JPS63216941A - High-toughness cermet for cutting tool - Google Patents
High-toughness cermet for cutting toolInfo
- Publication number
- JPS63216941A JPS63216941A JP5049187A JP5049187A JPS63216941A JP S63216941 A JPS63216941 A JP S63216941A JP 5049187 A JP5049187 A JP 5049187A JP 5049187 A JP5049187 A JP 5049187A JP S63216941 A JPS63216941 A JP S63216941A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- cermet
- toughness
- cutting
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011195 cermet Substances 0.000 title claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 7
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract 6
- 239000002131 composite material Substances 0.000 claims description 15
- 229910052715 tantalum Inorganic materials 0.000 claims description 12
- 239000012535 impurity Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 abstract description 22
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 6
- 238000005245 sintering Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 2
- 239000011162 core material Substances 0.000 abstract 3
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 13
- 229910000831 Steel Inorganic materials 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 229910003178 Mo2C Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 241000257465 Echinoidea Species 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Landscapes
- Cutting Tools, Boring Holders, And Turrets (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、すぐれた靭性な有し、かつ耐摩耗性にもす
ぐれ、鋼の連続切削は勿論のこと、特に断続切削に切削
工具として用いた場合にすぐれた切削性能を発揮するサ
ーメットに関するものである。[Detailed Description of the Invention] [Field of Industrial Application] This invention has excellent toughness and wear resistance, and can be used as a cutting tool not only for continuous cutting of steel, but especially for interrupted cutting. This relates to a cermet that exhibits excellent cutting performance when
従来、切削工具用サーメットとして、容量チで(以下チ
は容量チを示す)、
Tiと%TaおよびNbのうちの1種または2種(以下
、Ta/Nbで示す)と、WおよびMoのうちの1種ま
たは2af(以下、W/Moで示す)の複合金属炭窒化
物〔以下、(Ti、 Ta/Nb、 W/Mo) CN
で示す〕からなる硬質分散相:80〜95%、
を含有し、残りが結合相形成成分としてのN】およびc
oのうちの1flfまたは2種(以下、Ni/Coで示
す)と不可避不純物からなる組成、並びに上記複合金属
炭窒化物が芯部とリング部からなる2重構造組織を有す
るサーメットが提案されている。Conventionally, cermets for cutting tools have been made of capacitance chi (hereinafter referred to as capacitance Chi), Ti, one or two of %Ta and Nb (hereinafter referred to as Ta/Nb), W and Mo. Composite metal carbonitride of one type or 2af (hereinafter referred to as W/Mo) [hereinafter referred to as (Ti, Ta/Nb, W/Mo) CN
A hard dispersed phase consisting of: 80 to 95%, the remainder being N as a binder phase forming component and c
A cermet has been proposed that has a composition consisting of one flf or two (hereinafter referred to as Ni/Co) of o (hereinafter referred to as Ni/Co) and unavoidable impurities, and a double structure in which the composite metal carbonitride has a core and a ring. There is.
しかし、上記の従来サーメットは、すぐれた耐摩耗性を
もつものの、これを例えば鋼の断続切削に用いた場合に
は、靭性不足が原因で切刃に欠損が発生し易く、実用に
供することができないのが現状である。However, although the above-mentioned conventional cermets have excellent wear resistance, when they are used, for example, for interrupted cutting of steel, the cutting edge tends to break due to lack of toughness, making it difficult to put them into practical use. The current situation is that this is not possible.
そこで、本発明者等は、上記の従来サーメットに着目し
、これのもつすぐれた耐摩耗性を損なうことなく、これ
にすぐれた靭性を付与すべく研究を行なった結果、
(a) サーメットの硬質分散相は、上記の従来サー
メットの場合、原料粉末として、TiCN粉末、TiN
粉末、TaC粉末、NbC粉末、WC粉末、Mo2C粉
末、 Ni粉末、およびCOC粉末使用しているので、
焼結時にNi/Coの液相中に、 TiCNの一部、
並びにTiN%TaC%NbC,WC,およびMo2C
が溶解し、これらが冷却過程で、未溶解のTiCN粒の
胸囲にそれもTiCN 、 TiN、つぎにWCおよび
Mo2 C、最後にTaCおよびNbCの順で析出する
ことによって形成されるものでアシ、シたがって上記従
来サーメットにおける硬質分散相の2重構造組織は、芯
部がTiCNで構成され、リング部が((Ti 、 T
a、/Nb。Therefore, the present inventors focused on the above-mentioned conventional cermet, and conducted research to add excellent toughness to it without impairing its excellent wear resistance. As a result, (a) hardness of cermet In the case of the above-mentioned conventional cermet, the dispersed phase is TiCN powder, TiN
Since we use powder, TaC powder, NbC powder, WC powder, Mo2C powder, Ni powder, and COC powder,
During sintering, a part of TiCN is added to the liquid phase of Ni/Co.
