JPS63203880A - Treatment agent for hydrophobic fiber - Google Patents
Treatment agent for hydrophobic fiberInfo
- Publication number
- JPS63203880A JPS63203880A JP62029524A JP2952487A JPS63203880A JP S63203880 A JPS63203880 A JP S63203880A JP 62029524 A JP62029524 A JP 62029524A JP 2952487 A JP2952487 A JP 2952487A JP S63203880 A JPS63203880 A JP S63203880A
- Authority
- JP
- Japan
- Prior art keywords
- treatment agent
- fibers
- present
- parts
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims description 38
- 239000000835 fiber Substances 0.000 title claims description 37
- 230000002209 hydrophobic effect Effects 0.000 title claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 description 25
- 238000004043 dyeing Methods 0.000 description 14
- 239000000975 dye Substances 0.000 description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- -1 alkylbenzene sulfonates Chemical class 0.000 description 11
- 239000004744 fabric Substances 0.000 description 11
- 229920000728 polyester Polymers 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 6
- 238000000859 sublimation Methods 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 230000008022 sublimation Effects 0.000 description 5
- 239000000986 disperse dye Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- DCBNMBIOGUANTC-UHFFFAOYSA-N [5-[(5-benzoyl-4-hydroxy-2-methoxyphenyl)methyl]-2-hydroxy-4-methoxyphenyl]-phenylmethanone Chemical compound COC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1CC(C(=CC=1O)OC)=CC=1C(=O)C1=CC=CC=C1 DCBNMBIOGUANTC-UHFFFAOYSA-N 0.000 description 3
- 229920006221 acetate fiber Polymers 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000002274 desiccant Substances 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000009998 heat setting Methods 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OTDFRLWOMRZKDR-UHFFFAOYSA-N Repenol Natural products CC(=O)OC1Oc2cc(O)ccc2C3=C1Oc4cc(O)c(O)c(O)c4C3=O OTDFRLWOMRZKDR-UHFFFAOYSA-N 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical class O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Landscapes
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野
本発明は繊維用処理剤に関するものである。更に詳しく
は分散染料、カチオン染料等で染色された疎水性繊維１
％匿ポリエステル系繊維の耐光性を向上させる為の処理
剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a treatment agent for textiles. More specifically, hydrophobic fibers dyed with disperse dyes, cationic dyes, etc. 1
The present invention relates to a treatment agent for improving the light resistance of polyester fibers containing %-containing polyester fibers.
従来の技術
近年分散染料やカチオン染料で染色された疎水性繊維が
、カーシートあるいはカーテン等、天然光に長時間曝さ
れる機会の多い分野に広く使用されるようになった。こ
のように、天然光に長（曝された場合、経時的に光によ
る染色物の褪色が顕著であり、使用上大きな問題となっ
ている。もちろん染色に供される染料自体の光に対する
堅牢度を高める検討も盛んに進められているが、その効
果は不充分であり、広い色相にわたる染料においてその
耐光性を改善することは困難な状況である。BACKGROUND OF THE INVENTION In recent years, hydrophobic fibers dyed with disperse dyes or cationic dyes have come to be widely used in fields that are often exposed to natural light for long periods of time, such as car seats and curtains. In this way, if the dyed product is exposed to natural light for a long time, the color fading due to the light will be noticeable over time, which poses a major problem in use.Of course, the fastness of the dye itself to light is also important. Although efforts are being made to improve the light resistance of dyes over a wide range of hues, it is difficult to improve their light resistance.
一方、染色に際し、ベンゾトリアゾール系の光堅牢度向
上剤（例、２−（２’−ヒドロキシ−５′−ｔ−フチル
ー５′−メチルフェニル）−５−クロロベンゾトリアゾ
ール）で処理することが行われている。しかし一部の染
料については、それらの光堅牢度向上剤で処理すること
によって却って耐光堅牢度が低下するという問題点や、
それらの光堅牢度向上剤の昇華堅牢度が弱いため、ヒー
トセクト工程等で、昇華し効果がなくなるという問題点
がある。又ベンゾフェノン系光堅牢度向上剤の１部はこ
れを樹脂の中に練り込むことによってそれから得られる
樹脂成型物の耐光堅牢度を向上させるという目的の為に
使用されているが、それらのものは概して疎水性繊維に
対する親和力が小さいので後処理剤として繊維に付与せ
しめることは困難である。又このような練り込み法にお
いては十分な耐熱性があるものだけが使用されている。On the other hand, when dyeing, it is possible to treat with a benzotriazole-based light fastness improver (e.g., 2-(2'-hydroxy-5'-t-phthyl-5'-methylphenyl)-5-chlorobenzotriazole). It is being said. However, some dyes have the problem that their light fastness actually decreases when they are treated with these light fastness improvers.
