JPS6318998B2 - - Google Patents
Info
- Publication number
- JPS6318998B2 JPS6318998B2 JP57089961A JP8996182A JPS6318998B2 JP S6318998 B2 JPS6318998 B2 JP S6318998B2 JP 57089961 A JP57089961 A JP 57089961A JP 8996182 A JP8996182 A JP 8996182A JP S6318998 B2 JPS6318998 B2 JP S6318998B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- bathtub
- cleaning
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 benzotriazole amine salt Chemical class 0.000 claims description 12
- 239000012459 cleaning agent Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000004115 Sodium Silicate Substances 0.000 claims description 7
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 4
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZDWPBMJZDNXTPG-UHFFFAOYSA-N 2h-benzotriazol-4-amine Chemical class NC1=CC=CC2=C1NN=N2 ZDWPBMJZDNXTPG-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
【発明の詳細な説明】
本発明は、風呂釜洗浄剤組成物に関するもの
で、より詳細には優れた洗浄作用と防錆作用との
組合せを有する風呂釜洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a bathtub cleaning composition, and more particularly to a bathtub cleaning composition that has an excellent combination of cleaning action and antirust action.
風呂釜の熱交換面には使用中に垢、人毛、その
他のスケール類が付着し、これらスケール類の付
着に伴なつて風呂釜の熱効率が低下するという問
題がある。従来、これらのスケール類を除去する
ための風呂釜洗浄剤としては、界面活性剤、溶剤
及び金属封鎖剤を含有するものが使用されている
が、公知の風呂釜洗浄剤は、洗浄後の熱交換用金
属表面、即ち銅金属表面を腐食する傾向があり、
風呂釜を長持ちさせ、熱効率を高めるという目的
には未だ不満足なものである。更に公知の風呂釜
洗浄剤は不透明な液体であつて、液自体の分散安
定性や外観特性においても不満足なものである。 Dirt, human hair, and other scales adhere to the heat exchange surface of the bathtub during use, and as these scales adhere, the thermal efficiency of the bathtub decreases. Conventionally, bathtub cleaning agents containing surfactants, solvents, and metal sequestering agents have been used to remove these scales. Tends to corrode replacement metal surfaces, i.e. copper metal surfaces;
It is still unsatisfactory for the purpose of extending the life of the bathtub and increasing its thermal efficiency. Furthermore, known bathtub cleaning agents are opaque liquids and are unsatisfactory in terms of dispersion stability and appearance characteristics.
従つて、本発明の目的は、風呂釜の洗浄に際し
て優れた洗浄力を示すと共に、洗浄後の金属表面
の錆の発生を顕著に抑制することが可能な風呂釜
洗浄剤を提供するにある。 SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a bathtub cleaning agent that exhibits excellent cleaning power when cleaning bathtubs and can significantly suppress the formation of rust on metal surfaces after cleaning.
本発明の他の目的は、全体が透明な液であり、
分散安定性及び貯蔵安定性に優れ且つ商品として
の外観特性も良好な風呂釜洗浄剤を提供するにあ
る。 Another object of the invention is a completely transparent liquid;
To provide a bathtub cleaning agent which has excellent dispersion stability and storage stability and also has good appearance characteristics as a product.
本発明の更に他の目的は、プロペラントとの組
合せでエアゾール型洗浄剤として使用することの
可能な風呂釜洗浄剤組成物を提供するにある。 Still another object of the present invention is to provide a bathtub cleaning composition that can be used as an aerosol type cleaning agent in combination with a propellant.
本発明によれば、全量100重量部当たり、界面
活性剤0.5乃至７重量部、ブチルカルビノール乃
至はセロソルブ系溶媒２乃至10重量部、メタケイ
酸ソーダ0.3乃至５重量部、エチレンジアミンテ
トラ酢酸２ナトリウム0.5乃至５重量部及びベン
ゾトリアゾールアミン塩0.01乃至0.1重量部を含
有するPH8.5乃至11.5の水性組成物から成ること
を特徴とする風呂釜洗浄剤が提供される。 According to the present invention, per 100 parts by weight of the total amount, 0.5 to 7 parts by weight of surfactant, 2 to 10 parts by weight of butyl carbinol or cellosolve solvent, 0.3 to 5 parts by weight of sodium metasilicate, and 0.5 parts by weight of disodium ethylenediaminetetraacetate. There is provided a bathtub cleaning agent characterized by comprising an aqueous composition having a pH of 8.5 to 11.5 and containing 5 to 5 parts by weight and 0.01 to 0.1 part by weight of a benzotriazole amine salt.