and TiN%TaC%NbC, WC, and Mo2C
is dissolved, and during the cooling process, TiCN, TiN, then WC and Mo2C, and finally TaC and NbC are precipitated on the chest circumference of the undissolved TiCN grains. Therefore, in the double structure structure of the hard dispersed phase in the conventional cermet, the core part is made of TiCN and the ring part is made of ((Ti, T
a, /Nb.
W/Mo ) CNで構成されること。W/Mo) Must be composed of CN.
(b) このような2重構造組織の硬質分散相で構成
された従来サーメットが靭性に劣るのは、2重構造を構
成する芯部に原因があること。(b) The reason why conventional cermets composed of such a hard dispersed phase with a double structure structure is inferior in toughness is due to the core portion that constitutes the double structure.
(C) 原料粉末として、従来サーメットの製造に用
いられていたTiCN粉末、 TiN粉末、 TaC粉
末、およびNi)C粉末に代って%Tiと、Ta/Nb
の炭窒化物〔以下、(Ti、 Ta/Nb ) CNで
示す〕粉末を用いると、製造されたサーメットには、芯
部が(Ti゜Ta/ Nb ) CNで構成され、リン
グ部が((Ti 、 Ta/Nb。(C) As raw material powders, %Ti and Ta/Nb were used instead of TiCN powder, TiN powder, TaC powder, and Ni)C powder, which were conventionally used in the production of cermets.
When carbonitride [hereinafter referred to as (Ti, Ta/Nb) CN] powder is used, the manufactured cermet has a core composed of (Ti゜Ta/Nb)CN and a ring part composed of (((Ti゜Ta/Nb)CN) powder. Ti, Ta/Nb.
W/Mo ) CH)で構成された2重構造組織の硬質
分散相が形成されるようになり、この結果のサーメット
は、著しくすぐれた靭性な有し、かつ耐摩耗性にもすぐ
れていること。A hard dispersed phase with a dual structure composed of W/Mo) CH) is formed, and the resulting cermet has extremely high toughness and excellent wear resistance. .
以上(a)〜(C)に示される知見を得たのである。The findings shown in (a) to (C) above were obtained.
この発明は、上記知見にもとづいてなされたものであっ
て、
硬質分散相形成成分として、[(Ti、 Ta/Nb。This invention was made based on the above findings, and includes [(Ti, Ta/Nb.
W/Mo ) CNからなる複合金属炭窒化ウニ80〜
95%。W/Mo) Composite metal carbonitride sea urchin consisting of CN 80~
95%.
を含有し、残シが結合相形成成分としてのNi / C
。and the remainder is Ni/C as a binder phase forming component.
.
と不可避不純物からなる組成、並びに上記複合金属炭窒
化物が芯部とリング部の2重構造組織を有し、かつ、
上記芯部が、(Ti、 Ta/Nb) CNで構成され
、上記リング部が、 (Ti 、 Ta/ Nb、
W/ Mo ) CNで構成された、高靭性とすぐれた
耐摩耗性を有する切削工具用サーメットに特徴を有する
ものである。and unavoidable impurities, and the composite metal carbonitride has a double structure structure of a core part and a ring part, and the core part is composed of (Ti, Ta/Nb)CN, and the ring The part is (Ti, Ta/Nb,
This is a cermet for cutting tools that is composed of W/Mo) CN and has high toughness and excellent wear resistance.
なお、この発明のサーメットにおいて、複合金属炭窒化
物の含有量が80%未満では所望のすぐれた耐摩耗性を
確保することができず、一方その含有量が95%を越え
ると、相対的に結合相形成成分の含有量が少なくなシす
ぎ、硬質分散相組織の何如にかかわらず所望の高靭性を
確保することができないことから、複合金属炭窒化物の
含有量を80〜95%と定めた。In the cermet of the present invention, if the content of composite metal carbonitride is less than 80%, the desired excellent wear resistance cannot be ensured, while if the content exceeds 95%, the relatively Since the content of the binder phase-forming component is too low and the desired high toughness cannot be secured regardless of the hard dispersed phase structure, the content of the composite metal carbonitride is set at 80 to 95%. Ta.
