JPS63174908A - Termite-controlling agent and method for vermin-proofing of wood using said agent - Google Patents
Termite-controlling agent and method for vermin-proofing of wood using said agentInfo
- Publication number
- JPS63174908A JPS63174908A JP882687A JP882687A JPS63174908A JP S63174908 A JPS63174908 A JP S63174908A JP 882687 A JP882687 A JP 882687A JP 882687 A JP882687 A JP 882687A JP S63174908 A JPS63174908 A JP S63174908A
- Authority
- JP
- Japan
- Prior art keywords
- termite
- agent
- wood
- tungsten
- molybdenum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 29
- 239000002023 wood Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 3
- 241000256602 Isoptera Species 0.000 claims abstract description 25
- 239000005078 molybdenum compound Substances 0.000 claims abstract description 16
- 150000002752 molybdenum compounds Chemical class 0.000 claims abstract description 16
- 150000003658 tungsten compounds Chemical class 0.000 claims abstract description 16
- 239000005667 attractant Substances 0.000 claims abstract description 5
- 230000031902 chemoattractant activity Effects 0.000 claims abstract description 5
- 241000238631 Hexapoda Species 0.000 claims description 3
- 230000000749 insecticidal effect Effects 0.000 abstract description 14
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 235000015393 sodium molybdate Nutrition 0.000 abstract description 6
- 239000011684 sodium molybdate Substances 0.000 abstract description 6
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 abstract description 6
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011575 calcium Substances 0.000 abstract description 3
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 239000002917 insecticide Substances 0.000 abstract description 3
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 abstract description 2
- 239000003755 preservative agent Substances 0.000 abstract description 2
- 239000005944 Chlorpyrifos Substances 0.000 abstract 1
- 241000222354 Trametes Species 0.000 abstract 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 abstract 1
- 229960000490 permethrin Drugs 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000000077 insect repellent Substances 0.000 description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 10
- 229910052750 molybdenum Inorganic materials 0.000 description 10
- 239000011733 molybdenum Substances 0.000 description 10
- 229910052721 tungsten Inorganic materials 0.000 description 10
- 239000010937 tungsten Substances 0.000 description 10
- 230000002195 synergetic effect Effects 0.000 description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 9
- 241000607479 Yersinia pestis Species 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000254173 Coleoptera Species 0.000 description 3
- 230000002262 irrigation Effects 0.000 description 3
- 238000003973 irrigation Methods 0.000 description 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- -1 re Species 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 241000252233 Cyprinus carpio Species 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 241000257303 Hymenoptera Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 2
- 235000018660 ammonium molybdate Nutrition 0.000 description 2
- 239000011609 ammonium molybdate Substances 0.000 description 2
- 229940010552 ammonium molybdate Drugs 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 229960000686 benzalkonium chloride Drugs 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- KGURSDWHGSLAPP-UHFFFAOYSA-N 4-bromo-2,6-dichlorophenol Chemical compound OC1=C(Cl)C=C(Br)C=C1Cl KGURSDWHGSLAPP-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910004829 CaWO4 Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910004619 Na2MoO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000195888 Physcomitrella Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical group [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 1
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 1
- 229950006824 dieldrin Drugs 0.000 description 1
- NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 229950001664 phoxim Drugs 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- TUCCZSRGFGBTOQ-UHFFFAOYSA-J terephthalate;tin(4+) Chemical compound [Sn+4].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 TUCCZSRGFGBTOQ-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は木材を加害するシロアリを対象とする白アリ防
除剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a termite control agent that targets termites that damage wood.
近年、木材を食害する害虫、例えばシフアリ、フナクイ
ムシ、ヒラタキクイムシ等の被害が問題となっている。In recent years, damage caused by pests that feed on wood, such as wood ants, carp beetles, and flat-eared wood beetles, has become a problem.
これらの害虫に食害されないために、あらかじめ用材に
適1−だ防虫剤処理が従来より行われ、この目的のため
、殺虫、防虫成分としてクロルデン、ディルドリン等の
有機塩素系殺虫剤が使われてきた。In order to prevent damage from these pests, materials have traditionally been treated with an appropriate insect repellent, and for this purpose, organic chlorine insecticides such as chlordane and dieldrin have been used as insecticidal and insect repellent ingredients. .
しかしながら、これらの防虫成分はいずれも残留性、毒
性、刹檄性、環境汚染などの点で問題があり、低毒性の
防虫剤の開発が望まれている。However, all of these insect repellent ingredients have problems in terms of persistence, toxicity, decomposition, environmental pollution, etc., and the development of low-toxicity insect repellents is desired.
