JPS63190744A - Glass panel applied with electron beam and its production - Google Patents
Glass panel applied with electron beam and its productionInfo
- Publication number
- JPS63190744A JPS63190744A JP2321687A JP2321687A JPS63190744A JP S63190744 A JPS63190744 A JP S63190744A JP 2321687 A JP2321687 A JP 2321687A JP 2321687 A JP2321687 A JP 2321687A JP S63190744 A JPS63190744 A JP S63190744A
- Authority
- JP
- Japan
- Prior art keywords
- ions
- glass
- panel
- irradiated
- electron beam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 52
- 238000010894 electron beam technology Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 19
- 229910001419 rubidium ion Inorganic materials 0.000 claims abstract description 12
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract description 10
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 150000003839 salts Chemical class 0.000 claims abstract description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 16
- 229910001414 potassium ion Inorganic materials 0.000 claims description 11
- 229910052792 caesium Inorganic materials 0.000 claims description 10
- -1 cesium ions Chemical class 0.000 claims description 9
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 8
- 239000005361 soda-lime glass Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 238000005342 ion exchange Methods 0.000 claims description 4
- 238000006124 Pilkington process Methods 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 3
- 235000011941 Tilia x europaea Nutrition 0.000 abstract description 3
- 239000004571 lime Substances 0.000 abstract description 3
- 229910052700 potassium Inorganic materials 0.000 abstract description 3
- 229910052701 rubidium Inorganic materials 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000006121 base glass Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 8
- 238000009125 cardiac resynchronization therapy Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- NCMHKCKGHRPLCM-UHFFFAOYSA-N caesium(1+) Chemical compound [Cs+] NCMHKCKGHRPLCM-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 241000270666 Testudines Species 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical class [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
Landscapes
- Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
- Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は陰極線管（本明細書においてＣＲＴと記す）等
のごとき電子線が照射されるガラスパネル及びその製造
方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a glass panel that is irradiated with an electron beam, such as a cathode ray tube (herein referred to as CRT), and a method for manufacturing the same.
従来、ＣＲＴのガラスパネルは電子線が照射されること
による着色（以下、ブラウニングと記す）を低減するた
め、Ｓｒ、Ｂａ＋Ｃｅ等の元素を含有する特定の組成の
ガラスを溶融し、成形型にそのゴブを供給し、プレス成
形した後、ガラスパネル面を研磨して平滑な面を形成す
ることにより製造された。Conventionally, in order to reduce coloration (hereinafter referred to as browning) caused by electron beam irradiation, glass panels for CRTs are melted with a specific composition of glass containing elements such as Sr, Ba+Ce, etc., and then placed in a mold. After supplying gobs and press-molding, the glass panel surface was polished to form a smooth surface.
〔発明が解決しようとする問題点〕
前記ＣＲＴのガラスパネルは特定の組成のガラスを溶解
する専用の窯が必要であったり、プレス成形後の研磨が
必要となり、コストが高くなったり、また生産性に問題
があった。[Problems to be Solved by the Invention] The CRT glass panel requires a special kiln to melt glass of a specific composition, and requires polishing after press molding, which increases costs and reduces production. There was a problem with sexuality.
また、約ＪＫｇ−ｆ／ｃｄ以上の耐圧強度をえるために
ガラスの厚さを厚くする必要が有り、重ｆが重くなる傾
向があった。Further, in order to obtain a pressure resistance of approximately JKg-f/cd or more, it was necessary to increase the thickness of the glass, which tended to increase the weight f.
ソーダ・ライム・シリカのガラス板を用いて、ＣＲＴの
パネルは成形できるが、これは電子線の照射によりブラ
ウニングが生じる欠点があった。CRT panels can be molded using soda-lime-silica glass plates, but this has the drawback of browning caused by electron beam irradiation.
〔問題を解決するための手段〕 。[Means for solving problems].