つぎに、この発明のサーメットを実施例により具体的に
説明する。Next, the cermet of the present invention will be specifically explained using Examples.
原料粉末として、第1表に示される組成、並びにいずれ
も0.8〜1.5μmの範囲内の所定の平均粒径を有す
る各種の粉末を用意し、これら原料粉末をそれぞれ第1
表に示される配合組成に配合し、通常の条件で混合し、
圧粉体にプレス成形し、焼結することによって、硬質分
散相形成成分としての複合金属炭窒化物および結合相形
成成分としてのNi/Coの含有量は配合組成と実質的
に同じで、かつ芯部が(Ti、 Ta/Nb ) CN
で構成され、リング部が(Ti、 Ta/Nb、 W
/Mo) ONで構成された2重構造組織の複合金属炭
窒化物で硬質分散相が形成された本発明サーメット1〜
8と、硬質分散相を構成する複合金属炭窒化物の芯部が
TiCNで構成される以外は、上記本発明サーメット1
〜8にそれぞれ対応した状態で同じである比較サーメッ
ト1〜8をそれぞれ製造した。なお、サーメットにおけ
る複合金属炭窒化物の芯部とリング部は、X線回折およ
びEPMA (電子プローブマイクロアナライザ)によ
り観察した。Various powders having the composition shown in Table 1 and a predetermined average particle size within the range of 0.8 to 1.5 μm are prepared as raw material powders, and these raw material powders are
Mix according to the composition shown in the table and mix under normal conditions,
By press-forming into a compact and sintering, the content of composite metal carbonitride as a hard dispersed phase forming component and Ni/Co as a binder phase forming component is substantially the same as the blended composition, and The core is (Ti, Ta/Nb) CN
The ring part is (Ti, Ta/Nb, W
/Mo) Cermets 1 to 1 of the present invention in which a hard dispersed phase is formed of a composite metal carbonitride with a double structure composed of ON.
8, and the cermet of the present invention 1 except that the core of the composite metal carbonitride constituting the hard dispersed phase is composed of TiCN.
Comparative cermets 1 to 8, which were the same but corresponding to conditions corresponding to cermets 1 to 8, respectively, were produced. Note that the core and ring portions of the composite metal carbonitride in the cermet were observed by X-ray diffraction and EPMA (electron probe microanalyzer).
つぎに、この結果得られた各種のサーメットを切削工具
として用い、
被削材: SN0M439(硬さ:HB260)の丸棒
。Next, the various cermets obtained as a result were used as a cutting tool, and a workpiece material: a round bar of SN0M439 (hardness: HB260).
切削速度:160m/諷、 送り: 0.3 mx / rev、、切込み=2B。Cutting speed: 160m/mute, Feed: 0.3 mx / rev, depth of cut = 2B.
切削時間:3nia。Cutting time: 3nia.
の条件での鋼の連続切削試験、並びに、被削材: SN
CM 439(硬さ:HB280)の角材、切削速度:
l 40 m 7nia。Continuous cutting test of steel under the conditions of and work material: SN
CM 439 (hardness: HB280) square material, cutting speed:
l 40m 7nia.
送り: 0.26 rtux/ rev、、切込み=2
H1
切削時間:3狐、
の条件での鋼の断続切削試験を行ない、連続切削試験で
は切刃の逃げ面摩耗幅とすくい面摩耗深さを測定し、断
続切削試験では、試験切刃数二10個のうちの欠損発生
数を測定した。これらの測定結果を第1表に示した。Feed: 0.26 rtux/rev, depth of cut = 2
H1 Cutting time: 3 hours, An interrupted cutting test was conducted on steel under the following conditions. In the continuous cutting test, the flank wear width and rake face wear depth of the cutting edge were measured, and in the interrupted cutting test, the number of test cutting edges was 2. The number of defects among the 10 pieces was measured. The results of these measurements are shown in Table 1.
