JPS63233884A - Thermal transfer recording material - Google Patents
Thermal transfer recording materialInfo
- Publication number
- JPS63233884A JPS63233884A JP62068538A JP6853887A JPS63233884A JP S63233884 A JPS63233884 A JP S63233884A JP 62068538 A JP62068538 A JP 62068538A JP 6853887 A JP6853887 A JP 6853887A JP S63233884 A JPS63233884 A JP S63233884A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- vapor
- recording material
- thermal transfer
- metallic luster
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 15
- 239000010410 layer Substances 0.000 claims abstract description 38
- 239000002932 luster Substances 0.000 claims abstract description 10
- 239000012790 adhesive layer Substances 0.000 claims abstract description 9
- 238000007740 vapor deposition Methods 0.000 claims abstract description 7
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 6
- 229920005992 thermoplastic resin Polymers 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 239000000470 constituent Substances 0.000 abstract description 4
- 229910052737 gold Inorganic materials 0.000 abstract description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000010931 gold Substances 0.000 abstract description 3
- 229920006267 polyester film Polymers 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- -1 pho-I77'lopyrene Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920006015 heat resistant resin Polymers 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、サーマルヘッド等の発熱記録部材？用い℃転
写方式により文字や１慮の記録が可能な感熱転写リボン
、感熱転写シート等の感熱転写記録体に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a heat-generating recording member such as a thermal head. The present invention relates to heat-sensitive transfer recording materials such as heat-sensitive transfer ribbons and heat-sensitive transfer sheets that are capable of recording characters and other images using the ℃ transfer method.
周知１）如＜、＋−マルヘッドやサーマルペン等の発熱
記録部材を用いた感熱転写記録方式は、記録装置が比較
的低１格であること、印字時の騒音が少ないこと、記録
ｉ ｉｔの保守が容易なことなどの利点により教多く用
いられている。Common knowledge 1) The thermal transfer recording method using a heat-generating recording member such as a +-maru head or a thermal pen has the following advantages: the recording device is relatively low-grade, there is little noise during printing, and it is easy to record. It is widely used due to its advantages such as easy maintenance.
ところで、この方式は、日本語ワープロ等のプリンター
に採用され、招待状、案内状、手紙等への印字によく使
われている。招待状や案内状等には、金１、限の文字な
使うことが多く、上記した数多くの利点？持つ感熱転写
記録方式を採用したプリンターにて金、銀光沢感のある
文字を表現できる熱転写記録体の開発が強（望まれてい
る。By the way, this method is adopted in printers such as Japanese word processors and is often used for printing on invitations, information cards, letters, etc. Invitations, information cards, etc. often use characters such as ``Kin1'' and ``Gin'', which have many of the advantages mentioned above. There is a strong desire to develop a thermal transfer recording medium that can express characters with a glossy appearance of gold or silver using a printer that uses a thermal transfer recording method.
本発明は、以上のような事情に鑑み成されたもので、支
持体の一方の面に、蒸庸了ン′カ一層、金属光沢？有す
る蒸着Ｉ−並びに接着層が少なくとも順設されていると
共に、接層・−は軟化点が５０〜２００℃の範囲にある
ポリ了ミド樹脂を主体とする層であること馨特徴とする
熱転写記録体である。The present invention was made in view of the above-mentioned circumstances, and has a metallic luster on one side of the support. A thermal transfer recording characterized in that at least a vapor deposited I- and an adhesive layer are sequentially provided, and the adhesive layer is a layer mainly composed of a polyamide resin having a softening point in the range of 50 to 200°C. It is the body.
ここで、支持体としては、厚さが３〜６μｍ程度ノポリ
エステルフィルム、ポリイミドフィルム、ポリサル７オ
ンフイルム等の耐熱性のプラスチックフィルム、あるい
はコンデンサーペーパー等の薄紙が用いられる。Here, as the support, a heat-resistant plastic film such as a polyester film, a polyimide film, or a polysal 7 film having a thickness of about 3 to 6 μm, or a thin paper such as a condenser paper is used.
