JPS6317320B2 - - Google Patents
Info
- Publication number
- JPS6317320B2 JPS6317320B2 JP57089962A JP8996282A JPS6317320B2 JP S6317320 B2 JPS6317320 B2 JP S6317320B2 JP 57089962 A JP57089962 A JP 57089962A JP 8996282 A JP8996282 A JP 8996282A JP S6317320 B2 JPS6317320 B2 JP S6317320B2
- Authority
- JP
- Japan
- Prior art keywords
- detergent
- paste
- weight
- hands
- dirt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 claims description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 239000010457 zeolite Substances 0.000 claims description 10
- 239000004113 Sepiolite Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 235000019355 sepiolite Nutrition 0.000 claims description 8
- 229910052624 sepiolite Inorganic materials 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims 1
- -1 polyoxyethylene Polymers 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940037001 sodium edetate Drugs 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】
本発明は、重質汚れ用ペースト状洗剤に関する
もので、より詳細には、ペースト状であり、手に
吊けてこすり込み、ウエス等の布で拭き取るのみ
で、作業者の手に付着する機械油等の重質汚れを
有効に洗浄除去できる乾式の、即ち水の使用を必
要としない重質汚れ用ペースト状洗剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a paste-like detergent for heavy dirt, and more specifically, it is a paste-like detergent that can be hung in the hand, rubbed in, and wiped off with a cloth such as a rag. The present invention relates to a dry paste detergent for heavy dirt that can effectively wash and remove heavy dirt such as machine oil that adheres to people's hands, that is, does not require the use of water.
従来、各種機械工場や機械の分解乃至は組立或
いは保守点検等に際して、作業者の手に付着する
油汚れを洗浄するための手洗い洗剤としては、ケ
ロシンをペーストとし、これに石鹸等の界面活性
剤或いは更にビルダーを配合したものが使用され
ているが、従来のこの種の手洗い洗剤において
は、脱脂が行われるとしても、洗浄後の手にケロ
シンの臭いやベト付きが残るという問題があり、
これを除去するためにはもう一度水を用い再洗浄
しなければならないという煩わしさがある。 Conventionally, hand-washing detergents used to clean oil stains from workers' hands during disassembly, assembly, maintenance and inspection of various machinery factories and machines have been made using kerosene as a paste and a surfactant such as soap. Alternatively, products containing a builder are used, but with conventional hand washing detergents of this type, even if degreasing is performed, there is a problem that the smell of kerosene and stickiness remain on the hands after washing.
In order to remove this, it is troublesome that it must be washed again using water.
また、パーライト石鹸と呼ばれる粉末状の脱脂
用の手洗い石鹸も知られているが、このものは表
面から水分が揮散し易い欠点があると共に、最後
には水洗しないと油汚れの除去が完全でないとい
う欠点がある。 There is also a powdered degreasing hand washing soap called perlite soap, but this has the disadvantage that water easily evaporates from the surface, and oil stains cannot be completely removed unless it is washed with water at the end. There are drawbacks.
従つて、本発明の目的は水の使用を必要とせず
に、手に付いた機械油等の重質汚れの除去が完全
に行い得るペースト状の重質汚れ用ペースト状洗
剤を提供するにある。 Therefore, an object of the present invention is to provide a pasty detergent for heavy dirt that can completely remove heavy dirt such as machine oil from hands without using water. .
本発明の他の目的は、手に付けてこすり込み、
ウエス等の布で拭き取るという簡単な操作で重質
汚れの洗浄除去が有効に行われる重質汚れ用ペー
スト状洗剤を提供するにある。 Another object of the present invention is to apply it to your hands and rub it in,
To provide a paste-like detergent for heavy dirt that can be effectively cleaned and removed by a simple operation of wiping with a cloth such as a waste cloth.
本発明の更に他の目的は、ウエス等の拭き取り
用布についた汚れが、水洗のみで簡単に除去し得
る重質汚れ用ペースト状洗剤を提供するにある。 Still another object of the present invention is to provide a paste-like detergent for heavy dirt that can easily remove dirt from a wiping cloth such as a rag by simply washing with water.