Since the sublimation fastness of these light fastness improvers is weak, there is a problem that they sublimate during the heat section process and lose their effect. In addition, some benzophenone-based light fastness improvers are used for the purpose of improving the light fastness of resin moldings obtained by kneading them into resin, but these Generally, it has a low affinity for hydrophobic fibers, so it is difficult to apply it to fibers as a post-treatment agent. Also, in this kneading method, only materials with sufficient heat resistance are used.
発明が解決しようとする問題点
疎水性繊維に対して十分な親和力があり昇華堅牢度の十
分たかい耐光堅牢度向上用の後処理剤の開発が望まれて
いる。Problems to be Solved by the Invention It is desired to develop a post-treatment agent for improving light fastness that has sufficient affinity for hydrophobic fibers and has sufficient sublimation fastness.
問題点を解決するための手段
本発明者らは前記したような問題点を解決するために、
鋭意検討した結果１本発明に到達した。Means for Solving the Problems In order to solve the above-mentioned problems, the present inventors
As a result of intensive studies, we have arrived at the present invention.
すなわち本発明は化合物（１） とスルホン酸塩型アニオン界面活性剤及び／又は。That is, the present invention provides compound (1) and a sulfonate type anionic surfactant and/or.
ポリオキシアルキル型非イオン界面活性剤とからなる疎
水性繊維用処理剤を提供する。Provided is a treatment agent for hydrophobic fibers comprising a polyoxyalkyl type nonionic surfactant.
本発明に用いられる式（１）の化合物は、２−ヒドロキ
シ−４−メトキシベンゾフェノンを例えば硫酸中で、ホ
ルマリン又はパラホルムアルデヒドにより縮合すること
により得ることができる。The compound of formula (1) used in the present invention can be obtained by condensing 2-hydroxy-4-methoxybenzophenone with formalin or paraformaldehyde in, for example, sulfuric acid.
又本発明で用いられるスルホン酸塩型アニオン界面活性
剤としては、ナフタリンスルホン酸ホルマリン縮金物の
ソーダ塩、特殊芳香族スルホン酸ホルマリンＭ合物のソ
ーダ塩、変形リグニンスルホン酸、アルキルベンゼンス
ルホン酸塩、アルキルナフタレンスルホン酸塩等が挙げ
られる。これらノウチ好ましいものは、ナフタリンスル
ホ／酸ホルマリン縮金物のソーダ塩、特殊芳香族スルホ
ン酸ホルマリン縮金物のソーダ塩、変形リグニンスルホ
ン酸である。In addition, the sulfonate type anionic surfactants used in the present invention include sodium salts of naphthalene sulfonic acid formalin condensates, soda salts of special aromatic sulfonic acid formalin M compounds, modified lignin sulfonic acids, alkylbenzene sulfonates, Examples include alkylnaphthalene sulfonate. Preferred among these are sodium salts of naphthalene sulfo/acid formalin condensates, soda salts of special aromatic sulfonic acid formalin condensates, and modified lignin sulfonic acids.
更にポリオキシアルキル型非イオン界面活性剤としては
、高級アルコールアルキレンオキサイド付加物、アルキ
ルフェノールアルキレンオキサイド付加物脂肪酸アルキ
レンオキサイド付加物、多価アルコール脂肪酸エステル
アルキレンオキサイド付加物、高級アルキルアミンアル
キレンオキサイド付加物、ポリプロビレ／グリコールエ
チレンオキサイド付加物及びそれらの脂肪酸エステル等
が挙げられる。これらのうち好ましいものは、高級アル
コールアルキレンオキサイド付加物、ポリプロピレング
リコールエチレンオキサイド付加物及び、それらの脂肪
酸エステルであり、特に好ましいものは、ポリプロピレ
ングリコールエチレンオキサイド付加物及び、その脂肪
酸エステルである。Furthermore, as polyoxyalkyl type nonionic surfactants, higher alcohol alkylene oxide adducts, alkylphenol alkylene oxide adducts, fatty acid alkylene oxide adducts, polyhydric alcohol fatty acid ester alkylene oxide adducts, higher alkylamine alkylene oxide adducts, polypropylene /glycol ethylene oxide adducts and their fatty acid esters. Among these, preferred are higher alcohol alkylene oxide adducts, polypropylene glycol ethylene oxide adducts, and fatty acid esters thereof, and particularly preferred are polypropylene glycol ethylene oxide adducts and fatty acid esters thereof.