一方、蒸青アンカー（４はその上に形成する＃；庸１−
が主として均一かつ確実に＃；着・形成できるように設
げるもので、塩化ゴム、塩素化ポリオレフィン、Ｌｉｍ
化ホＩ７７’ロピレン、ニトロセルロース樹脂、ポリエ
ステル樹脂、ポリウレタン樹脂等の耐熱性樹脂を主成分
として成るものである。この鴫の４さは０．３〜３．０
μｍ程度である。On the other hand, the vaporized blue anchor (4 is # formed on it; 庸1-
It is provided so that #; can be deposited and formed mainly uniformly and reliably. Chlorinated rubber, chlorinated polyolefin,
The main component is a heat-resistant resin such as pho-I77'lopyrene, nitrocellulose resin, polyester resin, or polyurethane resin. The 4 of this crow is 0.3~3.0
It is about μm.
従来の熱転写記録体には、感熱転写、ｄの剥離・転写ヰ
？考！差して剥離１−ケ設ける場合がある。本発明にお
いては、前述した蒸着アンカー層にこの剥離性がある場
合、この剥離−は特に設ける必要はない。蒸着アンカー
１だげでは所期の剥離性が得られない場合には、この蒸
着アンカー層と支持体）一方の面の間に、剥離層？形成
しておけば良い。剥離；−はｔＡ！ｌ１点もしくは軟化
点が５０〜２００℃のカルナウバワックス、ライスワッ
クス、キャンデリラワックス、モンタンワツクス、パラ
フィンワックス、あるいは熱可塑性の樹脂組成物？主体
とする層で、その厚さは０．５〜３，０μｍ程度である
。Conventional thermal transfer recording materials include thermal transfer, d peeling and transfer. Think! In some cases, one piece of peeling is provided. In the present invention, if the vapor-deposited anchor layer described above has this releasability, it is not necessary to provide this releasability. If the desired releasability cannot be obtained with the vapor-deposited anchor 1 alone, add a release layer between this vapor-deposited anchor layer and one side of the support. Just form it. Peeling; - is tA! Carnauba wax, rice wax, candelilla wax, montan wax, paraffin wax, or thermoplastic resin composition with a l1 point or softening point of 50 to 200°C? The main layer has a thickness of about 0.5 to 3.0 μm.
上記した蒸着アンカー・―や剥ｄ層中には顔料、染料等
の色材乞含有させてもよい。Coloring materials such as pigments and dyes may be contained in the above-mentioned vapor-deposited anchor and peeling layer.
また、金＠光沢？有する蒸着１−は被転写体側に転移し
て、転写画１象に金属尤沢乞付与するための層であり、
金、銀、銅、アルミニウム、クロム等の金属？蒸着アン
カー層上に蒸着して？４）られる。Also, gold @ gloss? The vapor deposition 1- is a layer for transferring to the transferred object side and imparting metal richness to the transferred image 1,
Metals such as gold, silver, copper, aluminum, chromium, etc.? Deposited on top of the deposited anchor layer? 4) It will be done.
その厚みは９０〜８００八程度である。Its thickness is about 90 to 800 mm.
一方、最上１−に設ける接着層は、軟化点が５０〜２０
０℃の範囲にあるポリアミド樹脂？主体とする１−であ
る。層の構成物質？このように特定するのは、この層に
前記蒸着１−との密着性と印字性？共に確保させるため
であり、その厚さは０．６〜３．０μｍ程度である。こ
の接層４ Ｙワックス乞主体とする１−とすると、接着
層のみが転移し、蒸着層が基材側に残ってしまい、所期
の印字ができなくなる。接層・傷中への、メルク、・炭
酸カルシウム、硫酸カルシウム、硫酸バリウム、ケイ酸
カルシウム等の微粉末やその他の充填剤の含有は、１０
重滑部以Ｆの割合であれば支１章はない。On the other hand, the adhesive layer provided on the top layer 1- has a softening point of 50 to 20
Polyamide resin in the 0℃ range? The main character is 1-. What is the constituent material of the layer? What is specified in this way is the adhesion and printability of this layer with the vapor deposition 1-? The thickness thereof is approximately 0.6 to 3.0 μm. If the contact layer 4 is 1-, in which Y wax is the main component, only the adhesive layer will be transferred and the vapor deposited layer will remain on the base material side, making it impossible to print as expected. The inclusion of fine powders such as Merck, calcium carbonate, calcium sulfate, barium sulfate, calcium silicate, etc. and other fillers in the contact layer/wound is 10
If the ratio is F for the heavy sliding part, there is no branch chapter 1.