前記問題点を解決すべく、本発明に係るガラスパネルは
市販のソーダ・ライム・シリカガラス板をｍいて成形し
たパネルの少なくとも電子線が照射される表面のナトリ
ウムイオンをカリウムイオン、ルビジウムイオン、およ
びセシウムイオンの少なくとも一種とリチウムイオンと
に置換したものである。In order to solve the above-mentioned problems, the glass panel according to the present invention is made by molding a commercially available soda-lime-silica glass plate, and replaces sodium ions on at least the surface that is irradiated with electron beams with potassium ions, rubidium ions, and At least one type of cesium ion and lithium ion are substituted.
前記ソーダ・ライム・シリカガラスは、フロート法で製
造されたものであり、その組成が重１％で表示して、５
ｉ０２６９〜７３％、ＡＩ！２０３０．ｊ 〜／、３％
＊ Ｆｅ２Ｏ３０へ０ 、 ／ ｊ％、ＣａＯ７〜／４
！％ｌＭｇＯＯ〜Ｌｊ％、Ｎａ２Ｏ／２〜＃％、に２ｏ
ｏ〜八よ％ 、 Ｔｉ０２０−０．／％＋ＳＯ３（７へ
Ｏ，Ｓ％の範囲であり、がっ、電子線が照射されるガラ
ス表面が、１０−トバス（７）溶融錫に接触する面と反
対側の面で有る事が好ましい。The soda lime silica glass is manufactured by the float method, and its composition is expressed as 1% by weight.
i0269~73%, AI! 2030. j ~/, 3%
*0 to Fe2O30, /j%, CaO7~/4
! %lMgOO~Lj%, Na2O/2~#%, 2o
o~8%, Ti020-0. /% + SO3 (7 to O, S% range, it is preferable that the glass surface to which the electron beam is irradiated is the surface opposite to the surface that contacts the molten tin of 10-Tobath (7) .
れたリチウムイオンは酸化リチウムとして存在するが、
該酸化リチウムは、少なくとも電子線が照射されるガラ
ス表面から１０μｍの深さの範囲での平均重量％が、０
．１〜３％の範囲であるのが好ましい。Lithium ions exist as lithium oxide, but
The lithium oxide has an average weight % of 0 at least in a depth of 10 μm from the glass surface where the electron beam is irradiated.
．． It is preferably in the range of 1 to 3%.
上記のようなパネルはソーダ・ライム・シリカガラス板
をＣＲＴ等の所望形状に成形し、ａ３ｏ”ｃ乃至ａｑｏ
℃のカリウムイオン、ルビジウムイオンおよびセシウム
イオンの少なくとも一種とリチウムイオンを含む溶融塩
中に、ｏ、ｒ時間乃至１時間浸漬し、該パネル表面のナ
トリウムイオンをカリウムイオン、ルビジウムイオン、
およびセシウムイオンの少なくとも一種とリチウムイオ
ンとに、一度のイオン交換で置換することによって得ら
れる。The above panel is made by molding a soda lime silica glass plate into a desired shape such as a CRT.
The panel is immersed in a molten salt containing at least one of potassium ions, rubidium ions, and cesium ions and lithium ions at ℃ for 0 to 1 hour to convert the sodium ions on the surface of the panel into potassium ions, rubidium ions, and lithium ions.
It can be obtained by replacing at least one type of cesium ion with lithium ion in a single ion exchange.
ｍｔＪ 記パネルはガラス表面のナトリウムイオンの一
部をカリウムイオン、ルビジウムイオン、オヨびセシウ
ムイオンの少なくとも一種とリチウムイオンとに置換さ
れているため、混合アルカリ効果により電子線が照射さ
れてもブラウニングを生じ難く、シかもガラスの表面に
圧縮層が生じるため、ガラス強度が向上する。In the mtJ panel, some of the sodium ions on the glass surface are replaced with at least one of potassium ions, rubidium ions, and cesium ions and lithium ions, so the mixed alkali effect prevents browning even when irradiated with electron beams. Since a compressed layer is formed on the surface of the glass, the strength of the glass is improved.