ところで、公開特許公報昭59−82309号の開示に
よれば、モリブデン及びタングステンより成る群より選
ばれる元素の有効に可溶性の化合物が窒素周定をする動
物を抑制することが提案されている。この発見は、
1、モリブデンやタングステンは安価である。By the way, according to the disclosure of Japanese Patent Publication No. 59-82309, it has been proposed that an effectively soluble compound of an element selected from the group consisting of molybdenum and tungsten suppresses animals that circumscribe nitrogen. This discovery is as follows: 1. Molybdenum and tungsten are cheap.
2、クロムや他の金属より安全性が高い。2.It is safer than chromium and other metals.
3、モリブデンやタングステンはシロアリやフナクイム
シ等窒素固定をする動物以外の害虫に毒性を示さず、選
択性が高い。3. Molybdenum and tungsten are not toxic to pests other than nitrogen-fixing animals such as termites and carp beetles, and are highly selective.
4、遅効性であり、それ故、白アリ等に忌避されること
はない。4. It is slow-acting, so it is not repelled by termites etc.
5、種々の形で安定である。5. Stable in various forms.
等の点で木材用防虫剤として極めて有用なものであるが
、その殺虫、防虫効果は、モリブデン化合物あるいはタ
ングステン化合物単独施用では必ずしも十分なものとは
いえない問題点があった。Although it is extremely useful as an insect repellent for wood in these respects, there is a problem in that its insecticidal and insect repellent effects are not necessarily sufficient when a molybdenum compound or a tungsten compound is applied alone.
しかるに、本発明者らは、更に実用的な見地からモリブ
デン化合物とタングステン化合物の混合物を検討した結
果、殺虫、防虫効果に著しい相乗効果が観察されること
を知シ、本発明を完成した(公開特許公報昭59−82
309号には、「モリブデン及びタングステンの一方又
は両者の化合物、好ましくは塩を含有する」という記載
があるが、同化合物の混合の実施例はなく、もちろん混
合による相乗効果に関する知見は全く開示されていない
。)その相乗効果の機構については不明な点が多いが、
モリブデン化合物とタングステン化合物の白アリに対す
る殺虫作用機構の差異に起因するものと考えられる。However, as a result of further studying the mixture of molybdenum compounds and tungsten compounds from a practical standpoint, the present inventors found that a remarkable synergistic effect was observed in insecticidal and insect repellent effects, and completed the present invention (published in the publication). Patent Publication 1982-82
No. 309 states that it "contains a compound, preferably a salt, of one or both of molybdenum and tungsten," but there are no examples of mixing the same compounds, and of course, no knowledge regarding the synergistic effect of mixing is disclosed. Not yet. ) Although there are many unknowns about the mechanism of the synergistic effect,
This is thought to be due to the difference in the mechanism of insecticidal action of molybdenum compounds and tungsten compounds against termites.
すなわち、タングステン化合物は公開特許公報59−8
2309号に記載されているように、シロアリの腸内で
共生生活を営む原生動物の窒素固定を阻害する作用の寄
与が大きいのに対し、モリブデン化合物のメインの殺虫
機構については、その酸化物のシロアリ体内への蓄積に
あることがほぼ確かめられ、同作用が相まって相乗的に
殺虫効果を増強させるものと推定される。これまで、モ
リブデン化合物とタングステン化合物の白アリに対する
殺虫作用は、一般に同機構で論じられており、両者の混
用が相乗効果を示すという本発見は従来の知見からは全
く予期されないものである。That is, the tungsten compound is disclosed in Japanese Patent Publication No. 59-8.
As described in No. 2309, the main insecticidal mechanism of molybdenum compounds is that the main insecticidal mechanism of molybdenum compounds is due to the action of inhibiting nitrogen fixation by protozoa that live symbiotically in the intestines of termites. It has been confirmed that the substance accumulates in the termite body, and it is presumed that the same effects combine to synergistically enhance the insecticidal effect. Until now, the insecticidal effects of molybdenum compounds and tungsten compounds against termites have generally been discussed by the same organization, and this discovery that the combined use of the two exhibits a synergistic effect is completely unexpected based on conventional knowledge.
