JPS63191871A - Ink composition - Google Patents
Ink compositionInfo
- Publication number
- JPS63191871A JPS63191871A JP62218600A JP21860087A JPS63191871A JP S63191871 A JPS63191871 A JP S63191871A JP 62218600 A JP62218600 A JP 62218600A JP 21860087 A JP21860087 A JP 21860087A JP S63191871 A JPS63191871 A JP S63191871A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- acid
- parts
- printing
- rosin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 amine compound Chemical class 0.000 claims description 17
- 239000002966 varnish Substances 0.000 abstract description 8
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 7
- 150000001412 amines Chemical class 0.000 abstract description 7
- 229920006122 polyamide resin Polymers 0.000 abstract description 7
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract description 5
- 229920000768 polyamine Polymers 0.000 abstract description 5
- 239000006229 carbon black Substances 0.000 abstract description 3
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 abstract description 2
- 239000002274 desiccant Substances 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 60
- 238000000034 method Methods 0.000 description 12
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920002379 silicone rubber Polymers 0.000 description 4
- 239000004945 silicone rubber Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 125000005375 organosiloxane group Chemical group 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は、インキ組成物、特に水なし平版印刷において
、好適に使用されるインキ組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an ink composition, particularly an ink composition suitably used in waterless lithographic printing.
[従来技術]
現在の印刷の主流をなす湿し水によるインキ反撥性を利
用した平版印刷法に対して、かかる湿し水を必要としな
い平版印刷法を使用する水なし平版印刷法が提案され、
特にシリコーンゴムを非画線部に設けた平版印刷用刷版
を用いて印刷する方法が実用化されている。[Prior Art] In contrast to the current mainstream printing method, which uses the ink repellency of dampening water, a waterless planographic printing method has been proposed that uses a planographic printing method that does not require dampening water. ,
In particular, a method of printing using a lithographic printing plate provided with silicone rubber in the non-image area has been put into practical use.
このような水なし平版印刷において、従来の油性インキ
を用いて印刷すると、地汚れが発生して好ましくないと
いうことが知られている。In such waterless planographic printing, it is known that printing using conventional oil-based inks causes background smearing, which is undesirable.
水なし平版印刷における地汚れ発生という現象は印刷中
に印刷機の駆動部やローラの摩擦に起因して版面温度が
上昇し、インキ自体の凝集力が低下してしまい、本来イ
ンキ反撥性であるべき非画線部にインキが付着するもの
でおる。The phenomenon of background smudge in waterless planographic printing is caused by the friction of the drive unit and rollers of the printing press during printing, which causes the plate surface temperature to rise and the cohesive force of the ink itself to decrease, which is due to its inherent ink repellency. Ink adheres to the non-image areas.
これを改良するためにバインダー樹脂成分を多く使用し
て凝集力を上げ耐地汚れ性を改良する方法が考えられる
が、この方法ではブランケットへのパイリングや紙ムケ
等のトラブルが発生する。In order to improve this problem, a method can be considered in which a large amount of binder resin component is used to increase the cohesive force and improve soil stain resistance, but this method causes problems such as pile-up on the blanket and paper smearing.
また別の改良方法としては、特開昭57−12077号
公報におるような有機粘土を用いる方法がおる。しかし
ながら、この方法は耐地汚れ性を高めようとした場合、
光沢の低下や印刷適性が悪化する等の問題を生じる。ざ
らに特開昭59−147072号公報、特公昭50−1
1287号公報にはオルガノシロキサンを添加する方法
が提案されている。しかしながら、前者はすでに印刷イ
ンキとなっているものに添加して使用するものであり、
後者はインキ製造段階で添加するものであるが、いずれ
もインキに強い凝集力を与える目的で使用されるもので
ある。しかしこの方法を用いて高い耐地汚れ性を達成し
ようとすると、インキの転移性が極めて悪くなるという
問題点があり、また、追刷時のインキの乗り、あるいは
フィルムラミネート加工が添加したオルガノシロキサン
のブリードアウトによって不可能になる等の問題点が生
じる。Another improvement method is to use organic clay as disclosed in Japanese Patent Application Laid-Open No. 57-12077. However, when trying to improve stain resistance with this method,
Problems such as reduction in gloss and deterioration of printability occur. Zarani JP 59-147072, JP 50-1
Japanese Patent No. 1287 proposes a method of adding organosiloxane. However, the former is used by adding it to what is already a printing ink,
The latter is added during the ink production stage, and both are used for the purpose of imparting strong cohesive force to the ink. However, when trying to achieve high stain resistance using this method, there is a problem that the ink transfer property becomes extremely poor, and there is also a problem that the ink transfer during reprinting or the film lamination process is caused by the addition of organosiloxane. Problems arise, such as the bleed-out of the
ざらに市販のインキ添加剤としてオロテイクス5040
(大日精化(株)製)にポリアミド分子が使用されて
いる。オロテイクス5040は湿し水を使用する版式の
インキに対する効果として、湿し水に対する抵抗が高ま
り、インキが乳化しにくくなる。従って、乳化による地
汚れ、浮き汚れ等を防止する等の特長が示されている。Orotakes 5040 as a commercially available ink additive
(manufactured by Dainichiseika Co., Ltd.) uses polyamide molecules. Orotake 5040 has the effect of increasing resistance to dampening water and making it difficult for the ink to emulsify compared to plate-type inks that use dampening water. Therefore, it has been shown to have the advantage of preventing background stains, floating stains, etc. caused by emulsification.