電子線が照射されるガラス表面は、フロートバスの溶融
錫に接触する面と反対側の面であることが好ましい。ガ
ラス表面が１０−トバスの溶融錫に接触した面であると
前記イオン交換のスピードをおそくシ、イオン交換処理
時間がいたずらに長くなる。またガラス表面にＳｎがあ
るとブラウニングが生じ易い。The glass surface to which the electron beam is irradiated is preferably the surface opposite to the surface that contacts the molten tin of the float bath. If the glass surface is in contact with a 10-ton bath of molten tin, the ion exchange speed will be slow and the ion exchange treatment time will be unnecessarily long. Further, if Sn is present on the glass surface, browning is likely to occur.
該ガラスパネルにおいて、ナトリウムイオンと置換され
たリチウムイオンは酸化リチウムとして存在するが、該
酸化リチウムは、少なくとも電子線が照射されるガラス
表面から１０μｍの深さの範囲での平均重量％が、０．
１〜３％であるのが好ましい。該酸化リチウムの平均重
量％が３％をこえるとガラス強度は低下し、はなはだし
き場合にはガラス表面が白濁したり、微小なりラックが
生ずる。In the glass panel, lithium ions substituted with sodium ions exist as lithium oxide, and the average weight % of the lithium oxide is 0 at least in a depth of 10 μm from the glass surface where the electron beam is irradiated. ．．
It is preferably 1 to 3%. When the average weight percent of the lithium oxide exceeds 3%, the glass strength decreases, and if too much of the lithium oxide is used, the glass surface becomes cloudy and minute racks are formed.
カリウムイオン、ルビジウムイオン、およびセシウムイ
オンの少なくとも一種とリチウムイオンをふくむ溶融塩
において、リチウムイオンを除くカリウムイオン、ルビ
ジウムイオン、およびセシウムイオンの少なくとも一種
の陽イオンにたいするリチウムイオンのモル％が、ｏ、
ｏａへ０．４！％であることが好ましい。リチウムイオ
ンのモル％が０．１７％をこえると、前記と同様にガラ
ス強度が低下し、はなはだしき場合にはガラス表面が白
濁したり、微小なりラックが生ずる。また、置換された
カリウム、ルビジウム、セシウムのガラスパネル中への
浸入深さは５５ｍ乃至２０μｍであるのが好ましい。In a molten salt containing at least one of potassium ions, rubidium ions, and cesium ions and lithium ions, the mol% of lithium ions relative to the cations of at least one of potassium ions, rubidium ions, and cesium ions excluding lithium ions is o,
0.4 to oa! % is preferable. When the mol% of lithium ions exceeds 0.17%, the glass strength decreases as described above, and in extreme cases, the glass surface becomes cloudy and minute racks are formed. Further, the penetration depth of the substituted potassium, rubidium, and cesium into the glass panel is preferably 55 m to 20 μm.
これより浅き場合或は、深き場合には、ブラウニング防
止の効果が低下する。If the depth is shallower or deeper than this, the effect of preventing browning will be reduced.
また、前記パネルはガラス板から成形されるので、ガラ
ス表面を研磨することなく平坦に保つことができる。Furthermore, since the panel is formed from a glass plate, the glass surface can be kept flat without polishing.
以下に本発明に基づ〈実施例について説明する。 Examples based on the present invention will be described below.
フロート法で成形されたソーダ・ライム・シリカガラス
板を加熱し、プレスを併用した真空成形法により、幅ｊ
００１ｊｔＲ１長さ３１０朋、高さ、ｆＱｖｍ の第
１図のごとき一面に平滑面を有したパネルを成形した。By heating a soda lime silica glass plate formed by the float method and using a vacuum forming method combined with a press, width j
001jtR1 A panel having a length of 310 mm and a height of fQvm as shown in FIG. 1 having a smooth surface on one side was molded.