本発明の白アリ防除剤で用いられるモリブデン化合物と
しては例えばモリブデン酸ナトリウム(Na2MoO4
) =無水モリブデン酸(MoO3) 。Examples of molybdenum compounds used in the termite control agent of the present invention include sodium molybdate (Na2MoO4
) = molybdic anhydride (MoO3).
モリブデン酸(H2MOO4) 、モリブデン酸第−鉄
(FeMoO、モリブデン酸ニアンモニウム〔(NF2
)2MO207) 、モリブデン鉱石などがあげられ、
モリブデン単体も広義に含まれる。Molybdic acid (H2MOO4), ferrous molybdate (FeMoO, ammonium molybdate [(NF2
)2MO207), molybdenum ore, etc.
Molybdenum alone is also included in a broad sense.
一方、タングステン化合物としては、タングステン酸ナ
トリウム(lfa2WO4)−タングステン酸力yv’
yウム(CaWO4) 、あるいはタングステン単体な
どがあげられるがもちろんこれらのみに限定されるもの
ではない。On the other hand, as a tungsten compound, sodium tungstate (lfa2WO4)-tungsten acid power yv'
Examples include yum (CaWO4) and tungsten alone, but the material is not limited to these.
本発明臼アリ防除剤は、モリブデン及びタングステンの
それぞれの群から選ばれた1ないしは2以上の化合物を
混合することを特徴とし、使用されるモリブデン化合物
、タングステン化合物の組成、性状は問わない。The mortar ant control agent of the present invention is characterized by a mixture of one or more compounds selected from the respective groups of molybdenum and tungsten, and the composition and properties of the molybdenum compound and tungsten compound used are not limited.
例えば、モリブデン化合物及びタングステン化合物は一
般に水溶性の金属塩の形で用いられるが、必要に応じて
、他の無機物あるいは有機物とコンプレックスを形成さ
せることKよシ、不溶性の化合物に転換してもよい。For example, molybdenum compounds and tungsten compounds are generally used in the form of water-soluble metal salts, but if necessary, they may be converted into insoluble compounds by forming complexes with other inorganic or organic substances. .
各白アリ防除剤には殺虫、防虫成分としてモリブデン化
合物とタングステン化合物とを0.01〜90重景%含
重量ることができ、相乗効果を奏するモリブデン化合物
とタングステン化合物との混合比は1:10〜10:1
(好ましくは1:4〜4:1)が適当である。Each termite control agent can contain 0.01 to 90% by weight of a molybdenum compound and a tungsten compound as insecticidal and insect repellent ingredients, and the mixing ratio of the molybdenum compound and tungsten compound to have a synergistic effect is 1: 10-10:1
(preferably 1:4 to 4:1) is suitable.
また、殺虫、防虫効果をより効率的に発揮させるために
、白アリ誘引剤が好適に配合される。Furthermore, a termite attractant is suitably blended in order to exhibit insecticidal and insect repellent effects more efficiently.
白アリ誘引剤としては、例えばナミダタケ腐朽物、キチ
リメンタケ腐朽物があげられ、腐朽木片を適当な大きさ
に調整して製剤化してもよいし、腐朽木片からの溶剤抽
出物を殺虫、防虫成分に添加することも可能である。As a termite attractant, for example, rotten material of Physcomitrella sp. It is also possible to add.
更に、本発明の白アリ防除剤に、例えば、クロμピリホ
ス、ホキシム、ピリダフェンチオンなどの有機リン剤、
べμメトリン、フルパリネート、フェンバレレート、フ
ェンプロパスリンなどのピレスロイド剤、あるいはトリ
プロピρイソシアヌV−ト、カーバメート剤などの他の
殺虫剤、あるいは、S−421,ピベロニμブトキサイ
ドなどの共力剤を加えたり、また、次に示すような種々
のタイプの防腐剤
0CCA系化合物−CCA、CCBなどOハロフェノー
ル系化合物−ベンタクロμフェ二μラウレート、p−ブ
ロモ−2,6−ジクロルフェノールなど
0ヨ一ドプロパμギp系化合物−IB’−1000゜3
−ヨード−2−グロビニルブチルカーパメートなど
O第4級アンモニウム化合物およびアミン塩−ベンザル
コニウムクロリド、ジアルキpジメチμアンモニウムク
ロリドなど
・有機スズ化合物−ビス−(n−トリブチルスズ)オキ
シド、トリブチμスズテレフタレートなど
Oその他−ナフテン酸亜鉛、キシリゲンアルミニウム塩
など
を適宜混合して有用な多目的組成物を得ることもできる
。Furthermore, the termite control agent of the present invention may include organic phosphorus agents such as cloμ pyrifos, phoxim, and pyridafenthione;
Addition of pyrethroid agents such as betamethrin, fluparinate, fenvalerate, and fenpropathrin, or other insecticides such as tripropisocyanate, carbamates, or synergists such as S-421 and piperoni μbutoxide. In addition, various types of preservatives such as CCA compounds - CCA, CCB, etc. - O-halophenol compounds - bentacroμpheniμlaurate, p-bromo-2,6-dichlorophenol, etc. Dopropyl p-based compound-IB'-1000゜3
- Quaternary ammonium compounds and amine salts such as iodo-2-glovinylbutyl carpamate - Benzalkonium chloride, dialkyp dimethymu ammonium chloride, etc. - Organotin compounds - Bis-(n-tributyltin) oxide, tributyltin A useful multipurpose composition can also be obtained by appropriately mixing tin terephthalate, etc., zinc naphthenate, xyligen aluminum salt, and the like.