本発明の疎水性繊維処理剤は式（１）の化合物と前記例
で示したスルホン酸塩型アニオン界面活性剤及び／又は
前記例で示したポリオキシアルキレン型非イオン界面活
性剤を用いて下記するような方法によって調製される。The hydrophobic fiber treatment agent of the present invention is produced by using the compound of formula (1) and the sulfonate type anionic surfactant shown in the above example and/or the polyoxyalkylene type nonionic surfactant shown in the above example. It is prepared by such a method.
まず式（１）で示される化合物と前記したような界面活
性剤、水、さらに必要により通常の消泡剤増粘剤等の添
加剤を加えて混合物を作る。この場合混合物中の式（１
）の化合物の含量は５〜５０重量％であり、好ましくは
１０〜４０重量％である。First, a mixture is prepared by adding the compound represented by formula (1), the above-mentioned surfactant, water, and, if necessary, additives such as conventional antifoaming agents and thickeners. In this case, the formula (1
) is 5 to 50% by weight, preferably 10 to 40% by weight.
次に、上記混合物をサンドグラインド等で微粒子化する
。本発明の疎水性繊維用処理剤は通常液状であるが所望
によりスプレードライヤー等で乾燥して乾燥状（粉状又
は顆粒状）にしてもよい。Next, the above mixture is made into fine particles by sand grinding or the like. The treatment agent for hydrophobic fibers of the present invention is usually in liquid form, but if desired, it may be dried with a spray dryer or the like to form a dry form (powder or granules).
本発明の処理剤は、実際の使用に当たり、それが液状の
ときは水で稀釈した形で又それが乾燥品であるときは水
に分散せしめた形で用いられる。In actual use, the processing agent of the present invention is used in a diluted form with water when it is in liquid form, or in a form in which it is dispersed in water when it is in a dry form.
本発明の処理剤を使用するにあたっての水液中等におけ
る式（１）の化合物の濃度は、通常０．１部十分であり
逆に１０％ｏ、ｗ、ｆ より多くしても耐光性向上効
果は１０％０．Ｗ、ｆ以下の場合に比べそれ程大きくな
いので不経済である。When using the treatment agent of the present invention, the concentration of the compound of formula (1) in an aqueous solution or the like is usually sufficient to be 0.1 part; is 10%0. It is uneconomical because it is not so large compared to the case where W, f or less.
本処理剤を繊維に付与する方法としては、染色前に予め
繊維を本処理剤で処理する方法、染色時に染料と一緒に
本処理剤を用いて繊維を処理する方法、染色後に本処理
剤で繊維を処理する方法等が挙げられる。これらのうち
、染色時に染料と一緒だ繊維を処理する方法が１通常最
も好ましい。Methods for applying this treatment agent to fibers include treating the fibers with this treatment agent before dyeing, treating the fibers with this treatment agent together with the dye during dyeing, and applying this treatment agent after dyeing. Examples include methods for treating fibers. Among these, the method of treating the fiber together with the dye during dyeing is usually the most preferred.
浸染法またはサーモゾル法による染色方法によって本処
理剤を付与する場合には１本処理剤を染料と一緒に染色
浴に添加しておく。また捺染法による場合には１本処理
剤を色糊中に添加しておく。When applying this treatment agent by a dyeing method using a dip dyeing method or a thermosol method, one treatment agent is added to the dyeing bath together with the dye. In addition, when using the textile printing method, one treatment agent is added to the colored paste.
例えば、ポリエステル繊維の浸染法の場合は１００〜１
３５℃で通常１０〜６０分、サーモゾル法の場合は１５
０〜２１０℃で通常３０〜１２０秒である。捺染法の場
合ＨＴ法（常圧高温スチーミング法）では１６０〜１９
０℃で１通常５〜１０分、ＨＰ法（高圧スチーミング法
）では１１０〜１３０℃で２０〜４０分である。For example, in the case of the dyeing method for polyester fibers, 100 to 1
Usually 10 to 60 minutes at 35℃, 15 minutes in the case of thermosol method
It is usually 30 to 120 seconds at 0 to 210°C. In the case of the textile printing method, the HT method (normal pressure high temperature steaming method) is 160 to 19
It usually takes 5 to 10 minutes at 0°C, and 20 to 40 minutes at 110 to 130°C in the HP method (high pressure steaming method).
