JPS63188617A - Transparent gelatinous hair treatment composition - Google Patents
Transparent gelatinous hair treatment compositionInfo
- Publication number
- JPS63188617A JPS63188617A JP1940887A JP1940887A JPS63188617A JP S63188617 A JPS63188617 A JP S63188617A JP 1940887 A JP1940887 A JP 1940887A JP 1940887 A JP1940887 A JP 1940887A JP S63188617 A JPS63188617 A JP S63188617A
- Authority
- JP
- Japan
- Prior art keywords
- group
- formulas
- hair treatment
- carbon atoms
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 238000011282 treatment Methods 0.000 title claims description 31
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 7
- 125000005843 halogen group Chemical group 0.000 claims abstract description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 206010044625 Trichorrhexis Diseases 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 1
- 229940119217 chamomile extract Drugs 0.000 description 1
- 235000020221 chamomile extract Nutrition 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229940068886 polyethylene glycol 300 Drugs 0.000 description 1
- -1 polyoxy Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野] 本発明は、透明性に優れた毛髪
処理剤組成物、さらに詳しくは、透明性に優れ、かつ毛
髪に効果的な使用感を与え、温度安定性に優れたゲル試
毛髪処理剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention provides a hair treatment composition with excellent transparency, more specifically, a hair treatment composition with excellent transparency, which gives an effective feeling of use to the hair, and which has a temperature control property. This invention relates to a gel hair treatment composition with excellent stability.
[従来の技術] 通常、毛髪は頭皮より分泌される皮脂
、およびヘアーオイル、ヘアークリーム等の毛髪処理剤
に含まれる動植物油などによって覆われ、くシ、ブラシ
による機械的刺激から保護されている。しかしながら、
石鹸やシャンプー等で洗髪を行うと、それら油脂成分は
必要以上に除去されてしまう。この結果、毛髪からなめ
らかな風合がうりなわれ、パサパサとした硬い感触が生
じ、くしの通りが悪くなって、枝毛、切毛等、毛髪の損
傷の恐れが生じ易くなってしまう。とりわけ毛髪にコー
ルドウェーブやヘアダイ等の化学処理を施した場合にお
いて顕著である。[Prior Art] Normally, hair is covered with sebum secreted from the scalp and animal and vegetable oils contained in hair treatment agents such as hair oil and hair cream, and is protected from mechanical stimulation by combs and brushes. . however,
When you wash your hair with soap, shampoo, etc., these oil and fat components are removed more than necessary. As a result, the hair loses its smooth texture and feels dry and hard, making it difficult to comb through the hair, making it more likely that damage to the hair, such as split ends and cut hair, will occur. This is particularly noticeable when the hair has been subjected to chemical treatments such as cold waving or hair dye.
従来、このような不都合を解消するために各種の毛髪処
理剤が開発されている。例えば、このような毛髪処理剤
として、ジアルキルジメチルアンモニウームクロライド
やアルキルトリメチルアンモニウムクロライドで代表さ
れる第四級アンモニウム塩などを主成分とし、流動パラ
フィン、スラワラン、メチルポリシロキサン、イソプロ
ピルミリステート等の油性物質を配合した毛髪処理剤が
使用されている。このような毛髪処理剤は、お湯に溶解
または分散し、この液を用いて毛髪をすすぐのが一般的
である。Conventionally, various hair treatment agents have been developed in order to eliminate such inconveniences. For example, such hair treatment agents include quaternary ammonium salts such as dialkyldimethylammonium chloride and alkyltrimethylammonium chloride as the main ingredients, and oil-based hair treatment agents such as liquid paraffin, slawalan, methylpolysiloxane, and isopropyl myristate. Hair treatment agents containing substances are used. Such hair treatment agents are generally dissolved or dispersed in hot water, and this liquid is used to rinse the hair.