本発明の目的は、さらに、木材の防虫手段として本発明
の白アリ防除剤を提供することにある。A further object of the present invention is to provide the termite control agent of the present invention as a means for controlling wood insects.
白アリ防除剤の適用方法としては従来の方法例えば木材
に加圧注入する方法、木材に塗布する方法、あるいは家
屋下や周囲の土壌を処理する方法がそのまま用いること
ができ、史に、白アリ防除用ベイト剤、あるいは着色ペ
イントやニス等に含浸させて白アリ予防コーティング剤
として適用することも可能である。Conventional methods such as pressurized injection into wood, coating on wood, or treating the soil under and around houses can be used as a method for applying termite control agents. It is also possible to apply it as a termite prevention coating agent by impregnating it with a bait agent for pest control, or colored paint or varnish.
ベイト剤として用いる場合、セルロース錠剤、つまり、
水、紙、厚紙、木片又は綿のようなセルロース系物質に
必要ならば誘引剤とともに本発明組成物を含浸すればよ
い。When used as a bait, cellulose tablets, i.e.
Water, cellulosic materials such as paper, cardboard, wood chips or cotton may be impregnated with the composition of the invention, along with an attractant if necessary.
本発明白アリ防除剤の剤型としては、防除剤の性状、使
用目的によシ、油剤、乳剤、水利剤、水溶剤、粉剤、エ
アゾール剤など種々可能であり、殺虫、防虫成分として
モリブデン化合物とタングステン化合物とが、0.01
〜90重量%配合される。The present invention's clear ant control agent can be in various forms depending on the properties of the control agent and the purpose of use, such as oil solutions, emulsions, irrigation agents, water solutions, powders, and aerosols. and the tungsten compound are 0.01
~90% by weight is blended.
いずれの製剤も常法に従って調製することができ、固体
担体としては粘土類(カオリン、ベントナイト類など)
、りμり類などの微粉末ないし、粉状物があげられる。Both formulations can be prepared according to conventional methods, and solid carriers include clays (kaolin, bentonites, etc.).
Examples include fine powders such as sludge and powders.
液体担体としては、水、アルコール類などが一般的で、
その他適宜界面活性剤や、あるいは、カゼイン、ゼラチ
ン、でんぷんff1.cMc、ポリビニルアルコ−ル
される。Common liquid carriers include water and alcohols.
Other appropriate surfactants, casein, gelatin, starch ff1. cMc, polyvinyl alcohol.
以下、本発明による相乗効果を一層明確にするため、実
際の試験例について説明す名が本発明がこれらに限定さ
れるものでないことはもちろんである。Hereinafter, in order to further clarify the synergistic effect of the present invention, actual test examples will be described, but it goes without saying that the present invention is not limited to these.
試験例1
直径60のろ紙に、所定濃度のモリブデン酸ナトリウム
とタングステン酸ナトリウムを含有する水溶剤を1−滴
下して1日間風乾した後、同じく直径6−の深底シャー
レの底に置いた。ヤマトシロアリの職蟻30匹を放ち、
シャーレのフタをして28±2°C,90RHの条件で
飼育し一定時間毎に死生率を調べた。Test Example 1 One drop of an aqueous solvent containing sodium molybdate and sodium tungstate at a predetermined concentration was added to a filter paper with a diameter of 60 mm, air-dried for 1 day, and then placed on the bottom of a deep-bottom Petri dish with a diameter of 6 mm. Release 30 worker ants of Yamato termites,
The petri dish was covered with a lid and kept at 28±2°C and 90RH, and the mortality rate was checked at regular intervals.
