | 1988-10-04 |
Family
ID=13450548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62071092A Pending JPS63238004A (en) | 1987-03-25 | 1987-03-25 | Termite-controlling material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63238004A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE1006290A4 (en) * | 1992-10-02 | 1994-07-12 | Vandeplassche Jean Pierre | Method for repelling insects, including ants, more specifically wood antsand the composition used for this purpose |
| WO2007079535A1 (en) * | 2006-01-12 | 2007-07-19 | Fmc Australasia Pty Ltd | Granules for providing a barrier |
| CN105237475A (en) * | 2015-11-23 | 2016-01-13 | 南昌航空大学 | Green synthesizing method for 8-hydroxyquinoline strontium |
| WO2020001352A1 (en) * | 2018-06-29 | 2020-01-02 | 嘉兴市世诚贸易有限公司 | Use of calcium quinoline for preventing a plant disease and a composition of calcium quinoline |
-
1987
- 1987-03-25 JP JP62071092A patent/JPS63238004A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE1006290A4 (en) * | 1992-10-02 | 1994-07-12 | Vandeplassche Jean Pierre | Method for repelling insects, including ants, more specifically wood antsand the composition used for this purpose |
| WO2007079535A1 (en) * | 2006-01-12 | 2007-07-19 | Fmc Australasia Pty Ltd | Granules for providing a barrier |
| AU2007204594B2 (en) * | 2006-01-12 | 2012-06-14 | Fmc Australasia Pty Ltd | Granules for providing a barrier |
| CN105237475A (en) * | 2015-11-23 | 2016-01-13 | 南昌航空大学 | Green synthesizing method for 8-hydroxyquinoline strontium |
| WO2020001352A1 (en) * | 2018-06-29 | 2020-01-02 | 嘉兴市世诚贸易有限公司 | Use of calcium quinoline for preventing a plant disease and a composition of calcium quinoline |
| CN110651791A (en) * | 2018-06-29 | 2020-01-07 | 嘉兴市世诚贸易有限公司 | Application of calcium quinolate in preventing and treating plant diseases and composition thereof |
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