本発明の熱転写記録体は接ｆｌｄ’ａ’構成する組成物
の軟叱点馨５０〜２００℃の範囲とするポリアミド樹脂
？主体とし、剥離１−と蒸着アンカー１−と？介して形
成されている金属光沢を有する蒸着層上に股げであるた
め１ｇ着層と接着性の向上並びに印字性（転移性）の保
持を共に確保することが可能となり、金属光沢に優れる
印字物が（４）られるようになる。The thermal transfer recording material of the present invention is made of a polyamide resin whose softening temperature of the constituent composition is in the range of 50 to 200°C. Main body, peeling 1- and vapor deposition anchor 1-? Since it is spread over the vapor deposited layer with metallic luster formed through the 1g adhesion layer, it is possible to improve adhesion with the 1g adhesion layer and maintain printability (transferability), resulting in printing with excellent metallic luster. You will be able to do things (4).
以下１本発明の実楕例につき第１図？参照にして説明す
る。Figure 1 below is an actual elliptical example of the present invention. This will be explained for reference.
基材（２）とじて厚さ３．５μｍのポリエステル延伸フ
ィルム？用い、その片面に丁記第１表に示す組成物によ
り剥Ｍ１層＋３１、府色アンカー層（４）、蒸着層（５
）、接層曖；６）馨順役し、本発明の熱転写記録体（１
）を作成した０各１１の・−厚はそれぞれ第２表に示す
。Base material (2) Stretched polyester film with a thickness of 3.5 μm? The composition shown in Table 1 was used to coat one side of the peeled M1 layer +31, the Fuiro anchor layer (4), and the vapor deposited layer (5
), contact layer ambiguity; 6) Kaoru Junyaku, thermal transfer recording material of the present invention (1
) are shown in Table 2.
次にこの熱転写記録体ｍ ｒｇ ６ ｄｏｔ ／情のラ
インサーマルヘッド？有するサーマルプリンターに装填
して印字したところ、金属光沢感に優れる転写１浦な得
ることができた。Next is this thermal transfer recording medium m rg 6 dot / love line thermal head? When it was loaded into a thermal printer and printed, it was possible to obtain a perfect transfer with excellent metallic luster.
第１表 第２表Table 1 Table 2
第１図は本発明の一実施例に係る概略構成説明図である
。
＋１１・・・熱転写記録体 （２）・・・基材１３）
・・・剥離層 （４）・・・蒸石アンカー層（
５） ・・、ｉ ンごコ［ム（シ；
（６）・・・ 接デン１１八シラ持許出願人
凸版印刷株式会社
代表者 鈴 木 和 夫
第１図FIG. 1 is a schematic structural explanatory diagram according to an embodiment of the present invention. +11... Thermal transfer recording material (2)... Base material 13)
... Peeling layer (4) ... Steamstone anchor layer (
5) ..., i ngoko [mu(shi;
(6)... Applicant with 118 shillings of registration Kazuo Suzuki Representative of Toppan Printing Co., Ltd. Figure 1
Claims (2)
を有する蒸着層並びに接着層がこの順序で少なくとも順
設されていると共に、接着層は軟化点が５０〜２００℃
の範囲にあるポリアミド樹脂を主体とする層であること
を特徴とする熱転写記録体。(1) At least a vapor deposition anchor layer, a vapor deposition layer with metallic luster, and an adhesive layer are provided in this order on one side of the support, and the adhesive layer has a softening point of 50 to 200°C.
1. A thermal transfer recording material characterized by having a layer mainly composed of a polyamide resin in the range of .