その結果を次表に示す。The results are shown in the table below.
試験の結果、モリブデン酸ナトリウムとタングステン酸
ナトリウムの混合防除剤が、同濃度水準にある単独防除
剤に比べ顕著な相乗効果を示すことが確認された。(図
1参照)試験例2
1XIX10cjnの松柱に所定濃度のモリブデン51
1−eとタングステン酸力μシウムヲ含有する水利剤を
100g/rrfの割合で2回塗布し、深底シャーレの
底に置いた。イエシロアリの職蟻20匹を放ち、シャー
レのフタをして25±1°G,85RH以上の条件下で
飼育し一定時間毎に死生率及び木片の食害度(重量減少
率)を調べた。As a result of the test, it was confirmed that a mixed pest control agent of sodium molybdate and sodium tungstate exhibited a remarkable synergistic effect compared to a single pesticide at the same concentration level. (See Figure 1) Test Example 2 A predetermined concentration of molybdenum 51 on a 1XIX10cjn pine post
An irrigation agent containing 1-e and tungsten acid µsium was applied twice at a rate of 100 g/rrf and placed on the bottom of a deep petri dish. Twenty worker termites were released and kept in a petri dish with a lid under conditions of 25±1°G and 85RH or higher, and the mortality rate and the degree of damage to wood chips (weight loss rate) were checked at regular intervals.
試験の結果、モリブデン酸第−鉄とタングステン酸カル
シウムの混合防除剤においても試験例1と同様顕著な相
乗効果が認められた。As a result of the test, similar to Test Example 1, a remarkable synergistic effect was observed in the mixed pest control agent of ferrous molybdate and calcium tungstate.
次に本発明の実施例を示すが本発明はもちろんこれらの
みに限定されない。Next, examples of the present invention will be shown, but the present invention is of course not limited to these.
実施例1
モリブデン酸ナトリウム1部、タングステン酸ナトリウ
ム2部、3−ヨード−2−プロビニpブチρカーバメー
ト1部、珪藻土35部、クレー56部、フウリμスルホ
ン酸塩3部、力μポキシメチルセμローズ2部を粉砕混
合して水利剤を得る。これを水で希釈して防虫、防腐加
工する木材の表面に散布又は塗布するか、希釈液に木材
を浸漬する。Example 1 1 part of sodium molybdate, 2 parts of sodium tungstate, 1 part of 3-iodo-2-provinyl p-buty-rho carbamate, 35 parts of diatomaceous earth, 56 parts of clay, 3 parts of fulric acid sulfonate, 3 parts of poxymethylcellulose Two parts are ground and mixed to obtain an irrigation agent. This is diluted with water and sprayed or coated on the surface of the wood to be treated for insect repellency and antiseptic treatment, or the wood is immersed in the diluted solution.
実施例2
アμキルレゾμシノーμを主成分とするり二μオイル・
レゾ〜シノールホyムアルデヒド81111170部と
、モリブデン鉱石5部、タングステン酸カルシウム10
部、クロpピリホス3部、トリブチルスズテレフタレー
ト12部とを十分かく拌混合して防虫、防腐処理剤を得
る。この糊液を厚さ1.4mm、含水率10%のラワン
単板の両面に、片面当り13g/900iの割合で塗布
し、その両面に厚さ0.7mm、含水率14〜15%の
ラワン単板をそれぞれ重ね合わせて、常温下、10Kg
/cllの圧力で20分間圧縮した後、温度120°C
に保ったホットプレスに挿入して9Kf/cdの圧力で
1分間熱圧し、合板を得る。Example 2 Ri2μ oil containing AμKilResoμSinoμ as the main component.
81111170 parts of reso-sinol formaldehyde, 5 parts of molybdenum ore, 10 parts of calcium tungstate
1 part, 3 parts of clop-pyrifos, and 12 parts of tributyltin terephthalate are sufficiently stirred and mixed to obtain an insect repellent and antiseptic treatment agent. This size solution was applied to both sides of a lauan veneer with a thickness of 1.4 mm and a moisture content of 10% at a rate of 13 g/900i per side, and on both sides a lauan veneer with a thickness of 0.7 mm and a moisture content of 14 to 15% was applied. Each veneer is stacked on top of each other and weighs 10kg at room temperature.
After compressing for 20 minutes at a pressure of /cll, the temperature is 120°C.
The sample was inserted into a hot press maintained at a temperature of 9 Kf/cd and hot pressed for 1 minute to obtain plywood.
この合板は白アリ食害テストに供試した時、1ケ月を経
ても高い食害防止効果を示した。When this plywood was subjected to a termite damage test, it showed a high effectiveness in preventing damage even after one month.
一方、殺虫、防虫成分としてタングステン酸力〜シウム
15部十りロμピリホス3部を使用した以外は同様に処
理して得られた対照の合板には軽度の食害が観察された
。On the other hand, mild feeding damage was observed in a control plywood obtained by the same treatment except that 15 parts of tungsten acid to 3 parts of μpyrifos were used as insecticidal and insect repellent ingredients.
実施例3
モリブデン酸ニアンモニウム196i、タングステン酸
ナトリウム1%、ベンザルコニウムクロリド1%の水溶
剤10rneをα−セルローズ1gと混合し、ベレット
状に成型してベイト剤を得る。これを家屋下、周囲の土
壌中に配置したところ、共喰いにより白アリの県全体を
退治し、家屋への被害を防止できた。Example 3 10 rne of an aqueous solvent containing 196i of ammonium molybdate, 1% of sodium tungstate, and 1% of benzalkonium chloride is mixed with 1 g of α-cellulose and molded into a pellet to obtain a bait agent. When these were placed under houses and in the surrounding soil, they exterminated entire areas of termites through cannibalism and prevented damage to houses.
一方、殺虫、防虫成分としてモリブデン酸ニアンモニウ
ム2%を配合した以外は同様に稠製した対照のベイト剤
を用いたところ、県全体を根こそぎ退治するには至らず
、家屋に一部食害を受けた。On the other hand, when a control bait agent prepared in the same manner except for containing 2% niummonium molybdate as an insecticidal and insect repellent ingredient was used, it was not able to eradicate the entire prefecture, but some houses suffered from feeding damage. Ta.
第1図は試験例1の10日後における死去率とモリブデ
ン、タングステン各成分の濃度との関係を示したもので
あり、実線より上部は共力作用領域を示す。
第1図FIG. 1 shows the relationship between the mortality rate after 10 days and the concentrations of molybdenum and tungsten components in Test Example 1, and the area above the solid line shows the synergistic effect region. Figure 1
Claims (3)
含有することを特徴とする白アリ防除剤。(1) A termite control agent characterized by containing both a molybdenum compound and a tungsten compound.
、白アリ誘引剤とともに含有することを特徴とする特許
請求の範囲第(1)項記載の白アリ防除剤。(2) The termite control agent according to claim (1), which contains both a molybdenum compound and a tungsten compound together with a termite attractant.
含有する白アリ防除剤を木材に適用することを特徴とす
る木材の防虫方法。(3) A method for preventing insects from wood, which comprises applying to wood a termite control agent containing both a molybdenum compound and a tungsten compound.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP882687A JPH0768095B2 (en) | 1987-01-16 | 1987-01-16 | Termite control agent and wood insect control method using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP882687A JPH0768095B2 (en) | 1987-01-16 | 1987-01-16 | Termite control agent and wood insect control method using the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63174908A true JPS63174908A (en) | 1988-07-19 |
JPH0768095B2 JPH0768095B2 (en) | 1995-07-26 |
Family
ID=11703598
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP882687A Expired - Lifetime JPH0768095B2 (en) | 1987-01-16 | 1987-01-16 | Termite control agent and wood insect control method using the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0768095B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0242003U (en) * | 1988-09-08 | 1990-03-23 | ||
EP0882398A4 (en) * | 1996-09-30 | 2001-07-04 | Hazama Gumi | Thiobacillus thiooxidans growth inhibitor |
JP2007530704A (en) * | 2004-03-29 | 2007-11-01 | ダウ アグロサイエンシィズ エルエルシー | Insecticide composition |
-
1987
- 1987-01-16 JP JP882687A patent/JPH0768095B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0242003U (en) * | 1988-09-08 | 1990-03-23 | ||
EP0882398A4 (en) * | 1996-09-30 | 2001-07-04 | Hazama Gumi | Thiobacillus thiooxidans growth inhibitor |
JP2007530704A (en) * | 2004-03-29 | 2007-11-01 | ダウ アグロサイエンシィズ エルエルシー | Insecticide composition |
Also Published As
Publication number | Publication date |
---|---|
JPH0768095B2 (en) | 1995-07-26 |
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