本発明によれば、界面活性剤の濃厚水性溶液に
対して全体当り5乃至35重量%の合成ゼオライト
粉末及び5乃至25重量%のセピオライトを配合し
たペースト状物から成ることを特徴とする重質汚
れ用ペースト状洗剤が提供される。 According to the present invention, a heavy surfactant is characterized in that it consists of a paste-like material in which 5 to 35% by weight of synthetic zeolite powder and 5 to 25% by weight of sepiolite are blended into a concentrated aqueous solution of a surfactant. A soil paste detergent is provided.
本発明のペースト状洗剤は、合成ゼオライト粉
末及びセピオライトの両者を、洗剤濃厚水溶液当
り一定の量比で含有することが顕著な特徴であ
る。合成ゼオライト粉末とセピオライトとの組合
せは、外力の加わらない条件で、この洗剤組成物
を取扱いの容易なペースト状に維持すると共に、
容器から取出し掌にこすりつけた場合にはよく展
延して、手に付着した機械油等の重質汚れとよく
なじむという特性を示す。しかも、洗剤の作用に
より手の表面から遊離した重質汚れは、ペースト
中の合成ゼオライト粉末及びセピオライトの表面
に取込まれ、かくして手に付けてこすり込んだ後
には、これを布で拭き取ることにより重質汚れの
除去が、手に不快感を残すことなしに有効に行わ
れるのである。更に、合成ゼオライト粉末が、洗
浄に際して優れたビルダー作用を示すことは周知
のことであるが、本発明においては、合成ゼオラ
イト粉末は、ビルダーとしての諸作用(金属イオ
ン封鎖能、緩衝作用、再汚染防止作用)を呈する
他に、汚れの除去に際して所謂研摩作用をも示す
のであつて、これにより重質汚れの除去が完全に
行われるものである。さらに、セピオライトは、
界面活性剤の濃厚水溶液に対し、優れた増粘効果
を示し、手の表面から除去される汚れを手の表面
から浮かせてこれが再付着するのを防止する上で
も有効な作用を示す。 The pasty detergent of the present invention is distinctive in that it contains both synthetic zeolite powder and sepiolite in a fixed ratio of amounts per concentrated aqueous detergent solution. The combination of synthetic zeolite powder and sepiolite maintains the detergent composition in the form of an easy-to-handle paste in the absence of external forces;
When taken out of the container and rubbed on the palm of the hand, it spreads well and has the property of blending well with heavy dirt such as machine oil on the hands. Moreover, the heavy dirt released from the surface of the hands by the action of the detergent is incorporated into the surface of the synthetic zeolite powder and sepiolite in the paste. This allows the removal of dirt and grime to be carried out effectively without leaving any discomfort on the hands. Furthermore, it is well known that synthetic zeolite powder exhibits excellent builder action during cleaning. In addition to exhibiting a preventive action), it also exhibits a so-called abrasive action when removing dirt, thereby completely removing heavy dirt. Furthermore, sepiolite is
It has an excellent thickening effect on concentrated aqueous solutions of surfactants, and is also effective in lifting dirt removed from the surface of the hands and preventing it from re-adhering.
本発明において、合成ゼオライトとしては、A
型ゼオライト、X型ゼオライト等の任意の合成ゼ
オライトの粉末が使用されるが、特に粒度の微細
なA型ゼオライト、例えば一次粒径が2ミクロン
以下、特に1ミクロン以下のA型ゼオライト粉末
(水澤化学工業株式会社製、シルトンB)が有利
に使用される。 In the present invention, the synthetic zeolite is A
Any synthetic zeolite powder such as type zeolite, type Silton B) manufactured by Kogyo Co., Ltd. is advantageously used.