第1表に示される結果から、本発明サーメット1〜8は
、いずれも硬質分散相を構成する複合金属炭窒化物の芯
部がTiCNからなる比較サーメット1〜8と同等のす
ぐれた耐摩耗性を示し、かつこれより一段とすぐれた靭
性な示し、切刃における欠損の発生が著しく低いことが
明らかである。From the results shown in Table 1, cermets 1 to 8 of the present invention have excellent wear resistance equivalent to comparative cermets 1 to 8, in which the core of the composite metal carbonitride constituting the hard dispersed phase is made of TiCN. It is clear that the toughness is much better than this, and the occurrence of defects on the cutting edge is significantly lower.
上述のように、この発明のサーメットは、耐摩耗性にす
ぐれ、特にすぐれた靭性をもつので、これを切削工具と
して用いた場合、連続切削は勿論のこと、特に断続切削
において切刃に欠損の発生がなく、すぐれた切削性能を
著しく長期に亘って発揮するのである。As mentioned above, the cermet of the present invention has excellent wear resistance and particularly excellent toughness, so when it is used as a cutting tool, it can be used not only in continuous cutting, but especially in interrupted cutting. There is no occurrence of this, and excellent cutting performance can be achieved over a long period of time.
Claims (1)
うちの1種または2種と、WおよびMoのうちの1種ま
たは2種の複合金属炭窒化物:80〜95容量%、 を含有し、残りが結合相形成成分としてのNiおよびC
oのうちの1種または2種と不可避不純物からなる組成
、並びに上記複合金属炭窒化物が芯部とリング部からな
る2重構造組織を有し、かつ、上記芯部が、Tiと、T
aおよびNbのうちの1種または2種の複合金属炭窒化
物で構成され、 上記リング部が、Tiと、TaおよびNbのうちの1種
または2種と、WおよびMoのうちの1種または2種の
複合金属炭窒化物で構成されることを特徴とする切削工
具用高靭性サーメット。[Scope of Claims] A composite metal carbonitride of Ti, one or two of Ta and Nb, and one or two of W and Mo as hard dispersed phase forming components: 80 to 95 % by volume, with the remainder being Ni and C as binder phase forming components.
o and unavoidable impurities, and the composite metal carbonitride has a double structure structure consisting of a core and a ring, and the core has Ti and T.
The ring portion is composed of one or two composite metal carbonitrides of a and Nb, and the ring portion is made of Ti, one or two of Ta and Nb, and one of W and Mo. Or a high-toughness cermet for cutting tools, characterized by being composed of two types of composite metal carbonitrides.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5049187A JPS63216941A (en) | 1987-03-05 | 1987-03-05 | High-toughness cermet for cutting tool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5049187A JPS63216941A (en) | 1987-03-05 | 1987-03-05 | High-toughness cermet for cutting tool |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63216941A true JPS63216941A (en) | 1988-09-09 |
Family
ID=12860395
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5049187A Pending JPS63216941A (en) | 1987-03-05 | 1987-03-05 | High-toughness cermet for cutting tool |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63216941A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5308376A (en) * | 1989-06-26 | 1994-05-03 | Sandvik Ab | Cermet having different types of duplex hard constituents of a core and rim structure in a Co and/or Ni matrix |
US5314657A (en) * | 1992-07-06 | 1994-05-24 | Sandvik Ab | Sintered carbonitride alloy with improved toughness behavior and method of producing same |
US5672382A (en) * | 1985-12-24 | 1997-09-30 | Sumitomo Electric Industries, Ltd. | Composite powder particle, composite body and method of preparation |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61195950A (en) * | 1985-02-25 | 1986-08-30 | Mitsubishi Metal Corp | Cermet for cutting tool having high hardness and toughness |
-
1987
- 1987-03-05 JP JP5049187A patent/JPS63216941A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61195950A (en) * | 1985-02-25 | 1986-08-30 | Mitsubishi Metal Corp | Cermet for cutting tool having high hardness and toughness |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5672382A (en) * | 1985-12-24 | 1997-09-30 | Sumitomo Electric Industries, Ltd. | Composite powder particle, composite body and method of preparation |
US5308376A (en) * | 1989-06-26 | 1994-05-03 | Sandvik Ab | Cermet having different types of duplex hard constituents of a core and rim structure in a Co and/or Ni matrix |
US5314657A (en) * | 1992-07-06 | 1994-05-24 | Sandvik Ab | Sintered carbonitride alloy with improved toughness behavior and method of producing same |
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