・またオロテイクス5040中のポリアミド分子の効果
として、空気中の湿気や湿し水分子と重合し、インキの
セット、乾燥を促進し裏付を防止する等の効果が示され
ている。-Also, the polyamide molecules in Orotakes 5040 have been shown to polymerize with moisture in the air and dampening water molecules, promote ink setting and drying, and prevent backing.
しかしながら、このオロティクス5040を水なし平版
用インキに添加して印刷した場合、インキの転移性、機
上安定性等の改良効果は認められるが、耐地汚れ性の向
上には効果がなく、添加前のインキより耐地汚れ性が低
下する問題点がある。However, when Orotix 5040 is added to a waterless lithographic ink for printing, it is found to be effective in improving ink transferability, on-press stability, etc., but it is not effective in improving background stain resistance. There is a problem that the stain resistance is lower than the previous ink.
[発明が解決しようとする問題点]
本発明の目的は、上述の従来インキの諸欠点を解消し、
耐地汚れ性に優れ、印刷適性の優れたインキ組成物を提
供することにある。[Problems to be Solved by the Invention] The purpose of the present invention is to solve the above-mentioned drawbacks of conventional inks,
An object of the present invention is to provide an ink composition that has excellent background stain resistance and printability.
[問題点を解決するための手段]
かかる本発明の目的は、分子中に活性水素を含有するア
ミン化合物を0.1〜15重但%含有することを特徴と
するインキ組成物によって達成される。[Means for Solving the Problems] The object of the present invention is achieved by an ink composition characterized by containing 0.1 to 15% by weight of an amine compound containing active hydrogen in the molecule. .
本発明において用いられる活性水素を含有するアミン化
合物としては、エチルアミン、n−プロピルアミン、n
−ブチルアミン、ヘキシルアミン、ラウリルアミン、ス
テアリルアミン、エタノールアミン、アリルアミン等の
モノアミン、エチレンジアミン、トリメチレンジアミン
、テトラメヂレンジアミン、ペンタメチレンジアミン、
ヘキサメチレンジアミン等のジアミン、ジエチレントリ
アミン、トリエチレンテトラアミン、ビスヒドロキシジ
エチレントリアミンなどのポリアミンやアミンアダクト
等が有効に使用できる。The active hydrogen-containing amine compounds used in the present invention include ethylamine, n-propylamine, n-
- Monoamines such as butylamine, hexylamine, laurylamine, stearylamine, ethanolamine, allylamine, ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine,
Diamines such as hexamethylene diamine, polyamines such as diethylenetriamine, triethylenetetraamine, bishydroxydiethylenetriamine, and amine adducts can be effectively used.