第二成分として配合するセピオライトは、
Mg8H2(Si4O11)3・3H2Oで表わされる結晶性ケイ
酸マグネシウムを主体とする粘土鉱物であり、例
えば、武田薬品工業株式会社からエードプラスの
商品名で市販されている。 Sepiolite, which is blended as the second component, is
It is a clay mineral mainly composed of crystalline magnesium silicate represented by Mg 8 H 2 (Si 4 O 11 ) 3.3H 2 O. For example, it is commercially available from Takeda Pharmaceutical Co., Ltd. under the trade name AED+. .
合成ゼオライト粉末は、界面活性剤の濃厚水曜
液に対して全体当り5乃至35重量%、特に7乃至
20重量%で用いることも重要であり、この量が上
記範囲よりも少ないと前述した種々の利点が得ら
れず、また上記範囲よりも多いとペースト状とし
ての取扱いが困難となり、また経済的にも不利と
なる。 The synthetic zeolite powder contains 5 to 35% by weight, especially 7 to 35% by weight of the surfactant concentrated Wednesday solution.
It is also important to use it at 20% by weight; if this amount is less than the above range, the various advantages mentioned above will not be obtained, and if it is more than the above range, it will be difficult to handle it as a paste, and it will be economically disadvantageous. is also disadvantageous.
また、セピオライトは、前記濃厚水溶液に対し
て全体当り5乃至25重量%、特に7乃至18重量%
の量で用いることも重要であり、この量が上記範
囲よりも少ないと、所望の増粘性や前述した他の
利点が達成されず、一方上記範囲よりも多いと配
合組成物が固くなつて感触や、洗浄作用が失われ
ることになる。 In addition, sepiolite is contained in the concentrated aqueous solution in an amount of 5 to 25% by weight, particularly 7 to 18% by weight.
It is also important to use an amount below the above range and the desired thickening properties and other benefits mentioned above will not be achieved, while above the above range the formulation will become stiff and feel Otherwise, the cleaning action will be lost.
界面活性剤の濃厚水溶液としては、アニオン
系、ノニオン系或いは両性系の各種界面剤の1種
または2種以上の組合せを5乃至50重量%、特に
10乃40重量%の濃度で含有するものが使用され
る。 As a concentrated aqueous solution of surfactant, 5 to 50% by weight of one or a combination of two or more of various anionic, nonionic or amphoteric surfactants may be used.
A concentration of 10 to 40% by weight is used.
界面活性剤としては、石鹸、脂肪酸のモノまた
はジエタノールアミド、ポリオキシエチレンアル
キルエーテル、ポリオキシエチレンアルキルエー
テル硫酸のエタノールアミン塩、ポリオキシエチ
レンアルキルフエノール、ポリオキシエチレンソ
ルビタン脂肪酸エステル、ポリオキシエチレング
リセリン脂肪酸エステル等を挙げることができ
る。 As surfactants, soaps, fatty acid mono- or diethanolamides, polyoxyethylene alkyl ethers, ethanolamine salts of polyoxyethylene alkyl ether sulfuric acid, polyoxyethylene alkyl phenols, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene glycerin fatty acids Examples include esters.
この濃厚水溶液には、プロピレングリコール、
グリセリン等の湿潤剤やエデト酸ナトリウム、ク
エン酸等の金属イオン封鎖剤を含有させることが
でき、更に充填剤、香料、着色料、防カビ剤等の
微量を配合できる。 This concentrated aqueous solution contains propylene glycol,
It can contain a wetting agent such as glycerin and a sequestering agent such as sodium edetate and citric acid, and may further contain trace amounts of fillers, fragrances, colorants, antifungal agents, and the like.
本発明の洗剤は、取扱いの容易なペースト状で
あり、例えばチユーブ容器、他のプラスチツク製
絞り出し容器等に充填して、各種工場、作業場等
における作業者の手洗いに簡便に利用できる。 The detergent of the present invention is in the form of a paste that is easy to handle, and can be filled into, for example, a tube container or other plastic squeeze container, and used for hand washing by workers in various factories, workplaces, etc.
本発明を次の例で説明する。 The invention is illustrated by the following example.
実施例
界面活性剤濃厚水溶液* 76部
シルトンB 11部
エードプラス 11部
シリカ(カープレツクス) 1.6部
香 料 微 量
防カビ剤 微 量
上記組成物を真空釜中で混練し、ペースト状洗
剤を得た。Examples Concentrated aqueous surfactant solution * 76 parts Silton B 11 parts Adeplus 11 parts Silica (Carplex) 1.6 parts Fragrance Trace amount Antifungal agent Trace amount The above composition was kneaded in a vacuum pot to obtain a paste detergent. .
*界面活性剤濃厚水溶液としては、下記処方、
ポリオキシエチレンアルキルエーテル硫酸のトリ
エタノールアミン塩 16
ポリオキシエチレンのアルキルエーテル 12.5
ヤシ油脂肪酸のジエタノールアミド 4
プロピレングリコール 2
エデト酸2ナトリウム 0.2
水 残量
のものを使用した。*For a concentrated aqueous surfactant solution, use the following formula: Triethanolamine salt of polyoxyethylene alkyl ether sulfate 16 Alkyl ether of polyoxyethylene 12.5 Diethanolamide of coconut oil fatty acid 4 Propylene glycol 2 Disodium edetate 0.2 Water Remaining amount I used something.
上記洗剤の洗浄力を試験するため、エンジンオ
イル廃油に、全量当りグリース20重量%及びカー
ボンブラツク5重量%を配合したものを、手に塗
り付けた後、前記洗剤2乃至5gを手の掌に取
り、10秒間まんべんなく手にこすりつけた。しか
る後手をウエスで拭き取つたところ、油汚れの全
てが手から除去された。使用後のウエスを洗剤を
用いることなく水洗したところ、油汚れがウエス
からきれいに洗浄除去された。 In order to test the cleaning power of the above detergent, after applying a mixture of 20% by weight of grease and 5% by weight of carbon black to waste engine oil on the hands, 2 to 5 g of the above detergent was applied to the palm of the hand. I took it and rubbed it evenly on my hands for 10 seconds. After that, when I wiped my hands with a rag, all of the oil stains were removed from my hands. When the used rag was washed with water without detergent, oil stains were completely removed from the rag.
Claims (1)
り5乃至35重量%のゼオライト粉末及び5乃至25
重量%のセピオライトを配合したペースト状物か
ら成ることを特徴とする重質汚れ用ペースト状洗
剤。1 Based on the concentrated aqueous solution of surfactant, 5 to 35% by weight of zeolite powder and 5 to 25% by weight of the total
A paste-like detergent for heavy dirt, characterized by comprising a paste-like substance containing % by weight of sepiolite.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8996282A JPS58206695A (en) | 1982-05-28 | 1982-05-28 | Industrial detergent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8996282A JPS58206695A (en) | 1982-05-28 | 1982-05-28 | Industrial detergent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS58206695A JPS58206695A (en) | 1983-12-01 |
JPS6317320B2 true JPS6317320B2 (en) | 1988-04-13 |
Family
ID=13985308
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8996282A Granted JPS58206695A (en) | 1982-05-28 | 1982-05-28 | Industrial detergent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58206695A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5371111A (en) * | 1976-12-06 | 1978-06-24 | Kao Corp | Detergent composition |
JPS548A (en) * | 1973-04-13 | 1979-01-05 | Henkel Kgaa | Detergent containing waterrinsoluble silicates |
-
1982
- 1982-05-28 JP JP8996282A patent/JPS58206695A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS548A (en) * | 1973-04-13 | 1979-01-05 | Henkel Kgaa | Detergent containing waterrinsoluble silicates |
JPS5371111A (en) * | 1976-12-06 | 1978-06-24 | Kao Corp | Detergent composition |
Also Published As
Publication number | Publication date |
---|---|
JPS58206695A (en) | 1983-12-01 |
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