JPS63182241A - Manufacture of gravel from garbage incinerated ash - Google Patents

Manufacture of gravel from garbage incinerated ash

Info

Publication number
JPS63182241A
JPS63182241A JP62011296A JP1129687A JPS63182241A JP S63182241 A JPS63182241 A JP S63182241A JP 62011296 A JP62011296 A JP 62011296A JP 1129687 A JP1129687 A JP 1129687A JP S63182241 A JPS63182241 A JP S63182241A
Authority
JP
Japan
Prior art keywords
gravel
hardened
around
incineration ash
ash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62011296A
Other languages
Japanese (ja)
Other versions
JPH0319178B2 (en
Inventor
渡辺 彦逸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP62011296A priority Critical patent/JPS63182241A/en
Publication of JPS63182241A publication Critical patent/JPS63182241A/en
Publication of JPH0319178B2 publication Critical patent/JPH0319178B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/10Burned or pyrolised refuse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (発明の目的) イ、産業上の利用分野 本願発明は一般家庭より排出される塵芥を焼却処理した
後発生する焼却灰を以って砂利を造成し、これを以って
路盤材を始め一般建造物のコンクリート造成用骨材に供
せんとするものである。
[Detailed Description of the Invention] (Purpose of the Invention) A. Field of Industrial Application The present invention creates gravel using the incineration ash generated after incinerating garbage discharged from ordinary households, and It is intended to be used as aggregate for concrete construction of general buildings, including roadbed materials.

口、従来の技術 塵芥焼却灰をただ単に熔融するのみにてこれを急冷し、
粗粒子状として天然砂等と混合して路盤材に活用せんと
する技術は公知である。
However, the conventional technology involves simply melting the garbage incineration ash and rapidly cooling it.
Techniques are known in which coarse particles are mixed with natural sand and used for roadbed materials.

ハ0発明が解決しようとする問題煮 熟で一般家庭より排出される塵芥は特定事業や空罐から
金属製玩具の他陶磁器類の破片等々その内容は正に雑多
そのものである。
In order to solve the problem that this invention aims to solve, the garbage generated by ordinary households is truly miscellaneous, from specific businesses and empty cans to metal toys and fragments of ceramics.

そしてその焼却処理方法は各自治体に殆ど共通して70
0度程度の高熱回転炉中を一定の速度にて塵芥を通過せ
しめてその間に焼却処理をしているのであり、これに依
って連続発生する焼却灰は散水に依るか若しくは水と混
和して冷却処置をしているのである。
The incineration method is almost the same for each local government.
The garbage is passed through a high-temperature rotary furnace at a temperature of about 0 degrees Celsius at a constant speed, and incinerated during that time. It is undergoing cooling treatment.

この様な手段では難燃性物質は50%程度、又ガラスや
陶磁器類に到っては破壊する程度、更に又金属類に於い
ても変形する程度のみにて可燃性物質に依る粉末状残灰
と共に焼却灰として一括排出されるのである。
With this method, only about 50% of the flame retardant material is present, and only enough to destroy glass and ceramics, and only enough to deform metals is the powdery residue caused by flammable materials. It is discharged together with the ash as incineration ash.

そして焼却灰の排出時磁力を以って鉄類の自動選別を行
っているのであるがこれも微粉末灰に被覆されたものは
磁力を妨害せられてそのまま排出されるのである。
When the incineration ash is discharged, magnetic force is used to automatically sort out iron and other metals, but those covered with fine powder ash are obstructed by the magnetic force and are discharged as they are.

これ等の焼却灰は一括して夫々の遊休地に埋立処理され
ているのであるが、焼却灰の排出量は例えば人口30万
〜40万程度の中都市に於いても年間2万ton程度に
も達しこれを殆どの都市は周辺の遊休地に埋立処理をし
ているのであって、近時はその殆どが埋立使用し尽され
て新たに過疎地を求めて奔走する状態に迄追込まれその
対策に苦慮しているのである。
These incinerated ash are collectively disposed of in landfills on idle land, but the amount of incinerated ash discharged is around 20,000 tons per year even in medium-sized cities with a population of 300,000 to 400,000, for example. Most cities have reached this point by filling in idle land around them, and recently most of that land has been used up and people are scrambling to find new depopulated land. They are struggling to come up with countermeasures.

そして又更に焼却灰中には相当量の有機水銀やダイオキ
シン等の他多くの有害物質を含有せるためこれ等の有害
物質が降雨に依って地下に浸透し、次第に地下深部に及
ぶ時は終に地下水が全面汚染の事態に発展し、該事態が
我国上の全域に亘って進行中とあればその抜本的対策は
最早焦眉の急といわざるを得ないのである。
Furthermore, since incineration ash contains a considerable amount of organic mercury, dioxins, and many other harmful substances, these harmful substances permeate underground through rainfall and gradually reach deep underground. If the groundwater were to develop into a situation of total contamination, and if this situation were to continue throughout the country, drastic countermeasures would have to be taken as a matter of urgency.