本発明の洗浄剤組成物において、メタケイ酸ソ
ーダは、ビルダーとして界面活性剤及び有機溶媒
系浸透剤との組合せで風呂釜内に付着するスケー
ル類を洗浄除去する作用を呈するのみならず、ベ
ンゾトリアゾール系防錆剤や更にエチレンジアミ
ンテトラ酢酸アルカリ塩との組合せで洗浄後の金
属表面の錆発生を顕著に抑制し、更にこれら各成
分の分散性を助長して液自体の安定性、透明性を
向上させるという望ましい作用がある。 In the cleaning composition of the present invention, sodium metasilicate not only acts as a builder in combination with a surfactant and an organic solvent-based penetrant to clean and remove scales adhering to the inside of the bathtub, but also acts as a benzotriazole In combination with rust preventives and alkali salts of ethylenediaminetetraacetate, it significantly suppresses the occurrence of rust on metal surfaces after cleaning, and further promotes the dispersibility of these components to improve the stability and transparency of the liquid itself. It has the desirable effect of causing
本発明において、界面活性剤としては、従来洗
剤に使用されている任意の界面活性剤、即ちアニ
オン系界面活性剤、ノニオン系界面活性剤、両性
系界面活性剤もしくはこれらの組合せが使用され
る。好適な活性剤は、高級アルコール硫酸エステ
ルナトリウム塩、アルキル硫酸エステルナトリウ
ム塩、α―オレフイン硫酸塩、アルキルベンゼン
スルホン酸ナトリウム塩、アルキロールアミド硫
酸エステル、アルキルナフタリンスルホン酸ナト
リウム塩、脂肪酸エステルスルホン化物、複素環
式スルホン化物、脂肋酸アミドスルホン化物、ジ
アルキルスルホコハク酸ナトリウム、脂肪酸―ア
ミノ酸縮合物等のアニオン界面活性剤である。こ
の界面活性剤は洗浄力の点から全体当り0.5乃至
７重量部の量で使用される。 In the present invention, any surfactant conventionally used in detergents, ie, anionic surfactants, nonionic surfactants, amphoteric surfactants, or a combination thereof, can be used as the surfactant. Suitable activators include higher alcohol sulfate sodium salts, alkyl sulfate sodium salts, α-olefin sulfates, alkylbenzene sulfonate sodium salts, alkylolamide sulfates, alkylnaphthalene sulfonate sodium salts, fatty acid ester sulfonates, complex Anionic surfactants such as cyclic sulfonated products, fatty acid amide sulfonated products, sodium dialkyl sulfosuccinates, and fatty acid-amino acid condensates. This surfactant is used in an amount of 0.5 to 7 parts by weight based on the total detergency.
本発明においては、有機溶媒系浸透剤として、
ブチルカルビノール或は、ブチルセロソルブ、エ
チルセロソルブ、メチルセロソルブ等のセロソル
ブ系溶媒が使用される。この有機溶媒系浸透剤は
風呂釜に付着するスケール等に浸透してこれを軟
化させる作用を有するものであり、全体当り２乃
至10重量部の量で使用される。 In the present invention, as an organic solvent penetrant,
Butyl carbinol or a cellosolve solvent such as butyl cellosolve, ethyl cellosolve, methyl cellosolve, etc. is used. This organic solvent-based penetrant has the effect of penetrating and softening scale etc. adhering to the bathtub, and is used in an amount of 2 to 10 parts by weight per total.
本発明の特徴は、洗剤ビルダー、錆防止助剤及
び全成分の溶解安定化の目的でメタケイ酸ナトリ
ウム（Na2SiO2）を使用する。このメタケイ酸ナ
トリウムには、９水塩のものの他、５水塩等各種
のものが知られているが、本発明においては、こ
れら各種のものを用いることができる。メタケイ
酸ソーダは全体当り0.3乃至５重量部、特に0.7乃
至３重量部の量で使用するのがよく、上記量より
も少ないときには、液の分散安定性及び保存安定
性や錆防止効果、更には緩衝性、金属イオン封鎖
等のビルダー効果が低下するようになる。また、
上記範囲よりも多いと、かえつて液の透明性等が
失われ、分散安定性や保存安定性が低下する傾向
が認められる。 A feature of the present invention is the use of sodium metasilicate (Na 2 SiO 2 ) for the purpose of detergent builder, rust prevention aid and solubility stabilization of all ingredients. Various types of sodium metasilicate are known, such as a nonahydrate salt and a pentahydrate salt, and these various types can be used in the present invention. Sodium metasilicate is preferably used in an amount of 0.3 to 5 parts by weight, particularly 0.7 to 3 parts by weight, based on the total amount.When the amount is less than the above, it improves the dispersion stability and storage stability of the liquid, the rust prevention effect, and Builder effects such as buffering properties and sequestration of metal ions are reduced. Also,
If the amount exceeds the above range, the transparency of the liquid will be lost, and the dispersion stability and storage stability will tend to decrease.