また、アミン誘導体としてのアミド化合物としては、ギ
酸、酢酸、プロピオン酸、イタコン酸、カプリル酸、グ
リコール酸、アクリル酸、ラウリン酸、ミリスチン酸、
パルミチン酸、ステアリン酸、オレイン酸、リノール酸
、リルイン酸等のモノカルボン酸、マロン酸、コハク酸
、グルタル酸、アジピン酸、ピメリン酸、スペリン酸、
アゼライン酸、セバシン酸、マレイン酸、フマール酸、
ダイマー酸等の有機ジカルボン酸、トリメリット酸等の
有機トリカルボン酸、3,9−ビス(2カルボキシアル
キル) 2,4,8.10−テトラオキサスピロウン
デカン等の有機カルボン酸と前記のアミン、ジアミン、
ポリアミン等との縮合物が挙げられる。In addition, amide compounds as amine derivatives include formic acid, acetic acid, propionic acid, itaconic acid, caprylic acid, glycolic acid, acrylic acid, lauric acid, myristic acid,
Monocarboxylic acids such as palmitic acid, stearic acid, oleic acid, linoleic acid, lyluic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, superric acid,
azelaic acid, sebacic acid, maleic acid, fumaric acid,
Organic dicarboxylic acids such as dimer acid, organic tricarboxylic acids such as trimellitic acid, organic carboxylic acids such as 3,9-bis(2carboxyalkyl)2,4,8.10-tetraoxaspiroundecane, and the above amines and diamines. ,
Examples include condensates with polyamines and the like.
本発明に用いられる活性水素を含有するアミン化合物は
上述ような構造組成のものであるが、取扱い安全性等を
考慮すると、ポリアミド樹脂が好ましく、樹脂、溶剤と
の相溶性の点から炭素数6〜60の酸とポリアミンから
なるポリアミド樹脂が特に好ましく用いられる。The amine compound containing active hydrogen used in the present invention has the above-mentioned structural composition, but from the viewpoint of handling safety, polyamide resin is preferable, and from the viewpoint of compatibility with the resin and solvent, a polyamide resin having 6 carbon atoms is preferable. A polyamide resin consisting of a polyamine and an acid of 1 to 60% is particularly preferably used.
上記ポリアミド樹脂の分子量としては500〜20.0
00の範囲が好ましく、より好ましくは500〜10,
000の範囲でおる。The molecular weight of the polyamide resin is 500 to 20.0.
The range is preferably 00, more preferably 500 to 10,
It is in the range of 000.
これらの活性水素を含有するアミン化合物の添加量とし
ては0.1〜15重四%の範囲を選択する必要がおり、
より好ましくは0.3〜10重量%である。添加量が0
.1重量%未満では耐地汚れ性向上の効果が小さく、1
5%を越える場合はインキの転移性に問題が生じる。It is necessary to select the amount of the amine compound containing these active hydrogens in the range of 0.1 to 15% by weight,
More preferably, it is 0.3 to 10% by weight. Added amount is 0
.. If it is less than 1% by weight, the effect of improving dirt resistance is small;
If it exceeds 5%, problems arise with the transferability of the ink.
本発明のアミン化合物、すなわちアミンあるいはアミド
化合物は、単独のみならず、2種以上併用の場合も有効
であり、かつアミン化合物を反応性のない溶剤、樹脂等
で希釈しても有効に使用することができる。The amine compound of the present invention, that is, the amine or amide compound, is effective not only alone but also when used in combination of two or more, and can be used effectively even if the amine compound is diluted with a non-reactive solvent, resin, etc. be able to.
本発明のインキ組成物において、使用されるインキ組成
物用ビヒクルの他の構成成分としては、公知のもの、た
とえば、ロジン、ロジンエステル、フェノール樹脂、ロ
ジン変成フェノール樹脂、石油樹脂、アルキッド樹脂、
マレイン酸樹脂、キシレン樹脂、ウレタン樹脂、エポキ
シ樹脂、乾性油、スチレン、アクリル酸エステル、ウレ
タンアクリレート、ポリエステルアクリレート、エポキ
シアクリレート、ポリエーテルアクリレートなどが使用
できる。特にロジン変性フェノール樹脂、キシレン樹脂
、石油樹脂、マレイン酸樹脂、エポキシ樹脂、ポリエス
テルアクリレート、ポリエーテルアクリレート、エポキ
シアクリレートが好ましい。In the ink composition of the present invention, other components of the ink composition vehicle used are known ones, such as rosin, rosin ester, phenol resin, rosin-modified phenol resin, petroleum resin, alkyd resin,
Maleic acid resin, xylene resin, urethane resin, epoxy resin, drying oil, styrene, acrylic ester, urethane acrylate, polyester acrylate, epoxy acrylate, polyether acrylate, etc. can be used. Particularly preferred are rosin-modified phenolic resins, xylene resins, petroleum resins, maleic acid resins, epoxy resins, polyester acrylates, polyether acrylates, and epoxy acrylates.