この様な事態に対して公知技術が焼却灰を熔融してその
過程に於いて有害物質を別溜処理をして砂状粗粒子とし
て路盤材等に転用せんとする手段は重大なる進歩である
In response to such a situation, a known technology has developed a method of melting incineration ash, separately distilling harmful substances in the process, and converting it into sand-like coarse particles for use in roadbed materials, etc., which is a significant advance. .

しかし乍らこの様にして造成される粗粒子はガラス状の
脆弱体にして且軽比重のものであるから単体を以って路
盤材とする事は不可能であって天然砂に適量に混入され
て使用されるものであるからその消化量には限界がある
のである。
However, the coarse particles created in this way are glass-like, brittle, and have a light specific gravity, so it is impossible to use them alone as a roadbed material, so they are mixed in an appropriate amount with natural sand. Because it is used as a food, there is a limit to how much it can be digested.

一方産業構造の大変革期に当面した我国情は内需拡大政
策を以って各種建造物の造成並びに宅地造成等が活発と
なり、伴って砂利の需要は益々増大化される状況にあり
乍らその供給は天然川砂利の採取禁止を以って砕石砂利
に活路を求めざるを得ずして当業界は苦慮しているので
ある。
On the other hand, the situation in our country, which is currently undergoing a period of major change in the industrial structure, is that the construction of various buildings and residential land has become active due to the policy of expanding domestic demand, and as a result, the demand for gravel is increasing even further. Due to the ban on the extraction of natural river gravel, the industry has been forced to turn to crushed gravel for supply, and this industry is struggling.

かかる事情を以って公知技術を更に前進せしめてこれを
砂利に造成する事が可能となれば、国を挙げてその処分
に苦慮せる焼却灰が全量渇望して止まない砂利に変身す
ることとなってその利する処は正に甚大である。
Under these circumstances, if it becomes possible to further advance the known technology and turn it into gravel, all of the incineration ash, which the entire country is struggling to dispose of, will be transformed into gravel, which is in desperate need. The benefits of this are truly enormous.

二8問題を解決するための手段 塵芥焼却灰は1500度迄高熱化すると焼却灰中に残留
せる各種金属も陶磁器破片類やガラス類も殆どが熔融化
され同時に含有有害物質も別溜処理され、該熔融体より
金属類を分離除去するとその内容は陶磁器破片やガラス
類に依る珪素化合物と可燃性物質に依る炭素化合物並び
に少量ツカルシウム化合物に大別されるのである。
Measures to solve the 28 problems When the garbage incineration ash is heated to 1500 degrees, most of the various metals, ceramic shards, and glass remaining in the incineration ash are melted, and at the same time, the harmful substances contained are separately treated. When the metals are separated and removed from the melt, the contents are roughly divided into silicon compounds from ceramic fragments and glass, carbon compounds from combustible materials, and a small amount of calcium compounds.

そこでこれと適量のカルシウム系添加物質を混合して適
当な時間と高熱を以って融合し、これを徐冷硬化せしめ
れば相当な強度を有する石化状となり得るものと判断さ
れるのである。
Therefore, it has been determined that if this is mixed with an appropriate amount of calcium-based additives, fused for an appropriate amount of time and at high heat, and then slowly cooled and hardened, it can become a petrified material with considerable strength.

(発明の構成) ホ0作用及び実施例 焼却灰の石化処理に関する処理熱量と添加融合するべき
カルシウム系物質につき厖大量の実験資料を以って検討
せる結果、添加物質をセメントとして1200度前後に
て一定時分熔融してこれを徐冷処理すると天然石に匹敵
した強度の石状硬化物を造成し得ることが判明したので
ある。
(Structure of the Invention) As a result of examining the amount of processing heat related to the mineralization treatment of incinerated ash and the calcium-based substances to be added and fused using a large amount of experimental data, it was found that the additive substance was used as cement at around 1200 degrees Celsius. It was discovered that by melting it for a certain period of time and then slowly cooling it, it was possible to create a stone-like hardened product with strength comparable to natural stone.