その後、このパネルを約２００”Ｃの雰囲気中で約３０
分間予熱したあと、硝酸リチウムのｍｏｌ濃度を、０
、０．０１） 、０．ｌｊ 、 ０．１ｔ ％と変化さ
せた、硝酸カリウムと硝酸リチウムを混合したｔ６０°
Ｃに加熱した溶融塩中に、２時間浸漬後、取り出して洗
浄した。Afterwards, this panel was heated for about 30 minutes in an atmosphere of about 200"C.
After preheating for minutes, the mol concentration of lithium nitrate was reduced to 0.
,0.01) ,0. lj, t60° of a mixture of potassium nitrate and lithium nitrate varying with 0.1t%
After being immersed in a molten salt heated to C for 2 hours, it was taken out and washed.
上記ガラス・パネルの酸化リチウムのガラス・パネル表
面から深さ方向へ０〜１０μｍ の範囲での平均濃度（
重量％）を第１表にしめす。また、モル％比Ｎａ２Ｏ／
（Ｎａ２０ ＋ Ｋ２Ｏ）の値を同時にしめす。The average concentration of lithium oxide in the above glass panel in the range of 0 to 10 μm in depth from the glass panel surface (
% by weight) are shown in Table 1. In addition, the mol% ratio Na2O/
The values of (Na20 + K2O) are shown at the same time.
上記工程より得られたガラスパネルに、電子銃（陰極電
圧２ ／ ＫＶ、カソード電流、３００μＡ１面亀流密
度八００μＡ／ｆｆ１）による電子線の照射を３００時
間行った。しかる後、波長ＩＩｏｏｎｍでの光の透過率
を測定した。The glass panel obtained from the above process was irradiated with an electron beam for 300 hours using an electron gun (cathode voltage 2/KV, cathode current, 300 μA, one-plane turtle current density 800 μA/ff1). Thereafter, the transmittance of light at a wavelength of IIoonm was measured.
第 ／ 表 第 コ 表 吸光度の変化（ｌｎ（Ｔｏ／Ｔ））を第２表にしめす。Chapter/Table Table The change in absorbance (ln(To/T)) is shown in Table 2.
第２表において、ＴＯ及びＴ は、電子線照射前後の透
過率である。In Table 2, TO and T are the transmittances before and after electron beam irradiation.
第２表から明らかな如く硝酸リチウムのｍｏｌ濃度をｏ
、ｏｔＩ乃至０．１７％と変化させたものは、硝酸リチ
ウムのｍｏｌ ｍ度が０％のものよりもブラウニングが
少ないことがわかる。また上記ガラスパネルの表面応力
を測定した結果、ガラスパネル表面層に圧縮力が存在し
ガラス強度が向上している事がみとめられた。As is clear from Table 2, the molar concentration of lithium nitrate is
, otI to 0.17%, it can be seen that browning is less than that in which the mol degree of lithium nitrate is 0%. Furthermore, as a result of measuring the surface stress of the glass panel, it was found that compressive force was present in the surface layer of the glass panel, and the glass strength was improved.
本発明によるパネルガラスはガラス表面のナトリウムイ
オンの一部をカリウムイオン、ルビジウムイオン、およ
びセシウムイオンの少なくとも一種とリチウムイオンと
に置換し、電子線が照射されてもブラウニングが生じが
たくなるため、市販のソーダ・ライム・シリカガラス板
を素板としてもちいる事が可能になり、パネル面の研磨
作業を省くことができ、低コストで製造する事ができる
。In the panel glass according to the present invention, part of the sodium ions on the glass surface is replaced with at least one of potassium ions, rubidium ions, and cesium ions and lithium ions, and browning is less likely to occur even when irradiated with an electron beam. It becomes possible to use a commercially available soda/lime/silica glass plate as a base plate, and the polishing work of the panel surface can be omitted, making it possible to manufacture at low cost.
また本発明によるパネルは、ガラス表面のナトリウムイ
オンの一部をカリウムイオン、ルビジウムイオン、およ
びセシウムイオンの少なくとも一種により置換し、ガラ
ス表面に圧縮層が生じるため、パネルの強度が向上し、
従来のパネルに比し、ガラス厚みの薄いパネルの使用が
可能となる。In addition, in the panel according to the present invention, a portion of the sodium ions on the glass surface is replaced by at least one of potassium ions, rubidium ions, and cesium ions, and a compressed layer is formed on the glass surface, so that the strength of the panel is improved.