しかしながら、毛髪のより効果的な毛髪処理剤による処
理を行うためには、直接、毛髪に毛髪処理剤を塗布する
のが好ましい。この場合、組成物は手のひらより垂れ落
ちのないような、粘度を有することが必要である。However, in order to treat hair more effectively with a hair treatment agent, it is preferable to apply the hair treatment agent directly to the hair. In this case, the composition needs to have a viscosity that does not drip from the palm of your hand.
ところで、一般の毛髪処理剤には、外観上、透明タイプ
と不透明タイプのものとがあり、髪質等に応じ、配合成
分によって形態が異なっている。By the way, general hair treatment agents have a transparent type and an opaque type in terms of appearance, and the form differs depending on the ingredients, depending on the hair type, etc.
この中で、見た目に美しく、使用する時の楽しさがある
透明タイプの毛髪処理剤では、直接毛髪に塗布する適度
な粘度とするために増粘剤を必要とする。増粘剤として
は一般的にヒドロキシエチルセルロース、ヒドロキシプ
ロピルメチルセルロース等の水溶性高分子が使用されて
いた。Among these, transparent hair treatment agents that are aesthetically pleasing and enjoyable to use require a thickener to achieve an appropriate viscosity for direct application to the hair. Water-soluble polymers such as hydroxyethylcellulose and hydroxypropylmethylcellulose have generally been used as thickeners.
[発明が解決しようとする問題点] しかしながら、透
明ゲル状毛髪処理剤とするために、このようなヒドロキ
シエチルセルロース、ヒドロキシプロピルメチルセルロ
ース等の水溶性高分子を多量に配合すると、著しくリン
ス効果が損なわれ、一方、配合量が少ないと充分な増粘
効果が得られないという問題がある。[Problems to be Solved by the Invention] However, when a large amount of water-soluble polymers such as hydroxyethylcellulose and hydroxypropylmethylcellulose are blended into a transparent gel-like hair treatment agent, the rinsing effect is significantly impaired. On the other hand, there is a problem that if the amount is too small, a sufficient thickening effect cannot be obtained.
[問題を解決するための手段] 本発明者らは、上記の
点に着目し、鋭意研究を重ねた結果、特定の第四級アン
モニウム塩および特定のポリオキシアルキレン変性オル
ガノポリシロキサンを配合することにより、手のひらに
取って直接毛髪に塗布できる粘性を有し、リンス効果も
優れた透明ゲル状毛髪処理剤が得られる事を見出し、本
発明を完成するに至った。 ゛
即ち、本発明は、
(1) 一般式[1]:
は分岐のアルキル基およびアルケニル基または炭素数8
〜22のヒドロキシアルキル基;残りは、炭素数1〜3
のアルキル基または炭素数1〜3のヒドロキシアルキル
基;Xはハロゲン原子を表わす。]で表わされる第四級
アンモニウム塩の1種または2種以上、及び
一般式[2]
岐のアルキル基およびアルケニル基または炭素数8〜2
2のヒドロキシアルキル基;R6、R7、及で表わされ
る第四級アンモニウム塩の1種または2種以上、及び
一般式[3]、[4]、[5]または[6]で示される
ポリオキシアルキレン変性オルガノポリシロキサンの1
種または2種以上を配合したことを特徴とする透明ゲル
状毛髪処理剤組成物である。[Means for Solving the Problem] The present inventors focused on the above points and, as a result of extensive research, found that a specific quaternary ammonium salt and a specific polyoxyalkylene-modified organopolysiloxane were blended. The present inventors have discovered that a transparent gel-like hair treatment agent having a viscosity that allows it to be applied directly to the hair by taking it in the palm of the hand and has an excellent rinsing effect can be obtained, and has completed the present invention. That is, the present invention provides: (1) General formula [1]: is a branched alkyl group or alkenyl group or a carbon number of 8
~22 hydroxyalkyl groups; the rest have 1 to 3 carbon atoms
an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms; X represents a halogen atom. ] One or more quaternary ammonium salts represented by the general formula [2], an alkyl group and an alkenyl group, or a carbon number 8 to 2
2 hydroxyalkyl group; one or more quaternary ammonium salts represented by R6, R7, and polyoxy represented by general formula [3], [4], [5] or [6] Alkylene-modified organopolysiloxane 1
This is a transparent gel-like hair treatment composition characterized by containing one or more species.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
配合成分の配合割合は、前記一般式[1]および[2コ
で表わされる第四級アンモニウム塩、ならびに前記一般
式[3]、[4]、[5]、および[6]のポリオキシ
アルキレン変性オルガノポリシロキサンの合計配合量が
毛髪処理剤全重量に対して5〜50重量%、好ましくは
8〜35重量%配合される。これらの配合量が5重量%
未満であると、組成物は良好なゲル性を示さなくなり、
一方、50重量%を超えると、非常に粘度が増大して硬
くなって、使用が困難となることがあり好ましくない。The blending proportions of the ingredients are quaternary ammonium salts represented by the above general formulas [1] and [2], and polyoxyalkylenes of the above general formulas [3], [4], [5], and [6]. The total amount of modified organopolysiloxane blended is 5 to 50% by weight, preferably 8 to 35% by weight, based on the total weight of the hair treatment agent. The blending amount of these is 5% by weight.
If the amount is less than 1, the composition will not exhibit good gel properties;
On the other hand, if it exceeds 50% by weight, the viscosity increases significantly and becomes hard, making it difficult to use, which is not preferable.
また、前記一般式[1]で表わされる第四級アンモニウ
ム塩に対する前記一般式[2]で表わされる第四級アン
モニウム塩の重量配合比[1]/[2]は、20/1以
下1/10以上で、好ましくは10/1以下115以上
である。重量比が20/1を超えるとゲル性および透明
性が悪化することがあり、1/10未満だと、ゲル性に
劣ることがある。Further, the weight mixing ratio [1]/[2] of the quaternary ammonium salt represented by the general formula [2] to the quaternary ammonium salt represented by the general formula [1] is 20/1 or less 1/ 10 or more, preferably 10/1 or less and 115 or more. If the weight ratio exceeds 20/1, the gel properties and transparency may deteriorate, and if the weight ratio is less than 1/10, the gel properties may deteriorate.
さらに、前記一般式[1]および[2コで表わされる第
四級アンモニウム塩の合計配合量に対する前記一般式[
3]、[4]、[5]および[6〕のポリオキシアルキ
レン変性オルガノポリシロキサンの合計配合量の重量配
合比[1]+[2]/[3]+[4]+[5]+[6]
が、115〜15/1で、好ましくは1/2〜10/1
である。Further, the general formula [1] and the total amount of quaternary ammonium salts represented by [2]
3], [4], [5] and [6] Weight blending ratio of the total amount of polyoxyalkylene-modified organopolysiloxane [1]+[2]/[3]+[4]+[5]+ [6]
is 115 to 15/1, preferably 1/2 to 10/1
It is.
重量比が115未満の場合は透明性が、一方、重量比が
15/1を超える場合はゲル性及び透明性が悪化する傾
向がある。When the weight ratio is less than 115, transparency tends to deteriorate, while when the weight ratio exceeds 15/1, gel properties and transparency tend to deteriorate.
本発明に係る一般式[1]で表わすれる第四級アンモニ
ウム塩の代表例としては、ジステアリルジメチルアンモ
ニウムクロライド、ジステアリルジメチルアンモニウム
クロライド、ジ直鎖アルキル−ビス−(2−ヒドロキシ
エチル)アンモニウムクロライド、ジ直鎖アルキルポリ
エトキシ化アンモニウムクロライド等が挙げられ、これ
らの1種または2種以上を単独でも組合せても用いるこ
とができる。Representative examples of the quaternary ammonium salt represented by the general formula [1] according to the present invention include distearyldimethylammonium chloride, distearyldimethylammonium chloride, and dilinear alkyl-bis-(2-hydroxyethyl)ammonium chloride. , dilinear alkyl polyethoxylated ammonium chloride, etc., and one or more of these can be used alone or in combination.
又、本発明の一般式[2]で表わされる第4級アンモニ
ウム塩の代表例としては、セチルトリメチルアンモニウ
ムクロライド、ステアリルトリメチルアンモニウムクロ
ライド、ベヘニルトリメチルアンモニウムクロライド、
水素添加牛脂アルキルトリメチルアンモニウムクロライ
ド、モノ直鎖アルキルペンタエトキシ化アンモニウムク
ロライド等を挙げられ、これらの1種または2種以上を
単独でも組合せても用いることができる。Further, representative examples of the quaternary ammonium salt represented by the general formula [2] of the present invention include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride,
Examples include hydrogenated beef tallow alkyltrimethylammonium chloride, monolinear alkylpentaethoxylated ammonium chloride, and one or more of these can be used alone or in combination.
本発明の毛髪処理剤組成物には上記必須構成成分に加え
て、所望により、毛髪処理剤に配合される一般的な成分
、例えば適当な油分、高級アルコール類、保湿剤、生薬
、ラノリン誘導体、蛋白誘導体、水溶性高分子、防腐剤
、殺菌剤、紫外線吸収剤、酸化防止剤、色素、香料等を
透明性、ゲル性を損なわない範囲で添加してもよい。特
に、多価アルコールを、5〜45重量%、好ましくは1
0〜40重量%を配合することにより、より透明性が向
上する。In addition to the above-mentioned essential components, the hair treatment composition of the present invention may optionally include general ingredients that are included in hair treatment agents, such as appropriate oils, higher alcohols, humectants, crude drugs, lanolin derivatives, Protein derivatives, water-soluble polymers, preservatives, bactericidal agents, ultraviolet absorbers, antioxidants, pigments, fragrances, etc. may be added to the extent that they do not impair transparency and gelling properties. In particular, 5 to 45% by weight of polyhydric alcohol, preferably 1
By blending 0 to 40% by weight, transparency is further improved.
多価アルコールとしては、例えば、エチレングリコール
、プロピレングリコール、トリメチレングリコール、1
,2−ブチレングリコール、1゜3−ブチレングリコー
ル、テトラメチレングリコール及びジプロピレングリコ
ール等の2 (+Iのアルコール、グリセリン及びトリ
メチロールプロパン等の3価のアルコール、ペンタエリ
スリトール等の4価のアルコール、キシリトール等の5
価のアルコール、及びソルビトール及びマンニトール等
の6価のアルコール等の多価アルコールが例示される。Examples of polyhydric alcohols include ethylene glycol, propylene glycol, trimethylene glycol,
, 2-butylene glycol, 1゜3-butylene glycol, tetramethylene glycol, dipropylene glycol, etc. (+I alcohols, trihydric alcohols such as glycerin and trimethylolpropane, tetrahydric alcohols such as pentaerythritol, xylitol) etc. 5
and polyhydric alcohols such as hexahydric alcohols such as sorbitol and mannitol.
(以下余白) 実施例 次に本発明を実施例をもって詳細に説明する。(Margin below) Example Next, the present invention will be explained in detail using examples.
本発明はこれにより限定されるものではない。実施例に
先立ち、各実施例で採用した評価法を説明する。The present invention is not limited thereby. Prior to the examples, evaluation methods adopted in each example will be explained.
ゲル性 O・・良好なゲル性を示す。Gel property O: Shows good gel property.
O・・やや良好なゲル性を示す △・・良好なゲル性を示さない。O: Shows slightly good gel properties Δ: Does not exhibit good gel properties.
×・・保形性を示さない。×: Does not exhibit shape retention.
透明性 O・・良好な透明性を示す。Transparency O: Shows good transparency.
○・・やや良好な透明性を示す △・・少し濁る X・・白濁を示す。○: Shows somewhat good transparency △・・・A little cloudy X: Shows cloudiness.
温度安定性 得られた試料を各温度(0°C137 @C150°C)に1力月保存後、ゲ ル性、透明性を評価した。temperature stability The obtained sample was heated to each temperature (0°C137 After storing at 150°C for 1 month, We evaluated its transparency and transparency.
O・・ゲル性、透明性に変化無し ×・・ゲル性を示さなくなる、あるい は白濁を生ずる。O: No change in gel properties or transparency ×... No longer exhibits gel properties, or produces a cloudy appearance.
実施例1
成分 配合量(%)セチルトリメチ
ルアンモニウム 2.0クロライド
ジステアリルジメチルアンモニウム 8.0クロライ
ド
ポリオキシアルキレン変性 ::C10,0オルガノポ
リシロキサン
グリセリン 10.0ポリエチレ
ングリコール300 8.0色素
適量香料
0.3水
残部* ポリオキシアルキレン変性
オルガノポリシロキサン
(前記一般式[2]でR;メチル基、R”;水素、m;
60、n;3、x;8である)実施例1に示す配合組成
により毛髪処理剤組成物を製造した。該組成物を製造す
るには、セチルトリメチルアンモニウムクロライド、ジ
ステアリルジメチルアンモニウムクロライド、およびポ
リオキシアルキレン変性オルガノポリシロキサンを70
〜80” Cにて水に溶解し、これに残りの成分を撹拌
しながら加え、30°Cまで冷却する。Example 1 Component Amount (%) Cetyltrimethylammonium 2.0 Chloride distearyldimethylammonium 8.0 Chloride Polyoxyalkylene modification :: C10.0 Organopolysiloxane glycerin 10.0 Polyethylene glycol 300 8.0 Pigment
Appropriate amount of fragrance
0.3 water
Remainder* Polyoxyalkylene-modified organopolysiloxane (R in the general formula [2]; methyl group, R''; hydrogen, m;
60, n; 3, x; 8) A hair treatment composition was prepared using the formulation shown in Example 1. To prepare the composition, cetyltrimethylammonium chloride, distearyldimethylammonium chloride, and a polyoxyalkylene-modified organopolysiloxane are combined at 70%
Dissolve in water at ˜80”C, add remaining ingredients to this with stirring and cool to 30°C.
得られた組成物について、ゲル性および透明性について
評価した結果、優れたゲル性および透明性が得られ、毛
髪に効果的なリンス効果を与え、温度安定性も良好であ
った。The obtained composition was evaluated for its gel properties and transparency, and as a result, it was found that it had excellent gel properties and transparency, provided an effective rinsing effect on hair, and had good temperature stability.
実施例2〜8
実施例1と同様にして、下記の表1に示す配合組成によ
り毛髪処理剤組成物を製造した。結果を同様に表1に示
した。Examples 2 to 8 Hair treatment compositions were produced in the same manner as in Example 1 using the formulations shown in Table 1 below. The results are also shown in Table 1.
比較例1〜3
実施例1と同様にして、下記の表1に示す配合組成によ
り毛髪処理剤組成物を製造した。結果を同様に表1に示
した。Comparative Examples 1 to 3 Hair treatment compositions were produced in the same manner as in Example 1 using the formulations shown in Table 1 below. The results are also shown in Table 1.
(以下全白)
実施例6
成分 配合量(%)ステアリルトリ
メチルアンモニウム 4.0クロライド
ジステアリルジメチルアンモニウム 8.0クロライ
ド
ポリオキシアルキレン変性 * 12.0オルガノ
ボリシロキサン
プロピレングリコール 13.0カミツレ
エキス 0.01ビタミンEアセ
テート0.1
ピロリドンカルボン酸 0.02色素
適量香N
O,4水
残部* ポリオキシアルキレン変性
オルガノポリシロキサン
(前記一般式[2]でR;メチル基、Ro;水素、m:
60、ni3、X;10である)上記配合量にて、実施
例1と同様の方法により透明ゲル状毛髪処理剤組成物を
調整した。得られたリンス剤は、優れた透明性およびゲ
ル性を呈し、毛髪に効果的なリンス効果を与え、温度安
定性も良好であった。(All white below) Example 6 Ingredients Amount (%) Stearyltrimethylammonium 4.0 Chloride distearyldimethylammonium 8.0 Chloride polyoxyalkylene modified * 12.0 Organoborisiloxane propylene glycol 13.0 Chamomile extract 0.01 Vitamin E acetate 0.1 Pyrrolidone carboxylic acid 0.02 Pigment
Appropriate amount of incense N
O,4 water
Remainder* Polyoxyalkylene-modified organopolysiloxane (in the general formula [2] above, R: methyl group, Ro: hydrogen, m:
60, ni3, The resulting rinse agent exhibited excellent transparency and gel properties, provided an effective rinsing effect on hair, and had good temperature stability.
[発明の効果]
本発明に係わる透明ゲル状毛髪処理剤組成物は、手に取
りやすく、髪に塗布しやすい適度な粘性を有し、透明性
良好で、かつ使用感触や安定性、安全性にも優れた毛髪
処理剤組成物である。[Effects of the Invention] The transparent gel-like hair treatment composition according to the present invention has an appropriate viscosity that is easy to pick up and apply to hair, has good transparency, and has good feel, stability, and safety in use. It is also an excellent hair treatment composition.
Claims (1)
は分岐のアルキル基およびアルケニル基または炭素数8
〜22のヒドロキシアルキル基;残りは、炭素数1〜3
のアルキル基または炭素数1〜3のヒドロキシアルキル
基;Xはハロゲン原子を表わす。]で表わされる第四級
アンモニウム塩の1種または2種以上、及び 一般式[2] ▲数式、化学式、表等があります▼[2] [式中、R_5は、炭素数8〜22の直鎖または分岐の
アルキル基およびアルケニル基または炭素数8〜22の
ヒドロキシアルキル基;R_6、R_7、及びR_8は
、炭素数1〜3のアルキル基またはヒドロキシアルキル
基;Xはハロゲン原子を意味する]で表わされる第四級
アンモニウム塩の1種または2種以上、及び 一般式[3]、[4]、[5]または[6]で示される
ポリオキシアルキレン変性オルガノポリシロキサンの1
種または2種以上を配合したことを特徴とする透明ゲル
状毛髪処理剤組成物。 ▲数式、化学式、表等があります▼[3] ▲数式、化学式、表等があります▼[4] ▲数式、化学式、表等があります▼[5] ▲数式、化学式、表等があります▼[6] (式中、Rは炭素数1乃至3のアルキル基、又はフエニ
ル基、R′は水素、又は炭素数1乃至12のアルキル基
、pは1乃至5の整数、mは0乃至100の整数、nお
よびxは1乃至100の整数、tおよびyは0乃至10
0の整数である。)(2)前記一般式[1]および[2
]で表わされる第四組アンモニウム塩、ならびに前記一
般式[3]、[4]、[5]および[6]で表わされる
ポリオキシアルキレン変性オルガノポリシロキサンの合
計配合量が、全重量に対して5〜50重量%である前記
第(1)項記載の透明ゲル状毛髪処理剤。 (3)前記一般式[1]および[2]で表わされる第四
組アンモニウム塩、ならびに前記一般式[3]、[4]
、[5]および[6]で表わされるポリオキシアルキレ
ン変性オルガノポリシロキサンの合計配合量が全重量に
対して8〜35重量%である前記第(1)項項記載の透
明ゲル状毛髪処理剤。 (4)前記一般式[1]で表わされる第四組アンモニウ
ム塩に対する前記一般式[2]で表わされる第四組アン
モニウム塩の重量配合比[1]/[2]が、1/10以
上20/1以下である前記第(1)項記載ないし第(3
)項のいずれかに記載の透明ゲル状毛髪処理剤。 (5)前記一般式[1]および[2]で表わされる第四
組アンモニウム塩の合計配合量に対する前記一般式[3
]、[4]、[5]および[6]のポリオキシアルキレ
ン変性オルガノポリシロキサンの合計配合量の重量配合
比[1]+[2]/[3]+[4]+[5]+[6]が
、1/5〜15/1である前記第(1)項ないし第(4
)項のいずれかに記載の透明ゲル状毛髪処理剤。[Claims] (1) General formula [1]: ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [1] [In the formula, R_1 and R_2 are linear or branched alkyl groups having 8 to 22 carbon atoms. and alkenyl group or carbon number 8
~22 hydroxyalkyl groups; the rest have 1 to 3 carbon atoms
an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms; X represents a halogen atom. ] One or more quaternary ammonium salts represented by the general formula [2] ▲ Numerical formulas, chemical formulas, tables, etc. a chain or branched alkyl group or alkenyl group or a hydroxyalkyl group having 8 to 22 carbon atoms; R_6, R_7, and R_8 are an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms; X means a halogen atom]; One or more of the quaternary ammonium salts represented by the above formula, and one of the polyoxyalkylene-modified organopolysiloxanes represented by the general formula [3], [4], [5] or [6].
