JPS63203609A - Perfume composition - Google Patents
Perfume compositionInfo
- Publication number
- JPS63203609A JPS63203609A JP3652387A JP3652387A JPS63203609A JP S63203609 A JPS63203609 A JP S63203609A JP 3652387 A JP3652387 A JP 3652387A JP 3652387 A JP3652387 A JP 3652387A JP S63203609 A JPS63203609 A JP S63203609A
- Authority
- JP
- Japan
- Prior art keywords
- perfume
- fragrance
- trimethyl
- phenyl
- pentanone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 10
- 239000002304 perfume Substances 0.000 title abstract description 8
- 239000003205 fragrance Substances 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 abstract description 6
- DHFXVWXVZUATDN-UHFFFAOYSA-N 2,2,4-trimethyl-1-phenylpentan-3-one Chemical compound CC(C)C(=O)C(C)(C)CC1=CC=CC=C1 DHFXVWXVZUATDN-UHFFFAOYSA-N 0.000 abstract description 4
- -1 hair rinse Substances 0.000 abstract description 3
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 239000003599 detergent Substances 0.000 abstract description 2
- 239000008266 hair spray Substances 0.000 abstract description 2
- 239000000344 soap Substances 0.000 abstract description 2
- HXVNBWAKAOHACI-UHFFFAOYSA-N 2,4-dimethyl-3-pentanone Chemical compound CC(C)C(=O)C(C)C HXVNBWAKAOHACI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002453 shampoo Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 7
- 235000013399 edible fruits Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JIMGVOCOYZFDKB-UHFFFAOYSA-N 2-phenylethyl 3-methylbutanoate Chemical compound CC(C)CC(=O)OCCC1=CC=CC=C1 JIMGVOCOYZFDKB-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- DZNVIZQPWLDQHI-UHFFFAOYSA-N Citronellyl formate Chemical compound O=COCCC(C)CCC=C(C)C DZNVIZQPWLDQHI-UHFFFAOYSA-N 0.000 description 2
- 235000018791 Cymbopogon nardus Nutrition 0.000 description 2
- 244000166675 Cymbopogon nardus Species 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 235000019717 geranium oil Nutrition 0.000 description 2
- 239000010648 geranium oil Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 229910000104 sodium hydride Inorganic materials 0.000 description 2
- 239000012312 sodium hydride Substances 0.000 description 2
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- VVUMWAHNKOLVSN-UHFFFAOYSA-N 2-(4-ethoxyanilino)-n-propylpropanamide Chemical compound CCCNC(=O)C(C)NC1=CC=C(OCC)C=C1 VVUMWAHNKOLVSN-UHFFFAOYSA-N 0.000 description 1
- RCSBILYQLVXLJG-UHFFFAOYSA-N 2-Propenyl hexanoate Chemical compound CCCCCC(=O)OCC=C RCSBILYQLVXLJG-UHFFFAOYSA-N 0.000 description 1
- RHLVCLIPMVJYKS-UHFFFAOYSA-N 3-octanone Chemical compound CCCCCC(=O)CC RHLVCLIPMVJYKS-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- 102100034744 Cell division cycle 7-related protein kinase Human genes 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000005241 Cistus ladanifer Nutrition 0.000 description 1
- 240000008772 Cistus ladanifer Species 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 241000208152 Geranium Species 0.000 description 1
- 101000945740 Homo sapiens Cell division cycle 7-related protein kinase Proteins 0.000 description 1
- 239000004869 Labdanum Substances 0.000 description 1
- HYMLWHLQFGRFIY-UHFFFAOYSA-N Maltol Natural products CC1OC=CC(=O)C1=O HYMLWHLQFGRFIY-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- ZSBOMYJPSRFZAL-JLHYYAGUSA-N [(2e)-3,7-dimethylocta-2,6-dienyl] butanoate Chemical compound CCCC(=O)OC\C=C(/C)CCC=C(C)C ZSBOMYJPSRFZAL-JLHYYAGUSA-N 0.000 description 1
- 229910000102 alkali metal hydride Inorganic materials 0.000 description 1
- 150000008046 alkali metal hydrides Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- PHXATPHONSXBIL-JTQLQIEISA-N gamma-Undecalactone Natural products CCCCCCC[C@H]1CCC(=O)O1 PHXATPHONSXBIL-JTQLQIEISA-N 0.000 description 1
- 229940020436 gamma-undecalactone Drugs 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- FQMZVFJYMPNUCT-UHFFFAOYSA-N geraniol formate Natural products CC(C)=CCCC(C)=CCOC=O FQMZVFJYMPNUCT-UHFFFAOYSA-N 0.000 description 1
- NHCQMVNKPJAQJZ-UHFFFAOYSA-N geranyl n-butyrate Natural products CCCCOCC=C(C)CCC=C(C)C NHCQMVNKPJAQJZ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 1
- 239000003444 phase transfer catalyst Substances 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は２，２．４−トリメチル−１−フェニル−３−
ペンタノンを含有する香料組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to 2,2,4-trimethyl-1-phenyl-3-
The present invention relates to a fragrance composition containing pentanone.