また、着色剤としては、無機ないし有機系顔料などの従
来のインキ組成物において使用されているのを使用する
ことができる。Furthermore, as the colorant, those used in conventional ink compositions such as inorganic or organic pigments can be used.
ざらに、その他の添加剤としては、たとえば、ワックス
、グリース、乾燥剤、分散剤、充填材、その他の公知の
ものを使用することができる。In addition, as other additives, for example, wax, grease, desiccant, dispersant, filler, and other known additives can be used.
アミン化合物を添加するにあたっては、インキの製造の
中間工程において、アミン化合物と他のビヒクル構成成
分とからワニスを製造し、ついでこのワニスをベースに
してインキ化してもよいし、あるいはまた、他の構成成
分から作りあげたインキに添加してもよい。When adding an amine compound, it is possible to prepare a varnish from the amine compound and other vehicle components in an intermediate step of ink production, and then to form an ink based on this varnish, or alternatively, to add other vehicle components. It may also be added to ink made from the constituent components.
本発明のインキ組成物は、特に水なし平版印刷用インキ
として好適に使用されるが、勿論公知の他のインキ組成
物、たとえばU■インキ、電子線で硬化するEBキュア
インキ、湿し水を用いる平版印刷用のインキ等にも有効
に使用できる。The ink composition of the present invention is particularly suitable for use as an ink for waterless lithographic printing, but of course other known ink compositions such as U ink, EB cure ink cured by electron beam, and dampening solution may also be used. It can also be effectively used in lithographic printing inks.
また、印刷用途でみた場合、合成紙用、フィルム用、金
属用などの印刷に使用できる。Also, in terms of printing applications, it can be used for printing on synthetic paper, film, metal, etc.
「実施例コ 以下、実施例により本発明を具体的に説明する。"Example code" Hereinafter, the present invention will be specifically explained with reference to Examples.
実施例1
下記の組成でアミン化合物トリエチレンテトラアミンを
含むインキ(A>と、含まないインキ−B)とを作った
。耐地汚れ性の尺度である地汚れ発生温度を測定したと
ころ、インキ(A>は33℃であったのに対して、イン
キ(B)は25℃でおり、耐地汚れはアミン化合物トリ
エチレンテトラアミンを含むインキ(A)の方が優れて
いることがわかった。Example 1 Inks containing the amine compound triethylenetetraamine (A> and ink B not containing it) were prepared with the following compositions. When we measured the temperature at which scumming occurred, which is a measure of scumming resistance, ink (A>) had a temperature of 33°C, while ink (B) had a temperature of 25°C. Ink (A) containing tetraamine was found to be superior.
これらのインキのそれぞれについて、小点スプリント平
版印刷機で版面へ湿し水を供給することなしに、シリコ
ーンゴムよりなる非粘着層を有する水なし平版を用いて
印刷を行なった。For each of these inks, printing was carried out using a waterless planographic plate having a non-adhesive layer made of silicone rubber, without supplying dampening water to the plate surface, using a dot sprint planographic printing machine.
その結果、両者ともインキ着肉性、光沢などが良好な印
刷物が得られた。As a result, printed matter with good ink receptivity, gloss, etc. was obtained in both cases.
インキAニトリエチレンテトラアミンを含むインキ。Ink A An ink containing nitriethylenetetraamine.
印刷インキ用カーボンブラック 18.0部アルカリブ
ル−トナー ’5.0部ロジン変性フェノール
樹脂ワニス(I)34.0部
ロジン変性フェノール樹脂ゲルワニス(n)20.0部
トリエチレンテトラミン 1.0部ワックスコ
ンパウンド 3.0部ナフテン酸コバルト塩
0.5部(金属濃度7.5%)
ナフテン酸マンガン塩 0.5部(金属濃度
6.5%)
1石5号ソルベント 5.0部計 1
00.0部
上記混合物を三本ロールを用いて練りあげたところ、イ
ンコメ−ター、タック11.8 (400r、p、m
、30℃の1分値)の乾式平版用インキが得られた。Carbon black for printing ink 18.0 parts Alkaline blue toner '5.0 parts Rosin-modified phenolic resin varnish (I) 34.0 parts Rosin-modified phenolic resin gel varnish (n) 20.0 parts Triethylenetetramine 1.0 parts Wax Compound 3.0 parts Cobalt naphthenate 0.5 parts (metal concentration 7.5%) Manganese naphthenate 0.5 parts (metal concentration 6.5%) 1 stone No. 5 solvent 5.0 parts Total 1
00.0 parts The above mixture was kneaded using a three-roll mill, and the result was a tack of 11.8 (400 r, p, m) on an incometer.
, 1 minute value at 30° C.) was obtained.
ロジン変性フェノール樹脂ワニス(I)の処方。Formulation of rosin-modified phenolic resin varnish (I).
ロジン変性アルキルフェノール樹脂
42.0部
重合アマニ油4号 15.0部アマニ油変
性アルキッド樹脂 5.0部日石5号ソルベント
38.0部計 100.0部
ロジン変性フェノール樹脂ゲルワニス(II)の処方。Rosin modified alkylphenol resin 42.0 parts Polymerized linseed oil No. 4 15.0 parts Linseed oil modified alkyd resin 5.0 parts Nisseki No. 5 solvent
38.0 parts Total: 100.0 parts Formula of rosin-modified phenolic resin gel varnish (II).
ロジン変性アルキルフェノール樹脂
45.0部
重合アマニ油4号 17.0部アルミニウ
ムオクトエート 1.5部1石5号ソルベント
36.5部計 100.0部
インキB:アミン化合物を含まないインキ印刷インキ用
カーボンブラック 18.0部アルカリブルートナー
5.0部ロジン変性フェノール樹脂ワニス(
II)35.0部
ロジン変性フェノール樹脂グルワニス(n)20.0部
ワックスコンパウンド 3.0部ナフテン酸
コバルト塩 0.5部(金属濃度7.5%)
ナフテン酸マンガン塩 0.5部(金属濃度
6.5%)
1石5号ソルベント 5.0部計 1
00.0部
上記の混合物を三本ロールを用いて練り上げたところ、
インコメ−ター・タック14.5のインキが得られた。Rosin-modified alkylphenol resin 45.0 parts Polymerized linseed oil No. 4 17.0 parts Aluminum octoate 1.5 parts 1 stone No. 5 solvent
36.5 parts Total 100.0 parts Ink B: Ink that does not contain amine compounds Carbon black for printing ink 18.0 parts Alkaline blue toner
5.0 parts rosin modified phenolic resin varnish (
II) 35.0 parts Rosin modified phenolic resin Gluwanis (n) 20.0 parts Wax compound 3.0 parts Cobalt naphthenate 0.5 part (metal concentration 7.5%) Manganese naphthenate 0.5 part (metal Concentration 6.5%) 1 stone No. 5 solvent 5.0 parts total 1
00.0 parts When the above mixture was kneaded using three rolls,
An ink with an index tack of 14.5 was obtained.
耐地汚れ性の評価法(地汚れ発生指数の測定)版胴に温
水を通じて版面を昇温できるように改造した印刷機に、
シリコーンゴムよりなる非粘着性層を有する水なし平版
刷版をとりつけ、湿し水を供給することなしに、版面を
昇温しながら印刷し、一定のベタ濃度において印刷物に
地汚れが発生した際の版面温度を地汚れ発生指数とした
。地汚れ発生指数の高いインキはど実用印刷において地
汚れが発生しにくい。Method for evaluating background stain resistance (measurement of background stain occurrence index) A printing machine modified to raise the temperature of the plate surface by passing hot water into the plate cylinder.
When a waterless lithographic printing plate with a non-adhesive layer made of silicone rubber is attached and printing is performed while increasing the temperature of the plate surface without supplying dampening water, scumming occurs on the printed matter at a certain solid density. The plate surface temperature was taken as the background stain occurrence index. Ink with a high background smudge occurrence index is less likely to cause background smear in practical printing.
実施例2、比較例1
実施例1のインキAの組成でトリエチレンテトラミンの
代りに、ダイマー酸とジエチレントリアミンを縮合させ
て得られたポリアミド樹脂(分子量3000)を使用し
てインキCを得た。Example 2, Comparative Example 1 Ink C was obtained by using a polyamide resin (molecular weight 3000) obtained by condensing dimer acid and diethylenetriamine in place of triethylenetetramine in the composition of Ink A of Example 1.
また、実施例1のインキ組成でトリエチレンテトラミン
の代りに、市販のポリアミド含有インキ添加剤゛オロテ
イクス5040 ”を5部加え、また1石5号ソルベン
トを5部から1部に変・更したインキDを得た。Furthermore, in the ink composition of Example 1, 5 parts of a commercially available polyamide-containing ink additive "Orotakes 5040" was added instead of triethylenetetramine, and 1 part No. 5 solvent was changed from 5 parts to 1 part. I got a D.
インキC、インキDの地汚れ発生指数を測定したところ
、インキCは35℃、インキDは25℃であった。When the scumming index of Ink C and Ink D was measured, Ink C was 35°C and Ink D was 25°C.
インキCはインキBと比較して耐地汚れ性が向上してい
るのに対し、インキDはインキBと同じ耐地汚れ性を示
すにすぎなかった。Ink C had improved background smudge resistance compared to Ink B, whereas Ink D only showed the same background smear resistance as Ink B.
また、小点スプリント平版印刷機で版面へ湿し水を供給
することなしに、シリコーンゴムよりなる非粘着性層を
有する水なし平版を用いて印刷を行なった。インキの転
移性、着肉性、光沢などの良好な印刷物が得られた。Further, printing was carried out using a waterless planographic plate having a non-adhesive layer made of silicone rubber without supplying dampening water to the plate surface using a small dot sprint planographic printing machine. Printed matter with good ink transferability, ink receptivity, and gloss was obtained.
実施例3、比較例2
市販の水あり平版用インキに、ダイマー酸とジエチレン
トリアミンを縮合させて1qられたポリアミド樹脂(分
子15000)をそれぞれ1部加えて次のようなインキ
を作った。Example 3, Comparative Example 2 The following inks were prepared by adding 1 part of a polyamide resin (molecules 15,000) prepared by condensing dimer acid and diethylenetriamine to each of commercially available water-based lithographic inks.
インキE:フイルム用のインキであるTSP202(東
洋インキ(株)製)に加えたもの。Ink E: Added to TSP202 (manufactured by Toyo Ink Co., Ltd.), which is an ink for film.
インキF:UVキュアインキFD−o(東洋インキ(株
)製)に加えたもの。Ink F: Added to UV cure ink FD-o (manufactured by Toyo Ink Co., Ltd.).
上記のインキの地汚れ指数を測定したところ表に示すよ
うに耐地汚れ性が大きく向上した。When the scumming index of the above ink was measured, as shown in the table, the scumming resistance was greatly improved.
実施例1と同様に印刷テストを行なったところ、添加前
のインキはそれぞれ地汚れしたのに対し、インキEおよ
びFは地汚れもなく印刷できた。When a printing test was conducted in the same manner as in Example 1, each ink before addition had scumming, whereas ink E and F could be printed without scumming.
[発明の効果]
本発明よるアミン化合物を含有するインキ組成物は、耐
地汚れ性が良好で、かつ印刷適性の優れたものとなる。[Effects of the Invention] The ink composition containing the amine compound according to the present invention has good background stain resistance and excellent printability.
Claims (1)
5重量%含有することを特徴とするインキ組成物。0.1 to 1 amine compound containing active hydrogen in the molecule
An ink composition characterized by containing 5% by weight.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61-203626 | 1986-09-01 | ||
JP20362686 | 1986-09-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63191871A true JPS63191871A (en) | 1988-08-09 |
JPH0627274B2 JPH0627274B2 (en) | 1994-04-13 |
Family
ID=16477157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62218600A Expired - Fee Related JPH0627274B2 (en) | 1986-09-01 | 1987-09-01 | Waterless planographic printing ink composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0627274B2 (en) |
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JPS60115673A (en) * | 1983-11-25 | 1985-06-22 | Mitsubishi Pencil Co Ltd | Oil based ink |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7722715B2 (en) * | 2004-04-06 | 2010-05-25 | Ciba Specialty Chemicals Corporation | Pigment compositions for inks with improved rheology |
JP2006224586A (en) * | 2005-02-21 | 2006-08-31 | Hokkai Can Co Ltd | Seamless can body |
JP2006224585A (en) * | 2005-02-21 | 2006-08-31 | Hokkai Can Co Ltd | Seamless can |
JP2006224584A (en) * | 2005-02-21 | 2006-08-31 | Hokkai Can Co Ltd | Seamless can |
Also Published As
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---|---|
JPH0627274B2 (en) | 1994-04-13 |
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