Compared to conventional panels, it is possible to use panels with thinner glass.
図面は本発明の実施例を示すものであって、第１図は、
ＣＲＴガラスパネルの断面図である。
第１図The drawings show embodiments of the present invention, and FIG.
FIG. 2 is a cross-sectional view of a CRT glass panel. Figure 1
Claims (5)
とも電子線が照射される表面のナトリウムイオンをカリ
ウムイオン、ルビジウムイオン、およびセシウムイオン
の少なくとも一種とリチウムイオンとによって置換した
電子線が照射されるガラスパネル。(1) Glass that is irradiated with electron beams, in which sodium ions on at least the surface of the soda-lime-silica glass panel that is irradiated with electron beams are replaced with at least one of potassium ions, rubidium ions, and cesium ions, and lithium ions. panel.
ガラス表面においてガラス表面から１０μｍの深さの範
囲での酸化リチウムの平均重量％が、０．１〜３％であ
る特許請求の範囲第（１）項記載の電子線が照射される
ガラスパネル。(2) The average weight percent of lithium oxide in a depth range of 10 μm from the glass surface on the glass surface of the glass panel that is irradiated with the electron beam is 0.1 to 3% ( A glass panel that is irradiated with the electron beam described in item 1).
法で製造されたものであり、その組成が重量％で表示し
て、ＳｉＯ＿２ ６９〜７３％、Ａｌ＿２Ｏ＿３ ０．
５〜１．５％Ｆｅ＿２Ｏ＿３ ０〜０．１５％、ＣａＯ
７〜１４％、ＭｇＯ ０〜４．５％、Ｎａ＿２Ｏ １
２〜１６％、Ｋ＿２Ｏ ０〜１．５％、ＴｉＯ＿２ ０
〜０．１％、ＳＯ＿３ ０〜０．５％の範囲であり、か
つ、電子線が照射されるガラス表面が、フロートバスの
溶融錫に接触する面と反対側の面で有る事を特徴とする
特許請求の範囲第（１）項記載の電子線が照射されるガ
ラスパネル。(3) The soda-lime silica glass is manufactured by a float method, and its composition is expressed in weight percent: SiO_2 69-73%, Al_2O_3 0.
5-1.5% Fe_2O_3 0-0.15%, CaO
7-14%, MgO 0-4.5%, Na_2O 1
2-16%, K_2O 0-1.5%, TiO_2 0
~0.1%, SO_3 is in the range of 0 to 0.5%, and the glass surface to which the electron beam is irradiated is the surface opposite to the surface that contacts the molten tin of the float bath. A glass panel irradiated with an electron beam according to claim (1).
ネルに成形し、４３０℃乃至４９０℃のカリウムイオン
、ルビジウムイオン、およびセシウムイオンの少なくと
も一種とリチウムイオンを含む溶融塩中に、０．５時間
乃至４時間浸漬し、該パネル表面のナトリウムイオンを
カリウムイオン、ルビジウムイオン、およびセシウムイ
オンの少なくとも一種とリチウムイオンとに、イオン交
換で置換する、電子線が照射されるガラスパネルの製造
方法。(4) A soda-lime-silica glass plate is formed into a panel such as a CRT, and 0.5 A method for manufacturing a glass panel in which the glass panel is irradiated with an electron beam, the method comprising soaking the panel for 4 to 4 hours and replacing sodium ions on the surface of the panel with at least one of potassium ions, rubidium ions, and cesium ions and lithium ions through ion exchange.