従来より種々の化合物が香料の調合素材として知られて
いる。そして香料の調合においてその素材に対しては、
低価格であること、化学的に安定であること、他の香料
との調合性がよいこと、新しい香りであること等のさま
ざまな要望が存在する。特に新しい香シの素材を見い出
すことは、香料調合上極めて重要である。BACKGROUND ART Various compounds have been known as ingredients for preparing fragrances. And when preparing fragrances, for the ingredients,
There are various demands such as low price, chemical stability, good compatibility with other fragrances, and new fragrances. In particular, finding new incense materials is extremely important in perfume preparation.
本発明者らは香料の調合素材を見い出すべく鋭意研究し
ていたところ、文献既知〔例えば、Ｃｈ＠ｍ、Ａｂ、
７０ （２１） ：９６１０９ｍ ）の化合物である２
、２．４−トリメチル−１−フェニル−３−ペンタノン
は、これを調合香料の成分として配合するとメタリック
でグリーンなパラ様の香りを付与することができること
を見い出し１本発明を完成した。The inventors of the present invention were conducting intensive research in order to find a compounding material for fragrances, and found that the materials known in the literature [e.g., Ch@m, Ab,
70 (21):96109m) 2
, 2,4-trimethyl-1-phenyl-3-pentanone has been found to be able to impart a metallic, green para-like fragrance when blended as a component of a blended fragrance.1 The present invention has been completed.
すなわち本発明は、２，２．４−トリメチルー１−７二
二ルー３−ペンタノンｔ−含有スる香料組成物を提供す
るものである。That is, the present invention provides a fragrance composition containing 2,2,4-trimethyl-1-722-3-pentanone t-.
本発明香料組成物の調合素材である２、２．４−トリメ
チル−１−フェニル−３−−ｆ！ンタノン（以下本発明
香料化合物と称す）は、上記の如く既知の化合物である
が、その香りについての報告、まして調合香料として使
用されたという報告は全くない。2,2,4-trimethyl-1-phenyl-3-f! which is a compounding material for the fragrance composition of the present invention! Although tantanone (hereinafter referred to as the fragrance compound of the present invention) is a known compound as described above, there are no reports on its fragrance, much less on its use as a mixed fragrance.
本発明香料化合物は前記文献に従って製造、することも
できるが、例えばハロゲン化ペンシルとゾイソゾロビル
クトンを塩基の存在下に反応させることによって製造す
ることができる０
使用される塩基としてはアルカリ金属水酸化物、アルカ
リ金属アミド、アルカリ金属ノ）イドライド、アルカリ
金属＠３級アルコキシド等が挙げられる。塩基としてア
ルカリ金属水酸化物音用いる場合は、触媒として第４級
アンモニウム塩又はホスホニウム塩のような相関移動触
媒の存在下に行うことができる０このようなアルカリ金
属水酸化物としては、水酸化ナトリウム、水酸化カリウ
ムが好ましく、これはそのまま、あるいは約４０〜６５
％水溶液としてハロゲン化ペンシルに対し等モル〜ｌＯ
倍モル程度用いられる。Although the fragrance compound of the present invention can be produced according to the above-mentioned literature, it can also be produced, for example, by reacting a halogenated pencil and zoisozolobilctone in the presence of a base.The base used is alkali metal water. Examples include oxides, alkali metal amides, alkali metal hydrides, alkali metals@tertiary alkoxides, and the like. When using an alkali metal hydroxide as a base, it can be carried out in the presence of a phase transfer catalyst such as a quaternary ammonium salt or a phosphonium salt as a catalyst.Such alkali metal hydroxides include sodium hydroxide. , potassium hydroxide is preferred, which may be present neat or at about 40 to 65
% aqueous solution, equimolar to 1O to halogenated pencil
It is used at twice the molar level.
反応溶媒としては、ｎ−ヘキサン、ｎ−ヘプタン、ｎ−
オクタンのような飽和炭化水素、ベンゼン、トルエン、
キシレンのような芳香族炭化水素、ジエチルエーテル、
テトラヒドロフラン、ジオキサン、ゾメチルセロソルプ
のようなエーテル溶媒を用いる事ができる。As a reaction solvent, n-hexane, n-heptane, n-
Saturated hydrocarbons like octane, benzene, toluene,
Aromatic hydrocarbons such as xylene, diethyl ether,
Ether solvents such as tetrahydrofuran, dioxane, zomethyl cellosolp can be used.
反応温度は、用いる溶媒によって異なるが、室温〜１５
０℃が好ましい。The reaction temperature varies depending on the solvent used, but ranges from room temperature to 15
0°C is preferred.
本発明香料組成物には、本発明香料化合物を０．０５〜
３０重量％、特に５〜１０重量％配合することが好まし
いが、特にこの量に制限されるものではない。The fragrance composition of the present invention contains 0.05 to 0.05% of the fragrance compound of the present invention.
It is preferable to add 30% by weight, especially 5 to 10% by weight, but the amount is not particularly limited to this amount.
本発明香料組成物はメタリックでグリーンなバラ様の香
シを有するものであシ、高級な調合香料、香水、石鹸、
シャンノー、ヘアリンス、洗剤、化粧品、ヘアスプレー
、芳香剤等の賦香が必要とされるものに広汎に使用でき
る。The fragrance composition of the present invention has a metallic green rose-like fragrance, and is used as a high-grade blended fragrance, perfume, soap, etc.
It can be widely used in things that require fragrance, such as channeau, hair rinses, detergents, cosmetics, hair sprays, and fragrances.
次に参考例及び実施例を挙げて本発明を説明する。 Next, the present invention will be explained with reference to reference examples and examples.
参考例
脱水キシレン２０００ｄ中へ水素化ナトリウム（純分６
０％と流動）９ラフイン４０％）３００Ｆ（正味水素化
ナトリウム１ｓｏｒ。Reference example Sodium hydride (purity 6
0% and flow) 9 rough-in 40%) 300F (net sodium hydride 1 sor.
７．５モル）を仕込む。内温を１３０℃に保ち、約５時
間をかけてシイソグロビルケトン９４２Ｆ（８，２５モ
ル）を滴下する。滴下終了後、同温度で３０分間攪拌を
続けた後、塩化ペンシル９５０Ｆ（７，５モル）を冷却
しながら約６時間で滴下す、る。滴下終了後、約１時間
攪拌した後、内温が５０℃以下となるまで冷却する。こ
こへ水１２００ｓｕｔ−加え、食塩を溶解し分層する。7.5 mol). While keeping the internal temperature at 130° C., Siisoglobil Ketone 942F (8.25 mol) was added dropwise over about 5 hours. After the dropwise addition was completed, stirring was continued for 30 minutes at the same temperature, and then pencil chloride 950F (7.5 mol) was added dropwise over about 6 hours while cooling. After the dropwise addition is completed, the mixture is stirred for about 1 hour and then cooled until the internal temperature becomes 50°C or less. Add 1200 su of water to this, dissolve the salt, and separate the layers.
さらに１％硫酸水１０００ｄ。Furthermore, 1000 d of 1% sulfuric acid water.
ついで水１０００Ｍｌで各１回洗浄する。溶媒をエバー
レータ−で留去した後、減圧下で蒸留する事によｆｉ１
４２Ｌ５ｆ０２．２．４− トリメチル−１−フェニル
−３−−ｅンタノンが得られた（収率９２．８％）。Then, each sample is washed once with 1000 ml of water. After the solvent is distilled off using an evaporator, fi1 is distilled under reduced pressure.
42L5f02.2.4-trimethyl-1-phenyl-3-e tanthanone was obtained (yield 92.8%).
沸 点 １２５〜ｂ
元素分析 （Ｃｌ４Ｈ２゜Ｏとして）
計算値ｐ４：ｃ、８１３０；Ｈ，９，８７実測［ｅ：ｃ
＊８Ｚ５０：Ｈ，９，６ｔＩＲ（液膜、ｃｍ−’ ）：
１７２０．７５０．７１０’ＨＮＭＲ（ＣＤＣ７！、、
溶媒、ＴＭＳ内部標準、δ）ニア、１０（多重線、５Ｈ
）
３．０５（７重線、 Ｊ ＝７ Ｈｚ ＋ Ｉ Ｈ）２
．８０（１重線、３Ｈ）
１．１０（１重線、６Ｈ）
１．００（２重線、Ｊ＝７Ｈｚ、６Ｈ）ＭＳ（ｍ／・、
相対強度）
２０４（２７）、１６１（４２）、１３３（８３）、１
３２（３５）、１０５（２２）、９２（２３）、９１（
１０Ｇ）。Boiling point 125-b Elemental analysis (as Cl4H2°O) Calculated value p4: c, 8130; H, 9,87 actual measurement [e: c
*8Z50:H,9,6tIR (liquid film, cm-'):
1720.750.710'HNMR (CDC7!,,
Solvent, TMS internal standard, δ) near, 10 (multiplet, 5H
) 3.05 (septadite, J = 7 Hz + I H)2
．． 80 (single line, 3H) 1.10 (single line, 6H) 1.00 (double line, J=7Hz, 6H) MS (m/・,
relative strength) 204 (27), 161 (42), 133 (83), 1
32 (35), 105 (22), 92 (23), 91 (
10G).
７１ （６９）、５５ （３１）、４３（６６）実施例
１
トロピカルフルーツベース：
（重量部）
エチル ブチレート ２
５０エチル アミル ケトン ５
アリル ヘキサノエート １５
オレンゾ油 ベラ ９０％テルペンレス ｌＯペン
シル アルコール ４０ツメチ
ル ペンシル カルビニル ｎ−ブチレート５０フエニ
ルエチル イソ−バレレート２０γ−ウンデカ ラクト
ン ５マルトール
ｌバニリン
２ペンシル ベンゾエート
５０トリエチル シトレート
５２２上記トロピカルフルーツベース９７０！ｉ’
Ｊ１部に２．２．４−トリメチル−１−フェニル−３−
ペンタノン３０ｆｆｉｉ１部を加えることにより、力強
くグリーンなフルーツトーンが強調されたトロピカルフ
ルーツペースが得うれた０
実施例２
ゼラニウム油ペース：
（重量部）
ジメチル スルフィド ０．５ｅ
１ｍ−３−ヘキセノール ０．５ｔ
−リモネン ４０リ
ナロール ７０カ
リヨフイレン １０ターー
ネオール ２５シトラール
ｌＯゲラニル フォ
ーメート ６０シトロネリル フ
ォーメート １００ダラニル アセテ
ート ３０シトロネロール Ｅｘ
シトロネラ ２００ゲラニオール Ｅｘシ
トロネラ ３００ゲラニル ｎ−ブチレート
ｌＯオイゲノール
１ラブダナム レゾノイド
２・・−一リンＤ １）１３１
上記ゼラニウム油ベース９９０重量部に２．２，４−ト
リメチル−１−フェニル−３−ペンタノン１０重量部を
加えることによシ、よりナチュラル感のアップしたゼラ
ニウム油ベースが得られた。71 (69), 55 (31), 43 (66) Example 1 Tropical fruit base: (parts by weight) Ethyl butyrate 2
50 ethyl amyl ketone 5
Allyl hexanoate 15
Orenzo oil Vera 90% terpene-free lO pencil Alcohol 40 Methyl pencil Carvinyl n-butyrate 50 Phenylethyl Iso-valerate 20 γ-Undecalactone 5 Maltol
l vanillin
2 pencil benzoate
50 triethyl citrate
522 Above tropical fruit base 970! i'
2.2.4-trimethyl-1-phenyl-3- in J1 part
By adding 1 part of Pentanone 30ffii, a tropical fruit paste with strong green fruit tones was obtained.Example 2 Geranium oil paste: (parts by weight) Dimethyl sulfide 0.5e
1m-3-hexenol 0.5t
-Limonene 40 Linalool 70 Carillophyllene 10 Terneol 25 Citral
lO Geranyl Formate 60 Citronellyl Formate 100 Dalanyl Acetate 30 Citronellol Ex
Citronella 200 Geraniol Ex Citronella 300 Geranyl n-butyrate lO eugenol
1 labdanum resonoid
2...-1 Phosphorus D 1) 131 By adding 10 parts by weight of 2,2,4-trimethyl-1-phenyl-3-pentanone to 990 parts by weight of the above geranium oil base, geranium with a more natural feel can be obtained. An oil base was obtained.
１）バーコリンＤ（パーキュリーズ社商品名）二ロゾン
のメチルエステルの水添物
以上1) Vercolin D (trade name of Percules) Hydrogenated product of dilozone methyl ester or higher
Claims (1)
タノンを含有する香料組成物。A fragrance composition containing 1,2,2,4-trimethyl-1-phenyl-3-pentanone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3652387A JPS63203609A (en) | 1987-02-19 | 1987-02-19 | Perfume composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3652387A JPS63203609A (en) | 1987-02-19 | 1987-02-19 | Perfume composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63203609A true JPS63203609A (en) | 1988-08-23 |
Family
ID=12472166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3652387A Pending JPS63203609A (en) | 1987-02-19 | 1987-02-19 | Perfume composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63203609A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6204229B1 (en) * | 1997-03-18 | 2001-03-20 | Kao Corporation | Composition to be applied to hair or skin |
| EP1138755A3 (en) * | 2000-03-27 | 2002-06-12 | Takasago International Corporation | Aromatic bleaching agent composition |
| WO2005110961A1 (en) * | 2004-05-13 | 2005-11-24 | Firmenich Sa | Non-cyclic hindered ketones as perfuming ingredient |
| JP2006282627A (en) * | 2005-04-04 | 2006-10-19 | Takasago Internatl Corp | Stable composition for hair dye |
| US7494968B2 (en) | 2004-05-13 | 2009-02-24 | Firmenich Sa | Non-cyclic hindered ketones as perfuming ingredient |
-
1987
- 1987-02-19 JP JP3652387A patent/JPS63203609A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6204229B1 (en) * | 1997-03-18 | 2001-03-20 | Kao Corporation | Composition to be applied to hair or skin |
| EP1138755A3 (en) * | 2000-03-27 | 2002-06-12 | Takasago International Corporation | Aromatic bleaching agent composition |
| US6645254B1 (en) | 2000-03-27 | 2003-11-11 | Takasago International Corporation | Aromatic bleaching agent composition |
| WO2005110961A1 (en) * | 2004-05-13 | 2005-11-24 | Firmenich Sa | Non-cyclic hindered ketones as perfuming ingredient |
| JP2007537237A (en) * | 2004-05-13 | 2007-12-20 | フイルメニツヒ ソシエテ アノニム | Acyclic hindered ketones as perfuming ingredients |
| US7494968B2 (en) | 2004-05-13 | 2009-02-24 | Firmenich Sa | Non-cyclic hindered ketones as perfuming ingredient |
| JP2006282627A (en) * | 2005-04-04 | 2006-10-19 | Takasago Internatl Corp | Stable composition for hair dye |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS63203609A (en) | Perfume composition | |
| US5049544A (en) | Perfumery composition comprising 2-cyclohexylpropionic acid or its derivative | |
| JP3833347B2 (en) | Fragrance composition | |
| JP2001172666A (en) | Perfume composition | |
| JPS6270314A (en) | Method for increasing, modifying and improving perfume and aroma product | |
| JP2002155294A (en) | Method for imparting, improving, intensifying or modifying perfume property, perfume composition, perfumed product and unsaturated ester compound | |
| JPS62149797A (en) | Detergent composition | |
| JPS6456635A (en) | 2,2,4-trimethyl-1-phenyl-3-pentanol and perfume composition containing said compound | |
| JPS59130834A (en) | Manufacture of alkoxyacetic acid | |
| JP2000282084A (en) | Surfactant having excellent cleaning power | |
| JPS63203643A (en) | 1-cyclohexyl-2,2,4-trimethyl-3-pentanone and perfumery composition containing same | |
| JP3676394B2 (en) | Fragrance composition | |
| EP0181475B1 (en) | Unsaturated aliphatic ketone and its use as perfuming ingredient | |
| JPS63166853A (en) | 2-cyano-4-phenylpentane and perfumery composition containing the same | |
| DE60017910T2 (en) | ESTERS AND DIESTER OF 3-CYCLOHEXYL-2-METHYL-1-PROPANOL, THESE INCLUDING PERFUMED ARTICLES AND METHOD FOR ADDING A FRAGRANT COMPONENT | |
| JPS6087236A (en) | Bicyclic methylol derivative and perfume composition containing the same | |
| JPH0366637A (en) | 2-cyclohexylpropanol derivative and perfume composition containing the same | |
| JPH0359097A (en) | Perfume composition containing 2-cyclohexylpropyl acetate | |
| JPH0212935B2 (en) | ||
| JPS6078951A (en) | Novel schiff base and perfume composition containing the same | |
| JPS62270572A (en) | 3-substituted methyl-6-ethyl-5-oxatricyclo(4,2,1,03.7)nonane and perfume composition containing same | |
| JP2890000B2 (en) | 1- (2,6-dimethylphenyloxy) -2-alkanol and fragrance composition containing the same | |
| JPS6019738A (en) | Tricylic spiro compound | |
| JP2771241B2 (en) | Fragrance composition containing 3- and 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde diethyl acetal | |
| JPS6054936B2 (en) | Geometrically isomeric 5,5,8,8-tetramethyl- or 2,5,5,8,8-pentamethyl-decalins, their preparation and use |