は融点もしくは軟化点が５０〜２００℃のワックスもし
くは熱可塑性樹脂を主体とする剥離層が形成されている
ことを特徴とする特許請求の範囲第１項記載の熱転写記
録体。(2) A release layer mainly made of wax or thermoplastic resin having a melting point or softening point of 50 to 200° C. is formed between one surface of the support and the vapor-deposited anchor layer. A thermal transfer recording medium according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62068538A JP2774970B2 (en) | 1987-03-23 | 1987-03-23 | Thermal transfer recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62068538A JP2774970B2 (en) | 1987-03-23 | 1987-03-23 | Thermal transfer recording medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63233884A true JPS63233884A (en) | 1988-09-29 |
| JP2774970B2 JP2774970B2 (en) | 1998-07-09 |
Family
ID=13376618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62068538A Expired - Lifetime JP2774970B2 (en) | 1987-03-23 | 1987-03-23 | Thermal transfer recording medium |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2774970B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0812701A1 (en) * | 1996-06-10 | 1997-12-17 | Dai Nippon Printing Co., Ltd. | Thermal transfer sheet for printing images with metallic luster |
| JP2001191624A (en) * | 2000-01-14 | 2001-07-17 | Dainippon Printing Co Ltd | Thermal transfer sheet |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49138903U (en) * | 1973-03-30 | 1974-11-29 | ||
| JPS55121092A (en) * | 1979-03-13 | 1980-09-17 | Toyo Metaraijingu Kk | Transcription sheet having pattern |
| JPS55169449U (en) * | 1979-05-23 | 1980-12-05 | ||
| JPS5655282A (en) * | 1979-10-11 | 1981-05-15 | Toyo Ink Mfg Co Ltd | Thermal transfer sheet |
| JPS56167490A (en) * | 1980-05-28 | 1981-12-23 | Toppan Printing Co Ltd | Heat transfer copy sheet |
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS58208088A (en) * | 1982-05-28 | 1983-12-03 | Oike Kogyo Kk | Transfer foil for hot stamping |
| JPS6064897A (en) * | 1983-09-20 | 1985-04-13 | Fujitsu Ltd | Manufacture of thermal transfer recording ink sheet |
| JPS61116592A (en) * | 1984-11-13 | 1986-06-04 | Carbon Paper Kk | Thermal transfer type recording medium |
| JPS61189994A (en) * | 1985-02-20 | 1986-08-23 | Hitachi Ltd | Thermal transfer paper |
| JPS61273989A (en) * | 1985-05-30 | 1986-12-04 | Toppan Printing Co Ltd | Thermal transfer sheet |
| JPS6237190A (en) * | 1985-08-12 | 1987-02-18 | General Kk | Thermal transfer recording medium |
-
1987
- 1987-03-23 JP JP62068538A patent/JP2774970B2/en not_active Expired - Lifetime
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49138903U (en) * | 1973-03-30 | 1974-11-29 | ||
| JPS55121092A (en) * | 1979-03-13 | 1980-09-17 | Toyo Metaraijingu Kk | Transcription sheet having pattern |
| JPS55169449U (en) * | 1979-05-23 | 1980-12-05 | ||
| JPS5655282A (en) * | 1979-10-11 | 1981-05-15 | Toyo Ink Mfg Co Ltd | Thermal transfer sheet |
| JPS56167490A (en) * | 1980-05-28 | 1981-12-23 | Toppan Printing Co Ltd | Heat transfer copy sheet |
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS58208088A (en) * | 1982-05-28 | 1983-12-03 | Oike Kogyo Kk | Transfer foil for hot stamping |
| JPS6064897A (en) * | 1983-09-20 | 1985-04-13 | Fujitsu Ltd | Manufacture of thermal transfer recording ink sheet |
| JPS61116592A (en) * | 1984-11-13 | 1986-06-04 | Carbon Paper Kk | Thermal transfer type recording medium |
| JPS61189994A (en) * | 1985-02-20 | 1986-08-23 | Hitachi Ltd | Thermal transfer paper |
| JPS61273989A (en) * | 1985-05-30 | 1986-12-04 | Toppan Printing Co Ltd | Thermal transfer sheet |
| JPS6237190A (en) * | 1985-08-12 | 1987-02-18 | General Kk | Thermal transfer recording medium |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0812701A1 (en) * | 1996-06-10 | 1997-12-17 | Dai Nippon Printing Co., Ltd. | Thermal transfer sheet for printing images with metallic luster |
| JP2001191624A (en) * | 2000-01-14 | 2001-07-17 | Dainippon Printing Co Ltd | Thermal transfer sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2774970B2 (en) | 1998-07-09 |
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