処が1200度前後では介在する金属類や陶磁器破片類
を完全熔融することは不可能にて一部が熔融残として介
在するのであり、そこでこれを完全熔融するべく 15
00度前後迄加熱すると陶磁器破片類やガラス類は原形
が完全に破壊されて融合し、又各種金属類も完全熔融し
て熔融容器の下部に沈降して一体化するのであるが、こ
こで問題となる事態は焼却灰中に多量に介在する可燃性
難燃物質が激しく燃焼しつつ多量のガスを発生し、これ
を徐冷化しても徐冷化中にも尚多量のガスが発生するた
め石状硬化物は気泡に依る多くの空洞を内蔵しこのため
脆弱化されてしまうのである。
However, at around 1200 degrees, it is impossible to completely melt the intervening metals and ceramic fragments, and some of them remain as unmolten residue, so in order to completely melt them.
When heated to around 00 degrees, the original shapes of ceramic fragments and glass are completely destroyed and they fuse together, and various metals are also completely melted and settle to the bottom of the melting container and become integrated, but there is a problem here. This situation occurs because a large amount of combustible flame retardant substances present in the incineration ash burn violently and generate a large amount of gas, and even if this is slowly cooled, a large amount of gas is still generated during slow cooling. The stone-like hardened material contains many cavities due to air bubbles, which makes it brittle.

そして又理想的石状硬化物とするためには何としても1
200度前後が適当である要素と、陶磁器破片やガラス
類の完全熔融、並びに発生ガスの処理と各種金属類の除
去手段を何としても一括処理しなくてはならなくなるの
であるがここに於いて本願発明は苦慮しつつ意外な解決
手段を見出したのである。
Also, in order to make an ideal stone-like hardened product, 1
At this point, it is necessary to ensure that the temperature is around 200 degrees, complete melting of ceramic fragments and glass, treatment of generated gas, and means of removing various metals all at once. The present invention has found an unexpected solution after much consideration.

本願発明は先ず焼却灰のみを一旦1500度前後に加熱
処理をしてこれを自然冷却硬化せしめると陶磁器破片や
ガラス類並びにこれに類似する物質は全て燃焼熔融して
黒褐色ガラス状硬化物に造成され、〜又各種金属はこれ
又完全熔融して合金一体化され比重比を以って下部に沈
降して黒褐色ガラス状硬化物とは分離した金属塊となる
のである。
In the present invention, first, only the incineration ash is heated to around 1500 degrees, and then it is naturally cooled and hardened, and all of the ceramic fragments, glass, and similar substances are burned and melted to form a dark brown glass-like hardened product. The various metals are also completely melted and integrated into an alloy, which settles to the bottom with a specific gravity ratio to form a metal lump that is separated from the dark brown glass-like cured product.

そして又一旦1500度前後迄高熱処理された該硬化物
はこれを再加熱した処で1200度前後を限界とすれば
該時点に於ける可燃性物質は既に燃焼し尽されたもので
あるから改めてガス発生となる危惧はないのである。
Furthermore, once the cured product has been subjected to high heat treatment to around 1,500 degrees Celsius, if it is reheated to around 1,200 degrees Celsius, the combustible material at that point has already been burned out, so let's take a look again. There is no risk of gas generation.

ここに於いて上記黒褐色ガラス状硬化物とセメントを混
合して改めて1200度前後に加熱すると、今度はセメ
ント中に介在する微量の可燃性物質に依る微量のガス発
生を見るがこれは一定時分の経過を以って殆ど燃焼し尽
した熔融体となり、これを徐冷硬化せしめると灰褐色の
石状体となり外見強度共に天然石と全く同一な石塊が造
成されるのであり、若干の空洞は点在するがその一軸圧
縮強度は800kg/cnl程度となってこれは天然岩
石に於ける深成岩岩盤にて白亜期後期以降の花崗岩の平
均的−軸圧縮強度に匹敵するものであり、その用途は路
盤材は勿論一般建築用コンクリート骨材として充分に使
用され得るものである。
At this point, when the black-brown glassy hardened material and cement are mixed and heated again to around 1200 degrees, a small amount of gas is generated due to a small amount of flammable material present in the cement, but this occurs over a certain period of time. As a result, the molten material is almost completely burned out, and when it is slowly cooled and hardened, it becomes a grayish-brown stone, creating a stone mass that is exactly the same in appearance and strength as natural stone, but with some cavities. The unconfined compressive strength of these rocks is about 800 kg/cnl, which is comparable to the average axial compressive strength of granite from the late Cretaceous period onward, which is a plutonic natural rock. It can of course be used satisfactorily as a roadbed material and as a concrete aggregate for general construction.

へ8発明の効果 本願発明に依って国土全域の地下汚染とその処理対策に
苦慮せる一般都市の厖大量塵芥焼却灰が一転して益々そ
の需給関係に於いて逼迫しつつある砂利に活用されるこ
ととなって正に国家的重大福音となるのである。
8 Effects of the Invention With the present invention, the large amount of garbage incineration ash in general cities, which are struggling with underground pollution throughout the country and its treatment measures, will be turned around and used for gravel, where the supply and demand relationship is becoming increasingly tight. As a result, it truly becomes a nationally important gospel.