本発明の洗浄剤組成物には、金属封鎖済乃至は
キレート剤として、エチレンジアミンテトラ酢酸
（EDTA）２ナトリウムを含有させる。この
EDTA2ナトリウム塩は、全体当たり0.5乃至５重
量％の量で使用される。 The cleaning composition of the present invention contains disodium ethylenediaminetetraacetic acid (EDTA) as a sequestered or chelating agent. this
EDTA disodium salt is used in an amount of 0.5 to 5% by weight based on the total.
本発明においては、洗浄後の金属表面に錆が発
生するのを防止するため、前述したメタケイ酸ソ
ーダとの組合せで、ベンゾトリアゾールアミン塩
から成る防錆剤を使用する。この化合物は、下記
一般式、即ち
式中、ｎはゼロまたは１の数であり、
R1，R2及びR3の各々は全部が水素原子
でないという条件下に水素、アルキル、
オキシアルキルまたはフエニル基であ
る。 In the present invention, in order to prevent rust from forming on the metal surface after cleaning, a rust preventive agent consisting of a benzotriazole amine salt is used in combination with the above-mentioned sodium metasilicate. This compound has the following general formula: In the formula, n is a number of zero or 1,
Each of R 1 , R 2 and R 3 is hydrogen, alkyl,
It is an oxyalkyl or phenyl group.
で表わされる。このベンゾトリアゾールアミン類
は、全体当り0.01乃至0.1重量部の量で含有させ
ることにより、優れた錆防止効果が得られる。It is expressed as By containing this benzotriazoleamine in an amount of 0.01 to 0.1 part by weight based on the total weight, an excellent rust prevention effect can be obtained.
本発明によれば、上述した成分の残余の量の水
を添加して、透明でしかも分散安定性及び保存安
定性に優れた水性液体とする。この水性液体は、
洗浄力及び取扱いの点で8.5及至11.5のPHを有す
るのが望ましく、このPH調整の目的でこの水性液
体組成物には、クエン酸等のPH調整剤を配合する
ことができる。また、泡の発生を抑制するため
に、全体当り0.001乃至0.1重量部のシリコーン類
等の起泡抑制剤を配合でき、また微量の着色剤、
粘度調整剤、香料等を所望により配合できる。 According to the present invention, an amount of water remaining in the amount of the above-mentioned components is added to obtain a transparent aqueous liquid having excellent dispersion stability and storage stability. This aqueous liquid is
From the viewpoint of detergency and handling, it is desirable to have a pH of 8.5 to 11.5, and for the purpose of adjusting the pH, this aqueous liquid composition may contain a pH adjuster such as citric acid. In addition, in order to suppress the generation of bubbles, 0.001 to 0.1 part by weight of a foam suppressant such as silicone can be added to the total amount, and a trace amount of a coloring agent,
A viscosity modifier, fragrance, etc. can be added as desired.
本発明の洗浄剤組成物は、通常の容器に充填し
て風呂釜の洗浄に用いる他に、エアゾール容器中
にLPG等のプロペラントと共に充填し、風呂釜
の水導入口から風呂釜内に噴出させ、その洗浄に
用いることができる。 The cleaning composition of the present invention can be used to clean bathtubs by filling it into a normal container, or can also be filled into an aerosol container together with a propellant such as LPG and sprayed into the bathtub from the water inlet of the bathtub. It can be used for cleaning.
本発明を次の例で説明する。 The invention is illustrated by the following example.
実施例
高級アルコール硫酸エステルナトリウム塩
３重量部
アルキル硫酸エステルナトリウム塩 1.5〃
メタケイ酸ソーダ ５水塩 1.8〃
ブチルカルビノール ４〃
EDTA2ナトリウム 2.0〃
ベンゾトリアゾール・アミン塩 0.1〃
クエン酸 0.6〃
シリコーン 0.02重量部
に残量の水を加えて、PH10.9で透明な水溶液を製
造した。Example Higher alcohol sulfate ester sodium salt
3 parts by weight Alkyl sulfate ester sodium salt 1.5〃 Sodium metasilicate pentahydrate 1.8〃 Butyl carbinol 4〃 Disodium EDTA 2.0〃 Benzotriazole amine salt 0.1〃 Citric acid 0.6〃 Silicone Add the remaining amount of water to 0.02 parts by weight , a clear aqueous solution was prepared at pH 10.9.
上記水溶液に銅板を50℃で１週間浸透した後、
水洗し銅板表面の腐食状態を検査した。比較のた
め、市販の風呂釜洗浄剤についても同様の腐食試
験を行つた。市販の洗浄剤については、銅板表面
に腐食の進行が認められたが、上記実施列の洗浄
剤では腐食は殆んど認められなかつた。 After soaking a copper plate in the above aqueous solution at 50℃ for one week,
The corrosion state of the copper plate surface was inspected after washing with water. For comparison, a similar corrosion test was conducted on a commercially available bathtub cleaning agent. With the commercially available cleaning agents, progress of corrosion was observed on the surface of the copper plate, but with the cleaning agents of the above-mentioned series, almost no corrosion was observed.
上記実施例の水溶液を、LPGプロペラントと
共にエアゾール容器に充填し、ノズル備えたマウ
ンテイングカツプを取付け密封した。 The aqueous solution of the above example was filled into an aerosol container together with an LPG propellant, and a mounting cup equipped with a nozzle was attached and sealed.
家庭において、６ケ月間使用後の風呂釜から風
呂水を抜出し、水導入口からこの水溶液を射出し
た。30分間放置後、前記水導入口から水道のホー
スを挿入し、水洗浄を行つたところ、スケールの
除去が有効に行われることが確認された。 At home, bath water was extracted from a bathtub after 6 months of use, and this aqueous solution was injected from the water inlet. After leaving it for 30 minutes, a water hose was inserted through the water inlet to perform water washing, and it was confirmed that scale was effectively removed.
Claims (1)
重量部、ブチルカルビノール乃至はセロソルブ系
溶媒２乃至10重量部、メタケイ酸ソーダ0.3乃至
５重量部、エチレンジアミンテトラ酢酸２ナトリ
ウム0.5乃至５重量部及びベンゾトリアゾールア
ミン塩0.01乃至0.1重量部を含有するPH8.5乃至
11.5の水性組成物から成ることを特徴とする風呂
釜洗浄剤。1 Surfactant 0.5 to 7 per 100 parts by weight of total amount
PH8 containing parts by weight, 2 to 10 parts by weight of butyl carbinol or cellosolve solvent, 0.3 to 5 parts by weight of sodium metasilicate, 0.5 to 5 parts by weight of disodium ethylenediaminetetraacetate, and 0.01 to 0.1 parts by weight of benzotriazole amine salt. .5 to
A bathtub cleaning agent characterized by comprising an aqueous composition of 11.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8996182A JPS58206694A (en) | 1982-05-28 | 1982-05-28 | Bath boiler detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8996182A JPS58206694A (en) | 1982-05-28 | 1982-05-28 | Bath boiler detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58206694A JPS58206694A (en) | 1983-12-01 |
| JPS6318998B2 true JPS6318998B2 (en) | 1988-04-20 |
Family
ID=13985279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8996182A Granted JPS58206694A (en) | 1982-05-28 | 1982-05-28 | Bath boiler detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58206694A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0699703B2 (en) * | 1989-05-12 | 1994-12-07 | 花王株式会社 | Liquid cleaning composition for bathroom |
| JP2797571B2 (en) * | 1989-12-27 | 1998-09-17 | 株式会社ツムラ | Detergent composition |
| JP2628010B2 (en) * | 1993-08-03 | 1997-07-09 | 大阪市 | Hair treatment agent and hair treatment method |
| JP4862127B2 (en) * | 2005-08-03 | 2012-01-25 | ウエ・ルコ物流株式会社 | Sterilizing and washing method for remaining hot water supply hose, chemical for hose used for sterilizing and washing method, washing method for washing machine, and washing agent for washing machine used for washing method |
| JP4947264B2 (en) * | 2006-02-17 | 2012-06-06 | 日産化学工業株式会社 | Detergent composition for circulating bath, bath tub and cooling water system equipment |
| JP6516353B2 (en) * | 2014-12-26 | 2019-05-22 | ライオン株式会社 | Liquid cleaning agent for bathroom |
| CN109055960A (en) * | 2018-09-07 | 2018-12-21 | 合肥绿洁环保科技有限公司 | A kind of low bubble cleaning agent of metal cleaning |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5335710A (en) * | 1976-09-14 | 1978-04-03 | Kao Corp | Detergent composition for bath room |
| JPS5632599A (en) * | 1979-08-27 | 1981-04-02 | Riyouji Karasaki | Composition for bath tub cleaner |
-
1982
- 1982-05-28 JP JP8996182A patent/JPS58206694A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5335710A (en) * | 1976-09-14 | 1978-04-03 | Kao Corp | Detergent composition for bath room |
| JPS5632599A (en) * | 1979-08-27 | 1981-04-02 | Riyouji Karasaki | Composition for bath tub cleaner |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58206694A (en) | 1983-12-01 |
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