又、酸性化ポリエステル繊維（以下ＣＤＰ繊維と略す）
の場合、浸染法では、１００〜１２０℃で通常１０〜９
０分、サーモゾル法では、１５０℃〜２００℃で通常３
０〜１２０秒である。捺染法の場合、ＨＴ法では１２０
〜１６０℃で通常５〜１０分、ＨＰ法では１００〜１２
０℃で通常１０〜５０分である。Also, acidified polyester fiber (hereinafter abbreviated as CDP fiber)
In the case of dyeing, the dyeing temperature is usually 10 to 9 at 100 to 120℃.
0 minutes, in thermosol method, usually 3 minutes at 150℃~200℃
It is 0 to 120 seconds. In the case of the textile printing method, the HT method is 120
Usually 5 to 10 minutes at ~160℃, 100 to 12 minutes by HP method
It is usually 10 to 50 minutes at 0°C.
本処理剤を繊維に付与する場合、その方法に応じて各種
の薬剤と併用することができる。例えば染色前に処理す
る場合には、精練剤、浸染法の場合には染料の他、均染
剤、消泡剤等、またサーモゾル法の場合には染料の他マ
イグレーション防止剤、捺染法の場合には染料の他、糊
剤等、染色後に使用される場合には各種仕上剤等である
。When applying this treatment agent to fibers, it can be used in combination with various chemicals depending on the method. For example, in the case of treatment before dyeing, scouring agents, in addition to dyes in the case of dyeing method, leveling agents, antifoaming agents, etc. in the case of thermosol method, in addition to dyes, in the case of printing method, anti-migration agents, etc. In addition to dyes, these include sizing agents and various finishing agents when used after dyeing.
本発明の処理剤が適用される疎水性繊維としては、ポリ
エステル系合成繊維、アセテート系繊維およびナイロン
等の疎水性繊維が挙げられる。すなわち、ポリエチレン
テレフタレート、ポリエチレンテレフタレート・インフ
タレート、ポリエチレンテレフタレート・パラオキシベ
ンゾエート。Hydrophobic fibers to which the treatment agent of the present invention is applied include hydrophobic fibers such as polyester synthetic fibers, acetate fibers, and nylon. namely, polyethylene terephthalate, polyethylene terephthalate inphthalate, and polyethylene terephthalate paraoxybenzoate.
ポリエチレンテレフタレート・パラオキシベンゾエート
、ポリエチレンテレフタレート・ブチレンテレフタレー
ト、酸性化ポリエステル等のポリエステル繊維、および
ジアセテート、トリアセテート等のアセテート系繊維、
ナイロン等の疎水性繊維、さらにこれら繊維と他の天然
繊維、半合成繊維１合成繊維等との混紡、交編織物等が
挙げられる。そして、その形態としては、綿、糸、トウ
、トップ、カモ１編織物１不織布などが挙げられる。Polyester fibers such as polyethylene terephthalate/paraoxybenzoate, polyethylene terephthalate/butylene terephthalate, acidified polyester, and acetate fibers such as diacetate and triacetate,
Examples include hydrophobic fibers such as nylon, blends of these fibers with other natural fibers, semi-synthetic fibers, synthetic fibers, etc., interwoven fabrics, and the like. Examples of the form include cotton, thread, tow, top, duck 1 knit fabric 1 nonwoven fabric, etc.
本発明の処理剤は処理液中で均一に分散するとともに、
乳化安定性も優れており、疎水性繊維に対する親和力も
十分高いので疎水性繊維中にも均一に拡散浸透する。し
たがって１本発明の処理剤をポリエステル系繊維、アセ
テート系繊維、ナイロン等の疎水性繊維に使用すること
により１分散染料及びカチオン染料で染色された。これ
ら疎水性繊維の耐光性を格段に向上させることが出来る
。The processing agent of the present invention is uniformly dispersed in the processing liquid, and
It has excellent emulsion stability and has a sufficiently high affinity for hydrophobic fibers, allowing it to diffuse and permeate evenly into hydrophobic fibers. Therefore, by using the treatment agent of the present invention on hydrophobic fibers such as polyester fibers, acetate fibers, and nylon, the fibers were dyed with disperse dyes and cationic dyes. The light resistance of these hydrophobic fibers can be significantly improved.