処が本願発明に依って造成される砂利は製造原価を単純
比較する時は相当なる差異による経済的要因を以って画
餅に帰する憾に当面するがこれは余りにも短絡的見解で
ある。
However, when we simply compare the manufacturing costs of the gravel produced according to the present invention, it is a shame that it comes down to the economic factors due to the considerable difference, but this is an overly short-sighted view.

何故ならば現在各自治体が埋立処理をしている土地は殆
どが民有地であって、これを借受けた上にて相当深度に
掘削埋立をした後更に一定量の表土を冠し周囲の土壌と
同一状態に復元して返還しているのであるから土地の賃
借料と運搬埋立処理料は厖大である。
This is because most of the land currently being reclaimed by local governments is privately owned land, which is leased, excavated to a considerable depth, and then topped with a certain amount of topsoil to blend with the surrounding soil. Since the land is being restored and returned to the same condition, the land rental fees and transportation and landfill fees are enormous.

そして又焼却灰中より回収される各種金属に依る合金体
は約20%であってこれは鋳鉄増量材等その他の用途と
して充分に換金される等を以って相当量に補填されるも
のである。
Furthermore, the amount of alloyed materials recovered from the incineration ash is approximately 20%, and this amount is compensated for by being converted into cash for other uses such as cast iron fillers. be.

これ等に依って尚若干量として残存する差異は上記の如
き国家的問題として各自治体に於ける塵芥処理料の特別
徴収や各自治体や国庫補助等が連用されるべきものと思
考するのである。
We believe that the differences that still remain due to these factors should be treated as a national problem and should be subject to special collection of garbage disposal fees by each local government and subsidies from each local government and the national treasury.

以  上 乎続補正書 昭和62年 3月 5日that's all Continuing amendment March 5, 1986

Claims (1)

【特許請求の範囲】[Claims] 都市にて発生する塵芥焼却灰を一旦1500度前後に加
熱熔融して該時点に於ける発生ガスを処理して自然冷却
硬化体とし、該硬化体中に比重比を以って沈澱硬化せる
各種金属に依る合成金属塊を除去して焼却灰に依る硬化
体を造成し、該焼却灰硬化体と適量のセメントを混和し
て一定時間1200度前後に加熱熔融した上加熱を止め
て徐冷硬化して石状塊を造成し、これを破砕して砂利と
する如きを特徴とする塵芥焼却灰を利用した砂利の製造
方法。
Various types of waste incineration ash generated in cities are once heated and melted to around 1500 degrees, the gas generated at that point is treated, natural cooling is made into a hardened body, and the hardened body is precipitated at a specific gravity ratio in the hardened body. Synthesis of metal The metal lump is removed to create a hardened body of incinerated ash, and the hardened incinerated ash is mixed with an appropriate amount of cement, heated and melted at around 1200 degrees for a certain period of time, and then the heating is stopped and slowly cooled and hardened. A method for producing gravel using garbage incineration ash, which is characterized by creating stone-like lumps, which are then crushed to become gravel.
JP62011296A 1987-01-22 1987-01-22 Manufacture of gravel from garbage incinerated ash Granted JPS63182241A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62011296A JPS63182241A (en) 1987-01-22 1987-01-22 Manufacture of gravel from garbage incinerated ash

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62011296A JPS63182241A (en) 1987-01-22 1987-01-22 Manufacture of gravel from garbage incinerated ash

Publications (2)

Publication Number Publication Date
JPS63182241A true JPS63182241A (en) 1988-07-27
JPH0319178B2 JPH0319178B2 (en) 1991-03-14

Family

ID=11774033

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62011296A Granted JPS63182241A (en) 1987-01-22 1987-01-22 Manufacture of gravel from garbage incinerated ash

Country Status (1)

Country Link
JP (1) JPS63182241A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003010108A2 (en) 2001-07-23 2003-02-06 Ash Dec Umwelt Ag Method for rendering filter and fly ash inert

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56164063A (en) * 1980-05-20 1981-12-16 Daido Steel Co Ltd Manufacture of aggregate
JPS57200259A (en) * 1981-05-30 1982-12-08 Daido Steel Co Ltd Manufacture of hard aggregate from wastes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56164063A (en) * 1980-05-20 1981-12-16 Daido Steel Co Ltd Manufacture of aggregate
JPS57200259A (en) * 1981-05-30 1982-12-08 Daido Steel Co Ltd Manufacture of hard aggregate from wastes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003010108A2 (en) 2001-07-23 2003-02-06 Ash Dec Umwelt Ag Method for rendering filter and fly ash inert

Also Published As

Publication number Publication date
JPH0319178B2 (en) 1991-03-14

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