A transparent gel-like hair treatment composition characterized by containing one or more types. ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [3] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [4] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [5] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [ 6] (wherein, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, and m is an integer of 0 to 100. Integer, n and x are integers from 1 to 100, t and y are from 0 to 10
It is an integer of 0. ) (2) The above general formulas [1] and [2
] The total blending amount of the fourth group ammonium salt represented by The transparent gel-like hair treatment agent according to item (1) above, which contains 5 to 50% by weight. (3) Group 4 ammonium salts represented by the general formulas [1] and [2], and the general formulas [3] and [4]
, [5] and [6], wherein the total blending amount of the polyoxyalkylene-modified organopolysiloxanes represented by [5] and [6] is 8 to 35% by weight based on the total weight of the transparent gel-like hair treatment agent according to item (1) above. . (4) The weight mixing ratio [1]/[2] of the fourth group ammonium salt represented by the general formula [2] to the fourth group ammonium salt represented by the general formula [1] is 1/10 or more 20 /1 or less as described in paragraphs (1) to (3) above.
) The transparent gel-like hair treatment agent according to any one of the above items. (5) The general formula [3] relative to the total amount of the fourth group ammonium salts represented by the general formulas [1] and [2].
], [4], [5] and [6] Weight blending ratio of the total blending amount of polyoxyalkylene-modified organopolysiloxane [1] + [2] / [3] + [4] + [5] + [ 6] is 1/5 to 15/1.
) The transparent gel-like hair treatment agent according to any one of the above items.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1940887A JPS63188617A (en) | 1987-01-29 | 1987-01-29 | Transparent gelatinous hair treatment composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1940887A JPS63188617A (en) | 1987-01-29 | 1987-01-29 | Transparent gelatinous hair treatment composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63188617A true JPS63188617A (en) | 1988-08-04 |
Family
ID=11998431
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1940887A Pending JPS63188617A (en) | 1987-01-29 | 1987-01-29 | Transparent gelatinous hair treatment composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63188617A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02273609A (en) * | 1989-04-14 | 1990-11-08 | Kao Corp | Hair cosmetic stock |
WO1994018934A1 (en) * | 1993-02-26 | 1994-09-01 | The Boots Company Plc | Hair care compositions containing a silicone compound and a quaternary ammonium compound |
US6060044A (en) * | 1995-01-27 | 2000-05-09 | L'oreal | Cosmetic composition based on guar gum and silicones |
-
1987
- 1987-01-29 JP JP1940887A patent/JPS63188617A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02273609A (en) * | 1989-04-14 | 1990-11-08 | Kao Corp | Hair cosmetic stock |
WO1994018934A1 (en) * | 1993-02-26 | 1994-09-01 | The Boots Company Plc | Hair care compositions containing a silicone compound and a quaternary ammonium compound |
US6060044A (en) * | 1995-01-27 | 2000-05-09 | L'oreal | Cosmetic composition based on guar gum and silicones |
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