ウムイオン、ルビジウムイオン、およびセシウムイオン
の少なくとも一種の陽イオンにたいするリチウムイオン
のモル％が、０．０４〜０．４％である特許請求の範囲
第（４）項記載の、電子線が照射されるガラスパネルの
製造方法。(5) In the molten salt, the molar percentage of lithium ions to at least one cation of potassium ions, rubidium ions, and cesium ions other than lithium ions is 0.04 to 0.4%. The method for manufacturing a glass panel that is irradiated with an electron beam, as described in (4).
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2321687A JPH07108797B2 (en) | 1987-02-03 | 1987-02-03 | Glass panel irradiated with electron beam and method for manufacturing the same |
| US07/146,449 US4897371A (en) | 1987-02-03 | 1988-01-21 | Glass article protected from coloring by electron rays and method of using |
| GB888801574A GB8801574D0 (en) | 1987-02-03 | 1988-01-25 | Glass article protected from colouring by electron rays & process for producing same |
| GB8802222A GB2200627B (en) | 1987-02-03 | 1988-02-02 | Glass article protected from discolouring by electron rays |
| FR888801191A FR2610317B1 (en) | 1987-02-03 | 1988-02-02 | GLASS ARTICLE PROTECTED FROM COLORING BY ELECTRONIC RAYS AND METHOD FOR THE PRODUCTION THEREOF |
| DE19883803191 DE3803191C2 (en) | 1987-02-03 | 1988-02-03 | Float glass and process for its manufacture |
| DE3844883A DE3844883C2 (en) | 1987-02-03 | 1988-02-03 | Process for the preparation of a glass object protected against discoloration by electron beams |
| DE3844882A DE3844882C2 (en) | 1987-02-03 | 1988-02-03 | Soda lime silica glass for CRT resistant to browning |
| US07/384,126 US5057134A (en) | 1987-02-03 | 1989-07-24 | Process for producing a glass article protected from coloring by electron rays |
| GB9020023A GB2236317B (en) | 1987-02-03 | 1990-09-13 | Preparation of glass articles protected from discolouring by electron rays |
| GB9020022A GB2236316B (en) | 1987-02-03 | 1990-09-13 | Glass article protected from discolouring by electron rays |
| US07/989,826 US5296294A (en) | 1987-02-03 | 1992-12-14 | Glass panel resistant to coloring when irradiated with electron rays |
| EP97108222A EP0791563B1 (en) | 1987-02-03 | 1993-12-13 | Glass panel resistant to coloring when irradiated with electron rays |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2321687A JPH07108797B2 (en) | 1987-02-03 | 1987-02-03 | Glass panel irradiated with electron beam and method for manufacturing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63190744A true JPS63190744A (en) | 1988-08-08 |
| JPH07108797B2 JPH07108797B2 (en) | 1995-11-22 |
Family
ID=12104463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2321687A Expired - Fee Related JPH07108797B2 (en) | 1987-02-03 | 1987-02-03 | Glass panel irradiated with electron beam and method for manufacturing the same |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH07108797B2 (en) |
| GB (1) | GB8801574D0 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142039A (en) * | 1988-11-24 | 1990-05-31 | Nippon Sheet Glass Co Ltd | Image displaying front glass panel and manufacture thereof |
| KR100238117B1 (en) * | 1996-12-05 | 2000-01-15 | 박영구 | Substrate glasses for plasma display panel |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG99350A1 (en) | 2000-02-17 | 2003-10-27 | Hoya Corp | Glass for cathode-ray tube, strengthened glass, method for the production thereof and use thereof |
-
1987
- 1987-02-03 JP JP2321687A patent/JPH07108797B2/en not_active Expired - Fee Related
-
1988
- 1988-01-25 GB GB888801574A patent/GB8801574D0/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142039A (en) * | 1988-11-24 | 1990-05-31 | Nippon Sheet Glass Co Ltd | Image displaying front glass panel and manufacture thereof |
| KR100238117B1 (en) * | 1996-12-05 | 2000-01-15 | 박영구 | Substrate glasses for plasma display panel |
Also Published As
| Publication number | Publication date |
|---|---|
| GB8801574D0 (en) | 1988-02-24 |
| JPH07108797B2 (en) | 1995-11-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |