JPS63193998A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JPS63193998A JPS63193998A JP2689887A JP2689887A JPS63193998A JP S63193998 A JPS63193998 A JP S63193998A JP 2689887 A JP2689887 A JP 2689887A JP 2689887 A JP2689887 A JP 2689887A JP S63193998 A JPS63193998 A JP S63193998A
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- liquid detergent
- thickener
- present
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims description 15
- 239000007788 liquid Substances 0.000 title claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000003021 water soluble solvent Substances 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 150000004676 glycans Chemical class 0.000 claims description 3
- 229920001282 polysaccharide Polymers 0.000 claims description 3
- 239000005017 polysaccharide Substances 0.000 claims description 3
- 239000003352 sequestering agent Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims 1
- 239000002904 solvent Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 3
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は液体洗剤組成物、とくに浴室やトイレ等に好適
に使用される液体洗剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a liquid detergent composition, particularly a liquid detergent composition suitable for use in bathrooms, toilets, etc.
浴室及びトイレには、脂肪酸金属塩、リン酸カルシウム
、油脂等を主成分とする汚れが付若しており、この汚れ
は日数の経過に伴ない、非常に除去しにくい汚れとなっ
ている。浴室及びトイレ用洗剤としては一般に次のよう
な条件が要求される。1)洗浄性が優れること。2)比
較的狭い閉鎖された室内で使用するため溶剤臭がないこ
と。Bathrooms and toilets are covered with stains mainly composed of fatty acid metal salts, calcium phosphate, fats and oils, and as time passes, this stain becomes extremely difficult to remove. The following conditions are generally required for detergents for bathrooms and toilets. 1) Excellent cleaning properties. 2) There is no solvent odor as it is used in a relatively small closed room.
3)浴室又はトイレの垂直面に滞留して洗浄するため粘
性を有すること04)浴室又はトイレの壁面に傷をつけ
ないこと。3) Must have viscosity to stay on the vertical surfaces of the bathroom or toilet for cleaning; 04) Must not damage the walls of the bathroom or toilet.
従来、浴室又はトイレ用の洗剤としては、水溶性溶剤と
酸性物質を含む弱酸性ないし強酸性の洗浄剤または増粘
剤により研摩剤を分散した洗剤等が一般に用いられてい
る。しかしながら、前者の場合は、溶剤臭が強く、また
酸性では増粘剤の安定性が悪く粘性のものが得られない
。後者の場合は、浴室又はトイレの壁面に研摩剤による
傷がつき易いと云う欠点があった。BACKGROUND ART Conventionally, as detergents for bathrooms or toilets, weakly acidic to strongly acidic detergents containing a water-soluble solvent and an acidic substance, or detergents in which an abrasive is dispersed with a thickening agent, etc. are generally used. However, in the former case, the solvent odor is strong, and the stability of the thickener is poor in acidic conditions, making it impossible to obtain a viscous product. In the latter case, the disadvantage is that the walls of the bathroom or toilet are easily scratched by the abrasive.
本発明者は上記の実情のもと、溶剤臭がなく、安定した
粘性を有し、壁面に傷をつけることなく、しかも洗浄力
のある浴室又はトイレ用の洗剤を得ることを目的として
種々検討を行なった結果・特定の溶剤、界面活性剤及び
金属イオン封鎖剤の組合せが浴室又はトイレ内の汚れ除
去作用に優れ、またこれと特定の増粘剤との組合せによ
り安定した粘性が得られることを知見した。本発明はこ
の知見に基づくものである。Under the above circumstances, the present inventor conducted various studies with the aim of obtaining a detergent for bathrooms or toilets that does not have a solvent odor, has stable viscosity, does not damage walls, and has cleaning power. As a result, the combination of a specific solvent, surfactant, and metal ion sequestering agent has an excellent effect on removing stains in bathrooms or toilets, and the combination of this and a specific thickener provides stable viscosity. I found out. The present invention is based on this knowledge.
以下、本発明の詳細な説明するに、本発明において水溶
性溶剤としては1CH3OC(CH3)2CH2CH2
OHの化学式で示される3−メチル3−メトキシブタノ
ールが用いられる。これはイソブチンとメタノールとか
ら合成され、分子内に水酸基とエーテル基を持っている
ので、有機溶剤及び水に対して混和することができる。Hereinafter, to explain the present invention in detail, in the present invention, the water-soluble solvent is 1CH3OC(CH3)2CH2CH2
3-Methyl 3-methoxybutanol, which has the chemical formula OH, is used. It is synthesized from isobutyne and methanol and has a hydroxyl group and an ether group in its molecule, so it is miscible with organic solvents and water.
また、溶解力が大きく、毒性がなく安全性が優れ、臭気
を残さない等の特徴力ある。これはクラレイソケミカル
■よりツルフィツトの名称で販売されている。In addition, it has great dissolving power, is non-toxic, has excellent safety, and does not leave behind any odor. This is sold by Kurareiso Chemical ■ under the name Tsurfit.
次に界面活性剤としては、とくに制限されるものではな
く、通常の陰イオン性界面活性剤、非イオン性界面活性
剤及びカチオン性界面活性剤の一種又は二種以上が用い
られる。また、キレート剤としても通常のものが用いら
れる。例えば、エチレンジアミンテトラ酢酸(EDTA
)のアルカリ塩、ニトリロトリ酢酸(NTA’)のアル
カリ塩、ハイドロオキシエチレンジアミン三酢酸(HE
DTA)のアルカリ塩等が挙げられ、とくにNTAのア
ルカリ塩(NTA−3Na )及びEDTAのアルカリ
塩が好ましく用いられる。Next, the surfactant is not particularly limited, and one or more of ordinary anionic surfactants, nonionic surfactants, and cationic surfactants can be used. Also, common chelating agents can be used. For example, ethylenediaminetetraacetic acid (EDTA)
), alkali salt of nitrilotriacetic acid (NTA'), hydroxyethylenediaminetriacetic acid (HE
Examples include alkali salts of NTA (NTA-3Na) and alkali salts of EDTA.
本発明の洗剤は、増粘剤を長期安定的に含むことを特徴
とする。増粘剤としては、ザンサンガム(粘質多糖)、
アクリル酸重合体、グアーガム、セルロースllE体、
フルギン酸誘導体、ビニール系高分子、無機系増粘剤等
が挙げられるが、本発明の洗剤中に最も安定して配合さ
れる好ましい増粘剤としては、ザンサンガム及びアクリ
ル酸重合体である。ザンサンガム(Xanthan G
um)とは微生物系天然増粘剤であり、Kelco D
ivision of Merk&CO,ノケルザンと
して販売されている。ケルザンは例エバ、グルコース2
個、マンノース2個およびグルフン酸1個を構成単位と
する結合ブロックの反復よりなる高分子量の多糖である
(別名、キサンタンガムとも云う)。また、アクリル酸
重合体としては例えば、和光純薬工業株式会社のノ・イ
ヒスワフー(架橋型アクリル酸重合)として販売されて
いる。The detergent of the present invention is characterized by containing a thickener stably over a long period of time. As a thickener, xanthan gum (viscous polysaccharide),
Acrylic acid polymer, guar gum, cellulose LLE,
Examples include fulgic acid derivatives, vinyl polymers, inorganic thickeners, etc., but xanthan gum and acrylic acid polymers are preferred thickeners that are most stably incorporated into the detergent of the present invention. Xanthan G
um) is a microbial natural thickener, Kelco D
It is sold as ``Ivision of Merk&CO'' and ``Nokerzan''. Kelsan is an example of Eva, Glucose 2
It is a high-molecular-weight polysaccharide consisting of repeating bonding blocks each consisting of 2 mannose, 2 mannose, and 1 glufonic acid (also known as xanthan gum). Further, as an acrylic acid polymer, for example, Wako Pure Chemical Industries, Ltd. sells it as NOIHISWAFU (cross-linked acrylic acid polymerization).
本発明の液体洗剤組成物中に占める上記各成分の配合割
合(以下%は全てit%を示す)は次の通りである。The proportions of the above-mentioned components in the liquid detergent composition of the present invention (all percentages hereinafter indicate it%) are as follows.
A)水溶性溶剤0.1〜20%、好ましくは1〜10%
B)界面活性剤0.1〜20%、好ましくは1〜lO%
C)金属イオン封鎖剤0.1〜20%、好ましくは1〜
10%
D)増粘剤0.1〜5%、好ましくは0.2〜3%更に
この必須成分の他に液状とするための水が必要である0
その他、必要に応じ香料、色素、防錆剤、防黴剤等を含
有することもできる。A) Water-soluble solvent 0.1-20%, preferably 1-10%
B) Surfactant 0.1-20%, preferably 1-10%
C) Sequestering agent 0.1-20%, preferably 1-20%
10% D) Thickener 0.1-5%, preferably 0.2-3% In addition to these essential ingredients, water is required to make it liquid.
In addition, fragrances, pigments, rust preventives, antifungal agents, etc. can also be contained as necessary.
本発明の洗剤は洗浄効果が優れ、溶剤臭はなく、粘性も
安定しており、とくに浴室、トイレ用洗剤として好適に
用いられる。また引火点、発火点が高く安全であり、毒
性もないので排水処理も容易である。The detergent of the present invention has an excellent cleaning effect, has no solvent odor, and has stable viscosity, and is particularly suitable for use as a detergent for bathrooms and toilets. Furthermore, it is safe with a high flash point and ignition point, and is non-toxic, making wastewater treatment easy.
次に、実施例により本発明を更に具体的に説明するが、
本発明はその要旨を越えない限り、以下の実施例に限定
されるものではない。なお実施例中の数字はfffi%
を示す。Next, the present invention will be explained in more detail with reference to Examples.
The present invention is not limited to the following examples unless it exceeds the gist thereof. In addition, the numbers in the examples are fffi%
shows.
実施例1
第1表に示す配合割合の組成物を調製した。調製方法と
しては、先ず水にツルフィツトとケルザン又はハイピス
ワ! −130を混合したのち、他の成分を適宜添加し
混合する。Example 1 A composition having the blending ratio shown in Table 1 was prepared. As for the preparation method, first add Turfitz and Kerzan or Hipiswa! to water. After mixing -130, other components are appropriately added and mixed.
第 1 表
湯桶、洗面器等に付着した汚れに対し両組放物を用いて
スポンジで軽くこすり、水を流したところ、汚れは完全
に除去された。とくに湯桶の壁面の場合、本組成物の粘
性は適度であり、洗浄が容易であった。また、溶剤臭は
ほとんどなかった〇両組酸物の粘・性の安定度について
測定したところ、50°Cにて6ケ月以上安定であった
。No. 1 When stains on the front bathtub, washbasin, etc. were lightly rubbed with a sponge using a double-sided parabolite and water was rinsed off, the stains were completely removed. Particularly in the case of the walls of the bathtub, the viscosity of this composition was appropriate and cleaning was easy. In addition, there was almost no solvent odor. When the stability of the viscosity and properties of the two-group acid was measured, it was stable for more than 6 months at 50°C.
Claims (1)
して含有することを特徴とする液体洗剤組成物。 A)CH_3OC(CH_3)_2CH_2CH_2O
Hの化学式で示される水溶性溶剤 B)界面活性剤 C)金属イオン封鎖剤 D)増粘剤 2)特許請求の範囲第一項記載の増粘剤がザンサンガム
(粘質多糖)及び/又はアクリル酸重合体よりなる液体
洗剤組成物。[Scope of Claims] 1) A liquid detergent composition characterized by containing the following A), B), C) and D) as essential components. A) CH_3OC(CH_3)_2CH_2CH_2O
Water-soluble solvent represented by the chemical formula H B) Surfactant C) Sequestering agent D) Thickener 2) The thickener described in claim 1 is xanthan gum (viscous polysaccharide) and/or acrylic A liquid detergent composition comprising an acid polymer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2689887A JPS63193998A (en) | 1987-02-07 | 1987-02-07 | Liquid detergent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2689887A JPS63193998A (en) | 1987-02-07 | 1987-02-07 | Liquid detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63193998A true JPS63193998A (en) | 1988-08-11 |
Family
ID=12206057
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2689887A Pending JPS63193998A (en) | 1987-02-07 | 1987-02-07 | Liquid detergent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63193998A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06340892A (en) * | 1993-05-28 | 1994-12-13 | Miyoshi Oil & Fat Co Ltd | Flux-cleaning agent |
JPH06346094A (en) * | 1993-06-02 | 1994-12-20 | Kuraray Co Ltd | Non-flammable cleanser composition |
US5424010A (en) * | 1993-01-06 | 1995-06-13 | Duliba; Edward P. | Light duty liquid detergent composition containing 3-methyl-3-methoxy-butanol |
US5587022A (en) * | 1993-12-07 | 1996-12-24 | Black; Robert H. | Method of rinsing showers |
US5837664A (en) * | 1996-07-16 | 1998-11-17 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
US5910474A (en) * | 1995-05-11 | 1999-06-08 | Black; Robert H. | Method of rinsing showers clean |
-
1987
- 1987-02-07 JP JP2689887A patent/JPS63193998A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5424010A (en) * | 1993-01-06 | 1995-06-13 | Duliba; Edward P. | Light duty liquid detergent composition containing 3-methyl-3-methoxy-butanol |
JPH06340892A (en) * | 1993-05-28 | 1994-12-13 | Miyoshi Oil & Fat Co Ltd | Flux-cleaning agent |
JPH06346094A (en) * | 1993-06-02 | 1994-12-20 | Kuraray Co Ltd | Non-flammable cleanser composition |
US5587022A (en) * | 1993-12-07 | 1996-12-24 | Black; Robert H. | Method of rinsing showers |
US5910474A (en) * | 1995-05-11 | 1999-06-08 | Black; Robert H. | Method of rinsing showers clean |
US5837664A (en) * | 1996-07-16 | 1998-11-17 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
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