又本発明の処理剤中の式（１）の化合物は高い昇華堅牢
度を有するのでヒートセット等の熱処理によっても耐光
性を向上せしめる効果が落ちることがない。Further, since the compound of formula (1) in the processing agent of the present invention has high sublimation fastness, the effect of improving light resistance does not deteriorate even when heat treatment such as heat setting is performed.
実施例
以下実施例により本発明の疎水性繊維用処理剤について
更に具体的に説明するが１本発明はこれらに限定される
ものではない。なお、以下の実施例中で部、係はそれぞ
れ重量部、重量％を示す。EXAMPLES The hydrophobic fiber treatment agent of the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto. In addition, in the following examples, "part" and "part" indicate weight part and weight %, respectively.
実施例１
下記式口）のビス（５−ベンゾイル−４−ヒドロキシ−
２−メトキシフェニル）メタン１５部β−ナフタレンス
ルホン酸・ホルマリン縮金物のソーダ塩（デモールＮ、
花王アトラス（株）ａｌｌ）１５部、ポリプロピレング
リコールエチレンオキサイド付加物（レペノールＤＴ−
４００．花王アトラスｃ株）製）３部、不乾性剤〔ペト
リオール。Example 1 Bis(5-benzoyl-4-hydroxy-
2-methoxyphenyl)methane 15 parts β-naphthalenesulfonic acid/formalin condensate soda salt (Demol N,
Kao Atlas Co., Ltd. all) 15 parts, polypropylene glycol ethylene oxide adduct (Repenol DT-
400. 3 parts (manufactured by Kao Atlas C), non-drying agent [Petriol.
クラレ（株）製）１０部、消泡剤数滴、水５７部をビー
ズグラインダーに入れ、６時間練り潰しながら、微粒子
化分散して本発明の処理剤を得た。(manufactured by Kuraray Co., Ltd.), several drops of an antifoaming agent, and 57 parts of water were placed in a bead grinder, and the mixture was ground and dispersed into fine particles while being crushed for 6 hours to obtain a processing agent of the present invention.
尚武い）の化合物は次の様にして合成した。The compound (Naotakei) was synthesized as follows.
２−ヒドロキシ−４−メトキシベンゾフェノン２２．８
部を濃硫酸２７５部に溶解し、パラホルムアルデヒド１
．６５部を攪拌下−５〜０℃で少しずつ加えた。０〜５
℃で５時間攪拌した後、氷水３０００部中にあけ、析出
した結晶をヂ過、水洗。2-Hydroxy-4-methoxybenzophenone 22.8
1 part of paraformaldehyde was dissolved in 275 parts of concentrated sulfuric acid.
．． 65 parts were added in portions at -5 to 0°C with stirring. 0-5
After stirring at ℃ for 5 hours, the mixture was poured into 3,000 parts of ice water, and the precipitated crystals were filtered and washed with water.
乾燥して粗ケーキ２３．２部を得だ。この粗ケーキをエ
タノールより再結晶するとｍｐ１９０〜２３０℃の微黄
色結晶が得られた。このものはマススペクトルで分子量
４６８を示し弐〇）の構造を有することがわかった。After drying, 23.2 parts of a crude cake was obtained. When this crude cake was recrystallized from ethanol, pale yellow crystals with a mp of 190 to 230°C were obtained. This product showed a molecular weight of 468 in the mass spectrum and was found to have the structure 2).
実施例２
式（１）で示されるビス（５−ベンゾイル−４−ヒドロ
キシ−２−メトキシフェニル）メタン１５部、特殊芳香
族スルホン酸ホルマリン縮合物のソーダ塩（チモールＣ
。花王アトラスｃ株）製）１５部、ポリプロピレングリ
コールエチレンオキサイド付加物〔ニューボールＰＥ−
６４，三洋化成工業（株）製）３部、不乾性剤〔ベトリ
オール、クラレ（株）ｔｌＪ）１０部、消泡剤数滴、水
５７部をビーズグラインダーに入れ、６時間練り潰しな
がら。Example 2 15 parts of bis(5-benzoyl-4-hydroxy-2-methoxyphenyl)methane represented by formula (1), sodium salt of formalin condensate of special aromatic sulfonic acid (thymol C
. Kao Atlas C Co., Ltd.) 15 parts, polypropylene glycol ethylene oxide adduct [New Ball PE-
64 (manufactured by Sanyo Chemical Industries, Ltd.), 10 parts of a non-drying agent (Vetriol, Kuraray Co., Ltd. tlJ), several drops of an antifoaming agent, and 57 parts of water were placed in a bead grinder and kneaded for 6 hours.
微粒子化分散して本発明の処理剤をえた。The processing agent of the present invention was obtained by micronization and dispersion.
実施例３
弐い）で示されるビス（５−ベンゾイル−４−ヒドロキ
シ−２−メトキシフェニル）メタン１５部、変形リグニ
ンスルホン酸（パニレックスＮ。Example 3 15 parts of bis(5-benzoyl-4-hydroxy-2-methoxyphenyl)methane, modified ligninsulfonic acid (Panirex N).
山開国策パルプ（株）製）１５部、ポリプロピレングリ
コールエチレンオキサイド付加物（レベノールＤＴ ４
００．花王アトラスＣ株）製）３部、不乾性剤（ペトリ
オール、２２７０株）ｌｌ！り １０部、消泡剤数滴、
水５７部をビーズグラインダーに入れ。Yamakaikokusaku Pulp Co., Ltd.) 15 parts, polypropylene glycol ethylene oxide adduct (Levenol DT 4
00. (manufactured by Kao Atlas C)) 3 parts, non-drying agent (Petriol, 2270 stocks) ll! 10 parts, several drops of antifoaming agent,
Put 57 parts of water into a bead grinder.
６時間練り潰しながら、微粒子化分散して本発明処理剤
をえた。The treatment agent of the present invention was obtained by dispersing the mixture into fine particles while kneading it for 6 hours.
応用例
ポリエステル繊維への付与並びに耐光性試験結果（浸染
法）
■ 処理剤
浴 比 冒 ３０
供試布 ポリエステル加工糸織物
１３０℃
冷却、取シ出し→水洗→還元洗浄→乾燥■ 使用染料
Ｋａｙａｌｏｎ Ｐｏ１ｙｅｓｅｅｒ Ｐｉｎｋ ＲＣ
Ｌ−Ｆ！（日本化薬（株）製、分散染料）
Ｋａｙａｌｏｎ Ｐｏ１ｙｅｅｔｅｒ Ｒｕｂｉｎｅ
３ＧＬ−８（同 よ ）
Ｋａｙａｌｏｎ Ｐｏ１ｙｅｓｔｅｒ Ｒｅｄ ＴＬ−
８Ｆ（同 上 ）
■ 射光試験（加速照射試験）条件
上記の条件で作製した染色布とパネルの間に厚さ１０朋
のウレタンフオームを挾んで、８３℃Ｘ２００時間の条
件でカーボンフェードメーターで照射した。照射布と未
照射布とをＪ工Ｓ変退色用グレースケールでチェックし
、その結果を耐光堅牢度としその結果を第１表に示した
。Application example Application to polyester fibers and light resistance test results (dying method) ■ Treatment agent bath Ratio 30 Test fabric Polyester processed yarn fabric 130°C Cooling, taking out → washing with water → reduction washing → drying ■ Dye used: Kayalon Polyyeseer Pink R.C.
L-F! (Nippon Kayaku Co., Ltd., disperse dye) Kayalon Polyeeter Rubine
3GL-8 (same) Kayalon Polyester Red TL-
8F (same as above) ■ Irradiation test (accelerated irradiation test) conditions A 10 mm thick urethane foam was sandwiched between the panel and the dyed fabric prepared under the above conditions, and irradiated with a carbon fade meter at 83°C for 200 hours. did. The irradiated fabric and the non-irradiated fabric were checked using the J-Tech S discoloration/fading gray scale, and the results are shown in Table 1 as light fastness.
第１表
（注）フェードメーター照射時間
第１表に示すように本発明の処理剤の耐光堅牢度向上効
果は顕著である。又、市販ベンゾトリアゾール系耐光堅
牢度向上剤と比較しても１本発明の処理剤の方が耐光堅
牢度向上効果は高い。特にＫａｙａｌｏｎ Ｐｏ１ｙｅ
ｓｔｅｒ Ｒｅｄ ＴＬ−８Ｆにおいて、その差は顕著
である。即ち、市販トリアゾール系耐光堅牢度向上剤は
、無添加布よりも低下させるという感作用がみられる。Table 1 (Note) Fade meter irradiation time As shown in Table 1, the effect of improving light fastness of the processing agent of the present invention is remarkable. Furthermore, even when compared with commercially available benzotriazole-based light fastness improving agents, the processing agent of the present invention has a higher light fastness improving effect. Especially Kayalon Po1ye
In ster Red TL-8F, the difference is remarkable. That is, commercially available triazole-based light fastness improvers have a sensitizing effect that lowers the color fastness compared to fabrics without additives.
■ 対昇華性試験
前記■で得られた乾燥染布につき、１８０℃ｘ３０秒の
ヒートセットを行い、ヒートセットを行った後の染布と
、ヒートセットを行う前の染布をブラックライト照射下
で比較すると、（ロ）の市販ベンゾトリアゾール系耐光
堅牢度向上剤を使用したものは、吸収が著しく減退して
いたが、（イ）の本発明の処理剤を使用したものは、吸
収の減退はわずかじか認められなかった。この結果から
本発明の処理剤は熱処理に対しても堅牢である（耐昇華
性）ことが認められた。■ Anti-sublimation test The dried dyed fabric obtained in the above (■) was heat set at 180°C for 30 seconds, and the dyed fabric after heat setting and the dyed fabric before heat setting were irradiated with a black light. When compared with (b), the absorption was significantly reduced in the case using the commercially available benzotriazole-based light fastness improver, but the absorption was significantly reduced in the case (b), in which the treatment agent of the present invention was used. was barely recognized. From this result, it was confirmed that the treatment agent of the present invention is robust to heat treatment (sublimation resistance).
発明の効果
疎水性繊維に高い親和力を有し、高い耐昇華性をもった
日光堅牢度向上用繊維処理剤が得られた。Effects of the Invention A fiber treatment agent for improving sunlight fastness, which has a high affinity for hydrophobic fibers and has high sublimation resistance, was obtained.
Claims (1)
及び／又はポリオキシアルキレン型非イオン界面活性剤
とからなる疎水性繊維用処理剤[Claims] 1. A compound represented by the following formula (1) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (1) and a sulfonate type anionic surfactant and/or a polyoxyalkylene type nonionic surfactant Hydrophobic fiber treatment agent consisting of
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62029524A JP2584625B2 (en) | 1987-02-13 | 1987-02-13 | Treatment agent for hydrophobic fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62029524A JP2584625B2 (en) | 1987-02-13 | 1987-02-13 | Treatment agent for hydrophobic fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63203880A true JPS63203880A (en) | 1988-08-23 |
| JP2584625B2 JP2584625B2 (en) | 1997-02-26 |
Family
ID=12278493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62029524A Expired - Fee Related JP2584625B2 (en) | 1987-02-13 | 1987-02-13 | Treatment agent for hydrophobic fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2584625B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7372874B2 (en) * | 2020-04-30 | 2023-11-01 | 株式会社ブリヂストン | Adhesive composition, rubber-organic fiber cord composite and tire |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53101346A (en) * | 1977-02-14 | 1978-09-04 | Adeka Argus Chem Co Ltd | Preparation of 5,5'-methylene(2-hhdroxy-4-alkoxybenzoohenone) |
| JPS5663056A (en) * | 1979-10-25 | 1981-05-29 | Toray Industries | Polyester long fiber nonwoven fabric having excellent weather resistance |
| JPS59216979A (en) * | 1983-05-18 | 1984-12-07 | 三洋化成工業株式会社 | Treating agent for fiber |
-
1987
- 1987-02-13 JP JP62029524A patent/JP2584625B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53101346A (en) * | 1977-02-14 | 1978-09-04 | Adeka Argus Chem Co Ltd | Preparation of 5,5'-methylene(2-hhdroxy-4-alkoxybenzoohenone) |
| JPS5663056A (en) * | 1979-10-25 | 1981-05-29 | Toray Industries | Polyester long fiber nonwoven fabric having excellent weather resistance |
| JPS59216979A (en) * | 1983-05-18 | 1984-12-07 | 三洋化成工業株式会社 | Treating agent for fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2584625B2 (en) | 1997-02-26 |
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